ZA200806012B - Device for collecting gases in molten metals and measurement method - Google Patents
Device for collecting gases in molten metals and measurement method Download PDFInfo
- Publication number
- ZA200806012B ZA200806012B ZA200806012A ZA200806012A ZA200806012B ZA 200806012 B ZA200806012 B ZA 200806012B ZA 200806012 A ZA200806012 A ZA 200806012A ZA 200806012 A ZA200806012 A ZA 200806012A ZA 200806012 B ZA200806012 B ZA 200806012B
- Authority
- ZA
- South Africa
- Prior art keywords
- gas
- gases
- collection body
- molten metal
- layer
- Prior art date
Links
- 239000007789 gas Substances 0.000 title claims description 182
- 229910052751 metal Inorganic materials 0.000 title claims description 57
- 239000002184 metal Substances 0.000 title claims description 57
- 150000002739 metals Chemical class 0.000 title claims description 14
- 238000000691 measurement method Methods 0.000 title description 6
- 239000012159 carrier gas Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 238000007654 immersion Methods 0.000 claims description 11
- 238000005259 measurement Methods 0.000 claims description 11
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
- 230000000149 penetrating effect Effects 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052786 argon Inorganic materials 0.000 claims description 3
- AYTAKQFHWFYBMA-UHFFFAOYSA-N chromium dioxide Chemical compound O=[Cr]=O AYTAKQFHWFYBMA-UHFFFAOYSA-N 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000011029 spinel Substances 0.000 claims description 3
- 229910052596 spinel Inorganic materials 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- 229940090961 chromium dioxide Drugs 0.000 claims description 2
- 238000011156 evaluation Methods 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 239000010955 niobium Substances 0.000 claims description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 238000007750 plasma spraying Methods 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 2
- 229940105305 carbon monoxide Drugs 0.000 claims 1
- 229910052574 oxide ceramic Inorganic materials 0.000 claims 1
- 239000011224 oxide ceramic Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 22
- 239000011796 hollow space material Substances 0.000 description 5
- 239000000155 melt Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 208000028659 discharge Diseases 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- IAQWMWUKBQPOIY-UHFFFAOYSA-N chromium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Cr+4] IAQWMWUKBQPOIY-UHFFFAOYSA-N 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/22—Devices for withdrawing samples in the gaseous state
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/20—Metals
- G01N33/202—Constituents thereof
- G01N33/2022—Non-metallic constituents
- G01N33/2025—Gaseous constituents
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/20—Metals
- G01N33/205—Metals in liquid state, e.g. molten metals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Pathology (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Immunology (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Molecular Biology (AREA)
- Biomedical Technology (AREA)
- Investigating And Analyzing Materials By Characteristic Methods (AREA)
- Sampling And Sample Adjustment (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007032436A DE102007032436B4 (de) | 2007-07-10 | 2007-07-10 | Vorrichtung zum Sammeln von Gasen in Metallschmelzen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200806012B true ZA200806012B (en) | 2009-07-29 |
Family
ID=39820904
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200806012A ZA200806012B (en) | 2007-07-10 | 2008-07-10 | Device for collecting gases in molten metals and measurement method |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US8104325B2 (fr) |
