AU2007264068A1 - Method for the production of a windshield wiping concentrate in the form of tablets, windshield wiping concentrate, and corresponding presentation - Google Patents
Method for the production of a windshield wiping concentrate in the form of tablets, windshield wiping concentrate, and corresponding presentation Download PDFInfo
- Publication number
- AU2007264068A1 AU2007264068A1 AU2007264068A AU2007264068A AU2007264068A1 AU 2007264068 A1 AU2007264068 A1 AU 2007264068A1 AU 2007264068 A AU2007264068 A AU 2007264068A AU 2007264068 A AU2007264068 A AU 2007264068A AU 2007264068 A1 AU2007264068 A1 AU 2007264068A1
- Authority
- AU
- Australia
- Prior art keywords
- concentrate
- tablets
- additives
- windshield
- windshield washing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0052—Gas evolving or heat producing compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Medicinal Preparation (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
DECLARATION I, Uta I. Seidel, of the City of Ottawa, Ontario, Canada, hereby certify that I am acquainted with the German and English languages and that the following is a true translation made by me into the English language of the attached patent application entitled "Method For The Production Of A Windshield Washing Concentrate In The Form Of Tablets, Windshield Washing Concentrate, And Corresponding Presentation", bearing the reference number PCT/EP2007/005678 (WO 2008/000456 Al). Dated this 22nd day of December 2008. Uta I. Seidel Uta I. Seidel Method For The Production Of A Windshield Washing Concentrate In The Form Of Tablets, Windshield Washing Concentrate, And Corresponding Presentation The present invention relates to a method for pelleting a windshield washing concentrate in the form of tablets according to the preamble of the main claim, the presentation of pelleted windshield washing concentrates of this type and a windshield washing concentrate in the form of tablets produced in this way. It is known to add windshield washing concentrates in liquid form to the windshield washer container of a vehicle (see e.g. www.autosol.de). It is also known to add windshield washing concentrates in the form of tablets to the wash water of a supply container of a motor vehicle. The articles having the item number 369 579 which can be obtained under www.westfalia.de are tablets of about 8 grams in weight and are intended for approximately 2.5 liters of washing fluid. The problem is that these tablets are simply too large and heavy. For example, if one wishes to produce about 7 to 10 liters windshield washing concentrate, as e.g. in certain types of vehicles, then three to four tablets of this size are required for this purpose. This corresponds to approximately 24g - 32g concentrate addition. Consequently, the object of the invention is to propose a method for the production of windshield washing concentrate in the form of tablets, that leads to a windshield washing concentrate in the form 2 of tablets, which avoids the aforementioned disadvantages. A further object of the invention is to provide a packaging unit for the tablet form thus produced by means of which the windshield washing concentrate can be easily and accurately measured out and which nevertheless offers the necessary security against manipulation by children. A further object of the invention is to also give the windshield washing concentrate in the form of tablets according to the invention additional advantages in addition to the purely functional composition in order to increase marketability. This object and the secondary objects are solved by the features of the patent claims. The invention results in the advantage that the windshield washing concentrate exists in a form that can be measured very accurately for the amount of water present in each case, whereby the respectively produced tablet size easily fits into the inlet opening of every conventional wash water container. Therefore, excessively large molded articles do not have to be manipulated to provide the wash water with the cleaning concentrate. The molded articles can, for example, have a diameter of up to about 15 mm relative to one to three liters washer fluid, with a thickness of about 10 mm. In one embodiment, the tablet, which is measured for about 1 1 water, has a volume of about 0.5 cm". Thus, these are relatively small, easy-to-handle tablets which can be measured out without difficulty.
3 The essential aspect of the invention is based on a surfactant constituent of more than 40% relative to the raw material used. Consequently, up to 16 times as many percent by weight of surfactants are contained as in the aforementioned tablets of the prior art. In view of the fact that the high surfactant concentration is primarily responsible for the cleaning efficiency, additional cleaning adjuvants, such as phosphates and e.g. trisodium nitrilotriacetate, can be omitted. The missing phosphates lead to a clearly lower stress on waste water and waste-water purification plants, the latter cleaning adjuvant is even suspected of being carcinogenic. This advantage is obtained in that the surfactants required for the windshield washing must first be evaporated until they have a dry consistency. However, the addition ot a water-soluble inert substance to the aqueous surfactant solution is of significance in this respect. This inert substance must be such that it forms a complex with the surfactant without reacting chemically with said surfactant. This complex can be evaporated to form a dry powder which can then be pressed in association with citric acid and sodium bicarbonate to form tablets. The water-soluble inert substance which is added to the aqueous surfactant solution thereby forms a molecule-based complex with the surfactants without reacting with them.
