WO2024096093A1 - 複素環化合物及びそれを含有する有害節足動物防除組成物 - Google Patents

複素環化合物及びそれを含有する有害節足動物防除組成物 Download PDF

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WO2024096093A1
WO2024096093A1 PCT/JP2023/039557 JP2023039557W WO2024096093A1 WO 2024096093 A1 WO2024096093 A1 WO 2024096093A1 JP 2023039557 W JP2023039557 W JP 2023039557W WO 2024096093 A1 WO2024096093 A1 WO 2024096093A1
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group
optionally substituted
halogen atoms
compound
group optionally
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PCT/JP2023/039557
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English (en)
French (fr)
Japanese (ja)
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菜摘 佐藤
秀充 峯岸
文太 西川
柳原 早希 佐藤
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住友化学株式会社
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Priority to EP23885847.6A priority Critical patent/EP4613750A1/en
Priority to JP2024554581A priority patent/JPWO2024096093A1/ja
Priority to CN202380075601.6A priority patent/CN120187727A/zh
Publication of WO2024096093A1 publication Critical patent/WO2024096093A1/ja

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    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/26—Oxidation products of dithiocarbamic acid derivatives, e.g. thiuram sulfides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
    • A01N63/20—Bacteria; Substances produced thereby or obtained therefrom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P7/00—Arthropodicides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P7/00—Arthropodicides
    • A01P7/02—Acaricides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P7/00—Arthropodicides
    • A01P7/04—Insecticides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
    • C07D471/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D519/00—Heterocyclic compounds containing more than one system of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring system not provided for in groups C07D453/00 or C07D455/00

Definitions

  • the present invention relates to a heterocyclic compound and a composition for controlling arthropod pests containing the same.
  • Patent Document 1 describes that certain compounds have a pest control effect.
  • the objective of the present invention is to provide a compound that has excellent control effect against harmful arthropods.
  • Formula (I) [Wherein, Q expressed by the following formula (wherein # represents a bonding site with a sulfur atom, and ⁇ represents a bonding site with Het) represents a group represented by formula Q1 or a group represented by formula Q2, A 1 represents a nitrogen atom or CR 8 ; R8 represents a halogen atom or a hydrogen atom; R2 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a cyclopropyl group, or a cyclopropylmethyl group; n represents 0, 1 or 2; G 1 represents a nitrogen atom or CR 3a ; G2 represents a nitrogen atom or CR3b ; G3 represents a nitrogen atom or CR3c ; G4 represents a nitrogen atom or CR3d ; R 3a , R 3b , R 3c and R 3d are the same or different and each represents a C1-C6 chain
  • Group L a group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom.
  • Group M a group consisting of C1-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, C1-C6 alkoxy groups optionally substituted with one or more halogen atoms, C3-C6 alkenyloxy groups optionally substituted with one or more halogen atoms, C3-C6 alkynyloxy groups optionally substituted with one or more halogen atoms, and halogen atoms.
  • Group D a group consisting of a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, an amino group, NHR 21 , NR 21 R 22 , C(O)R 21 , OC
  • R 21 and R 22 are the same or different and each represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms.
  • Group E a group consisting of a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group.
  • Group F a group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group D, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from group M, an amino group, NHR 21 , NR 21 R 22 , a halogen atom, and a cyano group.
  • Group H a group consisting of C1-C6 alkyl groups optionally substituted by one or more halogen atoms, OR 10 , NR 9 R 10 , C(O)R 10 , C(O)NR 9 R 10 , OC(O)R 9 , OC(O)OR 9 , NR 10 C(O)R 9 , NR 10 C(O)OR 9 , C(O)OR 10 , halogen atoms, nitro groups, cyano groups, amino groups, and 5- or 6-membered aromatic heterocyclic groups optionally substituted by one or more substituents selected from group W.
  • R 9 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms;
  • R 10 represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom.
  • Group P the group consisting of a C2-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D2 , a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D2 , a C2-C6 alkylcarbonyl group optionally substituted with one or more halogen atoms, a C2-C6 alkoxycarbonyl group optionally substituted with one or more halogen atoms, an aminocarbonyl group, a (C1-C6 alkyl)aminocarbonyl group optionally substituted with one or more halogen atoms, a methyl group, and a di(C1-C4 alkyl)aminocarbonyl group optionally substituted with one or more halogen atom
  • Group J a group consisting of a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, and a cyano group.
  • Group K a group consisting of a C1-C6 alkoxy group optionally substituted by one or more halogen atoms, a phenyl group optionally substituted by one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted by one or more substituents selected from Group D, a C3-C7 cycloalkyl group optionally substituted by one or more halogen atoms, and a 3- to 7-membered non-aromatic heterocyclic group optionally substituted by one or more substituents selected from Group M.
  • Group T the group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from Group M, an amino group, NHR 21 , NR 21 R 22 , a halogen atom, and a cyano group.
  • Group U a group consisting of a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, and a cyano group.
  • Group V a group consisting of a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C
  • Group W a group consisting of a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, an amino group, NHR 21 , NR 21 R 22 , C(O)R 21 , OC
  • Group L2 a group consisting of C1-C6 alkoxy groups optionally substituted with one or more halogen atoms, C3-C6 alkenyloxy groups optionally substituted with one or more halogen atoms, C3-C6 alkynyloxy groups optionally substituted with one or more halogen atoms, C1-C6 alkylsulfanyl groups optionally substituted with one or more halogen atoms, C1-C6 alkylsulfinyl groups optionally substituted with one or more halogen atoms, C1-C6 alkylsulfonyl groups optionally substituted with one or more halogen atoms, C3-C6 cycloalkyl groups optionally substituted with one or more halogen atoms, cyano groups, hydroxy groups, and halogen atoms.
  • Group D 2 a group consisting of a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, an amino group, NHR 21 , NR 21 R 22 , C(O)R 21 ,
  • Group E2 a group consisting of C1-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, C1-C6 alkoxy groups optionally substituted with one or more halogen atoms, C3-C6 alkenyloxy groups optionally substituted with one or more halogen atoms, C3-C6 alkynyloxy groups optionally substituted with one or more halogen atoms, halogen atoms, oxo groups, hydroxy groups, cyano groups, and nitro groups.
  • Group F 2 the group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group D, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from group M, an amino group, NHR 21 , NR 21 R 22 , a halogen atom, and a cyano group.
  • Group H 2 a group consisting of C1-C6 alkyl groups optionally substituted by one or more halogen atoms, OR 10 , NR 9 R 10 , C(O)R 10 , C(O)NR 9 R 10 , OC(O)R 9 , OC(O)OR 9 , NR 10 C(O)R 9 , NR 10 C(O)OR 9 , C(O)OR 10 , halogen atoms, nitro groups, cyano groups, amino groups, and 5- or 6-membered aromatic heterocyclic groups optionally substituted by one or more substituents selected from group W.
  • Group J 2 a group consisting of C1-C6 alkyl groups optionally substituted with one or more halogen atoms, halogen atoms, and cyano groups.
  • Group L3 a group consisting of C1-C6 alkoxy groups optionally substituted with one or more halogen atoms, C3-C6 alkenyloxy groups optionally substituted with one or more halogen atoms, C3-C6 alkynyloxy groups optionally substituted with one or more halogen atoms, C1-C6 alkylsulfanyl groups optionally substituted with one or more halogen atoms, C1-C6 alkylsulfinyl groups optionally substituted with one or more halogen atoms, C1-C6 alkylsulfonyl groups optionally substituted with one or more halogen atoms, C3-C6 cycloalkyl groups optionally substituted with one or more halogen atoms, cyano
  • Group D 3 a group consisting of a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, an amino group, NHR 21 , NR 21 R 22 , C(O)R 21 ,
  • Group E3 a group consisting of C1-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, C1-C6 alkoxy groups optionally substituted with one or more halogen atoms, C3-C6 alkenyloxy groups optionally substituted with one or more halogen atoms, C3-C6 alkynyloxy groups optionally substituted with one or more halogen atoms, halogen atoms, oxo groups, hydroxy groups, cyano groups, and nitro groups.
  • Group F 3 a group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group D, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from group M, an amino group, NHR 21 , NR 21 R 22 , a halogen atom, and a cyano group.
  • Group H3 a group consisting of C1-C6 alkyl groups optionally substituted by one or more halogen atoms, OR10 , NR9R10 , C (O) R10 , C(O) NR9R10 , OC(O) R9 , OC(O) OR9 , NR10C(O) R9 , NR10C (O) OR9 , C ( O) OR10 , halogen atoms, nitro groups, cyano groups, amino groups, and 5- or 6-membered aromatic heterocyclic groups optionally substituted by one or more substituents selected from group W.
  • Group J 3 a group consisting of a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, and a cyano group.
  • compound N of the present invention or an N-oxide thereof (hereinafter, a compound represented by formula (I) or an N-oxide thereof will be referred to as compound of the present invention).
  • Q is a group represented by the formula Q1.
  • Q is a group represented by the formula Q2.
  • [7] The compound according to [1] or an N-oxide thereof, wherein Q is a group represented by the formula Q2 and A 1 is CR 8 .
  • [8] The compound or N-oxide thereof according to any one of [1] to [7], wherein Het is a group represented by the formula Het1, A2 is -CR7aR7b-, A3 is -CR7cR7d- or -CR7eR7f-CR7gR7h- * 1 , and W is an oxygen atom .
  • a composition comprising one or more components selected from the group consisting of group (a), group (b), group (c), and group (d), and a compound according to any one of [1] to [9] or an N-oxide thereof:
  • a method for controlling harmful arthropods comprising applying an effective amount of the compound or N-oxide thereof according to any one of [1] to [9], or an effective amount of the composition according to [11] to harmful arthropods or to a habitat of harmful arthropods.
  • a seed or a vegetative reproductive organ carrying an effective amount of the compound or N-oxide thereof according to any one of [1] to [9], or an effective amount of the composition according to [11].
  • Formula (II) [In the formula, X1 represents a chlorine atom, a bromine atom, an iodine atom, or a hydroxyl group, and the other symbols have the same meanings as in [1].] or a salt thereof (hereinafter, the compound represented by formula (II) or a salt thereof will be referred to as intermediate A). [15] Formula (III) [In the formula, X2 represents a chlorine atom, a bromine atom, an iodine atom, or a hydroxyl group, and the other symbols have the same meanings as in [1].] or a salt thereof (hereinafter, the compound represented by formula (III) or a salt thereof will be referred to as intermediate B).
  • the present invention makes it possible to control harmful arthropods.
  • a halogen atom means a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom.
  • a substituent is substituted with two or more halogen atoms or substituents, those halogen atoms or substituents may each be the same or different.
  • CX-CY means that the number of carbon atoms is X to Y.
  • C1-C6 means that the number of carbon atoms is 1 to 6.
  • the chain hydrocarbon group refers to an alkyl group, an alkenyl group, or an alkynyl group.
  • alkyl group examples include a methyl group, an ethyl group, a propyl group, an isopropyl group, a 1,1-dimethylpropyl group, a 1,2-dimethylpropyl group, a 1-ethylpropyl group, a butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, and a hexyl group.
  • alkenyl group examples include a vinyl group, a 1-propenyl group, a 2-propenyl group, a 1-methyl-1-propenyl group, a 1-methyl-2-propenyl group, a 1,2-dimethyl-1-propenyl group, a 1-ethyl-2-propenyl group, a 3-butenyl group, a 4-pentenyl group, and a 5-hexenyl group.
  • alkynyl group examples include an ethynyl group, a 1-propynyl group, a 2-propynyl group, a 1-methyl-2-propynyl group, a 1,1-dimethyl-2-propynyl group, a 1-ethyl-2-propynyl group, a 2-butynyl group, a 4-pentynyl group, and a 5-hexynyl group.
  • alkoxy groups include methoxy, ethoxy, propoxy, isopropoxy, butoxy, tert-butoxy, pentyloxy, and hexyloxy groups.
  • alkenyloxy group examples include a 2-propenyloxy group, a 2-butenyloxy group, and a 5-hexenyloxy group.
  • alkynyloxy group examples include a 2-propynyloxy group, a 2-butynyloxy group, and a 5-hexynyloxy group.
  • Cycloalkyl groups include, for example, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, and cycloheptyl groups.
  • Examples of cycloalkenyl groups include cyclopropenyl groups, cyclobutenyl groups, cyclopentenyl groups, cyclohexenyl groups, and cycloheptenyl groups.
  • Examples of the 3- to 7-membered non-aromatic heterocyclic group include an aziridinyl group, an oxiranyl group, a thiiranyl group, an azetidinyl group, an oxetanyl group, a thietanyl group, a pyrrolidinyl group, a tetrahydrofuranyl group, a tetrahydrothienyl group, a piperidyl group, a pyranyl group, a dihydropyranyl group, a tetrahydropyranyl group, a tetrahydrothiopyranyl group, an azepanyl group, an oxepanyl group, a thiepanyl group, a pyrazolinyl group, a pyrazolidinyl group, an imidazolinyl group, an imidazolidinyl group, an oxazolinyl group, a
  • Examples of the 5- or 6-membered aromatic heterocyclic group include a pyrrolyl group, a furyl group, a thienyl group, a pyrazolyl group, an imidazolyl group, a triazolyl group, a tetrazolyl group, an oxazolyl group, an isoxazolyl group, a thiazolyl group, an isothiazolyl group, an oxadiazolyl group, a thiadiazolyl group, a pyridyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a triazinyl group, and a tetrazinyl group.
  • Examples of the 6-membered aromatic heterocyclic group include a pyridyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a triazinyl group, and a tetrazinyl group.
  • Examples of the (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted by one or more halogen atoms include a cyclopropylmethyl group, a (2-fluorocyclopropyl)methyl group, a cyclopropyl(fluoro)methyl group, and a (2-fluorocyclopropyl)(fluoro)methyl group.
  • the (C3-C7 cycloalkyl)C1-C6 alkyl group optionally substituted with one or more halogen atoms refers to a group in which a (C3-C7 cycloalkyl) and/or a (C1-C6 alkyl) is optionally substituted with one or more halogen atoms, and examples thereof include a (2,2-difluorocyclopropyl)methyl group, a 2-cyclopropyl-1,1,2,2-tetrafluoroethyl group, a 2-(2,2-difluorocyclopropyl)-1,1,2,2-tetrafluoroethyl group, a (2,2-difluorocyclopropyl)propyl group, a (2,2-difluorocyclopropyl)butyl group, a (2,2-difluorocyclopropyl)pentyl group, and a (2,2-difluorocyclopropyl)
  • Examples of the phenyl C1-C3 alkyl group ⁇ the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from group D ⁇ , the phenyl C1-C3 alkyl group ⁇ the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from group D2 ⁇ , and the phenyl C1-C3 alkyl group ⁇ the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from group D3 ⁇ include a benzyl group, a 2-fluorobenzyl group, a 4-chlorobenzyl group, a 4-(trifluoromethyl)benzyl group, and a 2-[4-(trifluoromethyl)phenyl]ethyl group.
  • alkylsulfanyl group examples include a methylsulfanyl group, an ethylsulfanyl group, a propylsulfanyl group, and an isopropylsulfanyl group.
  • alkylsulfinyl group examples include a methylsulfinyl group, an ethylsulfinyl group, a propylsulfinyl group, and an isopropylsulfinyl group.
  • alkylsulfonyl group examples include a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, and an isopropylsulfonyl group.
  • alkylcarbonyl group examples include an acetyl group, a propanoyl group, a 2-methylpropanoyl group, and a hexanoyl group.
  • alkoxycarbonyl group examples include a methoxycarbonyl group, an ethoxycarbonyl group, an isopropoxycarbonyl group, and a pentyloxycarbonyl group.
  • Examples of the (C1-C6 alkyl)aminocarbonyl group optionally substituted with one or more halogen atoms include a methylaminocarbonyl group, a trifluoromethylaminocarbonyl group, an isopropylaminocarbonyl group, and a hexylaminocarbonyl group.
  • Examples of the di(C1-C4 alkyl)aminocarbonyl group optionally substituted with one or more halogen atoms include a dimethylaminocarbonyl group, a methylethylaminocarbonyl group, a trifluoromethylethylaminocarbonyl group, and a diisopropylaminocarbonyl group.
  • the N-oxide of the compound of formula (I) includes, for example, the compound of the following formula: (In the formula, the symbols have the same meanings as defined above.)
  • the compound of the present invention may exist as one or more stereoisomers.
  • stereoisomers include enantiomers, diastereomers, and geometric isomers.
  • the compound of the present invention includes each stereoisomer and a mixture of stereoisomers in any ratio.
  • the compound of the present invention, the compound represented by formula (II), and the compound represented by formula (III) may form an acid addition salt.
  • acids that form acid addition salts include inorganic acids such as hydrogen chloride, phosphoric acid, and sulfuric acid, and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, and p-toluenesulfonic acid.
  • the acid addition salt is obtained by mixing the compound of the present invention, the compound represented by formula (II), or the compound represented by formula (III) with an acid.
  • the embodiments of the compound N of the present invention include the following compounds.
  • [Embodiment 1] A compound of the present invention, in which W is an oxygen atom in compound N of the present invention.
  • [Embodiment 2] The compound N of the present invention, wherein R2 is a C1-C6 alkyl group.
  • [Embodiment 3] The compound N of the present invention, in which R2 is an ethyl group.
  • [Embodiment 5] The compound N of the present invention, wherein Q is a group represented by Q2.
  • Q is a group represented by Q1, and the combinations of G 1 , G 2 , G 3 and G 4 are as follows: G 1 is CR 3a , G 2 is CR 3b , G 3 is CR 3c and G 4 is a nitrogen atom; G 1 is CR 3a , G 2 is CR 3b, G 3 is a nitrogen atom and G 4 is CR 3d ; G 1 is CR 3a , G 2 is a nitrogen atom, G 3 is CR 3c and G 4 is CR 3d ; G 1 is a nitrogen atom, G 2 is CR 3b , G 3 is CR 3c and G 4 is CR 3d ; or G 1 is CR 3a , G 2 is CR 3b , G 3 is CR 3c and G 4 is CR 3d.
  • R 3a , R 3c , and R 3d are hydrogen atoms
  • R 3b is a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a halogen atom and a cyano group, a phenyl group optionally substituted with one or more halogen atoms, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more halogen atoms, or a halogen atom.
  • a compound of the present invention in which Q is a group represented by Q1, G1 is CR3a , G2 is CR3b , G3 is CR3c , G4 is a nitrogen atom or CR3d , R3a , R3c , and R3d are hydrogen atoms, and R3b is a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a halogen atom.
  • a compound of the present invention N in which Q is a group represented by Q1, G1 is CR3a , G2 is CR3b , G3 is CR3c , G4 is CR3d , R3a , R3c , and R3d are hydrogen atoms, and R3b is a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a halogen atom.
  • Q is a group represented by Q1, and the combinations of G 1 , G 2 , G 3 and G 4 are as follows: G 1 is CR 3a , G 2 is CR 3b , G 3 is CR 3c and G 4 is a nitrogen atom; G 1 is CR 3a , G 2 is CR 3b, G 3 is a nitrogen atom and G 4 is CR 3d ; G 1 is CR 3a , G 2 is a nitrogen atom, G 3 is CR 3c and G 4 is CR 3d ; G 1 is a nitrogen atom, G 2 is CR 3b , G 3 is CR 3c and G 4 is CR 3d ; or G 1 is CR 3a , G 2 is CR 3b , G 3 is CR 3c and G 4 is CR 3d.
  • a compound of the present invention N in which Q is a group represented by Q1, G1 is CR3a , G2 is CR3b , G3 is CR3c , G4 is a nitrogen atom or CR3d , R3a , R3b , and R3d are hydrogen atoms, and R3c is a halogen atom.
  • a compound of the present invention N in which Q is a group represented by Q1, G1 is CR3a , G2 is CR3b , G3 is CR3c , G4 is CR3d , R3a , R3b , and R3d are hydrogen atoms, and R3c is a halogen atom.
  • Q is a group represented by Q2 and A1 is CR8 .
  • G1 is CR3a
  • G2 is CR3b
  • G3 is CR3c
  • G4 is CR3d
  • R3a , R3c , and R3d are hydrogen atoms
  • R3b is a halogen atom
  • A1 is a nitrogen atom
  • k is 0 or 1
  • R4 is a phenyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, a C3-C7 cycloalkyl group, or a halogen atom.
  • a compound of the present invention in which, in compound N, Q is a group represented by Q1, G1 is CR3a , G2 is CR3b , G3 is CR3c , G4 is CR3d , R3a , R3c , and R3d are hydrogen atoms, and R3b is a halogen atom.
  • a compound N of the present invention in which Q is a group represented by Q2, A1 is a nitrogen atom, k is 0 or 1, and R4 is a phenyl group which may be substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, or a pyridyl group which may be substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom.
  • G 1 is CR 3a
  • G 2 is CR 3b
  • G 3 is CR 3c
  • G 4 is CR 3d
  • R 3a , R 3c , and R 3d are hydrogen atoms
  • R 3b is a halogen atom
  • a 1 is a nitrogen atom
  • k is 0 or 1
  • R 4 is a phenyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom
  • a pyridyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom
  • OR 42 , NR 41 R 42 , NR 41 C(O)R 43 , or NR 41 C(O)OR 44
  • R 41 is a C1-C6 alkyl group or a hydrogen atom
  • R 42 is a hydrogen atom
  • R 43 is a C1-
  • a compound of the present invention N in which Q is a group represented by Q2, A1 is a nitrogen atom, k is 0 or 1, and R4 is a phenyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, a C3-C7 cycloalkyl group, OR42 , NR41R42 , NR41C (O) R43 , NR41C (O) OR44 , or a halogen atom.
  • Q is a group represented by Q1 or a group represented by the formula Q2a wherein G 1 is CR 3a , G 2 is CR 3b , G 3 is CR 3c , G 4 is CR 3d , R 3a , R 3c , and R 3d are hydrogen atoms, R 3b is a halogen atom, A 1 is a nitrogen atom, ka is 0 or 1, and R 4b is a phenyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, a C3-C7 cycloalkyl group, OR , NR 41 R , NR 41 C(O) R , NR 41 C(O)
  • Q is a group represented by Q1 or a group represented by the above formula Q2a
  • G 1 is CR 3a
  • G 2 is CR 3b
  • G 3 is CR 3c
  • G 4 is CR 3d
  • R 3a , R 3c , and R 3d are hydrogen atoms
  • R 3b is a halogen atom
  • a 1 is a nitrogen atom
  • ka is 0 or 1
  • R 4b is a phenyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom
  • a pyridyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom
  • OR 42 , NR 41 R 42 , NR 41 C(O)R 43 , or NR 41 C(O)OR 44
  • R 41 is a C1-C6 alkyl group or
  • Aspect 204 The compound according to aspect 32, wherein Het is a group represented by Het2.
  • Aspect 205 A compound in any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, in which Het is a group represented by Het1, and the combinations of B 1 , B 2 , and B 3 are such that B 1 is CR 6a , B 2 is CR 6b , and B 3 is CR 6c ; B 1 is a nitrogen atom, B 2 is CR 6b , and B 3 is CR 6c ; B 1 is CR 6a , B 2 is a nitrogen atom, and B 3 is CR 6c ; or B 1 is CR 6a , B 2 is CR 6b , and B 3 is a nitrogen atom.
  • Aspect 206 In any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, Het is a group represented by Het1, and the combinations of B 1 , B 2 , and B 3 are: B 1 is CR 6a , B 2 is CR 6b , and B 3 is CR 6c ; B 1 is a nitrogen atom, B 2 is CR 6b , and B 3 is CR 6c ; B 1 is CR 6a , B 2 is a nitrogen atom, and B 3 is CR 6c ; or B 1 is CR 6a , B 2 is CR 6b , and B 3 is a nitrogen atom, and R 6a , R 6b , and R Compounds in which 6c is the same or different and is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the
  • Aspect 208 A compound in which, in any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, Het is a group represented by Het1, B 1 is a nitrogen atom, B 2 is CR 6b , B 3 is CR 6c , R 6b is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a halogen atom and a cyano group, or OR 72 , and R 6c is a hydrogen atom.
  • Aspect 209 A compound in any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, in which Het is a group represented by Het1, B 1 is a nitrogen atom, B 2 is CR 6b , B 3 is CR 6c , R 6b is a hydrogen atom, and R 6c is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a halogen atom and a cyano group, or OR 72 .
  • Aspect 210 A compound in any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, in which Het is a group represented by Het1, B 1 is CR 6a , B 2 is a nitrogen atom, B 3 is CR 6c , and R 6a and R 6c are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a halogen atom and a cyano group, or OR 72 .
  • Aspect 212 A compound in any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, in which Het is a group represented by Het1, B 1 is CR 6a , B 2 is CR 6b , B 3 is a nitrogen atom, R 6a is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a halogen atom and a cyano group, or OR 72 , and R 6b is a hydrogen atom.
  • Aspect 213 In any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, Het is a group represented by Het2, and the combinations of B 1 , B 2 , and B 3 are: B 1 is CR 6a , B 2 is CR 6b , and B 3 is CR 6c ; B 1 is a nitrogen atom, B 2 is CR 6b , and B 3 is CR 6c ; B 1 is CR 6a , B 2 is a nitrogen atom, and B 3 is CR 6c ; or B 1 is CR 6a , B 2 is CR 6b , and B 3 is a nitrogen atom, and R 6a , R 6b , and R Compounds in which 6c is the same or different and is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the
  • Aspect 214 A compound in any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, in which Het is a group represented by Het2, B 1 is CR 6a , B 2 is CR 6b , B 3 is a nitrogen atom, R 6a is a hydrogen atom, and R 6b is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a halogen atom and a cyano group, or OR 72 .
  • Aspect 215 In any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, Het is a group represented by Het1, and the combinations of A 2 and A 3 are such that A 2 is -CR 7a R 7b - and A 3 is -CR 7c R 7d -; A 2 is -CR 7a R 7b - and A 3 is -CR 7e R 7f -CR 7g R 7h -* 1 (* 1 represents the bonding position to A 2 ); A 2 is -NR 5a - and A 3 is -CR 7c R 7d -; or A 2 is -NR 5a - and A 3 is -CR 7e R 7f -CR 7g R 7h -* 1 (* 1 represents the bonding position to A 2).
  • Aspect 217 In any one of Aspects 1 to 5, Aspects 8 to 154, or the compound N of the present invention, Het is a group represented by Het2, and the combinations of A 2 and A 4 are as follows: A 2 is -CR 7a R 7b - and A 4 is -CR 7o R 7p -; A 2 is -CR 7a R 7b - and A 4 is -CR 7q R 7r -CR 7s R 7t -* 2 (* 2 represents the bonding position to A 2 ); A 2 is -CR 7a R 7b - and A 4 is -NR 5c -CR 7u R 7v -* 2 (* 2 represents the bonding position to A 2 ); A 2 is -NR 5a - and A 4 is -CR 7o R 7p or a compound in which A 2 is —NR 5a — and A 4 is —CR 7q R 7r —CR 7s R 7t —* 2 (* 2 represents the bonding position to A 2
  • Aspect 219 A compound in which, in any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, Het is a group represented by Het1, and the combination of A 2 and A 3 is such that A 2 is -CR 7a R 7b - and A 3 is -CR 7c R 7d -; or A 2 is -CR 7a R 7b - and A 3 is -CR 7e R 7f -CR 7g R 7h -* 1 (* 1 represents the bonding position to A 2 ), and R 7a , R 7b , R 7c , R 7d , R 7e , R 7f , R 7g , and R 7h are the same or different and are a C1-C6 alkyl group, or a hydrogen atom.
