JPH11181500A - Foamable detergent for keeping immersion and its use - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a detergent in a solid state for clothing, artificial tooth, tableware and accessory, containing a foamable organic acid, a carbonate, an anionic surfactant and a nonionic surfactant having a high HLB or the like. SOLUTION: This detergent contains an organic acid to be foamed by an acid base reaction, such as citric acid, succinic acid, tartaric acid, fumaric acid, malic acid, adipic acid or the like, a carbonate such as sodium hydrogencarbonate, sodium carbonate or the like, and anionic surfactant, preferably sodium lauryl sulfate, a nonionic surfactant having 10-20 HLB (e.g. a polyoxyethylene oleyl ether, a polyoxyethylene stearyl ether or the like) and/or a saccharide (e.g. trehalose, maltose or the like) in a solid state such as granule, tablet or the like.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an immersion foaming detergent for attaching and cleaning dentures, clothes, wigs, tableware, dentures, accessories, etc., and a wig detergent using the immersion detergent. The present invention relates to a detergent for clothes, a detergent for dentures, a detergent for dishes, and a detergent for accessories.

[0002]

2. Description of the Related Art In general, a wig is composed of a hair portion such as artificial hair and a wig fabric in contact with the scalp. When using such wigs, it is necessary to wash them regularly because long-term use will cause dirt to adhere to the hair and the contact surface of the wig fabric with the scalp will become dirty with sebum and the like. is there. Conventionally, when cleaning a wig, it is common practice to hand-wash the hair portion and the wig fabric portion using an existing liquid detergent or shampoo. However, hand washing is complicated,
There is a need for a pickling detergent that enables washing of the wig by pickling and washing, that is, by putting a detergent and a wig into a container filled with hot water or the like and leaving it for a few hours. Therefore, although a wig cleaning agent immersed in a liquid that is easily soluble in water has been developed, a cleaning agent dedicated to a solid wig that is easy to handle and easy to transport has not been known.

By the way, as a solid pickling detergent, a pickling detergent dedicated to dentures has conventionally been marketed in the form of tablets. This pickling detergent for dentures dissolves while being foamed by an acid-base reaction when poured into water or the like, and cleans the dentures. At this time, as the cleaning component, an anionic surfactant is mainly used.For example, when the blending ratio of the anionic surfactant is increased to further improve the cleaning effect, the dissolution time of the tablet is extended,
There is a risk of not dissolving in the desired time. Therefore, the compounding ratio of the anionic surfactant cannot be increased, and it is difficult to wash the sebum and the like adhering to the wig cloth with a commercially available pickling detergent for dentures. In fact, no pickling detergent other than those for dentures has been developed because of its solubility problem. Further, as a solid detergent, granules may be considered in addition to tablets. However, even in the case of granules having a size considerably smaller than tablets, in the case of use in which physical stirring is hardly intended, such as immersion washing, the granules are to be cleaned or a container containing the cleaning target. It is difficult to dissolve the particles immediately before reaching the bottom or immediately after the particles reach the bottom. Therefore, at present, no pickling detergent having a granular form has been implemented.

[0004]

SUMMARY OF THE INVENTION It is an object of the present invention to provide a pickling system in which the dissolution rate can be controlled according to the amount of the anionic surfactant as a cleaning component, the form of the solid, and the object to be cleaned. A solid foaming pickling detergent exhibiting an effective washing action as a standing wash, and a wig detergent, a clothing detergent, a dishwashing detergent, and a denture detergent using the foaming pickling detergent. And a cleaning agent for accessories. Another object of the present invention is to control the dissolution rate in accordance with the amount of an anionic surfactant as a cleaning component and the form of a solid, without damaging the hair of the wig, sebum and the like attached to the wig fabric, etc. Another object of the present invention is to provide a wig detergent capable of effectively washing the wig.

[0005]

