AR082013A1 - Sintesis de energia eficiente de aldheidos alifaticos de alcanos y dioxido de carbono - Google Patents

Sintesis de energia eficiente de aldheidos alifaticos de alcanos y dioxido de carbono

Info

Publication number
AR082013A1
AR082013A1 ARP110102118A ARP110102118A AR082013A1 AR 082013 A1 AR082013 A1 AR 082013A1 AR P110102118 A ARP110102118 A AR P110102118A AR P110102118 A ARP110102118 A AR P110102118A AR 082013 A1 AR082013 A1 AR 082013A1
Authority
AR
Argentina
Prior art keywords
hydroformylation
carbon dioxide
butene
butane
aldheids
Prior art date
Application number
ARP110102118A
Other languages
English (en)
Inventor
Franke Robert Dr
Dirk Fridag
Hamers Bart Dr
Zanthoff Horst Dr
Blug Matthias Werner-Dr
Strautmann Julia Dra
Nordhoff Stefan Dr
Original Assignee
Evonik Oxeno Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Oxeno Gmbh filed Critical Evonik Oxeno Gmbh
Publication of AR082013A1 publication Critical patent/AR082013A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Es objeto de la presente especificar un proceso para producir aldehídos que, en comparación con la hidroformilación convencional, ahorra CO2, que utiliza fuentes de materias primas alternativas y que no requiere una etapa de suministro de monóxido de carbono. Este problema se soluciona por medio de procesos que comprenden las siguientes etapas: a) suministro de al menos un alcano; b) deshidrogenación fotocatalítica del alcano en una mezcla que comprende al menos una olefina e hidrógeno; c) adición de dióxido de carbono e hidrógeno a la mezcla; d) hidroformilación de la olefina en al menos un aldehído. Más en particular, el n-butano se deshidrogena inicialmente de forma fotocatalítica y el 1-buteno resultante se hace reaccionar con CO2 en una hidroformilación para formar el valeraldehído. El proceso general ejemplificado para el n-butano y CO2 es el siguiente:n-butano ® 1-buteno + H2 (deshidrogenación fotocatalítica) 1-buteno + CO2 + 2 H2 ®@@@valeraldehído + H2O (hidroformilación con CO2).
ARP110102118A 2010-06-17 2011-06-17 Sintesis de energia eficiente de aldheidos alifaticos de alcanos y dioxido de carbono AR082013A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102010030209A DE102010030209A1 (de) 2010-06-17 2010-06-17 Energieeffiziente Synthese von aliphatischen Adelhyden aus Alkanen und Kohlendioxid

Publications (1)

Publication Number Publication Date
AR082013A1 true AR082013A1 (es) 2012-11-07

Family

ID=44454549

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP110102118A AR082013A1 (es) 2010-06-17 2011-06-17 Sintesis de energia eficiente de aldheidos alifaticos de alcanos y dioxido de carbono

Country Status (9)

