WO2024055712A1 - Double-sided superlens processing method - Google Patents

Double-sided superlens processing method Download PDF

Info

Publication number
WO2024055712A1
WO2024055712A1 PCT/CN2023/104802 CN2023104802W WO2024055712A1 WO 2024055712 A1 WO2024055712 A1 WO 2024055712A1 CN 2023104802 W CN2023104802 W CN 2023104802W WO 2024055712 A1 WO2024055712 A1 WO 2024055712A1
Authority
WO
WIPO (PCT)
Prior art keywords
alignment
structural layer
substrate
nanostructure
identification mark
Prior art date
Application number
PCT/CN2023/104802
Other languages
French (fr)
Chinese (zh)
Inventor
朱健
郝成龙
谭凤泽
Original Assignee
深圳迈塔兰斯科技有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 深圳迈塔兰斯科技有限公司 filed Critical 深圳迈塔兰斯科技有限公司
Publication of WO2024055712A1 publication Critical patent/WO2024055712A1/en

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B3/00Simple or compound lenses
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/20Exposure; Apparatus therefor
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F9/00Registration or positioning of originals, masks, frames, photographic sheets or textured or patterned surfaces, e.g. automatically

Definitions

  • the present invention relates to the technical field of super lens processing, and specifically, to a processing method of a double-sided super lens.
  • the manufacturing of double-sided metalens usually uses a contact exposure backside overlay process. After processing the nanostructure on the front of a certain wafer, An overlay mark is set on the back side, and the back side of the wafer is identified through a photolithography machine detector to identify the overlay mark, and the nanostructure on the back side is processed to finally obtain the double-sided super lens.
  • the accuracy of this processing method is limited by the accuracy of the traditional overlay process, which is plus or minus 1 ⁇ m, which is difficult to meet the alignment requirements of high-precision double-sided metalens.
  • the purpose of embodiments of the present invention is to provide a processing method of a double-sided super lens.
  • Embodiments of the present invention provide a method for processing a double-sided super lens, which includes: arranging a first structural layer on the first surface of a substrate, performing a first photolithography operation on the first structural layer, and obtaining a first nanostructure and Alignment identification mark; the substrate is transparent in the working band of the photolithography machine detector; a second structural layer is provided on the second surface of the substrate; and the second structural layer is located at a position corresponding to the alignment identification mark.
  • the size of the alignment window is larger than the size of the alignment identification mark; when the second surface is an operating surface, through the alignment window and based on the alignment identification mark Alignment is performed, and a second photolithography operation is performed on the second structural layer to obtain a second nanostructure; the operation surface represents the surface of the substrate currently processed by the photolithography machine.
  • performing a first photolithography operation on the first structural layer includes: coating a first photoresist layer on the surface of the first structural layer, and exposing and exposing the first photoresist layer.
  • making an alignment window at a position corresponding to the second structural layer and the alignment identification mark includes: coating a second photoresist layer on the surface of the second structural layer, and overlaying on the back side The process performs a window photolithography operation on the position corresponding to the alignment identification mark to obtain the alignment window.
  • performing a window photolithography operation on the position corresponding to the alignment identification mark based on a backside overlay process to obtain the alignment window includes: performing a window photolithography operation on the position corresponding to the alignment identification mark.
  • the resist layer is subjected to window exposure and development to obtain an alignment window structure;
  • the alignment window structure is the second structural layer exposed after the window exposure and development;
  • the alignment window structure is etched to obtain The alignment window.
  • performing a second photolithography operation on the second structural layer includes: exposing and developing the second photoresist layer again to obtain a second reference structure, the second reference structure being The second structural layer is exposed after the exposure and development; the second reference structure is etched to remove the remaining second photoresist layer to obtain the second nanostructure.
  • the double-sided super lens processing method further includes: aligning one side surface of the bonding substrate Spin-coating temporary bonding glue; the first surface of the substrate having the first nanostructure is temporarily bonded to the bonding substrate through the temporary bonding glue.
  • the double-sided hyperlens processing method further includes: debonding the first surface of the substrate with the first nanostructure and the bonding substrate. , the double-sided super lens is obtained.
  • debonding the first surface of the substrate with the first nanostructure from the bonding substrate includes: dissolving the temporary bonding glue.
  • arranging a first structural layer on the first surface of the substrate includes: evaporating the first structural layer on the first surface of the substrate; and arranging a second structural layer on the second surface of the substrate. , including: evaporating the second structural layer on the second surface of the substrate.
  • the substrate is a glass substrate.
  • the glass substrate includes: quartz wafer.
  • both the first structural layer and the second structural layer are made of polysilicon material.
  • the photolithography machine by performing the first photolithography operation on the first structural layer, at the same time
  • the first nanostructure and the alignment identification mark are obtained, and an alignment window is made on the surface of the second structural layer corresponding to the position of the alignment identification mark, so that the photolithography machine can align the operating surface (second surface) with the first nanostructure and the alignment identification mark.
  • micron-level alignment identification marks can be identified through the alignment window. Based on the accuracy of the photolithography machine itself, the second photolithography operation is performed and the double-layer structure is finally produced.
  • Surface metal lens by performing the first photolithography operation on the first structural layer, at the same time
  • the first nanostructure and the alignment identification mark are obtained, and an alignment window is made on the surface of the second structural layer corresponding to the position of the alignment identification mark, so that the photolithography machine can align the operating surface (second surface) with the first nanostructure and the alignment identification mark.
  • This method can break the accuracy limit of the traditional backside overlay process, improve the alignment accuracy when processing the first nanostructure and the second nanostructure to the accuracy of the photolithography machine itself, and improve the alignment accuracy of the front and back super lenses.
  • the alignment accuracy is controlled below 100nm.
  • Figure 1 shows a flow chart of a double-sided super lens processing method provided by an embodiment of the present invention
  • Figure 2 shows a schematic diagram of arranging a first structural layer on the first surface of the substrate in the double-sided hyperlens processing method provided by the embodiment of the present invention
  • Figure 3 shows a schematic diagram of the first nanostructure in the double-sided hyperlens processing method provided by the embodiment of the present invention
  • Figure 4 shows a schematic diagram of the alignment identification mark in the processing method of a double-sided super lens provided by an embodiment of the present invention
  • Figure 5 shows a schematic diagram of the arrangement of multiple alignment identification marks in the processing method of a double-sided super lens provided by an embodiment of the present invention
  • Figure 6 shows a schematic diagram of disposing a second structural layer on the second surface of the substrate in the double-sided hyperlens processing method provided by the embodiment of the present invention
  • Figure 7 shows a schematic diagram of making an alignment window in the second structural layer in the processing method of a double-sided super lens provided by an embodiment of the present invention
  • Figure 8 shows the second nanostructure in the double-sided hyperlens processing method provided by the embodiment of the present invention.
  • Figure 9 shows a flow chart of performing a first photolithography operation on the first structural layer in the processing method of a double-sided super lens provided by an embodiment of the present invention
  • Figure 10 shows a schematic diagram of disposing a first photoresist layer on the surface of the first structural layer in the double-sided super lens processing method provided by an embodiment of the present invention
  • Figure 11 shows a schematic diagram of arranging a first reference structure on the surface of the first photoresist layer in the processing method of a double-sided super lens provided by an embodiment of the present invention
  • Figure 12 shows a schematic diagram of coating a second photoresist layer on the surface of the second structural layer in the processing method of a double-sided super lens provided by an embodiment of the present invention
  • Figure 13 shows a schematic diagram of an alignment window structure being provided on the surface of the second photoresist layer in the double-sided hyperlens processing method provided by an embodiment of the present invention
  • Figure 14 shows a schematic diagram of the alignment window in the double-sided hyperlens processing method provided by the embodiment of the present invention.
  • Figure 15 shows a flow chart of performing a second photolithography operation on the second structural layer in the processing method of a double-sided super lens provided by an embodiment of the present invention
  • Figure 16 shows a schematic diagram of arranging a second reference structure on the surface of the second photoresist layer in the double-sided hyperlens processing method provided by the embodiment of the present invention
  • Figure 17 shows a schematic diagram of the second nanostructure in the double-sided hyperlens processing method provided by the embodiment of the present invention.
  • Figure 18 shows a schematic diagram of spin-coating temporary bonding glue on the bonding substrate in the double-sided super lens processing method provided by the embodiment of the present invention
  • Figure 19 shows a schematic diagram of temporary bonding using temporary bonding glue in the processing method of a double-sided super lens provided by an embodiment of the present invention.
  • first and second are used for descriptive purposes only and cannot be understood as indicating or implying relative importance or implicitly indicating the quantity of indicated technical features. Therefore, features defined as “first” and “second” may explicitly or implicitly include one or more of these features.
  • “plurality” means two or more than two, unless otherwise explicitly and specifically limited.
  • connection In the present invention, unless otherwise clearly stated and limited, the terms “installation”, “connection”, “connection”, “fixing” and other terms should be understood in a broad sense. For example, it can be a fixed connection or a detachable connection. , or integrally connected; it can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium; it can be an internal connection between two components.
  • connection connection
  • fixing and other terms should be understood in a broad sense. For example, it can be a fixed connection or a detachable connection. , or integrally connected; it can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium; it can be an internal connection between two components.
  • the specific meanings of the above terms in the present invention can be understood according to specific circumstances.
  • An embodiment of the present invention provides a method for processing a double-sided super lens. As shown in Figure 1 , the method includes the following steps 101 to 104.
  • Step 101 Set the first structural layer 21 on the first surface of the substrate 1, perform the first photolithography operation on the first structural layer 21, and obtain the first nanostructure 211 and the alignment identification mark 212; the substrate 1 is detected in the photolithography machine
  • the operating band of the device is transparent.
  • the substrate 1 has two surfaces, such as a first surface and a second surface.
  • the first surface may be the front surface of the substrate 1, and correspondingly, the second surface may be the back surface of the substrate 1; or, the first surface
  • the surface may be the back surface of the substrate 1 , and accordingly, the second surface may be the front surface of the substrate 1 , which is not limited in this embodiment of the present invention.
  • a first structural layer 21 is provided on the first surface of the substrate 1.
  • the first structural layer 21 is a material layer used to make the first nanostructure 211.
  • the material of the first structural layer 21 is a Materials with high transmittance for light in the working band (such as the working band of the photolithography machine detector).
  • the substrate 1 is transparent in the working band of the photolithography machine detector, and optionally, the substrate 1 is a glass substrate; because the working band of the photolithography machine detector used in the embodiment of the present invention can be the visible light band and/or infrared light band. Therefore, the material of the substrate 1 can be selected to have high resistance to the light in the above working band. Glass materials with high transmittance, such as crown glass, flint glass, etc., can be selected as the substrate 1; optionally, the glass substrate can include: quartz wafer, such as fused quartz (a kind of glassy quartz).
  • a quartz wafer is selected as the substrate 1, so that the substrate 1 of the double-sided hyperlens has a lower thermal expansion coefficient, a longer service life, and higher stability. Moreover, the material of the quartz wafer has a low thermal expansion coefficient under visible light.
  • the wavelength band and/or the infrared light band are transparent, and as the substrate 1, the photolithography machine detector can identify the other side through the substrate 1; in addition, the quartz wafer is also suitable for common photolithography machines.
  • the photolithography process performed on the first structural layer 21 is called a first photolithography operation.
  • the first photolithography operation is In the process of photolithography of the first structural layer 21 to obtain the first nanostructure 211, it is also necessary to obtain the alignment identification mark 212, as shown in Figures 3 and 4.
  • Figure 3 is a schematic side view of obtaining the first nanostructure 211.
  • different patterns are used in the drawings, but in fact, the first nanostructure 211 and the alignment identification mark 212 are both etched from the first structural layer 21.
  • Figure 4 is a top view of the alignment identification mark 212;
  • the alignment identification mark 212 is a mark made by a photolithography machine, which is a micron-level mark with high precision;
  • a photolithography machine which is a micron-level mark with high precision;
  • it can play a role in aligning the substrate 1 with the photolithography machine. It can include one or more cross patterns. For example, a row or a column can be set on the edge of the substrate 1.
  • the alignment identification mark 212 of the cross structure (shown in Figure 5).
  • Step 102 Set the second structural layer 22 on the second surface of the substrate 1 .
