ZA200303900B - Enzymatic detergent compositions. - Google Patents
Enzymatic detergent compositions. Download PDFInfo
- Publication number
- ZA200303900B ZA200303900B ZA200303900A ZA200303900A ZA200303900B ZA 200303900 B ZA200303900 B ZA 200303900B ZA 200303900 A ZA200303900 A ZA 200303900A ZA 200303900 A ZA200303900 A ZA 200303900A ZA 200303900 B ZA200303900 B ZA 200303900B
- Authority
- ZA
- South Africa
- Prior art keywords
- pyridin
- bis
- optionally substituted
- detergent composition
- ylmethyl
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 84
- 239000003599 detergent Substances 0.000 title claims description 83
- 230000002255 enzymatic effect Effects 0.000 title claims description 15
- 108090001060 Lipase Proteins 0.000 claims description 61
- 102000004882 Lipase Human genes 0.000 claims description 61
- 102000004190 Enzymes Human genes 0.000 claims description 59
- 108090000790 Enzymes Proteins 0.000 claims description 59
- 239000004367 Lipase Substances 0.000 claims description 59
- 235000019421 lipase Nutrition 0.000 claims description 59
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 44
- -1 cyclcalkyl Chemical group 0.000 claims description 35
- 229910052757 nitrogen Inorganic materials 0.000 claims description 33
- 239000004744 fabric Substances 0.000 claims description 25
- 238000004061 bleaching Methods 0.000 claims description 19
- 229910052723 transition metal Inorganic materials 0.000 claims description 19
- 150000003624 transition metals Chemical class 0.000 claims description 19
- 239000003446 ligand Substances 0.000 claims description 16
- 239000004094 surface-active agent Substances 0.000 claims description 16
- 230000002366 lipolytic effect Effects 0.000 claims description 14
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 10
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 claims description 9
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 241000223258 Thermomyces lanuginosus Species 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 4
- PRICLFAUAJHZLI-UHFFFAOYSA-N 1,1-dipyridin-2-yl-n,n-bis(pyridin-2-ylmethyl)methanamine Chemical compound C=1C=CC=NC=1CN(C(C=1N=CC=CC=1)C=1N=CC=CC=1)CC1=CC=CC=N1 PRICLFAUAJHZLI-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- YKCVYVYCIXFHMD-UHFFFAOYSA-N 2-phenyl-1,1-dipyridin-2-yl-n,n-bis(pyridin-2-ylmethyl)ethanamine Chemical compound C=1C=CC=NC=1CN(C(CC=1C=CC=CC=1)(C=1N=CC=CC=1)C=1N=CC=CC=1)CC1=CC=CC=N1 YKCVYVYCIXFHMD-UHFFFAOYSA-N 0.000 claims description 2
- QNPHFVFBJIYVAX-UHFFFAOYSA-N n,n-bis[(6-methylpyridin-2-yl)methyl]-1,1-dipyridin-2-ylmethanamine Chemical compound CC1=CC=CC(CN(CC=2N=C(C)C=CC=2)C(C=2N=CC=CC=2)C=2N=CC=CC=2)=N1 QNPHFVFBJIYVAX-UHFFFAOYSA-N 0.000 claims description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims 12
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 claims 8
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 claims 8
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 claims 8
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 claims 8
- 125000001072 heteroaryl group Chemical group 0.000 claims 7
- XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical compound N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 claims 6
- 229910052739 hydrogen Inorganic materials 0.000 claims 5
- 239000001257 hydrogen Substances 0.000 claims 5
- 150000002431 hydrogen Chemical class 0.000 claims 5
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 claims 4
