ZA200401100B - Arc furnace and method for operating this arc furnace. - Google Patents

Arc furnace and method for operating this arc furnace. Download PDF

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Publication number
ZA200401100B
ZA200401100B ZA200401100A ZA200401100A ZA200401100B ZA 200401100 B ZA200401100 B ZA 200401100B ZA 200401100 A ZA200401100 A ZA 200401100A ZA 200401100 A ZA200401100 A ZA 200401100A ZA 200401100 B ZA200401100 B ZA 200401100B
Authority
ZA
South Africa
Prior art keywords
bay
fact
tapping
taphole
arc furnace
Prior art date
Application number
ZA200401100A
Inventor
Peter Heinrich
Manfred Schubert
Original Assignee
Sms Demag Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sms Demag Ag filed Critical Sms Demag Ag
Publication of ZA200401100B publication Critical patent/ZA200401100B/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B3/00Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces
    • F27B3/10Details, accessories, or equipment peculiar to hearth-type furnaces
    • F27B3/19Arrangements of devices for discharging
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/52Manufacture of steel in electric furnaces
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/52Manufacture of steel in electric furnaces
    • C21C5/5211Manufacture of steel in electric furnaces in an alternating current [AC] electric arc furnace
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B3/00Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces
    • F27B3/08Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces heated electrically, with or without any other source of heat
    • F27B3/085Arc furnaces
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B3/00Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces
    • F27B3/06Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces with movable working chambers or hearths, e.g. tiltable, oscillating or describing a composed movement
    • F27B3/065Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces with movable working chambers or hearths, e.g. tiltable, oscillating or describing a composed movement tiltable
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/15Tapping equipment; Equipment for removing or retaining slag
    • F27D3/1509Tapping equipment
    • F27D3/1527Taphole forming equipment, e.g. boring machines, piercing tools
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/15Tapping equipment; Equipment for removing or retaining slag
    • F27D3/1509Tapping equipment
    • F27D3/1536Devices for plugging tap holes, e.g. plugs stoppers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Vertical, Hearth, Or Arc Furnaces (AREA)
  • Furnace Charging Or Discharging (AREA)

