AR111858A1 - Método para suavizar solución salina de litio utilizando nanofiltración - Google Patents

Método para suavizar solución salina de litio utilizando nanofiltración

Info

Publication number
AR111858A1
AR111858A1 ARP180101230A ARP180101230A AR111858A1 AR 111858 A1 AR111858 A1 AR 111858A1 AR P180101230 A ARP180101230 A AR P180101230A AR P180101230 A ARP180101230 A AR P180101230A AR 111858 A1 AR111858 A1 AR 111858A1
Authority
AR
Argentina
Prior art keywords
nanofiltration
softening
salt solution
lithium salt
sulfate
Prior art date
Application number
ARP180101230A
Other languages
English (en)
Inventor
Frederick Liberatore
Original Assignee
Bl Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bl Technologies Inc filed Critical Bl Technologies Inc
Publication of AR111858A1 publication Critical patent/AR111858A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C22B26/12—Obtaining lithium
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/02—Softening water by precipitation of the hardness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/027—Nanofiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/027—Nanofiltration
    • B01D61/0271—Nanofiltration comprising multiple nanofiltration steps
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/04—Chlorides
    • C01D3/06—Preparation by working up brines; seawater or spent lyes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/442—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by nanofiltration
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00—Multistage treatment of water, waste water or sewage
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/14—Alkali metal compounds
    • C25B1/16—Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/06—Specific process operations in the permeate stream
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/12—Addition of chemical agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2317/00—Membrane module arrangements within a plant or an apparatus
    • B01D2317/02—Elements in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2317/00—Membrane module arrangements within a plant or an apparatus
    • B01D2317/02—Elements in series
    • B01D2317/025—Permeate series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/26—Treatment of water, waste water, or sewage by extraction
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/101—Sulfur compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08—Seawater, e.g. for desalination
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/02—Softening water by precipitation of the hardness
    • C02F5/06—Softening water by precipitation of the hardness using calcium compounds

Abstract

Se trata la solución salina de litio con un sistema de membrana de nanofiltración de múltiples pasos. Se agrega sulfato al permeado desde un paso corriente arriba antes de que fluya a través de un paso corriente abajo. Opcionalmente se puede agregar el sulfato al permeado al dosificarlo con ácido sulfúrico o una sal tal como sulfato de sodio. La solución salina suavizada luego se puede procesar adicionalmente, por ejemplo mediante una combinación de extracción de solvente, electrólisis, cristalización y secado, para producir un producto de hidróxido de litio que se puede utilizar para elaborar baterías.
ARP180101230A 2017-05-11 2018-05-10 Método para suavizar solución salina de litio utilizando nanofiltración AR111858A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2017/032178 WO2018208305A1 (en) 2017-05-11 2017-05-11 Method for softening lithium brine using nanofiltration

Publications (1)

Publication Number Publication Date
AR111858A1 true AR111858A1 (es) 2019-08-28

Family

ID=58995239

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP180101230A AR111858A1 (es) 2017-05-11 2018-05-10 Método para suavizar solución salina de litio utilizando nanofiltración

Country Status (5)

Country Link
US (1) US11203542B2 (es)
CN (2) CN110603339B (es)
AR (1) AR111858A1 (es)
CL (1) CL2018001240A1 (es)
WO (1) WO2018208305A1 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10589188B2 (en) 2016-06-27 2020-03-17 Enviro Water Minerals Company, Inc. System and method for removal of scale forming components
US11365128B2 (en) 2017-06-15 2022-06-21 Energysource Minerals Llc Process for selective adsorption and recovery of lithium from natural and synthetic brines
US11634348B2 (en) 2019-01-30 2023-04-25 Enviro Water Minerals Company, Inc. System and method for treating hydrocarbon-containing feed streams
US11643703B2 (en) * 2019-06-18 2023-05-09 Schlumberger Technology Corporation Method of recovering alkali metals from an aqueous source
WO2023081688A1 (en) * 2021-11-02 2023-05-11 Energy Exploration Technologies, Inc. Monovalent anion selective membrane enabled by high concentration brine
CN114230076A (zh) * 2021-12-20 2022-03-25 廖崇亨 金属表面处理液回收利用系统及其操作方法
KR20230158212A (ko) 2022-05-11 2023-11-20 한국과학기술연구원 자성 나노 구조체 및 미생물을 포함하는 희유금속 회수용 복합체 및 상기 복합체를 포함하는 희유금속 회수 시스템
CN115571951A (zh) * 2022-09-26 2023-01-06 西藏矿业发展股份有限公司 一种盐湖提锂生产系统
WO2024073485A1 (en) * 2022-09-28 2024-04-04 Gradiant Corporation Lithium recovery from liquid streams using solute-permeable membranes

