AU2004303868A1 - Regenerative removal of trace carbon monoxide - Google Patents
Regenerative removal of trace carbon monoxide Download PDFInfo
- Publication number
- AU2004303868A1 AU2004303868A1 AU2004303868A AU2004303868A AU2004303868A1 AU 2004303868 A1 AU2004303868 A1 AU 2004303868A1 AU 2004303868 A AU2004303868 A AU 2004303868A AU 2004303868 A AU2004303868 A AU 2004303868A AU 2004303868 A1 AU2004303868 A1 AU 2004303868A1
- Authority
- AU
- Australia
- Prior art keywords
- carbon monoxide
- clinoptilolite
- adsorbent
- hydrogen
- ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims description 90
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims description 85
- 230000001172 regenerating effect Effects 0.000 title description 2
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 claims description 67
- 229910001603 clinoptilolite Inorganic materials 0.000 claims description 57
- 238000000034 method Methods 0.000 claims description 52
- 239000011575 calcium Substances 0.000 claims description 49
- 238000005342 ion exchange Methods 0.000 claims description 46
- 230000008569 process Effects 0.000 claims description 46
- 150000001768 cations Chemical class 0.000 claims description 45
- 239000003463 adsorbent Substances 0.000 claims description 43
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 40
- 229910052791 calcium Inorganic materials 0.000 claims description 38
- 239000001257 hydrogen Substances 0.000 claims description 37
- 229910052739 hydrogen Inorganic materials 0.000 claims description 37
- 239000011734 sodium Substances 0.000 claims description 37
- 229930195733 hydrocarbon Natural products 0.000 claims description 35
- 150000002430 hydrocarbons Chemical class 0.000 claims description 35
- 239000011148 porous material Substances 0.000 claims description 35
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 34
- 229910052708 sodium Inorganic materials 0.000 claims description 27
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 25
- 239000004215 Carbon black (E152) Substances 0.000 claims description 21
- -1 barium cations Chemical class 0.000 claims description 19
- 239000011777 magnesium Substances 0.000 claims description 19
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 16
- 229910052788 barium Inorganic materials 0.000 claims description 16
- 229910052700 potassium Inorganic materials 0.000 claims description 16
- 239000011591 potassium Substances 0.000 claims description 16
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 10
- 229910052744 lithium Inorganic materials 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- 238000006317 isomerization reaction Methods 0.000 claims description 8
- 239000012188 paraffin wax Substances 0.000 claims description 8
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 238000001833 catalytic reforming Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000000746 purification Methods 0.000 claims description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 2
- 230000008929 regeneration Effects 0.000 claims 1
- 238000011069 regeneration method Methods 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 description 35
- 238000011068 loading method Methods 0.000 description 24
- 239000000243 solution Substances 0.000 description 21
- 239000010457 zeolite Substances 0.000 description 21
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 18
- 239000005977 Ethylene Substances 0.000 description 18
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000002808 molecular sieve Substances 0.000 description 11
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 11
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 10
- 230000004913 activation Effects 0.000 description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 10
- 239000007789 gas Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 229910021536 Zeolite Inorganic materials 0.000 description 8
- 238000000926 separation method Methods 0.000 description 8