-4 In this respect, the term "inert substance" relates to the fact that there is no chemical reaction between the surfactants and the inert substance, but only a complex compound. In an advantageous embodiment of the invention, the evaporation of this complex is brought about by a process step in which a negative pressure of about up to 40 mbar is produced at a temperature in the order of magnitude of 50-600. The water contained in the surfactant solution, which is fed to the vacuum chamber together with the inert substance, evaporates in this vacuum and is drawn off via a corresponding pump. In this respect, this embodiment of the invention should be differentiated from spray drying which is less suitable for the invention. That is, in spray drying, a considerable portion of water is left behind, so that this concentrate can not be molded. Vacuum drying also differs from this insofar because it offers the possibility of keeping the substrate, which consists of the surfactant found in solution and added water-soluble inert substance, continuously in motion in the vacuum container by continuously intermixing using mixing blades, optionally also with cutting blades, in order to in this way produce a homogeneous powdery dry substance which can be easily pelleted. In contrast to the spray-drying method, a very high surfactant constituent of more than 40% can thereby be obtained. Nevertheless, there is pelleting with this high surfactant constituent.
- 5 In this case, the citric acid portion can be up to about 35% by weight. As all additives are thus water soluble, one also does not require any water-insoluble pelleting adjuvants, such as magnesium stearate, cellulose or explosives. The tablet according to the invention thereby completely dissolves in water and all conventional alcoholic antifreezes up to 100%. Sugar is, for example, suitable as a possible inert substance. Furthermore, due to the water-soluble properties, no antifreeze materials must be introduced into the tablets. Therefore, the concentrate of the surfactants is pulverized together with the inert substance and, optionally, also with the additives. The surfactants are originally found in an aqueous solution and are then concentrated accordingly together with the inert substance by evaporation. The required additives, which are also in a dry consistency form, can be added beforehand or subsequently. The mixture can also already be easily mixed during drying or also later with conventional means before it is molded in a corresponding pelleting press. Preferably, the windshield washing concentrate is in the form of tablets which contain no more than 10g, preferably no more than 5g, of the mixed dry substrate.
- 6 In a further embodiment of the invention, the individual tablets can also have no more than 2g and should then be used for half the amount of base volume of e.g. 2 liters washing liquid. The additive sodium bicarbonate together with citric acid dissolves quickly and uniformly in water in an effervescent manner, so that, in spite of a high mold density of the tablets, the entire tablet contents dissolve almost immediately after filling with wash water. Moreover, sodium bicarbonate together with citric acid also has a certain cleaning capability, so that the surfactants contained as active component are also assisted in their cleaning capability. In addition, pigments can also be added, preferably pigments which correspond to the main colours of predetermined consumers. The purpose of this step is to offer for sale to the consumer individually dyed tablets in each case which, due to their coloring - single-coloured or multicoloured - fit in the product image of the respective vendor. In addition to this, fragrant substances can also be introduced, e.g. perfume oils, in order to also appeal to the purchaser's sense of smell for specific use of said tablets. Furthermore, with the predetermined method, tablets can also be produced which do not have to be provided with a round cross section. For example, the tablets can have the outer contour of a pilgrim scallop, a diamond, a shield or the like. The purpose of this step is to also document the Corporate Identity of a specific vendor by the correspondingly contoured tablets.
- 7 Moreover, the use of a presentation in the form of a bubble wrap package offers the advantage of childproofing, because children usually can not easily open bubble wrappings of this type. Of course, without a bubble wrap package of this type, the tablet according to the invention can also reach the market in a tablet tube. By using a so-called matrix die pair, which is inserted into a corresponding perforated plate on both sides, tablets of this type can be produced with a slippery surface which is especially suitable to also clearly reproduce details of company logos. The components of the tablet are compressed so strongly by the high pressure applied in a table press of this type that there are no possible points of attack for germs or for moisture absorption on the slippery surface, and that, consequently, the addition of preservatives can be omitted. Tablets, whose density was about 2.5g per cubic centimeter, were thereby produced under a corresponding mold pressure. Tablets of this type were also still easily soluble in water and yet small from the volume point of view with the desired high cleaning efficiency. Nevertheless, the tablet alone is dissolved as quickly as possible in the wash water by use of sodium bicarbonate with citric acid. Furthermore, it is recommended that the tablet form be selected so large that it has a sufficient cleaning capability together with a predetermined amount of water, also called base volume, e.g. 2 liters.