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5587083A (en) 1995-04-17 1996-12-24 Chemetics International Company Ltd. Nanofiltration of concentrated aqueous salt solutions
CA2186963C (en) 1996-10-01 1999-03-30 Riad A. Al-Samadi High water recovery membrane purification process
US6004464A (en) * 1998-07-14 1999-12-21 Desalination Systems, Inc. Spent brine reclamation
GB2395946B (en) * 2002-12-05 2006-01-18 Thomas Altmann Method for the production of sodium chloride from seawater
CN100408705C (zh) * 2003-04-30 2008-08-06 中国科学院青海盐湖研究所 纳滤法从盐湖卤水中分离镁和富集锂的方法
WO2010006366A1 (en) 2008-07-18 2010-01-21 Rincon Lithium Limited A process for recovering lithium from a brine
MX347833B (es) * 2010-01-14 2017-05-12 Bp Exploration Operating Procedimiento de suministro de agua de salinidad controlada.
WO2011147019A1 (en) 2010-05-26 2011-12-01 Al-Samadi Riad A Multi-use high water recovery process
US8647509B2 (en) 2010-06-15 2014-02-11 General Electric Company Seawater desalination plant and production of high purity salt
US9199866B2 (en) 2011-08-17 2015-12-01 Riad A. Al-Samadi High recovery drinking water process
EP2773782B1 (en) 2011-11-03 2016-03-30 Advance Lithium Projects Ltd. Processes for metal ions removal of from aqueous solutions
US10105653B2 (en) 2012-08-13 2018-10-23 Enviro Water Minerals Company, Inc. System for rinsing electrodialysis electrodes
WO2014089796A1 (en) * 2012-12-13 2014-06-19 General Electric Company Method for treating high concentration wastewater such as ro brine
CN103074502B (zh) 2013-01-29 2014-04-23 中国科学院青海盐湖研究所 用于从高镁锂比的盐湖卤水分离锂的盐湖卤水处理方法
GB2526294B (en) 2014-05-19 2017-05-10 Tenova Advanced Tech Ltd Selective separation process
US10059611B2 (en) 2014-06-03 2018-08-28 Enviro Water Minerals Company, Inc. System and method for regenerating an ion separation resin
CN107949541A (zh) * 2015-08-28 2018-04-20 雅宝公司 从含锂卤水中回收锂值的方法
CN105293803A (zh) 2015-11-06 2016-02-03 北京沃特尔水技术股份有限公司 一种高浓度废水的处理方法
KR20150139486A (ko) * 2015-11-26 2015-12-11 한국해양과학기술원 Nf/ro/ed 분리막 연계시스템을 이용한 해수(해양심층수) 처리수 제조공정 개발

Also Published As

Publication number Publication date
CN110603339A (zh) 2019-12-20
CL2018001240A1 (es) 2018-11-23
CN115180688A (zh) 2022-10-14
CN110603339B (zh) 2022-07-05
CN115180688B (zh) 2024-05-07
US20200140305A1 (en) 2020-05-07
US11203542B2 (en) 2021-12-21
WO2018208305A1 (en) 2018-11-15

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