Country Link
US (1) US8884070B2 (es)
EP (1) EP2582651B1 (es)
KR (1) KR101790374B1 (es)
CN (1) CN102933537B (es)
AR (1) AR082013A1 (es)
DE (1) DE102010030209A1 (es)
ES (1) ES2717906T3 (es)
SG (1) SG185764A1 (es)
WO (1) WO2011157788A1 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012202779A1 (de) 2012-02-23 2013-08-29 Evonik Oxeno Gmbh Verfahren und Vorrichtung zur technischen Hydroformylierung von Isobuten und zum Auftrennen des Produktgemisches
DE102012205258A1 (de) 2012-03-30 2013-10-02 Evonik Industries Ag Photoelektrochemische Zelle, System und Verfahren zur lichtgetriebenen Erzeugung von Wasserstoff und Sauerstoff mit einer photoelektrochemischen Zelle und Verfahren zur Herstellung der photoelektrochemischen Zelle
ES2603929T3 (es) 2012-10-12 2017-03-02 Evonik Degussa Gmbh Bisfosfito asimétrico
DE102013225883A1 (de) 2013-12-13 2015-06-18 Evonik Industries Ag Zweistufige Hydroformylierung mit Kreisgas- und SILP-Technologie
DE102014203960A1 (de) * 2014-03-05 2015-09-10 Evonik Degussa Gmbh Verfahren zur Herstellung von Aldehyden aus Alkanen und Synthesegas
ES2607692T3 (es) 2014-08-14 2017-04-03 Evonik Degussa Gmbh Hidroformilación con CO2 catalizada por SILP
KR102379397B1 (ko) * 2016-06-30 2022-03-28 다우 글로벌 테크놀로지스 엘엘씨 메탄을 프로판알로 전환하기 위한 방법
US11420916B2 (en) * 2018-06-08 2022-08-23 Board Of Regents, The University Of Texas System Systems and methods for separation of olefins from mixtures that contain reducing agents
CN110028403B (zh) * 2019-04-19 2020-08-11 四川大学 一种合成丁二酸类化合物的方法
JP7291387B2 (ja) * 2019-07-05 2023-06-15 国立研究開発法人産業技術総合研究所 二酸化炭素を原料とするヒドロホルミル化反応用触媒
CN115403507B (zh) * 2022-09-02 2023-09-26 中钢集团南京新材料研究院有限公司 一种咔唑-3-甲醛的合成方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3343585B2 (ja) * 2000-02-23 2002-11-11 独立行政法人産業技術総合研究所 二酸化炭素を利用したヒドロホルミル化法
DE10031517A1 (de) 2000-06-28 2002-01-10 Basf Ag Verfahren zur Herstellung von Hydroformylierungspordukten von Olefinen mit 2 bis 8 Kohlenstoffatomen
DE10251262A1 (de) 2002-11-04 2004-05-13 Basf Ag Verfahren zur Herstellung von Aldehyden aus Alkanen
DE102004041850A1 (de) 2004-08-27 2006-03-02 Basf Ag Verfahren zur Herstellung von C5-Aldehyden und Propen aus einem 1-Buten- und 2-Buten-haltigen C4-Strom
DE102005061642A1 (de) 2004-12-23 2006-07-06 Basf Ag Phosphorchelatverbindungen
JP5271075B2 (ja) * 2006-03-28 2013-08-21 日立化成株式会社 二酸化炭素を原料とするアルコールの製造方法
EP2206694B1 (en) 2007-09-25 2014-02-12 Hitachi Chemical Company, Ltd. Method for producing alcohol using carbon dioxide as raw material
DE102008002187A1 (de) 2008-06-03 2009-12-10 Evonik Oxeno Gmbh Verfahren zur Herstellung von C5-Aldehydgemischen mit hohem n-Pentanalanteil
DE102009001594A1 (de) 2009-03-17 2010-09-30 Evonik Oxeno Gmbh Verfahren zur Herstellung von alpha, beta-ungesättigten C10-Aldehyden
DE102009045139A1 (de) 2009-09-30 2011-03-31 Evonik Oxeno Gmbh Herstellung von alpha,beta-ungesättigten Aldehyden mittels einer Reaktionsmischpumpe
DE102010041821A1 (de) 2010-09-30 2012-04-05 Evonik Oxeno Gmbh Einsatz von Supported Ionic Liquid Phase (SILP) Katalysatorsystemen in der Hydroformylierung von olefinhaltigen Gemischen zu Aldehydgemischen mit hohem Anteil von in 2-Stellung unverzweigten Aldehyden
DE102010043558A1 (de) 2010-11-08 2012-05-10 Evonik Oxeno Gmbh Verfahren zur Hydroformylierung von ungesättigten Verbindungen
DE102010044155A1 (de) 2010-11-19 2012-05-24 Evonik Degussa Gmbh Photosensibilisatoren und deren Einsatz zur Wasserstofferzeugung aus Wasser

Also Published As

Publication number Publication date
EP2582651B1 (de) 2018-12-26
EP2582651A1 (de) 2013-04-24
KR20130086150A (ko) 2013-07-31
DE102010030209A1 (de) 2011-12-22
US20130178657A1 (en) 2013-07-11
CN102933537A (zh) 2013-02-13
SG185764A1 (en) 2013-01-30
US8884070B2 (en) 2014-11-11
WO2011157788A1 (de) 2011-12-22
ES2717906T3 (es) 2019-06-26
KR101790374B1 (ko) 2017-10-25
CN102933537B (zh) 2015-02-18

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