ZA924016B - Processes for removing,separating and concentrating rhodium,iridium and ruthenium from solutions using macrocyclic and nonmacrocyclic polyalkylene-plyamine-containing ligands bonded to inorganic supports - Google Patents
Processes for removing,separating and concentrating rhodium,iridium and ruthenium from solutions using macrocyclic and nonmacrocyclic polyalkylene-plyamine-containing ligands bonded to inorganic supportsInfo
- Publication number
- ZA924016B ZA924016B ZA924016A ZA924016A ZA924016B ZA 924016 B ZA924016 B ZA 924016B ZA 924016 A ZA924016 A ZA 924016A ZA 924016 A ZA924016 A ZA 924016A ZA 924016 B ZA924016 B ZA 924016B
- Authority
- ZA
- South Africa
- Prior art keywords
- compound
- polyalkylene
- affinity
- contact
- ligand portion
- Prior art date
Links
- 239000003446 ligand Substances 0.000 title abstract 7
- 229910052741 iridium Inorganic materials 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 4
- 229910052703 rhodium Inorganic materials 0.000 title abstract 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 title 1
- 239000010948 rhodium Substances 0.000 title 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 title 1
- 229910052707 ruthenium Inorganic materials 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 7
- 150000002500 ions Chemical class 0.000 abstract 2
- 229920000768 polyamine Polymers 0.000 abstract 2
- 125000006850 spacer group Chemical group 0.000 abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 229910003480 inorganic solid Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 238000007670 refining Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B01J20/262—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3092—Packing of a container, e.g. packing a cartridge or column
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
- B01J20/3204—Inorganic carriers, supports or substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
- B01J20/3217—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
- B01J20/3217—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond
- B01J20/3219—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond involving a particular spacer or linking group, e.g. for attaching an active group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
- B01J20/3244—Non-macromolecular compounds
- B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
- B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
- B01J20/3244—Non-macromolecular compounds
- B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
- B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
- B01J20/3259—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulfur with at least one silicon atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
- B01J20/3244—Non-macromolecular compounds
- B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
- B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
- B01J20/3263—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such comprising a cyclic structure containing at least one of the heteroatoms nitrogen, oxygen or sulfur, e.g. an heterocyclic or heteroaromatic structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
- B01J20/3268—Macromolecular compounds
- B01J20/3272—Polymers obtained by reactions otherwise than involving only carbon to carbon unsaturated bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/20—Anion exchangers for chromatographic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
- B01J2220/58—Use in a single column
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Chemically Coating (AREA)
- Catalysts (AREA)
- Pens And Brushes (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Particle Accelerators (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/709,378 US5120443A (en) | 1991-06-03 | 1991-06-03 | Processes for removing, separating and concentrating rhodium, iridium, and ruthenium from solutions using macrocyclic and nonmacrocyclic polyalkylene-polyamine-containing ligands bonded to inorganic supports |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA924016B true ZA924016B (en) | 1993-02-24 |
Family
ID=24849622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA924016A ZA924016B (en) | 1991-06-03 | 1992-06-02 | Processes for removing,separating and concentrating rhodium,iridium and ruthenium from solutions using macrocyclic and nonmacrocyclic polyalkylene-plyamine-containing ligands bonded to inorganic supports |
