ZA200210162B - Oxirane production method. - Google Patents
Oxirane production method. Download PDFInfo
- Publication number
- ZA200210162B ZA200210162B ZA200210162A ZA200210162A ZA200210162B ZA 200210162 B ZA200210162 B ZA 200210162B ZA 200210162 A ZA200210162 A ZA 200210162A ZA 200210162 A ZA200210162 A ZA 200210162A ZA 200210162 B ZA200210162 B ZA 200210162B
- Authority
- ZA
- South Africa
- Prior art keywords
- process according
- catalyst
- reactor
- oxirane
- reaction medium
- Prior art date
Links
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 title claims description 23
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 238000000034 method Methods 0.000 claims description 49
- 230000008569 process Effects 0.000 claims description 49
- 239000003054 catalyst Substances 0.000 claims description 47
- 239000002245 particle Substances 0.000 claims description 29
- -1 peroxide compound Chemical class 0.000 claims description 29
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 23
- 239000012429 reaction media Substances 0.000 claims description 22
- 239000012530 fluid Substances 0.000 claims description 21
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 20
- 150000001336 alkenes Chemical class 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 17
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 17
- 239000002904 solvent Substances 0.000 claims description 14
- 238000012790 confirmation Methods 0.000 claims description 13
- 239000010457 zeolite Substances 0.000 claims description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 10
- 229910021536 Zeolite Inorganic materials 0.000 claims description 9
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 9
- 239000010936 titanium Substances 0.000 claims description 9
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- 239000006227 byproduct Substances 0.000 claims description 7
- 239000002826 coolant Substances 0.000 claims description 7
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 6
- 239000011949 solid catalyst Substances 0.000 claims description 6
- 230000000630 rising effect Effects 0.000 claims description 5
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 claims description 4
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical group ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 3
- 230000001174 ascending effect Effects 0.000 claims description 3
- 238000006735 epoxidation reaction Methods 0.000 description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 238000005243 fluidization Methods 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000007970 homogeneous dispersion Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical compound CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000006701 autoxidation reaction Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000006140 methanolysis reaction Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0008356A FR2810980B1 (fr) | 2000-06-28 | 2000-06-28 | Procede de fabrication d'oxiranne en presence d'un catalyseur sous forme de particules |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200210162B true ZA200210162B (en) | 2004-03-15 |
Family
ID=8851836
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200210162A ZA200210162B (en) | 2000-06-28 | 2002-12-13 | Oxirane production method. |
Country Status (15)
Country | Link |
---|---|
US (1) | US6720435B2 (ja) |
EP (1) | EP1299368B1 (ja) |
JP (1) | JP5087199B2 (ja) |
CN (1) | CN1240693C (ja) |
AT (1) | ATE303371T1 (ja) |
AU (1) | AU2001275684A1 (ja) |
BR (1) | BRPI0112056B1 (ja) |
CA (1) | CA2412545C (ja) |
DE (1) | DE60113116T2 (ja) |
ES (1) | ES2248359T3 (ja) |
FR (1) | FR2810980B1 (ja) |
MX (1) | MXPA02012527A (ja) |
RU (1) | RU2272032C2 (ja) |
WO (1) | WO2002000636A1 (ja) |
ZA (1) | ZA200210162B (ja) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1138387A1 (de) * | 2000-03-29 | 2001-10-04 | Degussa AG | Verfahren zur Herstellung eines Titansilicalitformkörpers |
WO2009063487A2 (en) * | 2007-08-10 | 2009-05-22 | Aditya Birla Science & Technology Co. Ltd. | An improved process for manufacture of epoxides, particularly epichlorohydrin |
EP2103604A1 (de) | 2008-03-17 | 2009-09-23 | Evonik Degussa GmbH | Verfahren zur Herstellung von Epichlorhydrin |