  • Aspect 220 In any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the Invention, Het is a group represented by Het1, A 2 is -CR 7a R 7b -, A 3 is -CR 7c R 7d -, and R 7a and R 7b , as well as R 7c and R 7d , may each be taken together with the carbon atom to which they are bonded to form a C3-C4 cycloalkyl group, or Het is a group represented by Het1, A 2 is -CR 7a R 7b -, A 3 is -CR 7e R 7f -CR 7g R 7h -* 1 (* 1 represents the bonding position with A 2 ), and R 7a and R 7b , R 7e and R 7f , as well as R 7g and R Compounds in which each of 7h may be taken together with the carbon atom to which they are attached to form a C3-C4 cycloalkyl group
  • Aspect 223 A compound in which, in any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, Het is a group represented by Het1, B 1 is CR 6a , B 2 is CR 6b , B 3 is a nitrogen atom, R 6a is a hydrogen atom, R 6b is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or OR 72 , and R 72 is a C1-C6 chain hydrocarbon group optionally substituted with a halogen atom.
  • Aspect 224 A compound according to any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, in which Het is a group represented by Het2, B 1 is CR 6a , B 2 is CR 6b , B 3 is a nitrogen atom, R 6a is a hydrogen atom, R 6b is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or OR 72 , and R 72 is a C1-C6 chain hydrocarbon group optionally substituted with a halogen atom.
  • Aspect 225 A compound in any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, wherein Het is a group represented by Het1, B 1 is CR 6a , B 2 is CR 6b , B 3 is a nitrogen atom, R 6a is a hydrogen atom, R 6b is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a halogen atom and a cyano group, a halogen atom, or OR 72 , and R 72 is a C1-C6 chain hydrocarbon group optionally substituted with a halogen atom.
  • Aspect 226 A compound in any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, wherein Het is a group represented by Het2, B 1 is CR 6a , B 2 is CR 6b , B 3 is a nitrogen atom, R 6a is a hydrogen atom, R 6b is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a halogen atom and a cyano group, a halogen atom, or OR 72 , and R 72 is a C1-C6 chain hydrocarbon group optionally substituted with a halogen atom.
  • Aspect 228 A compound in which, in any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, Het is a group represented by Het1, B 1 is CR 6a , B 2 is CR 6b , B 3 is a nitrogen atom, R 6a is a hydrogen atom, R 6b is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or OR 72 , R 72 is a C1-C6 chain hydrocarbon group optionally substituted with halogen atoms, A 2 is -CR 7a R 7b -, A 3 is -CR 7c R 7d -, and R 7a , R 7b , R 7c and R 7d are hydrogen atoms.
  • Aspect 229 A compound in any one of Aspects 1 to 5, Aspects 8 to 154, or Compound N of the present invention, in which Het is a group represented by Het1, B 1 is CR 6a , B 2 is CR 6b , B 3 is a nitrogen atom, R 6a is a hydrogen atom, R 6b is a C1-C6 alkyl group optionally substituted with one or more halogen atoms, OR 72 or a halogen atom, R 72 is a C1-C6 alkyl group optionally substituted with a halogen atom, A 2 is -CR 7a R 7b -, A 3 is -CR 7c R 7d -, and R 7a , R 7b , R 7c and R 7d are hydrogen atoms.
  • intermediate A examples include the following compounds.
  • [Aspect A1] A compound in which W in intermediate A is an oxygen atom.
  • [Aspect A2] A compound in which R2 in intermediate A is a C1-C6 alkyl group.
  • [Aspect A3] A compound in which R 2 in intermediate A is an ethyl group.
  • [Aspect A4] A compound in which X 1 in intermediate A is a chlorine atom, a bromine atom, or an iodine atom.
  • [Aspect A5] A compound in which X 1 in intermediate A is a hydroxy group.
  • the combinations of G 1 , G 2 , G 3 and G 4 are: a combination in which G 1 is CR 3a , G 2 is CR 3b , G 3 is CR 3c and G 4 is a nitrogen atom; a combination in which G 1 is CR 3a , G 2 is CR 3b , G 3 is a nitrogen atom and G 4 is CR 3d ; a combination in which G 1 is CR 3a , G 2 is a nitrogen atom, G 3 is CR 3c and G 4 is CR 3d ; a combination in which G 1 is a nitrogen atom, G 2 is CR 3b , G 3 is CR 3c and G 4 is CR 3d ; or a combination in which G 1 is CR 3a , G 2 is CR 3b , G 3 is CR 3c and G 4 is CR 3d , and R Compounds in which R 3a , R 3c , and R 3d are hydrogen
  • G 1 is CR 3a
  • G 2 is CR 3b
  • G 3 is CR 3c and G 4 is a nitrogen atom
  • G 1 is CR 3a
  • G 2 is CR 3b
  • G 3 is a nitrogen atom and G 4 is CR 3d
  • G 1 is CR 3a
  • G 2 is a nitrogen atom
  • G 3 is CR 3c and G 4 is CR 3d
  • G 1 is a nitrogen atom
  • G 2 is CR 3b
  • G 3 is CR 3c and G 4 is CR 3d
  • G 1 is a nitrogen atom
  • G 2 is CR 3b
  • G 3 is CR 3c and G 4 is CR 3d
  • R Compounds in which R 3a , R 3b and R 3d are hydrogen atoms
  • R 3c is a halogen atom.
  • Aspect A13 The compound in which W is an oxygen atom in Aspect A2.
  • Aspect A14 The compound in which W is an oxygen atom in Aspect A3.
  • Aspect A15 The compound in which W is an oxygen atom in A4.
  • Aspect A16 The compound in which W is an oxygen atom in A5.
  • Aspect A17 The compound in which W is an oxygen atom in A6.
  • Aspect A26 The compound in Aspect A6, wherein R 2 is a C1-C6 alkyl group.
  • Aspect A27 The compound in Aspect A7, wherein R 2 is a C1-C6 alkyl group.
  • Aspect A28 The compound in Aspect A8, wherein R 2 is a C1-C6 alkyl group.
  • Aspect A29 The compound in Aspect A9, wherein R 2 is a C1-C6 alkyl group.
  • Aspect A30 The compound in Aspect A10, wherein R 2 is a C1-C6 alkyl group.
  • Aspect A31 The compound in Aspect A11, wherein R 2 is a C1-C6 alkyl group.
  • Aspect A32 The compound in Aspect A12, wherein R 2 is a C1-C6 alkyl group.
  • Aspect A33 The compound in Aspect A4, wherein R 2 is an ethyl group.
  • Aspect A34 The compound in Aspect A5, wherein R 2 is an ethyl group.
  • Aspect A35 The compound in which R 2 in A6 is an ethyl group.
  • Aspect A36 The compound in Aspect A7, wherein R 2 is an ethyl group.
  • Aspect A37 The compound in Aspect A8, wherein R 2 is an ethyl group.
  • Aspect A38 The compound in Aspect A9, wherein R 2 is an ethyl group.
  • A54 The compound in Aspect A9, wherein X 1 is a chlorine atom, a bromine atom, or an iodine atom.
  • A55 The compound in A10, wherein X 1 is a chlorine atom, a bromine atom, or an iodine atom.
  • A56 The compound in Aspect A11, wherein X 1 is a chlorine atom, a bromine atom, or an iodine atom.
  • A57 The compound in A12, wherein X 1 is a chlorine atom, a bromine atom, or an iodine atom.
  • A58 The compound in which X 1 is a hydroxy group in the aspect A6.
  • Aspect A59 The compound in Aspect A7, wherein X 1 is a hydroxy group.
  • Aspect A60 The compound in which X 1 is a hydroxy group in the aspect A8.
  • Aspect A61 The compound in which X 1 is a hydroxy group in the aspect A9.
  • Aspect A62 The compound in Aspect A10, wherein X 1 is a hydroxy group.
  • Aspect A63 The compound in Aspect A11, wherein X 1 is a hydroxy group.
  • Aspect A64 The compound in A12, wherein X 1 is a hydroxy group.
  • a compound in any one of Aspects A1 to A64 or Intermediate A in which B 1 is CR 6a , B 2 is CR 6b , B 3 is CR 6c , R 6a is a hydrogen atom, and R 6b and R 6c are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a halogen atom and a cyano group, or OR 72 .
  • a compound in any one of A1 to A64 or Intermediate A wherein the combination of A2 and A3 is such that A2 is -CR7aR7b- and A3 is -CR7cR7d- ; or A2 is -CR7aR7b- and A3 is -CR7eR7f - CR7gR7h- * 1 (* 1 represents the bonding position to A2 ).
  • a compound in which, in any one of A1 to A64 or Intermediate A, the combination of A2 and A3 is such that A2 is -CR7aR7b- and A3 is -CR7cR7d- ; or A2 is -CR7aR7b- and A3 is -CR7eR7f - CR7gR7h- * 1 (* 1 represents the bonding position to A2 ), and R7a, R7b, R7c, R7d, R7e, R7f , R7g , and R7h are the same or different and are a C1 - C6 alkyl group, or a hydrogen atom.
  • intermediate B examples include the following compounds.
  • G 1 is CR 3a
  • G 2 is CR 3b
  • G 3 is CR 3c and G 4 is a nitrogen atom
  • G 1 is CR 3a
  • G 2 is CR 3b
  • G 3 is a nitrogen atom and G 4 is CR 3d
  • G 1 is CR 3a
  • G 2 is a nitrogen atom
  • G 3 is CR 3c and G 4 is CR 3d
  • G 1 is a nitrogen atom
  • G 2 is CR 3b
  • G 3 is CR 3c and G 4 is CR 3d
  • G 1 is a nitrogen atom
  • G 2 is CR 3b
  • G 3 is CR 3c and G 4 is CR 3d
  • R Compounds in which R 3a , R 3c , and R 3d are hydrogen atoms
  • R 3b is a C1-C6 alkyl group optionally substituted with one
  • G 1 is CR 3a
  • G 2 is CR 3b
  • G 3 is CR 3c and G 4 is a nitrogen atom
  • G 1 is CR 3a
  • G 2 is CR 3b
  • G 3 is a nitrogen atom and G 4 is CR 3d
  • G 1 is CR 3a
  • G 2 is a nitrogen atom
  • G 3 is CR 3c and G 4 is CR 3d
  • G 1 is a nitrogen atom
  • G 2 is CR 3b
  • G 3 is CR 3c and G 4 is CR 3d
  • G 1 is a nitrogen atom
  • G 2 is CR 3b
  • G 3 is CR 3c and G 4 is CR 3d
  • R Compounds in which R 3a , R 3b and R 3d are hydrogen atoms
  • R 3c is a halogen atom.
  • G 1 is CR 3a
  • G 2 is CR 3b
  • G 3 is CR 3c
  • G 4 is CR 3d
  • R 3a , R 3b and R 3d are hydrogen atoms
  • R 3c is a halogen atom.
  • G13 The compound in which W is an oxygen atom in the aspect B2.
  • Aspect B14 The compound in which W is an oxygen atom in the aspect B3.
  • Aspect B15 The compound in which W is an oxygen atom in the aspect B4.
  • Aspect B16 The compound in which W is an oxygen atom in the aspect B5.
  • Aspect B17 The compound in which W is an oxygen atom in the aspect B6.
  • Aspect B68 A compound in any one of Aspects B1 to B64 or Intermediate B, in which B 1 is a nitrogen atom, B 2 is CR 6b , B 3 is CR 6c , R 6b is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a halogen atom and a cyano group, or OR 72 , and R 6c is a hydrogen atom.
  • Aspect B73 A compound in any one of Aspects B1 to B64 or Intermediate B, wherein the combination of A2 and A3 is: A2 is -CR7aR7b- and A3 is -CR7cR7d- ; A2 is -CR7aR7b- and A3 is -CR7eR7f -CR7gR7h-*1 (*1 represents the bonding position to A2); A2 is -NR5a- and A3 is -CR7cR7d- ; or A2 is -NR5a- and A3 is -CR7eR7f - CR7gR7h- * 1 ( * 1 represents the bonding position to A2 ) .
  • Aspect B74 A compound in any one of Aspects B1 to B64 or Intermediate B, wherein the combination of A2 and A3 is such that A2 is -CR7aR7b- and A3 is -CR7cR7d- ; or A2 is -CR7aR7b- and A3 is -CR7eR7f - CR7gR7h- * 1 (* 1 represents the bonding position to A2 ).
  • Aspect B75 A compound in which, in any one of Aspects B1 to B64 or Intermediate B, the combination of A2 and A3 is such that A2 is -CR7aR7b- and A3 is -CR7cR7d- ; or A2 is -CR7aR7b- and A3 is -CR7eR7f - CR7gR7h- * 1 (* 1 represents the bonding position to A2 ), and R7a, R7b, R7c, R7d, R7e, R7f, R7g , and R7h are the same or different and are a C1 - C6 alkyl group, or a hydrogen atom.
  • Aspect B78 The compound in any one of Aspects B1 to B64 or Intermediate B, wherein A 2 is -CR 7a R 7b -, A 3 is -CR 7c R 7d -, and R 7a , R 7b , R 7c and R 7d are hydrogen atoms.
  • Aspect B80 A compound in any one of Aspects B1 to B64 or Intermediate B, in which B 1 is CR 6a , B 2 is CR 6b , B 3 is a nitrogen atom, R 6a is a hydrogen atom, R 6b is a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or OR 72 , R 72 is a C1-C6 alkyl group optionally substituted with a halogen atom, A 2 is -CR 7a R 7b -, A 3 is -CR 7c R 7d -, and R 7a , R 7b , R 7c and R 7d are hydrogen atoms.
  • Aspect B81 A compound in any one of Aspects B1 to B64 or Intermediate B, in which B 1 is CR 6a , B 2 is CR 6b , B 3 is a nitrogen atom, R 6a is a hydrogen atom, R 6b is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, or OR 72 , and R 72 is a C1-C6 chain hydrocarbon group optionally substituted with a halogen atom.
  • a compound represented by formula (I-b) (hereinafter referred to as compound (I-b)) or a compound represented by formula (I-c) (hereinafter referred to as compound (I-c)) can be produced by reacting a compound represented by formula (I-a) (hereinafter referred to as compound (I-a)) with an oxidizing agent.
  • an oxidizing agent a compound represented by formula (I-a) (hereinafter referred to as compound (I-a))
  • the symbols have the same meanings as defined above.
  • halogenated hydrocarbons such as dichloromethane and chloroform (hereinafter referred to as halogenated hydrocarbons), nitriles such as acetonitrile (hereinafter referred to as nitriles), alcohols such as methanol and ethanol (hereinafter referred to as alcohols), acetic acid, water, and mixtures of two or more of these.
  • halogenated hydrocarbons such as dichloromethane and chloroform
  • nitriles such as acetonitrile (hereinafter referred to as nitriles)
  • alcohols such as methanol and ethanol (hereinafter referred to as alcohols)
  • a base or a catalyst may be used as necessary.
  • the base may be, for example, sodium carbonate.
  • the base is usually used in a ratio of 0.01 to 1 mole per mole of compound (Ia).
  • the catalyst include tungstic acid and sodium tungstate.
  • the catalyst is usually used in a ratio of 0.01 to 0.5 moles per mole of compound (Ia).
  • the oxidizing agent is usually used in a ratio of 1 to 1.2 moles per mole of compound (Ia).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 80° C.
  • the reaction time is usually in the range of 0.1 to 12 hours.
  • the reaction is usually carried out in a solvent, such as halogenated hydrocarbons, nitriles, alcohols, acetic acid, water, and mixtures of two or more of these.
  • Oxidizing agents include, for example, mCPBA and hydrogen peroxide.
  • a base or a catalyst may be used as necessary.
  • the base may be, for example, sodium carbonate.
  • the base is usually used in a ratio of 0.01 to 1 mol per 1 mol of compound (Ib).
  • An example of the catalyst is sodium tungstate.
  • the catalyst When a catalyst is used in the reaction, the catalyst is usually used in a ratio of 0.01 to 0.5 moles per mole of compound (Ib).
  • the oxidizing agent In the reaction, the oxidizing agent is usually used in a ratio of 1 to 2 moles per mole of compound (Ib).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 120° C.
  • the reaction time is usually in the range of 0.1 to 12 hours.
  • water is added to the reaction mixture, which is then extracted with an organic solvent.
  • the organic layer is washed with an aqueous solution of a reducing agent (e.g., sodium sulfite, sodium thiosulfate) and an aqueous solution of a base (e.g., sodium hydrogen carbonate) as necessary.
  • the organic layer is dried and concentrated to obtain compound (I-c).
  • Compound (Ic) can also be produced in a one-step reaction (one-pot) by reacting compound (Ia) with an oxidizing agent.
  • the reaction can be carried out according to the method for producing compound (Ic) from compound (Ib) using an oxidizing agent usually in a ratio of 2 to 5 moles per mole of compound (Ia).
  • the compound represented by formula (IS-1) (hereinafter referred to as compound (IS-1)) can be produced by reacting a compound represented by formula (IO-1) (hereinafter referred to as compound (IO-1)) with a sulfurizing agent. [In the formula, the symbols have the same meanings as defined above.] The reaction is carried out in a solvent or in the absence of a solvent.
  • ethers such as tetrahydrofuran (hereinafter referred to as THF), methyl tert-butyl ether (hereinafter referred to as MTBE), ethylene glycol dimethyl ether, 1,4-dioxane, and cyclopentyl methyl ether
  • halogenated hydrocarbons aromatic hydrocarbons (hereinafter referred to as aromatic hydrocarbons) such as toluene and xylene
  • aromatic hydrocarbons such as toluene and xylene
  • nitrogen-containing aromatic compounds hereinafter referred to as nitrogen-containing aromatic compounds
  • nitrogen-containing aromatic compounds such as pyridine, picoline, lutidine, and quinoline; and mixtures of two or more of these.
  • the sulfurizing agent examples include diphosphorus pentasulfide and Lawesson's reagent (2,4-bis(4-methoxyphenyl)-1,3-dithia-2,4-diphosphetane-2,4-disulfide).
  • the sulfurizing agent is usually used in a ratio of 1 mol to 3 mol per mol of compound (IO-1).
  • the reaction temperature is usually in the range of 0° C. to 200° C.
  • the reaction time is usually in the range of 1 to 24 hours.
  • the compound (IS-1) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer.
  • the compound represented by formula (I-S-2) (hereinafter referred to as compound (I-S-2)) can be produced by reacting a compound represented by formula (IO-2) (hereinafter referred to as compound (IO-2)) with a sulfurizing agent.
  • IO-2 a compound represented by formula (IO-2)
  • IO-2 a compound represented by formula (IO-2)
  • Compound (IO-1) can be produced by reacting a compound represented by formula (M-1) (hereinafter referred to as compound (M-1)) with a compound represented by formula (M-2) (hereinafter referred to as compound (M-2)) in the presence of a base.
  • M-1 a compound represented by formula (M-1)
  • M-2 a compound represented by formula (M-2)
  • Xa represents a leaving group such as a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, etc., and the other symbols have the same meanings as defined above.
  • the reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents (hereinafter referred to as aprotic polar solvents) such as N,N-dimethylformamide (hereinafter referred to as DMF), N-methylpyrrolidone (hereinafter referred to as NMP), dimethylsulfoxide (hereinafter referred to as DMSO), and mixtures of two or more of these.
  • a solvent such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents (hereinafter referred to as aprotic polar solvents) such as N,N-dimethylformamide (hereinafter referred to as DMF), N-methylpyrrol
  • the base examples include organic bases such as triethylamine, N,N-diisopropylethylamine, pyridine, and 4-(dimethylamino)pyridine (hereinafter referred to as organic bases); alkali metal carbonates such as sodium carbonate, potassium carbonate, and cesium carbonate (hereinafter referred to as alkali metal carbonates); and alkali metal hydrides such as sodium hydride (hereinafter referred to as alkali metal hydrides).
  • organic bases such as triethylamine, N,N-diisopropylethylamine, pyridine, and 4-(dimethylamino)pyridine
  • alkali metal carbonates such as sodium carbonate, potassium carbonate, and cesium carbonate
  • alkali metal hydrides such as sodium hydride (hereinafter referred to as alkali metal hydrides).
  • the reaction can be carried out using a metal catalyst, if necessary.
  • the metal catalyst examples include copper catalysts such as copper (I) iodide, copper (I) bromide, copper (I) chloride, copper (I) oxide, trifluoromethanesulfonic acid copper (I) benzene complex, tetrakis (acetonitrile) copper (I) hexafluorophosphate, and 2-thiophene carboxylate copper (I); nickel catalysts such as bis (cyclooctadiene) nickel (0) and nickel chloride (II); and palladium catalysts such as palladium (II) acetate, tetrakis (triphenylphosphine) palladium (0), and tris (dibenzylideneacetone) dipalladium (0).
  • copper catalysts such as copper (I) iodide, copper (I) bromide, copper (I) chloride, copper (I) oxide, trifluoromethanesulfonic acid copper (I) benzene complex, tetra
  • the metal catalyst When a metal catalyst is used in the reaction, the metal catalyst is usually used in a ratio of 0.01 to 0.5 moles per mole of compound (M-1).
  • the reaction can be carried out using a ligand as necessary.
  • the ligand include triphenylphosphine, 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (hereinafter referred to as xantphos), 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol,
  • the ligand When a ligand is used in the reaction, the ligand is usually used in a ratio of 0.01 to 0.5 moles per mole of compound (M-1).
  • compound (M-2) In the reaction, compound (M-2) is usually used in a ratio of 0.8 to 1.2 moles and base is usually used in a ratio of 1 to 3 moles per mole of compound (M-1).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 150° C.
  • the reaction time is usually in the range of 0.5 to 24 hours.
  • the compound (IO-1) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer.
  • Compound (M-1) is a commercially available compound, or can be produced, for example, according to the method described in WO 2013/192346.
  • Compound (IO-2) can be produced by reacting a compound represented by formula (M-3) (hereinafter referred to as compound (M-3)) with compound (M-2) in the presence of a base. [In the formula, the symbols have the same meanings as defined above.] The reaction can be carried out according to Production Method 4, except that compound (M-3) is used in place of compound (M-1). Compound (M-3) is a commercially available compound or can be prepared using known methods.
  • the compound represented by formula (In0-1) (hereinafter referred to as compound (In0-1)) can be produced according to the following scheme. [In the formula, Xd represents a chlorine atom, a bromine atom, or an iodine atom, and the other symbols have the same meanings as defined above.]
  • a method for producing the compound represented by formula (M-5) (hereinafter referred to as compound (M-5)) will be described.
  • Compound (M-5) can be produced in accordance with Production Method 4, using a compound represented by formula (M-4) (hereinafter referred to as compound (M-4)) instead of compound (M-2).
  • the compound (M-6) can be produced by reacting the compound (M-5) with a halogenating agent.
  • the reaction is usually carried out in a solvent, such as alcohols, nitriles, ethers, aromatic hydrocarbons, aprotic polar solvents, halogenated hydrocarbons, water, and mixtures of two or more of these.
  • halogenating agents include chlorine, bromine, iodine, N-chlorosuccinimide, N-bromosuccinimide, and N-iodosuccinimide.
  • the halogenating agent is usually used in an amount of 1 to 20 moles per mole of compound (M-5).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 200° C.
  • the reaction time is usually in the range of 0.1 to 72 hours.
  • Compound (I-n0-1) can be produced by reacting compound (M-5), a compound represented by formula (R-1) (hereinafter referred to as compound (R-1)), and a halogenating agent.
  • the reaction is usually carried out in a solvent, such as alcohols, nitriles, ethers, aromatic hydrocarbons, aprotic polar solvents, halogenated hydrocarbons, water, and mixtures of two or more of these.
  • halogenating agents include chlorine, bromine, iodine, N-chlorosuccinimide, N-bromosuccinimide, and N-iodosuccinimide.
  • compound (R-1) is usually used in a ratio of 1 to 20 moles and a halogenating agent is usually used in a ratio of 1 to 20 moles per mole of compound (M-5).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 200° C.
  • the reaction time is usually in the range of 0.1 to 72 hours.
  • the compound (I-n0-1) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
  • Compound (R-1) is a commercially available compound or can be prepared using known methods.
  • Compound (I-n0-1) can also be produced by reacting compound (M-6) with compound (R-1) in the presence of a metal catalyst and a base.
  • the reaction is usually carried out in a solvent, such as alcohols, nitriles, ethers, aromatic hydrocarbons, aprotic polar solvents, water, and mixtures of two or more of these.
  • the metal catalyst examples include palladium catalysts such as tetrakis(triphenylphosphine)palladium(0), [1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloride, tris(dibenzylideneacetone)dipalladium(0), and palladium(II) acetate; nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; and copper catalysts such as copper(I) iodide and copper(I) chloride.
  • bases include alkali metal hydrides, alkali metal carbonates, and organic bases. A ligand can also be used in the reaction.
  • Examples of the ligand include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, and 1,10-phenanthroline.
  • the ligand is usually used in a ratio of 0.01 to 1 mole per mole of compound (M-6).
  • compound (R-1) is usually used in a ratio of 1 to 20 moles
  • metal catalyst is usually used in a ratio of 0.01 to 0.5 moles
  • base is usually used in a ratio of 0.1 to 5 moles, relative to 1 mole of compound (M-6).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 200° C.
  • the reaction time is usually in the range of 0.1 to 72 hours.
  • the compound (I-n0-1) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
  • Production method 7 The compound represented by the formula (In0-2) (hereinafter referred to as compound (In0-2)) can be produced according to the following scheme. [In the formula, the symbols have the same meanings as defined above.]
  • the compound represented by formula (M-7) (hereinafter referred to as compound (M-7)) can be produced according to Production Method 6, using compound (M-3) instead of compound (M-1).
  • the compound represented by formula (M-8) (hereinafter referred to as compound (M-8)) can be produced by using compound (M-7) instead of compound (M-5) in accordance with the method for producing compound (M-6) from compound (M-5) in Production Method 6.
  • Compound (I-n0-2) can be produced by using compound (M-7) instead of compound (M-5) in accordance with the method for producing compound (I-n0-1) from compound (M-5) in Production Method 6.
  • Compound (I-n0-2) can also be produced by using compound (M-8) instead of compound (M-6) in accordance with the method for producing compound (I-n0-1) from compound (M-6) in Production Method 6.
  • Compound (IO-1) can also be produced by reacting a compound represented by formula (M-9-X) (hereinafter referred to as compound (M-9-X)) with a base.
  • XA represents a chlorine atom, a bromine atom, or an iodine atom, and the other symbols have the same meanings as defined above.
  • the reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more of these.
  • the base include organic bases; alkali metal carbonates; and alkali metal hydrides.
  • the reaction can be carried out using a metal catalyst as necessary.
  • the metal catalyst examples include copper catalysts such as copper (I) iodide, copper (I) bromide, copper (I) chloride, copper (I) oxide, copper (I) trifluoromethanesulfonate benzene complex, tetrakis (acetonitrile) copper (I) hexafluorophosphate, and 2-thiophene carboxylate copper (I); nickel catalysts such as bis (cyclooctadiene) nickel (0) and nickel (II) chloride; and palladium catalysts such as palladium (II) acetate, tetrakis (triphenylphosphine) palladium (0), and tris (dibenzylideneacetone) dipalladium (0).
  • copper catalysts such as copper (I) iodide, copper (I) bromide, copper (I) chloride, copper (I) oxide, copper (I) trifluoromethanesulfonate benzene complex, te
  • the metal catalyst is usually used in a ratio of 0.01 to 0.5 moles per mole of compound (M-9-X).
