AU2002359593A1 - Delayed cooking process for producing anisotropic free-flowing shot coke - Google Patents
Delayed cooking process for producing anisotropic free-flowing shot coke Download PDFInfo
- Publication number
- AU2002359593A1 AU2002359593A1 AU2002359593A AU2002359593A AU2002359593A1 AU 2002359593 A1 AU2002359593 A1 AU 2002359593A1 AU 2002359593 A AU2002359593 A AU 2002359593A AU 2002359593 A AU2002359593 A AU 2002359593A AU 2002359593 A1 AU2002359593 A1 AU 2002359593A1
- Authority
- AU
- Australia
- Prior art keywords
- coke
- residuum
- flowing
- coking
- anisotropic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000571 coke Substances 0.000 title claims description 96
- 238000000034 method Methods 0.000 title claims description 45
- 230000008569 process Effects 0.000 title claims description 39
- 230000003111 delayed effect Effects 0.000 title claims description 32
- 238000010411 cooking Methods 0.000 title 1
- 238000004939 coking Methods 0.000 claims description 39
- 239000007800 oxidant agent Substances 0.000 claims description 19
- 239000003518 caustics Substances 0.000 claims description 12
- 239000003039 volatile agent Substances 0.000 claims description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 150000002432 hydroperoxides Chemical class 0.000 claims description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 2
- 150000004966 inorganic peroxy acids Chemical class 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 150000001451 organic peroxides Chemical class 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- 238000010791 quenching Methods 0.000 claims description 2
- 230000000171 quenching effect Effects 0.000 claims description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 10
- 239000003921 oil Substances 0.000 description 9
- 239000003208 petroleum Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- 229910052717 sulfur Inorganic materials 0.000 description 8
- 239000011593 sulfur Substances 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000011331 needle coke Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 238000005553 drilling Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- -1 i.e. Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Inorganic materials [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000004517 catalytic hydrocracking Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000386 microscopy Methods 0.000 description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 description 2
- 150000002830 nitrogen compounds Chemical class 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000011269 tar Substances 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 125000005608 naphthenic acid group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G55/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process
- C10G55/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only
- C10G55/04—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only including at least one thermal cracking step
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B55/00—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/08—Non-mechanical pretreatment of the charge, e.g. desulfurization
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Coke Industry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US33677801P | 2001-12-04 | 2001-12-04 | |
| US60/336,778 | 2001-12-04 | ||
| US10/293,373 US20030102250A1 (en) | 2001-12-04 | 2002-11-12 | Delayed coking process for producing anisotropic free-flowing shot coke |
| US10/293,373 | 2002-11-12 | ||
| PCT/US2002/038699 WO2003048271A1 (en) | 2001-12-04 | 2002-12-03 | Delayed coking process for producing anisotropic free-flowing shot coke |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2002359593A1 true AU2002359593A1 (en) | 2003-06-17 |
Family
ID=26967910
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2002359593A Abandoned AU2002359593A1 (en) | 2001-12-04 | 2002-12-03 | Delayed cooking process for producing anisotropic free-flowing shot coke |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20030102250A1 (ja) |
| EP (1) | EP1451266A1 (ja) |
| JP (1) | JP2006500431A (ja) |
| CN (1) | CN1599784A (ja) |
| AR (1) | AR037685A1 (ja) |
| AU (1) | AU2002359593A1 (ja) |
| CA (1) | CA2468711A1 (ja) |
| WO (1) | WO2003048271A1 (ja) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8147676B2 (en) * | 2001-12-04 | 2012-04-03 | Exxonmobil Research And Engineering Company | Delayed coking process |
| US7645375B2 (en) | 2003-05-16 | 2010-01-12 | Exxonmobil Research And Engineering Company | Delayed coking process for producing free-flowing coke using low molecular weight aromatic additives |
