ZA200100865B - Biodegradable thermoplastic polyester composition with improved wettability. - Google Patents
Biodegradable thermoplastic polyester composition with improved wettability. Download PDFInfo
- Publication number
- ZA200100865B ZA200100865B ZA200100865A ZA200100865A ZA200100865B ZA 200100865 B ZA200100865 B ZA 200100865B ZA 200100865 A ZA200100865 A ZA 200100865A ZA 200100865 A ZA200100865 A ZA 200100865A ZA 200100865 B ZA200100865 B ZA 200100865B
- Authority
- ZA
- South Africa
- Prior art keywords
- acid
- thermoplastic composition
- weight percent
- polymer
- weight
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 160
- 229920001169 thermoplastic Polymers 0.000 title claims description 114
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 114
- 229920000728 polyester Polymers 0.000 title description 3
- 229920000642 polymer Polymers 0.000 claims description 176
- 229920003232 aliphatic polyester Polymers 0.000 claims description 84
- 239000002253 acid Substances 0.000 claims description 80
- 239000000080 wetting agent Substances 0.000 claims description 78
- -1 polybutylene succinate Polymers 0.000 claims description 63
- 239000000835 fiber Substances 0.000 claims description 60
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 30
- 229920002961 polybutylene succinate Polymers 0.000 claims description 27
- 239000004631 polybutylene succinate Substances 0.000 claims description 27
- 229920001748 polybutylene Polymers 0.000 claims description 25
- 229920001610 polycaprolactone Polymers 0.000 claims description 18
- 239000001361 adipic acid Substances 0.000 claims description 17
- 229920001577 copolymer Polymers 0.000 claims description 16
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 claims description 16
- 235000011037 adipic acid Nutrition 0.000 claims description 15
- 150000001298 alcohols Chemical class 0.000 claims description 14
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 claims description 10
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 claims description 10
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 10
- 150000007513 acids Chemical class 0.000 claims description 9
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 8
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 5
- 150000001408 amides Chemical class 0.000 claims description 5
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 150000002989 phenols Chemical class 0.000 claims 2
- 239000000463 material Substances 0.000 description 29
- 239000000047 product Substances 0.000 description 28
- 238000000034 method Methods 0.000 description 23
- 230000002745 absorbent Effects 0.000 description 20
- 239000002250 absorbent Substances 0.000 description 20
- 238000012545 processing Methods 0.000 description 13
- 239000007787 solid Substances 0.000 description 13
- 230000008569 process Effects 0.000 description 12
- 238000001816 cooling Methods 0.000 description 11
- 238000002425 crystallisation Methods 0.000 description 10
- 230000008025 crystallization Effects 0.000 description 10
- 230000002209 hydrophobic effect Effects 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 239000002667 nucleating agent Substances 0.000 description 9
- 238000009987 spinning Methods 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 230000006870 function Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910001868 water Inorganic materials 0.000 description 5
- 230000001747 exhibiting effect Effects 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000010791 quenching Methods 0.000 description 4
- 239000010865 sewage Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 229920002959 polymer blend Polymers 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 230000000171 quenching effect Effects 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 241000364021 Tulsa Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 150000002194 fatty esters Chemical class 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920000747 poly(lactic acid) Polymers 0.000 description 2
- 239000004632 polycaprolactone Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000002910 solid waste Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 206010021639 Incontinence Diseases 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229920002988 biodegradable polymer Polymers 0.000 description 1
- 239000004621 biodegradable polymer Substances 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 210000001124 body fluid Anatomy 0.000 description 1