  • the reaction can be carried out using a ligand as necessary.
  • the ligand include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, trans-1,2-cyclohexanediamine, trans-N,N'-dimethylcycl
  • the ligand When a ligand is used in the reaction, the ligand is usually used in a ratio of 0.01 to 0.5 mol per 1 mol of the compound (M-9-X). In the reaction, 1 to 5 moles of the base are usually used per mole of the compound (M-9-X).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 150° C.
  • the reaction time is usually in the range of 0.5 to 24 hours.
  • the compound (IO-1) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer.
  • Compound (IO-1) can also be produced by intramolecular condensation of a compound represented by formula (M-9-OH) (hereinafter referred to as compound (M-9-OH)) in the presence of a condensing agent.
  • a condensing agent such as ethers, halogenated hydrocarbons, aromatic hydrocarbons, esters such as ethyl acetate and butyl acetate (hereinafter referred to as esters), nitriles, aprotic polar solvents, nitrogen-containing aromatic compounds, and mixtures of two or more of these.
  • the condensing agent used in the reaction may be, for example, a mixture of triphenylphosphine and an azodiester compound, etc.
  • the azodiester compound may be, for example, diethyl azodicarboxylate.
  • the condensing agent is usually used in a ratio of 1 to 5 moles per mole of the compound (M-9-OH).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 200° C.
  • the reaction time is usually in the range of 0.1 to 24 hours.
  • the compound (IO-1) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer.
  • Compound (IO-1) can also be produced by reacting a compound represented by formula (M-10-X) (hereinafter referred to as compound (M-10-X)) with a base. [In the formula, the symbols have the same meanings as defined above.] Compound (IO-1) can also be produced according to Production Method 8, using compound (M-10-X) instead of compound (M-9-X).
  • Compound (IO-1) can also be produced by intramolecular condensation of a compound represented by formula (M-10-OH) (hereinafter referred to as compound (M-10-OH)) in the presence of a condensing agent. [In the formula, the symbols have the same meanings as defined above.] Compound (IO-1) can also be produced according to Production Method 9, except for using compound (M-10-OH) instead of compound (M-9-OH).
  • the compound represented by formula (I-b-p) (hereinafter referred to as compound (I-b-p)) or the compound represented by formula (I-c-p) (hereinafter referred to as compound (I-c-p)) can be produced by reacting a compound represented by formula (I-a-p) (hereinafter referred to as compound (I-a-p)) with an oxidizing agent.
  • a compound represented by formula (I-a-p) hereinafter referred to as compound (I-a-p)
  • compound (I-a-p) [In the formula, the symbols have the same meanings as defined above.]
  • Compound (I-bp) can be produced according to Production Method 1, except that compound (I-ap) is used instead of compound (Ia).
  • Compound (Icp) can be produced according to Production Method 1, except that compound (Ibp) is used in place of compound (Ib).
  • compound (I-cp) can also be produced according to Production Method 1, except that compound (I-
  • the compound represented by formula (I-S-1p) (hereinafter referred to as compound (I-S-1p)) can be produced by reacting a compound represented by formula (IO-1p) (hereinafter referred to as compound (IO-1p)) with a sulfurizing agent. [In the formula, the symbols have the same meanings as defined above.]
  • Compound (IS-1p) can be produced according to Production Method 2, except that compound (IO-1p) is used instead of compound (IO-1).
  • the compound represented by formula (I-S-2p) (hereinafter referred to as compound (I-S-2p)) can be produced by reacting a compound represented by formula (IO-2p) (hereinafter referred to as compound (IO-2p)) with a sulfiding agent. [In the formula, the symbols have the same meanings as defined above.]
  • Compound (IS-2p) can be produced according to Production Method 2, except that compound (IO-2p) is used instead of compound (IO-1).
  • Compound (IO-1p) can be produced by reacting compound (M-1) with a compound represented by formula (M-11) (hereinafter referred to as compound (M-11)) in the presence of a base. [In the formula, the symbols have the same meanings as defined above.] Compound (IO-1p) can be produced according to Production Method 4, except that compound (M-11) is used instead of compound (M-2).
  • Compound (IO-2p) can be produced by reacting compound (M-3) with compound (M-11) in the presence of a base. [In the formula, the symbols have the same meanings as defined above.] Compound (IO-2p) can be produced according to Production Method 5, except that compound (M-11) is used instead of compound (M-2).
  • the compound represented by the formula (In0-1p) (hereinafter referred to as compound (In0-1p)) can be produced according to the following scheme. [In the formula, the symbols have the same meanings as defined above.]
  • the compound represented by formula (M-13) (hereinafter referred to as compound (M-13)) can be produced according to Production Method 6, using compound (M-12) instead of compound (M-4).
  • Compound (M-12) is a commercially available compound or can be prepared using known methods.
  • compound (M-14) The compound represented by formula (M-14) (hereinafter referred to as compound (M-14)) can be produced in accordance with the method of producing compound (M-6) from compound (M-5) in Production Method 6, using compound (M-13) instead of compound (M-5).
  • Compound (I-n0-1p) can also be produced by using compound (M-13) instead of compound (M-5) in accordance with the method for producing compound (I-n0-1) from compound (M-5) in Production Method 6.
  • Compound (I-n0-1p) can also be produced by using compound (M-14) instead of compound (M-6) in accordance with the method for producing compound (I-n0-1) from compound (M-6) in Production Method 6.
  • the compound represented by the formula (In0-2p) (hereinafter referred to as compound (In0-2p)) can be produced according to the following scheme. [In the formula, the symbols have the same meanings as defined above.]
  • the compound represented by formula (M-15) (hereinafter referred to as compound (M-15)) can be produced according to Production Method 7, using compound (M-12) instead of compound (M-4).
  • compound (M-16) The compound represented by formula (M-16) (hereinafter referred to as compound (M-16)) can be produced by using compound (M-15) instead of compound (M-7) in accordance with the method for producing compound (M-8) from compound (M-7) in Production Method 7.
  • Compound (I-n0-2p) can also be produced by using compound (M-15) instead of compound (M-7) in accordance with the method for producing compound (I-n0-2) from compound (M-7) in Production Method 7.
  • Compound (I-n0-2p) can also be produced by using compound (M-16) instead of compound (M-8) in accordance with the method for producing compound (I-n0-2) from compound (M-8) in Production Method 7.
  • Compound (IO-1p) can also be produced by reacting a compound represented by formula (M-17-X) (hereinafter referred to as compound (M-17-X)) with a base. [In the formula, the symbols have the same meanings as defined above.] Compound (IO-1p) can be produced according to Production Method 8, except that compound (M-17-X) is used instead of compound (M-9-X).
  • Compound (IO-1p) can also be produced by intramolecular condensation of a compound represented by formula (M-17-OH) (hereinafter referred to as compound (M-17-OH)) in the presence of a condensing agent. [In the formula, the symbols have the same meanings as defined above.] Compound (IO-1p) can be produced according to Production Method 9, except that compound (M-17-OH) is used instead of compound (M-9-OH).
  • Compound (IO-1p) can also be produced by reacting a compound represented by formula (M-18-X) (hereinafter referred to as compound (M-18-X)) with a base. [In the formula, the symbols have the same meanings as defined above.] Compound (IO-1p) can be produced according to Production Method 10, except that compound (M-18-X) is used instead of compound (M-10-X).
  • Compound (IO-1p) can also be produced by intramolecular condensation of a compound represented by formula (M-18-OH) (hereinafter referred to as compound (M-18-OH)) in the presence of a condensing agent. [In the formula, the symbols have the same meanings as defined above.] Compound (IO-1p) can also be produced according to Production Method 11, except for using compound (M-18-OH) instead of compound (M-10-OH).
  • N-oxide of the compound represented by formula (I) can be produced by reacting the compound represented by formula (I) with an oxidizing agent.
  • the reaction can be carried out, for example, in accordance with Production Method 1, the method described in U.S. Patent Application Publication No. 2018/0009778, or WO 2016/121970.
  • the compound represented by formula (I-O-1ph) (hereinafter referred to as compound (I-O-1ph)) can be produced by reacting a compound represented by formula (I-O-1pp) (hereinafter referred to as compound (I-O-1pp)) with a compound represented by formula (Ph-BOH) (hereinafter referred to as compound (Ph-BOH)) or a compound represented by formula (Ph-Bpin) (hereinafter referred to as compound (Ph-Bpin)) in the presence of a metal catalyst and a base.
  • a compound represented by formula (I-O-1pp) hereinafter referred to as compound (I-O-1pp)
  • a compound represented by formula (Ph-BOH) hereinafter referred to as compound (Ph-BOH)
  • Ph-Bpin a compound represented by formula (Ph-Bpin)
  • R 4p represents a chlorine atom, a bromine atom, or an iodine atom
  • R 4h represents a substituent selected from group H2
  • y represents 0, 1, 2, 3, 4, or 5
  • the other symbols have the same meanings as defined above.
  • the reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, water, and mixtures of two or more of these.
  • a solvent such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, water, and mixtures of two or more of these.
  • the base used in the reaction include organic bases; alkali metal carbonates; alkali metal hydrides; and alkali metal phosphates such as potassium phosphate (hereinafter referred to as alkali metal phosphates).
  • metal catalyst used in the reaction examples include nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel chloride(II); and palladium catalysts such as palladium acetate(II), tetrakis(triphenylphosphine)palladium(0), tris(dibenzylideneacetone)dipalladium(0), and [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II).
  • nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel chloride(II)
  • palladium catalysts such as palladium acetate(II), tetrakis(triphenylphosphine)palladium(0), tris(dibenzylideneacetone)dipalladium(0), and [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II).
  • the reaction can also be
  • Examples of the ligand include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, trans-1,2-cyclohexanediamine, trans-N,N'-dimethylcyclohexane-1,2-diamine, and N,N'-dimethylethylenediamine.
  • the ligand is usually used in a ratio of 0.01 to 0.5 mol per 1 mol of the compound (IO-1pp).
  • the compound (Ph-BOH) or the compound (Ph-Bpin) is usually used in a ratio of 1 to 5 moles
  • the metal catalyst is usually used in a ratio of 0.01 to 0.5 moles
  • the base is usually used in a ratio of 1 to 5 moles, relative to 1 mole of the compound (IO-1pp).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 150° C.
  • the reaction time is usually in the range of 0.5 to 24 hours.
  • the compound (IO-1ph) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer.
  • the compound represented by formula (I-O-2ph) (hereinafter referred to as compound (I-O-2ph)) can be produced by reacting a compound represented by formula (I-O-2pp) (hereinafter referred to as compound (I-O-2pp)) with a compound (Ph-BOH) or a compound (Ph-Bpin) in the presence of a metal catalyst and a base. [In the formula, the symbols have the same meanings as defined above.] Compound (IO-2ph) can be produced according to Production Method 24, except for using compound (IO-2pp) instead of compound (IO-1pp).
  • the compound represented by formula (IO-1Ar) (hereinafter referred to as compound (IO-1Ar)) can be produced according to the following scheme.
  • a 1a represents CR 1a or a nitrogen atom
  • R 1a represents a hydrogen atom or a substituent selected from the group H2
  • Xh represents a halogen atom
  • the other symbols have the same meanings as defined above.
  • Compound (IO-1-Bpin) can be produced by reacting compound (IO-1pa) with Bis(pinacolato)diboron in the presence of a metal catalyst and a base.
  • the reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more of these.
  • the base used in the reaction include organic bases, alkali metal carbonates, alkali metal hydrides, and alkali metal phosphates.
  • the metal catalyst used in the reaction includes, for example, a palladium catalyst such as [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II) and the like.
  • Bis(pinacolato)diboron is usually used in a ratio of 1 to 3 moles
  • a metal catalyst is usually used in a ratio of 0.01 to 0.5 moles
  • a base is usually used in a ratio of 1 to 5 moles, relative to 1 mole of compound (IO-1pa).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 150° C.
  • the reaction time is usually in the range of 0.5 to 24 hours.
  • the compound (IO-1-Bpin) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer.
  • Compound (IO-1Ar) can be produced by reacting compound (IO-1-Bpin) with a compound represented by formula (Ar-hal) (hereinafter referred to as compound (Ar-hal)) in the presence of a metal catalyst and a base.
  • the reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, water, and mixtures of two or more of these.
  • a solvent such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, water, and mixtures of two or more of these.
  • the base used in the reaction include organic bases, alkali metal carbonates, alkali metal hydrides, and alkali metal phosphates.
  • metal catalyst used in the reaction examples include palladium catalysts such as palladium acetate(II), tetrakis(triphenylphosphine)palladium(0), tris(dibenzylideneacetone)dipalladium(0), and [1,1′-bis(diphenylphosphino)ferrocene]dichloropalladium(II).
  • the reaction can also be carried out using a ligand, if necessary.
  • Examples of the ligand include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, trans-1,2-cyclohexanediamine, trans-N,N'-dimethylcyclohexane-1,2-diamine, and N,N'-dimethylethylenediamine.
  • the ligand When a ligand is used in the reaction, the ligand is usually used in a ratio of 0.01 to 0.5 mol per 1 mol of compound (IO-1-Bpin).
  • compound (Ar-hal) is usually used in a ratio of 1 to 5 moles
  • metal catalyst is usually used in a ratio of 0.01 to 0.5 moles
  • base is usually used in a ratio of 1 to 5 moles, relative to 1 mole of compound (IO-1-Bpin).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 150° C.
  • the reaction time is usually in the range of 0.5 to 24 hours.
  • the compound (IO-1Ar) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer.
  • the compound represented by the formula (IO-2Ar) (hereinafter referred to as compound (IO-2Ar)) can be produced according to the following scheme. [In the formula, the symbols have the same meanings as defined above.]
  • Compound (I-O-2Ar) can be produced from compound (I-O-2-Bpin) produced according to Production Method 26, using compound (I-O-2pa) instead of compound (I-O-1pa), in a similar manner to Production Method 26.
  • the compound represented by formula (IO-1NBoc) (hereinafter referred to as compound (IO-1NBoc)) can be produced by reacting compound (IO-1pp) with tert-butyl carbamate in the presence of a metal catalyst and a base.
  • a metal catalyst such as a metal iridium, nickel, nickel, nickel, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium
  • metal catalyst used in the reaction examples include nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; and palladium catalysts such as palladium(II) acetate, tetrakis(triphenylphosphine)palladium(0), tris(dibenzylideneacetone)dipalladium(0), and [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II).
  • nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride
  • palladium catalysts such as palladium(II) acetate, tetrakis(triphenylphosphine)palladium(0), tris(dibenzylideneacetone)dipalladium(0), and [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II).
  • the reaction
  • Examples of the ligand include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, trans-1,2-cyclohexanediamine, trans-N,N'-dimethylcyclohexane-1,2-diamine, and N,N'-dimethylethylenediamine.
  • the ligand is usually used in a ratio of 0.01 to 0.5 mol per 1 mol of the compound (IO-1pp).
  • the metal catalyst is usually used in a ratio of 0.01 to 0.5 moles
  • the base is usually used in a ratio of 1 to 5 moles, relative to 1 mole of compound (IO-1pp).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 150° C.
  • the reaction time is usually in the range of 0.5 to 24 hours.
  • the compound (IO-1NBoc) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer.
  • the compound represented by the formula (I-O-2NBoc) (hereinafter referred to as compound (I-O-2NBoc)) can be produced by reacting compound (I-O-2pp) with tert-butyl carbamate in the presence of a metal catalyst and a base. [In the formula, the symbols have the same meanings as defined above.]
  • Compound (IO-2NBoc) can be produced according to Production Method 28, except for using compound (IO-2pp) instead of compound (IO-1pp).
  • the compound represented by the formula (IO-1NH 2 ) (hereinafter referred to as compound (IO-1NH 2 )) can be produced by reacting compound (IO-1NBoc) with an acid.
  • the reaction is usually carried out in a solvent, such as halogenated hydrocarbons, ethers, alcohols, water, or a mixture of two or more of these.
  • the acid used in the reaction includes, for example, mineral acids such as hydrochloric acid; and carboxylic acids such as trifluoroacetic acid.
  • the acid is usually used in a ratio of 1 to 50 moles per mole of compound (IO-1NBoc).
  • the reaction temperature is usually in the range of 0° C.
  • reaction time is usually in the range of 0.1 to 24 hours.
  • the reaction mixture is extracted with an organic solvent, and the organic layer is dried, concentrated, and other post-treatment procedures are carried out to obtain the compound (IO-1NH 2 ).
  • the compound represented by the formula (IO-2NH 2 ) (hereinafter referred to as compound (IO-2NH 2 )) can be produced by reacting compound (IO-2NBoc) with an acid. [In the formula, the symbols have the same meanings as defined above.]
  • the compound (IO-2NH 2 ) can be produced according to Production Method 30, using the compound (IO-2NBoc) instead of the compound (IO-1NBoc).
  • the compound represented by formula (IO-1-NHamide) (hereinafter referred to as compound (IO-1-NHamide)) can be produced by reacting compound (IO-1NH 2 ) with a compound represented by formula (R-13) (hereinafter referred to as compound (R-13)).
  • R Alkyl represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group D2 , or a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group D2 , and the other symbols have the same meanings as above.
  • the reaction is usually carried out in a solvent.
  • Examples of the solvent used in the reaction include ethers, aliphatic hydrocarbons such as hexane, heptane, and octane (hereinafter referred to as aliphatic hydrocarbons), aromatic hydrocarbons, halogenated hydrocarbons, esters, nitriles, aprotic polar solvents, nitrogen-containing aromatic compounds, and mixtures of two or more of these.
  • a base can be used in the reaction as necessary.
  • Examples of the base used in the reaction include alkali metal carbonates; alkali metal hydroxides such as sodium hydroxide and potassium hydroxide (hereinafter referred to as alkali metal hydroxides); and organic bases.
  • the base is usually used in a ratio of 1 to 2 moles per mole of compound (IO-1NH 2 ).
  • the compound (R-13) is usually used in a ratio of 0.8 to 2 moles per mole of the compound (IO-1NH 2 ).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 200° C.
  • the reaction time is usually in the range of 0.1 to 24 hours.
  • the compound (IO-1-NHamide) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
  • Compound (R-13) is a commercially available compound or can be prepared using known methods.
  • the compound represented by the formula (IO-2-NHamide) (hereinafter referred to as compound (IO-2-NHamide)) can be produced by reacting compound (IO-2NH 2 ) with compound (R-13). [In the formula, the symbols have the same meanings as defined above.] Compound (IO-2-NHamide) can be produced according to Production Method 32, except that compound (IO-2NH 2 ) is used instead of compound (IO-1NH 2 ).
  • the compound represented by formula (I-O-1-amide) (hereinafter referred to as compound (I-O-1-amide)) can be produced by reacting compound (I-O-1-NHamide) with compound (R-14) in the presence of a base.
  • L2 represents a leaving group such as a chlorine atom, a bromine atom, or an iodine atom
  • R amide represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, and the other symbols have the same meanings as above.
  • the reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more of these.
  • Examples of the base used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases.
  • compound (R-14) is usually used in a ratio of 1 to 5 moles and base is usually used in a ratio of 1 to 5 moles per mole of compound (IO-1-NHamide).
  • the reaction temperature is usually in the range of 0° C. to 100° C.
  • the reaction time is usually in the range of 0.1 to 24 hours.
  • the compound (IO-1-amide) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer.
  • Compound (R-14) is a commercially available compound or can be prepared using known methods.
  • the compound represented by the formula (I-O-2-amide) (hereinafter referred to as compound (I-O-2-amide)) can be produced by reacting compound (I-O-2-NHamide) with compound (R-14) in the presence of a base. [In the formula, the symbols have the same meanings as defined above.]
  • Compound (IO-2-amide) can be produced according to Production Method 34, using compound (IO-2-NHamide) instead of compound (IO-1-NHamide).
  • the compound represented by formula (IO-1-OH) (hereinafter referred to as compound (IO-1-OH)) can be produced by reacting compound (IO-1-OBn) with hydrogen in the presence of a catalyst.
  • a catalyst In the formula, the symbols have the same meanings as defined above.
  • Hydrogen gas is used in the reaction, and the pressure of the hydrogen gas is usually 1 to 100 atmospheres.
  • the reaction is usually carried out in a solvent, such as ethers, esters, alcohols, water, or a mixture of two or more of these.
  • the catalyst used in the reaction include transition metal compounds such as palladium on carbon, palladium (II) hydroxide, Raney nickel, and platinum oxide.
  • the catalyst is usually used in a ratio of 0.001 to 0.5 mol per 1 mol of the compound (IO-1-OBn).
  • the reaction can be carried out using an acid, a base, etc., if necessary.
  • the acid include acetic acid and hydrochloric acid
  • examples of the base include tertiary amines such as triethylamine.
  • the acid is usually used in a ratio of 0.001 to 0.5 moles per mole of compound (I-O-1-OBn).
  • a base is used in the reaction, the base is usually used in a ratio of 0.1 to 5 moles per mole of compound (I-O-1-OBn).
  • the reaction temperature is usually in the range of ⁇ 20° C.
  • reaction time is usually in the range of 0.1 to 24 hours.
  • the reaction mixture is filtered, and if necessary, extracted with an organic solvent, and the organic layer is dried, concentrated, and other post-treatment operations are carried out to obtain the compound (IO-1-OH).
  • the compound represented by the formula (I-O-2-OH) (hereinafter referred to as compound (I-O-2-OH)) can be produced by reacting compound (I-O-2-OBn) with hydrogen in the presence of a catalyst. [In the formula, the symbols have the same meanings as defined above.]
  • Compound (IO-2-OH) can be produced according to Production Method 36, except for using compound (IO-2-OBn) instead of compound (IO-1-OBn).
  • the compound represented by the formula (I-O-1-OAlkyl) (hereinafter referred to as compound (I-O-1-OAlkyl)) can be produced by reacting compound (I-O-1-OH) with a compound represented by the formula (R-15) (hereinafter referred to as compound (R-15)) in the presence of a base.
  • L3 represents a leaving group such as a chlorine atom, a bromine atom, an iodine atom, etc.
  • ROH represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group F2 , a C3-C7 cycloalkyl group which may be substituted with one or more substituents selected from group J2 , a C3-C7 cycloalkenyl group which may be substituted with one or more substituents selected from group J2 , a phenyl group which may be substituted with one or more substituents selected from group D2 , or a 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group D2 , and the other symbols have the same meanings as above.
  • the reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more of these
  • Examples of the base used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases.
  • compound (R-15) is usually used in a ratio of 1 to 5 moles and base is usually used in a ratio of 1 to 5 moles per mole of compound (IO-1-OH).
  • the reaction temperature is usually in the range of 0° C. to 100° C.
  • the reaction time is usually in the range of 0.1 to 24 hours.
  • the compound (IO-1-OAlkyl) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer.
  • Compound (R-15) is a commercially available compound or can be prepared using known methods.
  • the compound represented by the formula (I-O-2-OAlkyl) (hereinafter referred to as compound (I-O-2-OAlkyl)) can be produced by reacting compound (I-O-2-OH) with compound (R-15) in the presence of a base. [In the formula, the symbols have the same meanings as defined above.]
  • Compound (IO-2-OAlkyl) can be produced according to Production Method 38, except for using compound (IO-2-OH) instead of compound (IO-1-OH).
  • the compound represented by formula (M-2-d) (hereinafter referred to as compound (M-2-d)) can be produced according to the following scheme.
  • Xc represents a chlorine atom or a bromine atom
  • R52 represents a hydrogen atom, a methyl group, or an ethyl group
  • the other symbols have the same meanings as defined above.
  • the compound represented by formula (M-20) (hereinafter referred to as compound (M-20)) can be produced by reacting a compound represented by formula (M-19) (hereinafter referred to as compound (M-19)) with a compound represented by formula (R-6) (hereinafter referred to as compound (R-6)).
  • the reaction is usually carried out in a solvent, such as aromatic hydrocarbons, alcohols, nitriles, and mixtures of two or more of these.
  • compound (M-19) is usually used in a ratio of 1 to 10 moles per mole of compound (R-6).
  • the reaction temperature is usually in the range of 0° C. to 200° C.
  • the reaction time is usually in the range of 0.1 to 48 hours.
  • the compound (M-20) can be obtained by carrying out a usual post-treatment operation.
  • the compound (R-6) and the compound (M-19) are commercially available compounds or can be prepared using known methods.
  • the compound represented by formula (M-21) (hereinafter referred to as compound (M-21)) can be produced by reacting compound (M-20) with a compound represented by formula (R-7) (hereinafter referred to as compound (R-7)).
  • the reaction is usually carried out in a solvent, such as aromatic hydrocarbons, nitriles, and mixtures of two or more of these.
  • compound (R-7) is usually used in a ratio of 1 to 10 moles per mole of compound (M-20).
  • the reaction temperature is usually in the range of 60° C. to 120° C.
  • the reaction time is usually in the range of 0.1 to 48 hours.
  • the compound (M-21) can be obtained by carrying out a usual post-treatment operation.
  • Compound (R-7) is a commercially available compound or can be prepared using known methods.
  • the compound represented by formula (M-22) (hereinafter referred to as compound (M-22)) can be produced by reacting compound (M-21) with N-iodosuccinimide.
  • the reaction can be carried out in accordance with the method for producing compound (M-6) from compound (M-5) in Production Method 6.
  • Compound (M-2-d) can be produced by reacting compound (M-21) or compound (M-22) with compound (R-1). These reactions can be carried out in accordance with the method for producing compound (I-n0-1) from compound (M-5) or compound (M-6) in Production Method 6.
  • the compound represented by formula (M-2-f) can be produced by reacting a compound represented by formula (M-2-e) (hereinafter referred to as compound (M-2-e)) with silver fluoride in the presence of a metal catalyst.
  • a compound represented by formula (M-2-e) hereinafter referred to as compound (M-2-e)
  • the reaction can be carried out, for example, according to the method described in Journal of the American Chemical Society, 2014, 136, 3792.
  • the compound represented by the formula (M-2-g) can be produced by reacting the compound (M-2-e) with sodium iodide in the presence of a metal catalyst. [In the formula, the symbols have the same meanings as defined above.] The reaction can be carried out, for example, according to the method described in Journal of the American Chemical Society, 2002, 124, 14844.
  • Compound (M-9-X) can be produced by reacting a compound represented by formula (M-23) (hereinafter referred to as compound (M-23)) with a compound represented by formula (M-24) (hereinafter referred to as compound (M-24)) in the presence of a condensing agent.
  • a condensing agent such as ethers, halogenated hydrocarbons, aromatic hydrocarbons, esters, nitriles, aprotic polar solvents, nitrogen-containing aromatic compounds, and mixtures of two or more of these.
  • the condensing agent used in the reaction includes, for example, carbodiimide compounds such as 1-ethyl-3-[3-(dimethylamino)propyl]carbodiimide hydrochloride and 1,3-dicyclohexylcarbodiimide.
  • a catalyst can be used in the reaction, if necessary.
  • An example of the catalyst used in the reaction is 1-hydroxybenzotriazole.
  • the catalyst is usually used in a ratio of 0.01 to 0.5 moles per mole of compound (M-24).
  • a base can be used as necessary. Examples of the base include organic bases.
  • the base is usually used in a ratio of 1 to 2 moles per mole of compound (M-24).
  • compound (M-23) is usually used in a ratio of 1 to 2 moles and a condensing agent is usually used in a ratio of 1 to 2 moles per mole of compound (M-24).
  • the reaction temperature is usually in the range of 0° C. to 200° C.
  • the reaction time is usually in the range of 0.1 to 12 hours.
