ATE289585T1 - Verfahren zur hydrocyanierung von organischen ethylenisch ungesättigten verbindungen - Google Patents

Verfahren zur hydrocyanierung von organischen ethylenisch ungesättigten verbindungen

Info

Publication number
ATE289585T1
ATE289585T1 AT99959509T AT99959509T ATE289585T1 AT E289585 T1 ATE289585 T1 AT E289585T1 AT 99959509 T AT99959509 T AT 99959509T AT 99959509 T AT99959509 T AT 99959509T AT E289585 T1 ATE289585 T1 AT E289585T1
Authority
AT
Austria
Prior art keywords
phase
hydrocyanation
solid phase
organic
aqueous phase
Prior art date
Application number
AT99959509T
Other languages
English (en)
Inventor
Paolo Burattin
Pierre Coqueret
Marc Huser
Original Assignee
Rhodia Polyamide Intermediates
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Polyamide Intermediates filed Critical Rhodia Polyamide Intermediates
Application granted granted Critical
Publication of ATE289585T1 publication Critical patent/ATE289585T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
    • B01J2231/342—Aldol type reactions, i.e. nucleophilic addition of C-H acidic compounds, their R3Si- or metal complex analogues, to aldehydes or ketones
    • B01J2231/343—Aldol type reactions, i.e. nucleophilic addition of C-H acidic compounds, their R3Si- or metal complex analogues, to aldehydes or ketones to prepare cyanhydrines, e.g. by adding HCN or TMSCN
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT99959509T 1998-12-22 1999-12-21 Verfahren zur hydrocyanierung von organischen ethylenisch ungesättigten verbindungen ATE289585T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9816468A FR2787446B1 (fr) 1998-12-22 1998-12-22 Procede d'hydrocyanation de composes organiques a insaturations ethyleniques
PCT/FR1999/003231 WO2000037431A1 (fr) 1998-12-22 1999-12-21 Procede d'hydrocyanation de composes organiques a insaturations ethyleniques

Publications (1)

Publication Number Publication Date
ATE289585T1 true ATE289585T1 (de) 2005-03-15

Family

ID=9534529

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99959509T ATE289585T1 (de) 1998-12-22 1999-12-21 Verfahren zur hydrocyanierung von organischen ethylenisch ungesättigten verbindungen

Country Status (17)

