AU2010267626A1

AU2010267626A1 - Ethylene/vinyl acetate/unsaturated esters terpolymer as an additive for improving the resistance to cold of liquid hydrocarbons such as middle distillates and fuels

Info

Publication number: AU2010267626A1
Application number: AU2010267626A
Authority: AU
Inventors: Erwan Chevrot; Laurent Dalix; Frederic Tort
Original assignee: Total Raffinage Marketing SA
Current assignee: TotalEnergies Onetech SAS
Priority date: 2009-07-03
Filing date: 2010-06-25
Publication date: 2012-02-02
Anticipated expiration: 2030-06-25
Also published as: FR2947558B1; EP2449063B2; FR2947558A1; KR20120040161A; CL2011003342A1; US20120102825A1; KR102002887B1; ES2706903T5; ZA201109307B; MX363328B; CA2765245A1; TW201116617A; EP2449063B1; AU2010267626B2; WO2011001352A1; SG177381A1; JP2012532225A; MX2012000172A; PT2449063T; CN102549120A

Abstract

The invention relates to the use, as an additive improving the resistance to cold and carbide filterability of fuels, of at least one copolymer including: 81 to 87 mol % of at least one alpha-olefin, preferably of at least ethylene; 10.5 to less than 12 mol % of at least one vinyl ester, preferably of at least vinyl acetate; and 1 to 8 mol % of at least one alpha-beta unsaturated monocarboxylic acid ester, preferably of at least ethyl-2 or hexyl acrylate.

Description

ETHYLENE /VINYL ACETATE/UNSATURATED ESTERS TERPOLYMER AS 5 AN ADDITIVE FOR IMPROVING THE RESISTANCE TO COLD OF LIQUID HYDROCARBONS SUCH AS MIDDLE DISTILLATES AND FUELS Technical field. The invention relates to the use of copolymers of a-olefin, vinyl ester and a,p 10 unsaturated carboxylic acid ester, as additives improving cold resistance of fuels and lubricants as well as fuel oils and packages containing these copolymers. Prior art. At a reduced temperature, compositions of hydrocarbons, notably based on middle distillate types containing paraffinic waxes, such as for example diesel fuels and 15 heating oils, exhibit a significant decrease in their flow properties. It is well-known that the crystallization of paraffins is a limiting factor in the use of middle distillates. Also, it is important to prepare diesel fuels adapted to temperatures at which they will be used in motor vehicles, i.e. to the surrounding climate. Generally, cold operability of fuels at -10 *C is sufficient in many hot or temperate countries. But in countries with a cold 20 climate such as the Scandinavian countries, Canada and the countries of North Asia, temperatures of use of the fuels much lower than -20 *C may be attained. The same applies to domestic oils stored outside buildings (houses, apartment blocks,..), This adequacy of cold operability of fuels of the middle distillate type is important, notably for the cold starting of engines. If the paraffins are crystallized at the bottom of the tank, 25 upon starting they may be driven into the fuel circuit and notably block the filters and pre-filters positioned upstream from the injection systems (pump and injectors). Also, when storing domestic oils, paraffins precipitate to the bottom of the tank and may be driven and obstruct the conduits upstream from the pump and from the supply system of the boiler (nozzle and filter). It is obvious that the presence of solids, such as paraffin 30 crystals, prevents normal circulation of the middle distillate. In order to improve their flow either in the engine or towards the boilers, several types of additives have been developed. In a first phase, the petrol industry was committed to developing so-called cold flow additives (cold flow improvers or CFI) promoting dispersion of paraffin crystals 35 and thereby preventing them from organizing themselves as large size lattices, 2 responsible for obstructing the filter pores. These additives essentially act on the limiting filterability temperature (LFT) and on the pour point, but do not modify the cloud point. The prior art has described many CFI additives (see for example US 3,048,479, US 3,627,838, US 3,790,359, US 3,961,961, EP 261 957) which are generally 5 copolymers of ethylene and of an unsaturated ester, such as ethylene/vinyl acetate (EVA), ethylene/vinyl propionate (EVP), ethylene/vinyl ethanoate (EVE), ethylene/methyl methacrylate (EMMA), and ethylene/alkyl fumarate copolymers. In order to improve the properties of standard CFIs, the prior art also proposes mixtures of conventional CFI additives of the ethylene/unsaturated ester type with 10 lubricants (mono- or poly-carboxylic acid esters of mono- or poly-alcohols (see for example EP 721 492), with anti-sedimentation agents (see for example FR 2 490 669), with ethers (see for example US 3,999,960, EP 187 488) Improved CFI additives which are terpolymers or copolymers derived from more than 3 distinct monomers are also found, 15 For example, US 6,509,424 describes a method for preparing terpolymers of ethylene and of at least two compounds containing ethylenic unsaturations, such as vinyl esters, (meth)acrylic esters, alkyl vinyl ethers, in a tubular reactor. These terpolymers may be used as additives improving cold flow of petroleums and petroleum distillates. US 3,642,459 describes terpolymers comprising 40-89% by weight of ethylene, 20 10-40% by weight of vinyl ester derived from a short chain (C 2

