AT28352B - Process for the production of calcium nitrate from alkaline chlorine-containing lyes, in particular from the final lyes of the ammonia soda factory. - Google Patents
Process for the production of calcium nitrate from alkaline chlorine-containing lyes, in particular from the final lyes of the ammonia soda factory.Info
- Publication number
- AT28352B AT28352B AT28352DA AT28352B AT 28352 B AT28352 B AT 28352B AT 28352D A AT28352D A AT 28352DA AT 28352 B AT28352 B AT 28352B
- Authority
- AT
- Austria
- Prior art keywords
- lyes
- final
- production
- calcium nitrate
- ammonia soda
- Prior art date
Links
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 title description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 title description 4
- 229910021529 ammonia Inorganic materials 0.000 title description 4
- 238000004519 manufacturing process Methods 0.000 title description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title description 2
- 239000000460 chlorine Substances 0.000 title description 2
- 229910052801 chlorine Inorganic materials 0.000 title description 2
- 238000000034 method Methods 0.000 title description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 5
- 239000001110 calcium chloride Substances 0.000 description 5
- 229910001628 calcium chloride Inorganic materials 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 3
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- RAFRTSDUWORDLA-UHFFFAOYSA-N phenyl 3-chloropropanoate Chemical compound ClCCC(=O)OC1=CC=CC=C1 RAFRTSDUWORDLA-UHFFFAOYSA-N 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Landscapes
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Description
<Desc/Clms Page number 1>
Verfahren zur Gewinnung von Kalziumnitrat aus Chlorkalzium enthaltenden Laugen, insbesondere aus den Endlaugen der Ammoniaksoda-Fabrikation.
In der vorher entsprechend gereinigten chlorkalziumhältigen Lauge wird eine dem Chlorkalziumgehalt äquivalente Menge Natronsalpeter gelöst und hierauf die. Lösung ein- gedampft. Dabei setzt sich Chlorkalzium mit Salpeter in der Weise um, dass Kalziumnitrit und Chlornatrium entsteht, welch letzteres bei zunehmender Konzentration, die zweckmässig bis zum Siedepunkte von 127o C gesteigert wird, ausfällt und von der hauptsächlich Kalziumnitrat enthaltenden Lösung getrennt werden kann. Die vom ChlornatriuIl1 getrennte Mutterlauge wird weiter eingedampft und dadurch Kalziumnitrat bzw. durch Zusatz von Kalkmilch basisches Kalziumnitrat gewonnen.
BeiverschiedenenFabrikationenwerdengrosseMengenchlorkalziumhältigerEnd- laugf'n erhalten, die zum grossen Teile wertlos sind, da man für so grosse Mengen Chlor- kalzium keine Verwendung hat. Die Lauge, welche z. B. bei der Ammoniaksoda-Fabrikation erhaben werden, enthalten etwa zwei Drittel der festen Salze als Ca Cl2 und ein Dritte ! als Na ez. Aus diesen gewinnt man an manchen Orten durch Eindampfen beide Salze. Aber
EMI1.1
salpeter in der I. andwirtschaft Verwendung nnden kann.
In dem speziellen Falle der Endlaugen der Ammoniaksoda-Fabrikation stellen sich din Verhältnisse folgendermassen dar : Nachdem die Laugen von Schlamm und Gips gereinigt
EMI1.2
**WARNUNG** Ende DESC Feld kannt Anfang CLMS uberlappen**.
<Desc / Clms Page number 1>
Process for the production of calcium nitrate from alkaline chlorine-containing lyes, in particular from the final lyes of the ammonia soda factory.
An amount of sodium nitrate equivalent to the calcium chloride content is dissolved in the previously appropriately purified calcium chloride-containing lye and then the. Solution evaporated. Here, calcium chloride reacts with saltpetre in such a way that calcium nitrite and sodium chloride are formed, the latter precipitating with increasing concentration, which is expediently increased to the boiling point of 127o C, and can be separated from the solution, which mainly contains calcium nitrate. The mother liquor separated from the sodium chloride is evaporated further and calcium nitrate or basic calcium nitrate through the addition of milk of lime is obtained.
In various manufactures, large amounts of calcium chloride-containing final liquors are obtained, which for the most part are worthless, since there is no use for such large amounts of calcium chloride. The lye, which z. B. be raised in the ammonia soda fabrication, contain about two thirds of the solid salts as Ca Cl2 and a third! as Na ez. In some places, both salts are obtained from these by evaporation. But
EMI1.1
Saltpeter can be used in agriculture.
In the special case of the final liquors in the ammonia soda production, the ratios are as follows: After the liquors have been cleaned of sludge and gypsum
EMI1.2
** WARNING ** End of DESC field may overlap beginning of CLMS **.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT28352T | 1905-12-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT28352B true AT28352B (en) | 1907-05-10 |
Family
ID=3541033
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT28352D AT28352B (en) | 1905-12-31 | 1905-12-31 | Process for the production of calcium nitrate from alkaline chlorine-containing lyes, in particular from the final lyes of the ammonia soda factory. |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT28352B (en) |
-
1905
- 1905-12-31 AT AT28352D patent/AT28352B/en active
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