| EP (2) | EP2015049B1 (fr) |
| JP (3) | JP5295667B2 (fr) |
| KR (2) | KR101435687B1 (fr) |
| CN (1) | CN101344465B (fr) |
| AR (2) | AR067474A1 (fr) |
| AU (2) | AU2008202464B2 (fr) |
| BR (1) | BRPI0803059A2 (fr) |
| CA (2) | CA2634401C (fr) |
| CL (1) | CL2008001997A1 (fr) |
| DE (2) | DE102007063673B4 (fr) |
| ES (1) | ES2534344T3 (fr) |
| MX (2) | MX2008008912A (fr) |
| PL (1) | PL2015049T3 (fr) |
| PT (1) | PT2015049E (fr) |
| RU (1) | RU2478954C2 (fr) |
| TW (2) | TWI426967B (fr) |
| UA (2) | UA100493C2 (fr) |
| ZA (1) | ZA200806012B (fr) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007063673B4 (de) | 2007-07-10 | 2018-02-08 | Heraeus Electro-Nite International N.V. | Messverfahren |
| TWI384078B (zh) * | 2009-01-15 | 2013-02-01 | China Steel Corp | An adapter for the eddy current detection device |
| BRPI1103889B1 (pt) * | 2011-08-17 | 2020-09-24 | Ecil Met Tec Ltda | Sonda de imersão para análise de gases em metal fundido |
| DE102013224565A1 (de) * | 2013-04-30 | 2014-10-30 | Heraeus Electro-Nite International N.V. | Probennehmer und Verfahren zur Probenentnahme |
| EP3366683A1 (fr) | 2017-02-28 | 2018-08-29 | Acousia Therapeutics GmbH | Amides, acetamides et ureas cycliques pour ouvris les voies de calcium |
| EP3581913B1 (fr) | 2018-06-12 | 2023-06-07 | Heraeus Electro-Nite International N.V. | Échantillonneur de métal en fusion amélioré |
| PL3581914T3 (pl) | 2018-06-12 | 2023-09-18 | Heraeus Electro-Nite International N.V. | Próbniki stopionego metalu do zastosowań z wysoką i niską zawartością tlenu |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB821821A (en) * | 1954-08-10 | 1959-10-14 | British Aluminium Co Ltd | Improvements in the determination of the gas content of liquid metals |
| US3529459A (en) * | 1965-08-06 | 1970-09-22 | Atomic Power Dev Ass Inc | Continuous reading hydrogen meter |
| US3820380A (en) * | 1972-11-03 | 1974-06-28 | Nat Steel Corp | Sampling molten metal baths |
| US3886444A (en) * | 1974-02-07 | 1975-05-27 | Us Energy | Hydrogen detector for sodium cooled reactors |
| DE2423783A1 (de) | 1974-05-16 | 1975-12-04 | George R Fitterer | Tauchsonde fuer die bestimmung des geloesten sauerstoffgehalts von schmelzen |
| GB1510957A (en) * | 1975-05-07 | 1978-05-17 | National research development corp investigation of the gas content of molten metals | |
| US3950992A (en) * | 1975-08-27 | 1976-04-20 | Leeds & Northrup Company | Immersion sampler for molten metal |
| SU917065A1 (ru) * | 1980-04-16 | 1992-05-23 | Институт геохимии и аналитической химии им.В.И.Вернадского | Устройство дл определени газов в жидких металлах |
| SU1138728A1 (ru) * | 1982-03-19 | 1985-02-07 | Ордена Ленина Институт Геохимии И Аналитической Химии Им.В.И.Вернадского | Устройство дл определени содержани газов в металлах |
| GB2188417B (en) * | 1986-03-19 | 1990-02-21 | British Steel Corp | Molten metal gas analysis |
| SU1396755A1 (ru) * | 1986-07-24 | 1992-05-30 | Институт геохимии и аналитической химии им.В.И.Вернадского | Устройство дл определени содержани газообразующих элементов в жидких металлах |
| US4838336A (en) | 1987-02-24 | 1989-06-13 | Foseco International Limited | Hot metal sampling |
| EP0307430B1 (fr) | 1987-03-18 | 1992-01-29 | Heraeus Electro-Nite International N.V. | Appareil et procede de mesure de la teneur en gaz d'un metal liquide, et sonde utilisee a cet effet |
| CA1276235C (fr) | 1987-05-28 | 1990-11-13 | Ghyslain Dube | Sonde pour determiner la concentration de gaz dans des metaux en fusion |
| JPH02118242U (fr) * | 1989-03-07 | 1990-09-21 | ||