Country Status (16)
Country | Link |
---|---|
US (1) | US5120443A (el) |
EP (1) | EP0588941B1 (el) |
JP (1) | JPH06508338A (el) |
AT (1) | ATE149860T1 (el) |
BR (1) | BR9206085A (el) |
CA (1) | CA2103144A1 (el) |
DE (1) | DE69218201T2 (el) |
DK (1) | DK0588941T3 (el) |
ES (1) | ES2101852T3 (el) |
FI (1) | FI935405A0 (el) |
GR (1) | GR3023454T3 (el) |
NO (1) | NO306701B1 (el) |
RU (1) | RU2095314C1 (el) |
TW (1) | TW267948B (el) |
WO (1) | WO1992021419A1 (el) |
ZA (1) | ZA924016B (el) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5501767A (en) * | 1992-11-13 | 1996-03-26 | Micron Technology, Inc. | Method for gettering noble metals from mineral acid solution |
US5441643A (en) * | 1993-11-29 | 1995-08-15 | The United States Of America As Represented By The Secretary Of The Interior | Process for recovering metals from solution utilizing metalloprotein affinity chromatography |
JP3808500B2 (ja) * | 1994-02-22 | 2006-08-09 | キューレータズ オブ ディ ユニバーシティ オブ ミズーリ | 分離剤としての大環状抗生物質 |
US5547760A (en) * | 1994-04-26 | 1996-08-20 | Ibc Advanced Technologies, Inc. | Compositions and processes for separating and concentrating certain ions from mixed ion solutions using ion-binding ligands bonded to membranes |
AUPM632894A0 (en) * | 1994-06-21 | 1994-07-14 | Alldredge, Robert Louis | Immobilised branched polyalkyleneimines |
US5612275A (en) * | 1994-09-27 | 1997-03-18 | Syracuse University | Chemically active ceramic compositions with a phospho-acid moiety |
US5616533A (en) * | 1994-09-27 | 1997-04-01 | Syracuse University | Chemically active ceramic compositions with a thiol and/or amine moiety |
US5624881A (en) * | 1994-09-27 | 1997-04-29 | Syracuse University | Chemically active ceramic compositions with a pyrogallol moiety |
US5668079A (en) * | 1994-09-27 | 1997-09-16 | Syracuse University | Chemically active ceramic compositions with an hydroxyquinoline moiety |
FR2725382B1 (fr) * | 1994-10-05 | 1997-01-03 | Commissariat Energie Atomique | Polyazacycloalcanes, complexes tri-, tetra- ou pentaazamacrocycliques, procede de fabrication de ces polyazacycloalcanes substitues ou non et greffes sur un support et utilisations des polyazacycloalcanes |
WO1996029146A1 (en) | 1995-03-22 | 1996-09-26 | Minnesota Mining And Manufacturing Company | Solid phase extraction membrane |
AU731142B2 (en) * | 1996-06-24 | 2001-03-22 | Ibc Advanced Technologies, Inc. | Poly N-cyclic aromatic ligands bonded to solid supports for removing and concentrating ions from solutions |
US6106723A (en) * | 1997-02-10 | 2000-08-22 | Grandics; Peter | Method for removing pyrogens from dialysate |
FR2774092B1 (fr) * | 1998-01-26 | 2000-02-18 | Air Liquide | Procede de preparation de polyazacycloalcanes greffes sur gel de silice et utilisation des composes greffes |
FR2774093B1 (fr) * | 1998-01-26 | 2000-03-17 | Air Liquide | Nouveau gel de silice incorporant des motifs polyazacycloalcanes, procede de preparation et utilisation |
US6339039B1 (en) | 1998-06-12 | 2002-01-15 | Jerker Porath | Hydrogel product for adsorption purposes |
SE512234C2 (sv) * | 1998-06-12 | 2000-02-14 | Jerker Porath | Hydrogelprodukt för adsorptionsändamål bestående av en vattenolöslig stödmatris som är tvärbunden med polymerer |
US6232265B1 (en) * | 1999-06-11 | 2001-05-15 | Ibc Advanced Technologies, Inc. | Particulate solid supports functionalized with polyhydroxypyridinone ligands |
FR2796645B1 (fr) * | 1999-07-23 | 2001-09-14 | Air Liquide | Nouveau gel de silice incorporant des motifs polyazacycloalcanes comportant plus de six atomes d'azote, procede de preparation et utilisation |
GB0210099D0 (en) * | 2002-05-02 | 2002-06-12 | Anglo Platinum Ltd | Separation of metals |
JP4144311B2 (ja) * | 2002-10-08 | 2008-09-03 | 住友金属鉱山株式会社 | 白金族元素の分離回収方法 |
EP1847553B1 (en) * | 2004-12-28 | 2014-10-08 | Nippon Soda Co., Ltd. | Method for removing metal and method for producing polymer |
EP1922422A4 (en) * | 2005-04-13 | 2009-05-27 | Metals Recovery Technology Inc | METHOD FOR OBTAINING PLATING GROUT METALS, RHENIUM AND GOLD |
US7604784B2 (en) * | 2005-06-24 | 2009-10-20 | Metals Recovery Technology Inc. | Process for the extraction of specific transition metals with gaseous HCL |
