WO2024169713A1 - Bearing steel for vehicle hub and manufacturing method for bearing steel - Google Patents
Bearing steel for vehicle hub and manufacturing method for bearing steel Download PDFInfo
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- WO2024169713A1 WO2024169713A1 PCT/CN2024/075902 CN2024075902W WO2024169713A1 WO 2024169713 A1 WO2024169713 A1 WO 2024169713A1 CN 2024075902 W CN2024075902 W CN 2024075902W WO 2024169713 A1 WO2024169713 A1 WO 2024169713A1
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- Prior art keywords
- bearing steel
- steel
- wheel hub
- hub
- vehicle
- Prior art date
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 116
- 239000010959 steel Substances 0.000 title claims abstract description 116
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- 229910052718 tin Inorganic materials 0.000 claims description 4
- 238000005266 casting Methods 0.000 claims description 3
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- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 238000007373 indentation Methods 0.000 abstract description 8
- 239000002893 slag Substances 0.000 description 18
- 229910052799 carbon Inorganic materials 0.000 description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 14
- 239000010949 copper Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 13
- 239000011572 manganese Substances 0.000 description 12
- 239000011651 chromium Substances 0.000 description 11
- 229910052782 aluminium Inorganic materials 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 229910052802 copper Inorganic materials 0.000 description 9
- 229910052710 silicon Inorganic materials 0.000 description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 8
- 229910052748 manganese Inorganic materials 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 229910052804 chromium Inorganic materials 0.000 description 7
- 239000010955 niobium Substances 0.000 description 7
- 238000010079 rubber tapping Methods 0.000 description 7
- 239000010703 silicon Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
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- 229910052758 niobium Inorganic materials 0.000 description 5
- 229910052720 vanadium Inorganic materials 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
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- 238000010891 electric arc Methods 0.000 description 4
- 230000006698 induction Effects 0.000 description 4
- 230000000977 initiatory effect Effects 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
- 229910000838 Al alloy Inorganic materials 0.000 description 3
- -1 Manganese-aluminum Chemical compound 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 150000001247 metal acetylides Chemical class 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000009849 vacuum degassing Methods 0.000 description 3
- 229910000881 Cu alloy Inorganic materials 0.000 description 2
- 229910000592 Ferroniobium Inorganic materials 0.000 description 2
- 229910000628 Ferrovanadium Inorganic materials 0.000 description 2
- 229910018540 Si C Inorganic materials 0.000 description 2
- 238000007545 Vickers hardness test Methods 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910001566 austenite Inorganic materials 0.000 description 2
- 238000009749 continuous casting Methods 0.000 description 2
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- ZFGFKQDDQUAJQP-UHFFFAOYSA-N iron niobium Chemical compound [Fe].[Fe].[Nb] ZFGFKQDDQUAJQP-UHFFFAOYSA-N 0.000 description 2
- PNXOJQQRXBVKEX-UHFFFAOYSA-N iron vanadium Chemical compound [V].[Fe] PNXOJQQRXBVKEX-UHFFFAOYSA-N 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
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- 102220259718 rs34120878 Human genes 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- 229910001309 Ferromolybdenum Inorganic materials 0.000 description 1
- 101001121408 Homo sapiens L-amino-acid oxidase Proteins 0.000 description 1
- 102100026388 L-amino-acid oxidase Human genes 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003044 adaptive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 238000005255 carburizing Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/06—Surface hardening
- C21D1/09—Surface hardening by direct application of electrical or wave energy; by particle radiation
- C21D1/10—Surface hardening by direct application of electrical or wave energy; by particle radiation by electric induction
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/04—Making ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/20—Ferrous alloys, e.g. steel alloys containing chromium with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
Definitions
- the present invention relates to a steel material and a manufacturing method thereof, and in particular to a bearing steel and a manufacturing method thereof.
- the function of automobile wheel hub bearings is to support the vehicle body and guide the rotation of the wheels. They bear both axial and radial loads.
- the bearing steel used to manufacture automobile wheel hub bearings is generally medium carbon bearing steel, such as S55C, whose chemical composition is: C: 0.52-0.58%, Si: 0.15-0.35%, Mn: 0.60-0.90%, Cr ⁇ 0.20%, P ⁇ 0.030%, S ⁇ 0.035%, Ni ⁇ 0.20%, Cu ⁇ 0.30%, Ni+Cr ⁇ 0.35%.
- S55C medium carbon bearing steel
- wheel hub bearings made of existing bearing steel are prone to failure during use.
- the failure modes of wheel hub bearings mainly include fatigue failure, wear, corrosion, electrolytic corrosion, plastic deformation, and cracks. Therefore, wheel hub bearing steel needs to have fine grains, uniform hardness, corrosion resistance, high purity, and also good upsetting performance and die life.
- a Chinese patent document with publication number CN101376948B, publication date March 30, 2011, and titled "A method for manufacturing low-cost and high-purity medium-carbon bearing steel for automobile wheels” discloses a medium-carbon carbon bearing steel optimized on the basis of S55C, which reduces the range of carbon content to obtain a smaller raceway hardness difference, and limits the Al content to refine the grain size and reduce Al2O3 type inclusions.
- a Chinese patent document with publication number CN105568134A publication date May 11, 2016, and titled “A micro-alloyed carbon wheel hub bearing steel for passenger cars” has a chemical composition of C 0.45-0.70%, Si 0.10-0.50%, Mn 0.30-0.70%, Cr 0.20-0.60%, P ⁇ 0.025%, S 0.003-0.030%, Mo ⁇ 0.1%, Ni ⁇ 0.2%, and Al ⁇ 0.04%, and refines the grains by limiting the Al element content.
- One of the purposes of the present invention is to provide a bearing steel for a vehicle hub, which aims to improve the quenched martensite structure in the raceway of the automobile hub bearing steel by adding a trace amount of vanadium and niobium to the steel for microalloying, using alloy elements such as carbon, silicon, manganese, copper and performing corresponding composition design, in particular to improve the brinelling indentation phenomenon in the raceway of the automobile hub rolling bearing, and prevent the contact part between the rolling element and the raceway wheel from breaking due to the initiation of microcracks caused by Brinell damage.
- the present invention provides a bearing steel for a vehicle wheel hub, which contains Fe and inevitable impurities, and further contains the following chemical elements in the following mass percentages:
- the present invention also provides a bearing steel for a vehicle wheel hub, wherein the mass percentage of each chemical element is:
- the Brinell damage caused by vibration and shaking at the contact part of the rolling element and the raceway wheel is often the origin of micro-cracks.
- More than 50% of the wear caused by pseudo-Brinell indentation in the wheel hub bearing unit can be improved by packaging and lubrication.
- the present invention improves the quenched martensite structure in the raceway of the automobile hub bearing steel through the design of the chemical element composition system supplemented by an adaptive process, thereby improving the brinelling phenomenon of the raceway of the automobile hub rolling bearing and preventing the contact part between the rolling element and the raceway wheel from breaking due to the initiation of microcracks caused by Brinell damage.
- C It is generally believed that carbon will deteriorate toughness. However, in the present invention, carbon is an important element to ensure the strength, wear resistance and hardenability of bearing steel. In order to make the hardness of the high-frequency quenching raceway surface of the automobile hub bearing steel of the present invention reach 730-780HV and the depth of the hardened layer of the raceway surface reach 2.0-3.5mm, it is necessary to design a carbon content of 0.70-0.80%.
- Si Silicon can partially replace chromium and nickel elements to improve strength, and is also a good reducing agent and deoxidizer in the smelting process.
- silicon can reduce the concentration gradient of carbon, promote carbon diffusion in the austenite state, inhibit the precipitation of carbides, and improve toughness. Based on this, the silicon content of the present invention is controlled at 0.50-0.70% to meet the strength and toughness requirements in combination with other elements.
- Mn Manganese can partially replace chromium to maintain strength, and manganese is the main element that can significantly improve hardenability.
- manganese has the disadvantage of promoting austenite grain growth in steel, and the manganese content should be controlled.
- the present invention adds manganese content of 0.95-1.05%, so that it cooperates with carbon element to ensure that the hardness of the high-frequency quenching raceway surface reaches 730-780HV, and the depth of the hardened layer of the raceway surface reaches 2.0-3.5mm.
- Chromium can significantly improve strength, hardness and wear resistance, but at the same time reduce plasticity and toughness. Chromium and carbon in steel mainly form M23C. 0.60-0.70% chromium is added to the steel of the present invention.
- Cu Copper is generally controlled as a harmful element because the disadvantage of copper is that it is easy to become hot brittle during hot working, especially when the copper content exceeds 0.5%, the plasticity is significantly reduced. Due to different smelting methods, electric arc furnace smelting (the raw material is mainly scrap steel) often has a copper content of 0.10-0.20% without special control, while converter smelting (the raw material is mainly blast furnace iron) The copper content is generally less than 0.05% and requires additional addition of copper alloy. However, unlike the general prior art, 0.10-0.25% of Cu is added to the steel of the present invention to improve strength and toughness, and in addition, it can also improve atmospheric corrosion resistance. The inventor has shown through multiple rounds of laboratory experiments that 0.10-0.25% of copper can effectively improve the corrosion resistance of automobile wheel hub bearings, especially reduce atmospheric pitting and reduce surface peeling of bearings.
- Al It is generally believed that aluminum is a deoxidizer and a grain-refining element. However, the inventors have found through experiments that excessive Al often forms Al2O3 - type non-metallic inclusions. These non-metallic inclusions that are difficult to deform often become fatigue fracture sources and affect the impact resistance of the bearing. Based on this, the present invention controls the aluminum content in the finished steel to be 0.010-0.040%.
