ATE189274T1 - METHOD FOR SELECTIVE OR PARTIAL ELECTROLYTIC METALIZING OF SURFACES OF SUBSTRATES MADE OF NON-CONDUCTIVE MATERIALS - Google Patents
METHOD FOR SELECTIVE OR PARTIAL ELECTROLYTIC METALIZING OF SURFACES OF SUBSTRATES MADE OF NON-CONDUCTIVE MATERIALSInfo
- Publication number
- ATE189274T1 ATE189274T1 AT96907505T AT96907505T ATE189274T1 AT E189274 T1 ATE189274 T1 AT E189274T1 AT 96907505 T AT96907505 T AT 96907505T AT 96907505 T AT96907505 T AT 96907505T AT E189274 T1 ATE189274 T1 AT E189274T1
- Authority
- AT
- Austria
- Prior art keywords
- treatment
- metal
- selective
- metallization
- substrates made
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/54—Electroplating of non-metallic surfaces
- C25D5/56—Electroplating of non-metallic surfaces of plastics
Abstract
The invention concerns a process for the selective or partial electrolytic metallization of surfaces of substrates made from electrically non-conducting materials which for the purpose of the coating process are secured to plastic-coated holding elements. The proposed process involves the following steps: a) preliminary treatment of the surfaces with an etching solution containing chromium (VI) oxide; followed immediately by b) treatment of the surfaces with a colloidal acidic solution of palladium-/zinc compounds, care being taken to prevent prior contact with adsorption-promoting solutions; c) treatment of the surfaces with a solution containing a soluble metal compound capable of being reduced by zinc (II) compounds, an alkali or alkaline earth metal hydroxide, and a complex forming agent for the metal in a quantity sufficient at least to prevent precipitation of metal hydroxides; d) treatment of the surfaces with an electrolytic metallization solution. By applying this process, it is possible to ensure that only the surfaces of the work piece are coated with metal, not the holding elements or, where applicable, non-conductive plastic layers applied to parts of the work pieces. In addition, the process facilitates direct electrolytic metallization even of large plastic surfaces without prior currentless metallization.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19510855A DE19510855C2 (en) | 1995-03-17 | 1995-03-17 | Process for the selective or partial electrolytic metallization of substrates made of non-conductive materials |
PCT/EP1996/001190 WO1996029452A1 (en) | 1995-03-17 | 1996-03-15 | Process for the selective or partial electrolytic metallization of surfaces of substrates made from non-conducting materials |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE189274T1 true ATE189274T1 (en) | 2000-02-15 |
Family
ID=7757663
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT96907505T ATE189274T1 (en) | 1995-03-17 | 1996-03-15 | METHOD FOR SELECTIVE OR PARTIAL ELECTROLYTIC METALIZING OF SURFACES OF SUBSTRATES MADE OF NON-CONDUCTIVE MATERIALS |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0815292B1 (en) |
JP (1) | JPH11502263A (en) |
KR (1) | KR19980703108A (en) |
AT (1) | ATE189274T1 (en) |
BR (1) | BR9607848A (en) |
CA (1) | CA2210883A1 (en) |
DE (2) | DE19510855C2 (en) |
ES (1) | ES2142572T3 (en) |
HK (1) | HK1008552A1 (en) |
WO (1) | WO1996029452A1 (en) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6541080B1 (en) | 1998-12-14 | 2003-04-01 | Enthone Inc. | Double-dip Pd/Sn crosslinker |
DE19857290C2 (en) * | 1998-12-14 | 2001-02-01 | Lpw Chemie Gmbh | Process for the direct metallization of the surface of a plastic object |
DE10208674B4 (en) * | 2002-02-28 | 2011-07-07 | BIA Kunststoff- und Galvanotechnik GmbH & Co. KG, 42655 | Process for the production of electroplated elements with backlightable symbols and elements produced by the process |
DE10223081A1 (en) * | 2002-05-17 | 2003-12-04 | Hansgrohe Ag | Process for the production of galvanized plastic sanitary ware |
KR100913265B1 (en) * | 2002-07-30 | 2009-08-21 | 엘지전자 주식회사 | Power supply port |
