ZA200302878B - Process for treating a solid-liquid mixture. - Google Patents
Process for treating a solid-liquid mixture. Download PDFInfo
- Publication number
- ZA200302878B ZA200302878B ZA200302878A ZA200302878A ZA200302878B ZA 200302878 B ZA200302878 B ZA 200302878B ZA 200302878 A ZA200302878 A ZA 200302878A ZA 200302878 A ZA200302878 A ZA 200302878A ZA 200302878 B ZA200302878 B ZA 200302878B
- Authority
- ZA
- South Africa
- Prior art keywords
- solid
- contaminant
- mixture
- liquid
- treating
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 60
- 239000007788 liquid Substances 0.000 title claims description 40
- 239000000203 mixture Substances 0.000 title claims description 28
- 239000007787 solid Substances 0.000 claims description 63
- 239000000356 contaminant Substances 0.000 claims description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 31
- 238000000354 decomposition reaction Methods 0.000 claims description 24
- 239000000377 silicon dioxide Substances 0.000 claims description 14
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 238000002144 chemical decomposition reaction Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- 238000009210 therapy by ultrasound Methods 0.000 claims description 5
- 239000004927 clay Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000005416 organic matter Substances 0.000 claims description 3
- 239000003575 carbonaceous material Substances 0.000 claims description 2
- 150000003071 polychlorinated biphenyls Chemical group 0.000 description 27
- 239000000758 substrate Substances 0.000 description 16
- 239000002245 particle Substances 0.000 description 14
- -1 PCB compounds Chemical class 0.000 description 13
- 238000002604 ultrasonography Methods 0.000 description 10
- 239000000575 pesticide Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- BIWJNBZANLAXMG-YQELWRJZSA-N chloordaan Chemical compound ClC1=C(Cl)[C@@]2(Cl)C3CC(Cl)C(Cl)C3[C@]1(Cl)C2(Cl)Cl BIWJNBZANLAXMG-YQELWRJZSA-N 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000013049 sediment Substances 0.000 description 5
- 238000000527 sonication Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000007086 side reaction Methods 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000000383 hazardous chemical Substances 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- 231100000678 Mycotoxin Toxicity 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 150000002013 dioxins Chemical class 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 239000002636 mycotoxin Substances 0.000 description 2
- 150000004045 organic chlorine compounds Chemical class 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000006557 surface reaction Methods 0.000 description 2
- 208000010201 Exanthema Diseases 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 231100000693 bioaccumulation Toxicity 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 150000004074 biphenyls Chemical class 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 201000005884 exanthem Diseases 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 230000008821 health effect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 238000005067 remediation Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/10—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by subjecting to electric or wave energy or particle or ionizing radiation
- A62D3/13—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by subjecting to electric or wave energy or particle or ionizing radiation to sonic energy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/008—Processes for carrying out reactions under cavitation conditions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/10—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing sonic or ultrasonic vibrations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/08—Reclamation of contaminated soil chemically