- Nb and V These two elements are microalloying elements added in the present invention.
- the present invention forms composite dispersed nano-scale carbide type precipitates by adding 0.025-0.035% niobium and 0.10-0.15% vanadium.
- the carbide type precipitates are mainly in the form of point-shaped and short rod-shaped carbides.
- the composite microalloy form of niobium and vanadium can refine the matrix structure and refine the texture of martensite in the raceway of the automobile hub bearing.
- Mo can generally improve hardenability and heat resistance and prevent temper brittleness.
- ferromolybdenum alloy is a precious alloy element, in the present invention, in order to avoid the formation of molybdenum-containing carbides that are difficult to deform, the present invention controls its upper limit to 0.01%.
- the chemical element mass percentage of the bearing steel for vehicle hub of the present invention also satisfies: 10Nb+V ⁇ 0.40%.
- 10Nb+V is in the range of 0.40-0.50%, preferably in the range of 0.40-0.46%.
- each element satisfies at least one of the following conditions: S ⁇ 0.015%; P ⁇ 0.015%; O ⁇ 0.0006%; H ⁇ 0.0001%; Ti ⁇ 0.0015%; Pb ⁇ 0.002%, As ⁇ 0.04%, Sn ⁇ 0.05%, Sb ⁇ 0.004%, Ca ⁇ 0.0010%.
- the above-mentioned elements are all impurity elements in the steel of the present invention, which will significantly reduce the plasticity and toughness of the steel. Therefore, their content should be reduced as much as possible under the technical conditions.
- the microstructure of the local quenching area of the bearing steel for vehicle hub of the present invention is a fine and uniform martensitic structure.
- the length of the needle-shaped martensite is ⁇ 10 ⁇ m.
- the bearing steel for vehicle hub of the present invention has a microstructure of ferrite+pearlite in the region not subjected to local quenching.
- the area ratio of pearlite is ⁇ 8%, preferably ⁇ 5%.
- the grain size of the local quenching area of the bearing steel for vehicle hub described in the present invention is 7-9.
- the maximum size of a single inclusion at any position of the bearing steel for vehicle hub of the present invention is ⁇ 27 ⁇ m. In some embodiments, the maximum size of a single inclusion at any position of the bearing steel for vehicle hub of the present invention is 9 to 27 ⁇ m.
- the local quenching area of the bearing steel for vehicle hub according to the present invention has dispersedly distributed composite nano-scale carbide precipitates, and the size of the carbide precipitates is 15nm-35nm.
- microhardness of the local quenching area of the bearing steel for vehicle hub described in the present invention is 730-780 HV, and the depth of the hardened layer is 2.0-3.5 mm.
- microhardness deviation of the bearing steel for vehicle hub according to the present invention at the same hardened layer depth in the local quenching area is ⁇ 40HV, such as 20-40HV or 30-40HV.
- the tensile strength of the bearing steel for vehicle wheel hub of the present invention is ⁇ 830MPa, preferably ⁇ 850MPa. In some embodiments, the tensile strength of the bearing steel for vehicle wheel hub of the present invention is in the range of 850-880MPa.
- the center segregation index ie, center C%/melting C%, is in the range of 0.95 to 1.05, preferably in the range of 0.98 to 1.02.
- Another object of the present invention is to provide a method for manufacturing bearing steel for vehicle wheel hubs, wherein the bearing steel for vehicle wheel hubs obtained can improve the brinelling phenomenon of the raceway of automobile wheel hub rolling bearings and prevent the contact part between the rolling element and the raceway wheel from breaking due to the initiation of microcracks caused by Brinell damage.
- the present invention provides a method for manufacturing a bearing steel for a vehicle wheel hub as described above, comprising the steps of:
- a three-step process flow can be adopted: the first step: initial smelting in an electric arc furnace (or converter) ⁇ vacuum refining in a ladle furnace ⁇ continuous casting; the second step: hot processing and rolling in a rolling mill; the third step: local quenching.
- an electric arc furnace (or converter) can be used for primary smelting of molten steel, followed by ladle refining, and then continuous casting to produce a steel billet of a certain size having a chemical composition in accordance with the present invention.
- the molten steel tapped from the primary refining furnace can reach: [P] ⁇ 0.025%, [C] ⁇ 0.05%, T ⁇ 1620°C for tapping. In some embodiments, the molten steel tapped from the primary refining furnace reaches: [P] ⁇ 0.015%, [C] ⁇ 0.10%, T ⁇ 1630°C for tapping.
- Manganese-aluminum alloy is added to the ladle during tapping, and Mn is added to the upper limit of the product composition at a recovery rate of 100%.
- the primary refining furnace is a converter, Cu alloy is added during tapping to control Cu to 0.10-0.20%.
- the aluminum content of the added manganese-aluminum alloy can be 15-25%.
- the heating station of the outer refining furnace (LF), low-basicity synthetic slag is added to the ladle for slag making, Al particles are used for precipitation deoxidation, Si-C powder is used for slag surface deoxidation, and the addition amount and batch are adjusted according to the slag condition and the silicon content in the steel, so that the refining process always maintains good deoxidation.
- the low-basicity slag can be adjusted once to control the basicity of the refining furnace top slag to 2-4.
- low-basicity synthetic slag with ingredients such as those shown in Table 1 of this application is added for slag making.
- the addition amount of synthetic slag can be 1 to 5 kg/t.
- ferroniobium and ferrovanadium can be added before vacuum degassing.
- Aluminum wire is fed to supplement aluminum to 0.025-0.040%.
- No aluminum wire is added after vacuum pumping.
- the temperature of the molten steel after vacuum degassing is 1530-1560°C.
- the ladle is calmed for more than 40 minutes, and Ar is soft-blown.
- the Ar pressure and flow rate are suitable for the liquid surface to vibrate slightly.
- the molten steel is poured continuously, and the superheat is controlled to be ⁇ 35°C.
- the soft pressure at the end of solidification and electromagnetic stirring technology are used to improve the segregation of steel.
- step (2) of the manufacturing method described in the present invention the temperature of the ingot entering the furnace is controlled to be 600-900°C and kept warm for 20-40 minutes; then the temperature is raised to 1180-1220°C after 120-200 minutes and kept warm for 80-180 minutes.
- the heating temperature of the steel billet is controlled to be 1160-1200° C.
- the heating time is 80-180 min
- the temperature difference on the surface of the steel billet is ⁇ 40° C.
- the final rolling temperature is 760-900° C.
- the temperature difference on the surface of the steel billet is controlled to be in the range of 20-40° C., such as 30-40° C.
- the present invention does not improve the local quenching process.
- an induction quenching device can be used for local quenching, the quenching temperature can be 880°C ⁇ 10°C, and the cooling method is water cooling.
- the bearing steel for vehicle wheel hub and the manufacturing method thereof according to the present invention have the following advantages and beneficial effects:
- the bearing steel for vehicle hub of the present invention is micro-alloyed by adding trace amounts of vanadium and niobium into the steel, and adopts alloy elements such as carbon, silicon, manganese, copper and the like and makes corresponding compositions, so as to form dispersed composite nano-scale carbide precipitates, thereby refining the structure of martensite in the raceway of the automobile hub bearing.
- the microhardness of the bearing steel for the vehicle hub of the present invention on the working surface can reach 730-780HV, the depth of the hardened layer can reach 2.0-3.5mm, and the microhardness deviation of the same hardened layer depth is ⁇ 40HV.
- the bearing steel for the vehicle wheel hub of the present invention has a low impurity content, and the maximum size of a single inclusion is ⁇ 27 ⁇ m.
- FIG. 1 shows the microstructure of a non-local quenching region of a bearing steel for a vehicle hub according to Example 3 of the present invention.
- FIG. 2 shows the microstructure of a local quenched area of a bearing steel for a vehicle hub according to Example 3 of the present invention.
- FIG. 3 shows the depth of the hardened layer in the local quenching area of the vehicle hub bearing steel according to Example 3 of the present invention.
- the bearing steels for vehicle hubs of Examples 1-7 are all prepared by the following steps:
- the steel liquid is primary refining in a 150-ton electric arc furnace.
- the tapping of steel from the primary refining furnace begins when the molten steel reaches: [P] ⁇ 0.015%, [C] ⁇ 0.10%, T ⁇ 1630°C.
- an appropriate amount of synthetic slag is added.
- a manganese-aluminum alloy is added to the ladle, in which the Al content can be 22%, and Mn is added to the upper limit of the product composition at a 100% recovery rate.
- Ladle refining furnace In the heating station of the refining furnace (LF), low basicity synthetic slag is added to the ladle.
- the composition of the synthetic slag can be shown in Table 1) 2kg/t slag making, Al particles are used for precipitation deoxidation, Si-C powder is used for slag surface deoxidation, and the addition amount and batch are adjusted according to the slag condition and the silicon content in the steel. For example, a batch can be added every 15 minutes, and the dosage can be 0.2-0.8kg/t, so that the refining process should always maintain good deoxidation. Adjust the low basicity slag once at the beginning of LF, and control the basicity of the top slag of the refining furnace to 2-4 or 3-4.
- the steel ingot is rolled into a 200 mm ⁇ 200 mm square steel billet using a primary rolling mill according to a conventional rolling process.
- the steel billet is transferred to the heating furnace of the rolling mill for heating.
- the heating temperature of the steel billet is controlled to be 1160-1200°C
- the heating time is 80-180 min
- the temperature difference on the surface of the steel billet is ⁇ 40°C
- the final rolling temperature is controlled to be 760-900°C.
- the induction quenching temperature is 880°C ⁇ 10°C
- the cooling method is water cooling.
