ATE265406T1 - Verzweigte alkyl-aromatische sulfonsäure- dispersionsmittel zur lösung von asphaltenen in mineralölen - Google Patents

Verzweigte alkyl-aromatische sulfonsäure- dispersionsmittel zur lösung von asphaltenen in mineralölen

Info

Publication number
ATE265406T1
ATE265406T1 AT99962842T AT99962842T ATE265406T1 AT E265406 T1 ATE265406 T1 AT E265406T1 AT 99962842 T AT99962842 T AT 99962842T AT 99962842 T AT99962842 T AT 99962842T AT E265406 T1 ATE265406 T1 AT E265406T1
Authority
AT
Austria
Prior art keywords
sulfonic acid
branched alkyl
asphaltenes
solving
mineral oils
Prior art date
Application number
AT99962842T
Other languages
English (en)
Inventor
Irwin Andrew Wiehe
Ramesh Varadaraj
Torris G Jermansen
Raymond John Kennedy
Cornelius Hendrick Brons
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Application granted granted Critical
Publication of ATE265406T1 publication Critical patent/ATE265406T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/29—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings
    • C07C309/30—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings of six-membered aromatic rings substituted by alkyl groups
    • C07C309/31—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings of six-membered aromatic rings substituted by alkyl groups by alkyl groups containing at least three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/33—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of six-membered aromatic rings being part of condensed ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/33—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of six-membered aromatic rings being part of condensed ring systems
    • C07C309/34—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of six-membered aromatic rings being part of condensed ring systems formed by two rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/33—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of six-membered aromatic rings being part of condensed ring systems
    • C07C309/34—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of six-membered aromatic rings being part of condensed ring systems formed by two rings
    • C07C309/35—Naphthalene sulfonic acids
    • C07C309/36—Naphthalene sulfonic acids substituted by alkyl groups
    • C07C309/37—Naphthalene sulfonic acids substituted by alkyl groups by alkyl groups containing at least three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
    • C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2462—Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds
    • C10L1/2475—Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon to carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/10—One of the condensed rings being a six-membered aromatic ring the other ring being six-membered, e.g. tetraline
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/02—Ortho- or ortho- and peri-condensed systems
    • C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
    • C07C2603/22—Ortho- or ortho- and peri-condensed systems containing three rings containing only six-membered rings
    • C07C2603/26—Phenanthrenes; Hydrogenated phenanthrenes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/905—Agent composition per se for colloid system making or stabilizing, e.g. foaming, emulsifying, dispersing, or gelling
    • Y10S516/909—The agent contains organic compound containing sulfoxy*

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Lubricants (AREA)
  • Working-Up Tar And Pitch (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
AT99962842T 1998-12-01 1999-11-23 Verzweigte alkyl-aromatische sulfonsäure- dispersionsmittel zur lösung von asphaltenen in mineralölen ATE265406T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/203,141 US6048904A (en) 1998-12-01 1998-12-01 Branched alkyl-aromatic sulfonic acid dispersants for solublizing asphaltenes in petroleum oils
PCT/US1999/027772 WO2000032546A1 (en) 1998-12-01 1999-11-23 Branched alkyl-aromatic sulfonic acid dispersants for solubilizing asphaltenes in petroleum oils

Publications (1)

Publication Number Publication Date
ATE265406T1 true ATE265406T1 (de) 2004-05-15

Family

ID=22752686

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99962842T ATE265406T1 (de) 1998-12-01 1999-11-23 Verzweigte alkyl-aromatische sulfonsäure- dispersionsmittel zur lösung von asphaltenen in mineralölen

Country Status (9)

