AR018743A1 - Catalizador a base de compuestos de metales de transicion y proceso para la (co)polimerizacion de olefinas usando dicho catalizador, proceso parala preparacion del catalizador, metodo para seleccionar la porcion de distribucion de pm y un copolimero de etileno y 1-olefina - Google Patents
Catalizador a base de compuestos de metales de transicion y proceso para la (co)polimerizacion de olefinas usando dicho catalizador, proceso parala preparacion del catalizador, metodo para seleccionar la porcion de distribucion de pm y un copolimero de etileno y 1-olefinaInfo
- Publication number
- AR018743A1 AR018743A1 ARP990101068A ARP990101068A AR018743A1 AR 018743 A1 AR018743 A1 AR 018743A1 AR P990101068 A ARP990101068 A AR P990101068A AR P990101068 A ARP990101068 A AR P990101068A AR 018743 A1 AR018743 A1 AR 018743A1
- Authority
- AR
- Argentina
- Prior art keywords
- catalyst
- olefins
- polymerization
- transition metal
- parally
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 3
- 150000001336 alkenes Chemical class 0.000 title 1
- 229920001038 ethylene copolymer Polymers 0.000 title 1
- 150000003623 transition metal compounds Chemical class 0.000 title 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 4
- 125000004429 atom Chemical group 0.000 abstract 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
- C07D213/53—Nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
- C07F13/005—Compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Pyridine Compounds (AREA)
Abstract
Se describe un catalizador para la polimerizacion de 1-olefinas que comprende: (1) un compuesto de formula (B), en donde M es Fe [II], Fe [III], Co [I],Co [II], Mn [I], Mn [II], Mn [III], Mn [IV], Ru [II], Ru [III] o Ru [IV]; x representa un átomo ogrupo enlazado covalente o ionicamente almetal de transicion M; T es el estado de oxidacion del metal de transicion M y b es la valencia del átomo o grupo X; R1, R2, R3, R4, R5, R6 y R7 seeligen independientemente entre hidrogeno, halogeno, hidrocarbilo, hidrocarbilo sustituido, heterohidrocarbilo o heterohidrocarbilo sustituido; ycuando dos o más cualesquiera de R1-R7 son hidrocarbilo, hidrocarbilo sustituido, heterohidrocarbilo o heterohidrocarbilo sustituido, dichos doso más cualesquiera de R1-R7 pueden estar enlazados para formar uno o más sustituyentes cíclicos; (2) otro catalizador. También se describen copolímerospreparados usando el catalizador que tienen propiedades físicas específicas.
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9805336.6A GB9805336D0 (en) | 1998-03-12 | 1998-03-12 | Polymerisation catalysts |
GBGB9806106.2A GB9806106D0 (en) | 1998-03-20 | 1998-03-20 | Polymerisation catalyst |
GBGB9806661.6A GB9806661D0 (en) | 1998-03-27 | 1998-03-27 | Polymerisation catalysts |
GBGB9809598.7A GB9809598D0 (en) | 1998-05-07 | 1998-05-07 | Polymerisation catalysts |
GBGB9814496.7A GB9814496D0 (en) | 1998-07-03 | 1998-07-03 | Polymerisation catalysts |
GBGB9820036.3A GB9820036D0 (en) | 1998-09-16 | 1998-09-16 | Polymerisation catalysts |
GBGB9823983.3A GB9823983D0 (en) | 1998-11-02 | 1998-11-02 | Polymerisation catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
AR018743A1 true AR018743A1 (es) | 2001-12-12 |
Family
ID=27562947
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP990101068A AR018743A1 (es) | 1998-03-12 | 1999-03-11 | Catalizador a base de compuestos de metales de transicion y proceso para la (co)polimerizacion de olefinas usando dicho catalizador, proceso parala preparacion del catalizador, metodo para seleccionar la porcion de distribucion de pm y un copolimero de etileno y 1-olefina |