- VHMICKWLTGFITH-UHFFFAOYSA-N 2H-isoindole Chemical compound C1=CC=CC2=CNC=C21 VHMICKWLTGFITH-UHFFFAOYSA-N 0.000 claims 4
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 claims 4
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 claims 4
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 claims 4
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 claims 4
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims 4
- 125000003342 alkenyl group Chemical group 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 4
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 claims 4
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 claims 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 4
- 150000003852 triazoles Chemical class 0.000 claims 4
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims 3
- 229910052736 halogen Inorganic materials 0.000 claims 3
- 150000002367 halogens Chemical class 0.000 claims 3
- 125000000623 heterocyclic group Chemical group 0.000 claims 3
- 125000000592 heterocycloalkyl group Chemical group 0.000 claims 3
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 2
- CYFIRTJCYHPOLQ-UHFFFAOYSA-N 2-[6-[[[5-(carboxymethyl)pyridin-2-yl]methyl-(dipyridin-2-ylmethyl)amino]methyl]pyridin-3-yl]acetic acid Chemical compound N1=CC(CC(=O)O)=CC=C1CN(C(C=1N=CC=CC=1)C=1N=CC=CC=1)CC1=CC=C(CC(O)=O)C=N1 CYFIRTJCYHPOLQ-UHFFFAOYSA-N 0.000 claims 1
- 125000004174 2-benzimidazolyl group Chemical group [H]N1C(*)=NC2=C([H])C([H])=C([H])C([H])=C12 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 241000589516 Pseudomonas Species 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 125000003037 imidazol-2-yl group Chemical group [H]N1C([*])=NC([H])=C1[H] 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
- SHODXMYKLLGZQP-UHFFFAOYSA-N n-methyl-1,1-dipyridin-2-yl-n-(pyridin-2-ylmethyl)methanamine Chemical compound C=1C=CC=NC=1C(C=1N=CC=CC=1)N(C)CC1=CC=CC=N1 SHODXMYKLLGZQP-UHFFFAOYSA-N 0.000 claims 1
- 229940088598 enzyme Drugs 0.000 description 56
- 239000003921 oil Substances 0.000 description 44
- 239000007983 Tris buffer Substances 0.000 description 35
- 239000007844 bleaching agent Substances 0.000 description 23
- 239000003054 catalyst Substances 0.000 description 21
- 230000000694 effects Effects 0.000 description 21
- 150000001875 compounds Chemical class 0.000 description 20
- MLCJWRIUYXIWNU-OWOJBTEDSA-N (e)-ethene-1,2-diamine Chemical compound N\C=C\N MLCJWRIUYXIWNU-OWOJBTEDSA-N 0.000 description 19
- 239000000243 solution Substances 0.000 description 19
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- 238000005406 washing Methods 0.000 description 14
- 239000000047 product Substances 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
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- 239000002243 precursor Substances 0.000 description 12
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- 229940012017 ethylenediamine Drugs 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 10
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 9
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- 108010059892 Cellulase Proteins 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
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- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 6
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- 125000006514 pyridin-2-ylmethyl group Chemical group [H]C1=C([H])C([H])=C([H])C(=N1)C([H])([H])* 0.000 description 5
