ATE211478T1 - Nichtaromatische anionische dienylgruppe enthaltende metall (iii) komplexe und diese enthaltende additionspolymerizationskatalysatoren - Google Patents

Nichtaromatische anionische dienylgruppe enthaltende metall (iii) komplexe und diese enthaltende additionspolymerizationskatalysatoren

Info

Publication number
ATE211478T1
ATE211478T1 AT95925522T AT95925522T ATE211478T1 AT E211478 T1 ATE211478 T1 AT E211478T1 AT 95925522 T AT95925522 T AT 95925522T AT 95925522 T AT95925522 T AT 95925522T AT E211478 T1 ATE211478 T1 AT E211478T1
Authority
AT
Austria
Prior art keywords
complexes
iii
addition polymerization
polymerization catalysts
dienyl group
Prior art date
Application number
AT95925522T
Other languages
English (en)
Inventor
David R Wilson
David R Neithamer
Peter N Nickias
W Jack Kruper Jr
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ATE211478T1 publication Critical patent/ATE211478T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Polymerization Catalysts (AREA)
AT95925522T 1994-09-12 1995-07-06 Nichtaromatische anionische dienylgruppe enthaltende metall (iii) komplexe und diese enthaltende additionspolymerizationskatalysatoren ATE211478T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/304,315 US5495036A (en) 1994-09-12 1994-09-12 Metal (III) complexes containing conjugated, non-aromatic anionic II-bound groups and addition polymerization catalysts therefrom
PCT/US1995/008466 WO1996008497A1 (en) 1994-09-12 1995-07-06 Metal (iii) complexes containing, non-aromatic, anionic, dienyl groups and addition polymerization catalysts therefrom

Publications (1)

Publication Number Publication Date
ATE211478T1 true ATE211478T1 (de) 2002-01-15

Family

ID=23175993

Family Applications (1)

Application Number Title Priority Date Filing Date
AT95925522T ATE211478T1 (de) 1994-09-12 1995-07-06 Nichtaromatische anionische dienylgruppe enthaltende metall (iii) komplexe und diese enthaltende additionspolymerizationskatalysatoren

Country Status (7)

Country Link
US (1) US5495036A (de)
EP (1) EP0781287B1 (de)
JP (1) JPH10505609A (de)
AT (1) ATE211478T1 (de)
CA (1) CA2196896A1 (de)
DE (1) DE69524879T2 (de)
WO (1) WO1996008497A1 (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5631202A (en) 1993-09-24 1997-05-20 Montell Technology Company B.V. Stereospecific metallocene catalysts with stereolocking α-CP substituents
US6419881B1 (en) 1994-10-18 2002-07-16 Symyx Technologies, Inc. Combinatorial arrays of organometallic compounds and catalysts
US6030917A (en) 1996-07-23 2000-02-29 Symyx Technologies, Inc. Combinatorial synthesis and analysis of organometallic compounds and catalysts
US6440745B1 (en) 1994-10-18 2002-08-27 Symyx Technologies Combinatorial synthesis and screening of organometallic compounds and catalysts
WO1996016094A1 (en) * 1994-11-23 1996-05-30 The Dow Chemical Company Preparation of syndiotactic polyolefins from prochiral olefins
DE19522013A1 (de) * 1995-06-21 1997-01-02 Hoechst Ag Übergangsmetallverbindung
US6403772B1 (en) * 1995-09-11 2002-06-11 Montell Technology Company, Bv Open-pentadienyl metallocenes, precursors thereof and polymerization catalysts therefrom
KR20000067941A (ko) * 1996-07-22 2000-11-25 그래햄 이. 테일러 가교결합된 비방향족 음이온 디에닐기를 함유하는 금속 착화합물
US6015868A (en) * 1996-10-03 2000-01-18 The Dow Chemical Company Substituted indenyl containing metal complexes and olefin polymerization process
US6720186B1 (en) 1998-04-03 2004-04-13 Symyx Technologies, Inc. Method of research for creating and testing novel catalysts, reactions and polymers
US5856258A (en) * 1996-10-15 1999-01-05 Northwestern University Phenolate constrained geometry polymerization catalyst and method for preparing
US6160072A (en) * 1997-05-02 2000-12-12 Ewen; John A. Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes
DE19728126A1 (de) * 1997-07-02 1999-01-07 Bayer Ag Katalysatorsystem auf Basis von Monoazadien-Metallkomplexen
US6511936B1 (en) 1998-02-12 2003-01-28 University Of Delaware Catalyst compounds with β-diminate anionic ligands and processes for polymerizing olefins
CA2347501C (en) 1998-11-02 2010-03-23 Larry Duane Cady Shear thinning ethylene/.alpha.-olefin interpolymers and their preparation
US6239062B1 (en) 1999-09-02 2001-05-29 Equistar Chemicals, L.P. Olefin polymerization catalysts containing indolyl-amido ligands
US7078164B1 (en) 2000-06-19 2006-07-18 Symyx Technologies, Inc. High throughput screen for identifying polymerization catalysts from potential catalysts
KR101092349B1 (ko) * 2003-02-21 2011-12-09 다우 글로벌 테크놀로지스 엘엘씨 공액 올레핀의 단독중합법 또는 공중합법
EP1763542B1 (de) 2004-06-16 2011-04-06 Dow Global Technologies Inc. Verfahren zur auswahl von polymerisationsmodifikatoren