Means for Solving the Problems The present inventors have developed a practical immersion cleaning agent having a balance between dissolution time and cleaning action in a solid cleaning agent which is easy to handle and easy to transport. As a result of intensive studies for development, the inclusion of a specific nonionic surfactant and / or sugar in a solid detergent containing an organic acid and a carbonate that foams by an acid-base reaction makes it an excellent pickling detergent. It has been found that the present invention exerts the above-mentioned effects, and the present invention has been completed. That is, according to the present invention, an organic acid and a carbonate that foam by an acid-base reaction, an anionic surfactant, and an HLB of 10
More than 20 or less of a nonionic surfactant and / or sugar and, if necessary, further comprising one or more selected from the group consisting of a protease, a lipolytic enzyme and lysodium chloride, a tablet type or A pickling detergent characterized by being in the form of a solid such as a granule is provided. Further, according to the present invention, there is provided a wig cleaning agent characterized in that an antistatic agent is added to the pickled cleaning agent.
Further, according to the present invention, there is provided a cleaning agent for clothing, wherein a dirt re-adhesion preventing agent is blended with the pickled cleaning agent. Furthermore, according to the present invention, there is provided a dishwashing detergent characterized by containing the above-mentioned pickling detergent. Further, according to the present invention, there is provided a denture cleaning agent or an accessory cleaning agent, characterized in that a bleaching agent is blended with the pickled cleaning agent.

[0006]

DESCRIPTION OF THE PREFERRED EMBODIMENTS The foaming pickling detergent of the present invention comprises an organic acid and a carbonate foaming by an acid-base reaction, an anionic surfactant, a nonionic surfactant having a specific HLB and / or a sugar. As an essential component.

The above-mentioned organic acids and carbonates are foamed by an acid-base reaction when the pickling detergent is put into water or the like, to assist in pickling washing and to assist the solubility of the pickling detergent. It is not particularly limited as long as it is a component that acts and foams by an acid-base reaction. Examples of the carbonate include sodium hydrogencarbonate, sodium carbonate and a mixture thereof, and examples of the organic acid include citric acid, succinic acid, tartaric acid, fumaric acid, malic acid, adipic acid and a mixture thereof. The mixing ratio of the carbonate and the organic acid can be appropriately selected according to the form and use of the pickled detergent, but the carbonate is usually 10 to 70% by weight, preferably based on the total amount of the pickled detergent. Is 15-50
%, While the organic acid is usually 10 to 70% by weight, preferably 15 to 50% by weight, based on the total amount of the pickling detergent.
% By weight.

The above-mentioned anionic surfactant is a component exhibiting a detergency, and includes, for example, sodium lauryl sulfate, sodium tetradecene sulfonate, sodium polyoxyethylene lauryl ether sulfate or a mixture thereof. Sodium is particularly preferred. The mixing ratio of the anionic surfactant can be appropriately selected depending on the object to be cleaned, but is usually 0.1 to 70% by weight, preferably 1 to 70% by weight, based on the total amount of the immersion cleaning agent.
50% by weight.

The nonionic surfactant has an HLB of 10
, And 20 or less, preferably 12-18. Specifically, polyoxyethylene oleyl ether, polyoxyethylene stearyl ether, polyoxyethylene nonyl phenyl ether, or a mixture thereof, in which the HLB is within such a range, may be mentioned. At this time, a nonionic surfactant having an HLB of 10 or less can be contained, but the HLB of the entire nonionic surfactant in the immersion cleaning agent needs to be more than 10. When the HLB of the entire nonionic surfactant contained in the pickled detergent is 10 or less, the solubility of the pickled detergent decreases, and in particular, the solubility decreases when the blending amount of the anionic surfactant is increased. It becomes remarkable. The mixing ratio of the nonionic surfactant is preferably 1 to 20 parts by weight of the nonionic surfactant based on 100 parts by weight of the anionic surfactant.

The sugar is a component that improves the solubility of the pickled detergent and, in particular, maintains the desired solubility even when the amount of the anionic surfactant is increased in order to enhance the cleaning action. Examples thereof include monosaccharides, disaccharides, oligosaccharides, dextrins, and mixtures thereof.
Specifically, trehalose, maltose, glucose,
Xylose, sucrose and the like. The mixing ratio of sugar
30 to 60 parts by weight per 100 parts by weight of the anionic surfactant
Parts by weight are preferred.

[0011] The nonionic surfactant having an HLB of more than 10 and not more than 20 and the saccharide may contain either one or both.

[0012] In addition to the above components, the pickled detergent of the present invention may further contain various components commonly used according to each application. Examples include antistatic agents; antifouling agents; builders; enzymes such as proteolytic enzymes and lipolytic enzymes; lysodium chloride; pH adjusters; bleaches; fluorescent brighteners;

The pickling detergent of the present invention must be in a solid form such as granules and tablets. In order to prepare such a pickled detergent, the above-mentioned components can be obtained by a usual granulation or tableting method.