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- 239000000758 substrate Substances 0.000 description 5
- ITWBWJFEJCHKSN-UHFFFAOYSA-N 1,4,7-triazonane Chemical compound C1CNCCNCCN1 ITWBWJFEJCHKSN-UHFFFAOYSA-N 0.000 description 4
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- 229940116332 glucose oxidase Drugs 0.000 description 1
- 235000019420 glucose oxidase Nutrition 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 108010002430 hemicellulase Proteins 0.000 description 1
- 229940059442 hemicellulase Drugs 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 229960002773 hyaluronidase Drugs 0.000 description 1
- 230000001900 immune effect Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000004966 inorganic peroxy acids Chemical class 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- 239000001573 invertase Substances 0.000 description 1
- 235000011073 invertase Nutrition 0.000 description 1
- 150000004698 iron complex Chemical class 0.000 description 1
- GYCHYNMREWYSKH-UHFFFAOYSA-L iron(ii) bromide Chemical compound [Fe+2].[Br-].[Br-] GYCHYNMREWYSKH-UHFFFAOYSA-L 0.000 description 1
- 108010011519 keratan-sulfate endo-1,4-beta-galactosidase Proteins 0.000 description 1
- 108090000287 lactocepin Proteins 0.000 description 1
- 108010062085 ligninase Proteins 0.000 description 1
- 235000019626 lipase activity Nutrition 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 229960000274 lysozyme Drugs 0.000 description 1
- 239000004325 lysozyme Substances 0.000 description 1
- 235000010335 lysozyme Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 108010050604 mycodextranase Proteins 0.000 description 1
- QUEIOYSLAIWQPJ-UHFFFAOYSA-N n'-(furan-2-yl)-n,n,n'-tris[(3-methylpyridin-2-yl)methyl]ethane-1,2-diamine Chemical compound CC1=CC=CN=C1CN(CC=1C(=CC=CN=1)C)CCN(C=1OC=CC=1)CC1=NC=CC=C1C QUEIOYSLAIWQPJ-UHFFFAOYSA-N 0.000 description 1
- UEHURUIPMKYNBO-UHFFFAOYSA-N n'-[(3-methylpyridin-2-yl)methyl]ethane-1,2-diamine Chemical compound CC1=CC=CN=C1CNCCN UEHURUIPMKYNBO-UHFFFAOYSA-N 0.000 description 1
- RJTPPAKVEZAPHT-UHFFFAOYSA-N n,n',n'-tris[(3-methylpyridin-2-yl)methyl]ethane-1,2-diamine Chemical compound CC1=CC=CN=C1CNCCN(CC=1C(=CC=CN=1)C)CC1=NC=CC=C1C RJTPPAKVEZAPHT-UHFFFAOYSA-N 0.000 description 1
- IFWXWCMXLKGUOC-UHFFFAOYSA-N n,n',n'-tris[(5-ethylpyridin-2-yl)methyl]-n-methylethane-1,2-diamine Chemical compound N1=CC(CC)=CC=C1CN(C)CCN(CC=1N=CC(CC)=CC=1)CC1=CC=C(CC)C=N1 IFWXWCMXLKGUOC-UHFFFAOYSA-N 0.000 description 1
- AURBNAIBZFMGBT-UHFFFAOYSA-N n,n'-bis(dipyridin-2-ylmethyl)-n,n'-bis(pyridin-2-ylmethyl)propane-1,3-diamine Chemical compound C=1C=CC=NC=1CN(C(C=1N=CC=CC=1)C=1N=CC=CC=1)CCCN(C(C=1N=CC=CC=1)C=1N=CC=CC=1)CC1=CC=CC=N1 AURBNAIBZFMGBT-UHFFFAOYSA-N 0.000 description 1
- GNOLWGAJQVLBSM-UHFFFAOYSA-N n,n,5,7-tetramethyl-1,2,3,4-tetrahydronaphthalen-1-amine Chemical compound C1=C(C)C=C2C(N(C)C)CCCC2=C1C GNOLWGAJQVLBSM-UHFFFAOYSA-N 0.000 description 1
- RKSLDIUKXNUQID-UHFFFAOYSA-N n,n,n',n'-tetrakis[(3-methylpyridin-2-yl)methyl]ethane-1,2-diamine Chemical compound CC1=CC=CN=C1CN(CC=1C(=CC=CN=1)C)CCN(CC=1C(=CC=CN=1)C)CC1=NC=CC=C1C RKSLDIUKXNUQID-UHFFFAOYSA-N 0.000 description 1
- ZMIIJNKZTOCEME-UHFFFAOYSA-N n,n-bis(1h-benzimidazol-2-ylmethyl)-1,1-dipyridin-2-ylmethanamine Chemical compound N=1C2=CC=CC=C2NC=1CN(CC=1NC2=CC=CC=C2N=1)C(C=1N=CC=CC=1)C1=CC=CC=N1 ZMIIJNKZTOCEME-UHFFFAOYSA-N 0.000 description 1