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
PL166690B1 (pl) * 1990-06-04 1995-06-30 Exxon Chemical Patents Inc Sposób wytwarzania polimerów olefin PL
US5200379A (en) * 1990-06-07 1993-04-06 Phillips Petroleum Company Olefin polymerization using supported pentadienyl derivative-transition metal complexes
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
JP3275211B2 (ja) * 1991-05-20 2002-04-15 ザ ダウ ケミカル カンパニー 付加重合触媒の製造方法
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
JP3341117B2 (ja) * 1991-10-15 2002-11-05 ザ ダウ ケミカル カンパニー 金属配位錯体の製造
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
WO1994000500A1 (en) * 1992-06-26 1994-01-06 Exxon Chemical Patents Inc. Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers

Also Published As

Publication number Publication date
JPH10505609A (ja) 1998-06-02
EP0781287A1 (de) 1997-07-02
CA2196896A1 (en) 1996-03-21
US5495036A (en) 1996-02-27
EP0781287B1 (de) 2002-01-02
DE69524879T2 (de) 2002-08-22
WO1996008497A1 (en) 1996-03-21
DE69524879D1 (de) 2002-02-07

Similar Documents

Publication Publication Date Title
ATE211478T1 (de) Nichtaromatische anionische dienylgruppe enthaltende metall (iii) komplexe und diese enthaltende additionspolymerizationskatalysatoren
ATE229026T1 (de) Verbrückte nicht-aromatische anionische dienylgruppen enthaltende metallkomplexe und darauf basierte polymerisatonskatalysatoren
DE69401509D1 (de) Titan-und zirkoniumkomplexe und diese enthaltende polymerisationskatalysatoren
BR9908887A (pt) Complexos catalìticos de metal contendo ligando tridentado para polimerização de olefina
RU92016448A (ru) Катализаторы на основе алюминия и свободного моноциклопентадиенилов для полимеризации олефинов
NZ332843A (en) Pyrrolaldimine transition metal catalyst, compositions and processes for olefin oligomerization and polymerization thereof
PT990003E (pt) Novos sistemas de catalisador para reaccoes de (co-)polimerizacao halogenetos de metalocenamida e sua utilizacao
FI971823A (fi) Katalyyttikoostumus ja olefiinin polymerointiprosessi
DE60122018D1 (de) Aktiver nichtmetallocen-präkatalysator und verfahren zur taktischen katalytischen polymerisation von alpha-olefin-monomeren
BR9809735A (pt) Catalisador e processo para a polimerização de olefinas
DK0955304T3 (da) Metallocenkomplekser med bro til (co)polymerisation af olefiner
MY112742A (en) Improved preparation of titanium (ii) or zirconium (ii) complexes
DE60205368D1 (de) Aktivierung von "single site" polymerisationskatalysatoren durch (dialkylalumino)broronsäureester
DE69925630D1 (de) Polymerisationskatalysatoren
NZ332678A (en) New compounds having an element of group 13 linked to a mono- or di-anionic tridentate ligand, their preparation process and their use as polymerization catalysts
MX9702453A (es) Proceso de polimerizacion de olefina proquiral sindiotactica.
DE59804679D1 (de) Katalysatorlösung zur polymerisation von alpha-olefinen
ATE196909T1 (de) Polymerisationskatalysatoren
DK0740671T3 (da) Metallocener med broer til brug i katalysatorsystemer til polymerisering af alkener
ES2135239T3 (es) Composiciones cataliticas que comprenden compuestos organometalicos.

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties