AR042256A1 - Derivados de 1-aril-pirazol-3-sustituido-amidoxima, procedimiento para su preparacion y uso como pesticida - Google Patents
Derivados de 1-aril-pirazol-3-sustituido-amidoxima, procedimiento para su preparacion y uso como pesticidaInfo
- Publication number
- AR042256A1 AR042256A1 ARP030104422A ARP030104422A AR042256A1 AR 042256 A1 AR042256 A1 AR 042256A1 AR P030104422 A ARP030104422 A AR P030104422A AR P030104422 A ARP030104422 A AR P030104422A AR 042256 A1 AR042256 A1 AR 042256A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- substituted
- halo
- cycloalkyl
- halogen
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000000575 pesticide Substances 0.000 title abstract 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 18
- 229910052736 halogen Inorganic materials 0.000 abstract 12
- 150000002367 halogens Chemical class 0.000 abstract 9
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 7
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 7
- 125000000217 alkyl group Chemical group 0.000 abstract 5
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 5
- 125000005843 halogen group Chemical group 0.000 abstract 5
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 5
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 abstract 4
- 125000000304 alkynyl group Chemical group 0.000 abstract 4
- -1 halo (C1-6) alkyl Chemical group 0.000 abstract 4
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 4
- 125000003342 alkenyl group Chemical group 0.000 abstract 3
- 125000004438 haloalkoxy group Chemical group 0.000 abstract 3
- 125000000232 haloalkynyl group Chemical group 0.000 abstract 3
- 229910052757 nitrogen Inorganic materials 0.000 abstract 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 2
- 125000006272 (C3-C7) cycloalkyl group Chemical group 0.000 abstract 2
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 2
- 229910006069 SO3H Inorganic materials 0.000 abstract 2
- 125000001118 alkylidene group Chemical group 0.000 abstract 2
- 125000002541 furyl group Chemical group 0.000 abstract 2
- 125000005842 heteroatom Chemical group 0.000 abstract 2
- 125000000623 heterocyclic group Chemical group 0.000 abstract 2
- 125000002883 imidazolyl group Chemical group 0.000 abstract 2
- 125000000842 isoxazolyl group Chemical group 0.000 abstract 2
- 125000002971 oxazolyl group Chemical group 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 125000003373 pyrazinyl group Chemical group 0.000 abstract 2
- 125000003226 pyrazolyl group Chemical group 0.000 abstract 2
- 125000002098 pyridazinyl group Chemical group 0.000 abstract 2
- 125000004076 pyridyl group Chemical group 0.000 abstract 2
- 125000000714 pyrimidinyl group Chemical group 0.000 abstract 2
- 125000000168 pyrrolyl group Chemical group 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 125000001113 thiadiazolyl group Chemical group 0.000 abstract 2
- 125000000335 thiazolyl group Chemical group 0.000 abstract 2
- 125000001544 thienyl group Chemical group 0.000 abstract 2
- 125000004306 triazinyl group Chemical group 0.000 abstract 2
- 125000001425 triazolyl group Chemical group 0.000 abstract 2
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 1
- 241000239223 Arachnida Species 0.000 abstract 1
- 241000238421 Arthropoda Species 0.000 abstract 1
- 125000006519 CCH3 Chemical group 0.000 abstract 1
- 241000238631 Hexapoda Species 0.000 abstract 1
- 241000244206 Nematoda Species 0.000 abstract 1
- 125000003302 alkenyloxy group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000005119 alkyl cycloalkyl group Chemical group 0.000 abstract 1
- 125000005133 alkynyloxy group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000005291 haloalkenyloxy group Chemical group 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 125000001475 halogen functional group Chemical group 0.000 abstract 1