| US7658838B2 (en) | 2003-05-16 | 2010-02-09 | Exxonmobil Research And Engineering Company | Delayed coking process for producing free-flowing coke using polymeric additives |
| EP1633831B1 (en) | 2003-05-16 | 2015-05-06 | ExxonMobil Research and Engineering Company | Delayed coking process for producing free-flowing shot coke |
| MXPA06011752A (es) * | 2004-05-14 | 2007-01-16 | Exxonmobil Res & Eng Co | Produccion y remocion de coque de flujo libre de tambor coquizador retrasado. |
| CN101550096A (zh) | 2004-05-14 | 2009-10-07 | 埃克森美孚研究工程公司 | 抑制剂增强的重油热改质 |
| EP1773967A1 (en) | 2004-05-14 | 2007-04-18 | Exxonmobil Research And Engineering Company | Viscoelastic upgrading of heavy oil by altering its elastic modulus |
| AU2005245863A1 (en) | 2004-05-14 | 2005-12-01 | Exxonmobil Research And Engineering Company | Blending of resid feedstocks to produce a coke that is easier to remove from a coker drum |
| US7914668B2 (en) * | 2005-11-14 | 2011-03-29 | Exxonmobil Research & Engineering Company | Continuous coking process |
| US7811444B2 (en) | 2006-06-08 | 2010-10-12 | Marathon Oil Canada Corporation | Oxidation of asphaltenes |
| US7871510B2 (en) | 2007-08-28 | 2011-01-18 | Exxonmobil Research & Engineering Co. | Production of an enhanced resid coker feed using ultrafiltration |
| US7794587B2 (en) | 2008-01-22 | 2010-09-14 | Exxonmobil Research And Engineering Company | Method to alter coke morphology using metal salts of aromatic sulfonic acids and/or polysulfonic acids |
| FR2958657B1 (fr) * | 2010-04-13 | 2012-05-11 | Inst Francais Du Petrole | Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape de cokefaction. |
| GB2478332A (en) | 2010-03-04 | 2011-09-07 | Grimley Smith Associates | Method of metals recovery from refinery residues |
| WO2011152426A1 (ja) * | 2010-05-31 | 2011-12-08 | Ｊｘ日鉱日石エネルギー株式会社 | リチウムイオン二次電池負極材料用原料炭組成物 |
| CN102899079B (zh) * | 2011-07-27 | 2014-09-10 | 中国石油化工股份有限公司 | 一种延迟焦化方法 |
| CN102435605A (zh) * | 2011-09-19 | 2012-05-02 | 中国石油天然气股份有限公司 | 一种优选延迟焦化加热炉出口温度的方法 |
| CN103805226B (zh) * | 2012-11-02 | 2016-05-11 | 中国石油化工集团公司 | 一种延迟焦化方法 |
| JP6198640B2 (ja) * | 2014-03-04 | 2017-09-20 | 株式会社神戸製鋼所 | 石油コークス吹込み高炉操業方法 |
| US10053630B2 (en) | 2014-05-14 | 2018-08-21 | Exxonmobil Research And Engineering Company | Control of coke morphology in delayed coking |
| US10591456B2 (en) | 2016-03-30 | 2020-03-17 | Exxonmobil Research And Engineering Company | In situ monitoring of coke morphology in a delayed coker using AC impedance |
| ZA202000573B (en) | 2019-04-09 | 2021-07-28 | Indian Oil Corp Ltd | Process for production of anisotropic coke |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB844698A (en) * | 1956-12-13 | 1960-08-17 | British Petroleum Co | Improvements relating to the production of petroleum coke |
| US3702816A (en) * | 1970-06-29 | 1972-11-14 | Exxon Research Engineering Co | Low sulfur coke from virgin residua |
| US3960704A (en) * | 1974-08-27 | 1976-06-01 | Continental Oil Company | Manufacture of isotropic delayed petroleum coke |
| US5258115A (en) * | 1991-10-21 | 1993-11-02 | Mobil Oil Corporation | Delayed coking with refinery caustic |
-
2002
- 2002-11-12 US US10/293,373 patent/US20030102250A1/en not_active Abandoned
- 2002-12-02 AR ARP020104644A patent/AR037685A1/es not_active Application Discontinuation
- 2002-12-03 EP EP02794141A patent/EP1451266A1/en not_active Ceased
- 2002-12-03 CN CNA028240057A patent/CN1599784A/zh active Pending
- 2002-12-03 WO PCT/US2002/038699 patent/WO2003048271A1/en active Application Filing
- 2002-12-03 AU AU2002359593A patent/AU2002359593A1/en not_active Abandoned
- 2002-12-03 JP JP2003549451A patent/JP2006500431A/ja not_active Withdrawn
- 2002-12-03 CA CA002468711A patent/CA2468711A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US20030102250A1 (en) | 2003-06-05 |
| JP2006500431A (ja) | 2006-01-05 |
| EP1451266A1 (en) | 2004-09-01 |
| AR037685A1 (es) | 2004-12-01 |
| CN1599784A (zh) | 2005-03-23 |
| WO2003048271A1 (en) | 2003-06-12 |
| CA2468711A1 (en) | 2003-06-12 |
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| US7658838B2 (en) | Delayed coking process for producing free-flowing coke using polymeric additives | |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK1 | Application lapsed section 142(2)(a) - no request for examination in relevant period | ||
| TH | Corrigenda |
Free format text: IN VOL 20, NO 18, PAGE(S) 1742 UNDER THE HEADING APPLICATIONS LAPSED, REFUSED OR WITHDRAWN, PATENTSCEASED OR EXPIRED - 2002 DELETE ALL REFERENCE TO 2002359593 |
|
| MK3 | Application lapsed section 142(2)(c) - examination deferred under section 46 no request for examination |