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/02—Chemical warfare substances, e.g. cholinesterase inhibitors
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/04—Pesticides, e.g. insecticides, herbicides, fungicides or nematocides
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/22—Organic substances containing halogen
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/26—Organic substances containing nitrogen or phosphorus
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2203/00—Aspects of processes for making harmful chemical substances harmless, or less harmful, by effecting chemical change in the substances
- A62D2203/10—Apparatus specially adapted for treating harmful chemical agents; Details thereof
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/34—Treatment of water, waste water, or sewage with mechanical oscillations
- C02F1/36—Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/06—Treatment of sludge; Devices therefor by oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/306—Pesticides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/36—Organic compounds containing halogen
- C02F2101/363—PCB's; PCP's
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S210/00—Liquid purification or separation
- Y10S210/902—Materials removed
- Y10S210/908—Organic
- Y10S210/909—Aromatic compound, e.g. pcb, phenol
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Emergency Management (AREA)
- Business, Economics & Management (AREA)
- Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Physical Water Treatments (AREA)
- Processing Of Solid Wastes (AREA)
- Fire-Extinguishing Compositions (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Extraction Or Liquid Replacement (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPR487100 | 2000-09-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200302878B true ZA200302878B (en) | 2004-04-13 |
Family
ID=3828860
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200302878A ZA200302878B (en) | 2000-09-13 | 2003-04-11 | Process for treating a solid-liquid mixture. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6908559B2 (ja) |
| EP (1) | EP1337327B1 (ja) |
| JP (1) | JP2004507360A (ja) |
| AT (1) | ATE460980T1 (ja) |
| CA (1) | CA2421916C (ja) |
| DE (1) | DE60141598D1 (ja) |
| WO (1) | WO2002022252A1 (ja) |
| ZA (1) | ZA200302878B (ja) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100346889C (zh) | 2002-04-23 | 2007-11-07 | 索尼科环境方案公司 | 多氯联苯污染介质的超声波处理 |
| US7265255B2 (en) * | 2003-03-10 | 2007-09-04 | Joseph Essenter | Soil decontamination method and apparatus for river bottoms |
| JP4997407B2 (ja) * | 2003-05-29 | 2012-08-08 | 独立行政法人産業技術総合研究所 | 固体導入によるキャビテーション気泡増加方法 |
| DE102004009636B4 (de) * | 2004-02-27 | 2007-03-01 | Schmid, Andreas, Dr.-Ing. | Verfahren und Vorrichtung zur Behandlung von schadstoffbelastetem Wasser |
| EP1945574A4 (en) * | 2005-10-20 | 2011-04-27 | Commw Scient Ind Res Org | PROCESS FOR TREATING A SOLID-LIQUID MIXTURE |
| US7810743B2 (en) | 2006-01-23 | 2010-10-12 | Kimberly-Clark Worldwide, Inc. | Ultrasonic liquid delivery device |
| US9283188B2 (en) | 2006-09-08 | 2016-03-15 | Kimberly-Clark Worldwide, Inc. | Delivery systems for delivering functional compounds to substrates and processes of using the same |
| US7712353B2 (en) * | 2006-12-28 | 2010-05-11 | Kimberly-Clark Worldwide, Inc. | Ultrasonic liquid treatment system |
| US8858892B2 (en) | 2007-12-21 | 2014-10-14 | Kimberly-Clark Worldwide, Inc. | Liquid treatment system |
| US9421504B2 (en) | 2007-12-28 | 2016-08-23 | Kimberly-Clark Worldwide, Inc. | Ultrasonic treatment chamber for preparing emulsions |
| JP5284255B2 (ja) * | 2009-12-18 | 2013-09-11 | 株式会社熊谷組 | 汚染土壌の浄化方法 |
| CA2800323A1 (en) | 2010-05-07 | 2011-11-10 | B9 Plasma, Inc. | Controlled bubble collapse milling |
| CN102765775A (zh) * | 2012-06-19 | 2012-11-07 | 哈尔滨工程大学 | 超声波强化硅藻土处理污水的方法 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE943768C (de) * | 1945-01-09 | 1956-06-01 | Atlas Werke Ag | Verfahren zur Schallbehandlung von Fluessigkeiten und Gasen |