- Table 1 lists a low-basicity synthetic slag used in the refining step of Examples 1-7 of the present invention, which is only illustrative and not limiting of the present invention.
- Table 2-1 and Table 2-2 list the mass percentages of various chemical elements in the bearing steels for vehicle hubs of Examples 1-7 of the present invention.
- Table 3-1 and Table 3-2 list the specific process parameters of the vehicle wheel hub bearing steel in each step of Examples 1-7.
- the inventors sampled the rolling bearing steel for vehicle hub Example 3 without local quenching and observed its microstructure under an optical microscope, as shown in FIG1 .
- the microstructure of the vehicle hub bearing steel in the area not subjected to local quenching is ferrite+pearlite.
- the inventors also sampled the partially quenched vehicle wheel hub bearing steel Example 3 and observed its microstructure under an optical microscope, as shown in FIG. 2 .
- the microstructure of the local quenching area of the bearing steel for vehicle hub is a fine and uniform martensite structure, the needle-like structure is not obvious, and the length of the needle-like martensite is ⁇ 10 ⁇ m.
- the local quenching area has dispersed composite nano-scale carbide precipitates, and the size of the carbide precipitates is 15nm-35nm.
- Hardness test Test according to the testing standard GB/T4043-1999 "Metal Vickers hardness test”.
- Grain size test The grain size of the bearing steel for vehicle wheel hub prepared in Examples 1-7 was evaluated by carburizing method.
- Maximum inclusion size test refer to GB/T 10561-2005 Standard rating chart microscopic inspection method for determination of non-metallic inclusion content in steel, inspection area ⁇ 300mm2, select the largest field of view for inclusion assessment.
- Table 4 lists the test results of the vehicle wheel hub bearing steels of Examples 1-7.
- the depth of the hardened layer in the local quenching area in Table 4 is a range value rather than a fixed value because the depth of the hardened layer in different positions of the same product is different. Therefore, the depth of the hardened layer of the same product is reflected as a range value rather than a fixed value.
- the hardness of the local quenching area of the bearing steel for vehicle hub of Examples 1-7 designed by the present invention is 730-780HV
- the depth of the hardened layer is 2.0-3.5mm
- the microhardness deviation of the local quenching area at the same hardened layer depth is ⁇ 40HV
- the tensile strength is ⁇ 852MPa. Therefore, it can effectively improve the Brinell indentation phenomenon of the raceway of the automobile hub rolling bearing and prevent the contact part of the rolling element and the raceway wheel from breaking due to the initiation of microcracks caused by Brinell damage.
- FIG. 3 shows the depth of the hardened layer in the local quenching area of the vehicle hub bearing steel according to Example 3 of the present invention.
- the depth of the hardened layer in the local quenching area of the bearing steel for a vehicle hub in Example 3 of the present invention is 2.0 to 3.5 mm.
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Abstract
Disclosed in the present invention is bearing steel for a vehicle hub. The bearing steel comprises Fe and inevitable impurities, and further comprises the following chemical elements in percentage by mass: 0.70-0.80% of C; 0.50-0.70% of Si; 0.95-1.05% of Mn; 0.60-0.70% of Cr; 0.10-0.25% of Cu, 0.010-0.040% of Al; 0.025-0.035% of Nb; and 0.10-0.15% of V. Accordingly, also disclosed in the present invention is a manufacturing method for the bearing steel for a vehicle hub. The present invention can ameliorate the Brinell indentation phenomenon of a rolling bearing raceway of the vehicle hub, and prevent breakage caused by micro-cracks generated due to Brinell damage of a contact part of a rolling body and a raceway roller.
Description
本发明涉及一种钢材及其制造方法,尤其涉及一种轴承钢及其制造方法。The present invention relates to a steel material and a manufacturing method thereof, and in particular to a bearing steel and a manufacturing method thereof.
汽车轮毂轴承的作用是支撑车体和引导车轮旋转,其既承受轴向载荷又承受径向载荷。The function of automobile wheel hub bearings is to support the vehicle body and guide the rotation of the wheels. They bear both axial and radial loads.
在现有技术中,用于制造汽车轮毂轴承的轴承钢一般为中碳轴承钢,例如S55C,其化学成分为:C:0.52~0.58%,Si:0.15~0.35%,Mn:0.60~0.90%,Cr≤0.20%,P≤0.030%,S≤0.035%,Ni≤0.20%,Cu≤0.30%,Ni+Cr≤0.35%。In the prior art, the bearing steel used to manufacture automobile wheel hub bearings is generally medium carbon bearing steel, such as S55C, whose chemical composition is: C: 0.52-0.58%, Si: 0.15-0.35%, Mn: 0.60-0.90%, Cr≤0.20%, P≤0.030%, S≤0.035%, Ni≤0.20%, Cu≤0.30%, Ni+Cr≤0.35%.
然而,采用现有的轴承钢制造的汽车轮毂轴承在使用过程中易于发生失效。轮毂轴承失效模主要包括疲劳失效、磨损、腐蚀、电蚀、塑性变形、裂纹。因此,轮毂轴承钢需要具有晶粒细小、均匀的硬度、耐腐蚀性能、高的纯净度,此外,还应该具有良好的镦锻性能和模具寿命。However, automobile wheel hub bearings made of existing bearing steel are prone to failure during use. The failure modes of wheel hub bearings mainly include fatigue failure, wear, corrosion, electrolytic corrosion, plastic deformation, and cracks. Therefore, wheel hub bearing steel needs to have fine grains, uniform hardness, corrosion resistance, high purity, and also good upsetting performance and die life.
对此,公开号为CN101376948B,公开日为2011年3月30日,名称为“一种低成本高纯净度汽车轮毂用中碳轴承钢的制造方法”的中国专利文献公开了一种在S55C基础上进行优化的中碳碳素轴承钢,其为获得较小的滚道面硬度差而缩小碳含量的范围,同时为细化晶粒尺寸和减少Al2O3类型夹杂物对Al含量进行限定。In this regard, a Chinese patent document with publication number CN101376948B, publication date March 30, 2011, and titled "A method for manufacturing low-cost and high-purity medium-carbon bearing steel for automobile wheels" discloses a medium-carbon carbon bearing steel optimized on the basis of S55C, which reduces the range of carbon content to obtain a smaller raceway hardness difference, and limits the Al content to refine the grain size and reduce Al2O3 type inclusions.
此外,公开号为CN105568134A,公开日为2016年5月11日,名称为“一种微合金化轿车碳素轮毂轴承用钢”的中国专利文献,其化学成分为C0.45~0.70%,Si0.10~0.50%,Mn0.30~0.70%,Cr0.20~0.60%,P≤0.025%,S0.003~0.030%,Mo≤0.1%,Ni≤0.2%,Al≤0.04%,其通过限定Al元素含量来细化晶粒。In addition, a Chinese patent document with publication number CN105568134A, publication date May 11, 2016, and titled “A micro-alloyed carbon wheel hub bearing steel for passenger cars” has a chemical composition of C 0.45-0.70%, Si 0.10-0.50%, Mn 0.30-0.70%, Cr 0.20-0.60%, P ≤ 0.025%, S 0.003-0.030%, Mo ≤ 0.1%, Ni ≤ 0.2%, and Al ≤ 0.04%, and refines the grains by limiting the Al element content.
发明内容
Summary of the invention
本发明的目的之一在于提供一种车辆轮毂用轴承钢,其旨在通过在钢中加入微量的钒、铌进行微合金化,采用碳、硅、锰、铜等合金元素并进行相应的成分设计,特别是改善汽车轮毂轴承钢滚道内淬火马氏体组织,以改善汽车轮毂滚动轴承滚道布氏压痕现象,防止滚动体和滚道轮的接触部分由于布氏损伤造成微裂的萌生而引起断裂。One of the purposes of the present invention is to provide a bearing steel for a vehicle hub, which aims to improve the quenched martensite structure in the raceway of the automobile hub bearing steel by adding a trace amount of vanadium and niobium to the steel for microalloying, using alloy elements such as carbon, silicon, manganese, copper and performing corresponding composition design, in particular to improve the brinelling indentation phenomenon in the raceway of the automobile hub rolling bearing, and prevent the contact part between the rolling element and the raceway wheel from breaking due to the initiation of microcracks caused by Brinell damage.
为了实现上述目的,本发明提供了一种车辆轮毂用轴承钢,其含有Fe和不可避免的杂质,其还含有质量百分比如下的下述化学元素:In order to achieve the above object, the present invention provides a bearing steel for a vehicle wheel hub, which contains Fe and inevitable impurities, and further contains the following chemical elements in the following mass percentages:
C:0.70~0.80%;Si:0.50~0.70%;Mn:0.95~1.05%;Cr:0.60~0.70%;Cu:0.10~0.25%;Al:0.010~0.040%;Nb:0.025~0.035%;V:0.10~0.15%。C: 0.70~0.80%; Si: 0.50~0.70%; Mn: 0.95~1.05%; Cr: 0.60~0.70%; Cu: 0.10~0.25%; Al: 0.010~0.040%; Nb: 0.025~0.035%; V :0.10~0.15%.
本发明还提供了一种车辆轮毂用轴承钢,其各化学元素质量百分比为:The present invention also provides a bearing steel for a vehicle wheel hub, wherein the mass percentage of each chemical element is:
C:0.70~0.80%;Si:0.50~0.70%;Mn:0.95~1.05%;Cr:0.60~0.70%;Cu:0.10~0.25%;Al:0.010~0.040%;Nb:0.025~0.035%;V:0.10~0.15%;余量为Fe和不可避免的杂质。C: 0.70~0.80%; Si: 0.50~0.70%; Mn: 0.95~1.05%; Cr: 0.60~0.70%; Cu: 0.10~0.25%; Al: 0.010~0.040%; Nb: 0.025~0.035%; V: 0.10~0.15%; the balance is Fe and inevitable impurities.