Description

TRANSLATION (HM-565PCT-original)
PCT/EP02/09, 794
ARC FURNACE WITH BUILT-ON BAY FOR TAPPING THE MELT
AND METHOD OF OPERATING THIS ARC FURNACE
The invention concerns an arc furnace, which can be tilted or remains stationary for tapping the melt or the slag and has an eccentric and/or centric tap, and a method of operating this arc furnace.
The melt can be tapped on the basis of various well-known designs of the arc furnace: Tapping can be accomplished with an open tapping spout by tilting. Tapping can also be accomplished by a tapping spout with a connected siphon. In arc furnaces of the designated designs, eccentric bottom tapping in a vessel bay (EBT) is well known (DE 82 31 869.7 Ul and DE 198 26 085 Al).
Eccentric tapping of this type is also used in an oval vessel (OBT). In addition, centric bottom tapping (CBT) is used in circular vessels.
Although some of these designs have proven effective, bottom tapping can be further improved to meet operational needs.
The objective of the invention is to improve production, in-service performance, and the operating sequence.
In accordance with the invention, this objective is achieved by providing the tap in a separately mounted bay, which abuts a terminal wall of a lower vessel, and by providing at least one tapping channel that passes through the terminal wall to connect the furnace shell and the bay. These design modifications result in more cost-effective production, especially if the vessel is, for example, circular or oval. The terminal wall can be continuously formed in the region of the bay, which results in greater dimensional stability and improved mounting of the refractory lining. The separately mounted bay means high operational flexibility, because this makes a bay of this type interchangeable. An exchange of the nozzle bricks does not have to be carried out in the hot region of the furnace. The tapping channels are readily accessible from the bay. In individual cases, it is possible to dispense with a bay cover. The provision of a taphole valve or a taphole door is not absolutely necessary and can be limited to special cases.
In addition, savings of lining material are achieved.
In an especially advantageous refinement, the bay can be connected to the terminal wall of the lower vessel by a flange joint. Such a flange joint may even be designed as a door that can be swung open.
To achieve thorough emptying of the lower vessel, it is then advantageous in accordance with other features of the invention for one or more siphon-like tapping channels to run through the terminal wall more or less tangent to the lining profile.
In this regard, in accordance with additional features of the invention, the tap is arranged in such a way that the taphole of the tap in the bay runs vertically in the zero position, i.e., the horizontal position, of the arc furnace.
Alternatively, the taphole may be designed with an angle adapted to the tapping angle of the tiltable furnace.
A method of operating an arc furnace, which is tilted in one swivel direction to tap the melt and in the other swivel direction to tap the slag, such that the melt is tapped eccentrically to the lower vessel, can be carried out in such a way that first the tapping channels are burned out in the lower vessel from the bay side, and, when the melt flows into the bay,
the tilting operation is initiated; in that the bay is then sufficiently filled, and the taphole is opened (from the outside); and in that, when the desired amount of melt has been tapped, the arc furnace is tilted back into the zero position or beyond it. This results in a more advantageous operation due to simpler operating sequences.
Another step is alternatively designed in such a way that first the tapping channels are burned out in the lower vessel from the bay side, and, when the melt flows into the bay through the unclosed taphole, the tilting operation is initiated. This eliminates the need to close the taphole.
In a refinement of the method, in an additional sequence of steps, after the zero position has been reached, the tapping channel and/or the taphole is cleaned and closed with refractory material.
In an alternative embodiment, after a suitably long operating time, for relining purposes, the flange joint is disconnected, and the bay is removed and replaced by a relined bay.
It is also advantageous to add necessary fluxes and alloys or portions of the required amounts of these additives to the bay during the tapping.
An alternative method of operating an arc furnace, which is tilted in one swivel direction to tap the melt, such that the melt is tapped eccentrically to the lower vessel, consists in controlling the tapping rate by controlling the gas pressure in the bay by pressurization of the pressure-tight and vacuum-tight covered bay with inert gas. During this process, the taphole of the tiltable furnace must not be closed. The siphoning effect that develops during ongoing tapping, depending on the length of the tapping channel between the hearth and the bay, and that manifests itself in a negative pressure in the bay above the bath level, can be influenced by controlling the gas pressure.
Another alternative embodiment of the invention in an arc furnace with a closable taphole, whose lower vessel is stationary and has a bottom taphole, is designed in such a way that the tap is provided in a separately mounted, pressure-tight and vacuum-tight bay, which abuts a terminal wall of the lower vessel, and that at least one tapping channel that passes through the terminal wall to connect the furnace shell and the bay is provided, such that the lower edge of the tapping channel on the bay side and the upper edge of the bay taphole are at about the same level. In this case, the arc furnace no longer needs to be tiltable, which means that the entire tilting mechanism is eliminated. In addition, the operating sequences and the in-service performance change.
The necessary gas space in the bay is created by providing the bay with a pressure-tight and vacuum-tight cover.
In addition, the bay taphole can be maintained, despite the cover, by mounting a hollow plug in a hollow plug housing on the pressure-tight and vacuum-tight cover. The housing can be disconnected or connected and opened or closed by a sluice.
Other design refinements arise from the connection of a gas supply line with a gas valve to the pressure-tight and vacuum- tight cover.
The aforementioned alternative with a stationary arc furnace can be regarded as the basis for a method of operating an arc furnace that is stationary, has a bay built onto a lower furnace, and is provided with a bay taphole and with a centric bottom taphole. A method of this type consists in opening the bay taphole, pressurizing the bay with inert gas, and then controlling the tapping of the melt in such a way that the ongoing tapping is interrupted by reducing the negative pressure in the bay as soon as the bath level in the lower vessel is below the lower edge of the tapping channel on the bay side. In this way, the tapping can be interrupted with little work.
