AR107628A1 - Regeneración de catalizador - Google Patents

Regeneración de catalizador

Info

Publication number
AR107628A1
AR107628A1 ARP170100372A ARP170100372A AR107628A1 AR 107628 A1 AR107628 A1 AR 107628A1 AR P170100372 A ARP170100372 A AR P170100372A AR P170100372 A ARP170100372 A AR P170100372A AR 107628 A1 AR107628 A1 AR 107628A1
Authority
AR
Argentina
Prior art keywords
air
alkane
gallium
soaking
regeneration process
Prior art date
Application number
ARP170100372A
Other languages
English (en)
Inventor
Lin Luo
David Gordon Barton
Andrzej Malek
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of AR107628A1 publication Critical patent/AR107628A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/42—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using halogen-containing material
    • B01J38/44—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using halogen-containing material and adding simultaneously or subsequently free oxygen; using oxyhalogen compound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/02—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/14—Treating with free oxygen-containing gas with control of oxygen content in oxidation gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/18—Treating with free oxygen-containing gas with subsequent reactive gas treating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/30—Treating with free oxygen-containing gas in gaseous suspension, e.g. fluidised bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/30—Treating with free oxygen-containing gas in gaseous suspension, e.g. fluidised bed
    • B01J38/34—Treating with free oxygen-containing gas in gaseous suspension, e.g. fluidised bed with plural distinct serial combustion stages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C07C5/324—Catalytic processes with metals
    • C07C5/325—Catalytic processes with metals of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/58—Platinum group metals with alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Un método para reducir el tiempo de proceso de regeneración que contiene remojo por vía aérea. El proceso incluye (i) eliminar las especies de carbono en superficie de un catalizador de deshidrogenación de alcano en base a galio en un proceso de combustión en presencia de un gas combustible; (ii) preparar el catalizador de deshidrogenación de alcano en base a galio después de (i) en el tratamiento de remojo por vía aérea a una temperatura de 660 grados Celsius (ºC) a 850ºC con (iii) un flujo de gas que contiene oxígeno que tiene (iv) 0,1 a 100 partes por millón en volumen (ppmv) de una fuente de cloro seleccionada de cloro, un compuesto de cloro o una combinación de los mismos y lograr un porcentaje de conversión de alcano predeterminado para el catalizador de deshidrogenación de alcano en base a galio que se somete al proceso de regeneración que contiene remojo por vía aérea usando (i) a (iv) 10 por ciento (%) a 50% más rápido en el tratamiento de remojo por vía aérea que el requerido para lograr el mismo porcentaje de conversión de alcano predeterminado para el catalizador de deshidrogenación de alcano en base a galio que se somete al proceso de regeneración que contiene remojo por vía aérea usando (i) a (ii), pero sin (iv).
ARP170100372A 2016-03-01 2017-02-15 Regeneración de catalizador AR107628A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US201662301856P 2016-03-01 2016-03-01

Publications (1)

Publication Number Publication Date
AR107628A1 true AR107628A1 (es) 2018-05-16

Family

ID=58231735

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP170100372A AR107628A1 (es) 2016-03-01 2017-02-15 Regeneración de catalizador

Country Status (8)