In the case of the tablet, in addition to the essential components, sodium edetate or the like for preventing discoloration with time after tableting, and a lubricant such as magnesium carbonate for improving the tableting property; polyethylene A shape retaining agent such as glycol,
It is preferable to add a disintegrating agent such as calcium carboxymethylcellulose in order to improve disintegration during use. The shape of the tablet is not particularly limited, but is preferably about 0.5 to 5 cm in diameter from the viewpoint of solubility, handleability, and the like.

To use the pickling detergent of the present invention,
An object to be cleaned and an appropriate amount of a detergent to be immersed in water or hot water are put into the apparatus, and the object to be cleaned can be used after being left for about 1 to 30 minutes and then washed with water.

The wig cleaner of the present invention is a solid form of the immersion cleaner further containing an antistatic agent as an essential component.

Examples of antistatic agents include cationized cellulose, alkyl quaternary ammonium, polyvinylpyrrolidone derivative quaternary ammonium, polyacrylic acid derivative quaternary ammonium, polyamide derivative quaternary ammonium, benzalkonium chloride, stearyltrimethylammonium chloride, chloride And cationic surfactants such as distearyl dimethyl ammonium. The content ratio of the antistatic agent is usually in the range of 0.01 to 2% by weight, preferably 0.1 to 1% by weight, based on the total amount of the wig detergent. If the amount of the antistatic agent is less than 0.01% by weight, static electricity is easily generated in the washed hair, which is not preferable.

The mixing ratio of the organic acid and carbonate, anionic surfactant, and nonionic surfactant and / or sugar having an HLB of more than 10 and not more than 20 to be contained in the wig cleaning agent is as follows. The amount is preferably within the range described for the agent, particularly, the organic acid is 10 to 50% by weight, the carbonate is 10 to 50% by weight, the anionic surfactant is 10 to 70% by weight, based on the total amount of the wig detergent. The nonionic surfactant is preferably 0.1 to 10% by weight, and the sugar is preferably 0.1 to 35% by weight.

The wig detergent of the present invention comprises the essential components and, if necessary, the desired components which can be used in ordinary detergents, in the form of granules or tablets, as in the case of the pickled detergent. Can be obtained. In order to use a wig detergent, a wig and an appropriate amount of a wig detergent are added to water or hot water, left for about 1 to 30 minutes, and then the wig is washed with water or the like.

The detergent for clothing of the present invention is a solid detergent comprising the above-mentioned pickled detergent and a soil re-adhesion inhibitor as an essential component. Examples of the stain re-adhesion preventive include carboxymethyl cellulose, polyethylene glycol, polyvinyl alcohol, polyvinyl pyrrolidone, and the like. The compounding ratio of the stain redeposition inhibitor is usually in the range of 0.1 to 7% by weight, preferably 1 to 5% by weight, based on the total amount of the detergent for clothing. The antifouling agent is 0.
If the amount is less than 1% by weight, it is not preferable because the washed dirt may adhere to the clothes again.

The mixing ratio of the organic acid and carbonate, the anionic surfactant, and the nonionic surfactant and / or sugar having an HLB of more than 10 and not more than 20 to be contained in the detergent for clothing is as follows. The range is preferably within the range described for the detergent. Particularly, the organic acid is 10 to 50% by weight, the carbonate is 10 to 50% by weight, and the anionic surfactant is 10 to 70% by weight based on the total amount of the detergent for clothing. %, The nonionic surfactant is preferably 0.1 to 10% by weight, and the sugar is preferably 0.1 to 35% by weight.

The detergent for clothing of the present invention may further contain, if necessary, a builder (cleaning aid), a bleaching agent, a fluorescent brightener, an enzyme, etc., which are usually used in detergents for clothing. Can also. Examples of the builder include sodium silicate, sodium metasilicate, zeolite, tripolyphosphate, edetate, and hydroxyethanephosphonic acid. Examples of the bleaching agent include sodium percarbonate and isocyanurate. Examples of the fluorescent whitening agent include diaminostilbenzylsulfonic acid, bis (triazinylamino) stilbenzylsulfonic acid derivatives, coumarin derivatives, and pyrazoline derivatives. As an enzyme,
Cellulase, amylase and the like can be mentioned. The mixing ratio of each optional component is not particularly limited and can be appropriately selected and mixed, but in the case of a builder, it is preferably 50% by weight.
Below, when blending, the lower limit is desirably 5% by weight.
In the case of a bleaching agent, the content is preferably 20% by weight or less, and the lower limit when it is blended is preferably 0.1% by weight. In the case of an optical brightener, the content is preferably 5% by weight or less, and the lower limit in the case of mixing is 0.1% by weight. In the case of an enzyme, the content is preferably 5% by weight or less, and the lower limit in the case of blending is desirably 0.01% by weight.