- 8 Advantageous embodiments can be found in the subclaims. The invention is described in greater detail in the following with reference to an example of an embodiment. Fig. 1 shows a first embodiment of the invention. Fig. 2 shows a schematic representation of the method with variants. Unless otherwise stated in the following, the following description applies to all figures. The windshield washer container of a motor vehicle is furnished on site with a pelleted form of a windshield washing concentrate according to the invention. Thereafter or beforehand, the container is filled with normal tap water. It is important that the windshield washer concentrate is pelleted and consists of a concentrate comprised of evaporated surfactants previously in an aqueous solution which are mixed with an inert substance, e.g. with sugar, so that the dry consistency of the tablet 100 contains an essentially highly concentrated surfactant. Additives can be added to these surfactants which are in the evaporated concentrate of the original solution, including the inert substance which must be water soluble, said additives preferably having also been in a dry consistency form. These additives are pulverized together with the evaporated concentrate in a dry consistency form and thoroughly mixed such -9 that a charge of tablets 100 of this type produced has a homogeneous quality. According to the invention, a tablet 100 of this type should not weigh more than o10g, preferably not more than 5g or as 1/2 a dosage not more than 2g. It was shown that tablets 200 could be produced with the present method which are suitable at about 4g weight for about 1 liter washing fluid, analogously, a tablet 100 of up to about 2g weight would be suitable for about 1/2 liter washing fluid. These correlations are linear and tablets 100 could also be easily used which are provided for up to about 2 to 4 liters washing fluid or e.g. for trucks at 30 cubic centimeters volume for 65 liters of cleaning fluid. It is also essential that, in addition to the evaporated surfactants 1, sodium bicarbonate be present in order to be able to dissolve the tablet 100 quickly in an effervescent manner in added water. Citric acid, which has a supplementary cleaning effect together with sodium bicarbonate, can be present as a further additive. Furthermore, pigments, fragrant substances or also antifreeze additives can be provided to furnish the tablets 100 according to the invention with further functions. This results in the advantage that the recognition value of such products, e.g. due to the respectively recognizable colour, can be preprogrammed.
- 10 Thus, for example, it can be provided that tablets 100 of this type which are red in colour are provided with high concentrations of active substances, those which are green with low concentrations, etc. Moreover, a tablet 100 of this type can also be furnished in the form of the logo of a specific vendor, vendor chain or the like. In addition, the arrangement of these tablets 100 in a bubble wrap package is of considerable importance. This step is not only useful for keeping the individual tablets 100 absolutely dry against environmental influences but also for childproofing, as already noted. Since the tablets 100 preferably contain sodium bicarbonate they are also hydrophilic. For this reason, the bubble wrapping also presents itself because each individual tablet 100 is then accommodated in a self-contained volume which is protected against ambient moisture. The tablets 100 shown have a diamter of not more than 20 mm at a thickness of not more than 15 mm. Depending on conditions, the thickness can also be less than 10 mm at a diameter of less than 15 mm. If tablets 100 of this type are produced by a matrix die pair known in the prior art, the applied pressures are so high that the surfaces become slippery. This offers the further advantage that company logos or marks can be easily pressed into the surface by correspondingly contoured - 11 matrix dies The applied pressures that can be produced with matrix die pairs of this type are, in fact, clearly higher than the pressures which can be obtained via allocated press roll pairs. Moreover, Fig. 2 schematically illustrates the procedural steps for producing the product according to the invention. A surfactant 1 which is in solution and an inert water-soluble substance 2 are combined. This mixture can be provided with individual additives 3a, 3b, 3c before or after combining, it being irrelevant, in principle, at what point the additives are added. However, if the additives are in a liquid state, they must be added prior to drying of the mixture consisting of surfactant 1 and inert substance 2, so that they can also be subjected to the drying process. This mixture, which consists of a surfactant 1 in solution and inert substance 2, is then placed in a drying container 4, optionally together with the additives 3a-3c, where the surfactant 1 is first evaporated together with the inert substance until it has a dry consistency to form a concentrate 5. In this respect, it is essential that the drying container 4 have a suction connection 6 via which it can ultimately be evacuated via a suction pump 7. Taking into consideration an ambient pressure of about 1 bar, it is proposed that it be possible to evacuate the drying container 4 to - 12 such an extent that the static pressure present there is less than 0.1 bar, preferably less than 0.05 bar. It was shown that a process pressure of about 40 mbar can be realized and enables the process to be conducted efficiently. In addition, it is proposed that the drying container 4 be heated to an internal temperature of about 50-600 C via a suitable heating device. In this respect, a process temperature is essential that is above the ambient temperature to aid the evaporation of the liquid in the mixture. Furthermore, a known mixing device is arranged inside the drying container 4 which can be rotary-driven via an electromotor 9 situated outside of the container. A mixing device 8 of this type has, for example, mixing blades 10 which can, however, also be designed in such a way that the processed mixture is continuously broken down in a pulverizing manner during the evaporation process. If the additives 3a-3c are in a liquid form, they must be introduced into the drying container 4 prior to filling in the mixture. If the additives are in powder form, they can be introduced into the drying container 4 prior to inserting the mixture or, optionally, also thereafter. In any event, the dried intermediate product 12 leaving the drying container 4, which is in a powdery modable substance, can then be further processed in a pelleting machine.