  • the compound (M-9-X) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer.
  • Compound (M-23) can be produced by hydrolyzing a compound represented by formula (M-25) (hereinafter referred to as compound (M-25)).
  • R A represents a C1-C3 alkyl group such as a methyl group or an ethyl group, and the other symbols have the same meanings as above.
  • the reaction is usually carried out in an aqueous solution of the acid as a solvent.
  • the acid used in the reaction include mineral acids such as hydrochloric acid, nitric acid, phosphoric acid, and sulfuric acid; and carboxylic acids such as acetic acid and trifluoroacetic acid.
  • the reaction temperature is usually in the range of 0° C. to 100° C.
  • the reaction time is usually in the range of 0.1 to 24 hours.
  • compound (M-23) can be obtained by carrying out post-treatment operations such as extraction with an organic solvent, drying and concentrating the organic layer.
  • the reaction is usually carried out in the presence of a solvent.
  • the solvent used in the reaction includes, for example, ethers, alcohols, water, and mixtures of two or more of these.
  • the base used in the reaction includes, for example, alkali metal hydroxides. In the reaction, 1 to 10 moles of the base are usually used per mole of compound (M-25).
  • the reaction temperature is usually in the range of 0° C. to 120° C.
  • the reaction time is usually in the range of 0.1 to 24 hours.
  • the reaction solution is acidified, and then the reaction mixture is extracted with an organic solvent. The organic layer is dried, concentrated, and other post-treatment procedures can be carried out to obtain compound (M-23).
  • Compound (M-25) can be produced by reacting a compound represented by formula (M-26) (hereinafter referred to as compound (M-26)) with a compound represented by formula (R-8) (hereinafter referred to as compound (R-8)) in the presence of a condensing agent.
  • a compound represented by formula (M-26) hereinafter referred to as compound (M-26)
  • R-8 compound represented by formula (R-8)
  • the reaction is usually carried out in a solvent, such as ethers, halogenated hydrocarbons, aromatic hydrocarbons, esters, nitriles, aprotic polar solvents, nitrogen-containing aromatic compounds, and mixtures of two or more of these.
  • the condensing agent used in the reaction may be, for example, a mixture of triphenylphosphine and an azodiester compound, etc.
  • the azodiester compound may be, for example, diethyl azodicarboxylate.
  • compound (R-8) is usually used in a ratio of 1 to 5 moles and a condensing agent is usually used in a ratio of 1 to 5 moles per mole of compound (M-26).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 200° C.
  • the reaction time is usually in the range of 0.1 to 24 hours.
  • compound (M-25) is a commercially available compound or can be prepared using known methods.
  • compound (R-8) is a commercially available compound or can be prepared using known methods.
  • the compound (M-24) can be produced by reacting the compound (M-2-h) with ammonia.
  • Xe represents a fluorine atom or a chlorine atom, and the other symbols have the same meanings as defined above.
  • the reaction is usually carried out in a solvent, such as ethers, nitriles, aprotic polar solvents, alcohols, water, and mixtures of two or more of these.
  • a base can be used as necessary. Examples of the base used in the reaction include organic bases and alkali metal carbonates. When a base is used in the reaction, the base is usually used in a ratio of 0.1 to 5 moles per mole of compound (M-2-h).
  • Ammonia can also be used as a solution, such as aqueous ammonia and ammonia in methanol.
  • ammonia is usually used in a ratio of 1 to 100 moles per mole of compound (M-2-h).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 100° C.
  • the reaction time is usually in the range of 0.1 to 48 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (M-24).
  • Compound (M-9-X) can also be produced by reacting a compound represented by formula (M-27) (hereinafter referred to as compound (M-27)) with compound (M-24). [In the formula, the symbols have the same meanings as defined above.]
  • the reaction is usually carried out in a solvent.
  • the solvent used in the reaction include ethers, aliphatic hydrocarbons, aromatic hydrocarbons, halogenated hydrocarbons, esters, nitriles, aprotic polar solvents, and mixtures of two or more of these.
  • a base can be used in the reaction as necessary. Examples of the base used in the reaction include alkali metal carbonates, alkali metal hydroxides, and organic bases.
  • the base When a base is used in the reaction, the base is usually used in a ratio of 1 to 2 moles per mole of compound (M-24).
  • compound (M-27) is usually used in an amount of 0.8 to 1.2 moles per mole of compound (M-24).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 200° C.
  • the reaction time is usually in the range of 0.1 to 24 hours.
  • the compound (M-9-X) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer.
  • the compound (M-27) can be produced by reacting the compound (M-23) in the presence of a chlorinating agent.
  • a chlorinating agent for example, ethers, aromatic hydrocarbons, halogenated hydrocarbons, and mixtures of two or more of these.
  • the chlorinating agent used in the reaction includes, for example, thionyl chloride, oxalyl dichloride, phosphorus oxychloride and the like.
  • the chlorinating agent is usually used in a ratio of 1 to 5 moles per mole of compound (M-23).
  • the reaction temperature is usually in the range of 0° C. to 100° C.
  • the reaction time is usually in the range of 0.1 to 24 hours. After the reaction is completed, the solvent can be distilled off to obtain compound (M-27).
  • Reference Manufacturing Method 11 Compound (M-9-OH) can be produced by reacting a compound represented by formula (M-9-P) (hereinafter referred to as compound (M-9-P)) with an acid.
  • XB represents ORB
  • RB represents a protecting group such as a tetrahydropyranyl group, a methoxymethyl group, a 2-methoxyethoxymethyl group, a tert-butyldimethylsilyl group, or a tribenzylsilyl group, and the other symbols have the same meanings as above.
  • the reaction is usually carried out in a solvent, such as ethers, alcohols, water, or a mixture of two or more of these.
  • Examples of the acid used in the reaction include mineral acids such as hydrochloric acid, nitric acid, phosphoric acid, and sulfuric acid; and carboxylic acids such as acetic acid and trifluoroacetic acid.
  • the reaction temperature is usually in the range of 0° C. to 120° C.
  • the reaction time is usually in the range of 0.1 to 24 hours.
  • the acid is usually used in a ratio of 1 to 10 moles per mole of compound (M-9-P).
  • the reaction mixture is extracted with an organic solvent, and the organic layer is dried, concentrated, and other post-treatment operations are carried out to obtain the compound (M-9-OH).
  • Compound (M-9-P) can be produced by reacting a compound represented by formula (M-28) (hereinafter referred to as compound (M-28)) with compound (M-24) in the presence of a condensing agent. [In the formula, the symbols have the same meanings as defined above.] Compound (M-9-P) can be produced according to Reference Production Method 5, except that compound (M-28) is used instead of compound (M-23).
  • Compound (M-28) can be produced by hydrolyzing a compound represented by formula (M-29) (hereinafter referred to as compound (M-29)) in the presence of a base.
  • a compound represented by formula (M-29) hereinafter referred to as compound (M-29)
  • the reaction is usually carried out in a solvent, such as ethers, alcohols, water, or a mixture of two or more of these.
  • the base used in the reaction includes, for example, alkali metal hydroxides. In the reaction, 1 to 10 moles of the base are usually used per mole of compound (M-29).
  • the reaction temperature is usually in the range of 0° C. to 120° C.
  • the reaction time is usually in the range of 0.1 to 24 hours.
  • the reaction solution is acidified, and the reaction mixture is extracted with an organic solvent. The organic layer is then dried, concentrated, and other post-treatment procedures can be carried out to obtain compound (M-28).
  • Compound (M-29) can be produced by reacting compound (M-26) with a compound represented by formula (R-9) (hereinafter referred to as compound (R-9)) in the presence of a condensing agent. [In the formula, the symbols have the same meanings as defined above.] Compound (M-29) can be produced according to Reference Production Method 7, except that compound (R-9) is used instead of compound (R-8). Compound (R-9) is a commercially available compound or can be prepared using known methods.
  • the compound (M-10-X) can be produced by reacting the compound (M-10-OH) in the presence of a halogenating agent.
  • a halogenating agent such as ethers, alcohols, aromatic hydrocarbons, halogenated hydrocarbons, aprotic polar solvents, water, and mixtures of two or more of these.
  • halogenating agent used in the reaction examples include hydrogen halides such as hydrogen chloride; phosphorus halides such as phosphorus tribromide; thionyl halides such as thionyl chloride; a mixture of triphenylphosphine and carbon tetrachloride; a mixture of triphenylphosphine and carbon tetrabromide, and the like.
  • the halogenating agent is usually used in a ratio of 1 to 10 moles per mole of the compound (M-10-OH).
  • a base can be used as necessary. Examples of the base used in the reaction include organic bases.
  • the base When a base is used in the reaction, the base is usually used in a ratio of 1 to 2 moles per mole of the compound (M-10-OH).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 150° C.
  • the reaction time is usually in the range of 0.1 to 24 hours.
  • the compound (M-10-X) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
  • Reference Manufacturing Method 16 Compound (M-10-OH) can be produced by reacting a compound represented by formula (M-10-P) (hereinafter, compound (M-10-P)) with an acid. [In the formula, the symbols have the same meanings as defined above.]
  • the compound (M-10-OH) can be produced according to Reference Production Method 11, using the compound (M-10-P) instead of the compound (M-9-P).
  • Compound (M-10-P) can be produced by reacting a compound represented by formula (M-30) (hereinafter referred to as compound (M-30)) with a compound represented by formula (M-33) (hereinafter referred to as compound (M-33)) in the presence of a condensing agent. [In the formula, the symbols have the same meanings as defined above.] Compound (M-10-P) can be produced in accordance with Reference Production Method 5, except for using compound (M-30) instead of compound (M-23) and compound (M-33) instead of compound (M-24). Compound (M-30) is a commercially available compound or can be prepared using known methods.
  • Compound (M-10-P) can also be produced by reacting a compound represented by formula (M-32) (hereinafter referred to as compound (M-32)) with compound (M-33). [In the formula, the symbols have the same meanings as defined above.] Compound (M-10-P) can be produced according to Reference Production Method 9, except for using compound (M-32) instead of compound (M-27) and compound (M-33) instead of compound (M-24). Compound (M-32) is a commercially available compound or can be prepared using known methods.
  • Compound (M-33) can be produced by reacting compound (M-24) with a compound represented by formula (R-12) (hereinafter referred to as compound (R-12)) in the presence of a base.
  • R-12 a compound represented by formula (R-12)
  • L represents a leaving group such as a chlorine atom or a bromine atom, and the other symbols have the same meanings as defined above.
  • the reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more of these.
  • the base used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases.
  • compound (R-12) is usually used in a ratio of 1 to 5 moles and base is usually used in a ratio of 1 to 2 moles per mole of compound (M-24).
  • the reaction temperature is usually in the range of 0° C. to 100° C.
  • the reaction time is usually in the range of 0.1 to 24 hours.
  • the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (M-33).
  • Compound (R-12) is a commercially available compound or can be prepared using known methods.
  • the compound (M-2-n0) can be produced according to the following scheme.
  • Xb represents SR2 or a hydrogen atom
  • Xf represents a chlorine atom, a bromine atom or an iodine atom
  • the other symbols have the same meanings as above.
  • a process for producing a compound represented by formula (M-4-f) (hereinafter referred to as compound (M-4-f)) from compound (M-4) will be described.
  • the compound (M-4-f) can be produced by reacting the compound (M-4) with a halogenating agent.
  • the reaction is usually carried out in a solvent, such as alcohols, nitriles, ethers, aromatic hydrocarbons, aprotic polar solvents, halogenated hydrocarbons, water, and mixtures of two or more of these.
  • a solvent such as alcohols, nitriles, ethers, aromatic hydrocarbons, aprotic polar solvents, halogenated hydrocarbons, water, and mixtures of two or more of these.
  • halogenating agents include chlorine, bromine, iodine, N-chlorosuccinimide, N-bromosuccinimide, and N-iodosuccinimide.
  • the halogenating agent is usually used in a ratio of 1 to 20 moles per mole of compound (M-4).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 200° C.
  • the reaction time is usually in the range of 0.1 to 72 hours.
  • the compound (M-4-f) can be obtained by carrying out post-treatment
  • the compound (M-2-n0) can be produced by reacting the compound (M-4-f) with the compound (R-1) in the presence of a metal catalyst and a base.
  • the reaction is usually carried out in a solvent, such as alcohols, nitriles, ethers, aromatic hydrocarbons, aprotic polar solvents, water, and mixtures of two or more of these.
  • Examples of the metal catalyst used in the reaction include palladium catalysts such as tetrakis(triphenylphosphine)palladium(0), [1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloride, tris(dibenzylideneacetone)dipalladium(0), palladium(II) acetate, etc.; nickel catalysts such as bis(cyclooctadiene)nickel(0), nickel(II) chloride, etc.; and copper catalysts such as copper(I) iodide, copper(I) chloride, etc.
  • Examples of the base used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases.
  • a ligand can also be used in the reaction.
  • the ligand include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, and 1,10-phenanthroline.
  • the ligand is usually used in a ratio of 0.01 to 1 mole per mole of compound (M-4-f).
  • compound (R-1) is usually used in a ratio of 1 to 20 moles
  • a metal catalyst is usually used in a ratio of 0.01 to 0.5 moles
  • a base is usually used in a ratio of 0.1 to 5 moles, relative to 1 mole of compound (M-4-f).
  • the reaction temperature is usually in the range of ⁇ 20° C. to 200° C.
  • the reaction time is usually in the range of 0.1 to 72 hours.
  • the compound (M-2-n0) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
  • Compound (M-2-n0) can also be produced by reacting compound (M-4) with a compound represented by formula (R-3) (hereinafter referred to as compound (R-3)) in the presence of a halogenating agent.
  • a halogenating agent such as bromine, iodine, sodium bromide, potassium bromide, sodium iodide, and potassium iodide.
  • An oxidizing agent can be used in the reaction as necessary.
  • the oxidizing agent used in the reaction include hydrogen peroxide, tert-butyl hydroperoxide, DMSO, etc.
  • the oxidizing agent is usually used in a ratio of 1 to 20 moles per mole of compound (M-4).
  • compound (R-3) is usually used in a ratio of 0.5 to 10 moles and the halogenating agent is usually used in a ratio of 0.05 to 10 moles per mole of compound (M-4).
  • the reaction temperature is usually in the range of 0° C. to 200° C.
  • the reaction time is usually in the range of 0.1 to 72 hours.
  • the compound (M-2-n0) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
  • the compound (R-3) is a known compound or can be produced according to a known method.
  • Compound (M-4) is known or can be produced according to the methods described in WO 2015/157093, WO 2016/109706, Organic & Biomolecular Chemistry, 2017, 15, 4199., and European Journal of Medicinal Chemistry, 2016, 123, 916.
  • a compound represented by formula (M-11-n1) (hereinafter referred to as compound (M-11-n1)) or a compound represented by formula (M-11-n2) (hereinafter referred to as compound (M-11-n2)) can be produced by reacting compound (M-11-n0) with an oxidizing agent.
  • Compound (M-11-n2) can also be produced by reacting compound (M-11-n1) with an oxidizing agent. [In the formula, the symbols have the same meanings as defined above.] These reactions can be carried out according to Production Method 1.
  • Compound (M-17-X) can be produced by reacting compound (M-23) with a compound represented by formula (M-34) (hereinafter referred to as compound (M-34)) in the presence of a condensing agent. [In the formula, the symbols have the same meanings as defined above.] Compound (M-17-X) can be produced according to Reference Production Method 5, except that compound (M-34) is used instead of compound (M-24).
  • Compound (M-17-X) can also be produced by reacting compound (M-27) with compound (M-34). [In the formula, the symbols have the same meanings as defined above.] Compound (M-17-X) can be produced according to Reference Production Method 9, except that compound (M-34) is used instead of compound (M-24).
  • Compound (M-34) can be produced by reacting a compound represented by formula (M-11-h) (hereinafter referred to as compound (M-11-h)) with ammonia. [In the formula, the symbols have the same meanings as defined above.] Compound (M-34) can be produced according to Reference Production Method 8, except that compound (M-11-h) is used instead of compound (M-2-h).
  • Reference Manufacturing Method 26 Compound (M-17-OH) can be produced by reacting a compound represented by formula (M-17-P) (hereinafter referred to as compound (M-17-P)) with an acid. [In the formula, the symbols have the same meanings as defined above.] Compound (M-17-OH) can be produced according to Reference Production Method 11, except that compound (M-17-P) is used instead of compound (M-9-P).
  • Compound (M-17-P) can be produced by reacting a compound represented by formula (M-28) (hereinafter referred to as compound (M-28)) with compound (M-34) in the presence of a condensing agent. [In the formula, the symbols have the same meanings as defined above.] Compound (M-17-P) can be produced according to Reference Production Method 12, except that compound (M-34) is used instead of compound (M-24).
  • Reference Manufacturing Method 28 Compound (M-18-OH) can be produced by reacting a compound represented by formula (M-18-P) (hereinafter referred to as compound (M-18-P)) with an acid. [In the formula, the symbols have the same meanings as defined above.]
  • the compound (M-18-OH) can be produced according to Reference Production Method 11, except that the compound (M-18-P) is used in place of the compound (M-9-P).
  • Compound (M-18-P) can be produced by reacting compound (M-30) with a compound represented by formula (M-35) (hereinafter referred to as compound (M-35)) in the presence of a condensing agent. [In the formula, the symbols have the same meanings as defined above.] Compound (M-18-P) can be produced in accordance with Reference Production Method 5, using compound (M-30) instead of compound (M-23) and compound (M-35) instead of compound (M-24).
  • Reference Manufacturing Method 30 Compound (M-18-P) can also be produced by reacting compound (M-32) with compound (M-35). [In the formula, the symbols have the same meanings as defined above.] Compound (M-18-P) can be produced according to Reference Production Method 9, except for using compound (M-32) instead of compound (M-27) and compound (M-35) instead of compound (M-24).
  • Compound (M-35) can be produced by reacting compound (M-34) with compound (R-12) in the presence of a base. [In the formula, the symbols have the same meanings as defined above.] Compound (M-35) can be produced according to Reference Production Method 19, except that compound (M-34) is used instead of compound (M-24).
  • the compound (M-18-X) can be produced by reacting the compound (M-18-OH) in the presence of a halogenating agent. [In the formula, the symbols have the same meanings as defined above.] Compound (M-18-X) can be produced according to Reference Production Method 15, except that compound (M-18-OH) is used instead of compound (M-10-OH).
  • Compound (M-2) can also be produced, for example, according to the method described in WO 2020/158889.
  • the compound (M-1) can also be produced according to the following scheme.
  • X represents a protecting group such as a tert-butoxycarbonyl group, and the other symbols have the same meanings as above.
  • a method for producing a compound represented by formula (M-29-N) (hereinafter referred to as compound (M-29-N)) from a compound represented by formula (M-29-N-PG) (hereinafter referred to as compound (M-29-N-PG)) will be described.
  • the compound (M-29-N) can be produced by reacting the compound (M-29-N-PG) with an acid.
  • the reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more of these.
  • a solvent such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more of these.
  • the acid used in the reaction include mineral acids such as hydrochloric acid, nitric acid, phosphoric acid, and sulfuric acid; and carboxylic acids such as acetic acid and trifluoroacetic acid.
  • the acid is usually used in a ratio of 1 to 30 moles per mole of the compound (M-29-N-PG).
  • the reaction temperature is usually in the range of 0° C. to 100° C.
  • the reaction time is usually in the range of 0.1 to 24 hours.
  • the reaction mixture can be subjected to post-treatment such as concentration to obtain the compound (M-29-N).
  • Compound (M-1) can be produced by reacting compound (M-29-N) with a base.
  • the reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, water, and mixtures of two or more of these.
  • the base used in the reaction includes, for example, alkali metal carbonates. In the reaction, 1 to 30 moles of the base are usually used per mole of the compound (M-29-N).
  • the reaction temperature is usually in the range of 0° C. to 100° C.
  • the reaction time is usually in the range of 0.1 to 24 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (M-1).
  • the compound of the present invention can be mixed or used in combination with one or more components selected from the group consisting of the following groups (a), (b), (c), and (d) (hereinafter referred to as the present components).
  • the above-mentioned mixed or concomitant use means that the compound of the present invention and the present ingredient are used simultaneously, separately or with an interval between them.
  • the compound of the present invention and this ingredient may be contained in separate preparations or may be contained in a single preparation.
  • composition A containing one or more components selected from the group consisting of Group (a), Group (b), Group (c), and Group (d) (i.e., the present component) and a compound of the present invention.
  • Group (a) includes acetylcholinesterase inhibitors (e.g., carbamate insecticides, organophosphate insecticides), GABAergic chloride channel blockers (e.g., phenylpyrazole insecticides), sodium channel modulators (e.g., pyrethroid insecticides), nicotinic acetylcholine receptor competitive modulators (e.g., neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamatergic chloride channel allosteric modulators (e.g., macrolide insecticides), juvenile hormone mimics, multisite inhibitors, chordotonal organ TRPV channel modulators, mite growth inhibitors, The group consists of microbial insect midgut membrane disruptors, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncouplers, nicotinic acetylcholine receptor channel blockers (e.g., ner
  • Group (b) consists of nucleic acid synthesis inhibitors (e.g., phenylamide fungicides, acylamino acid fungicides), cell division and cytoskeleton inhibitors (e.g., MBC fungicides), respiratory inhibitors (e.g., QoI fungicides, QiI fungicides), amino acid synthesis and protein synthesis inhibitors (e.g., anilinopyrimidine fungicides), signal transduction inhibitors, lipid synthesis and membrane synthesis inhibitors, sterol biosynthesis inhibitors (e.g., DMI fungicides such as triazoles), cell wall biosynthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multisite contact active fungicides, microbial fungicides, and other fungicidal active ingredients. These are described in the classification based on the mechanism of action of FRAC.
  • nucleic acid synthesis inhibitors e.g., phenylamide fungicides, acylamin
  • Group (c) is a group of plant growth regulators (including mycorrhizal fungi and rhizobia).
  • Group (d) is a group of repellent components.
  • alanycarb + SX means a combination of alanycarb and SX.
  • the abbreviation SX means any one of the compounds of the present invention selected from the compound group SX1 to SX1840.
  • the present components described below are all known components and can be obtained from commercially available preparations or produced by known methods. When the present components are microorganisms, they can also be obtained from a bacterial depository institution. The numbers in parentheses represent CAS RN (registered trademark).
  • strain AQ175 + SX Bacillus sp. strain AQ177 + SX, Bacillus sp. strain AQ178 + SX, Bacillus sphaericus strain 2362 serotype H5a5b + SX, Bacillus sphaericus strain ABTS1743 + SX, Bacillus thuringiensis strain AQ52 + SX, Bacillus thuringiensis strain BD#32 + SX, Bacillus thuringiensis strain CR-371 + SX, Bacillus thuringiensis subsp. Aizawai strain ABTS-1857 + SX, Bacillus thuringiensis subsp.
  • Kurstaki strain EG2348 + SX Bacillus thuringiensis subsp. Kurstaki strain EG7841 + SX, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19 + SX, Bacillus thuringiensis subsp. Kurstaki strain F810 + SX, Bacillus thuringiensis subsp. Kurstaki strain HD-1 + SX, Bacillus thuringiensis subsp. Kurstaki strain PB54 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-11 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-12 + SX, Bacillus thuringiensis subsp.
  • Amyloliquefaciens strain FZB24 + SX Bacillus subtilis strain Y1336 + SX, Burkholderia cepacia + SX, Burkholderia cepacia type Wisconsin strain J82 + SX, Burkholderia cepacia type Wisconsin strain M54 + SX, Candida oleophila strain O + SX, Candida saitoana + SX, Chaetomium cupreum + SX, Clonostachys rosea + SX, Coniothyrium minitans strain CGMCC8325 + SX, Coniothyrium minitans strain CON/M/91-8 + SX, cryptococcus albidus + SX, Erwinia carotovora subsp.
  • the ratio of the compound of the present invention to this component is not particularly limited, but examples of the ratio by weight (compound of the present invention: this component) include 1000:1 to 1:1000, 500:1 to 1:500, 100:1 to 1:100, 50:1, 20:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, and 1:50.
  • the compound of the present invention can control harmful arthropods such as harmful insects and harmful mites, harmful nematodes, and harmful mollusks.
  • harmful arthropods such as harmful insects and harmful mites, harmful nematodes, and harmful mollusks.
  • harmful arthropods, harmful nematodes, and harmful mollusks include the following:
  • Delphacidae such as the small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), white-backed planthopper (Sogatella furcifera), corn planthopper (Peregrinus maidis), yellow-eared planthopper (Javesella pellucida), black horned planthopper (Perkinsiella saccharicida), Tagosodes orizicolus, and Stenocranus pacificus.
  • Delphacidae such as the small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), white-backed planthopper (Sogatella furcifera), corn planthopper (Peregrinus maidis), yellow-eared planthopper (Javesella pellucida), black horned planthopper (Perkinsiella saccharicida), Tagosodes orizicolus, and Stenocranus pacificus.
  • Aphis pomi, snow willow aphid (Aphis spiraecola), green peach aphid (Myzus persicae), strawberry aphid (Brachycaudus helichrysi), radish aphid (Brevicoryne brassicae), rosy apple aphid (Dysaphis plantaginea), false radish aphid (Lipaphis erysimi), tulip long-horn aphid (Macrosiphum euphorbiae), oats Aulacorthum solani, lettuce aphid (Nasonovia ribisnigri), wheat curl aphid (Rhopalosiphum padi), corn aphid (Rhopalosiphum maidis), citrus black aphid (Toxoptera citricida), peach buttercup aphid (Hyalopterus pruni), barnyard millet aphid (Melana
  • the Miridae family such as the long-spined wheat grass bug (Stenodema calcarata) and the rusty whitefly (Lygus lineolaris);
  • Trialeurodes vaporariorum Bemisia tabaci, Dialeurodes citri, Aleurocanthus spiniferus, Aleurocanthus camelliae, and the Japanese whitefly (Aleurocanthus schidigera).
  • the family Aleyrodidae such as the whitefly (Pealius euryae); the family Coccinellidae, such as the palm scale insect (Abgrallaspis cyanophylli), the red scale insect (Aonidiella aurantii), the pear scale insect (Diaspidiotus perniciosus), the mulberry scale insect (Pseudaulacaspis pentagona), the Yanon scale insect (Unaspis yanonensis), and the false Yanon scale insect (Unaspis citri).
  • the family Coccinellidae such as the palm scale insect (Abgrallaspis cyanophylli), the red scale insect (Aonidiella aurantii), the pear scale insect (Diaspidiotus perniciosus), the mulberry scale insect (Pseudaulacaspis pentagona), the Yanon scale insect (Unaspis yanonensis), and the false
  • Psyllidae such as Cacopsylla pyrisuga, Chinese pear psylla chinensis, potato psylla Bactericera cockerelli, and Cacopsylla pyricola; Corythucha ciliata, Corythucha marmorata, Stephanitis nashi, and Stephanitis pyrioi des and other Tingidae; Cimicidae such as Cimex lectularius and Cimex hempterus; Cicadidae such as Quesada gigas; Reduviidae such as Triatoma infestans, Triatoma rubrofasciata, Triatoma dimidiata, and Rhodonius prolixus.