The detergent for clothing of the present invention comprises the essential components, optional components and, if necessary, the desired components which can be used in ordinary detergents, such as granules or tablets, as in the case of the pickled detergent. It can be obtained by preparing it in a solid form. In order to use the clothing detergent, the clothing and an appropriate amount of the clothing detergent are put into water or hot water, left for about 1 to 30 minutes, and then the clothing is washed with water or the like.

The dishwashing detergent of the present invention is a solid detergent containing the above-mentioned pickled detergent. The mixing ratio of the organic acids and carbonates, anionic surfactants, and nonionic surfactants and / or sugars having an HLB of more than 10 and not more than 20 to be contained in the dishwashing detergent is as follows: Preferably within the range described, particularly,
The organic acid is 10 to 50% by weight, the carbonate is 10 to 50% by weight, the anionic surfactant is 10 to 70% by weight, and the nonionic surfactant is 0.1 to 10% by weight based on the total amount of the dishwashing detergent.
% By weight, and 0.1 to 35% by weight of sugar.

The dishwashing agent of the present invention may further contain, if necessary, a builder (washing aid), a bleaching agent, an enzyme, a pH adjuster, etc., which are usually used in dishwashing agents. it can. Examples of the builder include sodium silicate, sodium metasilicate, zeolite, and tripolyphosphate. Examples of the bleaching agent include sodium percarbonate, isocyanurate, hypochlorous acid, and sulfite. Examples of the enzyme include amylase. As the pH adjuster, the mixing ratio of each optional component such as sodium hydroxide, potassium hydroxide and the like is not particularly limited and can be appropriately selected and mixed, but in the case of a builder, it is preferably 50% by weight or less. In the case of blending, the lower limit is desirably 5% by weight. In the case of a bleaching agent, it is preferably 50% by weight or less, and the lower limit in the case of blending is desirably 0.1% by weight. In the case of an enzyme, the content is preferably 10% by weight or less, and the lower limit in the case of blending is desirably 0.01% by weight. In the case of a pH adjuster, it is desirable to mix it so as to have a pH of 7 to 11, preferably 40% by weight or less, when the dishwashing detergent is dissolved.

The dishwashing detergent of the present invention comprises the essential components, optional components and, if necessary, the desired components which can be used in ordinary detergents, such as granules or tablets, like the pickled detergent. It can be obtained by preparing it in a solid form. In order to use the dishwashing detergent, it is possible to put the dish and an appropriate amount of dishwashing detergent in water or hot water, leave it for about 1 to 30 minutes, and then wash the dish with water or the like.

The denture cleaner of the present invention further contains a bleaching agent as an essential component in the pickling detergent. Examples of the bleaching agent include sodium percarbonate, isocyanurate, hypochlorous acid, and sulfite. The content of the bleaching agent is preferably 0.1 to 50% by weight based on the total amount of the denture cleaner. If the blending ratio of the bleaching agent is less than 0.1% by weight, it is not preferable because stains such as tar by cigarettes are not removed and the disinfection effect is not exhibited.

The mixing ratio of the organic acid and carbonate, the anionic surfactant, and the nonionic surfactant and / or sugar having an HLB of more than 10 to 20 or less, which are contained in the denture cleaner, is as follows. It is desirable that the cleaning agent is within the range described above.
Organic acid is 10 to 50% by weight, carbonate is 10 to 50% by weight, anionic surfactant is 0.1 to 50% by weight, nonionic surfactant is 0.1 to 5% by weight, sugar is 0.1 to 50% by weight. 15% by weight is preferred.

The denture cleaner of the present invention may further contain, if necessary, a builder (cleaning aid) which is usually contained in a denture cleaner. Examples of the builder include sodium silicate, sodium metasilicate, zeolite, and tripolyphosphate. The compounding ratio of the builder is preferably 50% by weight or less, and the lower limit in the case of compounding is preferably 5% by weight.

The denture cleaner of the present invention comprises the essential components, optional components, and, if necessary, the desired components which can be used in ordinary detergents, such as granules or tablets, like the pickled detergent. It can be obtained by preparing it in a solid form. To use the denture cleaner, add dentures in water or hot water and an appropriate amount of denture cleaner,
After leaving it for about 30 minutes, it can be used by a method of washing the dentures with water or the like.

The accessory detergent of the present invention further comprises a bleaching agent as an essential component in the pickled detergent. Examples of the bleaching agent include sodium percarbonate, isocyanurate, hypochlorous acid, and sulfite.