- 13 A rotating matrix 13 which has corresponding holes is used for this purpose. The holes can be brought into aligning positions at those points where the pelleting machine has a matrix die pair 14 and 15 each. If the holes are filled with the intermediate product 12 to be pressed, then the matrix die pairs 14, 15 are driven toward one another and the intermediate product 12 situated in the holes is compacted to such an extent that a pelleted product is ultimately produced. However, this method is part of the prior art, so that reference is made to the prior art for all details not mentioned here. It should thereby also be made clear that the intermediate product 12 is the substance evaporated to the dry consistency to form a concentrate which is ultimately suitable for pelleting, in spite of a surfactant concentration of more than 40% by weight.
- 14 List of Reference Numbers 1 Surfactant 2 Inert substance 3a Additive, NaHCO, 3b Additive, pigments 3c Additive, others such as fragrance, citric acid 4 Drying container 5 Concentrate 6 Suction connection 7 Suction pump 8 Mixing device 9 Electromotor 10 Mixing blades 12 Intermediate product 13 Matrix 14 Upper matrix die 15 Lower matrix die 100 Tablet
Claims (28)
1. A method for pelleting a windshield washing concentrate consisting of at least one surfactant (1) in solution and additional additives (3a, 3b, 3c), at least one of which is an inert water-soluble substance (2), wherein the surfactant (1) is first of all evaporated together with the inert substance (2) to a dry consistency to form a concentrate and that the additives (3a, 3b, 3c) are added subsequently or beforehand and that the pelleting then takes place.
2. The method according to claim 1, characterized in that sugar is added as inert substance (2).
3. The method according to claim 1 or 2, characterized in that additives (3a, 3b, 3c) are added in their dry consistency state.
4. The method according to claim 1, 2 or 3, characterized in that the substrate (12) in the dry consistency form is pulverized prior to the pelleting and, optionally, mixed with the added additives (3a, 3b, 3c) which are also present in a dry consistency form.
5. The method according to any one of the claims 1 to 4, characterized in that not more than o10g are pelleted from the concentrate (12) to form a tablet (100) each.
6. The method according to claim 5, characterized in that not more than 5g are pelleted from the concentrate (12) to form a tablet (100) each. - 16
7. The method according to claim 5 or 6, characterized in that not more than 2g are pelleted from the concentrate to form a tablet (100) each.
8. The method according to any one of the claims 1 to 7, characterized in that sodium bicarbonate (3a) is supplied as additive.
9. The method according to claim 8, characterized in that citric acid (3c) is supplied as additive.
10. The method according to any one of the claims 1 to 9, characterized in that a substance (3b) containing a pigment is supplied as a further additive.
11. The method according to any one of the claims 1 to 10, characterized in that a substance (3c) containing a fragrance is supplied as further additive.
12. The method according to any one of the claims 1 to 11, characterized in that the surfactant (1) together with the inert substance (2) is evaporated in an atmosphere which has a static pressure of less than 1 bar.
13. The method according to claim 12, characterized in that the atmosphere has a pressure of less than 0.1 bar.
14. The method according to claim 12 or 13, characterized in that the atmosphere has a pressure of less than 0.05 bar.
15. The method according to any one of the claims 1 to 14, characterized in that the surfactant (1) is evaporated together with the inert substance (2) and continuously mixed - 17 during this process.