DE102005026633A1 (en) | 2005-06-03 | 2006-12-28 | Hansgrohe Ag | Process for the production of galvanized plastic sanitary articles |
DE102005031454A1 (en) * | 2005-07-04 | 2007-01-11 | Huf Hülsbeck & Fürst Gmbh & Co. Kg | Door handle, door handle housing and method of making the door handle housing |
DE102005051632B4 (en) * | 2005-10-28 | 2009-02-19 | Enthone Inc., West Haven | Process for pickling non-conductive substrate surfaces and for metallizing plastic surfaces |
DE102006042269B4 (en) * | 2006-09-08 | 2014-08-28 | Automobile Patentverwaltungs- und -verwertungsgesellschaft mbH | Process for galvanic coating of carrier parts made of plastics |
EP1988192B1 (en) * | 2007-05-03 | 2012-12-05 | Atotech Deutschland GmbH | Process for applying a metal coating to a non-conductive substrate |
EP2305856A1 (en) | 2009-09-28 | 2011-04-06 | ATOTECH Deutschland GmbH | Process for applying a metal coating to a non-conductive substrate |
EP2602357A1 (en) | 2011-12-05 | 2013-06-12 | Atotech Deutschland GmbH | Novel adhesion promoting agents for metallization of substrate surfaces |
EP2639332A1 (en) | 2012-03-15 | 2013-09-18 | Atotech Deutschland GmbH | Method for metallising non-conductive plastic surfaces |
EP2639333A1 (en) | 2012-03-15 | 2013-09-18 | Atotech Deutschland GmbH | Method for metallising non-conductive plastic surfaces |
EP2644744A1 (en) | 2012-03-29 | 2013-10-02 | Atotech Deutschland GmbH | Method for promoting adhesion between dielectric substrates and metal layers |
WO2014098064A1 (en) | 2012-12-21 | 2014-06-26 | 奥野製薬工業株式会社 | Conductive coating film forming bath |
CN114107984A (en) | 2013-09-26 | 2022-03-01 | 德国艾托特克公司 | Novel adhesion promotion method for substrate surface metallization |
JP6024044B2 (en) | 2014-01-27 | 2016-11-09 | 奥野製薬工業株式会社 | Conductive film forming bath |
ES2727075T5 (en) | 2015-02-23 | 2022-05-27 | Macdermid Enthone Inc | Inhibiting composition for frames when chrome-free mordants are used in a galvanizing process on plastic materials |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5376248A (en) * | 1991-10-15 | 1994-12-27 | Enthone-Omi, Inc. | Direct metallization process |
DE4206680C1 (en) * | 1992-02-28 | 1994-01-27 | Schering Ag | Process for the metallization of non-conductive surfaces and the use of hydroxymethanesulfinic acid in the process |
EP0616053B9 (en) * | 1993-03-18 | 2010-09-15 | ATOTECH Deutschland GmbH | Self accelerating and replenishing non-formaldehyde immersion coating method |
GB2277745A (en) * | 1993-04-20 | 1994-11-09 | Enthone Omi | Post activator solution for use in electroplating non-conductive substrates e.g in plating through holes in PCB,s |
-
1995
- 1995-03-17 DE DE19510855A patent/DE19510855C2/en not_active Revoked
-
1996
- 1996-03-15 DE DE59604301T patent/DE59604301D1/en not_active Revoked
- 1996-03-15 JP JP8528081A patent/JPH11502263A/en active Pending
- 1996-03-15 CA CA002210883A patent/CA2210883A1/en not_active Abandoned
- 1996-03-15 WO PCT/EP1996/001190 patent/WO1996029452A1/en not_active Application Discontinuation
- 1996-03-15 AT AT96907505T patent/ATE189274T1/en active
- 1996-03-15 BR BR9607848A patent/BR9607848A/en not_active IP Right Cessation
- 1996-03-15 KR KR1019970706510A patent/KR19980703108A/en not_active Application Discontinuation
- 1996-03-15 EP EP96907505A patent/EP0815292B1/en not_active Revoked
- 1996-03-15 ES ES96907505T patent/ES2142572T3/en not_active Expired - Lifetime
-
1998
- 1998-06-30 HK HK98108815A patent/HK1008552A1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
WO1996029452A1 (en) | 1996-09-26 |
EP0815292A1 (en) | 1998-01-07 |
HK1008552A1 (en) | 1999-05-14 |
KR19980703108A (en) | 1998-10-15 |
DE19510855A1 (en) | 1996-09-19 |
CA2210883A1 (en) | 1996-09-26 |
ES2142572T3 (en) | 2000-04-16 |
BR9607848A (en) | 1998-07-14 |
DE59604301D1 (en) | 2000-03-02 |
JPH11502263A (en) | 1999-02-23 |
EP0815292B1 (en) | 2000-01-26 |
DE19510855C2 (en) | 1998-04-30 |
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