Country Link
US (1) US6048904A (de)
EP (1) EP1135354B1 (de)
JP (1) JP2002531591A (de)
AT (1) ATE265406T1 (de)
AU (1) AU756901B2 (de)
CA (1) CA2355196C (de)
DE (1) DE69916884T2 (de)
ES (1) ES2220134T3 (de)
WO (1) WO2000032546A1 (de)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
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DE50103554D1 (de) 2000-06-15 2004-10-14 Clariant Internat Ltd Muttenz Additive zur verbesserung von kaltfliesseigenschaften und lagerstabilität von rohölen
US6489368B2 (en) * 2001-03-09 2002-12-03 Exxonmobil Research And Engineering Company Aromatic sulfonic acid demulsifier for crude oils
US20040232051A1 (en) * 2001-03-09 2004-11-25 Ramesh Varadaraj Low viscosity hydrocarbon oils by sonic treatment
AU2002355787B2 (en) * 2001-07-31 2008-02-21 Ic16 Limited Method of controlling asphaltene precipitation in a fluid
DE10163244A1 (de) * 2001-12-21 2003-07-10 Cognis Deutschland Gmbh Verwendung von sulfierten Alkylphenolformaldehyden zur Stabilisierung von Asphaltenen in Rohöl
US7306713B2 (en) * 2003-05-16 2007-12-11 Exxonmobil Research And Engineering Company Delayed coking process for producing free-flowing coke using a substantially metals-free additive
US20050279673A1 (en) * 2003-05-16 2005-12-22 Eppig Christopher P Delayed coking process for producing free-flowing coke using an overbased metal detergent additive
US7658838B2 (en) * 2003-05-16 2010-02-09 Exxonmobil Research And Engineering Company Delayed coking process for producing free-flowing coke using polymeric additives
US7645375B2 (en) * 2003-05-16 2010-01-12 Exxonmobil Research And Engineering Company Delayed coking process for producing free-flowing coke using low molecular weight aromatic additives
MXPA06011746A (es) * 2004-05-14 2007-01-16 Exxonmobil Res & Eng Co La produccion de coque de flujo substancialmente libre de un corte mas profundo de residuo de vacio en coquificacion retrasada.
BRPI0510984A (pt) * 2004-05-14 2007-12-04 Exxonmobil Res & Eng Co método para o melhoramento das propriedades de escoamento de uma carga de alimentação de óleo pesado por diminuição do seu módulo elástico, e, método de coqueificação retardado
WO2005113706A1 (en) * 2004-05-14 2005-12-01 Exxonmobil Research And Engineering Company Production and removal of free-flowing coke from delayed coker drum
JP2007537345A (ja) * 2004-05-14 2007-12-20 エクソンモービル　リサーチ　アンド　エンジニアリング　カンパニー 油溶性多核芳香族化合物を用いたメソフェーズ抑制を介する、抑制剤により改善された熱による重油の品質向上
BRPI0511024A (pt) * 2004-05-14 2007-11-27 Exxonmobil Res & Eng Co processo de coqueificação retardada, e, coque
US7901564B2 (en) * 2006-08-21 2011-03-08 Exxonmobil Research & Engineering Company Mitigation of refinery process unit fouling using high-solvency-dispersive-power (HSDP) resid fractions
US7837855B2 (en) * 2006-08-21 2010-11-23 Exxonmobil Research & Engineering Company High-solvency-dispersive-power (HSDP) crude oil blending for fouling mitigation and on-line cleaning
US7833407B2 (en) * 2006-08-21 2010-11-16 Exxonmobil Research & Engineering Company Method of blending high TAN and high SBN crude oils and method of reducing particulate induced whole crude oil fouling and asphaltene induced whole crude oil fouling
US20080047874A1 (en) * 2006-08-23 2008-02-28 Exxonmobil Research And Engineering Company Crude oil blending to reduce organic-based fouling of pre-heat train exchangers and furnaces
CO5930079A1 (es) * 2006-12-06 2008-06-27 Ecopetrol Sa Aditivos anti-gomas, antiensuciante y dispersantes de asfalto y procedimiento para su obtencion
US8062504B2 (en) * 2007-08-06 2011-11-22 Exxonmobil Research & Engineering Company Method for reducing oil fouling in heat transfer equipment
US8440069B2 (en) * 2007-08-06 2013-05-14 Exxonmobil Research And Engineering Company Methods of isolating and using components from a high solvency dispersive power (HSDP) crude oil
US7871510B2 (en) * 2007-08-28 2011-01-18 Exxonmobil Research & Engineering Co. Production of an enhanced resid coker feed using ultrafiltration
US7794587B2 (en) * 2008-01-22 2010-09-14 Exxonmobil Research And Engineering Company Method to alter coke morphology using metal salts of aromatic sulfonic acids and/or polysulfonic acids
US8425761B2 (en) * 2008-12-11 2013-04-23 Exxonmobil Research And Engineering Company Non-high solvency dispersive power (non-HSDP) crude oil with increased fouling mitigation and on-line cleaning effects
US9255043B2 (en) * 2011-08-31 2016-02-09 Chevron Oronite Company Llc Liquid crude hydrocarbon composition
US9120978B2 (en) 2012-02-24 2015-09-01 Baker Hughes Incorporated Exfoliation of asphaltenes for improved recovery of unconventional oils
US9017546B2 (en) 2012-06-19 2015-04-28 Baker Hughes Incorporated Exfoliation of asphaltenes
US9683163B2 (en) 2012-12-31 2017-06-20 Baker Hughes Incorporated Functionalized silicate nanoparticle composition, removing and exfoliating asphaltenes with same
US9012377B2 (en) * 2012-12-31 2015-04-21 Baker Hughes Incorporated Functionalized silicate nanoparticle composition, removing and exfoliating asphaltenes with same
EP2940104B1 (de) 2014-03-31 2022-01-05 INDIAN OIL CORPORATION Ltd. Flüssigphasenadditiv zur verwendung in thermischen crackverfahren zur verbesserung der produktausbeute
MX368309B (es) 2014-12-11 2019-09-26 Mexicano Inst Petrol Liquidos zwitterionicos geminales base hidroxipropil betaina, proceso de obtencion y uso como modificadores de la mojabilidad con propiedades inhibitorias/dispersantes de asfaltenos.
CA2982344A1 (en) * 2015-03-17 2016-09-22 Baker Hughes, A Ge Company, Llc Functionalized silicate nanoparticle composition, removing and exfoliating asphaltenes with same
EP3795661B1 (de) 2019-09-17 2022-03-09 Infineum International Limited Asphaltensolvatisierungs- und -dispersionsverfahren
CN117285708B (zh) * 2023-11-24 2024-01-30 西南石油大学 沥青质分散稳定剂及其制备方法