-C

4 ) carboxylic acid, such as vinyl acetate, and unsaturated monoesters having a Cio-C22 alkyl chain; these terpolymers are used as additives for lowering the pour point of petroleum distillates and as anti-wax agents and for improving their filterability. US 4,156,434 describes terpolymers of ethylene, vinyl acetate and of acrylic 25 ester deriving from a C 12

-C

24 alcohol which lower the pour point of the fuels into which they are incorporated but nothing is said on the improvement of cold filterability of these additives. WO 2005/054314 describes terpolymers of a-olefin, vinyl ester and a,p unsaturated mono carboxylic acid ester, which may be used. Terpolymers are 30 exemplified, particularly preferred by the applicant, which contain more than 80% by moles of ethylene and less than 9% by moles of vinyl acetate. Now, these terpolymers containing less than 9% by moles of vinyl acetate although having an effect on the decrease in LFT for middle distillates containing more than 18% of n-paraffins, are not satisfactory as regards solubility on the one hand and tendency to blocking (or room 35 temperature filterability) on the other hand: damageable filter cloggings are reported.

3 EP 1 391 498 describes additives improving low temperature fluidity of middle distillates, which are vinyl polymers (A), preferably ethylene-vinyl ester copolymers, for which the amount of hexane-insoluble materials exceeds 60 % by weight at -20 'C and is less than 30% by weight at 10*C; the examples of EP 1391 498 clearly show that the 5 filterability temperature (cold filter plug point (CFPP)) is lowered for copolymers and terpolymers, for which the amount of hexane-insoluble material exceeds 60% by weight at -20 'C and is less than 30% by weight at 10"C as compared with copolymers and terpolymers having the same recurrent units present in the same proportions, but for which the amount of hexane-insoluble materials is out of the claimed range; the 10 exemplified copolymers are EVA copolymers and ethylene-(vinyl acetate)-(vinyl neodecanoate or 2-ethylhexanoate) terpolymers. There is an unsolved need for additives in order to improve cold resistance of fuels (LFT and pour point) while reducing or even eliminating the risk of clogging, so as to avoid blocking of the filters of supply systems for engines or boilers (injection system 15 and tanks). Description of the invention The present invention relates to the use of copolymers as additives improving cold resistance of fuels (CFI additives); these copolymers contain units derived from at least one a-olefin, at least one vinyl ester and at least one a,p-unsaturated mono 20 carboxylic ester, and are preferably terpolymers of ethylene, of vinyl acetate and of ethyl-2-hexyl acrylate. The copolymers according to the invention which may be used as CFI additives comprise - from 81 to 87 % by moles of at least one a-olefin, preferably at least ethylene, 25 - from 10.5 to less than 12% by moles of at least one vinyl ester, preferably at least vinyl acetate, * from 1 to 8.5 % by moles of at least one a,p-unsaturated mono-carboxylic acid ester, preferably at least ethyl-2-hexyl acrylate. Preferably, the copolymers which may be used as CFI additives are inscribed in a 30 quadrilateral ABCD in which A, B, C and D represent the apices of said quadrilateral and correspond to the molar percentages of at least the vinyl ester and of at least the a,p unsaturated mono-carboxylic acid ester: A: 12; 1 35 B: 12; 6 4 C: 10.5; 4 D: 10.5; 8.5. Advantageously, the copolymers which may be used as CFI additives are inscribed in a quadrilateral A 1