Country Link
US (1) US10654035B2 (es)
EP (1) EP3423187A1 (es)
CN (1) CN108698042A (es)
AR (1) AR107628A1 (es)
BR (1) BR112018017237B1 (es)
CA (1) CA3015623A1 (es)
RU (1) RU2724336C2 (es)
WO (1) WO2017151361A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3104495A1 (en) 2018-07-05 2020-01-09 Dow Global Technologies Llc Chemical processes and systems that include the combustion of supplemental fuels
CA3104490A1 (en) 2018-07-05 2020-01-09 Dow Global Technologies Llc Chemical processing utilizing hydrogen containing supplemental fuel for catalyst processing
EP3817849A1 (en) 2018-07-05 2021-05-12 Dow Global Technologies LLC Processes for commencing operations of fluidized catalytic reactor systems
WO2020048983A1 (en) 2018-09-04 2020-03-12 Haldor Topsøe A/S Regeneration procedure for iron-based dehydrogenation catalysts
CN112536064B (zh) * 2019-09-20 2022-07-12 中国石油化工股份有限公司 一种失活丙烷脱氢催化剂的再生方法
US11577237B2 (en) * 2019-12-13 2023-02-14 Uop Llc Process and apparatus for regenerating catalyst with supplemental fuel
WO2021151813A1 (en) * 2020-01-30 2021-08-05 Haldor Topsøe A/S Process for dehydrogenation of a hydrocarbon feed stock in a fixed bed reactor
WO2021250567A1 (en) * 2020-06-10 2021-12-16 Sabic Global Technologies B.V. A process for reconstructing a spent dehydrogenation catalyst
US20220126281A1 (en) * 2021-06-30 2022-04-28 Uop Llc Process for regenerating a dehydrogenation catalyst
US20230211332A1 (en) * 2021-12-31 2023-07-06 Uop Llc Stripping of regenerated catalyst during start-up and shutdown

Family Cites Families (15)

* Cited by examiner, † Cited by third party
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US1499297A (en) 1921-08-06 1924-06-24 Mattia Bros De Collapsible core for pneumatic tires
GB1436622A (en) * 1973-06-21 1976-05-19 British Petroleum Co Regeneration of zeolite catalysts
GB1499297A (en) 1976-06-29 1978-01-25 Kogan S Catalyst for dehydrogenation of paraffin hydrocarbons to olefines and method of preparing such a catalyst
US4480046A (en) 1982-05-05 1984-10-30 Exxon Research & Engineering Co. Reactivation process for iridium-containing catalysts using low halogen flow rates
US4738939A (en) * 1987-06-29 1988-04-19 Exxon Research And Engineering Company Regeneration and reactivation of reforming catalysts while passivating iron scale carryover from the regenerator circuit to the reactors
US4872970A (en) * 1988-09-23 1989-10-10 Exxon Research And Engineering Company Reactivation of iridium-containing catalysts
US5227566A (en) * 1991-01-09 1993-07-13 Uop Process for the dehydrogenation of hydrocarbons
US5189234A (en) 1991-10-31 1993-02-23 Amoco Corporation Selective dehydrogenation processes and catalysts
IT1254252B (it) * 1992-03-11 1995-09-14 Snam Progetti Procedimento per l'attivazione di precursori catalitici per la deidrogenazione di paraffine c2-c5 e composizione catalitica attivata con tale procedimento
FR2726486B1 (fr) * 1994-11-07 1997-01-24 Eurecat Europ Retrait Catalys Procede de regeneration hors site de catalyseur comprenant au moins un metal precieux
US6756340B2 (en) 2002-04-08 2004-06-29 Uop Llc Dehydrogenation catalyst composition
CN102355947A (zh) 2009-03-19 2012-02-15 陶氏环球技术有限责任公司 脱氢方法和催化剂
US20120277089A1 (en) * 2009-11-06 2012-11-01 Mahesh Venkataraman Iyer Process for the regeneration of hydrocarbon conversion catalysts
BR112014000199B1 (pt) * 2011-07-13 2020-06-02 Dow Global Technologies Llc Processo para desidrogenar um alcano
CN104755167B (zh) 2012-08-28 2018-08-07 陶氏环球技术有限责任公司 催化剂组合物和用于烷烃脱氢的再活化方法

Also Published As

Publication number Publication date
RU2018132833A (ru) 2020-03-17
BR112018017237A2 (pt) 2019-01-15
CA3015623A1 (en) 2017-09-08
US20190046968A1 (en) 2019-02-14
EP3423187A1 (en) 2019-01-09
RU2018132833A3 (es) 2020-04-28
CN108698042A (zh) 2018-10-23
WO2017151361A1 (en) 2017-09-08
US10654035B2 (en) 2020-05-19
RU2724336C2 (ru) 2020-06-23
BR112018017237B1 (pt) 2022-02-08

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