AU2006283693A1 - Controlled release of additive gel(s) for functional fluids - Google Patents

Controlled release of additive gel(s) for functional fluids Download PDF

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Publication number
AU2006283693A1
AU2006283693A1 AU2006283693A AU2006283693A AU2006283693A1 AU 2006283693 A1 AU2006283693 A1 AU 2006283693A1 AU 2006283693 A AU2006283693 A AU 2006283693A AU 2006283693 A AU2006283693 A AU 2006283693A AU 2006283693 A1 AU2006283693 A1 AU 2006283693A1
Authority
AU
Australia
Prior art keywords
fluid
functional fluid
gel
additive
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2006283693A
Other languages
English (en)
Inventor
Mark R. Baker
Bryan A. Grisso
Jennifer M. Ineman
Brian M. O'connor
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lubrizol Corp
Original Assignee
Lubrizol Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lubrizol Corp filed Critical Lubrizol Corp
Publication of AU2006283693A1 publication Critical patent/AU2006283693A1/en
Abandoned legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M163/00Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/028Overbased salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26Overbased carboxylic acid salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26Overbased carboxylic acid salts
    • C10M2207/262Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28Amides; Imides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046Overbasedsulfonic acid salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/089Overbased salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/043Ammonium or amine salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/042Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/044Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/08Hydraulic fluids, e.g. brake-fluids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines
    • C10N2040/255Gasoline engines
    • C10N2040/26Two-strokes or two-cycle engines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/08Solids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/12Micro capsules
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00Specific manufacturing methods for lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00Specific manufacturing methods for lubricant compositions
    • C10N2070/02Concentrating of additives

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
AU2006283693A 2005-08-24 2006-08-16 Controlled release of additive gel(s) for functional fluids Abandoned AU2006283693A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/210,616 US20070049505A1 (en) 2005-08-24 2005-08-24 Controlled release of additive gel(s) for functional fluids
US11/210,616 2005-08-24
PCT/US2006/031948 WO2007024590A1 (en) 2005-08-24 2006-08-16 Controlled release of additive gel(s) for functional fluids

Publications (1)

Publication Number Publication Date
AU2006283693A1 true AU2006283693A1 (en) 2007-03-01

Family

ID=37564422

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2006283693A Abandoned AU2006283693A1 (en) 2005-08-24 2006-08-16 Controlled release of additive gel(s) for functional fluids

Country Status (10)

Country Link
US (1) US20070049505A1 (zh)
EP (1) EP1924673A1 (zh)
JP (1) JP2009506162A (zh)
KR (1) KR20080045239A (zh)
CN (1) CN101292017A (zh)
AU (1) AU2006283693A1 (zh)
BR (1) BRPI0615067A2 (zh)
CA (1) CA2618851A1 (zh)
MX (1) MX2008002476A (zh)
WO (1) WO2007024590A1 (zh)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6843916B2 (en) * 2002-07-16 2005-01-18 The Lubrizol Corporation Slow release lubricant additives gel
US7833955B2 (en) * 2006-11-08 2010-11-16 The Lubrizol Corporation Viscosity modifiers in controlled release lubricant additive gels
US8022021B2 (en) * 2007-02-05 2011-09-20 The Lubrizol Corporation Low ash controlled release gels
US20090075853A1 (en) * 2007-09-18 2009-03-19 Mathur Naresh C Release additive composition for oil filter system
US20090101561A1 (en) * 2007-10-19 2009-04-23 The Lubrizol Corporation Filter Cap Additive Delivery System
CA2710250A1 (en) * 2007-12-27 2009-07-09 The Lubrizol Corporation Engine oil formulations for biodiesel fuels
US20090291865A1 (en) * 2008-05-23 2009-11-26 Brennan Brent L Controlled release of additives in gas turbine lubricating compositions
EP2393907A1 (en) * 2009-02-09 2011-12-14 The Lubrizol Corporation Method for improved performance of a functional fluid
US9296969B2 (en) 2009-02-16 2016-03-29 Chemtura Corporation Fatty sorbitan ester based friction modifiers
US20100210487A1 (en) 2009-02-16 2010-08-19 Chemtura Coproration Fatty sorbitan ester based friction modifiers
DE102010018311A1 (de) * 2009-04-24 2011-08-04 Chemische Werke Kluthe GmbH, 69115 Verfahren sowie Formulierungen für die biozide Behandlung eines Kühlschmierstoffs
DE102009031342A1 (de) 2009-07-01 2011-01-05 Daimler Ag Verwendung von Schmierölen mit mikrogekapselten Schmierstoffadditiven, Verwendung derselben in Schmierölen für Kraftfahrzeuge mit Verbrennungsmotor und Verbrennungsmotor mit mikrogekapselte Schmierstoffadditive enthaltenden Schmieröl
EP2462213A1 (en) * 2009-08-04 2012-06-13 The Lubrizol Corporation Compositions with fast and slow release components
US8727627B2 (en) 2009-09-14 2014-05-20 The Timken Company Apparatus and method for controlled release of lubricant additives in bearing and gear assemblies
KR102325606B1 (ko) * 2011-10-27 2021-11-16 더루우브리졸코오포레이션 씰 융화성이 향상된 윤활제
US20130146009A1 (en) * 2011-12-07 2013-06-13 GM Global Technology Operations LLC Microencapsulated engine lubricant additives
FR3004723B1 (fr) * 2013-04-19 2016-04-15 Total Raffinage Marketing Composition lubrifiante a base de nanoparticules metalliques
US9090850B1 (en) * 2014-06-19 2015-07-28 Afton Chemical Corporation Phosphorus anti-wear compounds for use in lubricant compositions
EP3420060A1 (en) * 2016-02-26 2019-01-02 ExxonMobil Research and Engineering Company Lubricant compositions containing controlled release additives
CN107418653B (zh) * 2017-07-04 2020-02-07 佛山科学技术学院 一种延长陶瓷压砖机在用液压油使用期的方法
CN110410418B (zh) * 2019-07-18 2021-07-13 风下电机(山东)有限公司 一种自主补充润滑油的含油轴承及补充方法
WO2022022929A1 (de) 2020-07-29 2022-02-03 Sew-Eurodrive Gmbh & Co. Kg Verfahren zum herstellen eines getriebes mit schmierstoff und getriebesystem