- 239000012266 salt solution Substances 0.000 description 7
- 150000003839 salts Chemical group 0.000 description 7
- 239000002585 base Substances 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 150000002500 ions Chemical group 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 5
- 230000007717 exclusion Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 5
- 238000010926 purge Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- 230000018044 dehydration Effects 0.000 description 4
- 238000006297 dehydration reaction Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 238000004220 aggregation Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 238000003795 desorption Methods 0.000 description 3
- 239000008246 gaseous mixture Substances 0.000 description 3
- 239000000395 magnesium oxide Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 238000005086 pumping Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000004931 aggregating effect Effects 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000005445 natural material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 241000269420 Bufonidae Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000002156 adsorbate Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001553 barium compounds Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000013101 initial test Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
- C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/165—Natural alumino-silicates, e.g. zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Water Supply & Treatment (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Separation Of Gases By Adsorption (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/741,739 US20050137443A1 (en) | 2003-12-19 | 2003-12-19 | Regenerative removal of trace carbon monoxide |
| US10/741,739 | 2003-12-19 | ||
| PCT/US2004/042305 WO2005061421A1 (en) | 2003-12-19 | 2004-12-16 | Regenerative removal of trace carbon monoxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2004303868A1 true AU2004303868A1 (en) | 2005-07-07 |
Family
ID=34678256
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2004303868A Abandoned AU2004303868A1 (en) | 2003-12-19 | 2004-12-16 | Regenerative removal of trace carbon monoxide |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US20050137443A1 (enExample) |
| EP (1) | EP1697284A1 (enExample) |
| JP (1) | JP5089171B2 (enExample) |
| CN (1) | CN1918091A (enExample) |
| AU (1) | AU2004303868A1 (enExample) |
| WO (1) | WO2005061421A1 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2584217C (en) * | 2004-10-29 | 2012-05-22 | Eisenmann Corporation | Natural gas injection system for regenerative thermal oxidizer |
| JP2007091498A (ja) * | 2005-09-27 | 2007-04-12 | Kobe Steel Ltd | 水素製造方法 |
| US7592284B2 (en) * | 2006-03-13 | 2009-09-22 | Honeywell International Inc. | Preparation of ion exchanged polymer bound nitrogen adsorbent |
| EP2006011A1 (en) * | 2007-06-22 | 2008-12-24 | Total Petrochemicals Research Feluy | Process for reducing carbon monoxide in olefin-containing hydrocarbon feedstocks |
| US7687049B2 (en) * | 2008-07-22 | 2010-03-30 | Uop Llc | Apparatus and process for removal of carbon monoxide |
| JP6093519B2 (ja) * | 2011-12-20 | 2017-03-08 | 東京瓦斯株式会社 | 窒素含有炭化水素ガスからの窒素分離方法および装置 |
| JP6123178B2 (ja) * | 2012-07-11 | 2017-05-10 | 東ソー株式会社 | メタン吸着剤およびそれを用いたメタン吸着除去方法 |
| JP7142279B2 (ja) * | 2016-09-29 | 2022-09-27 | 地方独立行政法人青森県産業技術センター | 有機化合物と水蒸気の低減剤 |
| US10717035B2 (en) * | 2017-02-13 | 2020-07-21 | Praxair Technology, Inc. | Tunable adsorbents |
| US10710887B2 (en) * | 2018-11-21 | 2020-07-14 | Uop Llc | Zeolitic material UZM-63 |
| US11420869B2 (en) * | 2019-02-22 | 2022-08-23 | Uop Llc | Process for removing oxygen from a hydrogen stream |
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| US3359198A (en) * | 1965-07-09 | 1967-12-19 | Universal Oil Prod Co | Gas purification method |
| SU552102A1 (ru) * | 1975-03-14 | 1977-03-30 | Белорусский технологический институт им.С.М.Кирова | Способ получени адсорбента |
