AR093480A1 - Metodo para la reduccion de oxido de hierro a hierro metalico con el empleo de gas natural - Google Patents

Metodo para la reduccion de oxido de hierro a hierro metalico con el empleo de gas natural

Info

Publication number
AR093480A1
AR093480A1 ARP130104185A ARP130104185A AR093480A1 AR 093480 A1 AR093480 A1 AR 093480A1 AR P130104185 A ARP130104185 A AR P130104185A AR P130104185 A ARP130104185 A AR P130104185A AR 093480 A1 AR093480 A1 AR 093480A1
Authority
AR
Argentina
Prior art keywords
reduction
gas stream
gas
blast furnace
iron
Prior art date
Application number
ARP130104185A
Other languages
English (en)
Inventor
C Meissner David
c montague Stephen
M Jr Mclelland James
E Metius Gary
Original Assignee
Midrex Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/955,654 external-priority patent/US9028585B2/en
Priority claimed from US14/069,493 external-priority patent/US9127326B2/en
Application filed by Midrex Technologies Inc filed Critical Midrex Technologies Inc
Publication of AR093480A1 publication Critical patent/AR093480A1/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/02Making spongy iron or liquid steel, by direct processes in shaft furnaces
    • C21B13/029Introducing coolant gas in the shaft furnaces
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/0073Selection or treatment of the reducing gases
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/02Making spongy iron or liquid steel, by direct processes in shaft furnaces
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20Increasing the gas reduction potential of recycled exhaust gases
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/22Increasing the gas reduction potential of recycled exhaust gases by reforming
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/28Increasing the gas reduction potential of recycled exhaust gases by separation
    • C21B2100/282Increasing the gas reduction potential of recycled exhaust gases by separation of carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/60Process control or energy utilisation in the manufacture of iron or steel
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/60Process control or energy utilisation in the manufacture of iron or steel
    • C21B2100/62Energy conversion other than by heat exchange, e.g. by use of exhaust gas in energy production
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/10Reduction of greenhouse gas [GHG] emissions
    • Y02P10/122Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/10Reduction of greenhouse gas [GHG] emissions
    • Y02P10/134Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/10Reduction of greenhouse gas [GHG] emissions
    • Y02P10/143Reduction of greenhouse gas [GHG] emissions of methane [CH4]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Abstract

En diversos ejemplos de formas de realización, la presente proporciona sistemas y métodos que pueden convertir gas natural limpio o en bruto, gas de horno de coque limpio o sucio o un material similar, en gas de reducción/gas de síntesis adecuado para la reducción directa con un procesamiento o limpieza mínimos. Los hidrocarburos y similares se convierten en H₂ y CO. El azufre no afecta la conversión en gas de reducción/gas de síntesis, pero se lo elimina o limpia de algún modo por medio del lecho de hierro en el horno de cuba de reducción directa. El gas de alto horno se puede reciclar en forma continua o se puede aplicar un enfoque de única vez. Reivindicación 1: Un método para la reducción de óxido de hierro a hierro metálico, que comprende: proporcionar una corriente de gas de alto horno proveniente de un horno de cuba de reducción directa; eliminar el dióxido de carbono de la corriente de gas de alto horno con el empleo de un sistema de eliminación de dióxido de carbono; calentar la corriente de gas de alto horno en un calentador de gas para formar una corriente de gas de reducción y proporcionar la corriente de gas de reducción al horno de cuba de reducción directa para reducir el óxido de hierro a hierro metálico; y agregar una corriente de gas natural o una corriente de gas de horno de coque a la corriente de gas de reducción a modo de una corriente de gas de síntesis.
ARP130104185A 2013-07-31 2013-11-14 Metodo para la reduccion de oxido de hierro a hierro metalico con el empleo de gas natural AR093480A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/955,654 US9028585B2 (en) 2010-05-14 2013-07-31 System and method for reducing iron oxide to metallic iron using coke oven gas and oxygen steelmaking furnace gas
US14/069,493 US9127326B2 (en) 2010-05-14 2013-11-01 System and method for reducing iron oxide to metallic iron using natural gas

Publications (1)

Publication Number Publication Date
AR093480A1 true AR093480A1 (es) 2015-06-10

Family

ID=52432302

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP130104185A AR093480A1 (es) 2013-07-31 2013-11-14 Metodo para la reduccion de oxido de hierro a hierro metalico con el empleo de gas natural

Country Status (15)

