AR120325A1 - Compuesto fenilisoxazolina y uso del mismo - Google Patents

Compuesto fenilisoxazolina y uso del mismo

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Publication number
AR120325A1
AR120325A1 ARP200102981A ARP200102981A AR120325A1 AR 120325 A1 AR120325 A1 AR 120325A1 AR P200102981 A ARP200102981 A AR P200102981A AR P200102981 A ARP200102981 A AR P200102981A AR 120325 A1 AR120325 A1 AR 120325A1
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Argentina
Prior art keywords
alkyl
substituted
haloalkyl
unsubstituted
phenyl
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ARP200102981A
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English (en)
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Hongjuan Ma
Zhengmao Lu
Jichun Yang
Aiying Guan
Qiao Wu
Changling Liu
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Shenyang Sinochem Agrochemicals R & D Co Ltd
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Publication of AR120325A1 publication Critical patent/AR120325A1/es

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D261/00Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
    • C07D261/02Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
    • C07D261/04Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/501,3-Diazoles; Hydrogenated 1,3-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D413/00Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/10Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D413/00Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/12Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D413/00Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/14Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D471/00Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/02Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
    • C07D471/04Ortho-condensed systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D487/00Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/04Ortho-condensed systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D513/00Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00
    • C07D513/02Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00 in which the condensed system contains two hetero rings
    • C07D513/04Ortho-condensed systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/0803Compounds with Si-C or Si-Si linkages
    • C07F7/081Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C07F7/0812Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