16. The method according to any one of the claims 1 to 15, characterized in that the surfactant (1) is evaporated together with the inert substance (2) and continuously broken down in a pulverizing manner during this process.
17. The method according to any one of the claims 1 to 16, characterized in that the temperature during evaporation is above the ambient temperature.
18. The method according to claim 17, characterized in that the temperature is in the order of magnitude of 50 to 60 degrees celsius.
19. The method according to any one of the claims 1 to 18, characterized in that the pelleting takes place with predetermined outer contour which is not circular.
20. The method according to any one of the claims 1 to 12, characterized in that the pelleting takes place in a matrix (13) which is acted upon on both sides by a matrix die (19, 15) each.
21. Presentation of a pelleted windshield washing concentrate according to any one of the claims 1 to 20, characterized by a bubble wrap packaging in which individual tablets are individually packed in each case.
22. A windshield washing concentrate in tablet form produced according to any one of the claims 1 to 21, characterized in that the diameter of the tablets (100) is not greater than 20 mm and their thickness not greater than 15 mm and that the - 18 tablets (100) contain a concentrate (12) consisting of surfactants (1) and a water-soluble inert substance (2) which has been evaporated until it has a dry consistency, so that they are destined for dissolving in windshield wash water of not more than 2 liters.
23. The windshield washing concentrate according to claim 22, characterized in that the diameter of the tablets (100) <= 15 mm and their thickness <= 10 mm and that the tablets (100) contain a concentrate (12) consisting of surfactants (1) and a water-soluble inert substance (2) which has been evaporated until it has a dry consistency, so that they are destined for dissolving in windshield wash water of not more than <= 1 liter.
24. The windshield washing concentrate according to any one of the claims 22 to 23, characterized in that at least sodium bicarbonate (3a) and citric acid (3c) are contained as additives.
25. The windshield washing concentrate according to any one of the claims 22 to 24, characterized in that pigments (3b) are contained as additives.
26. The windshield washing concentrate according to any one of the claims 22 to 25, characterized in that fragrant substances (3c) are contained as additives.
27. The windshield washing concentrate according to any one of the claims 22 to 26, characterized in that the outer contour has a company logo or the like.
28. The windshield washing concentrate according to any one of the - 19 claims 22 to 27, characterized in that the surface is compacted so as to be smooth by means of the applied pressure of a matrix die pair (14, 15).
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006029793A DE102006029793A1 (en) | 2006-06-27 | 2006-06-27 | Process for the preparation of a slide cleaner concentrate in tablet form, disc cleaner concentrate itself and appropriate presentation |
DE102006029793.8 | 2006-06-27 | ||
PCT/EP2007/005678 WO2008000456A1 (en) | 2006-06-27 | 2007-06-27 | Method for the production of a windshield wiping concentrate in the form of tablets, windshield wiping concentrate, and corresponding presentation |
Publications (1)
Publication Number | Publication Date |
---|---|
AU2007264068A1 true AU2007264068A1 (en) | 2008-01-03 |
Family
ID=38581921
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU2007264068A Abandoned AU2007264068A1 (en) | 2006-06-27 | 2007-06-27 | Method for the production of a windshield wiping concentrate in the form of tablets, windshield wiping concentrate, and corresponding presentation |
Country Status (14)
Country | Link |
---|---|
EP (1) | EP2038396A1 (en) |
JP (1) | JP2009541541A (en) |
KR (1) | KR20090034337A (en) |
CN (1) | CN101522882A (en) |
AU (1) | AU2007264068A1 (en) |
BR (1) | BRPI0713471A2 (en) |
CA (1) | CA2656164A1 (en) |
DE (1) | DE102006029793A1 (en) |