| SU679228A1 (ru) * | 1976-08-23 | 1979-08-15 | Институт Газа Ан Украинской Сср | Способ адсорбционной очистки газовых смесей от окиси углерода |
| SU895488A1 (ru) * | 1979-07-03 | 1982-01-07 | Всесоюзный Научно-Исследовательский И Проектный Институт По Подготовке @К Транспортировке И Переработке Природного Газа | Способ гидротермальной обработки клиноптилолита |
| US4483766A (en) * | 1983-06-20 | 1984-11-20 | Uop Inc. | Process for catalytic reforming |
| JPS60139337A (ja) * | 1983-12-27 | 1985-07-24 | Toyo Soda Mfg Co Ltd | 一酸化炭素吸着剤 |
| SU1189491A1 (ru) * | 1984-02-28 | 1985-11-07 | Тбилисский Ордена Трудового Красного Знамени Государственный Университет | Способ получени поглотител окислов азота и окиси углерода |
| JPS61255994A (ja) * | 1985-05-09 | 1986-11-13 | Kansai Coke & Chem Co Ltd | 高カロリ−ガスの製造方法 |
| JPS61255995A (ja) * | 1985-05-09 | 1986-11-13 | Kansai Coke & Chem Co Ltd | 高カロリ−ガスの製造法 |
| JPH062575B2 (ja) * | 1985-12-05 | 1994-01-12 | 東ソー株式会社 | クリノプチロライト型ゼオライトおよびその製造方法 |
| US4709116A (en) * | 1986-06-30 | 1987-11-24 | Union Carbide Corporation | Isomerization process and apparatus |
| JPS63139991A (ja) * | 1986-12-02 | 1988-06-11 | Kansai Coke & Chem Co Ltd | 高カロリ−ガスの製造方法 |
| JPS63139990A (ja) * | 1986-12-02 | 1988-06-11 | Kansai Coke & Chem Co Ltd | 高カロリ−ガスの製造法 |
| JPH0765059B2 (ja) * | 1987-01-18 | 1995-07-12 | 関西熱化学株式会社 | 高カロリ−ガスの製造法 |
| ES2024591B3 (es) * | 1987-06-15 | 1992-03-01 | Uop Inc | Proceso y aparato de isomerizacion. |
| US5019667A (en) * | 1988-06-14 | 1991-05-28 | Uop | Process for purification of hydrocarbons |
| US4935580A (en) * | 1988-06-14 | 1990-06-19 | Uop | Process for purification of hydrocarbons using metal exchanged clinoptilolite to remove carbon dioxide |
| US5116793A (en) * | 1988-06-14 | 1992-05-26 | Uop | Process for modifying clinoptilolite adsorbent |
| SU1715395A1 (ru) * | 1989-11-17 | 1992-02-28 | Тбилисский Государственный Университет Им.М.Джавахишвили | Способ получени катализатора дл очистки газов от оксидов азота и окиси углерода |
| US4964889A (en) * | 1989-12-04 | 1990-10-23 | Uop | Selective adsorption on magnesium-containing clinoptilolites |
| JPH0421639A (ja) * | 1990-05-07 | 1992-01-24 | Uop Inc | Ｃｏ↓２及び炭化水素混合物からｃｏ↓２を分離する方法と吸着剤 |
| US5164076A (en) * | 1991-01-22 | 1992-11-17 | Uop | Process for the adsorption of hydrogen sulfide with clinoptilolite molecular sieves |
| US5587003A (en) * | 1995-03-21 | 1996-12-24 | The Boc Group, Inc. | Removal of carbon dioxide from gas streams |
| FR2749004B1 (fr) * | 1996-05-24 | 1998-07-10 | Air Liquide | Procede pour la purification de melanges gazeux a base d'hydrogene utilisant une zeolithe x echangee au lithium |
| US5993517A (en) * | 1998-03-17 | 1999-11-30 | The Boc Group, Inc. | Two stage pressure swing adsorption process |
| US6340382B1 (en) * | 1999-08-13 | 2002-01-22 | Mohamed Safdar Allie Baksh | Pressure swing adsorption process for the production of hydrogen |
| AU2003239922A1 (en) * | 2002-05-31 | 2003-12-19 | Praxair Technology, Inc. | Production of high purity and ultra-high purity gas |
-
2003
- 2003-12-19 US US10/741,739 patent/US20050137443A1/en not_active Abandoned
-
2004
- 2004-12-16 JP JP2006545443A patent/JP5089171B2/ja not_active Expired - Fee Related
- 2004-12-16 AU AU2004303868A patent/AU2004303868A1/en not_active Abandoned
- 2004-12-16 EP EP04814484A patent/EP1697284A1/en not_active Withdrawn
- 2004-12-16 CN CNA2004800417300A patent/CN1918091A/zh active Pending
- 2004-12-16 WO PCT/US2004/042305 patent/WO2005061421A1/en not_active Ceased
-
2009
- 2009-09-25 US US12/567,157 patent/US20100005964A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US20100005964A1 (en) | 2010-01-14 |
| JP2007514537A (ja) | 2007-06-07 |
| US20050137443A1 (en) | 2005-06-23 |
| WO2005061421A1 (en) | 2005-07-07 |
| JP5089171B2 (ja) | 2012-12-05 |
| EP1697284A1 (en) | 2006-09-06 |
| CN1918091A (zh) | 2007-02-21 |
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