  • a method consistent with arranging the first structural layer 21 for the first surface can be used to dispose the second structural layer 22 for the second surface of the substrate 1 .
  • the second structural layer 22 is used to make
  • the material layer of the second nanostructure 221 and the second structural layer 22 can also be a material with high transmittance for light in the working wavelength band.
  • step 102 can perform step 102 after step 101, or can also perform step 102 while setting the first structural layer 21 in step 101, that is, setting corresponding structures on both surfaces of the substrate 1 at the same time. layer.
  • Step 103 Make an alignment window 10 at a position corresponding to the second structural layer 22 and the alignment identification mark 212.
  • the size of the alignment window 10 is larger than the size of the alignment identification mark 212.
  • the embodiment of the present invention can use the traditional backside overlay process to identify the area corresponding to the alignment identification mark 212 on the surface of the second structural layer 22 , and make a size update for this area.
  • a large alignment window 10 in other words, if the alignment window 10 is produced and projected onto the first surface, the first surface at the orthographic projection position will have the alignment identification mark 212; or it can also be It is considered that the orthographic projection of the alignment identification mark 212 located on the first surface does not exceed the range of the alignment window 10 , which is equivalent to the alignment identification mark 212 being included in the alignment window 10 .
  • the size of the alignment window 10 should be larger than the size (eg, area) of the alignment identification mark 212 by a certain value, such as at least greater than an accuracy of one unit. For example, if the size of the alignment identification mark 212 is 2 ⁇ m ⁇ 2 ⁇ m, the size of the produced alignment window 10 may be 3 ⁇ m ⁇ 3 ⁇ m.
  • Step 104 When the second surface is the operating surface, align through the alignment window 10 and based on the alignment identification mark 212, and perform a second photolithography operation on the second structural layer 22 to obtain the second nanostructure. 221;
  • the operating surface indicates the surface of substrate 1 currently processed by the photolithography machine.
  • the surface currently being processed by the photolithography machine is called the operating surface.
  • the orientation of the operating surface is generally upward, that is, the second surface of the substrate 1 faces upward (that is, the second surface is the operating surface).
  • the lithography machine can identify the alignment identification mark 212 located on the first surface through the alignment window 10 (located on the second surface) produced in step 103, and By aligning the alignment identification mark 212, the lithography machine and the substrate 1 can be aligned with nanometer-level precision, which is equivalent to directly improving the alignment accuracy of the first nanostructure 211 and the second nanostructure 221 to the lithography machine.
  • the second photolithography operation may be a traditional semiconductor photolithography process to obtain a second nanostructure 221 (as shown in FIG. 8 (shown) to realize the processing and production of double-sided super lenses.
  • the operating surface is the first surface.
  • the first nanostructure 211 and the alignment identification mark 212 are simultaneously obtained by performing the first photolithography operation on the first structural layer 21, and the second structural layer corresponding to the position of the alignment identification mark 212 is obtained. 22.
  • This method can break the accuracy limit of the traditional backside overlay process, improve the alignment accuracy when processing the first nanostructure and the second nanostructure to the accuracy of the photolithography machine itself, and improve The alignment accuracy of the front and back metalens, for example, is controlled to less than 100nm.
  • performing the first photolithography operation on the first structural layer 21 may include the following steps 1011-1012.
  • Step 1011 Coat the first photoresist layer 31 on the surface of the first structural layer 21, and expose and develop the first photoresist layer 31 to obtain the first reference structure; the first reference structure is after exposure and development The first structural layer 21 is exposed.
  • photoresist can be coated on the surface of the first structural layer 21 by spin coating to obtain the first photoresist layer 31 .
  • the photoresist is a kind of material used in traditional semiconductor processes. Materials that can change the solubility during the photolithography step; spin coating is the abbreviation of the spin coating method.
  • the equipment usually used is a glue dispensing machine, which is controlled by controlling the time, rotation speed, drop volume, and concentration and viscosity of the solution used.
  • the thickness of the film is controlled to make the thickness of the coated first photoresist layer 31 uniform and controllable.
  • one side surface (such as the first surface) of the substrate provided with the first photoresist layer 31 is facing upward and put into a photolithography machine for exposure and development.
  • the first surface is the operating surface that the photolithography machine currently needs to process; during the exposure and development process, the first photoresist layer 31 will be dissolved, exposing the first reference structure ;
  • the first reference structure is the first structural layer 21 corresponding to the dissolved first photoresist layer 31. In other words, the first reference structure is exposed without the first photoresist layer 31 on the surface.
  • the first structural layer 21 has a groove structure as shown in Figure 11; in addition, the exposure process includes but is not limited to ultraviolet exposure, deep ultraviolet exposure and extremely deep ultraviolet exposure.
  • Step 1012 Etch the first reference structure and remove the remaining first photoresist layer 31 to obtain the first nanostructure 211 and the alignment identification mark 212.
  • the first reference structure such as the exposed first structural layer 21
  • the first reference structure such as the exposed first structural layer 21
  • the first reference structure is etched away, and the The remaining first photoresist layer 31 on the surface of the first structural layer 21 finally obtains the first nanostructure 211 and the alignment identification mark 212 as shown in FIG. 3 (ie, the remaining first structural layer 21).
  • making the alignment window 10 at the position corresponding to the second structural layer 22 and the alignment identification mark 212 may include the following step 1031.
  • Step 1031 Coat the second photoresist layer 32 on the surface of the second structural layer 22, and perform a window photolithography operation at the corresponding position of the alignment identification mark 212 based on the backside overlay process to obtain the alignment window 10.
  • the method of coating the first photoresist layer on the surface of the first structural layer 22 may be used.
  • the second photoresist layer 32 is coated on the surface of the second structural layer 22 by the same means, such as spin coating, and the material of the second photoresist layer 32 can be the same as the material of the first photoresist layer 31 are the same; and, based on the traditional backside overlay process, the alignment identification mark 212 on the first structural layer 21 obtained in the above step 101 is identified on the surface of the second photoresist layer 32 away from the second structural layer 22, and A window photolithography operation is performed on the surface of the second photoresist layer 32 away from the second structural layer 22 at a position corresponding to the alignment identification mark 212 .
  • the window photolithography operation is an operation for obtaining the alignment window 10 process; after the window photolithography operation, the structure shown in Figure 7 can be obtained.
  • the alignment window 10 obtained by using the traditional backside overlay process has low accuracy due to the micron-level precision of the corresponding overlay process. Therefore, the embodiment of the present invention does not directly use this alignment
  • the window 10 is used as the basis for alignment, but the alignment window 10 is used to lock the truly required alignment identification mark 212.
  • the alignment identification mark 212 corresponds to micron-level accuracy, and its accuracy is relatively high. This method can process the second The alignment accuracy of the first nanostructure and the second nanostructure is improved to the accuracy of the lithography machine itself.
  • performing a window photolithography operation on the corresponding position of the alignment identification mark 212 based on the backside overlay process to obtain the alignment window 10 may include the following steps A1-A2.
  • Step A1 Perform window exposure and development on the second photoresist layer 32 at the corresponding position of the alignment identification mark 212 to obtain an alignment window structure; the alignment window structure is the second structural layer exposed after window exposure and development. twenty two.
  • the window exposure and development process performed in the embodiment of the present invention is the same as the exposure and development process performed on the first photoresist layer 31 in the above-mentioned step 1011, except that the structural layer targeted by the two processes is different from the resulting structure; window Exposure and development are operations performed on the second photoresist layer 32, and the alignment window structure can be obtained by dissolving the second photoresist layer 32 at the position corresponding to the alignment identification mark 212 (see FIG. 13 ), the alignment window structure is the second structural layer 22 corresponding to the dissolved second photoresist layer 32. In other words, the alignment window structure has no second photoresist layer 32 on the surface and is exposed.
  • the second structural layer 22 is located at the upper groove structure as shown in FIG. 13 .
  • Step A2 Etch the alignment window structure to obtain the alignment window 10.
  • the etching process performed on the alignment window structure in the embodiment of the present invention is the same as the etching process performed on the first reference structure in step 1012, that is, the alignment window structure (such as the exposed second structure) is etched away. layer 22), obtaining the alignment window 10 (ie, the exposed substrate 1) as shown in Figure 14.
  • performing the second photolithography operation on the second structural layer 22 may include the following steps 1041-1042.
  • Step 1041 Expose and develop the second photoresist layer 32 again to obtain a second reference structure.
  • the second reference structure is the second structural layer 22 exposed after being exposed and developed again.
  • the remaining second photoresist layer 32 is exposed and developed twice.
  • the structure obtained by this exposure and development is the second reference structure, in order to be able to undergo subsequent The etching process obtains the final desired second nanostructure 221.
  • the second reference structure is the second structural layer 22 corresponding to the second photoresist layer 32 that was dissolved this time.
  • the pair of second reference structures does not have the second photoresist layer 32 on the surface.
  • the second structural layer 22 exposed this time which is the groove structure located on the uppermost layer as shown in FIG. 16 .
  • Step 1042 Etch the second reference structure and remove the remaining second photoresist layer 32 to obtain the second nanostructure 221.
  • the second reference structure such as the exposed second structural layer 22
  • the second reference structure such as the exposed second structural layer 22
  • the second reference structure is etched away, and the The remaining second photoresist layer 32 on the surface of the second structural layer 22 finally obtains the second nanostructure 221 as shown in FIG. 17 (ie, the remaining second structural layer 22 after this step).
  • the operating surface needs to be replaced.
  • the operating surface is replaced from the first surface to a second surface that needs to continue processing the second nanostructure 221.
  • the existing processing technology cannot process the first nanostructure 211.
  • vacuum adsorption is used to adsorb the first surface.
  • the first surface with the first nanostructure 211 is vacuum adsorbed on the workbench, but due to the first The existence of the nanostructure 211 and the gaps on the first surface may cause the vacuum adsorption to be weak and cause vacuum leakage of the slide.
  • the embodiment of the present invention can perform the following steps B1-B2 before the above-mentioned step 103 of "making the alignment window 10 at the position corresponding to the second structural layer 22 and the alignment identification mark 212" to avoid slide leakage. Vacuum problem.
  • Step B1 Spin-coat temporary bonding glue on one side of the bonding substrate 4 .
  • the bonding substrate 4 is essentially a substrate, which can be a silicon wafer; in embodiments of the present invention, temporary bonding glue can be spin-coated on one side of the bonding substrate 4, as shown in Figure 18
  • the temporary bonding glue layer 5 shown in the material used for the temporary bonding glue may be a base resin.
  • Step B2 Temporarily bond the first surface of the substrate 1 with the first nanostructure 211 to the bonding substrate 4 through temporary bonding glue.
  • the embodiment of the present invention can bond the first surface with the first nanostructure 211 to the temporary bonding glue layer 5 composed of temporary bonding glue.
  • the temporary bonding glue can be bonded through the temporary bonding glue.
  • the first surface with the first nanostructure 211 is fixed on the bonding substrate 4 .
  • the first surface with the first nanostructure 211 is temporarily bonded to the bonding substrate 4, so that the first surface with the first nanostructure 211 is fixed, which facilitates the photolithography machine to directly process the second surface.
  • the surface (operating surface) is processed; and the temporary bonding process can also protect the first nanostructure 211, avoid the first nanostructure 211 from being contaminated and damaged, and at the same time solve the problem of vacuum leakage on the slide. .
  • the method may further include step C.
  • Step C Debonding the first surface of the substrate 1 having the first nanostructure 211 from the bonding substrate 4 to obtain a double-sided superlens.
  • debonding can be performed by heating or dissolving, and the first surface with the first nanostructure 211 is separated from the bonding substrate 4 to obtain the completed product. Double-sided metalens.
  • debonding the first surface of the substrate 1 with the first nanostructure 211 and the bonding substrate 4 includes: dissolving the temporary bonding glue; for example, a solvent that can dissolve the temporary bonding glue can be used to debond, to obtain the production Completed double-sided metalens.
  • disposing the first structural layer 21 on the first surface of the substrate 1 includes: evaporating the first structural layer 21 on the first surface of the substrate 1; disposing the second structural layer 22 on the second surface of the substrate 1 includes: : The second structural layer 22 is evaporated on the second surface of the substrate 1 .
  • the first structural layer 21 and the second structural layer 22 can be respectively provided on both sides of the substrate 1 (such as the first surface and the second surface) by evaporation; optionally, the first Both the structural layer 21 and the second structural layer 22 are made of polysilicon material.
  • the first structural layer 21 and the second structural layer 22 may be evaporated using polysilicon materials.
  • the polysilicon materials may include: titanium oxide, silicon nitride, fused quartz, aluminum oxide, gallium nitride, gallium phosphide, Amorphous silicon, crystalline silicon or hydrogenated amorphous silicon, etc.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)

