WO2024032163A1 - Procédé de préparation d'un revêtement céramique résistant à l'usure et aux hautes températures - Google Patents
Procédé de préparation d'un revêtement céramique résistant à l'usure et aux hautes températures Download PDFInfo
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- WO2024032163A1 WO2024032163A1 PCT/CN2023/102078 CN2023102078W WO2024032163A1 WO 2024032163 A1 WO2024032163 A1 WO 2024032163A1 CN 2023102078 W CN2023102078 W CN 2023102078W WO 2024032163 A1 WO2024032163 A1 WO 2024032163A1
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- temperature
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- resistant ceramic
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- 238000005524 ceramic coating Methods 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 10
- 238000000576 coating method Methods 0.000 claims abstract description 35
- 239000011248 coating agent Substances 0.000 claims abstract description 27
- 239000000919 ceramic Substances 0.000 claims abstract description 25
- 238000005245 sintering Methods 0.000 claims abstract description 25
- 239000000758 substrate Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims description 38
- 239000011521 glass Substances 0.000 claims description 31
- 238000005260 corrosion Methods 0.000 claims description 21
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 16
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 15
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 14
- 229910052878 cordierite Inorganic materials 0.000 claims description 12
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 6
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 6
- JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000010419 fine particle Substances 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 4
- 239000003973 paint Substances 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- HEQBUZNAOJCRSL-UHFFFAOYSA-N iron(ii) chromite Chemical compound [O-2].[O-2].[O-2].[Cr+3].[Fe+3] HEQBUZNAOJCRSL-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 2
- 238000010791 quenching Methods 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims description 2
- 230000008023 solidification Effects 0.000 claims description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 2
- BYFGZMCJNACEKR-UHFFFAOYSA-N aluminium(i) oxide Chemical compound [Al]O[Al] BYFGZMCJNACEKR-UHFFFAOYSA-N 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 15
- 239000013078 crystal Substances 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 5
- 230000006378 damage Effects 0.000 abstract description 4
- 229920005646 polycarboxylate Polymers 0.000 abstract description 3
- 239000006104 solid solution Substances 0.000 abstract description 3
- 230000007547 defect Effects 0.000 abstract description 2
- 238000000280 densification Methods 0.000 abstract description 2
- 229910000314 transition metal oxide Inorganic materials 0.000 abstract description 2
- 238000010276 construction Methods 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 5
- 238000010998 test method Methods 0.000 description 5
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 229910052661 anorthite Inorganic materials 0.000 description 3
- 239000004567 concrete Substances 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- GWWPLLOVYSCJIO-UHFFFAOYSA-N dialuminum;calcium;disilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] GWWPLLOVYSCJIO-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 239000010431 corundum Substances 0.000 description 2
- 230000007123 defense Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- JPZROSNLRWHSQQ-UHFFFAOYSA-N furan-2,5-dione;prop-2-enoic acid Chemical compound OC(=O)C=C.O=C1OC(=O)C=C1 JPZROSNLRWHSQQ-UHFFFAOYSA-N 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- -1 national defense Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910001428 transition metal ion Inorganic materials 0.000 description 2
- 229910000604 Ferrochrome Inorganic materials 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005464 sample preparation method Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
- C04B35/195—Alkaline earth aluminosilicates, e.g. cordierite or anorthite
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62222—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining ceramic coatings
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/08—Coating starting from inorganic powder by application of heat or pressure and heat
- C23C24/082—Coating starting from inorganic powder by application of heat or pressure and heat without intermediate formation of a liquid in the layer
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3241—Chromium oxides, chromates, or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3262—Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/36—Glass starting materials for making ceramics, e.g. silica glass
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6562—Heating rate
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6567—Treatment time
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
Definitions
- the invention belongs to the technical field of ceramic coatings, and in particular is a preparation method of high-temperature-resistant and wear-resistant ceramic coatings.