- 244000000013 helminth Species 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 125000006413 ring segment Chemical group 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/44—Oxygen and nitrogen or sulfur and nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
- C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Veterinary Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Tropical Medicine & Parasitology (AREA)
- Medicinal Chemistry (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Pharmacology & Pharmacy (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
Derivados de 1-aril-pirazol-3-sustituido-amidoxima, las composiciones pesticidas de los mismos, los procedimientos para su preparación, y su uso para el control de artrópodos (incluyendo insectos y arácnidos) y helmintos (incluyendo nematodos). Reivindicación 1: Un compuesto de fórmula (1a) o (1b), en la cual R1 es arilo no sustituido o sustituido con uno o más radicales R15; o es R10 o R19; X e Y son cada uno independientemente H, alquenilo (C3-6), haloalquenilo (C3-6), alquinilo (C3-6), haloalquinilo (C3-6), cicloalquilo (C3-7), alquilo (C1-4)-cicloalquilo (C3-7), -CO2-alquilo (C1-6), -CONR7R8, -CONR8R9, -CO2-(CH2)qR7, -(CH2)qR7, -(CH2)qR10, -COR8, -SO2R13 o -COR17; o alquilo (C1-6) no sustituido o sustituido con uno o más radicales R11; W es N, C-CH3 o C-halógeno; R2 es H, -CH3 o halógeno; R3 es halo, alquilo (C1-3), haloalquilo (C1-3), haloalcoxi (C1-3), S(O)p-haloalquilo(C1-3) o SF5; R4 es H, alquenilo (C3-6), haloalquenilo (C3-6), alquinilo (C3-6), haloalquinilo (C3-6), cicloalquilo (C3-7), -CO2-alquilo (C1-6), -CO2-cicloalquilo (C3-7), -CO2-alquilo (C1-4)-cicloalquilo (C3-7), -CO2-alquenilo (C3-6), -CO2-(CH2)qR7, -CONR8R9, -CO2-(CH2)qR10, -(CH2)qR7, -(CH2)qR10, -COR8, o -COCH2O-alquilo (C1-4); o alquilo (C1-6) no sustituido o sustituido con uno o más radicales R11; R5 es H, alquinilo (C2-6), -CO2-alquilo (C1-6), cicloalquilo (C3-7) o -SO2R12; o alquilo (C1-6), alquenilo (C2-6) o CO-alquilo (C1-6) donde los últimos tres grupos mencionados están no sustituidos o están sustituidos con uno o más radicales R11; R6 y R13 son cada uno independientemente alquilo (C1-6), haloalquilo (C1-6),alquenilo (C2-6), haloalquenilo (C2-6), alquinilo (C2-6), haloalquinilo (C2-6),o cicloalquilo (C3-7); R7 es fenilo no sustituido o sustituido con uno o más radicales seleccionados del grupo formado por halógeno, alquilo (C1-6), haloalquilo (C1-6), alcoxi (C1-6), haloalcoxi (C1-6), -CN, -NO2, -S(O)pR13 y NR9R14; R8 es H, alquilo (C1-6), haloalquilo (C1-6), cicloalquilo (C3-7), alquilo(C1-4)-cicloalquilo-(C3-7), -(CH2)qR7 o -(CH2)qR10; R9 y R14 son, cada uno independientemente H, alquilo (C1-6), haloalquilo (C1-6), cicloalquilo (C3-7) o alquilo (C1-4)-cicloalquilo(C3-7); o R8 y R9 conjuntamente con el átomo de N unido forman un anillo saturado de cinco o seis miembros que contiene opcionalmente un heteroátomo adicional en el anillo, el cual está seleccionado entre O, S y N; donde el anillo no está sustituido o está sustituido con uno o más radicales seleccionados del grupo formado por halógeno, alquilo (C1-6) y haloalquilo (C1-6) y halógeno; R10 es heterociclilo no sustituido o sustituido con uno o más radicales seleccionados del grupo formado por halógeno, alquilo (C1-4), haloalquilo(C1-4), alcoxi (C1-4), S(O)pR13, -OH y oxo; R11 es halógeno, alcoxi (C1-6), haloalcoxi (C1-6), cicloalquilo (C3-7), -S(O)pR13, -CO2-alquilo(C1-6), -O(C=O)-alquilo (C1-6), -CO-alquilo(C1-6), CO-haloalquilo (C1-6), NR8R9, CONR8R9, -SO2NR8R9, -OH, -CN, -NO2, -OR7, NR8COR14, NR8SO2R13 o-OR10, R12 es cicloalquilo (C3-7), alquenilo (C2-6), haloalquenilo (C2-6) o R10; o fenilo no sustituido o sustituido con uno o más radicales seleccionados del grupo