  • Lepidoptera Chilo suppressalis, Dark headed stem borer, Chilo polychrysus, White stem borer, Scirpophaga innotata, Scirpophaga incertulas, Rupela albina, Cnaphalocrocis medinalis, Marasmia patnalis, Marasmia exigua, Notarcha derogata, Ostrinia furnacalis, European corn borer, Hellula undalis, Herpetogramma luc Crambidae, such as the Japanese bush moth (Parapediasia teterrellus), the rice case worm (Nymphula depunctalis), the sugar cane borer (Diatraea saccharalis), and the eggplant fruit borer (Leucinodes orbonalis); Pyralidae, such as the corn moth (Elasmopalpus lignosellus), the Indian meal moth (Plodia interpunctella), the two-spotted moth (E
  • Heliothis virescens such as Heliothis virescens, Helicoverpa spp. such as Helicoverpa armigera, corn earworm (Helicoverpa zea), Noctuidae such as Velvet bean caterpillar (Anticarsia gemmatalis), cotton leafworm (Alabama argillacea), hop wine borer (Hydraecia immanis), Pieridae such as Pieris rapae, pear fruit moth (Grapholita molesta), plum fruit moth (Grapholita dimorpha), bean cicada (Coleoptera pedunculidae), Japanese quince (Pyral ...
  • Heliothis virescens such as Helicoverpa armigera, corn earworm (Helicoverpa zea), Noctuidae such as Velvet bean caterpillar (Anticarsia gemmatalis), cotton leafworm (Alabama argillacea), hop wine bore
  • Tortricidae such as the grass moth (Leguminivora glycinivorella), the bean pea moth (Matsumuraeses azukivora), the smaller apple tortrix moth (Adoxophyes orana fasciata), the smaller tea tortrix moth (Adoxophyes honmai), the tea tortrix moth (Homona magnima), the common tortrix moth (Archips fuscocupreanus), the codling moth (Cydia pomonella), the sugar candy moth (Tetramoera schistaceana), the bean shoot borer (Epinotia aporema), the citrus fruit borer (Citripestis sagittiferella), and the European grape wine moth (Lobesia botrana);
  • the Gracilariidae family includes the tea leaf moth (Caloptilia theivora) and the golden leaf moth (Phyllonorycter ringoniella); the Carposini
  • the family Plutellidae includes the long-legged moth (Plutella xylostella); the family Gelechiidae includes the peach leaf moth (Anarsia lineatella), the potato leaf moth (Helcystogramma triannulella), the red cotton moth (Pectinophora gossypiella), the potato tuber moth (Phthorimaea operculella), and the tomato leaf moth (Tuta absolutea); the family Arctiidae includes the fall webworm (Hyphantria cunea); the family Castniidae includes the giant sugarcane borer (Telchin licus); the family Cossidae includes the lesser cotton moth (Cossus insularis); the mugwort geometries (Ascotis selenaria) ), the Geometridae
  • Thysanoptera Thripidae, such as Frankliniella occidentalis, Thrips palmi, Scirtothrips dorsalis, Thrips tabaci, Frankliniella intonsa, Stenchaetothrips biformis, Echinothrips americanus, Scirtothrips perseae; Phlaeothripidae, such as Haplothrips aculeatus.
  • Diptera Anthomyiidae such as Delia platura, Delia antiqua, Pegomyia cunicularia, etc.; Ulidiidae such as Tetanops myopaeformis, etc.; Agromyza oryzae, Liriomyza sativae, Liriomyza trifolii, Chromatomyia horticola, etc.
  • Agromyzidae (Agromyzidae); Chloropidae (Chlorops oryzae), etc.; Bactrocera cucurbitae (Melon fly), Bactrocera dorsalis (Oriental fruit fly), Bactrocera latifrons (Eastern fruit fly), Bactrocera oleae (Olive fruit fly), Bactrocera tryoni (Queensland fruit fly), Ceratitis capitata (Mediterranean fruit fly), Rhagoletis pomonella (Apple maggot), Rhagoletis suzukii (Sugar apple fly), Tephritidae, such as Hacochlaena japonica; Ephydridae, such as Hydrellia griseola, Hydrellia philippina, and Hydrellia sasakii; Drosophilidae, such as Drosophila suzukii and Drosophila melanogaster; Megaselia spiracularis
  • Diabrotica spp. e.g. Western corn rootworm (Diabrotica virgifera virgifera), Southern corn rootworm (Diabrotica undecimpunctata howardi), Northern corn rootworm (Diabrotica barberi), Mexican corn rootworm (Diabrotica virgifera zeae), Banded cucumber beetle (Diabrotica balteata), Cucumber beetle (Diabrotica speciosa), etc.), Bean leaf beetle (Cerotoma trifurcata), Spotted neck leaf beetle (Oulema melanopus), Cucumber leaf beetle (Aulacophora femoralis), Striped flea beetle (Phyllotreta striolat a), cabbage free beetle (Phyllotreta cruciferae), western black free beetle (Phyllotreta pusilla), cabbage stem free beetle (Psylliodes chrys
  • fungus weevils such as Araecerus coffeee Family Anthriibidae; Family Aponidae such as sweet potato weevil (Cylas formicarius); Family Bruchidae such as Brazilian bean weevil (Zabrotes subfasciatus); Family Scolytidae such as pine bark beetle (Tomicus piniperda) and coffee berry borer (Hypothenemus hampei); Bug (Euscepes postfasciatus), Alfalfa weevil (Hypera postica), Maize weevil (Sitophilus zeamais), Rice weevil (Sitophilus oryzae), Granary maize weevil (Sitophilus granarius), Rice weevil (Echinocnemus squameus), Rice water weevil (Lissorhoptrus oryzophilus), White grain weevil (Rhabdoscelus lineatic
  • Aracanthus spp. such as the rust gourd weevil (Scepticus griseus), the brown gourd weevil (Scepticus uniformis), and Aracanthus mourei, and the cotton root borer (Eutinobothrus brasiliensis); Tenebrionidae such as the red flour beetle (Tribolium castaneum), the flat-headed red flour beetle (Tribolium confusum), and the mealworm beetle (Alphitobius diaperinus); Coccinellidae such as the 20-spotted ladybird beetle (Epilachna vigintioctopunctata); Lyctus brunneus, Rhizope rtha dominica; Ptinidae; Cerambycidae; Anoplophora malasiaca, Migdolus fryanus, Aromia bungii; Melanotus okinawensis, Brown-necked wire beet
  • the Dermestidae family including Anthrenus verbasci, Dermestes maculates, and Trogoderma granarium
  • the tobacco beetle Lasioderma serricorne
  • the Japanese cigar beetle Stepgobium paniceum and other Anobiidae
  • Brassicogethes aeneus and other Blossom Beetles Brassicogethes aeneus and other Blossom Beetles.
  • Hymenoptera Tenthredinidae such as Athalia rosae and Athalia japonica; Solenopsis spp. such as Solenopsis invicta and Solenopsis geminata; Atta spp.
  • Atta capiguara and Acro ant myrmex spp.
  • Paraponera clavata Ochetellus glaber
  • Monomorium pharaonis Argentine ant (Linepithema humile)
  • Formica japonica Pristomyrmex punctutus
  • Pheidole noda Pheidole megacephala
  • Camponotus spp. such as the Japanese camponotus (Camponotus japonicus), Camponotus spp., such as the red-breasted camponotus (Camponotus obscuripes)
  • Pogonomyrmex spp. such as Pogonomyrmex occidentalis
  • Wasmania spp. such as Wasmania auropunctata
  • Anoplolepis gracilipa such as Atta capiguara and Acro ant; myrmex spp.), Paraponera clavata, Ochetellus glaber, Monomor
  • Vespidae such as the giant hornet (Vespa mandarinia), the hairy hornet (Vespa simillima), the small hornet (Vespa analis), the red hornet (Vespa velutina), and the Japanese paper wasp (Polistes jokahamae); Siricidae (Wasps) such as the fir wasp (Urocerus gigas); and Bethylidae (Hornets).
  • Vespidae such as the giant hornet (Vespa mandarinia), the hairy hornet (Vespa simillima), the small hornet (Vespa analis), the red hornet (Vespa velutina), and the Japanese paper wasp (Polistes jokahamae); Siricidae (Wasps) such as the fir wasp (Urocerus gigas); and Bethylidae (Hornets).
  • Family Ectobiidae such as the German cockroach (Blattella germanica); Family Blattidae, such as the Siberian cockroach (Periplaneta fuliginosa), the American cockroach (Periplaneta americana), the American cockroach (Periplaneta australiae), the brown cockroach (Periplaneta brunnea), and the Asian cockroach (Blatta orientalis); Family Reticulitermes speratus, Formosan termite (Coptotermes formosanus), Formosan dry wood termite (Incisitermes minor), Formosan termite (Cryptotermes domesticus), Formosan termite (Odontotermes formosanus), and Formosan termite (Neotermes Termites of the family Termitidae, such as Glyptotermes satsumensis, Glyptotermes nakajimai, Glyptotermes fuscus,
  • Order Siphonaptera Family Pulicidae such as the human flea (Pulex irritans), cat flea (Ctenocephalides felis), dog flea (Ctenocephalides canis), rat flea (Xenopsylla cheopis), chicken flea (Echidnophaga gallinacea), etc.; Family Hectopsyllidae such as the sand flea (Tunga penetrans); Family Ceratophyllidae such as the European rat flea (Nosopsyllus fasciatus).
  • Family Pulicidae such as the human flea (Pulex irritans), cat flea (Ctenocephalides felis), dog flea (Ctenocephalides canis), rat flea (Xenopsylla cheopis), chicken flea (Echidnophaga gallinacea), etc.
  • Family Hectopsyllidae such as the sand flea (Tunga penetrans)
  • Psocodae Family Pediculidae such as head lice (Pediculus humanus capitis); Family Pthiridae such as pubic lice (Pthirus pubis); Family Haematopinidae such as cow lice (Haematopinus eurysternus) and pig lice (Haematopinus suis); Family Linognathus vituli, Sheep trunk lice Family Linognathidae, such as body lice (Linognathus ovillus) and cow lice (Solenopotes capillatus); Family Bovicoliidae, such as cow lice (Bovicola bovis), sheep lice (Bovicola ovis), Bovicola breviceps, Damalinia forficula, and Werneckiella spp.; Family Bovicoliidae, such as dog lice (T Family Trichodectidae, such as the cat louse (Felicola subrostratus) and the chicken louse
  • Menoponidae such as the chicken louse (Menopon gallinae), the chicken louse (Menacanthus stramineus), and the Trinoton spp. family Trinoton spp. family Cummingsia spp. family noponidae); Trogiidae, such as Trogium pulsatorium; Liposcelidae or Liposcelididae, such as Liposcelis corrodens, Liposcelis bostrychophila, Liposcelis pearmani, and Liposcelis entomophila.
  • Thysanura Family Lepismatidae, including the Japanese silverfish (Ctenolepisma villosa) and the European silverfish (Lepisma saccharina).
  • Eriophyidae such as Acarus carinatus, Acaphylla theavagrans, Eriophyes chibaensis, Aculus Louendali, Aceria diospyri, Aceria tosichella, Shevtchenkella sp.; Tarsonemidae, such as Polyphagotarsonemus latus; Deutzia purpurea, such as Brevipalpus phoenicis.
  • Order Araneae Family Eutichuridae such as Cheiracanthium japonicum; Family Theridiidae such as Latrodectus hasseltii.
  • Polydesmida Paradoxosomatidae, including Oxidus gracilis, Nedyopus tambanus, etc.
  • Isopoda Family Armadillidiidae, including Armadillidium vulgare.
  • Chilopoda Scutigeridae such as Thereuonema hilgendorfi; Scolopendridae such as Scolopendra subspinipes; Ethopolyidae such as Bothropolys rugosus.
  • Class Gastropoda Family Limacidae such as the brown slug (Limax marginatus) and the yellow slug (Limax flavus); Family Philomycidae such as the slug (Meghimatium bilineatum); Family Ampullariidae such as the apple snail (Pomacea canaliculata); Family Lymnaeidae such as the lymnae snail (Austropeplea ollula).
  • Nematoda Aphelenchoididae, such as Aphelenchoides besseyi; Pratylenchidae, such as Pratylenchus coffeee, Pratylenchus brachyurus, Pratylenchus neglectus, and Radopholus similis ); Java root-knot nematode (Meloidogyne javanica), sweet potato root-knot nematode (Meloidogyne incognita), guava root-knot nematodes (Meloidogyne enterolobii), northern root-knot nematode (Meloidogyne hapla), soybean cyst nematode (Heterodera glycines), potato cyst nematode (Globodera rostochien sis), Globodera pallida, Meloidogyne chitwoodi, and other members of the Heteroderidae family; Rotyle
  • the harmful insects, harmful arthropods such as harmful mites, harmful mollusks, and harmful nematodes may be harmful insects, harmful arthropods such as harmful mites, harmful mollusks, and harmful nematodes that have reduced sensitivity to insecticides, acaricides, molluscicides, or nematocides, or that have developed resistance to the insecticides, acaricides, molluscicides, or nematocides.
  • the method for controlling harmful arthropods of the present invention is carried out by applying an effective amount of the compound of the present invention or composition A directly to the harmful arthropods and/or to the habitat of the harmful arthropods (plants, soil, inside a house, animals, etc.).
  • Examples of the method for controlling harmful arthropods of the present invention include foliage treatment, soil treatment, root treatment, shower treatment, fumigation treatment, water surface treatment and seed treatment.
  • the compound of the present invention or composition A is usually mixed with an inert carrier such as a solid carrier, a liquid carrier, or a gaseous carrier and a surfactant, and formulation auxiliary agents such as a binder, a dispersant, or a stabilizer are added as necessary to prepare an aqueous suspension preparation, an oil suspension preparation, an oil solution, an emulsion, an emulsion preparation, a microemulsion preparation, a microcapsule preparation, a wettable powder, a wettable granule, a dust, a granule, a tablet, an aerosol, a resin preparation, etc.
  • an inert carrier such as a solid carrier, a liquid carrier, or a gaseous carrier and a surfactant
  • formulation auxiliary agents such as a binder, a dispersant, or a stabilizer are added as necessary to prepare an aqueous suspension preparation, an oil suspension preparation, an oil solution, an emulsion, an emulsion preparation,
  • Solid carriers include, for example, clay (pyrophyllite clay, kaolin clay, etc.), talc, calcium carbonate, diatomaceous earth, zeolite, bentonite, acid clay, attapulgite, white carbon, ammonium sulfate, vermiculite, perlite, pumice, silica sand, fine powders and granules of chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.), and resins (polyethylene, polypropylene, polyester, polyurethane, polyamide, polyvinyl chloride, etc.).
  • clay pyrophyllite clay, kaolin clay, etc.
  • talc calcium carbonate
  • diatomaceous earth zeolite
  • bentonite acid clay
  • attapulgite white carbon
  • ammonium sulfate vermiculite
  • perlite perlite
  • pumice pumice
  • Liquid carriers include, for example, water, alcohols (ethanol, cyclohexanol, benzyl alcohol, propylene glycol, polyethylene glycol, etc.), ketones (acetone, cyclohexanone, etc.), aromatic hydrocarbons (xylene, phenylxylylethane, methylnaphthalene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, etc.), esters (ethyl acetate, methyl oleate, propylene carbonate, etc.), nitriles (acetonitrile, etc.), ethers (ethylene glycol dimethyl ether, etc.), amides (N,N-dimethylformamide, N,N-dimethyloctaneamide, etc.), sulfoxides (dimethyl sulfoxide, etc.), lactams (N-methylpyrrolidone, N-octylpyrrolidone, etc.),
  • Gaseous carriers include, for example, fluorocarbons, butane gas, LPG (liquefied petroleum gas), dimethyl ether, nitrogen, and carbon dioxide.
  • Surfactants include, for example, nonionic surfactants (polyoxyethylene alkyl ethers, polyoxyethylene alkylaryl ethers, polyethylene glycol fatty acid esters, etc.) and anionic surfactants (alkyl sulfonates, alkylaryl sulfonates, alkyl sulfates, etc.).
  • formulation adjuvants include binders, dispersants, colorants, and stabilizers, and specific examples include polysaccharides (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acids, etc.), acid isopropyl phosphate, and dibutylhydroxytoluene.
  • adjuvants can be used as components that enhance or support the efficacy of the compounds of the present invention.
  • Specific examples include Nimbus (registered trademark), Assist (registered trademark), Aureo (registered trademark), Iharol (registered trademark), Silwet L-77 (registered trademark), BreakThru (registered trademark), SundanceII (registered trademark), Induce (registered trademark), Penetrator (registered trademark), AgriDex (registered trademark), Lutensol A8 (registered trademark), NP-7 (registered trademark), Triton (registered trademark), Nufilm (registered trademark), Emulgator NP7 (registered trademark), Emulad (registered trademark), TRITON X 45 (registered trademark), AGRAL 90 (registered trademark), AGROTIN (registered trademark), ARPON (registered trademark), EnSpray N (registered trademark), and BANOLE (registered trademark).
  • plants include whole plants, stems and leaves, flowers, spikes, fruits, trunks, branches, crowns, seeds, vegetative reproductive organs, and seedlings.
  • Vegetative reproductive organs are roots, stems, leaves, etc. of plants that have the ability to grow when separated from the main body and placed in soil.
  • vegetative reproductive organs include tuberous roots, creeping roots, bulbs, corms (or solid bulbs), tubers, rhizomes, stolons, rhizophores, cane cuttings, propagules, and vine cuttings. Stolons are sometimes called runners, and bulbils are also called bulbils and are divided into broad buds and bulbils. Vines refer to shoots (a collective term for leaves and stems) of sweet potatoes, Chinese yams, etc. Bulbs, corms, tubers, rhizomes, stem fragments, rhizopes, and tubers are collectively called bulbils. Potato cultivation begins by planting tubers in the soil, and the tubers used are generally called seed potatoes.
  • An example of a method for controlling harmful arthropods by applying an effective amount of the compound of the present invention or composition A to soil is a method of applying an effective amount of the compound of the present invention or composition A to the soil before or after planting a plant. More specifically, for example, planting hole treatment (spraying in planting holes, mixing soil for planting hole treatment), plant base treatment (spraying at the plant base, mixing soil at the plant base, irrigation at the plant base, plant base treatment in the latter half of the seedling raising period), planting furrow treatment (spraying in planting furrow, mixing soil in planting furrow), crop row treatment (spraying in crop row, mixing soil in crop row, crop row spray during the growing season), crop row treatment at the time of sowing (crop row spray at the time of sowing, mixing soil in crop row at the time of sowing), overall treatment (overall soil spray, overall soil mixing), side row treatment, water surface treatment (water surface application, water surface application after flooding), other soil spray treatments (foliar spraying of granules during the growing season, spraying under
  • irrigation treatments include (soil irrigation, seedling irrigation, chemical injection treatment, ground level irrigation, chemical drip irrigation, chemigation), seedling box treatments (seedling box spraying, seedling box irrigation, seedling box flooding with chemicals), seedling tray treatments (seedling tray spraying, seedling tray irrigation, seedling tray flooding with chemicals), seedbed treatments (seedling bed spraying, seedling bed irrigation, water seedling bed spraying, seedling immersion), bed soil mixing treatments (bed soil mixing, bed soil mixing before sowing, spraying before soil cover at sowing, spraying after soil cover at sowing, soil cover mixing), and other treatments (mixing culture soil, plowing in, mixing topsoil, mixing soil from areas that have fallen under rain, planting position treatment, spraying granular inflorescences, mixing paste fertilizer).
  • Examples of seed treatment include treatment of seeds or vegetative reproductive organs with the compound of the present invention or composition A. More specifically, examples of the treatment include spraying treatment in which a suspension of the compound of the present invention or composition A is misted and sprayed onto the surface of a seed or vegetative reproductive organ, smearing treatment in which the compound of the present invention or composition A is applied to the seed or vegetative reproductive organ, immersion treatment in which the seed or vegetative reproductive organ is immersed in a liquid of the compound of the present invention or composition A for a certain period of time, and a method of coating the seed or vegetative reproductive organ with a carrier containing the compound of the present invention or composition A (film coating treatment, pellet coating treatment, etc.).
  • the above-mentioned vegetative reproductive organ particularly includes seed potatoes.
  • composition A When applying composition A to seeds or vegetative reproductive organs, composition A can be applied to the seeds or vegetative reproductive organs as one formulation, or composition A can be applied to the seeds or vegetative reproductive organs in multiple separate applications as multiple different formulations.
  • Examples of the method of applying composition A in multiple separate applications as multiple different formulations include a method of applying a formulation containing only the compound of the present invention as an active ingredient, air-drying the seeds or vegetative reproductive organs, and then applying a formulation containing this component; and a method of applying a formulation containing the compound of the present invention and this component as active ingredients, air-drying the seeds or vegetative reproductive organs, and then applying a formulation containing this component other than the component that has already been applied.
  • the seed or vegetative reproductive organ carrying the compound of the present invention or composition A means a seed or vegetative reproductive organ having the compound of the present invention or composition A attached to the surface thereof.
  • the seed or vegetative reproductive organ carrying the compound of the present invention or composition A may have a material other than the compound of the present invention or composition A attached thereto before or after the compound of the present invention or composition A is attached to the seed or vegetative reproductive organ.
  • the layer may consist of one or more layers.
  • each layer may contain one or more active ingredients, or each layer may consist of a layer containing one or more active ingredients and a layer containing no active ingredients. Seeds or vegetative reproductive organs carrying the compound of the present invention or composition A can be obtained, for example, by applying a formulation containing the compound of the present invention or composition A to the seeds or vegetative reproductive organs by the seed treatment methods described above.
  • the application amount is usually 1 to 10,000 g of the compound of the present invention per 10,000 m2 .
  • the compound of the present invention is usually applied in an amount of 0.001 to 100 g per 1 kg of seeds or vegetative reproductive organs.
  • the compound of the present invention or composition A is formulated as an emulsifiable concentrate, wettable powder, flowable agent, or the like, it is usually applied after diluting with water so that the active ingredient concentration is 0.01 to 10,000 ppm, and granules, dusts, and the like are usually applied as they are.
  • the compound or composition A of the present invention can also be applied by wrapping the resin preparation in a sheet or string shape around the crop, stretching it near the crop, or spreading it on the soil around the base of the plant.
  • the application amount is usually 0.01 to 1000 mg of the compound of the present invention per 1 m2 of treatment area when applied on a surface, and usually 0.01 to 500 mg of the compound of the present invention per 1 m3 of treatment space when applied in a space.
  • the compound of the present invention or composition A is formulated as an emulsifiable concentrate, wettable powder, flowable agent, etc., it is usually applied after diluting with water so that the active ingredient concentration is 0.1 to 10000 ppm, and when it is an oil agent, aerosol agent, fumigation agent, poison bait, etc., it is applied as it is.
  • the compound of the present invention or composition A When the compound of the present invention or composition A is used for controlling external parasites in livestock such as cows, horses, pigs, sheep, goats, and chickens, and small animals such as dogs, cats, rats, and mice, it can be administered to animals by methods known in veterinary medicine. Specific methods of use include, for example, administration by tablet, inclusion in feed, suppository, and injection (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.) for systemic inhibition, and for non-systemic inhibition, for example, spraying an oil or aqueous liquid, pour-on treatment, spot-on treatment, washing the animal with a shampoo preparation, or attaching a resin preparation to the animal as a collar or ear tag.
  • the amount of the compound of the present invention or composition A when administered to an animal is usually in the range of 0.1 to 1000 mg per 1 kg of the animal's body weight.
  • the compound of the present invention or composition A can be used as an agent for controlling harmful arthropods in agricultural land such as fields, paddy fields, lawns, orchards, etc.
  • agricultural land such as fields, paddy fields, lawns, orchards, etc.
  • plants include the following.
  • the above plants are not particularly limited as long as they are varieties that are commonly cultivated.
  • the above plants also include plants that can be produced by natural crossbreeding, plants that can be generated by mutation, F1 hybrid plants, and genetically modified crops.
  • genetically modified crops include plants that have been given resistance to herbicides such as HPPD (4-hydroxyphenylpyruvate dioxygenase enzyme) inhibitors such as isoxaflutole, ALS (acetolactate synthase) inhibitors such as imazethapyr and thifensulfuron methyl, EPSP (5-enolpyruvylshikimate-3-phosphate synthase) inhibitors, glutamine synthetase inhibitors, PPO (protoporphyrinogen oxidase) inhibitors, bromoxynil, or dicamba; plants that are able to synthesize selective toxins known from the Bacillus genus, such as Bacillus thuringiensis; and plants that can be given specific insecticid
  • Me represents a methyl group
  • Et represents an ethyl group
  • Pr represents a propyl group
  • i-Pr represents an isopropyl group
  • Bu represents a butyl group
  • t-Bu represents a tert-butyl group
  • Hex represents a hexyl group
  • c-Pr represents a cyclopropyl group
  • c-Bu represents a cyclobutyl group
  • Ph represents a phenyl group
  • Boc represents a tert-butoxycarbonyl group
  • Bn represents a benzyl group
  • Py2 represents a 2-pyridyl group
  • Py3 represents a 3-pyridyl group
  • Py4 represents a 4-pyridyl group.
  • 1-CN-c-Pr represents a 1-cyanocyclopropyl group
  • 3,4-F 2 -Ph represents a 3,4-difluorophenyl group
  • 4-CF 3 -Py2 represents a 4-(trifluoromethyl)-2-pyridyl group.
  • LCMS liquid chromatography/mass spectrometry
  • Reference Manufacturing Example 12 The compound prepared according to Reference Preparation Example 11 using 3-bromo-2-chloro-5-(difluoromethoxy)pyridine instead of Intermediate 10 and its physical properties are shown below.
  • Intermediate 12 1H -NMR ( CDCl3 ) ⁇ : 8.04-8.03 (1H, m), 7.85-7.83 (1H, m), 6.53 (1H, t).
  • Reference Production Example 14 The compound and its physical properties are shown below, which were produced according to Reference Production Example 13, except that Intermediate 4 was used instead of Intermediate 6, and Intermediate 12 was used instead of 3-bromo-6-chloro-2-fluoropyridine.
  • Intermediate 14 1H -NMR ( CDCl3 ) ⁇ : 8.38 (1H, d), 7.87 (1H, d), 7.24 (1H, s), 6.60 (1H, t), 4.68-4.65 (2H, m), 4.52-4.45 (1H, m), 4.07-4.01 (1H, m).
  • Production Example 1-1 The compounds produced according to Production Example 1 and their physical properties are shown below.
  • Formula (B-1) In the compound represented by the formula (I), the combination of n, R 3b , R 3c and R 6b is any of the combinations described in [Table B-1].
  • Production Example 3-1 The compounds produced according to Production Example 3 or Production Example 4 and their physical properties are shown below.
  • Invention compound 25 1H -NMR ( CDCl3 ) ⁇ : 9.45 (1H, d), 9.04-9.03 (2H, m), 8.16 (1H, dd), 8.00 (1H, dd), 6.84 (1H, t), 6.57 (1H, s), 4.68-4.61 (1H, m), 4.51-4.42 (2H, m), 4.09-4.04 (1H, m), 3.46-3.40 (2H, m), 1.38 (3H, t).
  • Production Example 6 A mixture of 2.1 g of the present invention compound 34 and 1 mL of chloroform was brought to 0° C., 7.4 mL of trifluoroacetic acid was added, and the mixture was stirred for 2 hours after being brought to room temperature. The mixture was concentrated under reduced pressure, and water was added to the residue obtained, followed by extraction with chloroform. The organic layer obtained was dried over sodium sulfate and concentrated under reduced pressure. The residue obtained was subjected to silica gel column chromatography to obtain 1.2 g of the present invention compound 36.
  • Production Example 6-1 The compound prepared according to Preparation Example 6 using the compound 35 of the present invention instead of the compound 34 of the present invention and its physical properties are shown below.