Country Link
US (1) US6469194B2 (de)
EP (1) EP1140801B1 (de)
JP (1) JP4060532B2 (de)
KR (1) KR20010089687A (de)
CN (1) CN1173935C (de)
AT (1) ATE289585T1 (de)
BR (1) BR9916437A (de)
CA (1) CA2356381A1 (de)
CZ (1) CZ20012249A3 (de)
DE (1) DE69923867D1 (de)
FR (1) FR2787446B1 (de)
MX (1) MXPA01006383A (de)
PL (1) PL348298A1 (de)
SK (1) SK9102001A3 (de)
TW (1) TW453985B (de)
WO (1) WO2000037431A1 (de)
ZA (1) ZA200105887B (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2819250B1 (fr) * 2001-01-05 2004-12-03 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
FR2829763B1 (fr) 2001-09-18 2004-12-03 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles
MY134370A (en) * 2002-07-10 2007-12-31 Basf Ag Recycling of a lewis acid
FR2842196B1 (fr) * 2002-07-15 2006-01-13 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
FR2849027B1 (fr) * 2002-12-23 2005-01-21 Rhodia Polyamide Intermediates Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
EP1948591A1 (de) 2005-10-18 2008-07-30 INVISTA Technologies S.à.r.l. Verfahren zur herstellung von 3-aminopentannitril
US7629484B2 (en) 2006-03-17 2009-12-08 Invista North America S.A.R.L. Method for the purification of triorganophosphites by treatment with a basic additive
US7880028B2 (en) 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
WO2009075692A2 (en) 2007-05-14 2009-06-18 Invista Technologies S.A.R.L. High efficiency reactor and process
WO2008157218A1 (en) 2007-06-13 2008-12-24 Invista Technologies S.A.R.L. Process for improving adiponitrile quality
US7977502B2 (en) 2008-01-15 2011-07-12 Invista North America S.A R.L. Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
CN101918356B (zh) 2008-01-15 2013-09-25 因温斯特技术公司 戊烯腈的氢氰化
FR2932476B1 (fr) * 2008-06-17 2010-07-30 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
US8247621B2 (en) 2008-10-14 2012-08-21 Invista North America S.A.R.L. Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols
KR20120047251A (ko) 2009-08-07 2012-05-11 인비스타 테크놀러지스 에스.에이.알.엘. 디에스테르를 형성하기 위한 수소화 및 에스테르화
JP2015512862A (ja) 2011-12-21 2015-04-30 インヴィスタ テクノロジーズ エスアエルエル 安定なエマルジョンを減じるための抽出溶媒制御
US9133226B2 (en) 2011-12-21 2015-09-15 Invista North America S.A.R.L. Extraction solvent control for reducing stable emulsions
EP2794048B1 (de) 2011-12-21 2022-01-05 INVISTA Textiles (U.K.) Limited Regelung des extraktionslösungsmittels zur verminderung stabiler emulsionen
CN103804227B (zh) * 2014-02-17 2016-02-10 重庆中平紫光科技发展有限公司 一种烯腈混合液直接异构化合成2-甲基-2-丁烯腈的方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1621910A1 (de) 1967-09-06 1971-06-24 Bayer Ag Verfahren zum Beschichten mit Polyurethanen
FR2338253A1 (fr) 1976-01-13 1977-08-12 Rhone Poulenc Ind Procede d'hydrocyanation de composes organiques insatures comportant au moins une double liaison ethylenique
US4082811A (en) * 1977-02-23 1978-04-04 E. I. Du Pont De Nemours And Company Recovery of metal and triarylborane catalyst components from olefin hydrocyanation residue
US4539302A (en) * 1984-04-30 1985-09-03 E. I. Du Pont De Nemours And Company Recovery of zerovalent nickel complexes
US4990645A (en) * 1990-06-27 1991-02-05 E. I. Du Pont De Nemours And Company Hydrocyanation process
FR2711987B1 (fr) * 1993-11-03 1995-12-15 Rhone Poulenc Chimie Procédé d'hydrocyanation de nitriles insaturés en dinitriles.
FR2727637B1 (fr) 1994-12-06 1997-01-03 Rhone Poulenc Chimie Procede de preparation electrochimique de catalyseurs a base de metal de transition et de phosphine
FR2739378B1 (fr) 1995-09-29 1997-10-31 Rhone Poulenc Fibres Procede d'hydrocyanation de composes organiques a insaturation ethylenique
FR2743011B1 (fr) 1995-12-29 1998-02-20 Rhone Poulenc Fibres Procede de preparation electrochimique de catalyseurs a base de metal de transition et de phosphine

Also Published As

Publication number Publication date
EP1140801B1 (de) 2005-02-23
CZ20012249A3 (cs) 2001-11-14
KR20010089687A (ko) 2001-10-08
CN1173935C (zh) 2004-11-03
SK9102001A3 (en) 2001-12-03
US20020022736A1 (en) 2002-02-21
ZA200105887B (en) 2002-10-17
JP2002533321A (ja) 2002-10-08
WO2000037431A1 (fr) 2000-06-29
TW453985B (en) 2001-09-11
CA2356381A1 (fr) 2000-06-29
EP1140801A1 (de) 2001-10-10
FR2787446B1 (fr) 2001-02-02
MXPA01006383A (es) 2002-06-04
BR9916437A (pt) 2001-09-04
US6469194B2 (en) 2002-10-22
PL348298A1 (en) 2002-05-20
CN1333745A (zh) 2002-01-30
DE69923867D1 (de) 2005-03-31
FR2787446A1 (fr) 2000-06-23
JP4060532B2 (ja) 2008-03-12

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