ATE9875T1 - Verfahren und vorrichtung zur abscheidung gasfoermiger komponenten durch selektive adsorption. - Google Patents

Verfahren und vorrichtung zur abscheidung gasfoermiger komponenten durch selektive adsorption.

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Publication number
ATE9875T1
ATE9875T1 AT80200699T AT80200699T ATE9875T1 AT E9875 T1 ATE9875 T1 AT E9875T1 AT 80200699 T AT80200699 T AT 80200699T AT 80200699 T AT80200699 T AT 80200699T AT E9875 T1 ATE9875 T1 AT E9875T1
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AT
Austria
Prior art keywords
outlet
separation
inlet
gaseous components
selective adsorption
Prior art date
Application number
AT80200699T
Other languages
English (en)
Inventor
Abraham Johan Esselink
Original Assignee
Ingenieursbureau Essex B.V.
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Filing date
Publication date
Application filed by Ingenieursbureau Essex B.V. filed Critical Ingenieursbureau Essex B.V.
Application granted granted Critical
Publication of ATE9875T1 publication Critical patent/ATE9875T1/de

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047Pressure swing adsorption
    • B01D53/053Pressure swing adsorption with storage or buffer vessel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047Pressure swing adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30Physical properties of adsorbents
    • B01D2253/302Dimensions
    • B01D2253/304Linear dimensions, e.g. particle shape, diameter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/10Nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/16Hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/20Carbon monoxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/502Carbon monoxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702Hydrocarbons
    • B01D2257/7022Aliphatic hydrocarbons
    • B01D2257/7025Methane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/80Water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40003Methods relating to valve switching
    • B01D2259/40005Methods relating to valve switching using rotary valves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40011Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40013Pressurization
    • B01D2259/40015Pressurization with two sub-steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40011Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40013Pressurization
    • B01D2259/40016Pressurization with three sub-steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40011Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40028Depressurization
    • B01D2259/4003Depressurization with two sub-steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40011Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40028Depressurization
    • B01D2259/40032Depressurization with three sub-steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40011Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40028Depressurization
    • B01D2259/40033Depressurization with more than three sub-steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40011Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40043Purging
    • B01D2259/4005Nature of purge gas
    • B01D2259/40052Recycled product or process gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40011Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40058Number of sequence steps, including sub-steps, per cycle
    • B01D2259/40066Six
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40011Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40058Number of sequence steps, including sub-steps, per cycle
    • B01D2259/40069Eight
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40011Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40058Number of sequence steps, including sub-steps, per cycle
    • B01D2259/40071Nine
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/402Further details for adsorption processes and devices using two beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/403Further details for adsorption processes and devices using three beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/404Further details for adsorption processes and devices using four beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/406Further details for adsorption processes and devices using more than four beds
    • B01D2259/4061Further details for adsorption processes and devices using more than four beds using five beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/406Further details for adsorption processes and devices using more than four beds
    • B01D2259/4063Further details for adsorption processes and devices using more than four beds using seven beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/406Further details for adsorption processes and devices using more than four beds
    • B01D2259/4065Further details for adsorption processes and devices using more than four beds using eight beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/414Further details for adsorption processes and devices using different types of adsorbents
    • B01D2259/4141Further details for adsorption processes and devices using different types of adsorbents within a single bed
    • B01D2259/4145Further details for adsorption processes and devices using different types of adsorbents within a single bed arranged in series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0407Constructional details of adsorbing systems
    • B01D53/0446Means for feeding or distributing gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/20Capture or disposal of greenhouse gases of methane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
AT80200699T 1979-07-17 1980-07-17 Verfahren und vorrichtung zur abscheidung gasfoermiger komponenten durch selektive adsorption. ATE9875T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL7905561A NL7905561A (nl) 1979-07-17 1979-07-17 Werkwijze en inrichting voor het scheiden van gasvor- mige componenten door selectieve adsorptie.
EP80200699A EP0022603B1 (de) 1979-07-17 1980-07-17 Verfahren und Vorrichtung zur Abscheidung gasförmiger Komponenten durch selektive Adsorption

Publications (1)

Publication Number Publication Date
ATE9875T1 true ATE9875T1 (de) 1984-11-15

Family

ID=19833556

Family Applications (1)

Application Number Title Priority Date Filing Date
AT80200699T ATE9875T1 (de) 1979-07-17 1980-07-17 Verfahren und vorrichtung zur abscheidung gasfoermiger komponenten durch selektive adsorption.

Country Status (6)