  • Production Example 7 A mixture of 0.50 g of the present invention compound 36, 0.03 g of 4-(dimethylamino)pyridine, and 2.5 mL of pyridine was cooled to 0° C., 0.11 mL of acetyl chloride was added, and the mixture was stirred for 1.5 hours after being cooled to room temperature. The mixture was concentrated under reduced pressure, and a saturated aqueous solution of sodium bicarbonate was added to the residue, followed by extraction with chloroform. The organic layer was washed with water, dried over sodium sulfate, and concentrated under reduced pressure. The residue was subjected to silica gel column chromatography to obtain 0.47 g of the present invention compound 38.
  • Production Example 7-1 A compound prepared according to Preparation Example 7 using cyclopropanecarbonyl chloride instead of acetyl chloride and its physical properties are shown below.
  • Compound 39 of the present invention 1H -NMR ( CDCl3 ) ⁇ : 8.97 (1H, d), 8.66 (1H, d), 7.73 (1H, s), 7.18 (1H, s), 4.81-4.73 (1H, m), 4.62-4.57 (1H, m), 4.43-4.36 (1H, m), 4.06-4.01 (1H, m), 3.40-3.25 (2H, m), 1.55-1.53 (1H, m), 1.33 (3H, t), 1.20-1.16 (2H, m), 1.02-0.96 (2H, m).
  • Production Example 7-2 The compound prepared according to Preparation Example 7 using the present invention compound 37 instead of the present invention compound 36 and its physical properties are shown below.
  • Compound 40 of the present invention 1H -NMR ( CDCl3 ) ⁇ : 8.99 (1H, d), 8.59 (1H, d), 7.53 (1H, s), 6.82 (1H, t), 6.53 (1H, s), 4.64-4.56 (1H, m), 4.42-4.33 (2H, m), 4.01-3.96 (1H, m), 3.41-3.25 (2H, m), 2.28 (3H, s), 1.32 (3H, t).
  • Production Example 10-1 A compound produced according to Production Example 10 using Intermediate 13 instead of Intermediate 14 and its physical properties are shown below.
  • Compound 53 of the present invention 1H -NMR ( CDCl3 ) ⁇ : 8.15 (1H, d), 7.46 (1H, d), 6.99-6.40 (3H, m), 4.53-4.38 (3H, m), 3.96-3.92 (1H, m), 3.00-2.90 (2H, m), 1.35 (3H, t).
  • Production Example 11-1 The compounds prepared according to Preparation Example 11 and their physical properties are shown below.
  • Compound 57 of the present invention 1 H-NMR (CDCl 3 ) ⁇ : 8.67 (1H, d), 8.19 (1H, d), 7.02-6.54 (3H, m), 4.64-4.57 (1H, m), 4.45-4.35 (2H, m), 4.02-3.96 (1H, m), 3.42-3.28 (2H, m), 1.34-1.30 (3H, m).
  • Formula (L-1) (hereinafter, referred to as compound (L-1)), in which n is 0, R 4b is a hydrogen atom, R 4c is a hydrogen atom, and R 6b is any one of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX1).
  • compound (L-1) compounds in which n is 1, R 4b is a hydrogen atom, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX2).
  • compound (L-1) compounds in which n is 0, R 4b is a bromine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX7).
  • compound (L-1) compounds in which n is 1, R 4b is a bromine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX8).
  • compound group SX9 Compounds in which n is 2, R 4b is a bromine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in Tables 1A to 3A in compound (L-1) (hereinafter, referred to as compound group SX9).
  • compound (L-1) n is 0, R 4b is a trifluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX10).
  • compound (L-1) a compound in which n is 1, R 4b is a trifluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX11).
  • compound (L-1) a compound in which n is 2, R 4b is a trifluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX12).
  • compound (L-1) n is 0, R 4b is a difluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX13).
  • compound (L-1) a compound in which n is 1, R 4b is a difluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX14).
  • compound (L-1) a compound in which n is 2, R 4b is a difluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX15).
  • compound (L-1) n is 0, R 4b is a trifluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX16).
  • compound (L-1) a compound in which n is 1, R 4b is a trifluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX17).
  • compound (L-1) n is 2, R 4b is a trifluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX18).
  • compound (L-1) n is 0, R 4b is a difluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX19).
  • compound (L-1) a compound in which n is 1, R 4b is a difluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX20).
  • compound (L-1) a compound in which n is 1, R 4b is a cyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX23).
  • compound (L-1) compounds in which n is 2, R 4b is a cyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX24).
  • compound (L-1) a compound in which n is 0, R 4b is a 1-cyanocyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX25).
  • compound (L-1) compounds in which n is 1, R 4b is a 1-cyanocyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX26).
  • compound (L-1) a compound in which n is 2, R 4b is a 1-cyanocyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX27).
  • compound group SX27 Compounds in which n is 0, R 4b is a hydrogen atom, R 4c is a chlorine atom, and R 6b is any of the substituents shown in Tables 1A to 3A in compound (L-1) (hereinafter, referred to as compound group SX28).
  • compound (L-1) n is 0, R 4b is a hydrogen atom, R 4c is a bromine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX31).
  • compound (L-1) compounds in which n is 1, R 4b is a hydrogen atom, R 4c is a bromine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX32).
  • compound (L-1) compounds in which n is 2, R 4b is a hydrogen atom, R 4c is a bromine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX33).
  • compound (L-1) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX34).
  • compound (L-1) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX35).
  • compound group SX35 a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a trifluoromethyl group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] in compound (L-1) (hereinafter, referred to as compound group SX36).
  • compound (L-1) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX37).
  • compound (L-1) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX38).
  • compound (L-1) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX39).
  • compound (L-1) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX40).
  • compound (L-1) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX41).
  • compound (L-1) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX42).
  • compound (L-1) n is 0, R 4b is a hydrogen atom, R 4c is a difluoromethoxy group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX43).
  • compound (L-1) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX44).
  • compound (L-1) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX45).
  • compound (L-1) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX46).
  • compound (L-1) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a cyclopropyl group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX47).
  • compound (L-1) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a cyclopropyl group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX48).
  • compound (L-1) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX49).
  • compound (L-1) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX50).
  • compound (L-1) n is 2, R 4b is a hydrogen atom, R 4c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX51).
  • Formula (L-2) (hereinafter, referred to as compound (L-2)), in which n is 0, R 4b is a hydrogen atom, R 4c is a hydrogen atom, and R 6b is any one of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX52).
  • compound (L-2) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX53).
  • compound (L-2) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX54).
  • compound (L-2) a compound in which n is 0, R 4b is a chlorine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX55).
  • compound (L-2) a compound in which n is 1, R 4b is a chlorine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX56).
  • compound group SX56 Compounds in which n is 2, R 4b is a chlorine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] in compound (L-2) (hereinafter, referred to as compound group SX57).
  • compound (L-2) a compound in which n is 0, R 4b is a bromine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX58).
  • compound (L-2) a compound in which n is 1, R 4b is a bromine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX59).
  • compound (L-2) a compound in which n is 1, R 4b is a trifluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX62).
  • compound group SX62 Compounds in which n is 2, R 4b is a trifluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] in compound (L-2) (hereinafter, referred to as compound group SX63).
  • compound (L-2) a compound in which n is 0, R 4b is a difluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX64).
  • compound (L-2) a compound in which n is 1, R 4b is a difluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX65).
  • compound (L-2) a compound in which n is 1, R 4b is a trifluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX68).
  • compound group SX68 a compound in which n is 2, R 4b is a trifluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] in compound (L-2) (hereinafter, referred to as compound group SX69).
  • compound (L-2) a compound in which n is 0, R 4b is a difluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX70).
  • compound (L-2) a compound in which n is 1, R 4b is a difluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX71).
  • compound (L-2) a compound in which n is 2, R 4b is a difluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX72).
  • compound (L-2) a compound in which n is 0, R 4b is a cyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX73).
  • compound (L-2) a compound in which n is 1, R 4b is a cyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX74).
  • compound (L-2) a compound in which n is 2, R 4b is a cyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX75).
  • compound (L-2) a compound in which n is 0, R 4b is a 1-cyanocyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX76).
  • compound (L-2) a compound in which n is 1, R 4b is a 1-cyanocyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX77).
  • compound (L-2) a compound in which n is 2, R 4b is a 1-cyanocyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX78).
  • compound group SX78 Compounds in which n is 0, R 4b is a hydrogen atom, R 4c is a chlorine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] in compound (L-2) (hereinafter, referred to as compound group SX79).
  • compound (L-2) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a chlorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX80).
  • compound group SX80 Compounds in which n is 2, R 4b is a hydrogen atom, R 4c is a chlorine atom, and R 6b is any of the substituents shown in Tables 1A to 3A in compound (L-2) (hereinafter, referred to as compound group SX81).
  • compound (L-2) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a bromine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX82).
  • compound (L-2) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a bromine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX83).
  • compound (L-2) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX86).
  • compound group SX86 Compounds in which n is 2, R 4b is a hydrogen atom, R 4c is a trifluoromethyl group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] in compound (L-2) (hereinafter, referred to as compound group SX87).
  • compound (L-2) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX88).
  • compound (L-2) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX89).
  • compound (L-2) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX90).
  • compound (L-2) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX91).
  • compound (L-2) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX92).
  • compound (L-2) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX93).
  • compound (L-2) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX94).
  • compound (L-2) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX95).
  • compound (L-2) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX96).
  • compound (L-2) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX97).
  • compound (L-2) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX98).
  • compound (L-2) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX99).
  • compound (L-2) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX100).
  • compound (L-2) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX101).
  • compound (L-2) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX102).
  • Formula (L-3) (hereinafter, referred to as compound (L-3)), in which n is 0, R 4b is a hydrogen atom, R 4c is a hydrogen atom, and R 6b is any one of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX103).
  • compound (L-3) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX104).
  • compound (L-3) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX105).
  • compound (L-3) a compound in which n is 0, R 4b is a chlorine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX106).
  • compound (L-3) a compound in which n is 1, R 4b is a chlorine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX107).
  • compound group SX107 a compound in which n is 2, R 4b is a chlorine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] in the compound (L-3) (hereinafter, referred to as compound group SX108).
  • compound (L-3) a compound in which n is 0, R 4b is a bromine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX109).
  • compound (L-3) a compound in which n is 1, R 4b is a bromine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX110).
  • compound (L-3) a compound in which n is 2, R 4b is a bromine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX111).
  • compound (L-3) n is 0, R 4b is a trifluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX112).
  • compound (L-3) a compound in which n is 1, R 4b is a trifluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX113).
  • compound (L-3) n is 2, R 4b is a trifluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX114).
  • compound (L-3) n is 0, R 4b is a difluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX115).
  • compound (L-3) a compound in which n is 1, R 4b is a difluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX116).
  • compound (L-3) a compound in which n is 2, R 4b is a difluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX117).
  • compound (L-3) n is 0, R 4b is a trifluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX118).
  • compound (L-3) a compound in which n is 1, R 4b is a trifluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX119).
  • compound (L-3) a compound in which n is 2, R 4b is a trifluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX120).
  • compound (L-3) n is 0, R 4b is a difluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX121).
  • compound (L-3) a compound in which n is 1, R 4b is a difluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX122).
  • compound (L-3) a compound in which n is 2, R 4b is a difluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX123).
  • compound (L-3) n is 0, R 4b is a cyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX124).
  • compound (L-3) a compound in which n is 1, R 4b is a cyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX125).
  • compound (L-3) n is 2, R 4b is a cyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX126).
  • compound (L-3) a compound in which n is 0, R 4b is a 1-cyanocyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX127).
  • compound (L-3) a compound in which n is 1, R 4b is a 1-cyanocyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX128).
  • compound (L-3) a compound in which n is 2, R 4b is a 1-cyanocyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX129).
  • compound group SX129 Compounds in which n is 0, R 4b is a hydrogen atom, R 4c is a chlorine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] in the compound (L-3) (hereinafter, referred to as compound group SX130).
  • compound (L-3) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a chlorine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX131).
  • compound group SX131 a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a chlorine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] in the compound (L-3) (hereinafter, referred to as compound group SX132).
  • compound (L-3) n is 0, R 4b is a hydrogen atom, R 4c is a bromine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX133).
  • compound (L-3) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a bromine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX134).
  • compound (L-3) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a bromine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX135).
  • compound (L-3) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX136).
  • compound (L-3) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX137).
  • compound (L-3) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX138).
  • compound (L-3) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX139).
  • compound (L-3) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX140).
  • compound (L-3) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX141).
  • compound (L-3) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX142).
  • compound (L-3) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX143).
  • compound (L-3) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX144).
  • compound (L-3) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX145).
  • compound (L-3) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX146).
  • compound (L-3) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX147).
  • compound (L-3) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a cyclopropyl group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX148).
  • compound (L-3) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a cyclopropyl group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX149).
  • compound (L-3) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX150).
  • compound (L-3) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX151).
  • compound (L-3) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX152).
  • n 2
  • R 4b is a hydrogen atom
  • R 4c is a 1-cyanocyclopropyl group
  • R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX153).
  • Formula (L-4) (hereinafter, referred to as compound (L-4)), in which n is 0, R 4b is a hydrogen atom, R 4c is a hydrogen atom, and R 6b is any one of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX154).
  • compound (L-4) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX155).
  • compound (L-4) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX156).
  • compound (L-4) a compound in which n is 0, R 4b is a chlorine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX157).
  • compound (L-4) a compound in which n is 1, R 4b is a chlorine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX158).
  • compound (L-4) a compound in which n is 2, R 4b is a chlorine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX159).
  • compound (L-4) a compound in which n is 0, R 4b is a bromine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX160).
  • compound (L-4) a compound in which n is 1, R 4b is a bromine atom, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX161).
  • compound (L-4) a compound in which n is 1, R 4b is a trifluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX164).
  • compound (L-4) a compound in which n is 2, R 4b is a trifluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX165).
  • compound (L-4) a compound in which n is 0, R 4b is a difluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX166).
  • compound (L-4) a compound in which n is 1, R 4b is a difluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX167).
  • compound (L-4) a compound in which n is 2, R 4b is a difluoromethyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX168).
  • compound (L-4) n is 0, R 4b is a trifluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX169).
  • compound (L-4) a compound in which n is 1, R 4b is a trifluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX170).
  • compound (L-4) n is 2, R 4b is a trifluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX171).
  • compound (L-4) a compound in which n is 0, R 4b is a difluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX172).
  • compound (L-4) a compound in which n is 1, R 4b is a difluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX173).
  • compound (L-4) a compound in which n is 2, R 4b is a difluoromethoxy group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX174).
  • compound (L-4) a compound in which n is 0, R 4b is a cyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX175).
  • compound (L-4) a compound in which n is 1, R 4b is a cyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX176).
  • compound (L-4) a compound in which n is 2, R 4b is a cyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX177).
  • compound (L-4) a compound in which n is 0, R 4b is a 1-cyanocyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX178).
  • compound (L-4) a compound in which n is 1, R 4b is a 1-cyanocyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX179).
  • compound (L-4) a compound in which n is 2, R 4b is a 1-cyanocyclopropyl group, R 4c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX180).
  • compound (L-4) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a chlorine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX181).
  • compound (L-4) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a chlorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX182).
  • compound group SX182 Compounds in which n is 2, R 4b is a hydrogen atom, R 4c is a chlorine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] in the compound (L-4) (hereinafter, referred to as compound group SX183).
  • compound (L-4) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a bromine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX184).
  • compound (L-4) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a bromine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX185).
  • compound (L-4) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a bromine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX186).
  • compound (L-4) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX187).
  • compound (L-4) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX188).
  • compound (L-4) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX189).
  • compound (L-4) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX190).
  • compound (L-4) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX191).
  • compound (L-4) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX192).
  • compound (L-4) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX193).
  • compound (L-4) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX194).
  • compound (L-4) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX195).
  • compound (L-4) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX196).
  • compound (L-4) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX197).
  • compound (L-4) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX198).
  • compound (L-4) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX199).
  • compound (L-4) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX200).
  • compound (L-4) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a cyclopropyl group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX201).
  • compound (L-4) a compound in which n is 0, R 4b is a hydrogen atom, R 4c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX202).
  • compound (L-4) a compound in which n is 1, R 4b is a hydrogen atom, R 4c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX203).
  • compound (L-4) a compound in which n is 2, R 4b is a hydrogen atom, R 4c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX204).
  • Formula (L-5) (hereinafter, referred to as compound (L-5)), in which n is 0, R 3b is a hydrogen atom, R 3c is a hydrogen atom, and R 6b is any one of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX205).
  • compound (L-5) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX206).
  • compound (L-5) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX207).
  • compound (L-5) a compound in which n is 0, R 3b is a fluorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX208).
  • compound (L-5) a compound in which n is 1, R 3b is a fluorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX209).
  • compound group SX209 Compounds in which n is 2, R 3b is a fluorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] in compound (L-5) (hereinafter, referred to as compound group SX210).
  • compound (L-5) a compound in which n is 0, R 3b is a chlorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX211).
  • compound (L-5) a compound in which n is 1, R 3b is a chlorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX212).
  • compound (L-5) a compound in which n is 1, R 3b is a bromine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX215).
  • compound (L-5) a compound in which n is 2, R 3b is a bromine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX216).
  • compound (L-5) a compound in which n is 0, R 3b is an iodine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX217).
  • compound (L-5) a compound in which n is 1, R 3b is an iodine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX218).
  • compound (L-5) a compound in which n is 2, R 3b is an iodine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX219).
  • compound (L-5) a compound in which n is 0, R 3b is a trifluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX220).
  • compound (L-5) a compound in which n is 1, R 3b is a trifluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX221).
  • compound (L-5) a compound in which n is 2, R 3b is a trifluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX222).
  • compound (L-5) a compound in which n is 0, R 3b is a difluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX223).
  • compound (L-5) a compound in which n is 1, R 3b is a difluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX224).
  • compound (L-5) a compound in which n is 2, R 3b is a difluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX225).
  • compound (L-5) a compound in which n is 0, R 3b is a trifluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX226).
  • compound (L-5) a compound in which n is 1, R 3b is a trifluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX227).
  • compound (L-5) a compound in which n is 2, R 3b is a trifluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX228).
  • compound (L-5) a compound in which n is 0, R 3b is a difluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX229).
  • compound (L-5) a compound in which n is 1, R 3b is a difluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX230).
  • compound (L-5) a compound in which n is 2, R 3b is a difluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX231).
  • compound (L-5) a compound in which n is 0, R 3b is a cyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX232).
  • compound (L-5) a compound in which n is 1, R 3b is a cyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX233).
  • compound (L-5) a compound in which n is 2, R 3b is a cyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX234).
  • compound (L-5) a compound in which n is 0, R 3b is a 1-cyanocyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX235).
  • compound (L-5) a compound in which n is 1, R 3b is a 1-cyanocyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX236).
  • compound (L-5) a compound in which n is 2, R 3b is a 1-cyanocyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX237).
  • compound (L-5) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a fluorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX238).
  • compound (L-5) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a fluorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX239).
  • compound (L-5) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a fluorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX240).
  • compound (L-5) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a chlorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX241).
  • compound (L-5) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a chlorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX242).
  • compound (L-5) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a bromine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX245).
  • compound (L-5) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a bromine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX246).
  • compound (L-5) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is an iodine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX247).
  • compound (L-5) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is an iodine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX248).
  • compound (L-5) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is an iodine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX249).
  • compound (L-5) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX250).
  • compound (L-5) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX251).
  • compound (L-5) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX252).
  • compound (L-5) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX253).
  • compound (L-5) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX254).
  • compound (L-5) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX255).
  • compound (L-5) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX256).
  • compound (L-5) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX257).
  • compound (L-5) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX258).
  • compound (L-5) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX259).
  • compound (L-5) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX260).
  • compound (L-5) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX261).
  • compound (L-5) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a cyclopropyl group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX262).
  • compound (L-5) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX263).
  • compound (L-5) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX264).
  • compound (L-5) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX265).
  • compound (L-5) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX266).
  • compound (L-5) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX267).
  • Formula (L-6) (hereinafter, referred to as compound (L-6)), in which n is 0, R 3b is a hydrogen atom, R 3c is a hydrogen atom, and R 6b is any one of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX268).
  • compound (L-6) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX269).
  • compound (L-6) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX270).
  • compound (L-6) a compound in which n is 0, R 3b is a fluorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX271).
  • compound (L-6) a compound in which n is 1, R 3b is a fluorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX272).
  • compound (L-6) a compound in which n is 2, R 3b is a fluorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX273).
  • compound (L-6) a compound in which n is 0, R 3b is a chlorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX274).
  • compound (L-6) a compound in which n is 1, R 3b is a chlorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX275).
  • compound (L-6) a compound in which n is 1, R 3b is a bromine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX278).
  • compound (L-6) a compound in which n is 2, R 3b is a bromine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX279).
  • compound (L-6) a compound in which n is 0, R 3b is an iodine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX280).
  • compound (L-6) a compound in which n is 1, R 3b is an iodine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX281).
  • compound (L-6) a compound in which n is 2, R 3b is an iodine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX282).
  • compound (L-6) a compound in which n is 0, R 3b is a trifluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX283).
  • compound (L-6) a compound in which n is 1, R 3b is a trifluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX284).
  • compound (L-6) a compound in which n is 2, R 3b is a trifluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX285).
  • compound (L-6) a compound in which n is 0, R 3b is a difluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX286).
  • compound (L-6) a compound in which n is 1, R 3b is a difluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX287).
  • compound (L-6) a compound in which n is 2, R 3b is a difluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX288).
  • compound (L-6) a compound in which n is 0, R 3b is a trifluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX289).
  • compound (L-6) a compound in which n is 1, R 3b is a trifluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX290).
  • compound (L-6) a compound in which n is 2, R 3b is a trifluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX291).
  • compound (L-6) a compound in which n is 0, R 3b is a difluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX292).
  • compound (L-6) a compound in which n is 1, R 3b is a difluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX293).
  • compound (L-6) a compound in which n is 2, R 3b is a difluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX294).
  • compound (L-6) a compound in which n is 0, R 3b is a cyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX295).
  • compound (L-6) a compound in which n is 1, R 3b is a cyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX296).
  • compound (L-6) a compound in which n is 2, R 3b is a cyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX297).
  • compound (L-6) a compound in which n is 0, R 3b is a 1-cyanocyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX298).
  • compound (L-6) a compound in which n is 1, R 3b is a 1-cyanocyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX299).
  • compound (L-6) n is 2, R 3b is a 1-cyanocyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX300).
  • compound (L-6) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a fluorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX301).
  • compound (L-6) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a fluorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX302).
  • compound (L-6) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a fluorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX303).
  • compound (L-6) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a chlorine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX304).
  • compound (L-6) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a chlorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX305).
  • compound group SX306 Compounds in which n is 2, R 3b is a hydrogen atom, R 3c is a chlorine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] in the compound (L-6) (hereinafter, referred to as compound group SX306).
  • compound (L-6) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a bromine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX307).
  • compound (L-6) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a bromine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX308).
  • compound (L-6) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a bromine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX309).
  • compound (L-6) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is an iodine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX310).
  • compound (L-6) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is an iodine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX311).
  • compound (L-6) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is an iodine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX312).
  • compound (L-6) n is 0, R 3b is a hydrogen atom, R 3c is a trifluoromethyl group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX313).
  • compound (L-6) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX314).
  • compound (L-6) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX315).
  • compound (L-6) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX316).
  • compound (L-6) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX317).
  • compound (L-6) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX318).
  • compound (L-6) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX319).
  • compound (L-6) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX320).
  • compound (L-6) n is 2, R 3b is a hydrogen atom, R 3c is a trifluoromethoxy group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX321).
  • compound (L-6) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX322).
  • compound (L-6) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX323).
  • compound (L-6) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX324).
  • compound (L-6) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX325).
  • compound (L-6) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a cyclopropyl group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX326).
  • compound (L-6) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a cyclopropyl group, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX327).
  • compound (L-6) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX328).
  • compound (L-6) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX329).
  • n 2
  • R 3b is a hydrogen atom
  • R 3c is a 1-cyanocyclopropyl group
  • R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX330).
  • Formula (L-7) (hereinafter, referred to as compound (L-7)), in which n is 0, R 3b is a hydrogen atom, R 3c is a hydrogen atom, and R 6b is any one of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX331).
  • compound (L-7) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX332).
  • compound (L-7) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX333).
  • compound (L-7) a compound in which n is 0, R 3b is a fluorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX334).
  • compound (L-7) a compound in which n is 1, R 3b is a fluorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX335).
  • compound group SX336 a compound in which n is 2, R 3b is a fluorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX336).
  • compound (L-7) a compound in which n is 0, R 3b is a chlorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX337).
  • compound (L-7) a compound in which n is 1, R 3b is a chlorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX338).
  • compound (L-7) a compound in which n is 0, R 3b is a bromine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX340).
  • compound (L-7) a compound in which n is 1, R 3b is a bromine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX341).
  • compound (L-7) a compound in which n is 2, R 3b is a bromine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX342).
  • compound (L-7) a compound in which n is 0, R 3b is an iodine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX343).
  • compound (L-7) a compound in which n is 1, R 3b is an iodine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX344).
  • compound (L-7) a compound in which n is 2, R 3b is an iodine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX345).
  • compound (L-7) a compound in which n is 0, R 3b is a trifluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX346).
  • compound (L-7) a compound in which n is 1, R 3b is a trifluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX347).
  • compound (L-7) a compound in which n is 2, R 3b is a trifluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX348).
  • compound (L-7) a compound in which n is 0, R 3b is a difluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX349).
  • compound (L-7) a compound in which n is 1, R 3b is a difluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX350).
  • compound (L-7) a compound in which n is 2, R 3b is a difluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX351).
  • compound (L-7) a compound in which n is 0, R 3b is a trifluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX352).
  • compound (L-7) a compound in which n is 1, R 3b is a trifluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX353).
  • compound (L-7) a compound in which n is 2, R 3b is a trifluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX354).
  • compound (L-7) a compound in which n is 0, R 3b is a difluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX355).
  • compound (L-7) a compound in which n is 1, R 3b is a difluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX356).
  • compound (L-7) a compound in which n is 2, R 3b is a difluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX357).
  • compound (L-7) a compound in which n is 0, R 3b is a cyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX358).
  • compound (L-7) a compound in which n is 1, R 3b is a cyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX359).
  • compound (L-7) a compound in which n is 2, R 3b is a cyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX360).
  • compound (L-7) a compound in which n is 0, R 3b is a 1-cyanocyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX361).
  • compound (L-7) a compound in which n is 1, R 3b is a 1-cyanocyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX362).
  • compound (L-7) a compound in which n is 2, R 3b is a 1-cyanocyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX363).
  • compound (L-7) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a fluorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX364).
  • compound (L-7) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a fluorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX365).
  • compound group SX365 a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a fluorine atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] in the compound (L-7) (hereinafter, referred to as compound group SX366).
  • compound (L-7) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a chlorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX367).
  • compound (L-7) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a chlorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX368).
  • compound (L-7) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a bromine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX371).
  • compound (L-7) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a bromine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX372).
  • compound (L-7) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is an iodine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX373).
  • compound (L-7) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is an iodine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX374).
  • compound (L-7) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is an iodine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX375).
  • compound (L-7) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX376).
  • compound (L-7) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX377).
  • compound (L-7) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX378).
  • compound (L-7) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX379).
  • compound (L-7) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX380).
  • compound (L-7) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX381).