The mixing ratio of the bleach is preferably 0.1 to 50% by weight based on the total amount of the detergent for accessories. When the blending ratio of the bleaching agent is less than 0.1% by weight, it is not preferable because dirt is hardly removed and no germicidal effect is exhibited.

The mixing ratio of the organic acid and carbonate, the anionic surfactant, and the nonionic surfactant and / or sugar having an HLB of more than 10 to 20 or less to be contained in the accessory detergent is as follows. The range is preferably within the range described for the cleaning agent. Particularly, the organic acid is 10 to 50% by weight and the carbonate is 10 to 10% by weight based on the total amount of the cleaning agent for accessories.
To 50% by weight, 0.1 to 50% by weight of anionic surfactant, 0.1 to 5% by weight of nonionic surfactant, and 0.1 to 5% by weight of sugar.
1-15% by weight is preferred.

The accessory detergent of the present invention may further contain, if necessary, a builder (cleaning aid) which is usually contained in the accessory detergent. Examples of the builder include sodium silicate, sodium metasilicate, zeolite, and tripolyphosphate. The compounding ratio of the builder is preferably 50% by weight or less, and the lower limit in the case of compounding is preferably 5% by weight.

The detergent for accessories of the present invention comprises the essential components, optional components and, if necessary, desired components which can be used in ordinary detergents, such as granules or tablets, as in the case of the pickled detergent. It can be obtained by preparing it in a solid form. In order to use the accessory cleaning agent, the accessory and an appropriate amount of the accessory cleaning agent are added to water or hot water, left for about 1 to 30 minutes, and then the accessory is washed with water.

[0036]

The pickling detergent of the present invention and various detergents using the same are composed of an organic acid and a carbonate, an anionic surfactant, and a nonionic surfactant and / or a sugar having a specific HLB. Since it contains, desired solubility can be maintained even if the compounding amount of the anionic surfactant is increased in order to improve the detergency, and even in the form of granules, it can be immersed and washed with excellent detergency. . Moreover, since it is in a solid form, it is easy to transport and the like, and is useful as a wig detergent, a clothing detergent, a dish detergent, a denture detergent, an accessory detergent, and the like.

[0037]

The present invention will be described in more detail with reference to the following examples.
The present invention is not limited to these.

Examples 1 to 5 and Comparative Examples 1 to 3 Sodium carbonate as a carbonate, malic acid and / or adipic acid as an organic acid, sodium lauryl sulfate as an anionic surfactant, and H as a nonionic surfactant
Using polyoxyethylene oleyl ether of LB14, lactose as sugar and benzalkonium chloride as antistatic agent, respectively, and mixing with other components in the mixing ratio shown in Table 1, and then preparing wig detergent as granules did.

10 g of each of the obtained wig cleaners was added to about 3 liters of water (20 ° C.) and allowed to stand, and the dissolution time was measured. The same measurement was performed 30 times for one wig detergent. Table 2 shows the results. After soaking the dirty wig in about 3 liters of water (20 ° C.), the prepared wig cleaning agent was added and left for 3 minutes. After standing, the plate was washed with water and the state of washing was evaluated. The same measurement was performed 30 times for one wig detergent. Table 3 shows the results. The wig detergents of Comparative Examples 1 and 3 did not completely dissolve, and the wig detergent itself was attached to the wig.

[0040]

[Table 1]

[0041]

[Table 2]

[0042]

[Table 3]

Examples 6 to 9 and Comparative Examples 4 to 7 Sodium carbonate as a carbonate, malic acid as an organic acid, sodium lauryl sulfate as an anionic surfactant, and polyoxyethylene oleyl of HLB 14 as a nonionic surfactant Using ether, lactose as sugar and carboxymethylcellulose as a stain redeposition preventive agent, respectively, and mixing with other components at the mixing ratio shown in Table 4, the mixture was granulated to prepare a pickling detergent for clothing. Each of the obtained pickling detergents for clothes was added to 5 g of about 5 liters of water (20 ° C.) and allowed to stand, and the dissolution time was measured. 30 per pickling detergent for clothing
The same measurement was performed twice. Table 5 shows the results. Also, about 5
After immersing the clothing stained with sebum in 1 liter of water, 5 g of the prepared immersion cleaning agent for clothing was added and left for 20 minutes. After the standing, it was washed with water and the state of washing was evaluated. The same measurement was performed 30 times for one immersion detergent for clothes. Table 6 shows the results.