Another advantageous measure with respect to the method consists in adjusting the gas pressure in the bay and in the tapping channel to a pressure value at which the bath level is brought to the height of the upper edge of the tapping channel that runs to the lower vessel. After the bay taphole has been closed, the bay and the tapping channel can be kept free of metal in this way. The pressure in the bay can be adjusted in such a way that small, steady gas consumption indicates that a small amount of gas is bubbling into the metal bath on the furnace side of the tapping channel. Lateral burning out or reclosing of the tapping channel becomes superfluous with this method of operation.
In the method of operation described above, the gas pressure inside the bay automatically drops at once when the bay taphole is opened. Therefore, in accordance with another step of the method, the tapping operation can be started by opening the bay taphole. At this instant, the tapped melt starts to flow through the tapping channels and the bay taphole without any need to tilt the furnace. A sand filling in the bay tap is not encrusted at its surface, because it was not exposed to a molten metal bath. It may be assumed, therefore, that the tap opens smoothly and without problems solely by moving away a sliding plate.
The bay taphole can be closed from above despite the pressure-tight and vacuum-tight cover. To this end, it is proposed that the tapping is terminated by closing the open bay taphole by means of a hollow plug, which can be moved in through the cover and through which sand can be poured in as far as a slide gate. Therefore, the sand enters the bay taphole in front of the closed slide gate through the hollow plug and fills this entire space. The taphole prevents any pieces of scrap possibly lying on the bay taphole from interfering with the satisfactory functioning of the hollow plug.
The hollow plug can be changed after it has been used by replacing it on the cover after a sluice has been closed. In addition, a "“paddle'' is advantageous for preventing the sand from running out of the bay taphole.
Embodiments of the invention are explained below with reference to the drawings, and several methods of operating the arc furnace are described on the basis of these embodiments. -- Figure 1 shows a cross section through a tiltable arc furnace, in which only the lower vessel is shown. -- Figure 2 shows a top view of the arc furnace shown in
Figure 1. -- Figure 3 shows a cross section through a stationary arc furnace, in which only the lower vessel is shown. -- Figure 4 shows a top view of the arc furnace shown in
Figure 3.
The following description refers mainly to Figures 1 and 2 for the time being. The drawings show only the lower vessel 2 of an arc furnace 1 with the furnace shell 2a lined towards the hearth 3. The arc furnace 1 can be tilted in both swivel directions for tapping the melt or the slag (Figure 1).
A tap 9 for the melt is located in a separately mounted bay 6, which abuts a terminal wall 4 of the circular or oval lower vessel 2. The terminal wall 4 is formed as an upper flange (Figure 2). One or more siphon-like tapping channels 5 run from the hearth 3 transversely through the terminal wall 4 and completely through the bay wall more or less tangent to the lining profile 10.
The bay 6 is detachably connected to the terminal wall 4 of the lower vessel 2a by a flange joint 8. Corresponding flanges 7 are provided on the bay and on the lower vessel. The bay taphole 9a runs vertically in the zero position 11 of the arc furnace 1. Alternatively, the tap 9 can be designed with its axis at an angle adapted to the tapping angle of the furnace 1.
The arc furnace 1 can be tipped in one swivel direction or the other to tap the melt and the slag, such that the melt is tapped eccentrically to the lower vessel 2. In this regard, first the tapping channels 5 are burned out in the lower vessel 2, and, when the melt flows into the bay 6, the tilting operation is initiated. The bay 6 is then sufficiently filled, and the bay taphole 9a is opened. When the desired amount of melt has been tapped, the arc furnace 1 is tilted back into its zero position 11 or beyond it.
Another method of operation can be carried out in such a way that first the tapping channels 5 are burned out in the lower vessel 2 from the bay side, and, when the melt flows into the bay 6 through the unclosed tap 9, the tilting operation is initiated.
After the zero position 11 has been reached, the tapping channel 5 and/or the bay taphole 9a is cleaned and, if necessary, closed with refractory material.
Alternatively, for relining purposes after suitably long production, the flange joint 8 is disconnected, and the bay 6 is removed and replaced by a relined bay 6.
The bay 6 can also be advantageously used for the addition of necessary fluxes and alloys or portions of the required amounts of these additives to the bay 6 during the tapping.
The following description pertains to the stationary furnace shown in Figures 3 and 4.
Figure 3 shows a process situation in which a hollow plug 14 is inserted through a hollow plug housing 15 with the sluice 13 opened and through the pressure-tight and vacuum-tight cover 16 (with gas valve 17 closed). The bay 6 is pressurized with the gas valve 17 open. A slide gate 18 below the bay taphole 9a is closed. In a subsequent step of the method, the hollow plug 14 is moved into a standby or changing position (as illustrated) with the bay taphole 9a closed by the slide gate 18. The bay 6 is pressurized, and inert gas bubbles out at the upper edge of the tapping channel 5 in the hearth 3. In a third step of the method, the tapping begins. The slide gate 18 is opened, the sand filling that is present runs out, and the bay is unpressurized relative to the atmosphere. The molten metal is then tapped. A few seconds after the start of the tapping, the molten metal flows through the bay taphole 9a. In a fourth step of the method, a negative pressure develops in the bay by the siphon principle. The hollow plug 14 is still in the standby or changing position. In a fifth step of the method, the hollow plug 14 moves in, the slide gate 18 closes, sand runs in, and the bay 6 is pressurized with gas. The bay 6 runs empty, as does the tapping channel 5. The hollow plug 14 moves out into the standby or changing position.
The furnace can be completely emptied, if necessary, from the bottom taphole 12.
List of Reference Numbers 1 arc furnace 2 lower vessel 2a furnace shell 3 (circular) hearth 4 terminal wall tapping channel 6 bay 7 flange 8 flange joint 9 tap 9a bay taphole lining profile 11 zero position 12 bottom taphole 13 sluice 14 hollow plug hollow plug housing 16 pressure-tight and vacuum-tight cover 17 gas valve 18 slide gate