- HNTOXKSOQQSTOX-UHFFFAOYSA-N n-ethyl-n,n',n'-tris[(3-methylpyridin-2-yl)methyl]ethane-1,2-diamine Chemical compound N=1C=CC=C(C)C=1CN(CC)CCN(CC=1C(=CC=CN=1)C)CC1=NC=CC=C1C HNTOXKSOQQSTOX-UHFFFAOYSA-N 0.000 description 1
- OOTKJPZEEVPWCR-UHFFFAOYSA-N n-methyl-1-pyridin-2-ylmethanamine Chemical compound CNCC1=CC=CC=N1 OOTKJPZEEVPWCR-UHFFFAOYSA-N 0.000 description 1
- PEAFAHCIDIRMCA-UHFFFAOYSA-N n-methyl-n,n',n'-tris(1-methylbenzimidazol-2-yl)ethane-1,2-diamine Chemical compound C1=CC=C2N(C)C(N(CCN(C=3N(C4=CC=CC=C4N=3)C)C=3N(C4=CC=CC=C4N=3)C)C)=NC2=C1 PEAFAHCIDIRMCA-UHFFFAOYSA-N 0.000 description 1
- UHEQYVPNQJFCEA-UHFFFAOYSA-N n-methyl-n,n',n'-tris[(5-methylpyridin-2-yl)methyl]ethane-1,2-diamine Chemical compound C=1C=C(C)C=NC=1CN(C)CCN(CC=1N=CC(C)=CC=1)CC1=CC=C(C)C=N1 UHEQYVPNQJFCEA-UHFFFAOYSA-N 0.000 description 1
- 108010035855 neopullulanase Proteins 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 108090000021 oryzin Proteins 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229940055729 papain Drugs 0.000 description 1
- 235000019834 papain Nutrition 0.000 description 1
- 108010087558 pectate lyase Proteins 0.000 description 1
- 108020004410 pectinesterase Proteins 0.000 description 1
- 229940111202 pepsin Drugs 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 229940012957 plasmin Drugs 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 108010004131 poly(beta-D-mannuronate) lyase Proteins 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000019419 proteases Nutrition 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 239000000429 sodium aluminium silicate Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- 239000012064 sodium phosphate buffer Substances 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003900 succinic acid esters Chemical class 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 108010038851 tannase Proteins 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- 238000005494 tarnishing Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 108010031354 thermitase Proteins 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- 229960004072 thrombin Drugs 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- GKASDNZWUGIAMG-UHFFFAOYSA-N triethyl orthoformate Chemical compound CCOC(OCC)OCC GKASDNZWUGIAMG-UHFFFAOYSA-N 0.000 description 1
- NRTLTGGGUQIRRT-UHFFFAOYSA-N triethylazanium;bromide Chemical compound [Br-].CC[NH+](CC)CC NRTLTGGGUQIRRT-UHFFFAOYSA-N 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000012588 trypsin Substances 0.000 description 1
- 229960001322 trypsin Drugs 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 229960005356 urokinase Drugs 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 108010062040 wax-ester hydrolase Proteins 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 108010083879 xyloglucan endo(1-4)-beta-D-glucanase Proteins 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00204514 | 2000-12-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200303900B true ZA200303900B (en) | 2004-05-20 |
Family
ID=8172432
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200303900A ZA200303900B (en) | 2000-12-14 | 2001-11-14 | Enzymatic detergent compositions. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20020137654A1 (es) |
| EP (1) | EP1341893B1 (es) |
| AR (1) | AR031907A1 (es) |
| AT (1) | ATE361356T1 (es) |
| AU (1) | AU2002223681A1 (es) |
| BR (1) | BR0116133B1 (es) |
