AR119412A1 - Compuestos herbicidas - Google Patents

Compuestos herbicidas

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Publication number
AR119412A1
AR119412A1 ARP200101987A ARP200101987A AR119412A1 AR 119412 A1 AR119412 A1 AR 119412A1 AR P200101987 A ARP200101987 A AR P200101987A AR P200101987 A ARP200101987 A AR P200101987A AR 119412 A1 AR119412 A1 AR 119412A1
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Argentina
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alkyl
alkoxy
ring
haloalkyl
group
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ARP200101987A
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English (en)
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Peter Timothy Seden
Kenneth Bruce Ling
Christopher John Mathews
Stephen Edward Shanahan
Christiana Kitsiou
John Finney
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Syngenta Crop Protection Ag
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Publication of AR119412A1 publication Critical patent/AR119412A1/es

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    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D237/00Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings
    • C07D237/02Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings
    • C07D237/06Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D237/10Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D237/14Oxygen atoms
    • C07D237/16Two oxygen atoms
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    • C07DHETEROCYCLIC COMPOUNDS
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    • C07D237/02Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings
    • C07D237/04Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having less than three double bonds between ring members or between ring members and non-ring members
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/581,2-Diazines; Hydrogenated 1,2-diazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/713Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/761,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/781,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01PBIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P13/00Herbicides; Algicides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/10Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing aromatic rings
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    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D403/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/10Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a carbon chain containing aromatic rings
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    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D405/00Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/10Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing aromatic rings
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    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D409/00Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/10Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
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    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D413/00Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/10Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D417/00Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/10Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a carbon chain containing aromatic rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Reivindicación 1: Un compuesto de fórmula (1) o una sal o N-óxido del mismo, donde R¹ se selecciona del grupo que consiste en alquilo C₁₋₄, cicloalquilo C₃₋₆, alcoxi C₃₋₆, alcoxi C₁₋₂-alquilo C₁₋₂, alquenilo C₂₋₄, haloalquilo C₁₋₄, ciano-alquilo C₁₋₄, haloalquenilo C₂₋₄, alquinilo C₂₋₄ y haloalquinilo C₂₋₄; R² se selecciona del grupo que consiste en hidrógeno, halógeno, ciano, alquilo C₁₋₆, haloalquilo C₁₋₆, haloalcoxi C₁₋₆, haloalcoxi C₁₋₃-alquil C₁₋₃-, alcoxi C₁₋₆, alcoxi C₁₋₃-alquil C₁₋₃-, alcoxi C₁₋₃-alcoxi C₁₋₃-alquil C₁₋₃-, cicloalquilo C₃₋₆, alquenilo C₂₋₆, haloalquenilo C₂₋₆, alquinilo C₂₋₆, hidroxialquil C₁₋₆-, alquil C₁₋₆-carbonil-, -S(O)ₘ-alquilo C₁₋₆, amino, alquilamino C₁₋₆, dialquilamino C₁₋₆, -C(alquil C₁₋₃)=N-O-alquilo C₁₋₃ y haloalquinilo C₂₋₆; G es hidrógeno o C(O)R³; R³ se selecciona del grupo que consiste en alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, alquil C₁₋₆-S-, alcoxi C₁₋₆, -NR⁴R⁵ y fenilo opcionalmente sustituido con uno o más R⁶; cada uno de R⁴ y R⁵ se selecciona independientemente del grupo que consiste en hidrógeno, alquilo C₁₋₆, alcoxi C₁₋₆ y cicloalquilo C₃₋₆, o R⁴ y R⁵ pueden formar juntos un anillo de morfolinilo; y, cada uno de R⁴ᵃ y R⁵ᵃ se selecciona independientemente del grupo que consiste en alcoxi C₁₋₆ y cicloalquilo C₃₋₆, o R⁴ᵃ y R⁵ᵃ pueden formar juntos un anillo de morfolinilo; y, R⁶ se selecciona del grupo que consiste en halógeno, ciano, nitro, alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxi C₁₋₃ y haloalcoxi C₁₋₃; X e Y son cada uno independientemente hidrógeno, alquilo C₁₋₃, ciclopropilo, alcoxi C₁₋₃, haloalquilo C₁₋₃, haloalcoxi C₁₋₃ o halógeno; D es un anillo de heteroarilo monocíclico sustituido que contiene 1, 2 ó 3 heteroátomos seleccionados independientemente de oxígeno, nitrógeno y azufre, sustituido en al menos un átomo de carbono del anillo con R⁸ y/o en al menos un átomo de nitrógeno del anillo con R⁹; al menos un R⁸ se selecciona del grupo que consiste en haloalquilcarbonil C₁₋₆-, cicloalquilcarbonil C₃₋₆-, -S(O)ₘ-haloalquilo C₁₋₆, -S(O)ₘ-cicloalquilo C₃₋₆, -O-S(O)₂-alquilo C₁₋₃, -alquil C₁₋₃-S(O)ₘ-alquilo C₁₋₆, -alquil C₁₋₃-S(O)ₘ-haloalquilo C₁₋₆, -alquil C₁₋₃-S(O)ₘ-cicloalquilo C₃₋₆, ciano-alquil C₁₋₆-, -NR⁴ᵃR⁵ᵃ, -C(S)NR⁴R⁵, - S(O)₂NHC(O)alquilo C₁₋₃, -S(O)₂NR⁴R⁵, -C(O)OH, -C(O)O-alquilo C₁₋₆, -C(O)NHS-(O)₂-alquilo C₁₋₆, -C(O)NR⁴R⁵, -NR⁴C(O)NR⁴R⁵, alquilcarbonil C₁₋₆(alquil C₁₋₆)amino-, haloalquilcarbonilamino C₁₋₆-, haloalquilcarbonil C₁₋₆(alquil C₁₋₆)amino-, alquilsulfonilamino C₁₋₆-, alquilsulfonil C₁₋₆(alquil C₁₋₆)amino-, haloalquilsulfonilamino C₁₋₆-, haloalquilsulfonil C₁₋₆(alquil C₁₋₆)amino-, cicloalquilsulfonilamino C₃₋₆-, cicloalquilsulfonil C₃₋₆(alquil C₁₋₆)amino-, hidroxiamino-, hidroxi(alquil C₁₋₆)amino, alcoxiamino C₁₋₆, alcoxi C₁₋₆(alquil C₁₋₆)amino, haloalcoxiamino C₁₋₆, haloalcoxi C₁₋₆(alquil C₁₋₆)amino; y un sistema anular seleccionado del grupo que consiste en un anillo de fenilo, un anillo de heteroarilo de 5 - 6 miembros y un anillo de heterociclilo de 3 - 6 miembros, donde dicho sistema anular está sustituido con 0 a 5 R¹⁶; al menos un R⁹ se selecciona del grupo que consiste en alquilo C₅₋₆, haloalquilo C₅₋₆, cicloalquil C₃₋₆-, alcoxi C₁₋₃-alquil C₃-, alcoxi C₃-alquil C₁₋₂-, haloalcoxi C₁₋₃-alquil C₁₋₃-, alcoxi C₁₋₃-alcoxi C₁₋₃-alquil C₁₋₃-, hidroxialquil C₁₋₆-, -alquil C₁₋₃-S(O)ₘ-alquilo C₁₋₆, -alquil C₁₋₃-S(O)ₘ-haloalquilo C₁₋₆, -alquil C₁₋₃-S(O)ₘ-cicloalquilo C₃₋₆, ciano-alquil C₁₋₆- y un sistema anular seleccionado del grupo que consiste en: un anillo de fenilo, un anillo de heteroarilo de 5 - 6 miembros y un anillo de heterociclilo de 3 - 6 miembros, donde dicho sistema anular está sustituido con 0 a 5 R¹⁶; m es un número entero de 0, 1 ó 2; cada R¹⁶ es independientemente halógeno, ciano, alquilo C₁₋₆, haloalquilo C₁₋₆, alcoxi C₁₋₆ o haloalcoxi C₁₋₆; o D es un anillo de fenilo sustituido con al menos un R⁸; y, W es cualquiera de los compuestos del grupo de fórmulas (2) donde: “a” indica el punto de unión al resto fenil-piridazina diona / fenil-piridazinona, “b” indica el punto de unión al anillo D; R¹⁰, R¹², R¹⁴ y R¹⁵ son cada uno independientemente hidrógeno, alquilo C₁₋₃ o haloalquilo C₁₋₃; o R¹⁰ y R¹² junto con los átomos de carbono a los que están unidos forman un anillo carbocíclico C₃₋₆; y R¹¹ y R¹³ son cada uno independientemente hidrógeno, halógeno, alquilo C₁₋₃ o haloalquilo C₁₋₃; siempre que cuando uno de R¹¹ o R¹³ sea halógeno, alquilo C₁₋₃ o haloalquilo C₁₋₃, el otro sea hidrógeno.
ARP200101987A 2019-07-18 2020-07-15 Compuestos herbicidas AR119412A1 (es)