IL (1) | IL196029A0 (en) |
MA (1) | MA30570B1 (en) |
MX (1) | MX2008016465A (en) |
RU (1) | RU2009102284A (en) |
WO (1) | WO2008000456A1 (en) |
ZA (1) | ZA200900018B (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010080043A2 (en) | 2009-01-12 | 2010-07-15 | Sirseth Thorbjoem | Energy system |
DE102009011928A1 (en) | 2009-03-10 | 2010-09-23 | Licciardi, Natale, Dipl.-Ing. | Process for the preparation of cleaning tablets |
DE102017009771A1 (en) * | 2017-10-20 | 2019-04-25 | Chemprox Gmbh | Manufacturing process for a dry detergent ready mix and ready-mixed detergent mixture and use for liquid detergent production |
EP3835400A1 (en) * | 2019-12-10 | 2021-06-16 | Kevin Orchard Co., Ltd. | Solid detergent |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5130805A (en) * | 1974-09-10 | 1976-03-16 | Shinei Kk | |
DE2856143A1 (en) * | 1978-12-27 | 1980-07-17 | Hoechst Ag | WINDOW CLEANER |
DE3104371A1 (en) * | 1981-02-07 | 1982-11-11 | Henkel KGaA, 4000 Düsseldorf | Cleaning composition tablet |
DE3535516A1 (en) * | 1985-10-04 | 1987-04-09 | Fritz Buchner | TABLET-SHAPED DETERGENT AND CLEANING AGENT, METHOD FOR THE PRODUCTION THEREOF AND ITS USE |
DE3628406A1 (en) * | 1986-08-21 | 1988-02-25 | Henkel Kgaa | TABLET SHAPED GLASS CLEANER |
JPH01144499A (en) * | 1988-11-04 | 1989-06-06 | C C I Kk | Solid cleaning and reinforcing agent for windshield glass of automobile |
DE69637030T2 (en) * | 1996-12-06 | 2007-12-27 | The Procter & Gamble Company, Cincinnati | Coated cleaning agent in tablet form and manufacturing method therefor |
JPH11181500A (en) * | 1997-12-24 | 1999-07-06 | Kansai Kouso Kk | Foamable detergent for keeping immersion and its use |
US6361615B1 (en) * | 1999-03-04 | 2002-03-26 | Michael L. Callahan | Cleaning compound additive and method |
JP2000290697A (en) * | 1999-04-07 | 2000-10-17 | Daiichi Shoji Kk | Solid tablet for window washer solution |
DE19950765A1 (en) * | 1999-10-21 | 2001-04-26 | Henkel Kgaa | Compound used in laundry or other detergent tablets, e.g. for use in dish-washing machines, cleaning hard surfaces or as bleach, water softener or stain remover, contains anionic surfactant, hydrotrope and optionally carrier |
DE10015661A1 (en) * | 2000-03-29 | 2001-10-31 | Henkel Kgaa | Detergent tablets, include surfactant granules containing sugars, sugar acids and/or sugar acid salts for improved stability and solubility |
-
2006
- 2006-06-27 DE DE102006029793A patent/DE102006029793A1/en not_active Withdrawn
-
2007
- 2007-06-27 KR KR1020097000694A patent/KR20090034337A/en not_active Application Discontinuation
- 2007-06-27 MX MX2008016465A patent/MX2008016465A/en unknown
- 2007-06-27 BR BRPI0713471-1A patent/BRPI0713471A2/en not_active IP Right Cessation
- 2007-06-27 RU RU2009102284/04A patent/RU2009102284A/en unknown
- 2007-06-27 EP EP07764881A patent/EP2038396A1/en not_active Withdrawn
- 2007-06-27 AU AU2007264068A patent/AU2007264068A1/en not_active Abandoned
- 2007-06-27 CN CNA2007800240499A patent/CN101522882A/en active Pending
- 2007-06-27 WO PCT/EP2007/005678 patent/WO2008000456A1/en active Application Filing
- 2007-06-27 JP JP2009516983A patent/JP2009541541A/en active Pending
- 2007-06-27 CA CA002656164A patent/CA2656164A1/en not_active Abandoned
-
2008
- 2008-12-18 IL IL196029A patent/IL196029A0/en unknown
- 2008-12-30 MA MA31528A patent/MA30570B1/en unknown
-
2009
- 2009-01-05 ZA ZA200900018A patent/ZA200900018B/en unknown
Also Published As
Publication number | Publication date |
---|---|
CN101522882A (en) | 2009-09-02 |
DE102006029793A1 (en) | 2008-01-03 |
KR20090034337A (en) | 2009-04-07 |
RU2009102284A (en) | 2010-08-10 |
CA2656164A1 (en) | 2008-01-03 |
MX2008016465A (en) | 2009-03-02 |
EP2038396A1 (en) | 2009-03-25 |
IL196029A0 (en) | 2009-09-01 |
JP2009541541A (en) | 2009-11-26 |
MA30570B1 (en) | 2009-07-01 |
BRPI0713471A2 (en) | 2012-01-24 |
WO2008000456A1 (en) | 2008-01-03 |
ZA200900018B (en) | 2009-11-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK4 | Application lapsed section 142(2)(d) - no continuation fee paid for the application |