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US3234297A (en) * 1966-02-08 Alkyl aryl sulfonate detergents
BE529128A (de) * 1953-05-29
US4182613A (en) * 1976-11-24 1980-01-08 Exxon Research & Engineering Co. Compatibility additive for fuel oil blends
US4414035A (en) * 1979-05-21 1983-11-08 Petrolite Corporation Method for the removal of asphaltenic deposits
DE3368606D1 (en) * 1982-12-13 1987-02-05 Shell Int Research Alkylxylene sulphonate compounds, their preparation and use
FR2651228B1 (fr) * 1989-08-25 1992-06-12 Sandoz Sa Composes aromatiques contenant des groupes sulfo, leur preparation et leur utilisation.
DE4018873A1 (de) * 1990-06-13 1991-12-19 Basf Ag Verwendung von kondensaten auf basis von arylsulfonsaeuren und formaldehyd als dispergiermittel
EP0505582B1 (de) * 1990-10-12 1996-07-31 Konishi Chemical Ind. Co., Ltd. Sulfonierunsreagenz und -verfahren
US5202056A (en) * 1991-12-30 1993-04-13 Texaco Inc. Composition of matter for oligomeric aliphatic ethers as asphaltene dispersants

Also Published As

Publication number Publication date
CA2355196A1 (en) 2000-06-08
EP1135354B1 (de) 2004-04-28
DE69916884D1 (de) 2004-06-03
WO2000032546A1 (en) 2000-06-08
AU1919600A (en) 2000-06-19
DE69916884T2 (de) 2005-04-07
US6048904A (en) 2000-04-11
EP1135354A4 (de) 2002-02-06
AU756901B2 (en) 2003-01-23
JP2002531591A (ja) 2002-09-24
EP1135354A1 (de) 2001-09-26
CA2355196C (en) 2008-12-23
ES2220134T3 (es) 2004-12-01

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