BC

1 D wherein A, B, C 1 and D represent the apices of said 5 quadrilateral and correspond to the molar percentages of at least the vinyl ester and of at least the a,p-unsaturated mono-carboxylic acid ester:

A

1 : 12; 2 B: 12; 6 C 1 : 10.5; 5 10 D: 10.5; 8.5. The copolymers according to the invention which are random copolymers have a weight average molecular weight (Mw) measured by GPC generally comprised between 3,000 and 30,000, and a number average molecular weight (Mn) measured by GPC generally comprised between 1,000 and 15,000. 15 These copolymers may be prepared in a known way by any polymerization method, (see for example, Ullmann's Encyclopedia of Industrial Chemistry, 5"' Edition, "Waxes", Vol. A 28, p.

14 6 ; US 3,627,838; EP 7 590) notably by radical polymerization, preferably under high pressure, typically of the order of 1,000 to 3,000 bars (100 to 300 MPa), preferably from 1,500 to 2,000 bars (150 to 200 MPa), the reaction 20 temperatures generally ranging from 160 to 320 'C, preferably from 200 to 280 4C, and in the presence of at least one radical initiator generally selected from organic peroxides and/or oxygen- or nitrogen-containing compounds, and of a molecular weight regulator (aliphatic ketone or aldehyde,...). The copolymers may for example be prepared in a tubular reactor according to the method described in US 6,509,424. 25 The compositions based on hydrocarbons into which the copolymers according to the invention are incorporated, are selected from all types of oils or fuels, such as diesel fuels, domestics oils for heating installations (DOF), kerosene, aviation fuels, heavy fuels, etc ... Generally, the sulfur content of the hydrocarbon compositions is less than 5,000 30 ppm, preferably less than 500 ppm, and more preferentially less than 50 ppm, or even less than 10 ppm and advantageously without any sulfur. The compositions based on hydrocarbons comprise middle distillates with a boiling temperature comprised between 100 and 5004C; their initial crystallization temperature Tec is often greater than or equal to -20'C, generally comprised between 35 -15'C and +10'C. These distillates may for example be selected from distillates obtained 5 by direct distillation of crude hydrocarbons, distillates in vacuo, hydrotreated distillates, distillates from catalytic cracking and/or from hydrocracking of distillates in vacuo, distillates resulting from ARDS (atmospheric residue desulfurization) type conversion processes and/or viscoreduction processes, distillates from upgrading of Fischer Tropsch 5 cuts, distillates resulting from BTL (biomass to liquid) conversion of plant and/or animal biomass, taken alone or as a combination, and/or esters of plant and animal oils or mixtures thereof. The compositions of hydrocarbons may also contain distillates from more complex refining operations than those from direct distillation of hydrocarbons which may for 10 example stem from cracking, hydrocracking and/or catalytic cracking processes and viscoreduction processes. They may also contain novel sources of distillates, among which mention may notably be made of: - the heaviest cuts from cracking and viscoreduction processes, concentrated in heavy 15 paraffins, comprising more than 18 carbon atoms, - synthetic distillates from the transformation of gas such as those from the Fischer Tropsch process, - synthetic distillates resulting from the treatment of biomass of plant and/or animal origin, such as notably NexBTL, 20 - and oils and/or esters of plant and/or animal oils, - or further biodiesel fuels of animal and/or plant origin. These novel fuel bases may be used alone or as a mixture with standard petroleum middle distillates as a fuel base or as a domestic oil base; they generally comprise long paraffinic chains of 10 carbon atoms or more and preferentially from C 14 to C 3 0 . 25 The copolymers as defined earlier with Mw comprised between 5,000 and 27,000 and Mn comprised between 1,500 and 22,000, preferably with Mw comprised between 5,000 and 25,000 and Mn comprised between 1,500 and 20,000 are particularly effective when they are incorporated into light middle distillates and/or with low sulfur content (typically less than 50 ppm) and/or with low initial crystallization temperature (which 30 may typically range down to -20*C). By light middle distillates are meant distillates for which the content in n-paraffins having 24 carbon atoms or more ranges from 0 to less than about 0.7% by weight of the total fuel composition; the C 18

-C

23 n-paraffins of which account for about 3 to about 5% of the total weight of the fuel and for which the mass ratio of C 18

-C

2 3 n-paraffins over the C 24 and higher paraffins generally ranges from 10 to 35.