Abstract

The present invention provides a double-sided superlens processing method. The method comprises: providing a first structural layer on a first surface of a substrate, and performing a first photolithography operation on the first structural layer to obtain a first nanostructure and an alignment identification mark; providing a second structural layer on a second surface of the substrate; manufacturing an alignment window at the position of the second structural layer corresponding to the alignment identification mark; and performing alignment on the basis of the alignment identification mark, and performing a second photolithography operation on the second structural layer to obtain a second nanostructure. According to the double-sided superlens processing method provided in the embodiments of the present invention, on the basis of the alignment identification mark obtained from the first photolithography operation and the alignment window at the position of the second structural layer corresponding to the alignment identification mark, the alignment identification mark is identified through the alignment window, alignment is performed, and the second photolithography operation is performed. The method breaks the accuracy limits of conventional backside overlay processes, so that the alignment accuracy in the process of processing the first nanostructure and the second nanostructure is increased to the accuracy of a photolithography machine.

Description

一种双面超透镜的加工方法A kind of processing method of double-sided super lens 技术领域Technical field
本发明涉及超透镜加工技术领域,具体而言,涉及一种双面超透镜的加工方法。The present invention relates to the technical field of super lens processing, and specifically, to a processing method of a double-sided super lens.
背景技术Background technique
目前,制造双面超透镜(如在同一晶圆的正面和背面分别具有不同纳米结构的超透镜)通常采用接触式曝光背面套刻的工艺,在加工得到某晶圆正面的纳米结构后,在背面设置套刻标记,通过光刻机探测器识别晶圆的背面,以识别该套刻标记,并进行背面的纳米结构的加工,最终得到该双面超透镜。At present, the manufacturing of double-sided metalens (such as metalens with different nanostructures on the front and back of the same wafer) usually uses a contact exposure backside overlay process. After processing the nanostructure on the front of a certain wafer, An overlay mark is set on the back side, and the back side of the wafer is identified through a photolithography machine detector to identify the overlay mark, and the nanostructure on the back side is processed to finally obtain the double-sided super lens.
但是,该种加工方法的精度受限于传统套刻工艺的精度,其精度为正负1μm,很难满足高精度的双面超透镜的对准要求。However, the accuracy of this processing method is limited by the accuracy of the traditional overlay process, which is plus or minus 1 μm, which is difficult to meet the alignment requirements of high-precision double-sided metalens.
发明内容Contents of the invention
为解决上述问题,本发明实施例的目的在于提供一种双面超透镜的加工方法。In order to solve the above problems, the purpose of embodiments of the present invention is to provide a processing method of a double-sided super lens.
本发明实施例提供了一种双面超透镜的加工方法,包括:在基底的第一表面设置第一结构层,对所述第一结构层执行第一光刻操作,得到第一纳米结构和对准识别标记;所述基底在光刻机探测器的工作波段透明;在所述基底的第二表面设置第二结构层;在所述第二结构层与所述对准识别标记对应位置处制作对准窗口,所述对准窗口的尺寸大于所述对准识别标记的尺寸;在所述第二表面为操作表面的情况下,透过所述对准窗口并基于所述对准识别标记进行对准,并对所述第二结构层执行第二光刻操作,得到第二纳米结构;所述操作表面表示所述基底当前被光刻机处理的表面。Embodiments of the present invention provide a method for processing a double-sided super lens, which includes: arranging a first structural layer on the first surface of a substrate, performing a first photolithography operation on the first structural layer, and obtaining a first nanostructure and Alignment identification mark; the substrate is transparent in the working band of the photolithography machine detector; a second structural layer is provided on the second surface of the substrate; and the second structural layer is located at a position corresponding to the alignment identification mark. Make an alignment window, the size of the alignment window is larger than the size of the alignment identification mark; when the second surface is an operating surface, through the alignment window and based on the alignment identification mark Alignment is performed, and a second photolithography operation is performed on the second structural layer to obtain a second nanostructure; the operation surface represents the surface of the substrate currently processed by the photolithography machine.
可选地,对所述第一结构层执行第一光刻操作,包括:在所述第一结构层表面涂覆第一光刻胶层,并对所述第一光刻胶层进行曝光和显影,得到第一参考结构;所述第一参考结构为经过所述曝光和显影后暴露的所述第一结构层;对所述第一参考结构刻蚀,去除残留的所述第一光刻胶层,得到所述第一纳米结构和所 述对准识别标记。Optionally, performing a first photolithography operation on the first structural layer includes: coating a first photoresist layer on the surface of the first structural layer, and exposing and exposing the first photoresist layer. Develop to obtain a first reference structure; the first reference structure is the first structural layer exposed after the exposure and development; etching the first reference structure to remove the remaining first photolithography glue layer to obtain the first nanostructure and the Alignment identification mark.
可选地,在所述第二结构层与所述对准识别标记对应位置处制作对准窗口,包括:在所述第二结构层表面涂覆第二光刻胶层,并基于背面套刻工艺对所述对准识别标记对应位置处执行窗口光刻操作,得到所述对准窗口。Optionally, making an alignment window at a position corresponding to the second structural layer and the alignment identification mark includes: coating a second photoresist layer on the surface of the second structural layer, and overlaying on the back side The process performs a window photolithography operation on the position corresponding to the alignment identification mark to obtain the alignment window.
可选地,基于背面套刻工艺对所述对准识别标记对应位置处执行窗口光刻操作,得到所述对准窗口,包括:对所述对准识别标记对应位置处的所述第二光刻胶层进行窗口曝光和显影,得到对准窗口结构;所述对准窗口结构为经过所述窗口曝光和显影后暴露的所述第二结构层;对所述对准窗口结构刻蚀,得到所述对准窗口。Optionally, performing a window photolithography operation on the position corresponding to the alignment identification mark based on a backside overlay process to obtain the alignment window includes: performing a window photolithography operation on the position corresponding to the alignment identification mark. The resist layer is subjected to window exposure and development to obtain an alignment window structure; the alignment window structure is the second structural layer exposed after the window exposure and development; the alignment window structure is etched to obtain The alignment window.
可选地,对所述第二结构层执行第二光刻操作,包括:对所述第二光刻胶层再次进行曝光和显影,得到第二参考结构,所述第二参考结构为再次经过所述曝光和显影后暴露的所述第二结构层;对所述第二参考结构刻蚀,去除残留的所述第二光刻胶层,得到所述第二纳米结构。Optionally, performing a second photolithography operation on the second structural layer includes: exposing and developing the second photoresist layer again to obtain a second reference structure, the second reference structure being The second structural layer is exposed after the exposure and development; the second reference structure is etched to remove the remaining second photoresist layer to obtain the second nanostructure.
可选地,在所述在所述第二结构层与所述对准识别标记对应位置处制作对准窗口之前,该双面超透镜的加工方法还包括:对键合衬底的一侧表面旋涂临时键合胶水;将所述基底具有所述第一纳米结构的第一表面,通过所述临时键合胶水与所述键合衬底进行临时键合。Optionally, before making an alignment window at a position corresponding to the second structural layer and the alignment identification mark, the double-sided super lens processing method further includes: aligning one side surface of the bonding substrate Spin-coating temporary bonding glue; the first surface of the substrate having the first nanostructure is temporarily bonded to the bonding substrate through the temporary bonding glue.
可选地,在所述得到所述第二纳米结构之后,该双面超透镜的加工方法还包括:对所述基底具有所述第一纳米结构的第一表面与所述键合衬底解键合,得到所述双面超透镜。Optionally, after obtaining the second nanostructure, the double-sided hyperlens processing method further includes: debonding the first surface of the substrate with the first nanostructure and the bonding substrate. , the double-sided super lens is obtained.
可选地,对所述基底具有所述第一纳米结构的第一表面与所述键合衬底解键合,包括:溶解所述临时键合胶水。Optionally, debonding the first surface of the substrate with the first nanostructure from the bonding substrate includes: dissolving the temporary bonding glue.
可选地,在基底的第一表面设置第一结构层,包括:在所述基底的第一表面蒸镀所述第一结构层;所述在所述基底的第二表面设置第二结构层,包括:在所述基底的第二表面蒸镀所述第二结构层。Optionally, arranging a first structural layer on the first surface of the substrate includes: evaporating the first structural layer on the first surface of the substrate; and arranging a second structural layer on the second surface of the substrate. , including: evaporating the second structural layer on the second surface of the substrate.
可选地,基底为玻璃基底。Optionally, the substrate is a glass substrate.
可选地,玻璃基底包括:石英晶圆。Optionally, the glass substrate includes: quartz wafer.
可选地,第一结构层与所述第二结构层均为多晶硅材料。Optionally, both the first structural layer and the second structural layer are made of polysilicon material.
本发明实施例上述提供的方案中,通过对第一结构层进行第一光刻操作,同 时得到第一纳米结构和对准识别标记,并在与该对准识别标记位置处相对应的第二结构层表面制作对准窗口,使得光刻机在对操作表面(第二表面)的第二结构层进行第二光刻操作之前,可以透过该对准窗口识别到微米级别的对准识别标记,基于该光刻机本身的精度对准并进行第二光刻操作,最终制作得到双面超透镜。该方法可以打破传统背面套刻工艺的精度限制,将加工第一纳米结构和第二纳米结构时的对准精度提升至光刻机本身的精度,提高了正反两面超透镜的对准精度,例如,将对准精度控制在100nm以下。In the solution provided above in the embodiment of the present invention, by performing the first photolithography operation on the first structural layer, at the same time The first nanostructure and the alignment identification mark are obtained, and an alignment window is made on the surface of the second structural layer corresponding to the position of the alignment identification mark, so that the photolithography machine can align the operating surface (second surface) with the first nanostructure and the alignment identification mark. Before the second photolithography operation is performed on the second structural layer, micron-level alignment identification marks can be identified through the alignment window. Based on the accuracy of the photolithography machine itself, the second photolithography operation is performed and the double-layer structure is finally produced. Surface metal lens. This method can break the accuracy limit of the traditional backside overlay process, improve the alignment accuracy when processing the first nanostructure and the second nanostructure to the accuracy of the photolithography machine itself, and improve the alignment accuracy of the front and back super lenses. For example, the alignment accuracy is controlled below 100nm.
为使本发明的上述目的、特征和优点能更明显易懂,下文特举较佳实施例,并配合所附附图,作详细说明如下。In order to make the above-mentioned objects, features and advantages of the present invention more obvious and easy to understand, preferred embodiments are given below and described in detail with reference to the accompanying drawings.
附图说明Description of drawings
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to explain the embodiments of the present invention or the technical solutions in the prior art more clearly, the drawings needed to be used in the description of the embodiments or the prior art will be briefly introduced below. Obviously, the drawings in the following description are only These are some embodiments of the present invention. For those of ordinary skill in the art, other drawings can be obtained based on these drawings without exerting creative efforts.
图1示出了本发明实施例所提供的一种双面超透镜的加工方法的流程图;Figure 1 shows a flow chart of a double-sided super lens processing method provided by an embodiment of the present invention;
图2示出了本发明实施例所提供的双面超透镜的加工方法中,在基底的第一表面设置第一结构层的示意图;Figure 2 shows a schematic diagram of arranging a first structural layer on the first surface of the substrate in the double-sided hyperlens processing method provided by the embodiment of the present invention;
图3示出了本发明实施例所提供的双面超透镜的加工方法中,第一纳米结构的示意图;Figure 3 shows a schematic diagram of the first nanostructure in the double-sided hyperlens processing method provided by the embodiment of the present invention;
图4示出了本发明实施例所提供的双面超透镜的加工方法中,对准识别标记的示意图;Figure 4 shows a schematic diagram of the alignment identification mark in the processing method of a double-sided super lens provided by an embodiment of the present invention;