R15, o es alquilo (C1-6) no sustituido o sustituido con uno o más radicales seleccionados del grupo formado por halógeno, alcoxi (C1-6), haloalcoxi (C1-6), alqueniloxi (C3-6), haloalqueniloxi (C3-6), alquiniloxi (C3-6), haloalquiniloxi (C3-6), cicloalquilo (C3-7), S(O)pR7, S(O)pR10, S(O)pR13, -CN, -NO2, -OH, -COR8, NR8COR14, NR8SO2R13, CONR8R9, NR8R9, -OR7, -OR10, R16, R10 y CO2R8; R15 es halógeno, alquilo(C1-6), haloalquilo(C1-6), alcoxi (C1-6), haloalcoxi (C1-6), -CN, -NO2, -S(O)pR13, NR8R9, -COR13, -COR7, -CONR8R9, -SO2NR8R9, -R7, SF5, -OH, -OR7, R18, -OR18, -SO3H o alquilidenimino (C1-6); R16 es fenilo no sustituido o sustituido con uno o más radicales seleccionados del grupo formado por halógeno, alquilo (C1-6), haloalquilo (C1-6), alcoxi(C1-6), haloalcoxi(C1-6), -CN, -NO2, S(O)pR13, NR8R9, COR13, COR17, CONR8R9, SO2NR8R9, -OH, SO3H y alquilidenimino (C1-6); R17 es alquilo (C1-6) que está sustituido con alcoxi (C1-6), S(O)p-alquilo (C1-6) o S(O)p-haloalquilo (C1-6); R18 es un radical heteroaromático seleccionado del grupo formado por piridilo, pirimidinilo, piridazinilo, pirazinilo, triazinilo, tienilo, tiazolilo, tiadiazolilo, oxazolilo, isoxazolilo, furilo, pirrolilo, pirazolilo, imidazolilo y triazolilo, donde dichos grupos no están sustituidos o están sustituidos con uno o más grupos seleccionados del grupo formado por halógeno, alquilo (C1-6),haloalquilo (C1-6) y alcoxi (C1-6); R19 es un radical heteroaromático seleccionado del grupo formado por piridilo, pirimidinilo, piridazinilo, pirazinilo, triazinilo, tienilo, tiazolilo, tiadiazolilo, oxazolilo, isoxazolilo, furilo, pirrolilo, pirazolilo, imidazolilo y triazolilo, que no están sustituidos o están sustituidos con uno o más radicales seleccionados del grupo formado por halógeno, alquilo (C1-6), haloalquilo (C1-6) y alcoxi (C1-6), y donde el radical heteroaromático está sustituido con R7, R18 o -OR7; m es 1 o 2; n y p son cada uno independientemente 0, 1 o 2; q es 0 o 1; y cada heterociclilo en los radicales anteriormente mencionados es independientemente un radical heterocíclico que tiene 3 a 6 átomos en el anillo y 1, 2 o 3 heteroátomos en el anillo seleccionado del grupo formado por N, O y S; o una sal del mismo pesticidamente aceptable.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02027064 | 2002-12-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR042256A1 true AR042256A1 (es) | 2005-06-15 |
Family
ID=32405693
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP030104422A AR042256A1 (es) | 2002-12-03 | 2003-12-01 | Derivados de 1-aril-pirazol-3-sustituido-amidoxima, procedimiento para su preparacion y uso como pesticida |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US7514428B2 (es) |
| EP (1) | EP1599451B1 (es) |
| JP (1) | JP4839463B2 (es) |
| KR (1) | KR101146546B1 (es) |
| CN (1) | CN100408565C (es) |
| AR (1) | AR042256A1 (es) |
| AU (1) | AU2003289709B2 (es) |
| BR (2) | BR0316996B1 (es) |
| CA (1) | CA2508330C (es) |
| CO (1) | CO5690508A2 (es) |
| EA (1) | EA009644B1 (es) |
| ES (1) | ES2417016T3 (es) |
| MX (1) | MXPA05005900A (es) |
| NZ (1) | NZ540463A (es) |
| WO (1) | WO2004050633A1 (es) |
| ZA (1) | ZA200503744B (es) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0518593A2 (pt) * | 2004-12-07 | 2008-11-25 | Merial Ltd | derivados de 5-aminopirazol como compostos pesticidas |
| WO2006125641A2 (en) * | 2005-05-25 | 2006-11-30 | Basf Aktiengesellschaft | Pyridine compounds for combating arthropod pests and nematodes |
| DE102006014653A1 (de) * | 2006-03-28 | 2007-10-04 | Bayer Cropscience Ag | Verwendung von Tetramsäurederivaten zur Bekämpfung von Insekten durch Angiessen, Tröpfchenapplikation oder Bodeninjektion |
| UA120354C2 (uk) | 2013-09-30 | 2019-11-25 | Фмк Корпорейшн | Піноутворювальний препарат і пристрій для доставки |