| SU1679272A1 (ru) * | 1989-07-11 | 1991-09-23 | Сибирский Металлургический Институт Им.Серно Орджоникидзе | Способ определени содержани водорода в жидкой стали в ковше |
| DE4135510C2 (de) * | 1991-10-28 | 1994-02-24 | Heraeus Electro Nite Int | Tauchsensor für Metallschmelzen |
| JP2523016Y2 (ja) * | 1992-03-13 | 1997-01-22 | 東京窯業株式会社 | 金属溶湯中の水素濃度測定用プローブ |
| DE4211041C2 (de) * | 1992-04-03 | 1994-12-22 | Heraeus Electro Nite Int | Verfahren zur Bestimmung der Konzentration eines Gases in einer Metallschmelze |
| JP3231154B2 (ja) * | 1993-09-03 | 2001-11-19 | 新日本製鐵株式会社 | 溶鋼中微量炭素の迅速測定方法及び装置 |
| CN1047444C (zh) * | 1993-09-03 | 1999-12-15 | 日本贺利氏电测骑士公司 | 测定钢水中碳、氢和氮浓度的方法和装置 |
| US5850034A (en) * | 1997-06-17 | 1998-12-15 | Asarco Incorporated | Making of metal products using a gas analyzer |
| US6216526B1 (en) | 1998-12-16 | 2001-04-17 | Midwest Instrument Co., Inc. | Gas sampler for molten metal and method |
| CN2575649Y (zh) * | 2002-11-04 | 2003-09-24 | 向知杰 | 铝熔体及铝合金熔体用高速、高稳定测氢探头 |
| US20070240488A1 (en) * | 2004-09-14 | 2007-10-18 | Kreuser Joseph J | Molten Metal Gas Sampling |
| DE102005011181A1 (de) * | 2005-03-09 | 2006-09-14 | Heraeus Electro-Nite International N.V. | Vorrichtung zum Messen des Gasgehaltes in einer Metallschmelze |
| DE102007063673B4 (de) | 2007-07-10 | 2018-02-08 | Heraeus Electro-Nite International N.V. | Messverfahren |
-
2007
- 2007-07-10 DE DE102007063673.5A patent/DE102007063673B4/de not_active Expired - Fee Related
- 2007-07-10 DE DE102007032436A patent/DE102007032436B4/de not_active Expired - Fee Related
-
2008
- 2008-06-03 TW TW097120612A patent/TWI426967B/zh not_active IP Right Cessation
- 2008-06-03 TW TW100144485A patent/TWI460035B/zh not_active IP Right Cessation
- 2008-06-03 AU AU2008202464A patent/AU2008202464B2/en not_active Ceased
- 2008-06-06 CA CA2634401A patent/CA2634401C/fr not_active Expired - Fee Related
- 2008-06-06 CA CA2776507A patent/CA2776507C/fr not_active Expired - Fee Related
- 2008-06-12 PL PL08010689T patent/PL2015049T3/pl unknown
- 2008-06-12 EP EP08010689.1A patent/EP2015049B1/fr active Active
- 2008-06-12 EP EP14171474.1A patent/EP2775285B1/fr active Active
- 2008-06-12 PT PT80106891T patent/PT2015049E/pt unknown
- 2008-06-12 ES ES08010689.1T patent/ES2534344T3/es active Active
- 2008-07-07 AR ARP080102935A patent/AR067474A1/es active IP Right Grant
- 2008-07-07 CL CL2008001997A patent/CL2008001997A1/es unknown
- 2008-07-07 KR KR1020080065376A patent/KR101435687B1/ko active IP Right Grant
- 2008-07-09 UA UAA200809013A patent/UA100493C2/ru unknown
- 2008-07-09 BR BRPI0803059-6A patent/BRPI0803059A2/pt not_active Application Discontinuation
- 2008-07-09 UA UAA201200096A patent/UA102314C2/ru unknown
- 2008-07-09 RU RU2008128217/15A patent/RU2478954C2/ru active
- 2008-07-09 JP JP2008179271A patent/JP5295667B2/ja not_active Expired - Fee Related
- 2008-07-09 US US12/169,692 patent/US8104325B2/en not_active Expired - Fee Related
- 2008-07-10 ZA ZA200806012A patent/ZA200806012B/en unknown
- 2008-07-10 CN CN2008101305887A patent/CN101344465B/zh active Active
- 2008-07-10 MX MX2008008912A patent/MX2008008912A/es active IP Right Grant
-
2010
- 2010-08-04 AU AU2010206115A patent/AU2010206115B9/en not_active Ceased
-
2011
- 2011-10-07 MX MX2011010592A patent/MX2011010592A/es active IP Right Grant
- 2011-12-13 US US13/324,030 patent/US8671735B2/en active Active
-
2012
- 2012-10-03 JP JP2012221747A patent/JP5843737B2/ja not_active Expired - Fee Related
-
2013
- 2013-04-03 JP JP2013077851A patent/JP2013137328A/ja active Pending
-
2014
- 2014-06-10 KR KR1020140070001A patent/KR20140093646A/ko not_active Application Discontinuation
-
2015
- 2015-06-15 AR ARP150101902A patent/AR100845A2/es unknown
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