图5示出了本发明实施例所提供的双面超透镜的加工方法中,多个对准识别标记的排布示意图;Figure 5 shows a schematic diagram of the arrangement of multiple alignment identification marks in the processing method of a double-sided super lens provided by an embodiment of the present invention;
图6示出了本发明实施例所提供的双面超透镜的加工方法中,在基底的第二表面设置第二结构层的示意图;Figure 6 shows a schematic diagram of disposing a second structural layer on the second surface of the substrate in the double-sided hyperlens processing method provided by the embodiment of the present invention;
图7示出了本发明实施例所提供的双面超透镜的加工方法中,在第二结构层制作对准窗口的示意图;Figure 7 shows a schematic diagram of making an alignment window in the second structural layer in the processing method of a double-sided super lens provided by an embodiment of the present invention;
图8示出了本发明实施例所提供的双面超透镜的加工方法中,第二纳米结构 的示意图;Figure 8 shows the second nanostructure in the double-sided hyperlens processing method provided by the embodiment of the present invention. schematic diagram;
图9示出了本发明实施例所提供的双面超透镜的加工方法中,对第一结构层执行第一光刻操作的流程图;Figure 9 shows a flow chart of performing a first photolithography operation on the first structural layer in the processing method of a double-sided super lens provided by an embodiment of the present invention;
图10示出了本发明实施例所提供的双面超透镜的加工方法中,在第一结构层表面设置第一光刻胶层的示意图;Figure 10 shows a schematic diagram of disposing a first photoresist layer on the surface of the first structural layer in the double-sided super lens processing method provided by an embodiment of the present invention;
图11示出了本发明实施例所提供的双面超透镜的加工方法中,在第一光刻胶层表面设置第一参考结构的示意图;Figure 11 shows a schematic diagram of arranging a first reference structure on the surface of the first photoresist layer in the processing method of a double-sided super lens provided by an embodiment of the present invention;
图12示出了本发明实施例所提供的双面超透镜的加工方法中,在第二结构层表面涂覆第二光刻胶层的示意图;Figure 12 shows a schematic diagram of coating a second photoresist layer on the surface of the second structural layer in the processing method of a double-sided super lens provided by an embodiment of the present invention;
图13示出了本发明实施例所提供的双面超透镜的加工方法中,在第二光刻胶层表面设置对准窗口结构的示意图;Figure 13 shows a schematic diagram of an alignment window structure being provided on the surface of the second photoresist layer in the double-sided hyperlens processing method provided by an embodiment of the present invention;
图14示出了本发明实施例所提供的双面超透镜的加工方法中,对准窗口的示意图;Figure 14 shows a schematic diagram of the alignment window in the double-sided hyperlens processing method provided by the embodiment of the present invention;
图15示出了本发明实施例所提供的双面超透镜的加工方法中,对第二结构层执行第二光刻操作的流程图;Figure 15 shows a flow chart of performing a second photolithography operation on the second structural layer in the processing method of a double-sided super lens provided by an embodiment of the present invention;
图16示出了本发明实施例所提供的双面超透镜的加工方法中,在第二光刻胶层表面设置第二参考结构的示意图;Figure 16 shows a schematic diagram of arranging a second reference structure on the surface of the second photoresist layer in the double-sided hyperlens processing method provided by the embodiment of the present invention;
图17示出了本发明实施例所提供的双面超透镜的加工方法中,第二纳米结构的示意图;Figure 17 shows a schematic diagram of the second nanostructure in the double-sided hyperlens processing method provided by the embodiment of the present invention;
图18示出了本发明实施例所提供的双面超透镜的加工方法中,在键合衬底旋涂临时键合胶水的示意图;Figure 18 shows a schematic diagram of spin-coating temporary bonding glue on the bonding substrate in the double-sided super lens processing method provided by the embodiment of the present invention;
图19示出了本发明实施例所提供的双面超透镜的加工方法中,通过临时键合胶水进行临时键合的示意图。Figure 19 shows a schematic diagram of temporary bonding using temporary bonding glue in the processing method of a double-sided super lens provided by an embodiment of the present invention.
图标:
1-基底、21-第一结构层、22-第二结构层、31-第一光刻胶层、32-第二光刻胶
层、211-第一纳米结构、212-对准识别标记、221-第二纳米结构、10-对准窗口、4-键合衬底、5-临时键合胶水层。
icon:
1-Substrate, 21-First structural layer, 22-Second structural layer, 31-First photoresist layer, 32-Second photoresist layer, 211-First nanostructure, 212-Alignment identification mark, 221-Second nanostructure, 10-Alignment window, 4-Bonding substrate, 5-Temporary bonding glue layer.
具体实施方式 Detailed ways
在本发明的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“长度”、“宽度”、“厚度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”“内”、“外”、“顺时针”、“逆时针”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In the description of the present invention, it should be understood that the terms "center", "longitudinal", "transverse", "length", "width", "thickness", "upper", "lower", "front", " The directions or positions indicated by "back", "left", "right", "vertical", "horizontal", "top", "bottom", "inside", "outside", "clockwise", "counterclockwise" etc. The relationship is based on the orientation or positional relationship shown in the drawings, which is only for the convenience of describing the present invention and simplifying the description, and does not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore It should not be construed as a limitation of the present invention.
此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征。在本发明的描述中,“多个”的含义是两个或两个以上,除非另有明确具体的限定。In addition, the terms “first” and “second” are used for descriptive purposes only and cannot be understood as indicating or implying relative importance or implicitly indicating the quantity of indicated technical features. Therefore, features defined as "first" and "second" may explicitly or implicitly include one or more of these features. In the description of the present invention, "plurality" means two or more than two, unless otherwise explicitly and specifically limited.
在本发明中,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”、“固定”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本发明中的具体含义。In the present invention, unless otherwise clearly stated and limited, the terms "installation", "connection", "connection", "fixing" and other terms should be understood in a broad sense. For example, it can be a fixed connection or a detachable connection. , or integrally connected; it can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium; it can be an internal connection between two components. For those of ordinary skill in the art, the specific meanings of the above terms in the present invention can be understood according to specific circumstances.
本发明实施例提供了一种双面超透镜的加工方法,参见图1所示,该方法包括以下步骤101-步骤104。An embodiment of the present invention provides a method for processing a double-sided super lens. As shown in Figure 1 , the method includes the following steps 101 to 104.
步骤101:在基底1的第一表面设置第一结构层21,对第一结构层21执行第一光刻操作,得到第一纳米结构211和对准识别标记212;基底1在光刻机探测器的工作波段透明。Step 101: Set the first structural layer 21 on the first surface of the substrate 1, perform the first photolithography operation on the first structural layer 21, and obtain the first nanostructure 211 and the alignment identification mark 212; the substrate 1 is detected in the photolithography machine The operating band of the device is transparent.
本发明实施例中,基底1具有两个表面,如第一表面和第二表面,该第一表面可以是基底1的正面,相应地,第二表面可以是基底1的背面;或者,第一表面可以是基底1的背面,相应地,第二表面可以是基底1的正面,本发明实施例对此不做限定。参见图2所示,针对基底1的第一表面设置第一结构层21,该第一结构层21是用来制作第一纳米结构211的材料层,该第一结构层21的材料是一种对工作波段(如光刻机探测器的工作波段)的光具有高透过率的材料。本发明实施例中,基底1在光刻机探测器的工作波段透明,可选地,该基底1为玻璃基底;由于本发明实施例所采用的光刻机探测器的工作波段可以是可见光波段和/或红外光波段,因此,该基底1的材料可以选用对上述工作波段的光具有高 透过率的玻璃材料,例如,可以选用冕牌玻璃、火石玻璃等作为该基底1;可选地,该玻璃基底可以包括:石英晶圆,如熔融石英(一种玻璃状的石英)。本发明实施例选用石英晶圆作为基底1,使该双面超透镜的基底1具有较低的热膨胀系数和较长的使用寿命,稳定性也更高,并且,石英晶圆这种材料在可见光波段和/或红外光波段透明,其作为基底1能够令光刻机探测器透过该基底1识别到其另一侧;此外,石英晶圆也比较适用于常见的光刻机。In the embodiment of the present invention, the substrate 1 has two surfaces, such as a first surface and a second surface. The first surface may be the front surface of the substrate 1, and correspondingly, the second surface may be the back surface of the substrate 1; or, the first surface The surface may be the back surface of the substrate 1 , and accordingly, the second surface may be the front surface of the substrate 1 , which is not limited in this embodiment of the present invention. As shown in Figure 2, a first structural layer 21 is provided on the first surface of the substrate 1. The first structural layer 21 is a material layer used to make the first nanostructure 211. The material of the first structural layer 21 is a Materials with high transmittance for light in the working band (such as the working band of the photolithography machine detector). In the embodiment of the present invention, the substrate 1 is transparent in the working band of the photolithography machine detector, and optionally, the substrate 1 is a glass substrate; because the working band of the photolithography machine detector used in the embodiment of the present invention can be the visible light band and/or infrared light band. Therefore, the material of the substrate 1 can be selected to have high resistance to the light in the above working band. Glass materials with high transmittance, such as crown glass, flint glass, etc., can be selected as the substrate 1; optionally, the glass substrate can include: quartz wafer, such as fused quartz (a kind of glassy quartz). In the embodiment of the present invention, a quartz wafer is selected as the substrate 1, so that the substrate 1 of the double-sided hyperlens has a lower thermal expansion coefficient, a longer service life, and higher stability. Moreover, the material of the quartz wafer has a low thermal expansion coefficient under visible light. The wavelength band and/or the infrared light band are transparent, and as the substrate 1, the photolithography machine detector can identify the other side through the substrate 1; in addition, the quartz wafer is also suitable for common photolithography machines.
本发明实施例将针对第一结构层21所进行的光刻处理过程称为第一光刻操作,该第一光刻操作相比于传统的光刻工艺而言,该第一光刻操作在对第一结构层21光刻得到第一纳米结构211的过程中,还需要得到对准识别标记212,如图3和图4所示,图3为得到第一纳米结构211的侧视示意图,其中,为了方便区分第一纳米结构211和对准识别标记212,附图中采用了不同的图案表示,但实际上第一纳米结构211和对准识别标记212均为第一结构层21刻蚀得到的结构,二者的材料相同;图4为该对准识别标记212的俯视示意图;该对准识别标记212是由光刻机制作的标记,其是一种微米级别的标记,精度高;在后续加工该基底1的第二表面的过程中可以起到将基底1与光刻机对准的作用,其可以包括一个或多个十字图案,例如,可以在基底1的边缘设置一行或一列十字结构的对准识别标记212(如图5所示)。In the embodiment of the present invention, the photolithography process performed on the first structural layer 21 is called a first photolithography operation. Compared with the traditional photolithography process, the first photolithography operation is In the process of photolithography of the first structural layer 21 to obtain the first nanostructure 211, it is also necessary to obtain the alignment identification mark 212, as shown in Figures 3 and 4. Figure 3 is a schematic side view of obtaining the first nanostructure 211. Among them, in order to easily distinguish the first nanostructure 211 and the alignment identification mark 212, different patterns are used in the drawings, but in fact, the first nanostructure 211 and the alignment identification mark 212 are both etched from the first structural layer 21. The obtained structures are made of the same material; Figure 4 is a top view of the alignment identification mark 212; the alignment identification mark 212 is a mark made by a photolithography machine, which is a micron-level mark with high precision; During the subsequent processing of the second surface of the substrate 1, it can play a role in aligning the substrate 1 with the photolithography machine. It can include one or more cross patterns. For example, a row or a column can be set on the edge of the substrate 1. The alignment identification mark 212 of the cross structure (shown in Figure 5).
步骤102:在基底1的第二表面设置第二结构层22。Step 102: Set the second structural layer 22 on the second surface of the substrate 1 .
其中,如图6所示,可以采用与针对第一表面设置第一结构层21相一致的方法,针对基底1的第二表面设置第二结构层22,该第二结构层22是用来制作第二纳米结构221的材料层,该第二结构层22的材料同样也可以是一种对于工作波段的光具有高透过率的材料。Among them, as shown in FIG. 6 , a method consistent with arranging the first structural layer 21 for the first surface can be used to dispose the second structural layer 22 for the second surface of the substrate 1 . The second structural layer 22 is used to make The material layer of the second nanostructure 221 and the second structural layer 22 can also be a material with high transmittance for light in the working wavelength band.