发明人通过研究发现,汽车轮毂滚动轴承滚道布氏压痕现象会降低套圈的断裂强度,在微振动期间,在滚动体和滚道轮的接触部分由于振动和摇动造成的布氏损伤往往是微裂萌生的起源。轮毂轴承单元中50%以上由伪布氏压痕引起的磨损,可以通过包装、润滑加以改善,此外其与淬硬层马氏体组织的织构有关。The inventors found through research that the Brinell indentation phenomenon on the raceway of automobile wheel hub rolling bearings will reduce the fracture strength of the rings. During micro-vibration, the Brinell damage caused by vibration and shaking at the contact part of the rolling element and the raceway wheel is often the origin of micro-cracks. More than 50% of the wear caused by pseudo-Brinell indentation in the wheel hub bearing unit can be improved by packaging and lubrication. In addition, it is related to the texture of the martensite structure of the hardened layer.
基于此,本发明通过化学元素成分体系的设计辅以适配的工艺,以改善汽车轮毂轴承钢滚道内淬火马氏体组织,从而改善汽车轮毂滚动轴承滚道布氏压痕现象,防止滚动体和滚道轮的接触部分由于布氏损伤造成微裂的萌生而引起断裂。Based on this, the present invention improves the quenched martensite structure in the raceway of the automobile hub bearing steel through the design of the chemical element composition system supplemented by an adaptive process, thereby improving the brinelling phenomenon of the raceway of the automobile hub rolling bearing and preventing the contact part between the rolling element and the raceway wheel from breaking due to the initiation of microcracks caused by Brinell damage.
在本发明所述的车辆轮毂用轴承钢中,各化学元素的设计原理如下所述:In the bearing steel for vehicle wheel hub of the present invention, the design principles of each chemical element are as follows:
C:一般认为,碳元素会使韧性恶化。然而,在本发明中,碳元素是保证轴承钢强度和耐磨、淬透性能的重要元素,为了使得本发明的汽车轮毂轴承钢高频淬火滚道面的硬度达到730~780HV,滚道面的淬硬层深度达到2.0~3.5mm,需要设计0.70~0.80%的碳含量。C: It is generally believed that carbon will deteriorate toughness. However, in the present invention, carbon is an important element to ensure the strength, wear resistance and hardenability of bearing steel. In order to make the hardness of the high-frequency quenching raceway surface of the automobile hub bearing steel of the present invention reach 730-780HV and the depth of the hardened layer of the raceway surface reach 2.0-3.5mm, it is necessary to design a carbon content of 0.70-0.80%.
Si:硅能部分替代铬、镍元素作用提高强度,在冶炼过程还是很好的还原剂和脱氧剂。不仅如此,在本发明中,硅能降低碳的浓度梯度,在奥氏体状态下促进碳扩散作用,它能抑制碳化物的析出,可以提高韧性。基于此,本发明硅控制在0.50-0.70%%,以与其他元素配合满足强韧性要求。Si: Silicon can partially replace chromium and nickel elements to improve strength, and is also a good reducing agent and deoxidizer in the smelting process. In addition, in the present invention, silicon can reduce the concentration gradient of carbon, promote carbon diffusion in the austenite state, inhibit the precipitation of carbides, and improve toughness. Based on this, the silicon content of the present invention is controlled at 0.50-0.70% to meet the strength and toughness requirements in combination with other elements.
Mn:锰能部分代替铬以保持强度,而且锰是能显著提高淬透性的主要元素。但是锰在钢中有促进奥氏体化晶粒长大的缺点,对锰的含量应加以控制。基于此,本发明添加锰含量为0.95~1.05%,使得其与碳元素配合,保证高频淬火滚道面的硬度达到730~780HV,滚道面的淬硬层深度达到2.0~3.5mm。Mn: Manganese can partially replace chromium to maintain strength, and manganese is the main element that can significantly improve hardenability. However, manganese has the disadvantage of promoting austenite grain growth in steel, and the manganese content should be controlled. Based on this, the present invention adds manganese content of 0.95-1.05%, so that it cooperates with carbon element to ensure that the hardness of the high-frequency quenching raceway surface reaches 730-780HV, and the depth of the hardened layer of the raceway surface reaches 2.0-3.5mm.
Cr:铬能显著提高强度、硬度和耐磨性,但同时降低塑性和韧性。铬在钢中与碳主要形成M23C,本发明钢中添加铬0.60~0.70%。Cr: Chromium can significantly improve strength, hardness and wear resistance, but at the same time reduce plasticity and toughness. Chromium and carbon in steel mainly form M23C. 0.60-0.70% chromium is added to the steel of the present invention.
Cu:铜元素一般作为有害元素控制,因为铜的缺点是在热加工时容易产生热脆,特别是铜含量超过0.5%塑性显著降低。由于冶炼方式的不同,电弧炉冶炼(原料以废钢为主)往往铜含量在0.10~0.20%无需特殊控制,而转炉冶炼(原料以高炉铁水为主)铜含量一般小于0.05%需要额外添加铜合金。然而,与一般现有技术不同的是,本发明钢中添加0.10~0.25%的Cu,旨在提高强度和韧性,此外还能提高大气腐蚀性能。发明人经过实验室多轮次的实验表明,0.10~0.25%的铜能有效提高汽车轮毂轴承的耐腐蚀性能,特别是减少大气的点蚀,减少轴承的表面剥落。Cu: Copper is generally controlled as a harmful element because the disadvantage of copper is that it is easy to become hot brittle during hot working, especially when the copper content exceeds 0.5%, the plasticity is significantly reduced. Due to different smelting methods, electric arc furnace smelting (the raw material is mainly scrap steel) often has a copper content of 0.10-0.20% without special control, while converter smelting (the raw material is mainly blast furnace iron) The copper content is generally less than 0.05% and requires additional addition of copper alloy. However, unlike the general prior art, 0.10-0.25% of Cu is added to the steel of the present invention to improve strength and toughness, and in addition, it can also improve atmospheric corrosion resistance. The inventor has shown through multiple rounds of laboratory experiments that 0.10-0.25% of copper can effectively improve the corrosion resistance of automobile wheel hub bearings, especially reduce atmospheric pitting and reduce surface peeling of bearings.
Al:一般认为,铝是脱氧剂和细化晶粒元素。然而,发明人通过试验发现,过多的Al往往会形成Al2O3类非金属夹杂物,这些难变形的非金属夹杂物往往会成为疲劳断裂源,影响轴承的抗冲击性能。基于此,本发明控制成品钢中的铝含量为0.010~0.040%。Al: It is generally believed that aluminum is a deoxidizer and a grain-refining element. However, the inventors have found through experiments that excessive Al often forms Al2O3 - type non-metallic inclusions. These non-metallic inclusions that are difficult to deform often become fatigue fracture sources and affect the impact resistance of the bearing. Based on this, the present invention controls the aluminum content in the finished steel to be 0.010-0.040%.
Nb和V:这两种元素是本发明中添加的微合金化元素,本发明通过添加0.025-0.035%的铌以及0.10-0.15%的钒,以形成复合的弥散的纳米级碳化物类型的析出物,碳化物类型的析出物主要以点状和短棒状的碳化物。在发明钢的基础成分上,采用铌和钒的复合微合金形式,能细化基体组织,使得汽车轮毂轴承滚道内马氏体的织构细化。Nb and V: These two elements are microalloying elements added in the present invention. The present invention forms composite dispersed nano-scale carbide type precipitates by adding 0.025-0.035% niobium and 0.10-0.15% vanadium. The carbide type precipitates are mainly in the form of point-shaped and short rod-shaped carbides. Based on the basic components of the invention steel, the composite microalloy form of niobium and vanadium can refine the matrix structure and refine the texture of martensite in the raceway of the automobile hub bearing.
Mo:Mo一般可以提高淬透性和热强性,防止回火脆性,但由于钼铁合金属于贵重的合金元素,在本发明中,为了避免形成难以变形的含钼碳化物,本发明控制其上限为0.01%。Mo: Mo can generally improve hardenability and heat resistance and prevent temper brittleness. However, since ferromolybdenum alloy is a precious alloy element, in the present invention, in order to avoid the formation of molybdenum-containing carbides that are difficult to deform, the present invention controls its upper limit to 0.01%.
进一步地,本发明所述的车辆轮毂用轴承钢的化学元素质量百分含量还满足:10Nb+V≥0.40%。在一些实施方案中,10Nb+V在0.40~0.50%的范围内,优选在0.40~0.46%的范围内。
Furthermore, the chemical element mass percentage of the bearing steel for vehicle hub of the present invention also satisfies: 10Nb+V≥0.40%. In some embodiments, 10Nb+V is in the range of 0.40-0.50%, preferably in the range of 0.40-0.46%.
满足上述公式,可以进一步保证本发明的微合金化效果。Satisfying the above formula can further ensure the microalloying effect of the present invention.
进一步地,在本发明所述的车辆轮毂用轴承钢的不可避免的杂质中,各元素满足下列各项的至少其中之一:S≤0.015%;P≤0.015%;O≤0.0006%;H≤0.0001%;Ti≤0.0015%;Pb≤0.002%,As≤0.04%,Sn≤0.05%,Sb≤0.004%,Ca≤0.0010%。Furthermore, among the inevitable impurities in the bearing steel for vehicle hub according to the present invention, each element satisfies at least one of the following conditions: S≤0.015%; P≤0.015%; O≤0.0006%; H≤0.0001%; Ti≤0.0015%; Pb≤0.002%, As≤0.04%, Sn≤0.05%, Sb≤0.004%, Ca≤0.0010%.
