AR049832A1 - Piridinas 2-sustituidas, procedimientos para su obtencion y el uso de las mismas para combatir hongos nocivos - Google Patents
Piridinas 2-sustituidas, procedimientos para su obtencion y el uso de las mismas para combatir hongos nocivosInfo
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- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
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- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
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Abstract
Productos intermedios para la preparacion de las mismas, productos pesticidas que las contienen y procedimientos para combatir hongos nocivos y pestes animales, valiéndose de los compuestos segun la presente. Reivindicacion 1: Piridinas 2- sustituidas de la formula (1), en la que el índice y los sustituyentes tienen los significados siguientes: X1, X2: uno de los miembros de anillo, respectivamente, significa N, el otro significa C-H- o C-halogeno; Y significa un grupo -CH-R1-, -N-R1- , -O- o -S-; R1, R2 significan, independientemente, C1-8-alquilo, C2-8-alquenilo, C2-8-alquinilo, C3-6-cicloalquilo, C3-6-halogenocicloalquilo, pudiendo R1 y R2 a su vez estar parcialmente o completamente halogenados o llevar uno a cuatro grupos Rv; Rv significa ciano, C1-6-alquilo, C3-6-cicloalquilo, C4-6-cicloalquenilo, hidroxi, C1-6-alcoxi, C2-8-alqueniloxi, C2-8-alquiniloxi, C3-6-cicloalquiloxi, C4-6-cicloalqueniloxi, C1-6-alquiltio, -C(=O)-A, -C(=O)-O-A, -C(=O)-N(A')A, C(A')(=N-OA), N(A')A, N(A')-C(=O)-A, N(A'')-C(=O)-N(A')A, S(=O)m-A, S(=O)m-O-A o S(=O)m-N(A')A o fenilo, pudiendo la parte de fenilo llevar uno a tres radicales seleccionados del grupo: halogeno, C1-6-alquilo, C2-6-alquenilo, C2-6-alquinilo, C3-6-cicloalquilo, C1- 6-halogenoalquilo, C1-6-alcoxi, ciano, nitro, -C(=O)-A, -C(=O)-O-A, -C(=O)-N(A')A, C(A')(=N-OA), N(A')A; R1 puede significar, adicionalmente, hidrogeno; R1 y R2 también pueden formar junto con el átomo de nitrogeno o de carbono, al que están unidos, un anillo saturado o no saturado de cinco o seis miembros, que puede estar interrumpido por un grupo éter-(-O-), carbonilo-(C=O)-; tio-(-S-), sulfoxilo-(-S[=O]-) o sulfenilo-(-SO2-) u otro grupo amino-(-N(Ra)- adicional, donde Ra significa hidrogeno o C1-6-alquilo, y/o contener uno o varios sustituyentes del grupo: halogeno, C1-6-alquilo, C1-6-halogenoalquilo y oxi-C1-3-alqueniloxi; donde R1, R2 tienen, preferentemente, los significados siguientes: R1, R2 significan, independientemente, C1-6- alquilo, C2-6-alquenilo, C2-6-alquinilo, C3-6-cicloalquilo, C3-6-halogenocicloalquilo, pudiendo los grupos alifáticos de las definiciones de los radicales R1 y R2 a su vez estar parcialmente o completamente halogenados o llevar uno a cuatro grupos Rv; Rv significa ciano, C3-6-cicloalquilo, C4-6-cicloalquenilo, hidroxi, C1-6-alcoxi, C2-8-alqueniloxi, C2-8-alquiniloxi, C3-6-cicloalquiloxi, C4-6-cicloalqueniloxi, C1-6-alquiltio, -C(=O)-A, -C(=O)-O-A, -C(=O)-N(A')A, C(A')(=N-OA), N(A')A, N(A')- C(=O)-A, N(A'')-C(=O)-N(A')A, S(=O)m-A, S(=O)m-O-A o S(=O)m-N(A')A o fenilo, pudiendo la parte de fenilo llevar uno a tres radicales seleccionados del grupo: halogeno, C1-6-alquilo, C2-6-alquenilo, C2-6-alquinilo, C3-6- cicloalquilo, C1-6- halogenoalquilo, C1-6-alcoxi, ciano, nitro, -C(=O)-A, -C(=O)-O-A, -C(=O)-N(A')A, C(A')(=N-OA), N(A')A; R1 puede significar, adicionalmente hidrogeno; R1 y R2 también pueden formar junto con el átomo de nitrogeno o de carbono, al que están unidos, un anillo saturado o no saturado de cinco o seis miembros, que puede estar interrumpido por un grupo éter-(-O-), carbonilo-(C=O)-; tio-(-S-), sulfoxilo-(-S[=O]-) o sulfenilo-(-SO2-) u otro grupo amino-(-N(Ra)- adicional, donde Ra significa hidrogeno o C1-6-alquilo, y/o contener uno o varios sustituyentes del grupo: halogeno, C1-6-alquilo, C1-6-halogenoalquilo y oxi-C1-3-alqueniloxi; R3 significa halogeno, ciano, C1-4-alquilo, C2-4-alquenilo, C2-4-alquinilo, C3-6- cicloalquilo, C1-4-alcoxi, C3-4- alqueniloxi, C3-4-alquiniloxi, C1-6-alquiltio, di-(C1-6-alquil)amino o C1-6-alquilamino, pudiendo los radicales