AU2007297646B2 - Toughened poly(hydroxyalkanoic acid) compositions - Google Patents
Toughened poly(hydroxyalkanoic acid) compositions Download PDFInfo
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- AU2007297646B2 AU2007297646B2 AU2007297646A AU2007297646A AU2007297646B2 AU 2007297646 B2 AU2007297646 B2 AU 2007297646B2 AU 2007297646 A AU2007297646 A AU 2007297646A AU 2007297646 A AU2007297646 A AU 2007297646A AU 2007297646 B2 AU2007297646 B2 AU 2007297646B2
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- acid
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- REKYPYSUBKSCAT-UHFFFAOYSA-N 3-hydroxypentanoic acid Chemical compound CCC(O)CC(O)=O REKYPYSUBKSCAT-UHFFFAOYSA-N 0.000 claims description 4
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31797—Next to addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Wrappers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Biological Depolymerization Polymers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/523,276 | 2006-09-19 | ||
| US11/523,276 US8399101B2 (en) | 2006-09-19 | 2006-09-19 | Toughened poly(hydroxyalkanoic acid) compositions |
| PCT/US2007/020341 WO2008036335A2 (en) | 2006-09-19 | 2007-09-19 | Toughened poly(hydroxyalkanoic acid) compositions |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| AU2007297646A1 AU2007297646A1 (en) | 2008-03-27 |
| AU2007297646A2 AU2007297646A2 (en) | 2009-04-23 |
| AU2007297646B2 true AU2007297646B2 (en) | 2013-05-30 |
Family
ID=38870587
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2007297646A Ceased AU2007297646B2 (en) | 2006-09-19 | 2007-09-19 | Toughened poly(hydroxyalkanoic acid) compositions |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8399101B2 (https=) |
| EP (1) | EP2064288B1 (https=) |
| JP (1) | JP2010504397A (https=) |
| CN (1) | CN101522799A (https=) |
| AU (1) | AU2007297646B2 (https=) |
| WO (1) | WO2008036335A2 (https=) |
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| CN101336167B (zh) * | 2005-11-30 | 2012-07-18 | 东丽株式会社 | 聚乳酸类树脂叠层片及其成型体 |
| WO2008036334A2 (en) * | 2006-09-19 | 2008-03-27 | E. I. Du Pont De Nemours And Company | Toughened poly(hydroxyalkanoic acid) compositions |
| AU2007309512B2 (en) * | 2006-10-20 | 2012-09-13 | Natureworks Llc | Impact modified polylactide resins |
| EP2084208A4 (en) * | 2006-11-21 | 2011-03-30 | Arkema Inc | INDICATIVE AND OPAQUE ELASTIFICATORS FOR POLYMYLIC ACID |
| US7683117B2 (en) * | 2007-02-02 | 2010-03-23 | Fuji Xerox Co., Ltd. | Resin composition, resin mold and method for producing the same |
| WO2009058920A1 (en) * | 2007-10-31 | 2009-05-07 | E. I. Du Pont De Nemours And Company | Poly(hydroxyalkanoic acid) composition |
| US20130345363A1 (en) * | 2008-06-13 | 2013-12-26 | Arkema Inc. | Biodegradable impact-modified polymer compositions |
| US9526620B2 (en) * | 2009-03-30 | 2016-12-27 | DePuy Synthes Products, Inc. | Zero profile spinal fusion cage |
| US8729156B2 (en) | 2009-07-17 | 2014-05-20 | Arkema France | Polyhydroxyalkanoate composition exhibiting improved impact resistance at low levels of impact modifier |
| EA201200138A1 (ru) * | 2009-07-17 | 2012-08-30 | Аркема Франс | Способ получения полиэфирной композиции с улучшенной ударопрочностью |
| FR2956405B1 (fr) * | 2010-02-15 | 2012-03-16 | Arkema France | Composition de polyhydroxyalcanoate presentant une resistance au choc amelioree |
| WO2011031558A2 (en) * | 2009-08-27 | 2011-03-17 | Metabolix, Inc. | Toughened polyhydroxyalkanoate compositions |
| KR101164016B1 (ko) * | 2009-12-02 | 2012-07-18 | 유니띠까 가부시키가이샤 | 폴리락트산계 수지 조성물, 성형체, 및 폴리락트산계 마스터 배치 펠릿 |
| CN101831156B (zh) * | 2010-05-07 | 2012-11-07 | 四川大学 | 一种增韧无卤阻燃聚乳酸共混材料 |