Country Status (17)
Country | Link |
---|---|
US (3) | US6657026B1 (es) |
EP (1) | EP1062249B1 (es) |
JP (2) | JP4606579B2 (es) |
KR (1) | KR100587757B1 (es) |
CN (1) | CN1216079C (es) |
AR (1) | AR018743A1 (es) |
AT (1) | ATE280185T1 (es) |
AU (1) | AU2738599A (es) |
CA (2) | CA2586497A1 (es) |
CO (1) | CO5070721A1 (es) |
DE (1) | DE69921304T2 (es) |
DZ (1) | DZ2740A1 (es) |
ES (1) | ES2229683T3 (es) |
ID (1) | ID26574A (es) |
MX (1) | MXPA00008941A (es) |
PT (1) | PT1062249E (es) |
WO (1) | WO1999046302A1 (es) |
Families Citing this family (95)
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US7906451B2 (en) * | 1998-03-30 | 2011-03-15 | E.I. Du Pont De Nemours And Company | Mixed polymerization catalyst component for polymerizing olefins |
JP2002509954A (ja) * | 1998-03-30 | 2002-04-02 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | オレフィンの重合 |
US6441117B1 (en) | 1999-09-01 | 2002-08-27 | E. I. Du Pont De Nemours And Company | High density polyethylene packaging |
WO2001023166A1 (en) * | 1999-09-29 | 2001-04-05 | E.I. Du Pont De Nemours And Company | Improved processing polyethylenes |
AU7836300A (en) * | 1999-09-29 | 2001-04-30 | E.I. Du Pont De Nemours And Company | Polymerization of olefins with bimetallic polymerisation catalyst system |
CA2381288A1 (en) † | 1999-09-29 | 2001-04-05 | Lin Wang | Preparation of curable polymers |
GB9923072D0 (en) * | 1999-09-29 | 1999-12-01 | Bp Chem Int Ltd | Polymerisation catalyst |
US6399535B1 (en) | 1999-11-01 | 2002-06-04 | W. R. Grace & Co.-Conn. | Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
US6559090B1 (en) | 1999-11-01 | 2003-05-06 | W. R. Grace & Co.-Conn. | Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
GB9928679D0 (en) * | 1999-12-03 | 2000-02-02 | Bp Chem Int Ltd | Polymerisation process |
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GB0003363D0 (en) * | 2000-02-14 | 2000-04-05 | Bp Chem Int Ltd | Polymer blends |
WO2002088200A1 (en) | 2001-04-30 | 2002-11-07 | W.R. Grace & Co.-Conn. | Supported dual transition metal catalyst systems |
US6943224B2 (en) | 2001-04-30 | 2005-09-13 | W. R. Grace & Co.-Conn. | Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby |
EP1453868A2 (en) | 2001-04-30 | 2004-09-08 | W. R. Grace & Co.-Conn | Coordination catalyst systems employing chromium support-agglomerate and method of their preparation |
KR100628620B1 (ko) | 2001-04-30 | 2006-09-26 | 더블유.알. 그레이스 앤드 캄파니-콘. | 이종 크롬 촉매 및 이를 사용하는 올레핀의 중합 방법 |
EP1401889B1 (en) | 2001-04-30 | 2010-06-09 | W.R. Grace & Co.-Conn. | Method of making supported transition metal polymerization catalysts and compositions formed therefrom |
BE1014196A3 (fr) | 2001-05-23 | 2003-06-03 | Solvay | Complexes catalytiques et leur utilisation pour la polymerisation des alpha-olefines. |
US6761965B2 (en) | 2001-11-06 | 2004-07-13 | Cryovac, Inc. | Irradiated multilayer film having seal layer containing hyperbranched polymer |
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DE10226522A1 (de) * | 2002-06-14 | 2003-12-24 | Degussa | Verwendung von Übergangsmetallkomplexen mit stickstoffhaltigen mehrzähnigen Liganden als Bleichkatalysator und Bleichmittelzusammensetzung |
EP1403288A1 (en) * | 2002-09-27 | 2004-03-31 | ATOFINA Research | Dual site catalyst system comprising a hafnocene component for the production of bimodal polyolefins |