需要说明的是,本发明实施例可以在步骤101之后执行步骤102,或者,也可以在步骤101设置第一结构层21的同时执行步骤102,即同时对基底1的两个表面设置相应的结构层。It should be noted that the embodiment of the present invention can perform step 102 after step 101, or can also perform step 102 while setting the first structural layer 21 in step 101, that is, setting corresponding structures on both surfaces of the substrate 1 at the same time. layer.
步骤103:在第二结构层22与对准识别标记212对应位置处制作对准窗口10,对准窗口10的尺寸大于对准识别标记212的尺寸。Step 103: Make an alignment window 10 at a position corresponding to the second structural layer 22 and the alignment identification mark 212. The size of the alignment window 10 is larger than the size of the alignment identification mark 212.
参见图7所示,本发明实施例可以采用传统的背面套刻工艺,在该第二结构层22表面识别出与对准识别标记212相对应的区域,并针对该区域制作尺寸更 大的对准窗口10;换句话说,制作得到的对准窗口10,若将其正投影在第一表面上,该正投影位置处的第一表面具有该对准识别标记212;或者也可以认为,位于第一表面的对准识别标记212,其在第二表面的正投影不超出该对准窗口10的范围,相当于该对准识别标记212包含在该对准窗口10中。其中,由于本步骤中所得到的对准窗口10只用来表示对准识别标记212的大致位置,且传统的背面套刻工艺的套刻精度为正负1μm,因此,该对准窗口10尺寸(如面积)应比该对准识别标记212的尺寸(如面积)大一定数值,如至少大于一个单位的精度。例如,对准识别标记212的大小是2μm×2μm,则制作得到的对准窗口10的大小可以是3μm×3μm。As shown in FIG. 7 , the embodiment of the present invention can use the traditional backside overlay process to identify the area corresponding to the alignment identification mark 212 on the surface of the second structural layer 22 , and make a size update for this area. A large alignment window 10; in other words, if the alignment window 10 is produced and projected onto the first surface, the first surface at the orthographic projection position will have the alignment identification mark 212; or it can also be It is considered that the orthographic projection of the alignment identification mark 212 located on the first surface does not exceed the range of the alignment window 10 , which is equivalent to the alignment identification mark 212 being included in the alignment window 10 . Among them, since the alignment window 10 obtained in this step is only used to represent the approximate position of the alignment identification mark 212, and the overlay accuracy of the traditional backside overlay process is plus or minus 1 μm, therefore, the size of the alignment window 10 (eg, area) should be larger than the size (eg, area) of the alignment identification mark 212 by a certain value, such as at least greater than an accuracy of one unit. For example, if the size of the alignment identification mark 212 is 2 μm×2 μm, the size of the produced alignment window 10 may be 3 μm×3 μm.
步骤104:在第二表面为操作表面的情况下,透过对准窗口10并基于对准识别标记212进行对准,并对第二结构层22执行第二光刻操作,得到第二纳米结构221;操作表面表示基底1当前被光刻机处理的表面。Step 104: When the second surface is the operating surface, align through the alignment window 10 and based on the alignment identification mark 212, and perform a second photolithography operation on the second structural layer 22 to obtain the second nanostructure. 221; The operating surface indicates the surface of substrate 1 currently processed by the photolithography machine.
本发明实施例将光刻机当前正在处理的表面称作操作表面,该操作表面的朝向一般是向上的,也就是说,在该基底1的第二表面朝上(即第二表面为操作表面)的情况下(如图7所示),该光刻机可以通过上述步骤103所制作得到的对准窗口10(位于第二表面),识别到位于第一表面的对准识别标记212,并通过对准该对准识别标记212,使光刻机与该基底1实现纳米级别的精度对准,相当于将第一纳米结构211和第二纳米结构221的对准精度直接提高到了光刻机本身的精度;并基于对准后的第二结构层22执行第二光刻操作,例如,该第二光刻操作可以是传统的半导体光刻工艺,得到第二纳米结构221(如图8所示),实现双面超透镜的加工制作。本领域技术人员可以理解,在光刻机执行第一光刻操作的情况下,操作表面是第一表面。In the embodiment of the present invention, the surface currently being processed by the photolithography machine is called the operating surface. The orientation of the operating surface is generally upward, that is, the second surface of the substrate 1 faces upward (that is, the second surface is the operating surface). ) (as shown in Figure 7), the lithography machine can identify the alignment identification mark 212 located on the first surface through the alignment window 10 (located on the second surface) produced in step 103, and By aligning the alignment identification mark 212, the lithography machine and the substrate 1 can be aligned with nanometer-level precision, which is equivalent to directly improving the alignment accuracy of the first nanostructure 211 and the second nanostructure 221 to the lithography machine. its own accuracy; and perform a second photolithography operation based on the aligned second structural layer 22. For example, the second photolithography operation may be a traditional semiconductor photolithography process to obtain a second nanostructure 221 (as shown in FIG. 8 (shown) to realize the processing and production of double-sided super lenses. Those skilled in the art can understand that when the photolithography machine performs the first photolithography operation, the operating surface is the first surface.
本发明实施例通过对第一结构层21进行第一光刻操作,同时得到第一纳米结构211和对准识别标记212,并在与该对准识别标记212位置处相对应的第二结构层22制作对准窗口10,使得光刻机在对操作表面(第二表面)的第二结构层22进行第二光刻操作之前,可以透过该对准窗口10识别到位置精度是纳米级别的对准识别标记212,基于该光刻机本身的精度对准并进行第二光刻操作,最终制作得到双面超透镜。该方法可以打破传统背面套刻工艺的精度限制,将加工第一纳米结构和第二纳米结构时的对准精度提升至光刻机本身的精度,提高了 正反两面超透镜的对准精度,例如,将对准精度控制在100nm以下。In the embodiment of the present invention, the first nanostructure 211 and the alignment identification mark 212 are simultaneously obtained by performing the first photolithography operation on the first structural layer 21, and the second structural layer corresponding to the position of the alignment identification mark 212 is obtained. 22. Make the alignment window 10 so that the photolithography machine can identify through the alignment window 10 that the position accuracy is nanometer level before performing the second photolithography operation on the second structural layer 22 of the operating surface (second surface). Align the identification marks 212, align based on the accuracy of the photolithography machine itself, and perform a second photolithography operation to finally produce a double-sided super lens. This method can break the accuracy limit of the traditional backside overlay process, improve the alignment accuracy when processing the first nanostructure and the second nanostructure to the accuracy of the photolithography machine itself, and improve The alignment accuracy of the front and back metalens, for example, is controlled to less than 100nm.
可选地,参见图9所示,对第一结构层21执行第一光刻操作可以包括以下步骤1011-1012。Optionally, referring to FIG. 9 , performing the first photolithography operation on the first structural layer 21 may include the following steps 1011-1012.
步骤1011:在第一结构层21表面涂覆第一光刻胶层31,并对第一光刻胶层31进行曝光和显影,得到第一参考结构;第一参考结构为经过曝光和显影后暴露的第一结构层21。Step 1011: Coat the first photoresist layer 31 on the surface of the first structural layer 21, and expose and develop the first photoresist layer 31 to obtain the first reference structure; the first reference structure is after exposure and development The first structural layer 21 is exposed.
参见图10所示,本发明实施例可以采用旋涂的方式在第一结构层21表面涂覆光刻胶,得到第一光刻胶层31;该光刻胶是一种在传统半导体工艺的光刻步骤下,可以改变溶解度的材料;旋涂即为旋转涂抹法的简称,通常采用的设备为匀胶机,通过控制匀胶的时间、转速、滴液量以及所用溶液的浓度、粘度来控制成膜的厚度,使涂覆的第一光刻胶层31的厚度均匀且可控。其中,将设置有第一光刻胶层31的基底的一侧表面(如第一表面)朝上并放入光刻机中对其进行曝光和显影,需要说明的是,此时因该第一表面朝上,因此该第一表面为该光刻机当前需要进行处理的操作表面;在该曝光和显影过程中,该第一光刻胶层31将会被溶解,暴露出第一参考结构;该第一参考结构为被溶掉的第一光刻胶层31所对应的第一结构层21,换句话说,该第一参考结构是表面没有第一光刻胶层31从而暴露出的第一结构层21,如图11中示出的凹槽结构;此外,该曝光过程包括但不限于紫外线曝光、深紫外线曝光和极深紫外线曝光。As shown in FIG. 10 , according to the embodiment of the present invention, photoresist can be coated on the surface of the first structural layer 21 by spin coating to obtain the first photoresist layer 31 . The photoresist is a kind of material used in traditional semiconductor processes. Materials that can change the solubility during the photolithography step; spin coating is the abbreviation of the spin coating method. The equipment usually used is a glue dispensing machine, which is controlled by controlling the time, rotation speed, drop volume, and concentration and viscosity of the solution used. The thickness of the film is controlled to make the thickness of the coated first photoresist layer 31 uniform and controllable. Among them, one side surface (such as the first surface) of the substrate provided with the first photoresist layer 31 is facing upward and put into a photolithography machine for exposure and development. It should be noted that at this time, because of the One surface faces upward, so the first surface is the operating surface that the photolithography machine currently needs to process; during the exposure and development process, the first photoresist layer 31 will be dissolved, exposing the first reference structure ; The first reference structure is the first structural layer 21 corresponding to the dissolved first photoresist layer 31. In other words, the first reference structure is exposed without the first photoresist layer 31 on the surface. The first structural layer 21 has a groove structure as shown in Figure 11; in addition, the exposure process includes but is not limited to ultraviolet exposure, deep ultraviolet exposure and extremely deep ultraviolet exposure.
步骤1012:对第一参考结构刻蚀,去除残留的第一光刻胶层31,得到第一纳米结构211和对准识别标记212。Step 1012: Etch the first reference structure and remove the remaining first photoresist layer 31 to obtain the first nanostructure 211 and the alignment identification mark 212.
在本发明实施例中,通过对第一参考结构(如暴露出的第一结构层21)进行刻蚀,即刻蚀掉该第一参考结构(如暴露出的第一结构层21),并去除剩余的第一结构层21表面的第一光刻胶层31,最终得到如图3所示第一纳米结构211以及对准识别标记212(即剩余的第一结构层21)。In the embodiment of the present invention, by etching the first reference structure (such as the exposed first structural layer 21), the first reference structure (such as the exposed first structural layer 21) is etched away, and the The remaining first photoresist layer 31 on the surface of the first structural layer 21 finally obtains the first nanostructure 211 and the alignment identification mark 212 as shown in FIG. 3 (ie, the remaining first structural layer 21).
可选地,在第二结构层22与对准识别标记212对应位置处制作对准窗口10可以包括以下步骤1031。Optionally, making the alignment window 10 at the position corresponding to the second structural layer 22 and the alignment identification mark 212 may include the following step 1031.
步骤1031:在第二结构层22表面涂覆第二光刻胶层32,并基于背面套刻工艺对该对准识别标记212对应位置处执行窗口光刻操作,得到对准窗口10。Step 1031: Coat the second photoresist layer 32 on the surface of the second structural layer 22, and perform a window photolithography operation at the corresponding position of the alignment identification mark 212 based on the backside overlay process to obtain the alignment window 10.
其中,参见图12所示,可以采用与在第一结构层22表面涂覆第一光刻胶层 31相同的手段,如旋涂的方式,在第二结构层22表面涂覆第二光刻胶层32,且该第二光刻胶层32的材料可以与第一光刻胶层31的材料相同;并且,基于传统的背面套刻工艺,在第二光刻胶层32远离第二结构层22的表面识别出上述步骤101中得到的位于第一结构层21的对准识别标记212,并在该第二光刻胶层32远离第二结构层22的表面与该对准识别标记212相对应的位置处进行窗口光刻操作,该窗口光刻操作是用于得到对准窗口10的操作工艺;经该窗口光刻操作后,可以得到如图7所示的结构。Among them, as shown in FIG. 12 , the method of coating the first photoresist layer on the surface of the first structural layer 22 may be used. 31 The second photoresist layer 32 is coated on the surface of the second structural layer 22 by the same means, such as spin coating, and the material of the second photoresist layer 32 can be the same as the material of the first photoresist layer 31 are the same; and, based on the traditional backside overlay process, the alignment identification mark 212 on the first structural layer 21 obtained in the above step 101 is identified on the surface of the second photoresist layer 32 away from the second structural layer 22, and A window photolithography operation is performed on the surface of the second photoresist layer 32 away from the second structural layer 22 at a position corresponding to the alignment identification mark 212 . The window photolithography operation is an operation for obtaining the alignment window 10 process; after the window photolithography operation, the structure shown in Figure 7 can be obtained.