上述这些元素均是本发明钢中的杂质元素,其会显著降低钢的塑性和韧性,因此在技术条件允许情况下应尽可能降低其含量。The above-mentioned elements are all impurity elements in the steel of the present invention, which will significantly reduce the plasticity and toughness of the steel. Therefore, their content should be reduced as much as possible under the technical conditions.
进一步地,本发明所述的车辆轮毂用轴承钢的局部淬火区域的显微组织为细小均匀的马氏体组织。在一些实施方案中,所述马氏体组织中,针状马氏体的长度≤10μm。Furthermore, the microstructure of the local quenching area of the bearing steel for vehicle hub of the present invention is a fine and uniform martensitic structure. In some embodiments, in the martensitic structure, the length of the needle-shaped martensite is ≤10 μm.
进一步地,本发明所述的车辆轮毂用轴承钢,其未进行局部淬火的区域的显微组织为铁素体+珠光体。在一些实施方案中,未进行局部淬火的区域的显微组织中,珠光体的面积比≤8%,优选≤5%。Furthermore, the bearing steel for vehicle hub of the present invention has a microstructure of ferrite+pearlite in the region not subjected to local quenching. In some embodiments, in the microstructure of the region not subjected to local quenching, the area ratio of pearlite is ≤8%, preferably ≤5%.
进一步地,本发明所述的车辆轮毂用轴承钢的局部淬火区域的晶粒度为7-9级。Furthermore, the grain size of the local quenching area of the bearing steel for vehicle hub described in the present invention is 7-9.
进一步地,本发明所述的车辆轮毂用轴承钢,其任意位置的单颗最大夹杂物尺寸≤27μm。在一些实施方案中,本发明所述的车辆轮毂用轴承钢,其任意位置的单颗最大夹杂物尺寸为9~27μm。Furthermore, the maximum size of a single inclusion at any position of the bearing steel for vehicle hub of the present invention is ≤27 μm. In some embodiments, the maximum size of a single inclusion at any position of the bearing steel for vehicle hub of the present invention is 9 to 27 μm.
进一步地,本发明所述的车辆轮毂用轴承钢的局部淬火区域具有弥散分布的复合的纳米级碳化物析出物,所述碳化物析出物的尺寸为15nm-35nm。Furthermore, the local quenching area of the bearing steel for vehicle hub according to the present invention has dispersedly distributed composite nano-scale carbide precipitates, and the size of the carbide precipitates is 15nm-35nm.
进一步地,本发明所述的车辆轮毂用轴承钢的局部淬火区域的显微硬度为730~780HV,淬硬层深度为2.0~3.5mm。Furthermore, the microhardness of the local quenching area of the bearing steel for vehicle hub described in the present invention is 730-780 HV, and the depth of the hardened layer is 2.0-3.5 mm.
进一步地,本发明所述的车辆轮毂用轴承钢,其局部淬火区域的同一硬化层深度的显微硬度偏差≤40HV,如20~40HV或30~40HV。Furthermore, the microhardness deviation of the bearing steel for vehicle hub according to the present invention at the same hardened layer depth in the local quenching area is ≤40HV, such as 20-40HV or 30-40HV.
进一步地,本发明所述的车辆轮毂用轴承钢的抗拉强度≥830MPa,优选≥850MPa。在一些实施方案中,本发明所述的车辆轮毂用轴承钢的抗拉强度在850~880MPa范围内。Furthermore, the tensile strength of the bearing steel for vehicle wheel hub of the present invention is ≥830MPa, preferably ≥850MPa. In some embodiments, the tensile strength of the bearing steel for vehicle wheel hub of the present invention is in the range of 850-880MPa.
进一步地,本发明所述的车辆轮毂用轴承钢中,中心偏析指数,即中心C%/熔炼C%,在0.95~1.05的范围内,优选在0.98~1.02的范围内。Furthermore, in the bearing steel for vehicle hub according to the present invention, the center segregation index, ie, center C%/melting C%, is in the range of 0.95 to 1.05, preferably in the range of 0.98 to 1.02.
本发明的另一目的在于提供一种车辆轮毂用轴承钢的制造方法,其获得的车辆轮毂用轴承钢可以改善汽车轮毂滚动轴承滚道布氏压痕现象,防止滚动体和滚道轮的接触部分由于布氏损伤造成微裂的萌生而引起断裂。Another object of the present invention is to provide a method for manufacturing bearing steel for vehicle wheel hubs, wherein the bearing steel for vehicle wheel hubs obtained can improve the brinelling phenomenon of the raceway of automobile wheel hub rolling bearings and prevent the contact part between the rolling element and the raceway wheel from breaking due to the initiation of microcracks caused by Brinell damage.
为了实现上述目的,本发明提供了一种如上文所述的车辆轮毂用轴承钢的制造方法,其包括步骤:In order to achieve the above object, the present invention provides a method for manufacturing a bearing steel for a vehicle wheel hub as described above, comprising the steps of:
(1)冶炼、精炼和浇注;(1) Smelting, refining and casting;
(2)采用加热炉对铸坯进行加热;(2) heating the ingot using a heating furnace;
(3)采用初轧机开坯,得到钢坯;(3) using a primary rolling mill to produce a steel billet;
(4)对钢坯进行加热,然后轧制成棒材;(4) heating the steel billet and then rolling it into a bar;
(5)对用作车辆轮毂滚道面的区域进行局部淬火。(5) Local quenching of the area used as the wheel hub raceway surface.
在本发明的高温渗碳轴承钢的制造方法中,可以采用三步法工艺流程:第一步:电弧炉(或转炉)初炼→钢包炉真空精炼→连铸浇注;第二步:轧钢机热加工轧制成材;第三步:局部淬火。In the manufacturing method of high-temperature carburized bearing steel of the present invention, a three-step process flow can be adopted: the first step: initial smelting in an electric arc furnace (or converter) → vacuum refining in a ladle furnace → continuous casting; the second step: hot processing and rolling in a rolling mill; the third step: local quenching.
其中,在步骤(1)中,可以采用电弧炉(或转炉)进行钢液初炼,然后进行钢包精炼,然后连铸浇注,以生产出化学成分符合本发明的一定尺寸的钢坯。In step (1), an electric arc furnace (or converter) can be used for primary smelting of molten steel, followed by ladle refining, and then continuous casting to produce a steel billet of a certain size having a chemical composition in accordance with the present invention.
其中,在钢液初炼时,初炼炉出钢钢水可以达到:[P]≤0.025%,[C]≥0.05%,T≥1620℃开始出钢。在一些实施方案中,初炼炉出钢钢水达到:[P]≤0.015%,[C]≥0.10%,T≥1630℃开始出钢。出钢时在钢包中加入锰铝合金,Mn按100%回收率加到产品成分中上限,初炼炉为转炉时,出钢添加Cu合金控制Cu到0.10-0.20%。在一些实施方案中,加入的锰铝合金合金中,铝的含量可以为15~25%。Wherein, during the initial refining of the molten steel, the molten steel tapped from the primary refining furnace can reach: [P]≤0.025%, [C]≥0.05%, T≥1620°C for tapping. In some embodiments, the molten steel tapped from the primary refining furnace reaches: [P]≤0.015%, [C]≥0.10%, T≥1630°C for tapping. Manganese-aluminum alloy is added to the ladle during tapping, and Mn is added to the upper limit of the product composition at a recovery rate of 100%. When the primary refining furnace is a converter, Cu alloy is added during tapping to control Cu to 0.10-0.20%. In some embodiments, the aluminum content of the added manganese-aluminum alloy can be 15-25%.
其中,在钢包精炼炉,炉外精炼炉(LF)加热工位,钢包中加入低碱度合成渣进行造渣,采用Al粒进行沉淀脱氧,Si-C粉进行渣面脱氧,根据渣况以及钢中硅含量情况调整加入量及加入批次,使精炼过程始终保持脱氧良好。在LF初期,可以一次性调整低碱度渣,控制精炼炉顶渣碱度为2-4。在一些实施方案中,加入成分如本申请表1所示的低碱度合成渣进行造渣。合成渣的添加量可为1~5kg/t。Among them, in the ladle refining furnace, the heating station of the outer refining furnace (LF), low-basicity synthetic slag is added to the ladle for slag making, Al particles are used for precipitation deoxidation, Si-C powder is used for slag surface deoxidation, and the addition amount and batch are adjusted according to the slag condition and the silicon content in the steel, so that the refining process always maintains good deoxidation. In the early stage of LF, the low-basicity slag can be adjusted once to control the basicity of the refining furnace top slag to 2-4. In some embodiments, low-basicity synthetic slag with ingredients such as those shown in Table 1 of this application is added for slag making. The addition amount of synthetic slag can be 1 to 5 kg/t.
其中,进真空脱气前可以加入铌铁和钒铁。喂铝丝补铝至0.025~0.040%。真空退泵后不添加铝线。真空脱气结束后钢液的温度为1530~1560℃。Among them, ferroniobium and ferrovanadium can be added before vacuum degassing. Aluminum wire is fed to supplement aluminum to 0.025-0.040%. No aluminum wire is added after vacuum pumping. The temperature of the molten steel after vacuum degassing is 1530-1560℃.