- 239000010839 body fluid Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 235000019965 ethoxylated diglyceride Nutrition 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 210000004914 menses Anatomy 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- VMXUWOKSQNHOCA-UKTHLTGXSA-N ranitidine Chemical compound [O-][N+](=O)\C=C(/NC)NCCSCC1=CC=C(CN(C)C)O1 VMXUWOKSQNHOCA-UKTHLTGXSA-N 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 238000004781 supercooling Methods 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15203—Properties of the article, e.g. stiffness or absorbency
- A61F13/15252—Properties of the article, e.g. stiffness or absorbency compostable or biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/092—Polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/22—Thermoplastic resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/298—Physical dimension
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- General Chemical & Material Sciences (AREA)
- Heart & Thoracic Surgery (AREA)
- Vascular Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Textile Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Nonwoven Fabrics (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Biological Depolymerization Polymers (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/144,153 US6225388B1 (en) | 1998-08-31 | 1998-08-31 | Biodegradable thermoplastic composition with improved wettability |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200100865B true ZA200100865B (en) | 2001-07-16 |
Family
ID=22507316
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200100865A ZA200100865B (en) | 1998-08-31 | 2001-01-31 | Biodegradable thermoplastic polyester composition with improved wettability. |
Country Status (17)
Country | Link |
---|---|
US (1) | US6225388B1 (ja) |
EP (1) | EP1107999A2 (ja) |
JP (1) | JP2002523592A (ja) |
KR (1) | KR100591649B1 (ja) |
CN (1) | CN1318084A (ja) |
AR (1) | AR021471A1 (ja) |
AU (1) | AU752865B2 (ja) |
BR (1) | BR9913274A (ja) |
CO (1) | CO5100963A1 (ja) |
GT (1) | GT199900141A (ja) |
MY (1) | MY132877A (ja) |
PA (1) | PA8479501A1 (ja) |
PE (1) | PE20001146A1 (ja) |
RU (1) | RU2001108497A (ja) |
UY (1) | UY25685A1 (ja) |
WO (1) | WO2000012606A2 (ja) |
ZA (1) | ZA200100865B (ja) |
Families Citing this family (52)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR0015443A (pt) * | 1999-11-09 | 2002-06-25 | Kimberly Clark Co | Não-tecidos biodegradáveis com aperfeiçoadas propriedades de gerenciamento de fluido e artigos descartáveis contendo os mesmos |
US6177193B1 (en) * | 1999-11-30 | 2001-01-23 | Kimberly-Clark Worldwide, Inc. | Biodegradable hydrophilic binder fibers |
GB2387848B (en) * | 1999-11-30 | 2004-05-19 | Kimberly Clark Co | Core/sheath bi-component polyester binder fibers |
US6218009B1 (en) * | 1999-11-30 | 2001-04-17 | Kimberly-Clark Worldwide, Inc. | Hydrophilic binder fibers |
US6645618B2 (en) | 2001-06-15 | 2003-11-11 | 3M Innovative Properties Company | Aliphatic polyester microfibers, microfibrillated articles and use thereof |
US6890649B2 (en) | 2002-04-26 | 2005-05-10 | 3M Innovative Properties Company | Aliphatic polyester microfibers, microfibrillated articles and use thereof |
US20050280811A1 (en) * | 2003-09-19 | 2005-12-22 | Donald Sandell | Grooved high density plate |
US20050225751A1 (en) * | 2003-09-19 | 2005-10-13 | Donald Sandell | Two-piece high density plate |
CN101326312B (zh) * | 2005-12-15 | 2012-04-04 | 金伯利-克拉克环球有限公司 | 可生物降解的多组分纤维 |
US20070208161A1 (en) * | 2006-03-01 | 2007-09-06 | Isao Noda | Fibers formed of ester condensates and process for forming fibers from ester condensates |
KR101283172B1 (ko) | 2006-04-07 | 2013-07-08 | 킴벌리-클라크 월드와이드, 인크. | 생분해성 부직 라미네이트 |
WO2008008074A1 (en) * | 2006-07-14 | 2008-01-17 | Kimberly-Clark Worldwide, Inc. | Biodegradable polyactic acid for use in nonwoven webs |
MX2009000525A (es) | 2006-07-14 | 2009-01-27 | Kimberly Clark Co | Poliester alifatico biodegradable para usarse en telas no tejidas. |
KR101311060B1 (ko) * | 2006-07-14 | 2013-09-24 | 킴벌리-클라크 월드와이드, 인크. | 부직 웹에 사용하기 위한 생분해성 지방족-방향족코폴리에스테르 |
WO2008027046A1 (en) * | 2006-08-31 | 2008-03-06 | Kimberly-Clark Worldwide, Inc. | Highly breathable biodegradable films |
US7385020B2 (en) | 2006-10-13 | 2008-06-10 | 3M Innovative Properties Company | 2-octyl (meth)acrylate adhesive composition |
US8513329B2 (en) | 2006-10-31 | 2013-08-20 | Bio-Tec Environmental, Llc | Chemical additives to make polymeric materials biodegradable |
ES2773919T3 (es) * | 2006-10-31 | 2020-07-15 | Bio Tec Env Llc | Aditivos químicos para hacer biodegradables los materiales poliméricos |
US9555167B2 (en) | 2006-12-11 | 2017-01-31 | 3M Innovative Properties Company | Biocompatible antimicrobial compositions |
MX2009006136A (es) * | 2006-12-15 | 2009-08-07 | Kimberly Clark Co | Acidos polilacticos biodegradables para uso en la formacion de fibras. |