| CA (1) | CA2429621C (es) |
| DE (1) | DE60128259T2 (es) |
| ES (1) | ES2287072T3 (es) |
| WO (1) | WO2002048307A1 (es) |
| ZA (1) | ZA200303900B (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030050211A1 (en) * | 2000-12-14 | 2003-03-13 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Enzymatic detergent compositions |
| CA2472189A1 (en) * | 2002-02-28 | 2003-09-04 | Unilever Plc | Bleach catalyst enhancement |
| JP2008094726A (ja) * | 2006-10-06 | 2008-04-24 | Towa Koso Kk | マイクロバブル洗浄用組成物、マイクロバブル洗浄方法及びマイクロバブル洗浄装置 |
| EP2281551A1 (en) * | 2008-05-19 | 2011-02-09 | TOWA Enzyme Co., Ltd. | Method for growing or nourishing head hair |
| JP5913781B2 (ja) * | 2009-11-12 | 2016-04-27 | 有限会社ターレス | 編み込まれた髪型を有する頭髪の洗浄方法 |
| US8846596B2 (en) | 2011-02-16 | 2014-09-30 | The Procter & Gamble Company | Liquid cleaning compositions |
| US20120205581A1 (en) * | 2011-02-16 | 2012-08-16 | Robert Richard Dykstra | Compositions and methods of bleaching |
| WO2013092051A1 (en) | 2011-12-20 | 2013-06-27 | Unilever Plc | Liquid detergents comprising lipase and bleach catalyst |
| US9752103B2 (en) * | 2013-06-11 | 2017-09-05 | The Procter & Gamble Company | Detergent composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997048787A1 (en) * | 1996-06-19 | 1997-12-24 | Unilever N.V. | Bleach activation |
| DE19628809A1 (de) * | 1996-07-17 | 1998-01-22 | Henkel Kgaa | Katalytisch wirksame Aktivatorkomplexe mit N¶4¶-Liganden vom Diimin-Typ für Persauerstoffverbindungen |
| ATE213765T1 (de) * | 1996-10-18 | 2002-03-15 | Procter & Gamble | Waschmittelzusammensetzungen |
| DE19755493A1 (de) * | 1997-12-13 | 1999-06-17 | Henkel Kgaa | Verwendung von Übergangsmetallkomplexen mit tripodalen Liganden zur Verstärkung der Bleichwirkung von Persauerstoffverbindungen |
| DE19855607A1 (de) * | 1998-12-02 | 2000-06-08 | Henkel Kgaa | Verwendung von Übergangsmetallkomplexen mit stickstoffhaltigen heterocyclischen Liganden zur Verstärkung der Bleichwirkung von Persauerstoffverbindungen |
-
2001
- 2001-11-14 AU AU2002223681A patent/AU2002223681A1/en not_active Abandoned
- 2001-11-14 AT AT01270590T patent/ATE361356T1/de not_active IP Right Cessation
- 2001-11-14 ZA ZA200303900A patent/ZA200303900B/en unknown
- 2001-11-14 DE DE60128259T patent/DE60128259T2/de not_active Expired - Lifetime
- 2001-11-14 ES ES01270590T patent/ES2287072T3/es not_active Expired - Lifetime
- 2001-11-14 EP EP01270590A patent/EP1341893B1/en not_active Expired - Lifetime
- 2001-11-14 CA CA2429621A patent/CA2429621C/en not_active Expired - Fee Related
- 2001-11-14 WO PCT/EP2001/013251 patent/WO2002048307A1/en active IP Right Grant
- 2001-11-14 BR BRPI0116133-4A patent/BR0116133B1/pt not_active IP Right Cessation
- 2001-12-11 US US10/013,755 patent/US20020137654A1/en not_active Abandoned
- 2001-12-12 AR ARP010105768A patent/AR031907A1/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DE60128259D1 (de) | 2007-06-14 |
| BR0116133A (pt) | 2003-10-28 |
| AU2002223681A1 (en) | 2002-06-24 |
| CA2429621C (en) | 2011-01-18 |
| DE60128259T2 (de) | 2007-08-30 |
| AR031907A1 (es) | 2003-10-08 |
| CA2429621A1 (en) | 2002-06-20 |
| ES2287072T3 (es) | 2007-12-16 |
| EP1341893A1 (en) | 2003-09-10 |
| WO2002048307A1 (en) | 2002-06-20 |
| BR0116133B1 (pt) | 2012-11-27 |
| ATE361356T1 (de) | 2007-05-15 |
| EP1341893B1 (en) | 2007-05-02 |
| US20020137654A1 (en) | 2002-09-26 |
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