在浇注时,真空精炼结束后,钢包镇静40分钟以上,软吹Ar,Ar压力流量以液面微微颤动为宜。钢液采用连续浇注,控制过热度≤35℃,采用凝固末端轻压下和电磁搅拌技术改善钢材的偏析。During pouring, after vacuum refining, the ladle is calmed for more than 40 minutes, and Ar is soft-blown. The Ar pressure and flow rate are suitable for the liquid surface to vibrate slightly. The molten steel is poured continuously, and the superheat is controlled to be ≤35℃. The soft pressure at the end of solidification and electromagnetic stirring technology are used to improve the segregation of steel.
进一步地,在本发明所述的制造方法的步骤(2)中,控制铸坯入炉温度为600~900℃,保温20~40min;然后经过120~200min升温至1180~1220℃,保温80~180min。Furthermore, in step (2) of the manufacturing method described in the present invention, the temperature of the ingot entering the furnace is controlled to be 600-900°C and kept warm for 20-40 minutes; then the temperature is raised to 1180-1220°C after 120-200 minutes and kept warm for 80-180 minutes.
进一步地,在本发明所述的制造方法的步骤(4)中,控制钢坯加热温度为1160~1200℃,加热时间为80~180min,钢坯表面温差≤40℃,终轧温度为760~900℃。在一些实施方案中,控制钢坯表面温差在20~40℃的范围内,如30~40℃。Further, in step (4) of the manufacturing method of the present invention, the heating temperature of the steel billet is controlled to be 1160-1200° C., the heating time is 80-180 min, the temperature difference on the surface of the steel billet is ≤40° C., and the final rolling temperature is 760-900° C. In some embodiments, the temperature difference on the surface of the steel billet is controlled to be in the range of 20-40° C., such as 30-40° C.
本发明未对局部淬火工艺进行改进,在本发明中可以采用感应淬火装置进行局部淬火,淬火温度可以为880℃±10℃,冷却方式为水冷。The present invention does not improve the local quenching process. In the present invention, an induction quenching device can be used for local quenching, the quenching temperature can be 880°C±10°C, and the cooling method is water cooling.
相较于现有技术,本发明所述的车辆轮毂用轴承钢及其制造方法具有如下所述的优点以及有益效果:Compared with the prior art, the bearing steel for vehicle wheel hub and the manufacturing method thereof according to the present invention have the following advantages and beneficial effects:
本发明所述的车辆轮毂用轴承钢通过在钢中加入微量的钒、铌进行微合金化,采用碳、硅、锰、铜等合金元素并进行相应的成分,形成了弥散分布的复合的纳米级碳化物析出物,从而细化了汽车轮毂轴承滚道内马氏体的组织。The bearing steel for vehicle hub of the present invention is micro-alloyed by adding trace amounts of vanadium and niobium into the steel, and adopts alloy elements such as carbon, silicon, manganese, copper and the like and makes corresponding compositions, so as to form dispersed composite nano-scale carbide precipitates, thereby refining the structure of martensite in the raceway of the automobile hub bearing.
本发明所述的车辆轮毂用轴承钢在工作面的显微硬度可以达到730~780HV,淬硬层深度可以达到2.0~3.5mm,同一硬化层深度显微硬度偏差≤40HV。The microhardness of the bearing steel for the vehicle hub of the present invention on the working surface can reach 730-780HV, the depth of the hardened layer can reach 2.0-3.5mm, and the microhardness deviation of the same hardened layer depth is ≤40HV.
本发明所述的车辆轮毂用轴承钢,杂质含量低,单颗最大夹杂物尺寸≤27μm。The bearing steel for the vehicle wheel hub of the present invention has a low impurity content, and the maximum size of a single inclusion is ≤27 μm.
图1显示了本发明实施例3的车辆轮毂用轴承钢的非局部淬火区域的微观组织。FIG. 1 shows the microstructure of a non-local quenching region of a bearing steel for a vehicle hub according to Example 3 of the present invention.
图2显示了本发明实施例3的车辆轮毂用轴承钢的局部淬火区域的微观组织。FIG. 2 shows the microstructure of a local quenched area of a bearing steel for a vehicle hub according to Example 3 of the present invention.
图3显示了本发明实施例3的车辆轮毂用轴承钢的局部淬火区域的淬硬层深度。FIG. 3 shows the depth of the hardened layer in the local quenching area of the vehicle hub bearing steel according to Example 3 of the present invention.
下面将结合说明书附图和具体的实施例对本发明所述的车辆轮毂用轴承钢及其制造方法做进一步的解释和说明,然而该解释和说明并不对本发明的技术方案构成不当限定。The bearing steel for vehicle wheel hub and the manufacturing method thereof according to the present invention will be further explained and illustrated below in conjunction with the drawings and specific embodiments of the specification. However, such explanation and illustration do not constitute an improper limitation on the technical solution of the present invention.
实施例1-7Examples 1-7
实施例1-7的车辆轮毂用轴承钢均采用以下步骤制得:The bearing steels for vehicle hubs of Examples 1-7 are all prepared by the following steps:
(1)冶炼、精炼和浇注:(1) Smelting, refining and casting:
初炼:在150吨的电弧炉中进行钢液初炼,初炼炉出钢钢水达到:[P]≤0.015%,[C]≥0.10%,T≥1630℃开始出钢,出钢后期加入适量的合成渣。出钢时在钢包中加入锰铝合金,其中含Al量可以为22%,Mn按100%回收率加到产品成分中上限。Primary refining: The steel liquid is primary refining in a 150-ton electric arc furnace. The tapping of steel from the primary refining furnace begins when the molten steel reaches: [P] ≤ 0.015%, [C] ≥ 0.10%, T ≥ 1630°C. In the later stage of tapping, an appropriate amount of synthetic slag is added. When tapping, a manganese-aluminum alloy is added to the ladle, in which the Al content can be 22%, and Mn is added to the upper limit of the product composition at a 100% recovery rate.
钢包精炼炉:炉外精炼炉(LF)加热工位,钢包中加入低碱度合成渣,合成渣成分可以如表1所示)2kg/t造渣,采用Al粒进行沉淀脱氧,Si-C粉进行渣面脱氧,根据渣况及钢中硅含量,调整加入量及加入批次,例如可以每间隔15分钟加入一批,用量可以为0.2-0.8kg/t,使精炼过程要始终保持脱氧良好。在LF初期一次性调整低碱度渣,控制精炼炉顶渣碱度为2-4或者3-4。进真空脱气前加入铌铁和钒铁,收得率按95%计算。喂铝丝补铝至0.025~0.040%。真空退泵后不添加铝线。真空结束后温度为1530~1560℃。Ladle refining furnace: In the heating station of the refining furnace (LF), low basicity synthetic slag is added to the ladle. The composition of the synthetic slag can be shown in Table 1) 2kg/t slag making, Al particles are used for precipitation deoxidation, Si-C powder is used for slag surface deoxidation, and the addition amount and batch are adjusted according to the slag condition and the silicon content in the steel. For example, a batch can be added every 15 minutes, and the dosage can be 0.2-0.8kg/t, so that the refining process should always maintain good deoxidation. Adjust the low basicity slag once at the beginning of LF, and control the basicity of the top slag of the refining furnace to 2-4 or 3-4. Add ferroniobium and ferrovanadium before vacuum degassing, and the recovery rate is calculated as 95%. Feed aluminum wire to supplement aluminum to 0.025-0.040%. No aluminum wire is added after vacuum pumping. The temperature after vacuum is over is 1530-1560℃.
浇注:真空精炼结束后,钢包镇静40分钟以上,软吹Ar(Ar压力流量以液面微微颤动为宜)。钢液采用连续浇注,控制过热度≤35℃,采用末端轻压下和电磁搅拌技术改善钢材的偏析。生产出化学成分符合表的320mm×425mm方坯。Pouring: After vacuum refining, the ladle is calmed for more than 40 minutes, and Ar is softly blown (the Ar pressure and flow rate are suitable for slight vibration of the liquid surface). The molten steel is continuously poured, and the superheat is controlled to be ≤35℃. The end light pressure and electromagnetic stirring technology are used to improve the segregation of the steel. A 320mm×425mm square billet with chemical composition in accordance with the table is produced.
(2)采用加热炉对铸坯进行加热:控制铸坯入炉温度为600~900℃,保温20~40min;然后经过120~200min升温至1180~1220℃,保温80~180min。(2) Use a heating furnace to heat the ingot: control the ingot temperature to 600-900°C and keep it at that temperature for 20-40 minutes; then heat it to 1180-1220°C after 120-200 minutes and keep it at that temperature for 80-180 minutes.
(3)采用初轧机按常规轧制工艺开坯,将钢锭轧制开坯成200mm×200mm方钢坯。(3) The steel ingot is rolled into a 200 mm × 200 mm square steel billet using a primary rolling mill according to a conventional rolling process.
(4)对钢坯进行加热,然后轧制成棒材:将钢坯转移至轧钢机加热炉加热,控制钢坯加热温度为1160~1200℃,加热时间为80~180min,钢坯表面温差≤40℃,控制终轧温度为760~900℃。(4) Heating the steel billet and then rolling it into bars: The steel billet is transferred to the heating furnace of the rolling mill for heating. The heating temperature of the steel billet is controlled to be 1160-1200°C, the heating time is 80-180 min, the temperature difference on the surface of the steel billet is ≤40°C, and the final rolling temperature is controlled to be 760-900°C.
(5)对用作车辆轮毂滚道面(也即工作面)的区域进行局部淬火:感应淬火温度为880℃±10℃,冷却方式为水冷。
(5) Local quenching of the area used as the wheel hub raceway surface (i.e., the working surface): the induction quenching temperature is 880°C ± 10°C, and the cooling method is water cooling.
表1列出了本发明的实施例1-7在精炼步骤中采用的一种低碱度合成渣,其仅为示例性,并非对本发明的限制。Table 1 lists a low-basicity synthetic slag used in the refining step of Examples 1-7 of the present invention, which is only illustrative and not limiting of the present invention.