本发明实施例中,采用传统的背面套刻工艺所得到的对准窗口10,由于其对应套刻工艺所具有的微米级别精度,精度较低,因此,本发明实施例并非直接以该对准窗口10作为对准的依据,而是利用该对准窗口10锁定真正所需的对准识别标记212,该对准识别标记212对应微米级别的精度,其精度较高,该方法能够将加工第一纳米结构和第二纳米结构时的对准精度提升至光刻机本身的精度。In the embodiment of the present invention, the alignment window 10 obtained by using the traditional backside overlay process has low accuracy due to the micron-level precision of the corresponding overlay process. Therefore, the embodiment of the present invention does not directly use this alignment The window 10 is used as the basis for alignment, but the alignment window 10 is used to lock the truly required alignment identification mark 212. The alignment identification mark 212 corresponds to micron-level accuracy, and its accuracy is relatively high. This method can process the second The alignment accuracy of the first nanostructure and the second nanostructure is improved to the accuracy of the lithography machine itself.
可选地,基于背面套刻工艺对该对准识别标记212对应位置处执行窗口光刻操作,得到对准窗口10,可以包括以下步骤A1-A2。Optionally, performing a window photolithography operation on the corresponding position of the alignment identification mark 212 based on the backside overlay process to obtain the alignment window 10 may include the following steps A1-A2.
步骤A1:对该对准识别标记212对应位置处的第二光刻胶层32进行窗口曝光和显影,得到对准窗口结构;对准窗口结构为经过窗口曝光和显影后暴露的第二结构层22。Step A1: Perform window exposure and development on the second photoresist layer 32 at the corresponding position of the alignment identification mark 212 to obtain an alignment window structure; the alignment window structure is the second structural layer exposed after window exposure and development. twenty two.
本发明实施例所进行的窗口曝光和显影过程,与上述步骤1011对第一光刻胶层31进行的曝光和显影过程原理相同,只是两个过程所针对的结构层与得到的结构不同;窗口曝光和显影是针对第二光刻胶层32进行的操作,且能够通过对第二光刻胶层32对应对准识别标记212的位置处进行溶解,得到对准窗口结构(参见图13所示),该对准窗口结构为被溶掉的第二光刻胶层32所对应的第二结构层22,换句话说,该对准窗口结构是表面没有第二光刻胶层32从而暴露出的第二结构层22,如图13所示出的位于上方的凹槽结构处的第二结构层22。The window exposure and development process performed in the embodiment of the present invention is the same as the exposure and development process performed on the first photoresist layer 31 in the above-mentioned step 1011, except that the structural layer targeted by the two processes is different from the resulting structure; window Exposure and development are operations performed on the second photoresist layer 32, and the alignment window structure can be obtained by dissolving the second photoresist layer 32 at the position corresponding to the alignment identification mark 212 (see FIG. 13 ), the alignment window structure is the second structural layer 22 corresponding to the dissolved second photoresist layer 32. In other words, the alignment window structure has no second photoresist layer 32 on the surface and is exposed. The second structural layer 22 is located at the upper groove structure as shown in FIG. 13 .
步骤A2:对该对准窗口结构刻蚀,得到对准窗口10。Step A2: Etch the alignment window structure to obtain the alignment window 10.
其中,本发明实施例对准窗口结构所进行的刻蚀过程,与上述步骤1012对第一参考结构所进行的刻蚀过程相同,即刻蚀掉该对准窗口结构(如暴露出的第二结构层22),得到如图14所示对准窗口10(即暴露出的基底1)。 Among them, the etching process performed on the alignment window structure in the embodiment of the present invention is the same as the etching process performed on the first reference structure in step 1012, that is, the alignment window structure (such as the exposed second structure) is etched away. layer 22), obtaining the alignment window 10 (ie, the exposed substrate 1) as shown in Figure 14.
可选地,参见图15所示,对第二结构层22执行第二光刻操作可以包括以下步骤1041-1042。Optionally, referring to FIG. 15 , performing the second photolithography operation on the second structural layer 22 may include the following steps 1041-1042.
步骤1041:对第二光刻胶层32再次进行曝光和显影,得到第二参考结构,第二参考结构为再次经过曝光和显影后暴露的第二结构层22。Step 1041: Expose and develop the second photoresist layer 32 again to obtain a second reference structure. The second reference structure is the second structural layer 22 exposed after being exposed and developed again.
其中,在图14所示结构的基础上,对剩余的第二光刻胶层32进行二次曝光和显影,本次曝光和显影所得到的结构为第二参考结构,为的是能够经过后续刻蚀过程得到最终所需的第二纳米结构221。其中,该第二参考结构为本次被溶掉的第二光刻胶层32所对应的第二结构层22,换句话说,该对第二参考结构是表面没有第二光刻胶层32并且为本次所暴露出的第二结构层22,如图16所示位于最上层的凹槽结构。Among them, on the basis of the structure shown in Figure 14, the remaining second photoresist layer 32 is exposed and developed twice. The structure obtained by this exposure and development is the second reference structure, in order to be able to undergo subsequent The etching process obtains the final desired second nanostructure 221. Among them, the second reference structure is the second structural layer 22 corresponding to the second photoresist layer 32 that was dissolved this time. In other words, the pair of second reference structures does not have the second photoresist layer 32 on the surface. And it is the second structural layer 22 exposed this time, which is the groove structure located on the uppermost layer as shown in FIG. 16 .
步骤1042:对第二参考结构刻蚀,去除残留的第二光刻胶层32,得到第二纳米结构221。Step 1042: Etch the second reference structure and remove the remaining second photoresist layer 32 to obtain the second nanostructure 221.
在本发明实施例中,通过对第二参考结构(如暴露出的第二结构层22)进行刻蚀,即刻蚀掉该第二参考结构(如暴露出的第二结构层22),并去除剩余的第二结构层22表面的第二光刻胶层32,最终得到如图17所示第二纳米结构221(即此步骤后剩余的第二结构层22)。In the embodiment of the present invention, by etching the second reference structure (such as the exposed second structural layer 22), the second reference structure (such as the exposed second structural layer 22) is etched away, and the The remaining second photoresist layer 32 on the surface of the second structural layer 22 finally obtains the second nanostructure 221 as shown in FIG. 17 (ie, the remaining second structural layer 22 after this step).
通常情况下,在加工得到第一纳米结构211之后,需要更换操作表面,例如,将操作表面由第一表面更换为需要继续加工第二纳米结构221的第二表面;而现有加工技术在加工完第一表面的第一纳米结构211之后,会采用真空吸附的方式来吸附住第一表面,例如,将具有第一纳米结构211的第一表面真空吸附在工作台上,但由于该第一纳米结构211的存在,该第一表面具有缝隙,会导致真空吸附不牢固,出现载片漏真空的问题。Normally, after the first nanostructure 211 is processed, the operating surface needs to be replaced. For example, the operating surface is replaced from the first surface to a second surface that needs to continue processing the second nanostructure 221. However, the existing processing technology cannot process the first nanostructure 211. After completing the first nanostructure 211 on the first surface, vacuum adsorption is used to adsorb the first surface. For example, the first surface with the first nanostructure 211 is vacuum adsorbed on the workbench, but due to the first The existence of the nanostructure 211 and the gaps on the first surface may cause the vacuum adsorption to be weak and cause vacuum leakage of the slide.
可选地,本发明实施例可以在上述步骤103“在第二结构层22与对准识别标记212对应位置处制作对准窗口10”之前,执行以下步骤B1-B2,以避免出现载片漏真空的问题。Optionally, the embodiment of the present invention can perform the following steps B1-B2 before the above-mentioned step 103 of "making the alignment window 10 at the position corresponding to the second structural layer 22 and the alignment identification mark 212" to avoid slide leakage. Vacuum problem.
步骤B1:对键合衬底4的一侧表面旋涂临时键合胶水。Step B1: Spin-coat temporary bonding glue on one side of the bonding substrate 4 .
如图18所示,键合衬底4本质为衬底,其可以是硅晶圆;本发明实施例可以在该键合衬底4的一侧表面旋涂临时键合胶水,得到如图18中示出的临时键合胶水层5,该临时键合胶水所采用的材料可以是一种基础树脂。 As shown in Figure 18, the bonding substrate 4 is essentially a substrate, which can be a silicon wafer; in embodiments of the present invention, temporary bonding glue can be spin-coated on one side of the bonding substrate 4, as shown in Figure 18 The temporary bonding glue layer 5 shown in , the material used for the temporary bonding glue may be a base resin.
步骤B2:将基底1具有第一纳米结构211的第一表面,通过临时键合胶水与键合衬底4进行临时键合。Step B2: Temporarily bond the first surface of the substrate 1 with the first nanostructure 211 to the bonding substrate 4 through temporary bonding glue.
如图19所示,本发明实施例可以将具有第一纳米结构211的第一表面与由临时键合胶水构成的临时键合胶水层5进行贴合,该临时键合胶水可以通过临时键合的方式,将具有第一纳米结构211的第一表面固定在键合衬底4上。As shown in FIG. 19 , the embodiment of the present invention can bond the first surface with the first nanostructure 211 to the temporary bonding glue layer 5 composed of temporary bonding glue. The temporary bonding glue can be bonded through the temporary bonding glue. In a manner, the first surface with the first nanostructure 211 is fixed on the bonding substrate 4 .
本发明实施例通过将具有第一纳米结构211的第一表面和键合衬底4临时键合的方式,使具有第一纳米结构211的第一表面得到固定,便于光刻机直接对第二表面(操作表面)进行处理;并且,该临时键合的工艺还能保护第一纳米结构211,避免出现第一纳米结构211被沾污和破坏的情况出现,同时解决了载片漏真空的问题。In the embodiment of the present invention, the first surface with the first nanostructure 211 is temporarily bonded to the bonding substrate 4, so that the first surface with the first nanostructure 211 is fixed, which facilitates the photolithography machine to directly process the second surface. The surface (operating surface) is processed; and the temporary bonding process can also protect the first nanostructure 211, avoid the first nanostructure 211 from being contaminated and damaged, and at the same time solve the problem of vacuum leakage on the slide. .
可选地,在得到第二纳米结构221之后,该方法还可以包括步骤C。Optionally, after obtaining the second nanostructure 221, the method may further include step C.
步骤C:对基底1具有第一纳米结构211的第一表面与键合衬底4解键合,得到双面超透镜。Step C: Debonding the first surface of the substrate 1 having the first nanostructure 211 from the bonding substrate 4 to obtain a double-sided superlens.
其中,当第二表面的第二纳米结构221也制备完毕时,可以通过升温或溶解等方式进行解键合,将具有第一纳米结构211的第一表面与键合衬底4分离,得到制作完成的双面超透镜。When the second nanostructure 221 on the second surface is also prepared, debonding can be performed by heating or dissolving, and the first surface with the first nanostructure 211 is separated from the bonding substrate 4 to obtain the completed product. Double-sided metalens.
可选地,对基底1具有第一纳米结构211的第一表面与键合衬底4解键合,包括:溶解临时键合胶水;例如,可以采用能够溶解临时键合胶水的溶剂进行解键合,得到制作完成的双面超透镜。Optionally, debonding the first surface of the substrate 1 with the first nanostructure 211 and the bonding substrate 4 includes: dissolving the temporary bonding glue; for example, a solvent that can dissolve the temporary bonding glue can be used to debond, to obtain the production Completed double-sided metalens.
可选地,在基底1的第一表面设置第一结构层21,包括:在基底1的第一表面蒸镀第一结构层21;在基底1的第二表面设置第二结构层22,包括:在基底1的第二表面蒸镀第二结构层22。Optionally, disposing the first structural layer 21 on the first surface of the substrate 1 includes: evaporating the first structural layer 21 on the first surface of the substrate 1; disposing the second structural layer 22 on the second surface of the substrate 1 includes: : The second structural layer 22 is evaporated on the second surface of the substrate 1 .
本发明实施例中,可以采用蒸镀的方式在基底1的两侧表面(如第一表面和第二表面)相应地设置第一结构层21和第二结构层22;可选地,第一结构层21与第二结构层22均为多晶硅材料。例如,可以是采用多晶硅材料蒸镀得到的第一结构层21与第二结构层22,该多晶硅材料可以包括:氧化钛、氮化硅、熔融石英、氧化铝、氮化镓、磷化镓、非晶硅、晶体硅或氢化非晶硅等。In the embodiment of the present invention, the first structural layer 21 and the second structural layer 22 can be respectively provided on both sides of the substrate 1 (such as the first surface and the second surface) by evaporation; optionally, the first Both the structural layer 21 and the second structural layer 22 are made of polysilicon material. For example, the first structural layer 21 and the second structural layer 22 may be evaporated using polysilicon materials. The polysilicon materials may include: titanium oxide, silicon nitride, fused quartz, aluminum oxide, gallium nitride, gallium phosphide, Amorphous silicon, crystalline silicon or hydrogenated amorphous silicon, etc.
以上所述,仅为本发明的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到变化或 替换的技术方案,都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应以所述权利要求的保护范围为准。 The above are only specific embodiments of the present invention, but the protection scope of the present invention is not limited thereto. Any person familiar with the technical field can easily think of changes or modifications within the technical scope disclosed in the present invention. Alternative technical solutions should be covered by the protection scope of the present invention. Therefore, the protection scope of the present invention should be subject to the protection scope of the claims.