| DE821341C (de) * | 1948-10-02 | 1951-11-15 | Atlas Werke Ag | Verfahren zur Behandlung von Fluessigkeiten mit Aktivkohle |
| US4401131A (en) | 1981-05-15 | 1983-08-30 | Gca Corporation | Apparatus for cleaning semiconductor wafers |
| JPS59147689A (ja) * | 1983-02-09 | 1984-08-24 | Hourai Tekkosho:Kk | 水の殺菌装置 |
| US4477357A (en) * | 1983-09-06 | 1984-10-16 | Hazardous Waste Management, Inc. | Detoxification of substances by utilization of ultrasonic energy |
| FI79471C (fi) | 1987-12-02 | 1990-01-10 | Kari Uljas Laiho | Foerfarande och anordning foer rengoering av ett filter avsett foer filtrering av vaetskeformiga substanser. |
| US5130032A (en) * | 1989-10-10 | 1992-07-14 | Sartori Helfred E | Method for treating a liquid medium |
| US5130031A (en) * | 1990-11-01 | 1992-07-14 | Sri International | Method of treating aqueous liquids using light energy, ultrasonic energy, and a photocatalyst |
| DE4108746A1 (de) * | 1991-03-18 | 1992-09-24 | Lindner Wolfgang | Dekontamination und detoxifikation von getreide, welches mit trochothecen-mykotoxinen belastet ist |
| US5198122A (en) * | 1991-04-08 | 1993-03-30 | Trinity Environmental Technologies, Inc. | Method of detoxification of substances by utilization of ultrasonic energy |
| US5242601A (en) * | 1991-06-06 | 1993-09-07 | Alternative Technologies For Waste, Inc. | Sludge treatment with CaO or CaC2 and recovery of CaO therefrom |
| FI87535C (fi) * | 1991-08-27 | 1993-01-25 | Ekokem Oy Ab | Anordning och foerfarande foer rening av filtreringsaemnen som anvaends foer rening av vaetskor samt anvaendningarna av foerfarandet och anordningen |
| JPH0889975A (ja) * | 1994-09-26 | 1996-04-09 | Marusoo Sangyo Kk | 有機ハロゲン化合物含有水溶液の処理方法 |
| AU4856196A (en) | 1995-01-06 | 1996-07-24 | Trustees Of Boston University | Method and apparatus for enhancing chemical reactions through acoustic cavitation |
| US6117334A (en) | 1995-01-10 | 2000-09-12 | Coury; William S. | Decontamination reactor system and method of using same |
| US5984578A (en) * | 1997-04-11 | 1999-11-16 | New Jersey Institute Of Technology | Apparatus and method for in situ removal of contaminants using sonic energy |
| JP3537312B2 (ja) * | 1998-04-20 | 2004-06-14 | 株式会社クボタ | 汚泥中のダイオキシン類等の有機塩素化合物の分解除去方法 |
| JPH11300334A (ja) * | 1998-04-20 | 1999-11-02 | Kubota Corp | 土壌中のダイオキシン類等の有機塩素化合物の分解除去方法 |
| US6077431A (en) * | 1998-04-20 | 2000-06-20 | Kubota Corporation | Process for decomposition and removal of dioxins contained in sludge |
| JP2000024494A (ja) * | 1998-07-13 | 2000-01-25 | Toto Ltd | 超音波処理装置 |
| FR2783515B1 (fr) * | 1998-09-21 | 2000-12-15 | Conservatoire Nat Arts | Procede de traitement de substances organiques en milieu aqueux, notamment d'effluents et dispositif electrochimique pour mettre en oeuvre le procede |
-
2001
- 2001-09-13 AT AT01973805T patent/ATE460980T1/de not_active IP Right Cessation
- 2001-09-13 CA CA002421916A patent/CA2421916C/en not_active Expired - Fee Related
- 2001-09-13 WO PCT/AU2001/001164 patent/WO2002022252A1/en active IP Right Grant
- 2001-09-13 US US10/380,402 patent/US6908559B2/en not_active Expired - Fee Related
- 2001-09-13 JP JP2002526496A patent/JP2004507360A/ja active Pending
- 2001-09-13 DE DE60141598T patent/DE60141598D1/de not_active Expired - Lifetime
- 2001-09-13 EP EP01973805A patent/EP1337327B1/en not_active Expired - Lifetime
-
2003
- 2003-04-11 ZA ZA200302878A patent/ZA200302878B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ATE460980T1 (de) | 2010-04-15 |
| CA2421916C (en) | 2008-11-18 |
| EP1337327A1 (en) | 2003-08-27 |
| DE60141598D1 (de) | 2010-04-29 |
| EP1337327A4 (en) | 2004-04-28 |
| US20030168412A1 (en) | 2003-09-11 |
| JP2004507360A (ja) | 2004-03-11 |
| EP1337327B1 (en) | 2010-03-17 |
| CA2421916A1 (en) | 2002-03-21 |
| WO2002022252A1 (en) | 2002-03-21 |
| US6908559B2 (en) | 2005-06-21 |
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