6 The copolymers with Mw comprised between 5,000 and 10,000 and with Mn comprised between 1,500 and 8,000, preferably with Mw comprised between 5,000 and 8,000 and with Mn comprised between 1,500 and 5,000, are particularly effective when they are incorporated into heavy middle distillates and/or with a rather high initial 5 crystallization temperature (which may typically range from 0 to 15*C). By heavy middle distillates are meant distillates for which the content in n-paraffins with 24 carbon atoms or more ranges from about 0.7 to about 2% by weight of the total fuel composition; the C 18

-C

23 n-paraffins of which account for about 1 to about 10% of the total weight of the fuel and for which the mass ratio of Ci-C 23 n-paraffins over C 24 ' 10 paraffins generally ranges from I to 10. The copolymers may be added as such in the compositions of hydrocarbons or preferentially as concentrated solutions, in particular solutions containing from 50 to 80%, preferably from 60 to 70% by weight of copolymer(s) in a solvent, such as aliphatic or aromatic hydrocarbons, either alone or as a mixture (naphtha, kerosene, hydrocarbon 15 fractions such as Solvesso solvent, paraffinic hydrocarbons, such as pentane, hexane). According to a preferred embodiment of the invention, the compositions of hydrocarbons comprise from 10 to 50,000 ppm by weight of at least one copolymer described above, optionally, preferably from 100 to 1,000 ppm and advantageously from 150 to 500 ppm. 20 In addition to the CFI additives or cold resistance additives described above, the compositions of hydrocarbons may also contain one or more other additives different from the copolymers according to the invention, selected from detergents, anti-corrosion agents, dispersants, de-emulsifiers, antifoaming agents, biocides, reodorants, procetane additives, friction modifiers, lubricity additives or unctuousness additives, combustion 25 aids (combustion and soot catalytic promoters), agents improving the cloud point, the pour point, the limiting filterability temperature, antisedimentation agents, antiwear agents and/or agents modifying conductivity. Among these additives, mention may particularly be made of: a) procetane additives, notably (but not as a limitation) selected from alkyl 30 nitrates, preferably 2-ethyl hexyl nitrate, aroyl peroxides, preferably benzyl peroxide and alkyl peroxides, preferably tert-butyl peroxide; b) antifoaming additives, notably (but not as a limitation) selected from polysiloxanes, oxyalkylated polysiloxanes, and fatty acid amides from plant or animal oils. Examples of such additives are given in EP 861 882, EP 663 000, 35 EP 736 590; 7 c) detergent and/or anticorrosion additives, notably (but not as a limitation) selected from the group formed by amines, succinimides, alkenyl succinimides, polyalkylamines, polyalkyl polyamines and polyetheramines. Examples of such additives are given in EP 938 535; 5 d) lubricity additive or antiwear agent, notably (but not as a limitation) selected from the group formed by fatty acids and their ester or amide derivatives, notably glycerol monooleate, and mono- and poly-cyclic carboxylic acid derivatives. Examples of such additives are given in the following documents: EP 680 506, EP 860 494, WO 98/04656, EP 915 944, FR2 772 783, FR 2 772 10 784. e) cloud point additives, notably (but not as a limitation) selected from the group formed by long chain olefin/(meth)acrylic ester/maleimide terpolymers, and maleic/fumaric acid ester polymers. Examples of such additives are given in EP 71 513, EP 100 248, FR 2 528 051, FR 2 528 051, FR 2 528 423, EPI 12 15 195, EP 1 727 58, EP 271 385, EP 291 367; f) antisedimentation additives and/or paraffin dispersants notably (but not as a limitation) selected from the group formed by (meth)acrylic acid/polyamine amidified alkyl (meth)acrylate copolymers, polyamine alkenyl succinimides, derivatives of phthalamic acid and dual-chain fatty amine derivatives; alkyl 20 phenol resins. Examples of such additives are given in EP 261 959, EP593 331, EP 674 689, EP 327 423, EP 512 889, EP 