| TWI410439B (zh) * | 2010-09-10 | 2013-10-01 | Univ Southern Taiwan | 複合型樹脂微粒及含有其之經增韌的聚乳酸組成物 |
| US9173978B2 (en) | 2010-09-22 | 2015-11-03 | Ethicon, Inc. | Bioabsorbable polymeric compositions, processing methods, and medical devices therefrom |
| FR2965814B1 (fr) | 2010-10-08 | 2012-11-16 | Roquette Freres | Plastification de polyesters aliphatiques par des esters alkyliques de dianhydrohexitols |
| JP5852375B2 (ja) * | 2011-09-07 | 2016-02-03 | 麒麟麦酒株式会社 | ガスバリア性ポリ乳酸樹脂成形体 |
| CN109054254B (zh) | 2012-08-17 | 2021-02-02 | Cj第一制糖株式会社 | 用于聚合物共混物的生物基橡胶改性剂 |
| FR2995901B1 (fr) | 2012-09-21 | 2015-08-14 | Inst Corps Gras Etudes Et Rech S Tech Iterg | Nouveaux pre-polymeres biosources et leurs utilisations pour la preparation de polymeres utiles comme additifs dans une matrice poly(acide lactique) |
| FR3004188B1 (fr) | 2013-04-08 | 2016-02-05 | Univ Bordeaux 1 | Utilisation de polymeres comme additifs dans une matrice de polymere |
| WO2014184057A1 (en) | 2013-05-14 | 2014-11-20 | Basf Se | Process for production of polymer powders |
| EP3004225A1 (en) | 2013-05-30 | 2016-04-13 | Metabolix, Inc. | Recyclate blends |
| ES3049230T3 (en) | 2013-10-21 | 2025-12-15 | Clear Lam Packaging Inc | Additive for performance enhancement of pla articles |
| EP3122817B1 (en) | 2014-03-27 | 2020-07-29 | CJ CheilJedang Corporation | Highly filled polymer systems |
| CA2965102C (en) * | 2014-11-13 | 2018-02-13 | Kureha Corporation | Polyglycolic acid resin composition, molded product for well drilling, and downhole tool member |
| CN110429210B (zh) * | 2019-07-19 | 2021-12-31 | 厦门长塑实业有限公司 | 一种锂电池软包装用的聚酰胺薄膜及其制备工艺 |
| CN114395232B (zh) * | 2022-01-25 | 2023-08-15 | 广东盈尔实业有限公司 | 一种降解型包装薄膜的加工方法及降解型包装薄膜 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040242803A1 (en) * | 2001-08-03 | 2004-12-02 | Hiroyuki Ohme | Resin composition and molded article, film, and fiber each comprising the same |
| EP1657280A1 (en) * | 2004-11-12 | 2006-05-17 | Tosoh Corporation | Resin composition, and method for producing the same |
| EP1826241A1 (en) * | 2004-12-15 | 2007-08-29 | Kaneka Corporation | Biodegradable resin compositions and molded objects thereof |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL282755A (https=) * | 1961-08-31 | 1900-01-01 | ||
| JPS5493043A (en) * | 1977-12-29 | 1979-07-23 | Unitika Ltd | Resin composition and its production |
| JPS61501270A (ja) * | 1984-02-24 | 1986-06-26 | イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− | 強化熱可塑性ポリエステル組成物 |
| US4912167A (en) * | 1987-12-14 | 1990-03-27 | E. I. Du Pont De Nemours And Company | Polyester compositions for blow molding |
| US5063259A (en) * | 1990-07-03 | 1991-11-05 | Rohm And Haas Company | Clear, impact-resistant plastics |
| US5883199A (en) * | 1997-04-03 | 1999-03-16 | University Of Massachusetts | Polyactic acid-based blends |
| US20020197469A1 (en) * | 1998-10-26 | 2002-12-26 | Richard Roy Clikeman | Particles and a process for preparing the same |
| US6235825B1 (en) * | 1998-03-05 | 2001-05-22 | Mitsui Chemicals, Inc. | Polylactic acid resin composition and film therefrom |
| US6130290A (en) | 1998-04-29 | 2000-10-10 | Rohm And Haas Company | Impact modifier for amorphous aromatic polyester |
| EP1038906B1 (en) * | 1999-03-26 | 2004-01-21 | Toyo Boseki Kabushiki Kaisha | Polylactic acid film |
| US6462109B1 (en) * | 1999-10-12 | 2002-10-08 | Eastman Chemical Company | Surfactantless latex compositions and methods of making polymer blends using these compositions |
| JP3258302B2 (ja) * | 1999-10-26 | 2002-02-18 | 三菱樹脂株式会社 | 生分解性２軸延伸フィルム |
| JP3236842B2 (ja) * | 1999-10-27 | 2001-12-10 | 三菱樹脂株式会社 | 生分解性袋 |
| DE10029946A1 (de) * | 2000-06-17 | 2001-12-20 | Merck Patent Gmbh | Integrierte optische Wellenleiter für mikrofluidische Analysensysteme |