La presente se relaciona con el campo de los herbicidas agrícolas, y particularmente se relaciona con un compuesto fenilisoxazolina y el uso del mismo. Los compuestos fenilisoxazolina se representan por medio de la fórmula (1). Los compuestos de la fórmula (1) presentan una excelente actividad herbicida y son eficaces en el control de malezas, como por ejemplo Echinochloa crusgalli, Setaria viridis, Cyperus difformis, Juncellus serotinus, Digitaria sangunalis, Arthraxon hispidus, Abutilon theophrasti, Zinnia elegans, Amaranthus retrofluxes, Portulaca oleracea, Xanthium sibiricum, Solanum nigrum, Cassia tora, Hibiscus trionum, Glycine soja, y similares. Son eficaces en el control de malezas a dosis bajas. Los compuestos de la presente también son seguros para el trigo, el maíz y el arroz, y pueden usarse como herbicidas en agricultura. Reivindicación 1: Un compuesto fenilisoxazolina, caracterizado porque es representado por la fórmula (1), donde: R¹ y R² se seleccionan respectivamente entre hidrógeno, halógeno o C₁₋₆ alquilo; R³ se selecciona entre hidrógeno, ciano, C₁₋₆ alquilo, fenilo, o fenilo sustituido en forma independiente con 1 - 4 de los siguientes sustituyentes: halógeno, CN, NO₂, C₁₋₆ alquilo, C₁₋₆ haloalquilo, C₁₋₆ alcoxi, C₁₋₆ haloalcoxi, C₁₋₆ alcoxicarbonilo, C₁₋₆ alquiltio o C₁₋₆ alquilsulfonilo; R⁴ se selecciona entre hidrógeno, ciano, C₁₋₆ alquilo, CO₂R⁷ o CH₂OR⁸; R⁵ se selecciona entre hidrógeno, ciano, C₁₋₆ alquilo, C₁₋₆ alcoxi, C₁₋₆ haloalquilo, C₁₋₆ alquil-CO₂R⁷, CO₂R⁸, CH₂SiC[tri-(C₁₋₆ alquilo)], fenilo no sustituido, o fenilo sustituido en forma independiente con 1 - 4 de los siguientes sustituyentes: halógeno, CN, NO₂, C₁₋₆ alquilo, C₁₋₆ haloalquilo, C₁₋₆ alcoxi, C₁₋₆ haloalcoxi, C₁₋₆ alcoxicarbonilo, C₁₋₆ alquiltio o C₁₋₆ alquilsulfonilo; R⁶ se selecciona entre hidrógeno, ciano, C₁₋₆ alquilo, C₁₋₆ alcoxi, C₁₋₆ haloalquilo, C₃₋₆ cicloalquilo, C₁₋₆ alquil-CO₂R⁷, CO₂R⁷, CH₂OR⁸, CH₂NR⁹R¹⁰, CONR⁹R¹⁰, fenilo no sustituido, o fenilo sustituido en forma independiente con 1 - 4 de los siguientes sustituyentes: halógeno, CN, NO₂, C₁₋₆ alquilo, C₁₋₆ haloalquilo, C₁₋₆ alcoxi, C₁₋₆ haloalcoxi, C₁₋₆ alcoxicarbonilo, C₁₋₆ alquiltio o C₁₋₆ alquilsulfonilo; R⁵ y R⁶ pueden estar unidos a un C adyacente para formar un anillo de tres miembros, un anillo de cuatro miembros, un anillo de cinco miembros o un anillo de seis miembros; R³ y R⁵ pueden estar unidos a un C adyacente para formar un anillo de cinco miembros o un anillo de seis miembros; R⁷ se selecciona entre hidrógeno, C₁₋₆ alquilo, C₁₋₆ haloalquilo, C₃₋₆ cicloalquilo, C₃₋₆ alquenilo, C₃₋₆ alquinilo, C₁₋₆ alcoxi C₁₋₆ alquilo, C₁₋₆ alquilcarboniloxi C₂₋₄ alquilo, C₂₋₆ alquenilcarboniloxi C₂₋₄ alquilo, di(C₁₋₆ alquil)amino C₂₋₄ alquilo, (C₁₋₆ alquil)amino C₂₋₄ alquilo, fenilo no sustituido, bencilo no sustituido, furfurilideno no sustituido, tiazometileno no sustituido, tetrahidrofuranmetileno no sustituido, piridinmetileno no sustituido, fenilo sustituido, bencilo sustituido, furfurilideno sustituido, tiazometileno sustituido, tetrahidrofuranmetileno sustituido o piridinmetileno sustituido, donde los sustituyentes se seleccionan en forma independiente entre 1 - 4 de los siguientes grupos: halógeno, CN, NO₂, C₁₋₆ alquilo, C₁₋₆ haloalquilo, C₁₋₆ alcoxi, C₁₋₆ haloalcoxi, C₁₋₆ alcoxicarbonilo, C₁₋₆ alquiltio o C₁₋₆ alquilsulfonilo; R⁸ se selecciona entre hidrógeno, C₁₋₆ alquilo, C₁₋₆ haloalquilo, C₁₋₆ alcoxicarbonilo, C₁₋₆ alquilcarbonilo, C₁₋₆ haloalquilcarbonilo, C₃₋₆ cicloalquilcarbonilo, C₃₋₆ halocicloalquilcarbonilo, C₁₋₆ alquilsulfonilo, C₁₋₆ haloalquilsulfonilo, C₁₋₆ alquilaminosulfonilo, diC₁₋₆alquilaminosulfonilo, C₁₋₆ alquilaminocarbonilo, diC₁₋₆alquilaminocarbonilo, diC₁₋₆ alquilaminotiocarbonilo, C₁₋₆ alquiltio C₂₋₆ alquilcarbonilo, fenilo no sustituido, fenilo no sustituido C₁₋₂ alquilo, fenilo no sustituido C₂₋₄ alquenilo, fenilcarbonilo no sustituido, fenilo no sustituido C₁₋₂ alquilcarbonilo, fenoxi no sustituido-C₁₋₂ alquilcarbonilo, fenilo no sustituido C₂₋₄ alquenilcarbonilo, heteroarilo no sustituido, heteroarilo no sustituido C₁₋₂ alquilo y heteroarilcarbonilo no sustituido, fenilo sustituido, fenilo sustituido-C₁₋₂ alquilo, fenilo sustituido-C₂₋₄ alquenilo, fenilcarbonilo sustituido, fenilo sustituido-C₁₋₂ alquilcarbonilo, fenoxi sustituido-C₁₋₂ alquilcarbonilo, fenilo sustituido-C₂₋₄ alquenilcarbonilo, heteroarilo sustituido, heteroarilo sustituido C₁₋₂ alquilo o heteroarilcarbonilo sustituido, donde los sustituyentes se seleccionan en forma independiente entre 1 - 4 de los siguientes grupos: halógeno, CN, NO₂, C₁₋₆ alquilo, C₁₋₆ haloalquilo, C₁₋₆ alcoxi, C₁₋₆ haloalcoxi, C₁₋₆ alcoxicarbonilo, C₁₋₆ alquiltio, C₁₋₆ alquilsulfonilo o fenoxi sustituido con 1 - 4 grupos seleccionados en forma independiente entre los siguientes: halógeno, CN, NO₂, C₁₋₆ alquilo, C₁₋₆ haloalquilo, C₁₋₆ alcoxi o C₁₋₆ haloalcoxi; R⁹ y R¹⁰ se seleccionan respectivamente entre hidrógeno, C₁₋₆ alquilo, C₁₋₆ haloalquilo, C₁₋₆ alcoxicarbonil-C₁₋₆ alquilo, SO₂NH (C₁₋₆ alquilo) o SO₂N (C₁₋₆ alquil)(C₁₋₆ alquilo); Q se selecciona entre cualquiera de los restos Q1 - Q13 del grupo de fórmulas (2); R¹¹ se selecciona entre C₁₋₆ alquilo o C₁₋₆ haloalquilo; R¹² se selecciona entre C₁₋₆ alquilo, C₁₋₆ haloalquilo, C₁₋₆ alcoxi o C₁₋₆ haloalcoxi; R¹³ se selecciona entre hidrógeno, halógeno, CN, NO₂ o C₁₋₆ alquilo; R¹⁴ se selecciona entre C₁₋₆ alquilo o C₁₋₆ haloalquilo; R¹⁵ se selecciona entre C₁₋₆ alquilo, C₃₋₆ cicloalquilo o C₁₋₆ haloalquilo; o una sal o un derivado aceptable para uso en agricultura del compuesto de la fórmula (1).
ARP200102981A 2019-10-29 2020-10-28 Compuesto fenilisoxazolina y uso del mismo AR120325A1 (es)

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CN115433177A (zh) * 2021-06-03 2022-12-06 沈阳中化农药化工研发有限公司 一种芳基异恶唑啉类化合物及其用途

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