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US (1) US20220281827A1 (es)
EP (3) EP3999494B1 (es)
JP (1) JP2022542015A (es)
KR (1) KR20220035412A (es)
CN (4) CN118084802A (es)
AR (1) AR119412A1 (es)
AU (1) AU2020315159A1 (es)
BR (1) BR112022000906A2 (es)
CA (1) CA3146243A1 (es)
CO (1) CO2022000257A2 (es)
GB (1) GB201910290D0 (es)
IL (1) IL288733A (es)
MX (1) MX2022000561A (es)
TW (1) TW202116738A (es)
UY (1) UY38789A (es)
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GB201800305D0 (en) * 2018-01-09 2018-02-21 Syngenta Participations Ag Herbicidal compounds
AR125453A1 (es) 2021-04-27 2023-07-19 Bayer Ag Piridazinonas sustituidas, sales o n-óxidos de las mismas y su uso como sustancias herbicidamente activas
GB202116307D0 (en) 2021-11-12 2021-12-29 Syngenta Crop Protection Ag Herbicide resistance

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CL2008003785A1 (es) 2007-12-21 2009-10-09 Du Pont Compuestos derivados de piridazina; composiciones herbicidas que comprenden a dichos compuestos; y método para controlar el crecimiento de la vegetación indeseada.
GB0816880D0 (en) 2008-09-15 2008-10-22 Syngenta Ltd Improvements in or relating to organic compounds
WO2011035878A1 (de) * 2009-09-25 2011-03-31 Bayer Cropscience Ag Herbizid wirksame phenylsubstituierte pyridazinone
WO2011045271A1 (de) * 2009-10-15 2011-04-21 Bayer Cropscience Ag Herbizid wirksame heterocyclylsubstituierte pyridazinone
GB201206598D0 (en) 2012-04-13 2012-05-30 Syngenta Ltd Herbicidal compounds
GB201412735D0 (en) * 2014-07-17 2014-09-03 Syngenta Participations Ag Herbicidal compounds
GB201800305D0 (en) * 2018-01-09 2018-02-21 Syngenta Participations Ag Herbicidal compounds
GB201819747D0 (en) * 2018-12-04 2019-01-16 Syngenta Participations Ag Herbicidal compositions

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