Claims (12)

  1. 一种双面超透镜的加工方法,其特征在于,包括:A method for processing a double-sided super lens, which is characterized by including:
    在基底(1)的第一表面设置第一结构层(21),对所述第一结构层(21)执行第一光刻操作,得到第一纳米结构(211)和对准识别标记(212);所述基底(1)在光刻机探测器的工作波段透明;A first structural layer (21) is provided on the first surface of the substrate (1), and a first photolithography operation is performed on the first structural layer (21) to obtain a first nanostructure (211) and an alignment identification mark (212) ); the substrate (1) is transparent in the working band of the photolithography machine detector;
    在所述基底(1)的第二表面设置第二结构层(22);A second structural layer (22) is provided on the second surface of the substrate (1);
    在所述第二结构层(22)与所述对准识别标记(212)对应位置处制作对准窗口(10),所述对准窗口(10)的尺寸大于所述对准识别标记(212)的尺寸;An alignment window (10) is made at a position corresponding to the second structural layer (22) and the alignment identification mark (212). The size of the alignment window (10) is larger than the alignment identification mark (212). )size of;
    在所述第二表面为操作表面的情况下,透过所述对准窗口(10)并基于所述对准识别标记(212)进行对准,并对所述第二结构层(22)执行第二光刻操作,得到第二纳米结构(221);所述操作表面表示所述基底(1)当前被光刻机处理的表面。In the case where the second surface is an operating surface, alignment is performed through the alignment window (10) and based on the alignment identification mark (212), and is performed on the second structural layer (22). A second photolithography operation is performed to obtain a second nanostructure (221); the operation surface represents the surface of the substrate (1) currently processed by the photolithography machine.
  2. 根据权利要求1所述的方法,其特征在于,所述对所述第一结构层(21)执行第一光刻操作,包括:The method of claim 1, wherein performing a first photolithography operation on the first structural layer (21) includes:
    在所述第一结构层(21)表面涂覆第一光刻胶层(31),并对所述第一光刻胶层(31)进行曝光和显影,得到第一参考结构;所述第一参考结构为经过所述曝光和显影后暴露的所述第一结构层(21);Coat a first photoresist layer (31) on the surface of the first structural layer (21), and expose and develop the first photoresist layer (31) to obtain a first reference structure; A reference structure is the first structural layer (21) exposed after the exposure and development;
    对所述第一参考结构刻蚀,去除残留的所述第一光刻胶层(31),得到所述第一纳米结构(211)和所述对准识别标记(212)。The first reference structure is etched to remove the remaining first photoresist layer (31) to obtain the first nanostructure (211) and the alignment identification mark (212).
  3. 根据权利要求1所述的方法,其特征在于,所述在所述第二结构层(22)与所述对准识别标记(212)对应位置处制作对准窗口(10),包括:The method according to claim 1, characterized in that, making an alignment window (10) at a position corresponding to the second structural layer (22) and the alignment identification mark (212) includes:
    在所述第二结构层(22)表面涂覆第二光刻胶层(32),并基于背面套刻工艺对所述对准识别标记(212)对应位置处执行窗口光刻操作,得到所述对准窗口(10)。A second photoresist layer (32) is coated on the surface of the second structural layer (22), and a window photolithography operation is performed on the corresponding position of the alignment identification mark (212) based on the backside overlay process to obtain the Describe the alignment window (10).
  4. 根据权利要求3所述的方法,其特征在于,所述基于背面套刻工艺对所述对准识别标记(212)对应位置处执行窗口光刻操作,得到所述对准窗口(10),包括:The method according to claim 3, characterized in that, based on the backside overlay process, a window photolithography operation is performed on the corresponding position of the alignment identification mark (212) to obtain the alignment window (10), including :
    对所述对准识别标记(212)对应位置处的所述第二光刻胶层(32)进行窗 口曝光和显影,得到对准窗口结构;所述对准窗口结构为经过所述窗口曝光和显影后暴露的所述第二结构层(22);Perform windowing on the second photoresist layer (32) at the position corresponding to the alignment identification mark (212). Expose and develop to obtain an alignment window structure; the alignment window structure is the second structural layer (22) exposed after the window exposure and development;
    对所述对准窗口结构刻蚀,得到所述对准窗口(10)。The alignment window structure is etched to obtain the alignment window (10).
  5. 根据权利要求4所述的方法,其特征在于,所述对所述第二结构层(22)执行第二光刻操作,包括:The method of claim 4, wherein performing a second photolithography operation on the second structural layer (22) includes:
    对所述第二光刻胶层(32)再次进行曝光和显影,得到第二参考结构,所述第二参考结构为再次经过所述曝光和显影后暴露的所述第二结构层(22);The second photoresist layer (32) is exposed and developed again to obtain a second reference structure. The second reference structure is the second structural layer (22) exposed after the exposure and development again. ;
    对所述第二参考结构刻蚀,去除残留的所述第二光刻胶层(32),得到所述第二纳米结构(221)。The second reference structure is etched to remove the remaining second photoresist layer (32) to obtain the second nanostructure (221).
  6. 根据权利要求1所述的方法,其特征在于,在所述第二结构层(22)与所述对准识别标记(212)对应位置处制作对准窗口(10)之前,还包括:The method according to claim 1, characterized in that before making the alignment window (10) at the position corresponding to the second structural layer (22) and the alignment identification mark (212), it further includes:
    对键合衬底(4)的一侧表面旋涂临时键合胶水;Spin-coat temporary bonding glue on one side of the bonding substrate (4);
    将所述基底(1)具有所述第一纳米结构(211)的第一表面,通过所述临时键合胶水与所述键合衬底(4)进行临时键合。The first surface of the substrate (1) having the first nanostructure (211) is temporarily bonded to the bonding substrate (4) through the temporary bonding glue.
  7. 根据权利要求6所述的方法,其特征在于,在所述得到所述第二纳米结构(221)之后,还包括:The method according to claim 6, characterized in that, after obtaining the second nanostructure (221), further comprising:
    对所述基底(1)具有所述第一纳米结构(211)的第一表面与所述键合衬底(4)解键合,得到所述双面超透镜。The first surface of the substrate (1) having the first nanostructure (211) is debonded to the bonding substrate (4) to obtain the double-sided super lens.
  8. 根据权利要求7所述的方法,其特征在于,所述对所述基底(1)具有所述第一纳米结构(211)的第一表面与所述键合衬底(4)解键合,包括:溶解所述临时键合胶水。The method according to claim 7, characterized in that debonding the first surface of the substrate (1) with the first nanostructure (211) and the bonding substrate (4), including: Dissolve the temporary bonding glue.
  9. 根据权利要求1-8任一所述的方法,其特征在于,所述在基底(1)的第一表面设置第一结构层(21),包括:在所述基底(1)的第一表面蒸镀所述第一结构层(21);The method according to any one of claims 1 to 8, characterized in that: arranging the first structural layer (21) on the first surface of the substrate (1) includes: Evaporate the first structural layer (21);
    所述在所述基底(1)的第二表面设置第二结构层(22),包括:在所述基底(1)的第二表面蒸镀所述第二结构层(22)。The method of arranging the second structural layer (22) on the second surface of the substrate (1) includes evaporating the second structural layer (22) on the second surface of the substrate (1).
  10. 根据权利要求1-8任一所述的方法,其特征在于,所述基底(1)为玻璃基底。The method according to any one of claims 1 to 8, characterized in that the substrate (1) is a glass substrate.
  11. 根据权利要求10所述的方法,其特征在于,所述玻璃基底包括:石英 晶圆。The method of claim 10, wherein the glass substrate includes: quartz wafer.
  12. 根据权利要求11所述的方法,其特征在于,所述第一结构层(21)与所述第二结构层(22)均为多晶硅材料。 The method according to claim 11, characterized in that both the first structural layer (21) and the second structural layer (22) are made of polysilicon material.
PCT/CN2023/104802 2022-09-15 2023-06-30 Double-sided superlens processing method WO2024055712A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202211123393.6A CN117742078A (en) 2022-09-15 2022-09-15 Processing method of double-sided superlens
CN202211123393.6 2022-09-15