- High-temperature protection of materials from oxidation has important economic and social significance for countries around the world. After a single metal is oxidized and corroded, its shape, color, and mechanical properties will change, causing equipment damage, pipeline leakage, product pollution, and It can cause serious accidents such as combustion or explosion, as well as serious waste of resources and energy, causing huge losses to the national economy. It is estimated that the economic losses caused by metal corrosion in developed countries around the world account for approximately 3.5% to 4.2% of their gross national product every year, exceeding the total losses caused by major disasters (fires, wind disasters, earthquakes, etc.) every year. Some people even estimate that about 100 million tons of metal are corroded, scrapped and lost every year around the world.
- Japan's Toyo Rubber Industry Co., Ltd. has developed a patented product of wear-resistant ceramic coating in recent years.
- the main film-forming material of this coating is epoxy resin or unsaturated polyester resin, which is composed of ceramic powder as filler and curing agent.
- Another example is an improved ceramic anti-corrosion coating disclosed in Chinese patent CN2017114572480, which uses polymers The components are not resistant to high temperatures and are not ceramic anti-corrosion coatings in the true sense. Ceramic anti-corrosion coatings are different from traditional anti-corrosion coatings such as water-based polymer coatings and clays.
- Ceramic anti-corrosion and heat-insulating coatings can be evenly applied before curing where anti-corrosion is required. On the base material to protect or enhance the repair, it is cured to form a seamless and sealed coating. It not only has excellent anti-corrosion properties, but also has high strength, high wear resistance, high adhesion, high insulation, long service life and flame retardancy. performance. Ceramic coating is a very important fine chemical product, and its application has penetrated into various fields of the national economy. Scope of application of wear-resistant ceramic coatings: It can be widely used in cement, steel, thermal power, petrochemical industries, and defense industries in areas where many materials are subject to strong erosion, corrosion, and heavy wear.
- High-temperature resistant ceramic coatings are widely used in high-tech fields such as aerospace, electronics, automobiles, and machinery manufacturing.
- the key wear-resistant and anti-corrosion treatment layer suitable for various high and low-temperature equipment in cement, national defense, petroleum, chemical industry and other industries. It is a new generation of ideal material to replace the existing wear-resistant ceramic sheets and wear-resistant steel. It solves the problems caused by wind in various industries. Select problems such as abrasion, impact abrasion, and frequent component shutdowns for maintenance.
- Those skilled in the art urgently need to develop a method for preparing high-temperature and wear-resistant ceramic coatings to meet existing usage needs and performance requirements.
- the present invention aims to provide a preparation method of high-temperature-resistant and wear-resistant ceramic coatings.
- a method for preparing high-temperature and wear-resistant ceramic coatings including the following steps:
- step (1) Mix the glass-glued powder obtained in step (1) and the ceramic powder obtained in step (2) in a mass ratio of 40-50:50-60 respectively, then add 42-43% acrylic acid copolymer aqueous solution with a mass fraction of 42-43%, stir and disperse evenly to obtain a solid High temperature and wear-resistant ceramic coating with a content of 65-70%.
- the homogeneous mixture in step one is a mixture of 15.0-29.8% CaO, 28.3-33.3% Al 2 O 3 , 40.4-56.7% SiO 2 and 1-2% ZnO in weight percentage.
- the acrylic acid copolymer is one of maleic acid-acrylic acid copolymer or acrylic acid/itaconic acid copolymer.
- Maleic acid-acrylic acid copolymer has good temperature resistance and strong corrosion, scale, scale, and dispersion effects. It has been used in various types of circulating cooling water systems in the past like acrylic acid/itaconic acid copolymer.
- the present invention uses acrylic copolymer to react with glass powder to prepare sticky glass powder.
- the coating has good coating adhesion effect at room temperature and good construction effect.
- the blackening agent in step three is one of manganese oxide and iron chrome black.