832 172; US 2005/0223631; US 5,998,530; WO 93/14178. g) cold operability polyfunctional additives selected from the group formed by polymers based on olefin and alkenyl nitrates as described in EP 573 490; 25 h) other CF additives improving cold resistance and filterability, such as EVA and/or EVP copolymers. These other additives are generally added in an amount ranging from 100 to 1,000 ppm (each). The improved cold resistance additives according to the invention may be added 30 into the compositions of hydrocarbons inside the refinery, and/or be incorporated downstream from the refinery, optionally as a mixture with other additives, as a package or packet of additives. Examples In a tubular reactor, terpolymers of ethylene, vinyl acetate and ethyl-2 hexyl 35 acrylate are synthesized by radical polymerization under high pressure (1,400 to 8 2,500 bars (140 to 250 MPa) and at a polymerization temperature from 200 to 280*C. The synthesis is carried out by using an aliphatic aldehyde (propanal) in order to control the molecular masses and by using peroxides as polymerization initiators. In the Table I below, are indicated the Mn and Mw of the synthesized terpolymers as well as their 5 percentages of monomers. Table 1: Characteristics of the synthesized polymers Copolymer Ivinyl acetatel lethyl-2 hexyl acrylatel Mn Mw weight% Mol % weight% Mol % 6 (comparative) 13.3 6.6 22.1 5.1 12,627 14,610 7 (comparative) 13.1 6.5 22.4 5.2 8,842 10,460 12 (comparative) 27.6 13.7 20.7 4.8 11,180 13,255 13 (comparative) 28.4 14.1 20.4 4.7 12,100 14,372 16 (comparative) 19.3 9.6 21.5 5 4,498 8,443 18 (comparative) 36.7 17 3.5 0.8 10,000 11,000 17 19 10.4 30.8 7.9 12,000 15,000 19 (comparative) 28 11 0 0 3,000 8,000 20 (comparative) 30.5 12 0 04,000 ,9,000 The capability of improving the cold resistance of these terpolymers is evaluated by 10 incorporating them in 2 distillates of the motor gasoil type, called GOM 1 and GOM 2, the characteristics of which are grouped in the Table 2 below. Table 2: Characteristics of the fuels ASTM D86 distillation GOM 1 GOM 2 T90-T20 (DC) 129.6 100.4 PF-T90 ( 0 C) 19.5 24.9 T95 (0 C353,5 362.4 Cloud point (C) NF EN 2 3 015 -6 -4 LFT ( C) EN 116 -6 -7 Pour point ("C) NF T 60105 _ 15____ Paraffin content (mass %) Chromatography 14.72 14.68 TCC (C) IP 389 -6.2 .. 6.3 Sulfur content (ppm) EN ISO 20846 18,6 38 15 400 ppm by weight of each copolymer below are incorporated into the distillate of the motor gasoil type called GOM I and then the blocking index FBT (Filter Blocking Tendency) is measured according to the IP 387 standard. GOM I without any additive has an FBT blocking index of 1.01. It is seen that with the terpolymer 17 according to the invention, the blocking tendency of GOM 1 cannot be degraded, i.e. GOM I 9 additived with 400 ppm of terpolymer has an FBT of less than 1.41. The results are shown in Table 3 below. Table 3 : Blocking tendency (IP387) of GOM 1 additived with 400 ppm of different terpolymers. 5 Added additive Blocking index FBT (IP 387) 6 (comparative) 6.08 7 (comparative) 6.08 12 (comparative) 1.01 13 (comparative) 1.03 16 (comparative) 5.1 17 1.0 18 (comparative) 1.24 19 (comparative) 5.1 20 (comparative) 1 1.9 The cold resistance LFT efficiency of the terpolymers incorporated in GOM 1 and GOM 2 is measured at the concentration of 210 ppm; the results are grouped in Table 4. 10 Table 4 : LFT efficiency tests on 2 low sulfur content gasoils. Measurements of TLF C) EN 116 Added additive GOM I GOM 2 210 ppm 210 ppm Without an additive -6 -5 6 -15 7 -16 -15 12 -7 -4 13 .7 -5 17 -19 18 -7 19 -15 20 -16 It is seen that the terpolymer 17 according to the invention is the most efficient on the gasoil GOM 1. Moreover, from the results obtained in Table 3, it is seen that the terpolymer 17 added in an amount of 400 ppm in GOM I does not degrade the blocking 15 tendency. This is not the case of the comparative terpolymers 6; 7; 16 and 18 according to WO 2005/054314, which strongly degrade the blocking tendency measured according to IP 387 and are not as LFT-efficient as the additive 17 of the invention.