alquilo, alquenilo y alquinilo de R3 estar sustituidos por halogeno, ciano, nitro, C1-2-alcoxi o C1-4- alcoxicarbonilo; R4 significa un heterociclo mono o bicíclico, saturado, parcialmente insaturado o aromático de cinco o seis miembros, que contiene uno a cuatro heteroátomos del grupo O, N o S, que a su vez puede estar parcialmente o completamente halogenado o llevar uno a cuatro grupos Ru; Ru significa ciano, C1-8-alquilo, C2-8-alquenilo, C2-8-alquinilo, C1-6-alcoxi, C3-6-cicloalquilo, C2-8-alqueniloxi, C2-8-alquiniloxi, C4-6-cicloalquenilo, C3-6-cicloalquiloxi, C4-6-cicloalqueniloxi, -C(=O)- A, -C(=O)-O-A, -C(=O)-N(A')A, C(A')(=N-OA), N(A')A, N(A')-C(=O)-A, N(A'')-C(=O)-N(A')A, S(=O)m-A, S(=O)m-O-A o S(=O)m-N(A')A, donde m, A, 'A, A'' tienen los significados mencionados debidamente; adicionalmente, R4 puede significar: ciano, C(=Z)ORa, C(=Z)NRzRb, C(=Z)NRa-NRzRb, C(=Z)Ra, CRaRb-Orz, CRaRb-NRzRc; ON(=CRaRb), O-C(=Z)Ra; NRaRb', NRa(C(=Z)Rb), NRa(C(=Z)ORb), NRa(C(=Z)-NRzRb), NRa(N=CRcRb), NRa-NRzRb, NRz-Ra; donde Z representa O, S, NRa, o N-NRzRc; Ra, Rb, Rc representan, independientemente, hidrogeno, C1-6- alquilo, C2-6-alquenilo, C2-6-alquinilo, C3-6-cicloalquilo o C4-6-cicloalquenilo; Rb' tiene los mismos significados que Rb, con excepcion de hidrogeno; Rz tiene los mismos significados que Ra y puede significar adicionalmente -CO-Ra; pudiendo los grupos alifáticos o alicíclicos de las definiciones de los radicales Ra, Rb, Rc o Rz a su vez estar parcialmente o completamente halogenados o llevar uno a cuatro grupos Rw; Rw significa halogeno, ciano, C1-8- alquilo, C2-10-alquenilo, C2-10- alquinilo, C1-6-alcoxi, C2-10-alqueniloxi, C2-10-alquiniloxi, C3-6-cicloalquilo, C3-6-cicloalquenilo, C3-6-cicloalcoxi, C3-6-cicloalqueniloxi, y pudiendo Ra, Rb, Rc o Rz formar junto con los átomos a los que están ligados un heterociclo saturado, parcialmente insaturado o aromático de cinco a seis miembros, que contiene uno a cuatro heteroátomos del grupo O, N o S; ôEl anillo Bö representa hetarilo de cinco o seis miembros, que contiene 1 a 3 heteroátomos seleccionados del grupo O, N o S o fenilo; n es un numero entero de 1 a 5; L significa halogeno, ciano, cianato (OCN), C1-8-alquilo, C2-8-alquenilo, C2-8-alquinilo, C1-6-alcoxi, C2-8-alqueniloxi, C2-8-alquiniloxi, C3-6-cicloalquilo, C4-6- cicloalquenilo, C3-6-cicloalquiloxi, C4-6- cicloalqueniloxi, nitro, -C(=O)-A, -C(=O)-O-A, -C(=O)-N(A')A, -C(=S)-N(A')A, C(A')(=N-OA), N(A')A, N(A')-C(=O)-A, N(A'')-C(=O)-N(A')A, S(=O)m-A, S(=O)m-O-A o S(=O)m-N(A')A; m es 0, 1 o 2; A, A', A'' significan, independientemente, hidrogeno, C1-6- alquilo, C2-6-alquenilo, C2-6-alquinilo, C3-8-cicloalquilo, C3-8-cicloalquenilo, fenilo, pudiendo los radicales orgánicos estar parcialmente o completamente halogenados o sustituidos por nitro, cianato, ciano o C1-4-alcoxi; o A y A' representan junto con los átomos a los que están unidos un heterociclo saturado, parcialmente insaturado o aromático de cinco a seis miembros, que contiene uno a cuatro heteroátomos del grupo O, N o S; pudiendo los grupos alifáticos de las definiciones de los radicales L a su vez estar parcialmente o completamente halogenados o llevar uno a cuatro grupos RL: RL significa ciano, C1-6-alcoxi, C3-6-cicloalquilo, C2-8-alqueniloxi, C2-8-alquiniloxi, C4-6- cicloalquenilo, C3-6-cicloalquiloxi, C4-6- cicloalqueniloxi, -C(=O)-A, -C(=O)-O-A, -C(=O)-N(A')A, C(A')(=N-OA), N(A')A, N(A')-C(=O)-A, N(A'')-C(=O)-N(A')A, S(=O)m-A, S(=O)m-O-A o S(=O)m-N(A')A. Reivindicacion 11: Compuestos de las formulas (2), donde Ln tiene además de los significados indicados en la reivindicacion 2, los significados: C1-6-alquiltio o C1-6-alquilsulfenilo.
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PA8775801A1 (es) * | 2007-04-06 | 2009-05-15 | Neurocrine Biosciences Inc | Antagonista del receptor de la hormona liberadora de gonadotropina y procedimientos relacionados con los mismos |
US8263588B2 (en) | 2007-04-06 | 2012-09-11 | Neurocrine Biosciences, Inc. | Gonadotropin-releasing hormone receptor antagonists and methods relating thereto |
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