  • compound (L-7) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX382).
  • compound (L-7) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX383).
  • compound (L-7) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX384).
  • compound (L-7) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX385).
  • compound (L-7) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX386).
  • compound (L-7) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX387).
  • compound (L-7) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX388).
  • compound (L-7) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX389).
  • compound (L-7) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX390).
  • compound (L-7) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX391).
  • compound (L-7) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX392).
  • compound (L-7) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX393).
  • Formula (L-8) (hereinafter, referred to as compound (L-8)), in which n is 0, R 3b is a hydrogen atom, R 3c is a hydrogen atom, and R 6b is any one of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX394).
  • compound (L-8) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX395).
  • compound (L-8) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX396).
  • compound (L-8) a compound in which n is 0, R 3b is a fluorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX397).
  • compound (L-8) a compound in which n is 1, R 3b is a fluorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX398).
  • compound (L-8) a compound in which n is 2, R 3b is a fluorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX399).
  • compound (L-8) a compound in which n is 0, R 3b is a chlorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX400).
  • compound (L-8) a compound in which n is 1, R 3b is a chlorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX401).
  • compound (L-8) a compound in which n is 2, R 3b is a chlorine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX402).
  • compound (L-8) a compound in which n is 0, R 3b is a bromine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX403).
  • compound (L-8) a compound in which n is 1, R 3b is a bromine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX404).
  • compound (L-8) a compound in which n is 2, R 3b is a bromine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX405).
  • compound (L-8) a compound in which n is 0, R 3b is an iodine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX406).
  • compound (L-8) a compound in which n is 1, R 3b is an iodine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX407).
  • compound (L-8) a compound in which n is 2, R 3b is an iodine atom, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX408).
  • compound (L-8) a compound in which n is 0, R 3b is a trifluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX409).
  • compound (L-8) a compound in which n is 1, R 3b is a trifluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX410).
  • compound (L-8) a compound in which n is 2, R 3b is a trifluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX411).
  • compound (L-8) a compound in which n is 0, R 3b is a difluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX412).
  • compound (L-8) a compound in which n is 1, R 3b is a difluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX413).
  • compound (L-8) a compound in which n is 2, R 3b is a difluoromethyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX414).
  • compound (L-8) a compound in which n is 0, R 3b is a trifluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX415).
  • compound (L-8) a compound in which n is 1, R 3b is a trifluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX416).
  • compound (L-8) a compound in which n is 2, R 3b is a trifluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX417).
  • compound (L-8) a compound in which n is 0, R 3b is a difluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX418).
  • compound (L-8) a compound in which n is 1, R 3b is a difluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX419).
  • compound (L-8) a compound in which n is 2, R 3b is a difluoromethoxy group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX420).
  • compound (L-8) a compound in which n is 0, R 3b is a cyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents shown in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX421).
  • compound (L-8) a compound in which n is 1, R 3b is a cyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX422).
  • compound (L-8) a compound in which n is 2, R 3b is a cyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX423).
  • compound (L-8) a compound in which n is 0, R 3b is a 1-cyanocyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX424).
  • compound (L-8) a compound in which n is 1, R 3b is a 1-cyanocyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX425).
  • compound (L-8) a compound in which n is 2, R 3b is a 1-cyanocyclopropyl group, R 3c is a hydrogen atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX426).
  • compound (L-8) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a fluorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX427).
  • compound (L-8) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a fluorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX428).
  • compound (L-8) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a fluorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX429).
  • compound (L-8) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a chlorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX430).
  • compound (L-8) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a chlorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX431).
  • compound (L-8) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a chlorine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX432).
  • compound (L-8) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a bromine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX433).
  • compound (L-8) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a bromine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX434).
  • compound (L-8) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a bromine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX435).
  • compound (L-8) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is an iodine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX436).
  • compound (L-8) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is an iodine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX437).
  • compound (L-8) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is an iodine atom, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX438).
  • compound (L-8) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX439).
  • compound (L-8) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX440).
  • compound (L-8) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a trifluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX441).
  • compound (L-8) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX442).
  • compound (L-8) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX443).
  • compound (L-8) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a difluoromethyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX444).
  • compound (L-8) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX445).
  • compound (L-8) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX446).
  • compound (L-8) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a trifluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX447).
  • compound (L-8) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX448).
  • compound (L-8) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX449).
  • compound (L-8) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a difluoromethoxy group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX450).
  • compound (L-8) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX451).
  • compound (L-8) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX452).
  • compound (L-8) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a cyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX453).
  • compound (L-8) a compound in which n is 0, R 3b is a hydrogen atom, R 3c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX454).
  • compound (L-8) a compound in which n is 1, R 3b is a hydrogen atom, R 3c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX455).
  • compound (L-8) a compound in which n is 2, R 3b is a hydrogen atom, R 3c is a 1-cyanocyclopropyl group, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX456).
  • Formula (L-9) (hereinafter, referred to as compound (L-9)), in which n is 0, Q is a group represented by Q1-1, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX457).
  • compound (L-9) n is 1, Q is a group represented by Q1-1, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX458).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-1, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX459). In compound (L-9), n is 0, Q is a group represented by Q1-2, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX460). In compound (L-9), n is 1, Q is a group represented by Q1-2, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX461).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-2, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX462). In compound (L-9), n is 0, Q is a group represented by Q1-3, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX463). In compound (L-9), n is 1, Q is a group represented by Q1-3, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX464).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-3, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX465). In compound (L-9), n is 0, Q is a group represented by Q1-4, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX466). In compound (L-9), n is 1, Q is a group represented by Q1-4, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX467).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-4, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX468). In compound (L-9), n is 0, Q is a group represented by Q1-5, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX469). In compound (L-9), n is 1, Q is a group represented by Q1-5, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX470).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-5, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX471). In compound (L-9), n is 0, Q is a group represented by Q1-6, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX472). In compound (L-9), n is 1, Q is a group represented by Q1-6, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX473).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-6, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX474). In compound (L-9), n is 0, Q is a group represented by Q1-7, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX475). In compound (L-9), n is 1, Q is a group represented by Q1-7, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX476).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-7, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX477). In compound (L-9), n is 0, Q is a group represented by Q1-8, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX478). In compound (L-9), n is 1, Q is a group represented by Q1-8, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX479).
  • compound (L-9) n is 2, Q is a group represented by Q1-8, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX480).
  • compound (L-9) n is 0, Q is a group represented by Q1-9, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX481).
  • compound (L-9) n is 1, Q is a group represented by Q1-9, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX482).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-9, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX483). In compound (L-9), n is 0, Q is a group represented by Q1-10, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX484). In compound (L-9), n is 1, Q is a group represented by Q1-10, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX485).
  • compound (L-9) n is 2, Q is a group represented by Q1-10, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX486).
  • compound (L-9) a compound in which n is 0, Q is a group represented by Q1-11, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX487).
  • compound (L-9) n is 1, Q is a group represented by Q1-11, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX488).
  • compound (L-9) a compound in which n is 2, Q is a group represented by Q1-11, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX489).
  • compound (L-9) n is 0, Q is a group represented by Q1-12, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX490).
  • compound (L-9) n is 1, Q is a group represented by Q1-12, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX491).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-12, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX492). In compound (L-9), n is 0, Q is a group represented by Q1-13, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX493). In compound (L-9), n is 1, Q is a group represented by Q1-13, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX494).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-13, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX495). In compound (L-9), n is 0, Q is a group represented by Q1-14, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX496). In compound (L-9), n is 1, Q is a group represented by Q1-14, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX497).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-14, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX498). In compound (L-9), n is 0, Q is a group represented by Q1-15, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX499). In compound (L-9), n is 1, Q is a group represented by Q1-15, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX500).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-15, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX501). In compound (L-9), n is 0, Q is a group represented by Q1-16, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX502). In compound (L-9), n is 1, Q is a group represented by Q1-16, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX503).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-16, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX504). In compound (L-9), n is 0, Q is a group represented by Q1-17, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX505). In compound (L-9), n is 1, Q is a group represented by Q1-17, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX506).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-17, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX507). In compound (L-9), n is 0, Q is a group represented by Q1-18, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX508). In compound (L-9), n is 1, Q is a group represented by Q1-18, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX509).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q1-18, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX510). In compound (L-9), n is 0, Q is a group represented by Q2-1, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX511). In compound (L-9), n is 1, Q is a group represented by Q2-1, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX512).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-1, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX513). In compound (L-9), n is 0, Q is a group represented by Q2-2, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX514). In compound (L-9), n is 1, Q is a group represented by Q2-2, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX515).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-2, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX516). In compound (L-9), n is 0, Q is a group represented by Q2-3, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX517). In compound (L-9), n is 1, Q is a group represented by Q2-3, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX518).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-3, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX519). In compound (L-9), n is 0, Q is a group represented by Q2-4, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX520). In compound (L-9), n is 1, Q is a group represented by Q2-4, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX521).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-4, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX522). In compound (L-9), n is 0, Q is a group represented by Q2-5, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX523). In compound (L-9), n is 1, Q is a group represented by Q2-5, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX524).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-5, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX525). In compound (L-9), n is 0, Q is a group represented by Q2-6, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX526). In compound (L-9), n is 1, Q is a group represented by Q2-6, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX527).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-6, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX528). In compound (L-9), n is 0, Q is a group represented by Q2-7, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX529). In compound (L-9), n is 1, Q is a group represented by Q2-7, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX530).
  • compound (L-9) n is 2, Q is a group represented by Q2-7, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX531).
  • compound (L-9) n is 0, Q is a group represented by Q2-8, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX532).
  • compound (L-9) n is 1, Q is a group represented by Q2-8, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX533).
  • compound (L-9) n is 2, Q is a group represented by Q2-8, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX534).
  • compound (L-9) n is 0, Q is a group represented by Q2-9, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX535).
  • compound (L-9) n is 1, Q is a group represented by Q2-9, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX536).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-9, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX537). In the compound (L-9), n is 0, Q is a group represented by Q2-10, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX538). In compound (L-9), n is 1, Q is a group represented by Q2-10, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX539).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-10, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX540). In compound (L-9), n is 0, Q is a group represented by Q2-11, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX541). In compound (L-9), n is 1, Q is a group represented by Q2-11, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX542).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-11, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX543). In compound (L-9), n is 0, Q is a group represented by Q2-12, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX544). In compound (L-9), n is 1, Q is a group represented by Q2-12, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX545).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-12, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX546). In compound (L-9), n is 0, Q is a group represented by Q2-13, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX547). In compound (L-9), n is 1, Q is a group represented by Q2-13, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX548).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-13, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX549). In compound (L-9), n is 0, Q is a group represented by Q2-14, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX550). In compound (L-9), n is 1, Q is a group represented by Q2-14, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX551).
  • compound (L-9) n is 2, Q is a group represented by Q2-14, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX552).
  • compound (L-9) n is 0, Q is a group represented by Q2-15, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX553).
  • compound (L-9) n is 1, Q is a group represented by Q2-15, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX554).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-15, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX555). In compound (L-9), n is 0, Q is a group represented by Q2-16, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX556). In compound (L-9), n is 1, Q is a group represented by Q2-16, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX557).
  • compound (L-9) n is 2, Q is a group represented by Q2-16, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX558).
  • compound (L-9) a compound in which n is 0, Q is a group represented by Q2-17, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX559).
  • compound (L-9) n is 1, Q is a group represented by Q2-17, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX560).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-17, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX561). In compound (L-9), n is 0, Q is a group represented by Q2-18, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX562). In compound (L-9), n is 1, Q is a group represented by Q2-18, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX563).
  • compound (L-9) a compound in which n is 2, Q is a group represented by Q2-18, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX564).
  • compound (L-9) n is 0, Q is a group represented by Q2-19, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX565).
  • compound (L-9) n is 1, Q is a group represented by Q2-19, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX566).
  • compound (L-9) n is 2, Q is a group represented by Q2-19, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX567).
  • compound (L-9) a compound in which n is 0, Q is a group represented by Q2-20, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX568).
  • compound (L-9) n is 1, Q is a group represented by Q2-20, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX569).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-20, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX570). In compound (L-9), n is 0, Q is a group represented by Q2-21, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX571). In compound (L-9), n is 1, Q is a group represented by Q2-21, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX572).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-21, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX573). In compound (L-9), n is 0, Q is a group represented by Q2-22, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX574). In compound (L-9), n is 1, Q is a group represented by Q2-22, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX575).
  • compound (L-9) n is 2, Q is a group represented by Q2-22, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX576).
  • compound (L-9) n is 0, Q is a group represented by Q2-23, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX577).
  • compound (L-9) n is 1, Q is a group represented by Q2-23, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX578).
  • compound (L-9) n is 2, Q is a group represented by Q2-23, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX579).
  • compound (L-9) n is 0, Q is a group represented by Q2-24, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX580).
  • compound (L-9) n is 1, Q is a group represented by Q2-24, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX581).
  • compound (L-9) n is 2, Q is a group represented by Q2-24, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX582).
  • compound (L-9) n is 0, Q is a group represented by Q2-25, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX583).
  • compound (L-9) n is 1, Q is a group represented by Q2-25, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX584).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-25, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX585).
  • compound (L-9) a compound in which n is 0, Q is a group represented by Q2-26, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX586).
  • compound (L-9) In compound (L-9), n is 1, Q is a group represented by Q2-26, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX587).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-26, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX588). In compound (L-9), n is 0, Q is a group represented by Q2-27, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX589). In compound (L-9), n is 1, Q is a group represented by Q2-27, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX590).
  • compound (L-9) n is 2, Q is a group represented by Q2-27, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX591).
  • compound (L-9) n is 0, Q is a group represented by Q2-28, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX592).
  • compound (L-9) n is 1, Q is a group represented by Q2-28, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX593).
  • compound (L-9) n is 2, Q is a group represented by Q2-28, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX594).
  • compound (L-9) n is 0, Q is a group represented by Q2-29, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX595).
  • compound (L-9) n is 1, Q is a group represented by Q2-29, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX596).
  • compound (L-9) n is 2, Q is a group represented by Q2-29, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX597).
  • compound (L-9) a compound in which n is 0, Q is a group represented by Q2-30, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX598).
  • compound (L-9) n is 1, Q is a group represented by Q2-30, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX599).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-30, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX600). In compound (L-9), n is 0, Q is a group represented by Q2-31, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX601). In compound (L-9), n is 1, Q is a group represented by Q2-31, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX602).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-31, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX603). In compound (L-9), n is 0, Q is a group represented by Q2-32, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX604). In compound (L-9), n is 1, Q is a group represented by Q2-32, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX605).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-32, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX606). In compound (L-9), n is 0, Q is a group represented by Q2-33, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX607). In compound (L-9), n is 1, Q is a group represented by Q2-33, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX608).
  • compound (L-9) n is 2, Q is a group represented by Q2-33, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX609).
  • compound (L-9) n is 0, Q is a group represented by Q2-34, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX610).
  • compound (L-9) n is 1, Q is a group represented by Q2-34, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX611).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-34, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX612). In compound (L-9), n is 0, Q is a group represented by Q2-35, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX613). In compound (L-9), n is 1, Q is a group represented by Q2-35, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX614).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-35, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX615). In compound (L-9), n is 0, Q is a group represented by Q2-36, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX616). In compound (L-9), n is 1, Q is a group represented by Q2-36, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX617).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-36, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX618). In compound (L-9), n is 0, Q is a group represented by Q2-37, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX619). In compound (L-9), n is 1, Q is a group represented by Q2-37, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX620).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-37, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX621). In compound (L-9), n is 0, Q is a group represented by Q2-38, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX622). In compound (L-9), n is 1, Q is a group represented by Q2-38, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX623).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-38, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX624). In the compound (L-9), n is 0, Q is a group represented by Q2-39, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX625). In compound (L-9), n is 1, Q is a group represented by Q2-39, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX626).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-39, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX627). In compound (L-9), n is 0, Q is a group represented by Q2-40, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX628). In compound (L-9), n is 1, Q is a group represented by Q2-40, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX629).
  • compound (L-9) n is 2, Q is a group represented by Q2-40, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX630).
  • compound (L-9) n is 0, Q is a group represented by Q2-41, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX631).
  • compound (L-9) n is 1, Q is a group represented by Q2-41, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX632).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-41, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX633). In compound (L-9), n is 0, Q is a group represented by Q2-42, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX634). In compound (L-9), n is 1, Q is a group represented by Q2-42, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX635).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-42, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX636). In compound (L-9), n is 0, Q is a group represented by Q2-43, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX637). In compound (L-9), n is 1, Q is a group represented by Q2-43, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX638).
  • compound (L-9) n is 2, Q is a group represented by Q2-43, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX639).
  • compound (L-9) n is 0, Q is a group represented by Q2-44, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX640).
  • compound (L-9) n is 1, Q is a group represented by Q2-44, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX641).
  • compound (L-9) n is 2, Q is a group represented by Q2-44, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX642).
  • compound (L-9) n is 0, Q is a group represented by Q2-45, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX643).
  • compound (L-9) n is 1, Q is a group represented by Q2-45, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX644).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-45, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX645). In compound (L-9), n is 0, Q is a group represented by Q2-46, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX646). In compound (L-9), n is 1, Q is a group represented by Q2-46, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX647).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-46, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX648). In compound (L-9), n is 0, Q is a group represented by Q2-47, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX649). In compound (L-9), n is 1, Q is a group represented by Q2-47, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX650).
  • compound (L-9) n is 2, Q is a group represented by Q2-47, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX651).
  • compound (L-9) n is 0, Q is a group represented by Q2-48, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX652).
  • compound (L-9) n is 1, Q is a group represented by Q2-48, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX653).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-48, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX654).
  • n In the compound (L-9), n is 0, Q is a group represented by Q2-49, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX655).
  • compound (L-9) n is 1, Q is a group represented by Q2-49, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX656).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-49, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX657). In compound (L-9), n is 0, Q is a group represented by Q2-50, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX658). In compound (L-9), n is 1, Q is a group represented by Q2-50, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX659).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-50, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX660). In compound (L-9), n is 0, Q is a group represented by Q2-51, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX661). In compound (L-9), n is 1, Q is a group represented by Q2-51, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX662).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-51, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX663). In compound (L-9), n is 0, Q is a group represented by Q2-52, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX664). In compound (L-9), n is 1, Q is a group represented by Q2-52, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX665).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-52, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX666). In compound (L-9), n is 0, Q is a group represented by Q2-53, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX667). In compound (L-9), n is 1, Q is a group represented by Q2-53, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX668).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-53, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX669). In compound (L-9), n is 0, Q is a group represented by Q2-54, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX670). In compound (L-9), n is 1, Q is a group represented by Q2-54, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX671).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-54, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX672). In compound (L-9), n is 0, Q is a group represented by Q2-55, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX673). In compound (L-9), n is 1, Q is a group represented by Q2-55, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX674).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-55, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX675). In compound (L-9), n is 0, Q is a group represented by Q2-56, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX676). In compound (L-9), n is 1, Q is a group represented by Q2-56, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX677).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-56, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX678). In compound (L-9), n is 0, Q is a group represented by Q2-57, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX679). In compound (L-9), n is 1, Q is a group represented by Q2-57, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX680).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-57, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX681). In compound (L-9), n is 0, Q is a group represented by Q2-58, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX682). In compound (L-9), n is 1, Q is a group represented by Q2-58, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX683).
  • compound (L-9) In compound (L-9), n is 2, Q is a group represented by Q2-58, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX684). In the compound (L-9), n is 0, Q is a group represented by Q2-59, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX685). In compound (L-9), n is 1, Q is a group represented by Q2-59, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX686).
  • compound (L-9) n is 2, Q is a group represented by Q2-59, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX687).
  • compound (L-9) a compound in which n is 0, Q is a group represented by Q2-60, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX688).
  • compound (L-9) a compound in which n is 1, Q is a group represented by Q2-60, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX689).
  • compound (L-9) n is 2, Q is a group represented by Q2-60, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX690).
  • compound (L-9) n is 0, Q is a group represented by Q2-61, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX691).
  • n 1, Q is a group represented by Q2-61, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX692).
  • compound (L-9) n is 2, Q is a group represented by Q2-61, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX693).
  • compound (L-9) n is 0, Q is a group represented by Q2-62, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX694).
  • n 1, Q is a group represented by Q2-62, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX695).
  • n 2
  • Q is a group represented by Q2-62
  • R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX696).
  • compound (L-9) n is 0, Q is a group represented by Q2-63, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX697).
  • n 1, Q is a group represented by Q2-63, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX698).
  • n 2
  • Q is a group represented by Q2-63
  • R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX699).
  • compound (L-9) n is 0, Q is a group represented by Q2-64, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX700).
  • compound (L-9) n is 1, Q is a group represented by Q2-64, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX701).
  • compound (L-9) n is 2, Q is a group represented by Q2-64, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX702).
  • compound (L-9) n is 0, Q is a group represented by Q2-65, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX703).
  • n 1, Q is a group represented by Q2-65, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX704).
  • n 2, Q is a group represented by Q2-65, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX705).
  • compound (L-9) n is 0, Q is a group represented by Q2-66, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX706).
  • n 1, Q is a group represented by Q2-66, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX707).
  • compound (L-9) n is 2, Q is a group represented by Q2-66, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX708).
  • Q1-1 to Q1-18 and Q2-1 to Q2-66 are the groups shown below (# represents a bonding site to a sulfur atom, and ⁇ represents a bonding site to Het).
  • Formula (L-10) In the compound represented by the formula (hereinafter referred to as compound (L-10)), n is 0, Q is a group represented by Q1-1, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter referred to as compound group SX709). In compound (L-10), n is 1, Q is a group represented by Q1-1, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX710).
  • compound (L-10) n is 2, Q is a group represented by Q1-1, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX711).
  • compound (L-10) n is 0, Q is a group represented by Q1-2, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX712).
  • compound (L-10) n is 1, Q is a group represented by Q1-2, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX713).
  • compound (L-10) n is 2, Q is a group represented by Q1-2, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX714).
  • compound (L-10) n is 0, Q is a group represented by Q1-3, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX715).
  • compound (L-10) n is 1, Q is a group represented by Q1-3, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX716).
  • compound (L-10) n is 2, Q is a group represented by Q1-3, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX717).
  • compound (L-10) n is 0, Q is a group represented by Q1-4, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX718).
  • compound (L-10) n is 1, Q is a group represented by Q1-4, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX719).
  • compound (L-10) n is 2, Q is a group represented by Q1-4, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX720).
  • compound (L-10) n is 0, Q is a group represented by Q1-5, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX721).
  • compound (L-10) n is 1, Q is a group represented by Q1-5, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX722).
  • compound (L-10) n is 2, Q is a group represented by Q1-5, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX723).
  • compound (L-10) n is 0, Q is a group represented by Q1-6, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX724).
  • compound (L-10) n is 1, Q is a group represented by Q1-6, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX725).
  • compound (L-10) n is 2, Q is a group represented by Q1-6, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX726).
  • compound (L-10) n is 0, Q is a group represented by Q1-7, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX727).
  • compound (L-10) n is 1, Q is a group represented by Q1-7, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX728).
  • compound (L-10) n is 2, Q is a group represented by Q1-7, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX729).
  • compound (L-10) n is 0, Q is a group represented by Q1-8, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX730).
  • compound (L-10) n is 1, Q is a group represented by Q1-8, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX731).
  • compound (L-10) n is 2, Q is a group represented by Q1-8, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX732).
  • compound (L-10) n is 0, Q is a group represented by Q1-9, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX733).
  • compound (L-10) n is 1, Q is a group represented by Q1-9, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX734).
  • compound (L-10) n is 2, Q is a group represented by Q1-9, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX735).
  • compound (L-10) n is 0, Q is a group represented by Q1-10, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX736).
  • compound (L-10) n is 1, Q is a group represented by Q1-10, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX737).
  • compound (L-10) n is 2, Q is a group represented by Q1-10, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX738).
  • compound (L-10) n is 0, Q is a group represented by Q1-11, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX739).
  • compound (L-10) n is 1, Q is a group represented by Q1-11, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX740).
  • compound (L-10) n is 2, Q is a group represented by Q1-11, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX741).
  • compound (L-10) n is 0, Q is a group represented by Q1-12, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX742).
  • compound (L-10) n is 1, Q is a group represented by Q1-12, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX743).
  • compound (L-10) n is 2, Q is a group represented by Q1-12, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX744).
  • compound (L-10) n is 0, Q is a group represented by Q1-13, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX745).
  • compound (L-10) n is 1, Q is a group represented by Q1-13, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX746).
  • compound (L-10) n is 2, Q is a group represented by Q1-13, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX747).
  • compound (L-10) n is 0, Q is a group represented by Q1-14, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX748).
  • compound (L-10) n is 1, Q is a group represented by Q1-14, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX749).
  • compound (L-10) n is 2, Q is a group represented by Q1-14, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX750).
  • compound (L-10) n is 0, Q is a group represented by Q1-15, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX751).
  • compound (L-10) n is 1, Q is a group represented by Q1-15, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX752).
  • n 2
  • Q is a group represented by Q1-15
  • R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX753).
  • n 0, Q is a group represented by Q1-16, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX754).
  • n 1
  • Q is a group represented by Q1-16
  • R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX755).
  • compound (L-10) n is 2, Q is a group represented by Q1-16, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX756).
  • compound (L-10) n is 0, Q is a group represented by Q1-17, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX757).
  • compound (L-10) n is 1, Q is a group represented by Q1-17, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX758).
  • compound (L-10) n is 2, Q is a group represented by Q1-17, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX759).
  • compound (L-10) n is 0, Q is a group represented by Q1-18, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX760).
  • compound (L-10) n is 1, Q is a group represented by Q1-18, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX761).
  • compound (L-10) n is 2, Q is a group represented by Q1-18, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX762).
  • compound (L-10) n is 0, Q is a group represented by Q2-1, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX763).
  • compound (L-10) a compound in which n is 1, Q is a group represented by Q2-1, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX764).
  • compound (L-10) n is 2, Q is a group represented by Q2-1, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX765).
  • compound (L-10) n is 0, Q is a group represented by Q2-2, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX766).
  • compound (L-10) n is 1, Q is a group represented by Q2-2, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX767).
  • compound (L-10) n is 2, Q is a group represented by Q2-2, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX768).
  • compound (L-10) n is 0, Q is a group represented by Q2-3, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX769).
  • compound (L-10) n is 1, Q is a group represented by Q2-3, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX770).
  • compound (L-10) n is 2, Q is a group represented by Q2-3, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX771).
  • compound (L-10) n is 0, Q is a group represented by Q2-4, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX772).
  • compound (L-10) n is 1, Q is a group represented by Q2-4, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX773).
  • compound (L-10) n is 2, Q is a group represented by Q2-4, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX774).
  • compound (L-10) n is 0, Q is a group represented by Q2-5, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX775).
  • compound (L-10) n is 1, Q is a group represented by Q2-5, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX776).
  • n 2
  • Q is a group represented by Q2-5
  • R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX777).
  • n 0, Q is a group represented by Q2-6, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX778).
  • compound (L-10) n is 1, Q is a group represented by Q2-6, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX779).
  • compound (L-10) n is 2, Q is a group represented by Q2-6, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX780).
  • compound (L-10) n is 0, Q is a group represented by Q2-7, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX781).
  • compound (L-10) n is 1, Q is a group represented by Q2-7, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX782).
  • n 2
  • Q is a group represented by Q2-7
  • R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX783).
  • n 0, Q is a group represented by Q2-8, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX784).
  • n is 1, Q is a group represented by Q2-8, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX785).
  • compound (L-10) n is 2, Q is a group represented by Q2-8, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX786).