Claims

1. The use as an additive improving cold resistance and filterability of fuels, of at least one copolymer comprising 5 - from 81 to 87% by moles of at least one a-olefin, preferably at least ethylene, = from 10.5 to less than 12% by moles of at least one vinyl ester, preferably at least vinyl acetate, - from I to 8.5% by moles of at least one a,p-unsaturated mono-carboxylic acid ester, preferably at least ethyl-2-hexyl acrylate. 10

2. The use as an additive improving cold resistance and filterability of fuels, of at least one copolymer according to claim 1 inscribed in a quadrilateral ABCD in which A, B, C and D represent the apices of said quadrilateral and correspond to the molar percentages of at least the vinyl ester and of at least the a,$-unsaturated mono carboxylic acid ester: 15 A: 12; 1 B: 12; 6 C: 10.5; 4 D: 10.5; 8.5.

3. The use as an additive improving cold resistance and filterability of fuels, of 20 at least one copolymer according to claim 1 or 2 inscribed in a quadrilateral AIBCID in which A,, B, C 1 and D represent the apices of said quadrilateral and correspond to the molar percentages of at least the vinyl ester and of at least the a,p-unsaturated mono-carboxylic acid ester: A 1 : 12; 2 25 B: 12;6 CI: 10.5; 5 D: 10.5; 8.5.

4. The use according to any of claims I to 3 of at least one terpolymer comprising units derived from ethylene, units derived from vinyl acetate and units 30 derived from ethyl-2-hexyl acrylate.

5. The use according to any of claims I to 4 of at least one copolymer of weight average molecular weight (Mw) measured by GPC comprised between 3,000 and 30,000, preferably 3,000 to 20,000 and a number average molecular weight (Mn) measured by GPC generally comprised between 1,000 and 20,000, preferably ranging 35 from 1,500 to 15,000. 1

6. The use according to any of claims 1 to 5 of at least one copolymer as an additive improving cold resistance and filterability without degrading the blocking tendency of middle distillates such as diesel fuels, domestic oils for heating installations (FOD), kerosene, aviation fuels, heavy fuels. 5

7. The use according to any of claims 1 to 6 of at least one copolymer as an additive improving cold resistance and filterability of fuels, the sulfur content of which is less than 5,000 ppm, preferably less than 500 ppm, more preferentially less than 50 ppm, or even less than 10 ppm, and advantageously without any sulfur.

8. A composition of hydrocarbons comprising a majority amount of a 10 middle distillate with a boiling temperature ranging from 100 to 500*C and a minority amount of at least one copolymer as defined in any of claims 1 to 7.

9. The composition according to claim 8, characterized in that it contains from 0 to 100% by weight of biodiesel fuel of animal and/or plant origin.

10. The composition according to claim 8 or 9, characterized in that it is 15 selected from diesel fuels, domestic oils for heating installations (FOD), kerosene, aviation fuels, heavy fuels.

11. The composition according to any of claims 8 to 10, characterized in that it comprises from 10 to 5,000 ppm by weight of at least one copolymer as defined in claims 1 to 5, preferably from 100 to 1,000 ppm and advantageously from 150 to 500 ppm. 20

12. The composition according to any of claims 8 to 11, characterized in that it comprises one or several other additives different from the copolymers according to the invention, selected from detergents, anticorrosion agents, dispersants, de-emulsifiers, antifoaming agents, biocides, reodorants, procetane additives, friction modifiers, lubricity additives or unctuousness additives, combustion aids (combustion and soot 25 catalytic promoters), agents improving the cloud point, the pour point, the limiting filterability temperature, antisedimentation agents, antiwear agents and/or agents modifying conductivity.