Claims (20)

1. Arc furnace, which can be tilted or remains stationary for tapping the melt or the slag and has an eccentric or centric tap, characterized by the fact that the tap (9) is provided in a separately mounted bay (6), which abuts a terminal wall (4) of a lower vessel (2), and that at least one tapping channel (5) is provided, which passes through the terminal wall (4) to connect the furnace shell (2a) and the bay (6).
2. Arc furnace in accordance with Claim 1, characterized by the fact that the bay (6) can be connected to the terminal wall (4) of the lower vessel (2a) by a flange joint (8).
3. Arc furnace in accordance with Claim 1 or Claim 2, characterized by the fact that one or more siphon-like tapping channels (5) run through the terminal wall (4) more or less tangent to the lining profile (10).
4. Arc furnace in accordance with any of Claims 1 to 3, characterized by the fact that the taphole (9a) of the tap (9) in the bay (6) runs vertically in the zero position (11), i.e., the horizontal position, of the arc furnace (1).
5. Arc furnace in accordance with any of Claims 1 to 3, characterized by the fact that the taphole (9a) is designed with an angle adapted to the tapping angle of the tiltable furnace
(1).
6. Method of operating an arc furnace, which is tilted in one swivel direction to tap the melt and in the other swivel direction to tap the slag, such that the melt is tapped eccentrically to the lower vessel, characterized by the fact that first the tapping channels (5) are burned out in the lower vessel (2) from the bay side, and, when the melt flows into the bay (6), the tilting operation is initiated; in that the bay (6) is then sufficiently filled, and the taphole (9a) is opened; and in that, when the desired amount of melt has been tapped, the arc furnace (1) is tilted back into the zero position (11) or beyond it.
7. Method of operating an arc furnace, which is tilted in one swivel direction to tap the melt and in the other swivel direction to tap the slag, such that the melt is tapped eccentrically to the lower vessel, characterized by the fact that first the tapping channels (5) are burned out in the lower vessel (2) from the bay side, and, when the melt flows into the bay (6) through the unclosed taphole (9a), the tilting operation is initiated.
8. Method in accordance with Claim 6, characterized by the fact that, after the zero position (11) has been reached, the tapping channel (5) and/or the taphole (9a) is cleaned and closed with refractory material.
9. Method in accordance with any of Claims 6 to 8, characterized by the fact that, for relining purposes, the flange joint (8) is disconnected, and the bay (6) is removed and replaced by a relined bay (6).
10. Method in accordance with any of Claims 6 to 9, characterized by the fact that necessary fluxes and alloys or portions of the required amounts of these additives are added to the bay (6) during the tapping.
11. Method of operating an arc furnace, which is tilted in one swivel direction to tap the melt, such that the melt is tapped eccentrically to the lower vessel, characterized by the fact that the tapping rate is controlled by controlling the gas pressure in the bay (6) by pressurization of the pressure-tight and vacuum-tight covered bay (6) with inert gas.
12. Arc furnace with a closable taphole (9a), whose lower vessel (2) is stationary and has a bottom taphole (12), characterized by the fact that the tap (9) is provided in a separately mounted, pressure-tight and vacuum-tight bay (6), which abuts a terminal wall (4) of the lower vessel (2), and that at least one tapping channel (5) that passes through the terminal wall (4) to connect the furnace shell (2a) and the bay (6) is provided, such that the lower edge of the tapping channel (5) on the bay side and the upper edge of the bay taphole (9a) are at about the same level.
13. Arc furnace in accordance with Claim 12, characterized by the fact that the bay (6) is provided with a pressure-tight and vacuum-tight cover (16).
14. Arc furnace in accordance with Claim 12 or Claim 13, characterized by the fact that a hollow plug (14) in a hollow plug housing (15) is mounted on the pressure-tight and vacuum- tight cover (16), and that the hollow plug housing can be detached or connected and opened or closed by a sluice (13).
15. Arc furnace in accordance with any of Claims 12 to 14, characterized by the fact that a gas supply line with a gas valve (17) is connected to the pressure-tight and vacuum-tight cover (16).
16. Method of operating an arc furnace that is stationary, has a bay (6) built onto the lower furnace (2a), and is provided with a bay taphole (9a) and with a centric bottom taphole (12), characterized by the fact that, after the bay taphole (9a) has been opened, and the bay (6) has been pressurized with inert gas, the tapping of the melt is controlled in such a way that the ongoing tapping is interrupted by reducing the negative pressure in the bay (6) as soon as the bath level in the lower vessel (2) is below the lower edge of the tapping channel (5) on the bay side.
17. Method in accordance with Claim 16, characterized by the fact that the gas pressure in the bay (6) and in the tapping channel (5) is adjusted to a pressure value at which the bath level is brought to the height of the upper edge of the tapping channel (5) that runs to the lower vessel (2).
18. Method in accordance with Claim 16 or Claim 17, characterized by the fact that the tapping operation is started by opening the bay taphole (9a).
19. Method in accordance with any of Claims 16 to 18, characterized by the fact that the tapping is terminated by closing the open bay taphole (9a) by means of a hollow plug (14), which can be moved in through the cover (16) and through which sand can be poured in as far as a slide gate (18).
20. Method in accordance with any of Claims 16 to 19, characterized by the fact that the hollow plug (14) is replaced on the cover (16) after a sluice (13) has been closed.
ZA200401100A 2001-09-26 2004-02-11 Arc furnace and method for operating this arc furnace. ZA200401100B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10147543 2001-09-26