EP1496069A1 (en) * | 2003-07-09 | 2005-01-12 | Total Petrochemicals Research Feluy | Polymerisation process |
US7081506B2 (en) * | 2003-10-23 | 2006-07-25 | Fina Technology, Inc. | Ethylene polymerization employing bis-imino pyridinyl transition metal catalyst components |
ATE464324T1 (de) * | 2004-02-13 | 2010-04-15 | Total Petrochemicals Res Feluy | Gelarme chrom-katalyse |
DE102004020525A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Katalysatorsystem zur Olefinpolymerisation, dessen Herstellung und Verwendung |
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EP1773895B1 (en) | 2004-07-09 | 2011-12-28 | E.I. Du Pont De Nemours And Company | Catalysts for olefin polymerization or oligomerization |
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BRPI0617253A2 (pt) * | 2005-10-14 | 2016-04-19 | Basell Polyolefine Gmbh | sistemas catalisadores híbridos suportados sobre halogeneto de magnésio |
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-
1999
- 1999-03-10 AT AT99907755T patent/ATE280185T1/de not_active IP Right Cessation
- 1999-03-10 CA CA002586497A patent/CA2586497A1/en not_active Abandoned
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- 1999-03-10 CA CA002323477A patent/CA2323477C/en not_active Expired - Fee Related
- 1999-03-10 DZ DZ990041A patent/DZ2740A1/xx active
- 1999-03-10 JP JP2000535678A patent/JP4606579B2/ja not_active Expired - Fee Related
- 1999-03-10 CN CN998058432A patent/CN1216079C/zh not_active Expired - Lifetime
- 1999-03-10 DE DE69921304T patent/DE69921304T2/de not_active Expired - Lifetime
- 1999-03-10 PT PT99907755T patent/PT1062249E/pt unknown
- 1999-03-10 ES ES99907755T patent/ES2229683T3/es not_active Expired - Lifetime
- 1999-03-10 MX MXPA00008941A patent/MXPA00008941A/es not_active IP Right Cessation
- 1999-03-10 AU AU27385/99A patent/AU2738599A/en not_active Abandoned
- 1999-03-10 WO PCT/GB1999/000714 patent/WO1999046302A1/en active IP Right Grant
- 1999-03-10 ID IDW20001753A patent/ID26574A/id unknown
- 1999-03-10 KR KR1020007010098A patent/KR100587757B1/ko not_active IP Right Cessation
- 1999-03-11 CO CO99015151A patent/CO5070721A1/es unknown
- 1999-03-11 AR ARP990101068A patent/AR018743A1/es not_active Application Discontinuation
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- 2000-09-11 US US09/659,589 patent/US6657026B1/en not_active Expired - Lifetime
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US20040077489A1 (en) | 2004-04-22 |
ATE280185T1 (de) | 2004-11-15 |
ES2229683T3 (es) | 2005-04-16 |
KR20010041816A (ko) | 2001-05-25 |
MXPA00008941A (es) | 2002-06-04 |
CA2323477A1 (en) | 1999-09-16 |
JP4606579B2 (ja) | 2011-01-05 |
EP1062249B1 (en) | 2004-10-20 |
WO1999046302A1 (en) | 1999-09-16 |
KR100587757B1 (ko) | 2006-06-09 |
CN1216079C (zh) | 2005-08-24 |
ID26574A (id) | 2001-01-18 |
CA2586497A1 (en) | 1999-09-16 |
US20070078249A1 (en) | 2007-04-05 |
CO5070721A1 (es) | 2001-08-28 |
US6657026B1 (en) | 2003-12-02 |
JP5574875B2 (ja) | 2014-08-20 |
US7148304B2 (en) | 2006-12-12 |
EP1062249A1 (en) | 2000-12-27 |
DE69921304T2 (de) | 2005-02-24 |
PT1062249E (pt) | 2004-12-31 |
US7345129B2 (en) | 2008-03-18 |
DZ2740A1 (fr) | 2003-09-08 |
JP2010280897A (ja) | 2010-12-16 |
AU2738599A (en) | 1999-09-27 |
CN1299377A (zh) | 2001-06-13 |
JP2002506090A (ja) | 2002-02-26 |
CA2323477C (en) | 2007-09-25 |
DE69921304D1 (de) | 2004-11-25 |
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