| EP1302509B1 (en) * | 2000-07-17 | 2009-03-11 | Mitsui Chemicals, Inc. | Lactic acid-base resin compositions and molded articles made thereof |
| JP5177931B2 (ja) * | 2002-01-24 | 2013-04-10 | 東レ株式会社 | 脂肪族ポリエステル樹脂組成物およびそれからなる成形品 |
| CN1296432C (zh) | 2002-03-29 | 2007-01-24 | 三井化学株式会社 | 乳酸基树脂组合物 |
| FR2842456B1 (fr) * | 2002-07-22 | 2004-12-24 | Bourgogne Grasset | Procede de marquage par tampographie et sublimation et encres de tampographie sublimables |
| US6849687B2 (en) * | 2002-08-01 | 2005-02-01 | Bayer Polymers Llc | Thermoplastic composition having low gloss appearance |
| US7135509B2 (en) * | 2002-09-25 | 2006-11-14 | Toray Industries, Inc. | Flame-retardant polybutylene terephthalate resin composition and formed article |
| US7027580B2 (en) * | 2003-02-03 | 2006-04-11 | Oliver Wendel Gamble | Method and system for automatically sending, receiving and utilizing information transmitted over a communication network |
| JP4809233B2 (ja) | 2003-05-13 | 2011-11-09 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 強化されたポリオキシメチレン−ポリ乳酸組成物 |
| US6943214B2 (en) * | 2003-05-13 | 2005-09-13 | E. I. Du Pont De Nemours And Company | Toughened polyoxymethylene-poly(lactic acid) compositions |
| JP3936329B2 (ja) * | 2003-12-04 | 2007-06-27 | 古河電気工業株式会社 | 絶縁電線 |
| US7354973B2 (en) * | 2003-12-12 | 2008-04-08 | E.I. Du Pont De Nemours And Company | Toughened poly(lactic acid) compositions |
| US7078368B2 (en) * | 2004-02-20 | 2006-07-18 | Eastman Kodak Company | Thermal-dye-transfer media for labels comprising poly(lactic acid) and method of making the same |
| KR100711483B1 (ko) * | 2004-03-29 | 2007-04-24 | 가부시키가이샤 도모에가와 세이시쇼 | 방현 필름 |
| WO2005123831A1 (ja) | 2004-06-16 | 2005-12-29 | Unitika Ltd. | ポリ乳酸含有樹脂組成物及びそれより得られる成形体 |
| JP5008015B2 (ja) * | 2004-12-27 | 2012-08-22 | 株式会社豊田中央研究所 | 脂肪族ポリエステル組成物及びその成形体 |
| JP2006193561A (ja) * | 2005-01-11 | 2006-07-27 | Kaneka Corp | ポリ乳酸系樹脂組成物 |
| JP5183203B2 (ja) * | 2005-05-09 | 2013-04-17 | 株式会社カネカ | 生分解性樹脂組成物及びその成形体 |
| JP5135742B2 (ja) * | 2005-09-30 | 2013-02-06 | 東レ株式会社 | 樹脂組成物およびそれからなる成形品 |
| US20080057090A1 (en) * | 2006-09-01 | 2008-03-06 | Mcentire Edward Enns | Wrinkle masking film composition for skin |
-
2006
- 2006-09-19 US US11/523,276 patent/US8399101B2/en not_active Expired - Fee Related
-
2007
- 2007-09-19 WO PCT/US2007/020341 patent/WO2008036335A2/en not_active Ceased
- 2007-09-19 JP JP2009529232A patent/JP2010504397A/ja active Pending
- 2007-09-19 CN CNA2007800346027A patent/CN101522799A/zh active Pending
- 2007-09-19 AU AU2007297646A patent/AU2007297646B2/en not_active Ceased
- 2007-09-19 EP EP07838535.8A patent/EP2064288B1/en not_active Not-in-force
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040242803A1 (en) * | 2001-08-03 | 2004-12-02 | Hiroyuki Ohme | Resin composition and molded article, film, and fiber each comprising the same |
| EP1657280A1 (en) * | 2004-11-12 | 2006-05-17 | Tosoh Corporation | Resin composition, and method for producing the same |
| EP1826241A1 (en) * | 2004-12-15 | 2007-08-29 | Kaneka Corporation | Biodegradable resin compositions and molded objects thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2010504397A (ja) | 2010-02-12 |
| US8399101B2 (en) | 2013-03-19 |
| EP2064288B1 (en) | 2015-09-09 |
| CN101522799A (zh) | 2009-09-02 |
| WO2008036335A2 (en) | 2008-03-27 |
| AU2007297646A2 (en) | 2009-04-23 |
| US20080071008A1 (en) | 2008-03-20 |
| EP2064288A2 (en) | 2009-06-03 |
| AU2007297646A1 (en) | 2008-03-27 |
| WO2008036335A3 (en) | 2008-08-14 |
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| FGA | Letters patent sealed or granted (standard patent) | ||
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