[0044]

[Table 4]

[0045]

[Table 5]

[0046]

[Table 6]

Examples 10 to 12 and Comparative Examples 8 to 10 Sodium carbonate as a carbonate, malic acid as an organic acid, sodium lauryl sulfate as an anionic surfactant, and polyoxyethylene stearyl of HLB 18 as a nonionic surfactant Ether was used, and lactose was used as a sugar. The mixture was mixed with other components at the compounding ratio shown in Table 7 and then granulated to prepare a dishwashing detergent. Each of the obtained dishwashing detergents was added to 3 g of about 3 liters of water (20 ° C.) and allowed to stand, and the dissolution time was measured. 30 for one dishwashing detergent
The same measurement was performed twice. Table 8 shows the results. Also, about 3
After soaking the dirty tableware in 1 liter of water, 3 g of the prepared dishwashing detergent was added and left for 15 minutes. After the standing, it was washed with water and the state of washing was evaluated. The same measurement was performed 30 times for one dishwashing detergent. Table 9 shows the results.

[0048]

[Table 7]

[0049]

[Table 8]

[0050]

[Table 9]

Examples 13 to 15 and Comparative Examples 11 to 14 Sodium carbonate as a carbonate, tartaric acid as an organic acid, sodium lauryl sulfate as an anionic surfactant, and polyoxyethylene stearyl ether of HLB 18 as a nonionic surfactant And trehalose as a sugar and sodium percarbonate and sodium sulfite as a bleaching agent, respectively, were mixed together with other components at the mixing ratio shown in Table 10, and then granulated to prepare a pickling detergent for dentures. Each of the obtained pickling detergents for dentures was added to 3 g of about 0.2 liter of water (20 ° C.) and allowed to stand, and the dissolution time was measured. The same measurement was carried out 30 times for one denture pickling detergent. Table 11 shows the results. Also, after soaking the dirty dentures in about 0.2 liter of water, 3 g of the prepared denture pickling detergent is prepared.
Was added and left for 10 minutes. After the standing, it was washed with water and the state of washing was evaluated. The same measurement was carried out 30 times for one denture pickling detergent. Table 12 shows the results.

[0052]

[Table 10]

[0053]

[Table 11]

[0054]

[Table 12]

Examples 16 to 18 and Comparative Examples 15 to 18 Sodium carbonate as a carbonate, tartaric acid as an organic acid, sodium lauryl sulfate as an anionic surfactant, and polyoxyethylene stearyl ether of HLB 18 as a nonionic surfactant And maltose as sugar and sodium percarbonate and sodium sulfite as bleaching agents were mixed together with other components at the mixing ratio shown in Table 13, and then granulated to prepare a pickling detergent for accessories. Each of the obtained pickling detergents for accessories was added to 3 g of about 0.2 liter of water (20 ° C.) and allowed to stand, and the dissolution time was measured. The same measurement was performed 30 times for one accessory pickling detergent. Table 14 shows the results. Also, after soaking the dirty metal necklace in about 0.2 liter of water, 3 g of the prepared pickling detergent for accessories was added and left for 10 minutes. After the standing, it was washed with water and the state of washing was evaluated.
The same measurement was performed 30 times for one accessory pickling detergent. Table 15 shows the results.

[0056]

[Table 13]

[0057]

[Table 14]

[0058]

[Table 15]

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁶ Identification code FI C11D 3/386 C11D 3/386

Claims (8)

[Claims] 1. An organic acid and a carbonate which foam by an acid-base reaction, an anionic surfactant, and an HLB exceeding 10
0 or less nonionic surfactant and / or sugar,
A pickling detergent characterized by being in a solid form. 2. The pickling detergent according to claim 1, further comprising one or more members selected from the group consisting of a protease, a lipolytic enzyme and lysodium chloride. 3. The pickling detergent according to claim 1, wherein the form is a tablet type or a granular type. 4. A wig cleaning agent, characterized in that an antistatic agent is added to the pickled cleaning agent according to any one of claims 1 to 3. 5. A cleaning agent for clothing, comprising a pickling-in-place cleaning agent according to any one of claims 1 to 3, and a soil re-adhesion preventing agent. 6. A dishwashing detergent comprising the pickling detergent according to any one of claims 1 to 3. 7. A cleaning agent for dentures, characterized in that a bleaching agent is added to the pickling detergent according to any one of claims 1 to 3. 8. A cleaning agent for accessories, wherein a bleaching agent is blended with the pickling cleaning agent according to any one of claims 1 to 3.