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US3939082A (en) * 1970-05-05 1976-02-17 Sun Oil Company Of Pennsylvania Soap thickened lubricant composition
US3749247A (en) * 1970-09-21 1973-07-31 Phillips Petroleum Co Addition of oxidation inhibitor to lubricating oil
US4075097A (en) * 1975-04-01 1978-02-21 Monroe Auto Equipment Company Oil filter with oil improving dissolving body
US4144166A (en) * 1977-03-24 1979-03-13 Atlantic Richfield Company Compositions, apparatus and methods useful for releasing solid lubricating oil additive
EP0783032A4 (en) * 1995-07-20 1998-12-23 Idemitsu Kosan Co LUBRICATING OIL COMPOSITION
US5776494A (en) * 1996-12-20 1998-07-07 The Procter & Gamble Company Pharmaceuticals compositions containing gellants in the form of alkyl amides of di-and tri-carboxylic acids
US6969461B2 (en) * 2000-01-19 2005-11-29 Baldwin Filters, Inc. Combination particulate and acid-neutralizing filter
US6607694B1 (en) * 2000-03-31 2003-08-19 Dober Chemical Corp. Controlled release coolant additive composition
DE10297145T5 (de) * 2001-08-24 2004-07-22 Dober Chemical Corporation, Midlothian Kontrollierte Freisetzung von Additiven in Fluidsysteme
US7137243B2 (en) * 2002-07-03 2006-11-21 Rolls-Royce North American Technologies, Inc. Constant volume combustor
US7384896B2 (en) * 2002-07-16 2008-06-10 The Lubrizol Corporation Controlled release of additive gel(s) for functional fluids
US6843916B2 (en) * 2002-07-16 2005-01-18 The Lubrizol Corporation Slow release lubricant additives gel
US7056870B2 (en) * 2003-02-12 2006-06-06 General Motors Corporation Controlled release of antifoam additives from compounded rubber
US7087674B2 (en) * 2003-02-12 2006-08-08 General Motors Corporation Controlled release of perfluoropolyether antifoam additives from compounded rubber
US7124729B2 (en) * 2003-02-14 2006-10-24 General Motors Corporation Additive-containing, dissolvable coating on engine part that contacts oil
CN1993173B (zh) * 2004-06-11 2016-01-06 布拉斯通产品公司 汽车添加剂组合物

Also Published As

Publication number Publication date
WO2007024590A1 (en) 2007-03-01
US20070049505A1 (en) 2007-03-01
BRPI0615067A2 (pt) 2011-05-03
EP1924673A1 (en) 2008-05-28
CA2618851A1 (en) 2007-03-01
JP2009506162A (ja) 2009-02-12
CN101292017A (zh) 2008-10-22
KR20080045239A (ko) 2008-05-22
MX2008002476A (es) 2008-04-07

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MK1 Application lapsed section 142(2)(a) - no request for examination in relevant period