EP2149569A1 (en) | 2008-08-01 | 2010-02-03 | Hexion Specialty Chemicals Research Belgium S.A. | Process for the manufacture of a 1,2-Epoxide |
EP2149570A1 (en) * | 2008-08-01 | 2010-02-03 | Hexion Specialty Chemicals Research Belgium S.A. | Process for the manufacture of epichlorohydrin using hydrogen peroxide and a manganese komplex |
US8796478B2 (en) | 2011-01-27 | 2014-08-05 | Solvay Sa | Process for the manufacture of 1,2-epoxy-3-chloropropane |
EP2668172A1 (en) | 2011-01-27 | 2013-12-04 | Solvay SA | Process for the manufacture of 1,2-epoxy-3-chloropropane |
CN104130216B (zh) * | 2014-08-11 | 2016-02-03 | 河南骏化发展股份有限公司 | 双氧水直接氧化丙烯丙烷混合气连续生产环氧丙烷的工艺 |
US10774057B2 (en) * | 2016-07-13 | 2020-09-15 | Basf Se | Process for preparing ethene oxide |
CN110204514A (zh) * | 2019-07-25 | 2019-09-06 | 石河子大学 | 一种环氧植物油的生产工艺 |
CN112500371B (zh) * | 2019-09-14 | 2023-04-11 | 南京延长反应技术研究院有限公司 | 一种强化丙烯环氧化制备环氧丙烷的无醚化系统及工艺 |
CN115745918B (zh) * | 2022-09-19 | 2023-12-22 | 中国科学院大连化学物理研究所 | 一种利用液固循环流化床反应-再生系统的hppo法生产环氧丙烷工艺 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1440125A (fr) * | 1965-04-16 | 1966-05-27 | Aquitaine Petrole | Nouveau procédé d'époxydation des oléfines en phase liquide par l'eau oxygénée |
CA2137310C (en) | 1993-12-20 | 2004-02-17 | John C. Jubin Jr. | Catalytic converter and method for highly exothermic reactions |
US5916835A (en) * | 1996-12-20 | 1999-06-29 | Arco Chemical Technology, L.P. | Heterogeneous catalyst regeneration |
GB2331071A (en) | 1997-11-11 | 1999-05-12 | Solvay | Manufacture of micro spherical zeolite containing catalyst particles |
BE1011577A3 (fr) * | 1997-11-27 | 1999-11-09 | Solvay | Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de catalyseur. |
BE1011576A3 (fr) * | 1997-11-27 | 1999-11-09 | Solvay | Produit a base d'epichlorhydrine et procede de fabrication de ce produit. |
IT1298126B1 (it) * | 1998-01-15 | 1999-12-20 | Enichem Spa | Procedimento per la preparazione di epossidi olefinici |
BE1011851A3 (fr) | 1998-03-24 | 2000-02-01 | Solvay | Procede de fabrication d'un oxiranne. |
BE1011852A3 (fr) | 1998-03-24 | 2000-02-01 | Solvay | Procede de fabrication d'un oxiranne. |
BE1012303A3 (fr) | 1998-11-20 | 2000-09-05 | Solvay | Procede de fabrication d'un oxiranne. |
-
2000
- 2000-06-28 FR FR0008356A patent/FR2810980B1/fr not_active Expired - Fee Related
-
2001
- 2001-06-26 AU AU2001275684A patent/AU2001275684A1/en not_active Abandoned
- 2001-06-26 BR BRPI0112056A patent/BRPI0112056B1/pt active IP Right Grant
- 2001-06-26 DE DE60113116T patent/DE60113116T2/de not_active Expired - Lifetime
- 2001-06-26 EP EP01953176A patent/EP1299368B1/fr not_active Expired - Lifetime
- 2001-06-26 MX MXPA02012527A patent/MXPA02012527A/es active IP Right Grant
- 2001-06-26 ES ES01953176T patent/ES2248359T3/es not_active Expired - Lifetime
- 2001-06-26 CA CA2412545A patent/CA2412545C/fr not_active Expired - Lifetime
- 2001-06-26 AT AT01953176T patent/ATE303371T1/de not_active IP Right Cessation
- 2001-06-26 CN CNB018119786A patent/CN1240693C/zh not_active Expired - Lifetime
- 2001-06-26 RU RU2003102386/04A patent/RU2272032C2/ru active
- 2001-06-26 WO PCT/EP2001/007272 patent/WO2002000636A1/fr active IP Right Grant
- 2001-06-26 US US10/311,305 patent/US6720435B2/en not_active Expired - Lifetime
- 2001-06-26 JP JP2002505384A patent/JP5087199B2/ja not_active Expired - Lifetime
-
2002
- 2002-12-13 ZA ZA200210162A patent/ZA200210162B/en unknown
Also Published As
Publication number | Publication date |
---|---|
DE60113116D1 (de) | 2005-10-06 |
US6720435B2 (en) | 2004-04-13 |
CA2412545A1 (fr) | 2002-01-03 |
BRPI0112056B1 (pt) | 2017-04-11 |
CN1240693C (zh) | 2006-02-08 |
US20030158431A1 (en) | 2003-08-21 |
EP1299368B1 (fr) | 2005-08-31 |
MXPA02012527A (es) | 2003-05-14 |
BR0112056A (pt) | 2004-02-10 |
JP5087199B2 (ja) | 2012-11-28 |
FR2810980A1 (fr) | 2002-01-04 |
AU2001275684A1 (en) | 2002-01-08 |
CA2412545C (fr) | 2011-10-11 |
WO2002000636A1 (fr) | 2002-01-03 |
ATE303371T1 (de) | 2005-09-15 |
JP2004501907A (ja) | 2004-01-22 |
DE60113116T2 (de) | 2006-06-14 |
RU2272032C2 (ru) | 2006-03-20 |
EP1299368A1 (fr) | 2003-04-09 |
ES2248359T3 (es) | 2006-03-16 |
FR2810980B1 (fr) | 2004-05-21 |
CN1439000A (zh) | 2003-08-27 |
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