AR016450A1 - Proceso para la preparacion de compuestos 2-aril-5-(perfluoroalquil)pirrol, y compuestos de n-(arilmetilen)-1-cloro-1-(perfluoroalquil)metilamina - Google Patents

Proceso para la preparacion de compuestos 2-aril-5-(perfluoroalquil)pirrol, y compuestos de n-(arilmetilen)-1-cloro-1-(perfluoroalquil)metilamina

Info

Publication number
AR016450A1
AR016450A1 ARP990100536A ARP990100536A AR016450A1 AR 016450 A1 AR016450 A1 AR 016450A1 AR P990100536 A ARP990100536 A AR P990100536A AR P990100536 A ARP990100536 A AR P990100536A AR 016450 A1 AR016450 A1 AR 016450A1
Authority
AR
Argentina
Prior art keywords
compounds
hydrogen
perfluoroalkyl
halogen
perfluoroalquil
Prior art date
Application number
ARP990100536A
Other languages
English (en)
Original Assignee
American Cyanamid Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Publication of AR016450A1 publication Critical patent/AR016450A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
    • C07C251/24—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pyrrole Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Proceso para la preparacion de compuestos 2-aril-5-(perfluoroalquil)pirrol de formula (I), en la cual W es hidrogeno o CmF2m+1; Y es CN, NO2 o CO2R; R esalquilo C1-4; cada uno de m y n es independientemente un entero entre 1-8; A se selecciona delgr upo (V); L es hidrogeno o halogeno; cada uno de M y Q esindependientemente hidrogeno, halogeno, CN, NO2, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, haloalcoxi C1-4, alquiltio C1-4, haloalquiltio C1-4,alquilsulfinilo C1-4, haloalquilsulfinilo C1-4, alquilsulfonilo C1-4, haloalquilsulfonilo C1-4; o, cuando M y Q están en posiciones adyacentes, se pueden tomarjunto con los átomos de C a los cuales están unidos para formar un anillo en el cual MQ representa la estructura -OCH2O-, -OCF2O- o -CH=CH- CH=CH-; R1, R2 y R3son, independientemente, hidrogeno, halogeno, NO2, CHO o R2 y R3 pueden ser tomados junto con los átomos a los cuales están unidos para formar un anillo en elcual R2R3 está representado por la estructura (VI); cada uno deR4, R5, R 6 y R7 es independientemente hidrogeno, halogeno, CN o NO2 y X es O o S; que consisteen hacer reaccionar un compuesto N-(arilmetilen)-1-cloro-1-(perfluoroalquil)metilamina que tiene la formula estructural (II), en la cual A y n son comosedescribiera n anteriormente, con un compuesto dienofilo que tiene la formula estructural (III) o un compuesto alfa,beta-dihalo que tiene la formula estructural(IV), donde W y Y son como se describieran anteriormente y Z es Cl, Br o I, y una baseen presencia de un solvente; y compuestos de N-(arilmetilen)-1-cloro-1-(perfluoroalquil)metilamina que sirven como intermediarios en la preparacion de los compuestos arilpirrol. Los compuestos 2-aril-5-(perfluoroalquil)pirrol sonutiles para combatirplagas de insect os y ácaros, y también se pueden utilizar para preparar otros compuestos pesticidas de arilpirrol.
ARP990100536A 1998-02-09 1999-02-08 Proceso para la preparacion de compuestos 2-aril-5-(perfluoroalquil)pirrol, y compuestos de n-(arilmetilen)-1-cloro-1-(perfluoroalquil)metilamina AR016450A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2061198A 1998-02-09 1998-02-09

Publications (1)

Publication Number Publication Date
AR016450A1 true AR016450A1 (es) 2001-07-04

Family

ID=21799597

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP990100536A AR016450A1 (es) 1998-02-09 1999-02-08 Proceso para la preparacion de compuestos 2-aril-5-(perfluoroalquil)pirrol, y compuestos de n-(arilmetilen)-1-cloro-1-(perfluoroalquil)metilamina

Country Status (15)

Country Link
EP (1) EP0934929B1 (es)
JP (1) JP4494544B2 (es)
KR (1) KR19990072371A (es)
CN (1) CN1238330A (es)
AR (1) AR016450A1 (es)
AT (1) ATE250029T1 (es)
AU (1) AU743107B2 (es)
BR (1) BR9900545A (es)
CA (1) CA2260735A1 (es)
CZ (1) CZ35999A3 (es)
DE (1) DE69911274T2 (es)
HU (1) HUP9900272A1 (es)
IL (1) IL128343A0 (es)
SK (1) SK14899A3 (es)
ZA (1) ZA99941B (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL134856A0 (en) * 1999-03-09 2001-05-20 American Cyanamid Co Process for the preparation of 2-aryl-5-(perfluoroalkyl)pyrrole compounds from n-[1-chloro-1-(perfluoroalkyl) methyl]arylimidoyl choride compounds
US6320059B1 (en) 2000-03-07 2001-11-20 American Cyanamid Company Process for the preparation of 2-aryl-5-(perfluoro-alkyl) pyrrole compounds from N-[1-chloro-1-(perfluoroalkyl) methyl] arylimidoyl chloride compounds
WO2018166819A1 (en) * 2017-03-13 2018-09-20 BASF Agro B.V. Production of arylpyrrol compounds in the presence of dipea base

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5145986A (en) * 1991-09-09 1992-09-08 American Cyanamid Company Process for the manufacture of insecticidal, nematicidal and acaricidal 2-aryl-3-substituted-5-(trifluoromethyl)pyrrole compounds from N-(substituted benzyl)-2,2,2-trifluoro-acetimidoyl chloride compounds

Also Published As

Publication number Publication date
EP0934929B1 (en) 2003-09-17
HUP9900272A1 (hu) 2000-03-28
ZA99941B (en) 2000-08-07
DE69911274T2 (de) 2004-06-24
KR19990072371A (ko) 1999-09-27
AU743107B2 (en) 2002-01-17
HU9900272D0 (en) 1999-04-28
JP4494544B2 (ja) 2010-06-30
AU1547999A (en) 1999-08-26
ATE250029T1 (de) 2003-10-15
DE69911274D1 (de) 2003-10-23
JPH11269144A (ja) 1999-10-05
BR9900545A (pt) 2000-05-09
IL128343A0 (en) 2000-01-31
CN1238330A (zh) 1999-12-15
CA2260735A1 (en) 1999-08-09
CZ35999A3 (cs) 1999-09-15
SK14899A3 (en) 2000-03-13
EP0934929A1 (en) 1999-08-11

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