Country Link
US (1) US4350500A (de)
EP (1) EP0022603B1 (de)
JP (1) JPS5638121A (de)
AT (1) ATE9875T1 (de)
DE (1) DE3069454D1 (de)
NL (1) NL7905561A (de)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES8300304A1 (es) * 1980-12-09 1982-11-01 Linde Ag Procedimiento de absorcion para descomponer por lo menos dos corrientes de gas crudo .
DE3122701A1 (de) * 1981-06-06 1982-12-23 Bergwerksverband Gmbh, 4300 Essen Verfahren zur trennung von gasgemischen mittels druckwechseltechnik
US4461630A (en) * 1982-09-30 1984-07-24 Union Carbide Corporation Product recovery in pressure swing adsorption process and system
AU567567B2 (en) * 1982-09-30 1987-11-26 Union Carbide Corporation Modified purge cycle in pressure swing adsorption process
US4468237A (en) * 1982-10-19 1984-08-28 Union Carbide Corporation Pressure swing adsorption with direct and indirect pressure equalizations
FR2534827A1 (fr) * 1982-10-22 1984-04-27 Air Liquide Procede de traitement de gaz par adsorption comportant plusieurs adsorbeurs en phase de production simultanee
US4482361A (en) * 1983-01-14 1984-11-13 Union Carbide Corporation Pressure swing adsorption process
JPS60155501A (ja) * 1984-01-23 1985-08-15 Toyo Eng Corp アンモニア合成ガスの精製法
EP0157480B1 (de) * 1984-03-02 1989-07-26 Imperial Chemical Industries Plc Verfahren zur Herstellung von Ammoniaksynthesegas
US4689062A (en) * 1986-02-24 1987-08-25 The Boc Group, Inc. Argon recovery from ammonia plant purge gas utilizing a combination of cryogenic and non-cryogenic separating means
ZA871189B (en) * 1986-02-24 1987-11-25 Boc Group Inc Psa multicomponent separation tank equalization
US4687498A (en) * 1986-02-24 1987-08-18 The Boc Group, Inc. Argon recovery from hydrogen depleted ammonia plant purge gas utilizing a combination of cryogenic and non-cryogenic separating means
FR2599274B1 (fr) * 1986-06-02 1988-08-26 Air Liquide Procede et installation de separation d'un melange gazeux par adsorption.
JPH0430762Y2 (de) * 1987-02-23 1992-07-24
JP2981302B2 (ja) * 1991-05-13 1999-11-22 東洋エンジニアリング株式会社 ガスの分離方法
JP2981304B2 (ja) * 1991-05-13 1999-11-22 東洋エンジニアリング株式会社 ガス分離方法
US5565018A (en) * 1995-07-12 1996-10-15 Praxair Technology, Inc. Optimal pressure swing adsorption refluxing
US6007606A (en) * 1997-12-09 1999-12-28 Praxair Technology, Inc. PSA process and system
US6096115A (en) * 1998-11-25 2000-08-01 Air Products And Chemicals, Inc. Pressure swing adsorption process and system utilizing two product storage tanks
US6102985A (en) * 1998-11-25 2000-08-15 Air Products And Chemicals, Inc. Pressure swing adsorption process and system with dual product storage tanks
FR2796307B1 (fr) * 1999-07-16 2001-09-14 Air Liquide Unite d'adsorption a modulation de pression
NL1013314C2 (nl) * 1999-10-16 2001-04-18 Esselink B V Drukwisseladsorptiewerkwijze.
FR2835932B1 (fr) * 2002-02-13 2004-03-19 Air Liquide Procede de commande d'une installation de traitement d'un gaz par adsorption et installation de traitement correspondante
US7390350B2 (en) * 2005-04-26 2008-06-24 Air Products And Chemicals, Inc. Design and operation methods for pressure swing adsorption systems
FR3002160B1 (fr) * 2013-02-19 2017-02-24 Air Liquide Procede d'adsorption a pression alternee avec reservoirs de stockage combines
BE1023062A1 (nl) * 2015-05-13 2016-11-16 Atlas Copco Airpower Nv Inrichting voor het drogen van een samengeperst gas en compressorinstallatie voorzien van dergelijke inrichting.
US11007472B2 (en) 2018-09-28 2021-05-18 Uop Llc Adsorption vessels having reduced void volume through the use of non-porous, low-density filler material to reduce voids

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3103425A (en) * 1963-09-10 Adsorption apparatus and method
US3123453A (en) * 1964-03-03 Method and apparatus for processing a natural gas stream
NL286634A (de) * 1961-12-18 1900-01-01
NL297067A (de) * 1962-09-04 1900-01-01
CH417534A (de) * 1964-07-01 1966-07-31 Exxon Research Engineering Co Adsorptionsverfahren
US3564816A (en) * 1968-12-30 1971-02-23 Union Carbide Corp Selective adsorption process
US3788036A (en) * 1972-07-26 1974-01-29 D Stahl Pressure equalization and purging system for heatless adsorption systems
US3977845A (en) * 1975-06-20 1976-08-31 William Clarence Walter Adsorptive process for selective separation of gases
US3986849A (en) * 1975-11-07 1976-10-19 Union Carbide Corporation Selective adsorption process
DE2624346A1 (de) * 1976-05-31 1977-12-15 Linde Ag Verfahren zur zerlegung von gasen durch adsorption
FR2363362A1 (fr) * 1976-09-07 1978-03-31 Air Liquide Procede de traitement, par adsorption, d'un melange gazeux
US4077779A (en) * 1976-10-15 1978-03-07 Air Products And Chemicals, Inc. Hydrogen purification by selective adsorption
US4194890A (en) * 1976-11-26 1980-03-25 Greene & Kellogg, Inc. Pressure swing adsorption process and system for gas separation
DE2823211A1 (de) * 1978-05-27 1979-12-06 Bayer Antwerpen Nv Verfahren zum betrieb einer druck- wechsel-adsorptionsanlage

Also Published As

Publication number Publication date
JPS6247051B2 (de) 1987-10-06
US4350500A (en) 1982-09-21
DE3069454D1 (en) 1984-11-22
NL7905561A (nl) 1981-01-20
JPS5638121A (en) 1981-04-13
EP0022603B1 (de) 1984-10-17
EP0022603A1 (de) 1981-01-21

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