  • compound (L-10) n is 0, Q is a group represented by Q2-9, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX787).
  • compound (L-10) n is 1, Q is a group represented by Q2-9, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX788).
  • compound (L-10) n is 2, Q is a group represented by Q2-9, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX789).
  • compound (L-10) n is 0, Q is a group represented by Q2-10, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX790).
  • compound (L-10) n is 1, Q is a group represented by Q2-10, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX791).
  • compound (L-10) n is 2, Q is a group represented by Q2-10, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX792).
  • compound (L-10) n is 0, Q is a group represented by Q2-11, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX793).
  • compound (L-10) n is 1, Q is a group represented by Q2-11, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX794).
  • compound (L-10) n is 2, Q is a group represented by Q2-11, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX795).
  • compound (L-10) n is 0, Q is a group represented by Q2-12, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX796).
  • compound (L-10) n is 1, Q is a group represented by Q2-12, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX797).
  • compound (L-10) n is 2, Q is a group represented by Q2-12, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX798).
  • compound (L-10) n is 0, Q is a group represented by Q2-13, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX799).
  • compound (L-10) n is 1, Q is a group represented by Q2-13, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX800).
  • compound (L-10) n is 2, Q is a group represented by Q2-13, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX801).
  • compound (L-10) n is 0, Q is a group represented by Q2-14, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX802).
  • compound (L-10) n is 1, Q is a group represented by Q2-14, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX803).
  • compound (L-10) n is 2, Q is a group represented by Q2-14, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX804).
  • compound (L-10) n is 0, Q is a group represented by Q2-15, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX805).
  • compound (L-10) n is 1, Q is a group represented by Q2-15, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX806).
  • compound (L-10) n is 2, Q is a group represented by Q2-15, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX807).
  • compound (L-10) n is 0, Q is a group represented by Q2-16, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX808).
  • compound (L-10) n is 1, Q is a group represented by Q2-16, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX809).
  • compound (L-10) n is 2, Q is a group represented by Q2-16, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX810).
  • compound (L-10) n is 0, Q is a group represented by Q2-17, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX811).
  • compound (L-10) n is 1, Q is a group represented by Q2-17, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX812).
  • compound (L-10) n is 2, Q is a group represented by Q2-17, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX813).
  • compound (L-10) n is 0, Q is a group represented by Q2-18, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX814).
  • compound (L-10) n is 1, Q is a group represented by Q2-18, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX815).
  • compound (L-10) n is 2, Q is a group represented by Q2-18, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX816).
  • compound (L-10) n is 0, Q is a group represented by Q2-19, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX817).
  • compound (L-10) n is 1, Q is a group represented by Q2-19, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX818).
  • compound (L-10) n is 2, Q is a group represented by Q2-19, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX819).
  • compound (L-10) n is 0, Q is a group represented by Q2-20, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX820).
  • compound (L-10) n is 1, Q is a group represented by Q2-20, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX821).
  • compound (L-10) n is 2, Q is a group represented by Q2-20, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX822).
  • compound (L-10) n is 0, Q is a group represented by Q2-21, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX823).
  • compound (L-10) n is 1, Q is a group represented by Q2-21, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX824).
  • compound (L-10) n is 2, Q is a group represented by Q2-21, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX825).
  • compound (L-10) n is 0, Q is a group represented by Q2-22, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX826).
  • compound (L-10) n is 1, Q is a group represented by Q2-22, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX827).
  • compound (L-10) n is 2, Q is a group represented by Q2-22, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX828).
  • compound (L-10) n is 0, Q is a group represented by Q2-23, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX829).
  • compound (L-10) n is 1, Q is a group represented by Q2-23, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX830).
  • compound (L-10) n is 2, Q is a group represented by Q2-23, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX831).
  • compound (L-10) n is 0, Q is a group represented by Q2-24, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX832).
  • compound (L-10) n is 1, Q is a group represented by Q2-24, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX833).
  • compound (L-10) n is 2, Q is a group represented by Q2-24, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX834).
  • compound (L-10) n is 0, Q is a group represented by Q2-25, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX835).
  • compound (L-10) n is 1, Q is a group represented by Q2-25, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX836).
  • compound (L-10) n is 2, Q is a group represented by Q2-25, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX837).
  • compound (L-10) n is 0, Q is a group represented by Q2-26, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX838).
  • compound (L-10) n is 1, Q is a group represented by Q2-26, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX839).
  • compound (L-10) n is 2, Q is a group represented by Q2-26, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX840).
  • compound (L-10) n is 0, Q is a group represented by Q2-27, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX841).
  • compound (L-10) n is 1, Q is a group represented by Q2-27, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX842).
  • compound (L-10) n is 2, Q is a group represented by Q2-27, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX843).
  • compound (L-10) n is 0, Q is a group represented by Q2-28, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX844).
  • compound (L-10) n is 1, Q is a group represented by Q2-28, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX845).
  • compound (L-10) n is 2, Q is a group represented by Q2-28, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX846).
  • compound (L-10) n is 0, Q is a group represented by Q2-29, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX847).
  • compound (L-10) n is 1, Q is a group represented by Q2-29, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX848).
  • compound (L-10) n is 2, Q is a group represented by Q2-29, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX849).
  • compound (L-10) n is 0, Q is a group represented by Q2-30, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX850).
  • compound (L-10) n is 1, Q is a group represented by Q2-30, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX851).
  • compound (L-10) n is 2, Q is a group represented by Q2-30, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX852).
  • compound (L-10) n is 0, Q is a group represented by Q2-31, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX853).
  • compound (L-10) n is 1, Q is a group represented by Q2-31, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX854).
  • compound (L-10) n is 2, Q is a group represented by Q2-31, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX855).
  • compound (L-10) n is 0, Q is a group represented by Q2-32, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX856).
  • compound (L-10) n is 1, Q is a group represented by Q2-32, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX857).
  • compound (L-10) n is 2, Q is a group represented by Q2-32, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX858).
  • compound (L-10) n is 0, Q is a group represented by Q2-33, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX859).
  • compound (L-10) n is 1, Q is a group represented by Q2-33, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX860).
  • compound (L-10) n is 2, Q is a group represented by Q2-33, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX861).
  • compound (L-10) n is 0, Q is a group represented by Q2-34, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX862).
  • compound (L-10) n is 1, Q is a group represented by Q2-34, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX863).
  • compound (L-10) n is 2, Q is a group represented by Q2-34, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX864).
  • compound (L-10) n is 0, Q is a group represented by Q2-35, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX865).
  • compound (L-10) n is 1, Q is a group represented by Q2-35, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX866).
  • compound (L-10) n is 2, Q is a group represented by Q2-35, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX867).
  • compound (L-10) n is 0, Q is a group represented by Q2-36, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX868).
  • compound (L-10) n is 1, Q is a group represented by Q2-36, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX869).
  • compound (L-10) n is 2, Q is a group represented by Q2-36, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX870).
  • compound (L-10) n is 0, Q is a group represented by Q2-37, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX871).
  • compound (L-10) n is 1, Q is a group represented by Q2-37, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX872).
  • n 2
  • Q is a group represented by Q2-37
  • R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX873).
  • n 0, Q is a group represented by Q2-38, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX874).
  • n 1
  • Q is a group represented by Q2-38
  • R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX875).
  • compound (L-10) a compound in which n is 2, Q is a group represented by Q2-38, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX876).
  • compound (L-10) n is 0, Q is a group represented by Q2-39, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX877).
  • compound (L-10) n is 1, Q is a group represented by Q2-39, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX878).
  • compound (L-10) n is 2, Q is a group represented by Q2-39, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX879).
  • compound (L-10) n is 0, Q is a group represented by Q2-40, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX880).
  • compound (L-10) n is 1, Q is a group represented by Q2-40, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX881).
  • compound (L-10) n is 2, Q is a group represented by Q2-40, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX882).
  • compound (L-10) n is 0, Q is a group represented by Q2-41, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX883).
  • compound (L-10) a compound in which n is 1, Q is a group represented by Q2-41, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX884).
  • compound (L-10) n is 2, Q is a group represented by Q2-41, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX885).
  • compound (L-10) a compound in which n is 0, Q is a group represented by Q2-42, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX886).
  • compound (L-10) a compound in which n is 1, Q is a group represented by Q2-42, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX887).
  • compound (L-10) a compound in which n is 2, Q is a group represented by Q2-42, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX888).
  • compound (L-10) n is 0, Q is a group represented by Q2-43, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX889).
  • compound (L-10) n is 1, Q is a group represented by Q2-43, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX890).
  • compound (L-10) n is 2, Q is a group represented by Q2-43, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX891).
  • compound (L-10) n is 0, Q is a group represented by Q2-44, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX892).
  • compound (L-10) n is 1, Q is a group represented by Q2-44, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX893).
  • compound (L-10) n is 2, Q is a group represented by Q2-44, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX894).
  • compound (L-10) n is 0, Q is a group represented by Q2-45, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX895).
  • compound (L-10) a compound in which n is 1, Q is a group represented by Q2-45, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX896).
  • compound (L-10) n is 2, Q is a group represented by Q2-45, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX897).
  • compound (L-10) n is 0, Q is a group represented by Q2-46, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX898).
  • compound (L-10) n is 1, Q is a group represented by Q2-46, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX899).
  • compound (L-10) n is 2, Q is a group represented by Q2-46, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX900).
  • compound (L-10) n is 0, Q is a group represented by Q2-47, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX901).
  • compound (L-10) n is 1, Q is a group represented by Q2-47, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX902).
  • compound (L-10) n is 2, Q is a group represented by Q2-47, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX903).
  • compound (L-10) n is 0, Q is a group represented by Q2-48, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX904).
  • compound (L-10) n is 1, Q is a group represented by Q2-48, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX905).
  • compound (L-10) n is 2, Q is a group represented by Q2-48, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX906).
  • compound (L-10) n is 0, Q is a group represented by Q2-49, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX907).
  • compound (L-10) n is 1, Q is a group represented by Q2-49, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX908).
  • compound (L-10) n is 2, Q is a group represented by Q2-49, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX909).
  • compound (L-10) n is 0, Q is a group represented by Q2-50, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX910).
  • compound (L-10) n is 1, Q is a group represented by Q2-50, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX911).
  • compound (L-10) n is 2, Q is a group represented by Q2-50, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX912).
  • compound (L-10) n is 0, Q is a group represented by Q2-51, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX913).
  • compound (L-10) n is 1, Q is a group represented by Q2-51, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX914).
  • compound (L-10) n is 2, Q is a group represented by Q2-51, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX915).
  • compound (L-10) n is 0, Q is a group represented by Q2-52, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX916).
  • compound (L-10) n is 1, Q is a group represented by Q2-52, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX917).
  • compound (L-10) n is 2, Q is a group represented by Q2-52, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX918).
  • compound (L-10) n is 0, Q is a group represented by Q2-53, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX919).
  • compound (L-10) n is 1, Q is a group represented by Q2-53, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX920).
  • compound (L-10) n is 2, Q is a group represented by Q2-53, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX921).
  • compound (L-10) n is 0, Q is a group represented by Q2-54, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX922).
  • compound (L-10) n is 1, Q is a group represented by Q2-54, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX923).
  • compound (L-10) n is 2, Q is a group represented by Q2-54, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX924).
  • compound (L-10) n is 0, Q is a group represented by Q2-55, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX925).
  • compound (L-10) n is 1, Q is a group represented by Q2-55, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX926).
  • compound (L-10) n is 2, Q is a group represented by Q2-55, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX927).
  • compound (L-10) n is 0, Q is a group represented by Q2-56, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX928).
  • compound (L-10) n is 1, Q is a group represented by Q2-56, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX929).
  • compound (L-10) n is 2, Q is a group represented by Q2-56, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX930).
  • compound (L-10) n is 0, Q is a group represented by Q2-57, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX931).
  • compound (L-10) n is 1, Q is a group represented by Q2-57, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX932).
  • compound (L-10) n is 2, Q is a group represented by Q2-57, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX933).
  • compound (L-10) n is 0, Q is a group represented by Q2-58, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX934).
  • compound (L-10) n is 1, Q is a group represented by Q2-58, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX935).
  • compound (L-10) n is 2, Q is a group represented by Q2-58, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX936).
  • compound (L-10) n is 0, Q is a group represented by Q2-59, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX937).
  • compound (L-10) n is 1, Q is a group represented by Q2-59, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX938).
  • compound (L-10) n is 2, Q is a group represented by Q2-59, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX939).
  • compound (L-10) n is 0, Q is a group represented by Q2-60, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX940).
  • compound (L-10) n is 1, Q is a group represented by Q2-60, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX941).
  • compound (L-10) n is 2, Q is a group represented by Q2-60, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX942).
  • compound (L-10) n is 0, Q is a group represented by Q2-61, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX943).
  • compound (L-10) n is 1, Q is a group represented by Q2-61, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX944).
  • compound (L-10) n is 2, Q is a group represented by Q2-61, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX945).
  • compound (L-10) n is 0, Q is a group represented by Q2-62, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX946).
  • compound (L-10) n is 1, Q is a group represented by Q2-62, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX947).
  • compound (L-10) n is 2, Q is a group represented by Q2-62, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX948).
  • compound (L-10) n is 0, Q is a group represented by Q2-63, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX949).
  • compound (L-10) n is 1, Q is a group represented by Q2-63, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX950).
  • compound (L-10) n is 2, Q is a group represented by Q2-63, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX951).
  • compound (L-10) n is 0, Q is a group represented by Q2-64, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX952).
  • compound (L-10) n is 1, Q is a group represented by Q2-64, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX953).
  • compound (L-10) n is 2, Q is a group represented by Q2-64, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX954).
  • compound (L-10) a compound in which n is 0, Q is a group represented by Q2-65, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX955).
  • compound (L-10) n is 1, Q is a group represented by Q2-65, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX956).
  • compound (L-10) Q is a group represented by Q2-65, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX957).
  • compound (L-10) n is 0, Q is a group represented by Q2-66, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX958).
  • compound (L-10) n is 1, Q is a group represented by Q2-66, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX959).
  • compound (L-10) n is 2, Q is a group represented by Q2-66, and R 6b is any of the substituents described in [Table 1A] to [Table 3A] (hereinafter, referred to as compound group SX960).
  • Het3 to Het57 are the groups shown below.
  • Het is a group represented by Het3, and R 6a is a difluoromethyl group
  • R 4b is any one of the substituents described in [Table 7A] to [Table 15A]
  • R 4c is a hydrogen atom (hereinafter, referred to as compound group SX962).
  • compound (L-11) Het is a group represented by Het3, and R 6a is a trifluoromethoxy group
  • R 4b is any one of the substituents described in [Table 7A] to [Table 15A]
  • R 4c is a hydrogen atom (hereinafter, referred to as compound group SX963).
  • compound (L-11) Het is a group represented by Het3, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX964).
  • compound (L-11) Het is a group represented by Het4, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX965).
  • compound (L-11) Het is a group represented by Het4, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX966).
  • compound (L-11) Het is a group represented by Het4, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX967).
  • compound (L-11) Het is a group represented by Het4, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX968).
  • compound (L-11) Het is a group represented by He5, and R 6c is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX969).
  • compound (L-11) Het is a group represented by He5, and R 6c is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX970).
  • compound (L-11) Het is a group represented by He5, and R 6c is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX971).
  • compound (L-11) Het is a group represented by He5, and R 6c is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX972).
  • compound (L-11) Het is a group represented by Het6, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX973).
  • compound (L-11) Het is a group represented by Het6, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX974).
  • compound (L-11) Het is a group represented by Het6, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX975).
  • compound (L-11) Het is a group represented by Het6, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX976).
  • compound (L-11) Het is a group represented by Het7, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX977).
  • compound (L-11) Het is a group represented by Het7, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX978).
  • compound (L-11) Het is a group represented by Het7, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX979).
  • compound (L-11) Het is a group represented by Het8, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX982).
  • compound (L-11) Het is a group represented by Het8, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX983).
  • compound (L-11) Het is a group represented by Het8, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX984).
  • compound (L-11) Het is a group represented by Het9, and R 6c is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX985).
  • compound (L-11) Het is a group represented by Het9, and R 6c is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX986).
  • compound (L-11) Het is a group represented by Het9, and R 6c is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX987).
  • compound (L-11) Het is a group represented by Het9, and R 6c is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX988).
  • compound (L-11) Het is a group represented by Het10, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX989).
  • compound (L-11) Het is a group represented by Het10, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX990).
  • compound (L-11) Het is a group represented by Het10, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX991).
  • compound (L-11) Het is a group represented by Het10, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX992).
  • compound (L-11) Het is a group represented by Het11, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX993).
  • compound (L-11) Het is a group represented by Het11, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX994).
  • compound (L-11) Het is a group represented by Het11, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX995).
  • compound (L-11) Het is a group represented by Het11, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX996).
  • compound (L-11) Het is a group represented by Het12, and R 6c is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX997).
  • compound (L-11) Het is a group represented by Het12, and R 6c is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX998).
  • compound (L-11) Het is a group represented by Het12, and R 6c is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter referred to as compound group SX999).
  • compound (L-11) Het is a group represented by Het12, and R 6c is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1000).
  • compound (L-11) Het is a group represented by Het13, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1001).
  • compound (L-11) Het is a group represented by Het13, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1002).
  • compound (L-11) Het is a group represented by Het13, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1003).
  • compound (L-11) Het is a group represented by Het13, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1004).
  • compound (L-11) Het is a group represented by Het14, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1005).
  • compound (L-11) Het is a group represented by Het14, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1006).
  • compound (L-11) Het is a group represented by Het14, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1007).
  • compound (L-11) Het is a group represented by Het14, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1008).
  • compound (L-11) Het is a group represented by Het15, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1009).
  • compound (L-11) Het is a group represented by Het15, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1010).
  • compound (L-11) Het is a group represented by Het15, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1011).
  • compound (L-11) Het is a group represented by Het15, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1012).
  • compound (L-11) Het is a group represented by Het16, and R 6c is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1013).
  • compound (L-11) Het is a group represented by Het16, and R 6c is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1014).
  • compound (L-11) Het is a group represented by Het16, and R 6c is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1015).
  • compound (L-11) Het is a group represented by Het16, and R 6c is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1016).
  • compound (L-11) Het is a group represented by Het17, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1017).
  • compound (L-11) Het is a group represented by Het17, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1018).
  • compound (L-11) Het is a group represented by Het17, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1019).
  • compound (L-11) Het is a group represented by Het17, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1020).
  • compound (L-11) Het is a group represented by Het18, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1021).
  • compound (L-11) Het is a group represented by Het18, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1022).
  • compound (L-11) Het is a group represented by Het18, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1023).
  • compound (L-11) Het is a group represented by Het18, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1024).
  • compound (L-11) Het is a group represented by Het19, and R 6c is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1025).
  • compound (L-11) Het is a group represented by Het19, and R 6c is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1026).
  • compound (L-11) Het is a group represented by Het19, and R 6c is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1027).
  • compound (L-11) Het is a group represented by Het19, and R 6c is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1028).
  • compound (L-11) Het is a group represented by Het20, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1029).
  • compound (L-11) Het is a group represented by Het20, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1030).
  • compound (L-11) Het is a group represented by Het20, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1031).
  • compound (L-11) Het is a group represented by Het20, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1032).
  • compound (L-11) Het is a group represented by Het21, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1033).
  • compound (L-11) Het is a group represented by Het21, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1034).
  • compound (L-11) Het is a group represented by Het21, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1035).
  • compound (L-11) Het is a group represented by Het21, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1036).
  • compound (L-11) Het is a group represented by Het22, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1037).
  • compound (L-11) Het is a group represented by Het22, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1038).
  • compound (L-11) Het is a group represented by Het22, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1039).
  • compound (L-11) Het is a group represented by Het22, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1040).
  • compound (L-11) Het is a group represented by Het23, and R 6c is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1041).
  • compound (L-11) Het is a group represented by Het23, and R 6c is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1042).
  • compound (L-11) Het is a group represented by Het23, and R 6c is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1043).
  • compound (L-11) Het is a group represented by Het23, and R 6c is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1044).
  • compound (L-11) Het is a group represented by Het24, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1045).
  • compound (L-11) Het is a group represented by Het24, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1046).
  • compound (L-11) Het is a group represented by Het24, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1047).
  • compound (L-11) Het is a group represented by Het24, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1048).
  • compound (L-11) Het is a group represented by Het25, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1049).
  • compound (L-11) Het is a group represented by Het25, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1050).
  • compound (L-11) Het is a group represented by Het25, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1051).
  • compound (L-11) Het is a group represented by Het25, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1052).
  • compound (L-11) Het is a group represented by Het26, and R 6c is a trifluoromethyl group
  • R 4b is any one of the substituents described in [Table 7A] to [Table 15A]
  • R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1053).
  • compound (L-11) Het is a group represented by Het26, and R 6c is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1054).
  • compound (L-11) Het is a group represented by Het26, and R 6c is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1055).
  • compound (L-11) Het is a group represented by Het26, and R 6c is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1056).
  • compound (L-11) Het is a group represented by Het27, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1057).
  • compound (L-11) Het is a group represented by Het27, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1058).
  • compound (L-11) Het is a group represented by Het27, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1059).
  • compound (L-11) Het is a group represented by Het27, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1060).
  • compound (L-11) Het is a group represented by Het28, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1061).
  • compound (L-11) Het is a group represented by Het28, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1062).
  • compound (L-11) Het is a group represented by Het28, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1063).
  • compound (L-11) Het is a group represented by Het28, and R 6b is a difluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1064).
  • compound (L-11) Het is a group represented by Het29, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1065).
  • compound (L-11) Het is a group represented by Het29, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1066).
  • compound (L-11) Het is a group represented by Het29, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1067).
  • compound (L-11) Het is a group represented by Het29, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1068).
  • compound (L-11) Het is a group represented by Het30, and R 6c is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1069).
  • compound (L-11) Het is a group represented by Het30, and R 6c is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1070).
  • compound (L-11) Het is a group represented by Het30, and R 6c is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1071).
  • compound (L-11) Het is a group represented by Het30, and R 6c is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1072).
  • compound (L-11) Het is a group represented by Het31, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1073).
  • compound (L-11) Het is a group represented by Het31, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1074).
  • compound (L-11) Het is a group represented by Het31, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1075).
  • compound (L-11) Het is a group represented by Het31, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1076).
  • compound (L-11) Het is a group represented by Het32, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1077).
  • compound (L-11) Het is a group represented by Het32, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1078).
  • compound (L-11) Het is a group represented by Het32, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1079).
  • compound (L-11) Het is a group represented by Het32, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1080).
  • compound (L-11) Het is a group represented by Het33, and R 6c is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1081).
  • compound (L-11) Het is a group represented by Het33, and R 6c is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1082).
  • compound (L-11) Het is a group represented by Het33, and R 6c is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1083).
  • compound (L-11) Het is a group represented by Het33, and R 6c is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1084).
  • compound (L-11) Het is a group represented by Het34, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1085).
  • compound (L-11) Het is a group represented by Het34, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1086).
  • compound (L-11) Het is a group represented by Het34, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1087).
  • compound (L-11) Het is a group represented by Het34, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1088).
  • compound (L-11) Het is a group represented by Het35, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1089).
  • compound (L-11) Het is a group represented by Het35, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1090).
  • compound (L-11) Het is a group represented by Het35, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1091).
  • compound (L-11) Het is a group represented by Het35, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1092).
  • compound (L-11) Het is a group represented by Het36, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1093).
  • compound (L-11) Het is a group represented by Het36, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1094).
  • compound (L-11) Het is a group represented by Het36, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1095).
  • compound (L-11) Het is a group represented by Het36, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1096).
  • compound (L-11) Het is a group represented by Het37, and R 6c is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1097).
  • compound (L-11) Het is a group represented by Het37, and R 6c is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1098).
  • compound (L-11) Het is a group represented by Het37, and R 6c is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1099).
  • compound (L-11) Het is a group represented by Het37, and R 6c is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1100).
  • compound (L-11) Het is a group represented by Het38, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1101).
  • compound (L-11) Het is a group represented by Het38, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1102).
  • compound (L-11) Het is a group represented by Het38, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1103).
  • compound (L-11) Het is a group represented by Het38, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1104).
  • compound (L-11) Het is a group represented by Het39, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1105).
  • compound (L-11) Het is a group represented by Het39, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1106).
  • compound (L-11) Het is a group represented by Het39, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1107).
  • compound (L-11) Het is a group represented by Het39, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1108).
  • compound (L-11) Het is a group represented by Het40, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1109).
  • compound (L-11) Het is a group represented by Het40, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1110).
  • compound (L-11) Het is a group represented by Het40, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1111).
  • compound (L-11) Het is a group represented by Het40, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1112).
  • compound (L-11) Het is a group represented by Het41, and R 6c is a trifluoromethyl group
  • R 4b is any one of the substituents described in [Table 7A] to [Table 15A]
  • R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1113).
  • compound (L-11) Het is a group represented by Het41, and R 6c is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1114).
  • compound (L-11) Het is a group represented by Het41, and R 6c is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1115).
  • compound (L-11) Het is a group represented by Het41, and R 6c is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1116).
  • compound (L-11) Het is a group represented by Het42, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1117).
  • compound (L-11) Het is a group represented by Het42, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1118).
  • compound (L-11) Het is a group represented by Het42, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1119).
  • compound (L-11) Het is a group represented by Het42, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1120).
  • compound (L-11) Het is a group represented by Het43, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1121).
  • compound (L-11) Het is a group represented by Het43, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1122).
  • compound (L-11) Het is a group represented by Het43, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1123).
  • compound (L-11) Het is a group represented by Het43, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1124).
  • compound (L-11) Het is a group represented by Het44, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1125).
  • compound (L-11) Het is a group represented by Het44, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1126).
  • compound (L-11) Het is a group represented by Het44, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1127).
  • compound (L-11) Het is a group represented by Het44, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1128).
  • compound (L-11) Het is a group represented by Het45, and R 6c is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1129).
  • compound (L-11) Het is a group represented by Het45, and R 6c is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1130).
  • compound (L-11) Het is a group represented by Het45, and R 6c is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1131).
  • compound (L-11) Het is a group represented by Het45, and R 6c is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1132).
  • compound (L-11) Het is a group represented by Het46, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1133).
  • compound (L-11) Het is a group represented by Het46, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1134).
  • compound (L-11) Het is a group represented by Het46, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1135).
  • compound (L-11) Het is a group represented by Het46, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1136).
  • compound (L-11) Het is a group represented by Het47, and R 6b is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1137).
  • compound (L-11) Het is a group represented by Het47, and R 6b is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1138).
  • compound (L-11) Het is a group represented by Het47, and R 6b is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1139).
  • compound (L-11) Het is a group represented by Het47, and R 6b is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1140).
  • compound (L-11) Het is a group represented by Het48, and R 6a is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1141).
  • compound (L-11) Het is a group represented by Het48, and R 6a is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1142).
  • compound (L-11) Het is a group represented by Het48, and R 6a is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1143).
  • compound (L-11) Het is a group represented by Het48, and R 6a is a difluoromethoxy group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1144).
  • compound (L-11) Het is a group represented by Het49, and R 6c is a trifluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1145).
  • compound (L-11) Het is a group represented by Het49, and R 6c is a difluoromethyl group, R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1146).
  • compound (L-11) Het is a group represented by Het49, and R 6c is a trifluoromethoxy group, and R 4b is any one of the substituents described in [Table 7A] to [Table 15A], and R 4c is a hydrogen atom (hereinafter, referred to as compound group SX1147).

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