表1.(wt%)
Table 1. (wt%)
Table 1. (wt%)
表2-1和表2-2列出了本发明实施例1-7的车辆轮毂用轴承钢中的各化学元素质量百分比。Table 2-1 and Table 2-2 list the mass percentages of various chemical elements in the bearing steels for vehicle hubs of Examples 1-7 of the present invention.
表2-1.(wt%,余量为Fe和除S、P、O、H、Ti、Pb、As、Sn、Sb、Ca以外其他不可避免的杂质)
Table 2-1. (wt%, the balance is Fe and other inevitable impurities except S, P, O, H, Ti, Pb, As, Sn, Sb, Ca)
Table 2-1. (wt%, the balance is Fe and other inevitable impurities except S, P, O, H, Ti, Pb, As, Sn, Sb, Ca)
表2-2.(wt%,余量为Fe和除S、P、O、H、Ti、Pb、As、Sn、Sb、Ca以外其他不可避免的杂质)
Table 2-2. (wt%, the balance is Fe and other inevitable impurities except S, P, O, H, Ti, Pb, As, Sn, Sb, Ca)
Table 2-2. (wt%, the balance is Fe and other inevitable impurities except S, P, O, H, Ti, Pb, As, Sn, Sb, Ca)
表3-1和表3-2列出了实施例1-7的车辆轮毂用轴承钢在各步骤的具体工艺参数。Table 3-1 and Table 3-2 list the specific process parameters of the vehicle wheel hub bearing steel in each step of Examples 1-7.
表3-1.
Table 3-1.
Table 3-1.
表3-2.
Table 3-2.
Table 3-2.
发明人对轧制获得的车辆轮毂用轴承钢实施例3在未进行局部淬火的情况下进行取样,在光学显微镜下观察其微观组织,如图1所示。The inventors sampled the rolling bearing steel for vehicle hub Example 3 without local quenching and observed its microstructure under an optical microscope, as shown in FIG1 .
如图1所示的,该车辆轮毂用轴承钢在未进行局部淬火的区域的显微组织为铁素体+珠光体。
As shown in FIG. 1 , the microstructure of the vehicle hub bearing steel in the area not subjected to local quenching is ferrite+pearlite.
此外,发明人还对经过局部淬火的车辆轮毂用轴承钢实施例3进行取样,在光学显微镜下观察其微观组织,如图2所示。In addition, the inventors also sampled the partially quenched vehicle wheel hub bearing steel Example 3 and observed its microstructure under an optical microscope, as shown in FIG. 2 .
如图2所示的,该车辆轮毂用轴承钢的局部淬火区域的显微组织为细小均匀的马氏体组织,其针状组织不明显,针状马氏体的长度≤10μm。另外,还可以看出该局部淬火区域具有弥散分布的复合的纳米级碳化物析出物,所述碳化物析出物的尺寸为15nm-35nm。As shown in Figure 2, the microstructure of the local quenching area of the bearing steel for vehicle hub is a fine and uniform martensite structure, the needle-like structure is not obvious, and the length of the needle-like martensite is ≤10μm. In addition, it can be seen that the local quenching area has dispersed composite nano-scale carbide precipitates, and the size of the carbide precipitates is 15nm-35nm.
对各实施例的试样进行各项测试,所得的测试结果列于表4中。相关性能测试手段,如下所述:Various tests were performed on the samples of each embodiment, and the test results obtained are listed in Table 4. The relevant performance test methods are as follows:
硬度试验:按检测标准GB/T4043-1999《金属维氏硬度试验》进行检验。Hardness test: Test according to the testing standard GB/T4043-1999 "Metal Vickers hardness test".
淬硬层深度:感应淬火后检测硬度测量仪器检验硬化层深度,当显微硬度计检测梯度到一定值测量其距离表面的位移,具体硬度值的检测按检测标准GB/T4043-1999《金属维氏硬度试验》进行检验。具体为:硬度压痕应当打在垂直于表面的一条或多条平行线上,而且宽度为1.5mm区域内,最靠近表面的压痕中心与表面的距离为0.15mm,从表面到各逐次压痕中心的距离应每次增加0.1mm。当硬度值为HV=550时为不再进行硬度的测量,计算表面到HV=550硬度值所在的点的位移,为表面硬化层深度。Depth of hardened layer: After induction quenching, the hardness measuring instrument is used to test the depth of the hardened layer. When the microhardness tester detects the gradient to a certain value, the displacement from the surface is measured. The specific hardness value is tested according to the test standard GB/T4043-1999 "Metal Vickers Hardness Test". Specifically: the hardness indentation should be made on one or more parallel lines perpendicular to the surface, and within the 1.5mm width area, the distance between the center of the indentation closest to the surface and the surface is 0.15mm, and the distance from the surface to the center of each successive indentation should increase by 0.1mm each time. When the hardness value is HV=550, the hardness is no longer measured, and the displacement from the surface to the point where the hardness value of HV=550 is located is calculated as the depth of the surface hardened layer.
力学性能测试:在室温条件下,采用GB/T228进行检测,由此测得实施例1-7的抗拉强度。Mechanical property test: At room temperature, GB/T228 was used to test and the tensile strength of Examples 1-7 was measured.
中心偏析指数测试:参照GB/T 223.86《钢铁及合金总碳含量的测定感应炉燃烧后红外吸收法》分析任意棒材截面的碳含量。Central segregation index test: refer to GB/T 223.86 "Determination of total carbon content of steel and alloys - Infrared absorption method after induction furnace combustion" to analyze the carbon content of any bar cross section.
晶粒度测试:利用渗碳法评定实施例1-7所制备的车辆轮毂用轴承钢的晶粒度。Grain size test: The grain size of the bearing steel for vehicle wheel hub prepared in Examples 1-7 was evaluated by carburizing method.
最大夹杂物尺寸测试:参照GB/T 10561-2005钢中非金属夹杂物含量的测定标准评级图显微检验法,检验面积≥300mm2,选取夹杂物最大的视场进行评定。Maximum inclusion size test: refer to GB/T 10561-2005 Standard rating chart microscopic inspection method for determination of non-metallic inclusion content in steel, inspection area ≥ 300mm2, select the largest field of view for inclusion assessment.
表4列出了针对实施例1-7的车辆轮毂用轴承钢的测试结果。Table 4 lists the test results of the vehicle wheel hub bearing steels of Examples 1-7.
表4.
注:表4中的局部淬火区域淬硬层深度为范围值而非定值,是因为同一产品不用位置的淬硬层深度
是不同的,因此同一产品的淬硬层深度体现为范围值而非定值。Table 4.
Note: The depth of the hardened layer in the local quenching area in Table 4 is a range value rather than a fixed value because the depth of the hardened layer in different positions of the same product is different. Therefore, the depth of the hardened layer of the same product is reflected as a range value rather than a fixed value.
注:表4中的局部淬火区域淬硬层深度为范围值而非定值,是因为同一产品不用位置的淬硬层深度
是不同的,因此同一产品的淬硬层深度体现为范围值而非定值。Table 4.
Note: The depth of the hardened layer in the local quenching area in Table 4 is a range value rather than a fixed value because the depth of the hardened layer in different positions of the same product is different. Therefore, the depth of the hardened layer of the same product is reflected as a range value rather than a fixed value.
从表4可以看出,在经过局部淬火处理后,本发明所设计的实施例1-7的车辆轮毂用轴承钢局部淬火区域的硬度为730~780HV,淬硬层深度为2.0~3.5mm,其局部淬火区域在同一硬化层深度的显微硬度偏差≤40HV,并且其抗拉强度≥852MPa。因此,其可以有效改善汽车轮毂滚动轴承滚道布氏压痕现象,防止滚动体和滚道轮的接触部分由于布氏损伤造成微裂的萌生而引起断裂。As can be seen from Table 4, after local quenching treatment, the hardness of the local quenching area of the bearing steel for vehicle hub of Examples 1-7 designed by the present invention is 730-780HV, the depth of the hardened layer is 2.0-3.5mm, the microhardness deviation of the local quenching area at the same hardened layer depth is ≤40HV, and the tensile strength is ≥852MPa. Therefore, it can effectively improve the Brinell indentation phenomenon of the raceway of the automobile hub rolling bearing and prevent the contact part of the rolling element and the raceway wheel from breaking due to the initiation of microcracks caused by Brinell damage.
图3显示了本发明实施例3的车辆轮毂用轴承钢的局部淬火区域的淬硬层深度。FIG. 3 shows the depth of the hardened layer in the local quenching area of the vehicle hub bearing steel according to Example 3 of the present invention.
从图3中也可以看出,本发明实施例3的车辆轮毂用轴承钢的局部淬火区域的淬硬层深度为2.0~3.5mm。It can also be seen from FIG. 3 that the depth of the hardened layer in the local quenching area of the bearing steel for a vehicle hub in Example 3 of the present invention is 2.0 to 3.5 mm.
需要说明的是,本发明的保护范围中现有技术部分并不局限于本申请文件所给出的实施例,所有不与本发明的方案相矛盾的现有技术,包括但不局限于在先专利文献、在先公开出版物,在先公开使用等等,都可纳入本发明的保护范围。It should be noted that the prior art in the protection scope of the present invention is not limited to the embodiments given in the present application documents. All prior art that does not contradict the scheme of the present invention, including but not limited to prior patent documents, prior public publications, prior public uses, etc., can be included in the protection scope of the present invention.