KR20140014217A (ko) | 2011-03-10 | 2014-02-05 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 여과 매체 |
US9610576B2 (en) * | 2012-09-27 | 2017-04-04 | Agilent Technologies, Inc. | Hydrolytically stable ion-exchange stationary phases and uses thereof |
CN103554185A (zh) * | 2013-07-04 | 2014-02-05 | 上海工程技术大学 | 一类大环多胺类多齿配体及其合成方法 |
DE102014012566A1 (de) * | 2014-08-29 | 2016-03-03 | Instraction Gmbh | Sorbens zur Bindung von Metallen und dessen Herstellung |
RU2703011C1 (ru) * | 2019-04-30 | 2019-10-15 | Публичное акционерное общество "Горно-металлургическая компания "Норильский никель" | Способ селективного извлечения ионов платины из хлоридных растворов |
RU2742994C1 (ru) * | 2020-06-09 | 2021-02-12 | Игорь Владимирович Федосеев | Способ селективного выделения родия Rh, рутения Ru и иридия Ir из солянокислых растворов хлорокомплексов платины Pt(IV), палладия Pd(II), золота Au(III), серебра Ag(I), родия Rh(III), рутения Ru(IV) и иридия Ir(IV) |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2283101A1 (fr) * | 1974-08-30 | 1976-03-26 | Rhone Poulenc Ind | Supports mineraux modifies |
ZA763681B (en) * | 1976-06-21 | 1978-02-22 | Nat Inst Metallurg | The recovery and purification of iridium |
ZA763680B (en) * | 1976-06-21 | 1978-02-22 | Nat Inst Metallurg | The separation and purification of ruthenium |
ZA801718B (en) * | 1979-03-27 | 1981-10-28 | British Petroleum Co | Functionalised inorganic oxide products and their use in the removal of heavy metals,transistion metals and actinidemetals from solution |
US4560704A (en) * | 1982-11-12 | 1985-12-24 | Purdue Research Foundation | Polyamine based bonded phase chromatography |
US4943375A (en) * | 1987-09-04 | 1990-07-24 | Brigham Young University | The process of separating a selected ion from a plurality of other ions in a multiple ion solution by contacting the solution with a macrocyclic ligand bonded to silica which selectively complexes with the desired ion |
JPH01215726A (ja) * | 1988-02-24 | 1989-08-29 | Sumitomo Chem Co Ltd | ルテニウムの回収方法 |
US4952321A (en) * | 1988-10-07 | 1990-08-28 | Brigham Young University | Process of removing and concentrating desired ions from solutions |
AU646889B2 (en) * | 1990-10-10 | 1994-03-10 | Brigham Young University | Polytetraalkylammonium and polytrialkylamine containing ligands bonded to inorganic supports and processes of using the same for removing and concentrating desired ions from solution |
-
1991
- 1991-06-03 US US07/709,378 patent/US5120443A/en not_active Expired - Lifetime
-
1992
- 1992-06-02 JP JP5500607A patent/JPH06508338A/ja active Pending
- 1992-06-02 AT AT92913706T patent/ATE149860T1/de not_active IP Right Cessation
- 1992-06-02 ES ES92913706T patent/ES2101852T3/es not_active Expired - Lifetime
- 1992-06-02 ZA ZA924016A patent/ZA924016B/xx unknown
- 1992-06-02 WO PCT/US1992/004586 patent/WO1992021419A1/en active IP Right Grant
- 1992-06-02 DK DK92913706.5T patent/DK0588941T3/da active
- 1992-06-02 EP EP92913706A patent/EP0588941B1/en not_active Expired - Lifetime
- 1992-06-02 CA CA002103144A patent/CA2103144A1/en not_active Abandoned
- 1992-06-02 RU RU9693058601A patent/RU2095314C1/ru active
- 1992-06-02 BR BR9206085A patent/BR9206085A/pt not_active Application Discontinuation
- 1992-06-02 TW TW081104359A patent/TW267948B/zh active
- 1992-06-02 DE DE69218201T patent/DE69218201T2/de not_active Expired - Fee Related
-
1993
- 1993-12-01 NO NO934365A patent/NO306701B1/no unknown
- 1993-12-02 FI FI935405A patent/FI935405A0/fi unknown
-
1997
- 1997-05-16 GR GR970401103T patent/GR3023454T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
ES2101852T3 (es) | 1997-07-16 |
TW267948B (el) | 1996-01-11 |
EP0588941A4 (en) | 1994-08-10 |
JPH06508338A (ja) | 1994-09-22 |
FI935405A (fi) | 1993-12-02 |
EP0588941A1 (en) | 1994-03-30 |
NO306701B1 (no) | 1999-12-13 |
EP0588941B1 (en) | 1997-03-12 |
DE69218201T2 (de) | 1997-06-26 |
ATE149860T1 (de) | 1997-03-15 |
GR3023454T3 (en) | 1997-08-29 |
NO934365D0 (no) | 1993-12-01 |
NO934365L (no) | 1994-02-01 |
CA2103144A1 (en) | 1992-12-04 |
WO1992021419A1 (en) | 1992-12-10 |
RU2095314C1 (ru) | 1997-11-10 |
US5120443A (en) | 1992-06-09 |
FI935405A0 (fi) | 1993-12-02 |
BR9206085A (pt) | 1994-11-08 |
DE69218201D1 (de) | 1997-04-17 |
DK0588941T3 (da) | 1997-09-22 |
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