AR121981A1 - Sistemas catalizadores de deshidrogenación y métodos para usarlos - Google Patents

Sistemas catalizadores de deshidrogenación y métodos para usarlos

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Publication number
AR121981A1
AR121981A1 ARP210101182A ARP210101182A AR121981A1 AR 121981 A1 AR121981 A1 AR 121981A1 AR P210101182 A ARP210101182 A AR P210101182A AR P210101182 A ARP210101182 A AR P210101182A AR 121981 A1 AR121981 A1 AR 121981A1
Authority
AR
Argentina
Prior art keywords
dehydrogenation catalyst
particulate
weight
calculated
range
Prior art date
Application number
ARP210101182A
Other languages
English (en)
Inventor
Rong Xing
Vladimir Fridman
Original Assignee
Clariant Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant Int Ltd filed Critical Clariant Int Ltd
Publication of AR121981A1 publication Critical patent/AR121981A1/es

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/63Platinum group metals with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12Silica and alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/08Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of gallium, indium or thallium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/19Catalysts containing parts with different compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • B01J37/088Decomposition of a metal salt
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • C07C11/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321Catalytic processes
    • C07C5/324Catalytic processes with metals
    • C07C5/325Catalytic processes with metals of the platinum group
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56Platinum group metals
    • C07C2523/63Platinum group metals with rare earths or actinides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Reivindicación 1: Un sistema de lecho mixto que comprende un catalizador de deshidrogenación en partículas que comprende una especie primaria P1 seleccionada de Ga, In, Tl, Ge, Sn, Pb y cualquier mezcla de los mismos como metal activo, dispuesto sobre un soporte; y un aditivo no catalítico en partículas que comprende un material generador de calor y un vehículo seleccionado de óxidos inorgánicos, arcillas y cualquier mezcla de los mismos. Reivindicación 2: Un sistema de lecho mixto que comprende un catalizador de deshidrogenación en partículas que comprende una especie primaria P1 seleccionada de Ga, In, Tl, Ge, Sn, Pb y cualquier mezcla de los mismos, presente en el catalizador de deshidrogenación en partículas en una cantidad dentro del intervalo del 0.05% en peso al 20% en peso, calculada como metal elemental sobre una base calcinada; una especie primaria P2 seleccionada de los lantánidos y cualquier mezcla de los mismos, presente en el catalizador de deshidrogenación en partículas en una cantidad dentro del intervalo del 0.05% en peso al 10% en peso, calculada como metal elemental sobre una base calcinada; un promotor M1 seleccionado de Ni, Pd, Pt, La, Ir, Zn, Fe, Rh, Ru, Mn, Co, W y cualquier mezcla de los mismos, presente en el catalizador de deshidrogenación en partículas en una cantidad dentro del intervalo de 1 ppm a 500 ppm, calculada como metal elemental sobre una base calcinada; un promotor M2 seleccionado de Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba y cualquier mezcla de los mismos, presente en el catalizador de deshidrogenación en partículas en una cantidad dentro del intervalo del 0.05% en peso al 3% en peso, calculada como metal elemental sobre una base calcinada; y un soporte S1 seleccionado de sílice, alúmina, circona, titania, itria y cualquier mezcla de los mismos, presente en el catalizador de deshidrogenación en partículas en una cantidad dentro del intervalo del 50% en peso al 99% en peso, calculada como óxido sobre una base calcinada; y un aditivo no catalítico en partículas que comprende un material generador de calor; y un vehículo seleccionado de óxidos inorgánicos, arcillas y cualquier mezcla de los mismos.
ARP210101182A 2020-05-01 2021-04-30 Sistemas catalizadores de deshidrogenación y métodos para usarlos AR121981A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US202063018656P 2020-05-01 2020-05-01

Publications (1)

Publication Number Publication Date
AR121981A1 true AR121981A1 (es) 2022-07-27

Family

ID=75674798

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP210101182A AR121981A1 (es) 2020-05-01 2021-04-30 Sistemas catalizadores de deshidrogenación y métodos para usarlos

Country Status (7)

Country Link
US (1) US20230090285A1 (es)
EP (1) EP4142935A1 (es)
KR (1) KR20230005230A (es)
CN (1) CN115427143A (es)
AR (1) AR121981A1 (es)
TW (1) TW202214346A (es)
WO (1) WO2021219454A1 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115445612B (zh) * 2022-10-13 2024-05-24 钱颖 脱氢催化剂及其制备方法和应用和环己烷脱氢制苯环的方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7067455B2 (en) * 2003-11-21 2006-06-27 Conocophillips Company Copper modified catalysts for oxidative dehydrogenation
US9725380B2 (en) * 2014-03-14 2017-08-08 Clariant Corporation Dehydrogenation process with heat generating material
WO2019011660A1 (en) * 2017-07-13 2019-01-17 Haldor Topsøe A/S ALKANESHYDROGENATION CATALYST BASED ON PLATINUM-GALLIUM CONTAINING OXIDATION PROMOTER
US10792646B2 (en) * 2017-10-30 2020-10-06 Clariant Corporation Dehydrogenation catalysts
CN113286653A (zh) * 2018-10-30 2021-08-20 科莱恩国际有限公司 脱氢催化剂及其制备和使用方法

Also Published As

Publication number Publication date
US20230090285A1 (en) 2023-03-23
EP4142935A1 (en) 2023-03-08
WO2021219454A1 (en) 2021-11-04
CN115427143A (zh) 2022-12-02
TW202214346A (zh) 2022-04-16
KR20230005230A (ko) 2023-01-09

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