ZA201401358B - Method for producing formamides and formic acid esters - Google Patents

Method for producing formamides and formic acid esters

Info

Publication number
ZA201401358B
ZA201401358B ZA2014/01358A ZA201401358A ZA201401358B ZA 201401358 B ZA201401358 B ZA 201401358B ZA 2014/01358 A ZA2014/01358 A ZA 2014/01358A ZA 201401358 A ZA201401358 A ZA 201401358A ZA 201401358 B ZA201401358 B ZA 201401358B
Authority
ZA
South Africa
Prior art keywords
formamides
producing
acid esters
formic acid
formic
Prior art date
Application number
ZA2014/01358A
Other languages
English (en)
Inventor
Rocco Paciello
Thomas Schaub
Debora Preti
Giuseppe Fachinetti
Marek Pazicky
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of ZA201401358B publication Critical patent/ZA201401358B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B01J31/0238—Amines with a primary amino group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/10—Preparation of carboxylic acid amides from compounds not provided for in groups C07C231/02 - C07C231/08
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
ZA2014/01358A 2011-07-27 2014-02-24 Method for producing formamides and formic acid esters ZA201401358B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11175625 2011-07-27
PCT/EP2012/064508 WO2013014160A1 (fr) 2011-07-27 2012-07-24 Procédé permettant de fabriquer des foramides et des esters d'acide formique

Publications (1)

Publication Number Publication Date
ZA201401358B true ZA201401358B (en) 2015-12-23

Family

ID=46548496

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA2014/01358A ZA201401358B (en) 2011-07-27 2014-02-24 Method for producing formamides and formic acid esters

Country Status (9)

Country Link
EP (1) EP2736872A1 (fr)
JP (1) JP2014523448A (fr)
KR (1) KR20140044871A (fr)
CN (1) CN103702968A (fr)
BR (1) BR112014001571A2 (fr)
CA (1) CA2837793A1 (fr)
RU (1) RU2014107102A (fr)
WO (1) WO2013014160A1 (fr)
ZA (1) ZA201401358B (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015121357A1 (fr) * 2014-02-17 2015-08-20 Bayer Technology Services Gmbh Procédé d'hydrogénation du dioxyde de carbone en formamides
WO2015192282A1 (fr) * 2014-06-16 2015-12-23 Rhodia Operations Processus de formylation pour la préparation de formamides aromatiques
CN105373135B (zh) * 2014-08-01 2019-01-01 深圳中集天达空港设备有限公司 一种基于机器视觉的飞机入坞引导和机型识别的方法及系统
CN105985254B (zh) * 2015-02-17 2018-03-16 上海中科绿碳化工科技有限公司 一种制备甲酰胺类化合物的方法
US10435349B2 (en) * 2017-08-02 2019-10-08 Eastman Chemical Company Iron-catalyzed cross-coupling of methanol with secondary or tertiary alcohols to produce formate esters
CN107915653B (zh) * 2017-12-04 2020-02-14 苏州大学 催化酯和胺进行反应制备酰胺的方法
CN108623493B (zh) * 2018-06-20 2021-01-19 大连理工大学 一种温和条件下以co2为碳源的n-甲酰化合成方法
DE102019111058A1 (de) * 2019-04-29 2020-10-29 Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen Verfahren zur katalytischen Herstellung von Harnstoff
CN113979882A (zh) * 2021-11-29 2022-01-28 宿迁新亚科技有限公司 一种制备二丁基甲酰胺的生产工艺

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51138614A (en) * 1975-05-27 1976-11-30 Mitsubishi Gas Chem Co Inc Process for preparation of formic acid and its este r
US4269998A (en) 1980-02-19 1981-05-26 Uop Inc. Production of dialkyl formamide
DK0652202T3 (da) * 1993-11-04 1997-12-22 Japan Res Dev Corp Fremgangsmåde til fremstilling af myresyre eller derivater deraf
JP2962649B2 (ja) * 1994-06-07 1999-10-12 科学技術振興事業団 ホルムアミド誘導体の製造方法
JP2927677B2 (ja) * 1994-06-07 1999-07-28 科学技術振興事業団 ギ酸エステル化合物の製造方法
JP2005246261A (ja) * 2004-03-04 2005-09-15 Nippon Steel Corp ギ酸エステル及びメタノール合成用触媒とギ酸エステル及びメタノールの製造方法
JP5264084B2 (ja) * 2006-02-17 2013-08-14 新日鐵住金株式会社 メタノール合成用触媒及び当該触媒の製造方法、並びにメタノールの製造方法
JP5264083B2 (ja) * 2006-02-17 2013-08-14 新日鐵住金株式会社 メタノール合成用触媒及び当該触媒の製造方法、並びにメタノールの製造方法
JP4963112B2 (ja) * 2008-03-12 2012-06-27 新日本製鐵株式会社 メタノール合成用触媒の製造方法、及びメタノールの製造方法

Also Published As

Publication number Publication date
JP2014523448A (ja) 2014-09-11
BR112014001571A2 (pt) 2017-02-21
KR20140044871A (ko) 2014-04-15
CA2837793A1 (fr) 2013-01-31
WO2013014160A1 (fr) 2013-01-31
RU2014107102A (ru) 2015-09-10
CN103702968A (zh) 2014-04-02
EP2736872A1 (fr) 2014-06-04

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