US20100048081A1 (en) * | 2006-12-15 | 2010-02-25 | Topolkaraev Vasily A | Biodegradable polyesters for use in forming fibers |
WO2009024836A1 (en) * | 2007-08-22 | 2009-02-26 | Kimberly-Clark Worldwide, Inc. | Multicomponent biodegradable filaments and nonwoven webs formed therefrom |
KR20100098529A (ko) * | 2007-12-13 | 2010-09-07 | 킴벌리-클라크 월드와이드, 인크. | 폴리락트산 및 폴리에테르 공중합체를 함유하는 열가소성 조성물로부터 형성된 생분해성 섬유 |
US8227658B2 (en) | 2007-12-14 | 2012-07-24 | Kimberly-Clark Worldwide, Inc | Film formed from a blend of biodegradable aliphatic-aromatic copolyesters |
US7998888B2 (en) * | 2008-03-28 | 2011-08-16 | Kimberly-Clark Worldwide, Inc. | Thermoplastic starch for use in melt-extruded substrates |
US8147965B2 (en) * | 2008-05-14 | 2012-04-03 | Kimberly-Clark Worldwide, Inc. | Water-sensitive film containing thermoplastic polyurethane |
US8338508B2 (en) * | 2008-05-14 | 2012-12-25 | Kimberly-Clark Worldwide, Inc. | Water-sensitive film containing an olefinic elastomer |
CN102046861B (zh) * | 2008-05-30 | 2012-12-12 | 金伯利-克拉克环球有限公司 | 聚乳酸纤维 |
US8470222B2 (en) | 2008-06-06 | 2013-06-25 | Kimberly-Clark Worldwide, Inc. | Fibers formed from a blend of a modified aliphatic-aromatic copolyester and thermoplastic starch |
US8841386B2 (en) * | 2008-06-10 | 2014-09-23 | Kimberly-Clark Worldwide, Inc. | Fibers formed from aromatic polyester and polyether copolymer |
AU2009257365A1 (en) | 2008-06-12 | 2009-12-17 | 3M Innovative Properties Company | Melt blown fine fibers and methods of manufacture |
CN102119079B (zh) | 2008-06-12 | 2014-09-10 | 3M创新有限公司 | 生物相容性亲水性组合物 |
US8188185B2 (en) * | 2008-06-30 | 2012-05-29 | Kimberly-Clark Worldwide, Inc. | Biodegradable packaging film |
US8927617B2 (en) | 2008-06-30 | 2015-01-06 | Kimberly-Clark Worldwide, Inc. | Fragranced water-sensitive film |
US8759279B2 (en) * | 2008-06-30 | 2014-06-24 | Kimberly-Clark Worldwide, Inc. | Fragranced biodegradable film |
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KR20140134684A (ko) * | 2012-03-30 | 2014-11-24 | 미쯔비시 레이온 가부시끼가이샤 | 복합 중공사막 및 중공사막 모듈 |
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KR20160058952A (ko) | 2013-09-30 | 2016-05-25 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 에폭시화 지방 에스테르가 그 상에 배치된 섬유 및 와이프, 및 방법 |
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US4770656A (en) | 1986-12-31 | 1988-09-13 | Kimberly-Clark Corporation | Routing of leg elastic to reduce stresses in a stretchable outer diaper cover |
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US5952088A (en) * | 1996-12-31 | 1999-09-14 | Kimberly-Clark Worldwide, Inc. | Multicomponent fiber |
TR199901501T2 (xx) * | 1996-12-31 | 1999-09-21 | Kimberly-Clark Worldwide, Inc. | Termoplastik kompozisyon. |
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1998
- 1998-08-31 US US09/144,153 patent/US6225388B1/en not_active Expired - Fee Related
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1999
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- 1999-08-25 GT GT199900141A patent/GT199900141A/es unknown
- 1999-08-25 MY MYPI99003647A patent/MY132877A/en unknown
- 1999-08-26 PE PE1999000866A patent/PE20001146A1/es not_active Application Discontinuation
- 1999-08-27 AU AU16337/00A patent/AU752865B2/en not_active Ceased
- 1999-08-27 CN CN99810070A patent/CN1318084A/zh active Pending
- 1999-08-27 KR KR1020017002507A patent/KR100591649B1/ko not_active IP Right Cessation
- 1999-08-27 BR BR9913274-5A patent/BR9913274A/pt not_active Application Discontinuation
- 1999-08-27 JP JP2000567610A patent/JP2002523592A/ja active Pending
- 1999-08-27 EP EP99959092A patent/EP1107999A2/en not_active Withdrawn
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- 1999-08-27 RU RU2001108497/04A patent/RU2001108497A/ru unknown
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- 1999-08-30 UY UY25685A patent/UY25685A1/es not_active Application Discontinuation
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WO2000012606A3 (en) | 2000-06-02 |
EP1107999A2 (en) | 2001-06-20 |
UY25685A1 (es) | 2000-03-31 |
JP2002523592A (ja) | 2002-07-30 |
WO2000012606A2 (en) | 2000-03-09 |
CO5100963A1 (es) | 2001-11-27 |
AU752865B2 (en) | 2002-10-03 |
KR100591649B1 (ko) | 2006-06-20 |
KR20010073030A (ko) | 2001-07-31 |
CN1318084A (zh) | 2001-10-17 |
PA8479501A1 (es) | 2000-09-29 |
WO2000012606A9 (en) | 2000-08-03 |
AU1633700A (en) | 2000-03-21 |
RU2001108497A (ru) | 2004-03-20 |
PE20001146A1 (es) | 2000-10-25 |
GT199900141A (es) | 2001-02-15 |
MY132877A (en) | 2007-10-31 |
AR021471A1 (es) | 2002-07-24 |
US6225388B1 (en) | 2001-05-01 |
BR9913274A (pt) | 2001-10-09 |
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