Publications (1)

Publication Number Publication Date
ZA200401100B true ZA200401100B (en) 2004-05-04

Family

ID=7700409

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA200401100A ZA200401100B (en) 2001-09-26 2004-02-11 Arc furnace and method for operating this arc furnace.

Country Status (4)

Country Link
KR (1) KR20040031109A (en)
DE (1) DE10223906A1 (en)
UA (1) UA79599C2 (en)
ZA (1) ZA200401100B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005024924B8 (en) * 2005-05-23 2007-10-25 Strikowestofen Gmbh Melting or holding furnace
DE102008008033A1 (en) 2007-08-04 2009-02-05 Sms Demag Ag Device for slag-free tapping or for transferring a melt
KR200452034Y1 (en) * 2008-10-28 2011-01-26 이호석 apparatus for treating rainwater
KR101406503B1 (en) * 2012-12-21 2014-06-13 주식회사 포스코 Fixed type electric arc furnace and molten steel manufacturing method
KR101417500B1 (en) * 2012-12-21 2014-07-09 주식회사 포스코 Discharge Method Using Molten Metal Discharge Device
EP2803927A1 (en) * 2013-05-17 2014-11-19 Siemens VAI Metals Technologies GmbH Metallurgical furnace vessel and method for operating the same
KR101713614B1 (en) * 2015-09-25 2017-03-08 주식회사 포스코건설 Apparatus for tapping molten steel using vacumm and tapping control method using thereof

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Publication number Publication date
DE10223906A1 (en) 2003-04-10
KR20040031109A (en) 2004-04-09
UA79599C2 (en) 2007-07-10

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