此外,本案中各技术特征的组合方式并不限本案权利要求中所记载的组合方式或是具体实施例所记载的组合方式,本案记载的所有技术特征可以以任何方式进行自由组合或结合,除非相互之间产生矛盾。In addition, the combination of the various technical features in this case is not limited to the combination described in the claims of this case or the combination described in the specific embodiments. All technical features recorded in this case can be freely combined or combined in any way unless there is a contradiction between them.
还需要注意的是,以上列举的仅为本发明的具体实施例,显然本发明不限于以上实施例,随之有着许多的类似变化。本领域的技术人员如果从本发明公开的内容直接导出或联想到的所有变形,均应属于本发明的保护范围。
It should also be noted that the above examples are only specific embodiments of the present invention, and the present invention is obviously not limited to the above examples, and there are many similar variations. All variations that can be directly derived or associated with the contents disclosed by a person skilled in the art should fall within the protection scope of the present invention.
Claims (15)
- 一种车辆轮毂用轴承钢,其含有Fe和不可避免的杂质,其特征在于,其还含有质量百分比如下的下述化学元素:A bearing steel for a vehicle wheel hub, containing Fe and unavoidable impurities, characterized in that it also contains the following chemical elements in the following mass percentages:C:0.70~0.80%;Si:0.50~0.70%;Mn:0.95~1.05%;Cr:0.60~0.70%;Cu:0.10~0.25%;Al:0.010~0.040%;Nb:0.025~0.035%;V:0.10~0.15%;Mo≤0.01%。C: 0.70~0.80%; Si: 0.50~0.70%; Mn: 0.95~1.05%; Cr: 0.60~0.70%; Cu: 0.10~0.25%; Al: 0.010~0.040%; Nb: 0.025~0.035%; V :0.10~0.15%; Mo≤0.01%.
- 如权利要求1所述的车辆轮毂用轴承钢,其特征在于,其各化学元素质量百分比为:The bearing steel for a vehicle hub as claimed in claim 1 is characterized in that the mass percentage of each chemical element is:C:0.70~0.80%;Si:0.50~0.70%;Mn:0.95~1.05%;Cr:0.60~0.70%;Cu:0.10~0.25%;Al:0.010~0.040%;Nb:0.025~0.035%;V:0.10~0.15%;Mo≤0.01%;余量为Fe和不可避免的杂质。C: 0.70~0.80%; Si: 0.50~0.70%; Mn: 0.95~1.05%; Cr: 0.60~0.70%; Cu: 0.10~0.25%; Al: 0.010~0.040%; Nb: 0.025~0.035%; V: 0.10~0.15%; Mo≤0.01%; the balance is Fe and unavoidable impurities.
- 如权利要求1或2所述的车辆轮毂用轴承钢,其特征在于,其化学元素质量百分含量还满足:10Nb+V≥0.40%。The bearing steel for a vehicle hub as claimed in claim 1 or 2 is characterized in that the mass percentage of chemical elements also satisfies: 10Nb+V≥0.40%.
- 如权利要求1或2所述的车辆轮毂用轴承钢,其特征在于,在不可避免的杂质中的各元素满足下列各项的至少其中之一:S≤0.015%;P≤0.015%;O≤0.0006%;H≤0.0001%;Ti≤0.0015%;Pb≤0.002%,As≤0.04%,Sn≤0.05%,Sb≤0.004%,Ca≤0.0010%。The bearing steel for vehicle wheel hub as described in claim 1 or 2 is characterized in that each element in the inevitable impurities satisfies at least one of the following items: S≤0.015%; P≤0.015%; O≤0.0006%; H≤0.0001%; Ti≤0.0015%; Pb≤0.002%, As≤0.04%, Sn≤0.05%, Sb≤0.004%, Ca≤0.0010%.
- 如权利要求1或2所述的车辆轮毂用轴承钢,其特征在于,其局部淬火区域的显微组织为均匀的马氏体组织,其中,针状马氏体的长度≤10微米的。The bearing steel for a vehicle wheel hub as claimed in claim 1 or 2 is characterized in that the microstructure of the local quenching area is a uniform martensitic structure, wherein the length of the needle-shaped martensite is ≤10 microns.
- 如权利要求1或2所述的车辆轮毂用轴承钢,其特征在于,其未进行局部淬火的区域的显微组织为铁素体+珠光体;优选地,珠光体的面积比≤8%。The bearing steel for a vehicle wheel hub as claimed in claim 1 or 2, characterized in that the microstructure of the area not subjected to local quenching is ferrite+pearlite; preferably, the area ratio of pearlite is ≤8%.
- 如权利要求1或2所述的车辆轮毂用轴承钢,其特征在于,其局部淬火区域的晶粒度为7-9级。The bearing steel for a vehicle wheel hub as claimed in claim 1 or 2, characterized in that the grain size of the local quenching area is 7-9.
- 如权利要求1或2所述的车辆轮毂用轴承钢,其特征在于,轴承钢的单颗最大夹杂物尺寸≤27μm。The bearing steel for a vehicle wheel hub as claimed in claim 1 or 2, characterized in that the maximum size of a single inclusion in the bearing steel is ≤27 μm.
- 如权利要求1或2所述的车辆轮毂用轴承钢,其特征在于,其局部淬火区域具有弥散分布的复合的纳米级碳化物析出物,所述碳化物析出物的尺寸为15nm-35nm。 The bearing steel for a vehicle wheel hub as claimed in claim 1 or 2 is characterized in that the local quenching area thereof has dispersedly distributed composite nano-scale carbide precipitates, and the size of the carbide precipitates is 15nm-35nm.
- 如权利要求1或2所述的车辆轮毂用轴承钢,其特征在于,其局部淬火区域的显微硬度为730~780HV,淬硬层深度为2.0~3.5mm。The bearing steel for a vehicle wheel hub as claimed in claim 1 or 2 is characterized in that the microhardness of the local quenching area is 730 to 780 HV, and the depth of the hardened layer is 2.0 to 3.5 mm.
- 如权利要求1或2所述的车辆轮毂用轴承钢,其特征在于,其局部淬火区域在同一硬化层深度的显微硬度偏差≤40HV。The bearing steel for a vehicle wheel hub as claimed in claim 1 or 2 is characterized in that the microhardness deviation of the local quenching area at the same hardened layer depth is ≤40HV.
- 如权利要求1或2所述的车辆轮毂用轴承钢,其特征在于,其抗拉强度≥930MPa,和/或,中心偏析指数,即中心C%/熔炼C%,在0.95~1.05的范围内,优选在0.98~1.02的范围内。The bearing steel for a vehicle hub as claimed in claim 1 or 2 is characterized in that its tensile strength is ≥930 MPa, and/or the center segregation index, i.e., center C%/melting C%, is in the range of 0.95 to 1.05, preferably in the range of 0.98 to 1.02.
- 一种如权利要求1-12中任意一项所述的车辆轮毂用轴承钢的制造方法,其特征在于,包括步骤:A method for manufacturing a bearing steel for a vehicle hub as claimed in any one of claims 1 to 12, characterized in that it comprises the steps of:(1)冶炼、精炼和浇注;(1) Smelting, refining and casting;(2)采用加热炉对铸坯进行加热;(2) heating the ingot using a heating furnace;(3)采用初轧机开坯,得到钢坯;(3) using a primary rolling mill to produce a steel billet;(4)对钢坯进行加热,然后轧制成棒材;(4) heating the steel billet and then rolling it into a bar;(5)对用作车辆轮毂滚道面的区域进行局部淬火。(5) Local quenching of the area used as the wheel hub raceway surface.
- 如权利要求13所述的制造方法,其特征在于,在步骤(2)中,控制铸坯入炉温度为600~900℃,保温20~40min;然后经过120~200min升温至1180~1220℃,保温80~180min。The manufacturing method as described in claim 13 is characterized in that in step (2), the temperature of the ingot entering the furnace is controlled to be 600-900°C and kept warm for 20-40 minutes; then the temperature is raised to 1180-1220°C after 120-200 minutes and kept warm for 80-180 minutes.
- 如权利要求13所述的制造方法,其特征在于,在步骤(4)中,控制钢坯加热温度为1160~1200℃,加热时间为80~180min,钢坯表面温差≤40℃,终轧温度为760~900℃。 The manufacturing method as described in claim 13 is characterized in that in step (4), the heating temperature of the steel billet is controlled to be 1160-1200°C, the heating time is 80-180min, the surface temperature difference of the steel billet is ≤40°C, and the final rolling temperature is 760-900°C.
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CN108929997A (en) * | 2017-05-26 | 2018-12-04 | 宝山钢铁股份有限公司 | A kind of automotive hub bearing steel and its manufacturing method |
KR20190070737A (en) * | 2017-12-13 | 2019-06-21 | 현대자동차주식회사 | Steel for wheel bearing and manufacturing method of crank shaft using the same |
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2023
- 2023-02-17 CN CN202310126832.7A patent/CN118516619A/en active Pending
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- 2024-02-05 WO PCT/CN2024/075902 patent/WO2024169713A1/en unknown
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JP2009024233A (en) * | 2007-07-20 | 2009-02-05 | Nisshin Steel Co Ltd | High carbon steel sheet excellent in hardenability, fatigue property and toughness, and method for producing the same |
JP2009242937A (en) * | 2008-03-10 | 2009-10-22 | Jfe Steel Corp | Bearing steel having excellent rolling fatigue property, and method for producing the same |
CN101724786A (en) * | 2008-10-22 | 2010-06-09 | 洛阳轴研科技股份有限公司 | Bearing steel and technology for heating processing |
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KR20190070737A (en) * | 2017-12-13 | 2019-06-21 | 현대자동차주식회사 | Steel for wheel bearing and manufacturing method of crank shaft using the same |
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