Country Link
EP (1) EP3027779B1 (es)
JP (1) JP6152221B2 (es)
KR (1) KR20160048766A (es)
CN (1) CN105408500A (es)
AR (1) AR093480A1 (es)
AU (1) AU2013395619A1 (es)
BR (1) BR112016001590B1 (es)
CA (1) CA2915681C (es)
CL (1) CL2015003714A1 (es)
MX (1) MX2016000768A (es)
MY (1) MY183440A (es)
RU (1) RU2643007C2 (es)
TW (1) TWI494440B (es)
UA (1) UA114676C2 (es)
WO (1) WO2015016956A1 (es)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11952638B2 (en) 2019-09-27 2024-04-09 Midrex Technologies, Inc. Direct reduction process utilizing hydrogen

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RU2726175C1 (ru) * 2016-09-20 2020-07-09 Мидрэкс Текнолоджиз, Инк. Способы и системы для повышения содержания углерода в губчатом железе в восстановительной печи
CN106435081A (zh) * 2016-12-16 2017-02-22 江苏省冶金设计院有限公司 一种直接还原铁的制备系统及制备方法
CN106399617A (zh) * 2016-12-16 2017-02-15 江苏省冶金设计院有限公司 一种气基竖炉直接还原炼铁的系统及方法
CN106521073A (zh) * 2016-12-16 2017-03-22 江苏省冶金设计院有限公司 一种利用炉顶气制备直接还原铁的系统及方法
CN106636518A (zh) * 2016-12-16 2017-05-10 江苏省冶金设计院有限公司 一种采用气基法生产直接还原铁的系统及方法
US20190323098A1 (en) * 2016-12-22 2019-10-24 Sabic Global Technologies B.V. Direct reduction process for the production of direct-reduced iron with high purity methane
CN106702067A (zh) * 2017-03-14 2017-05-24 江苏省冶金设计院有限公司 一种利用气基竖炉制备直接还原铁的系统及方法
CN107058663A (zh) * 2017-03-14 2017-08-18 江苏省冶金设计院有限公司 一种生产直接还原铁的系统及方法
LU100453B1 (en) * 2017-09-25 2019-03-29 Wurth Paul Sa Method for Producing a Synthesis Gas, in particular for use in Blast Furnace Operation
JP2021533552A (ja) * 2018-07-27 2021-12-02 フォーム エナジー インク 電気化学セル用の負極
CN110846456A (zh) * 2019-11-22 2020-02-28 刘建华 一种还原氧化铁装置及工艺
EP4067508A4 (en) * 2019-11-25 2023-01-25 JFE Steel Corporation BLAST FURNACE OPERATING PROCESS AND BLAST FURNACE ANCILLARY
CN111961784B (zh) * 2020-08-31 2021-09-07 山东大学 一种铁矿粉鼓泡床还原反应的方法与系统
CN115491455B (zh) * 2021-06-18 2024-03-08 宝山钢铁股份有限公司 一种基于带式焙烧机的预还原球团制备装置及方法
CN115491489B (zh) * 2021-06-18 2023-12-12 宝山钢铁股份有限公司 基于链篦机-回转窑的预还原球团制备装置及方法
CN115491454B (zh) * 2021-06-18 2024-03-08 宝山钢铁股份有限公司 一种铁矿石微波高温烧结氢冷还原装置及方法
CN115261542A (zh) * 2022-07-11 2022-11-01 山东祥桓环境科技有限公司 一种煤粉与矿粉短流程冶炼的循环流化床直还原方法及工艺

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US4019724A (en) * 1973-02-20 1977-04-26 Armco Steel Corporation Apparatus for the direct reduction of iron ores
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US6506230B2 (en) * 1997-09-05 2003-01-14 Midrex Technologies, Inc. Method for increasing productivity of direct reduction process
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11952638B2 (en) 2019-09-27 2024-04-09 Midrex Technologies, Inc. Direct reduction process utilizing hydrogen

Also Published As

Publication number Publication date
CN105408500A (zh) 2016-03-16
JP6152221B2 (ja) 2017-06-21
MY183440A (en) 2021-02-18
CL2015003714A1 (es) 2016-12-09
EP3027779B1 (en) 2020-04-15
BR112016001590A2 (pt) 2017-08-29
RU2643007C2 (ru) 2018-01-29
CA2915681C (en) 2017-11-21
UA114676C2 (uk) 2017-07-10
TWI494440B (zh) 2015-08-01
EP3027779A4 (en) 2017-11-08
CA2915681A1 (en) 2015-02-05
KR20160048766A (ko) 2016-05-04
JP2016529383A (ja) 2016-09-23
EP3027779A1 (en) 2016-06-08
WO2015016956A1 (en) 2015-02-05
BR112016001590B1 (pt) 2019-10-22
RU2016106016A (ru) 2017-09-01
AU2013395619A1 (en) 2016-02-04
TW201504446A (zh) 2015-02-01
MX2016000768A (es) 2016-04-27

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