Publications (1)

Publication Number Publication Date
WO2024055712A1 true WO2024055712A1 (en) 2024-03-21

Family

ID=90253216

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2023/104802 WO2024055712A1 (en) 2022-09-15 2023-06-30 Double-sided superlens processing method

Country Status (2)

Country Link
CN (1) CN117742078A (en)
WO (1) WO2024055712A1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1531366A2 (en) * 2003-11-14 2005-05-18 International Business Machines Corporation Back to front alignment with latent imaging
CN106842815A (en) * 2017-04-06 2017-06-13 中国科学院光电技术研究所 A kind of method that double-sided alignment shaping naked eye three-dimensional shows thin-film device
CN112558437A (en) * 2020-12-18 2021-03-26 中国科学院光电技术研究所 Processing method of double-sided few-layer super-structured surface device
CN113608411A (en) * 2021-07-29 2021-11-05 华天慧创科技(西安)有限公司 Preparation method of double-sided graph of glass substrate

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1531366A2 (en) * 2003-11-14 2005-05-18 International Business Machines Corporation Back to front alignment with latent imaging
CN106842815A (en) * 2017-04-06 2017-06-13 中国科学院光电技术研究所 A kind of method that double-sided alignment shaping naked eye three-dimensional shows thin-film device
CN112558437A (en) * 2020-12-18 2021-03-26 中国科学院光电技术研究所 Processing method of double-sided few-layer super-structured surface device
CN113608411A (en) * 2021-07-29 2021-11-05 华天慧创科技(西安)有限公司 Preparation method of double-sided graph of glass substrate

Also Published As

Publication number Publication date
CN117742078A (en) 2024-03-22

Similar Documents

Publication Publication Date Title
US6750000B2 (en) Electron device manufacturing method, a pattern forming method, and a photomask used for those methods
US7494830B2 (en) Method and device for wafer backside alignment overlay accuracy
US6458494B2 (en) Etching method
CN1837956B (en) Graytone mask and film transistor substrate manufacturing method
WO2013177874A1 (en) Alignment identifier and method using alignment identifier to manufacture workpiece in exposure process
US8318607B2 (en) Immersion lithography wafer edge bead removal for wafer and scanner defect prevention
KR101695293B1 (en) Laser pattern mask and method for fabrication the same
WO2013185605A1 (en) Alignment mark and fabrication method thereof
JP2005014141A (en) Method of manufacturing compound element
WO2024055712A1 (en) Double-sided superlens processing method
CN103296031B (en) SOI wafer and manufacture method thereof
CN103454797B (en) A kind of liquid crystal display substrate and preparation method thereof, display device
JP2006228540A (en) Mask, manufacturing method of the mask, and manufacturing method of organic el device
JPH11212250A (en) Mask blank and production of mask
JPH09306807A (en) Manufacture of x-ray exposing mask structure
TWI778581B (en) Mask for forming oled picture element and template for supporting mask and mask integrated frame
TWI570873B (en) Semiconductor structure and manufacturing method for the same
JP2003158069A (en) Reticle for electron beam exposure, reticle blank for electron beam exposure and its manufacturing method
JPH09306822A (en) Plasma etching and manufacture of photomask
Bortolotti et al. Optical Lithography
TW202414669A (en) Transparent substrate with light blocking edge exclusion zone and method for forming the same
JP2004286892A (en) Alignment apparatus, alignment and adhesion apparatus, alignment mark, and adhesion method
JP2000286329A (en) Substrate-holding chuck, manufacture thereof, exposure method, manufacture of semiconductor device and aligner
JPH08306621A (en) Method of exposure, aligner and manufacture of semiconductor integrated circuit device
JPH0521317A (en) Manufacture of semiconductor device

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 23864449

Country of ref document: EP

Kind code of ref document: A1