| AR100936A1 (es) | 2014-06-24 | 2016-11-09 | Fmc Corp | Formulaciones de espumas y concentrados emulsionables |
| EP3393240A1 (en) | 2015-12-23 | 2018-10-31 | FMC Corporation | In situ treatment of seed in furrow |
| CN108148049B (zh) * | 2018-01-17 | 2020-03-10 | 河北大学 | 一种三嗪酮结构的5-吡唑酰胺类化合物制备方法与应用 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4631211A (en) | 1985-03-25 | 1986-12-23 | Scripps Clinic & Research Foundation | Means for sequential solid phase organic synthesis and methods using the same |
| GB8713768D0 (en) * | 1987-06-12 | 1987-07-15 | May & Baker Ltd | Compositions of matter |
| NO179282C (no) * | 1991-01-18 | 1996-09-11 | Rhone Poulenc Agrochimie | Nye 1-(2-pyridyl)pyrazolforbindelser til kontroll av skadeinsekter |
| WO1995013275A1 (fr) * | 1993-11-09 | 1995-05-18 | Idemitsu Kosan Co., Ltd. | Derives de pyrazole et herbicide les contenant |
| JPH10152476A (ja) * | 1996-01-30 | 1998-06-09 | Takeda Chem Ind Ltd | １−アリールピラゾール誘導体、その製造法および用途 |
| ZA9711534B (en) * | 1996-12-24 | 1998-06-24 | Rhone Poulenc Agrochimie | Pesticidal 1-arylpyrazoles. |
| US6350771B1 (en) * | 1996-12-24 | 2002-02-26 | Rhone-Poulenc, Inc. | Pesticidal 1-arylpyrazoles |
| ZA981776B (en) * | 1997-03-10 | 1998-09-03 | Rhone Poulenc Agrochimie | Pesticidal 1-arylpyrazoles |
| ZA200601794B (en) * | 2003-09-04 | 2007-04-25 | Bayer Cropscience Sa | Pesticidal 5-substituted-oxyalkylamino-1-arylpyrazole derivatives |
-
2003
- 2003-11-12 NZ NZ540463A patent/NZ540463A/en not_active IP Right Cessation
- 2003-11-12 US US10/537,466 patent/US7514428B2/en active Active
- 2003-11-12 CN CNB2003801048582A patent/CN100408565C/zh not_active Expired - Fee Related
- 2003-11-12 BR BRPI0316996-0B1A patent/BR0316996B1/pt active IP Right Grant
- 2003-11-12 CA CA2508330A patent/CA2508330C/en not_active Expired - Fee Related
- 2003-11-12 WO PCT/EP2003/012620 patent/WO2004050633A1/en active Application Filing
- 2003-11-12 EA EA200500931A patent/EA009644B1/ru not_active IP Right Cessation
- 2003-11-12 MX MXPA05005900A patent/MXPA05005900A/es active IP Right Grant
- 2003-11-12 EP EP03779896.4A patent/EP1599451B1/en not_active Expired - Lifetime
- 2003-11-12 JP JP2004556132A patent/JP4839463B2/ja not_active Expired - Fee Related
- 2003-11-12 BR BRPI0316996A patent/BRPI0316996B8/pt not_active IP Right Cessation
- 2003-11-12 ES ES03779896T patent/ES2417016T3/es not_active Expired - Lifetime
- 2003-11-12 AU AU2003289709A patent/AU2003289709B2/en not_active Ceased
- 2003-11-12 KR KR1020057009949A patent/KR101146546B1/ko not_active IP Right Cessation
- 2003-12-01 AR ARP030104422A patent/AR042256A1/es not_active Application Discontinuation
-
2005
- 2005-05-10 ZA ZA200503744A patent/ZA200503744B/en unknown
- 2005-05-31 CO CO05052702A patent/CO5690508A2/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| US7514428B2 (en) | 2009-04-07 |
| KR20050084101A (ko) | 2005-08-26 |
| AU2003289709B2 (en) | 2008-09-04 |
| BR0316996B1 (pt) | 2013-12-10 |
| ES2417016T3 (es) | 2013-08-05 |
| MXPA05005900A (es) | 2005-08-29 |
| EP1599451B1 (en) | 2013-04-24 |
| CN1720234A (zh) | 2006-01-11 |
| BR0316996A (pt) | 2005-10-25 |
| CO5690508A2 (es) | 2006-10-31 |
| AU2003289709A1 (en) | 2004-06-23 |
| BRPI0316996B1 (es) | 2013-12-10 |
| ZA200503744B (en) | 2006-11-29 |
| EA009644B1 (ru) | 2008-02-28 |
| EA200500931A1 (ru) | 2005-12-29 |
| BRPI0316996B8 (pt) | 2022-08-23 |
| EP1599451A1 (en) | 2005-11-30 |
| NZ540463A (en) | 2008-03-28 |
| CN100408565C (zh) | 2008-08-06 |
| BRPI0316996A2 (es) | 2005-10-25 |
| KR101146546B1 (ko) | 2012-07-03 |
| CA2508330A1 (en) | 2004-06-17 |
| WO2004050633A1 (en) | 2004-06-17 |
| US20060241105A1 (en) | 2006-10-26 |
| JP2006515288A (ja) | 2006-05-25 |
| JP4839463B2 (ja) | 2011-12-21 |
| CA2508330C (en) | 2011-06-28 |
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