- the acrylic acid copolymer when the acrylic acid copolymer is mixed with the glass powder, Al 3+ and Ca 2+ ions can react with polyacrylic acid to form polycarboxylate, forming a cross-linked network structure, and The unreacted glass powders are combined together and gradually change from paste to gel. Pure ionic bonds are formed between the polycarboxylic acid chains through electrostatic attraction, and there are some complex bonds.
- the sticky glass powder can easily absorb moisture. Can be eroded and dissolved. After further mixing with cordierite powder, it becomes hard and difficult to dissolve without pre-treatment after coating. Since cordierite contains Al 2 O 3 components, it can be evenly dispersed in the glass matrix at a certain temperature.
- the glass components CaO and SiO 2 can react at the interface with Al 2 O 3 to form anorthite, and the speed of anorthite formation is much greater than the speed of quartz precipitation from the glass, thereby achieving the purpose of inhibiting quartz precipitation.
- its hardness is higher.
- the presence of high-hardness ceramic crystals in the coating will significantly increase the hardness of the composite material. Since both cordierite and anorthite have higher hardness than glass, the ceramic coating has a higher hardness.
- the wear-resistant ceramic coating of the present invention is a non-metallic cementitious material. At the construction site, the construction personnel apply the coating evenly on Metals and concrete have high bonding strength and hardness at room temperature.
- transition metal oxide blackening agent added can easily dissolve in it to form a solid solution.
- Silicic acid with a cyclic structure Salt belongs to the hexagonal crystal system.
- the transition metal ions form a solid solution, causing lattice distortion, reducing the symmetry of ion vibration and increasing the infrared radiation rate of the material.
- the distance between transition metal ions and surrounding oxygen ions in the six-membered ring cavity is unequal, the dipole moment changes greatly, and the spectral bands overlap, increasing the emissivity.
- the present invention has the following advantages:
- the wear-resistant ceramic coating disclosed in the present invention is a non-metallic cementitious material that is applied manually or mechanically on the lining or surface substrate. It has extremely high mechanical strength and stiffness, high density, no large macroscopic defects, and can be effectively Resist the impact force and shear stress of the material, and use polycarboxylate gel in combination, which can form a chemical bond after sintering, resulting in high strength, good environmental compatibility, and will not react with slag. At the same time, due to this The materials are mostly high-temperature synthetic raw materials with well-developed crystals and complete structures. The ambient temperature will not have a big impact on it. It is an environmentally inert material, so it has poor environmental sensitivity and no environmental pollution.
- the first step is to prepare sticky glass powder: the composition of the glass powder is: 15.0% CaO, 28.3% Al 2 O 3 , 56.7% SiO 2 , 2% ZnO, and the chemical purity of the raw materials used is >99.0%.
- Various raw materials weighed according to composition are mixed evenly and put into a corundum crucible, and then melted in a silicon-aluminum rod electric furnace at 1400°C for 1 hour. After the glass is melted evenly, it is poured into water and quenched into fine particles, dried, crushed and ball milled.
- the second step is to prepare cordierite powder: mix MgO, Al 2 O 3 and SiO 2 with a purity of >99.0% according to the stoichiometric ratio of cordierite, MgO 13.8%, Al 2 O 3 34.8%, SiO 2 51.4%, And add 1.5% mass proportion of blackening agent manganese oxide.
- the batch materials were placed in a ball mill, absolute ethanol was added and ball milled for 24 hours, and the ball milling medium was agate balls.
- Step 3 Preparation of coating: Mix glass powder and ceramic powder in a mass ratio of 40:60, ball-mill for 16 hours with absolute ethanol as the medium, agate balls as the ball-milling medium, and then add 42% acrylic acid copolymer aqueous solution by mass.
- the maleic acid-acrylic acid copolymer MA/AA of Shandong Taihe Water Treatment Technology Co., Ltd. was stirred and dispersed evenly to obtain a high-temperature and wear-resistant ceramic coating with a solid content of 65%.
- the fourth step, coating with high temperature and wear-resistant ceramic coating is the fourth step, coating with high temperature and wear-resistant ceramic coating:
- (2)Baking stage Heating to 600°C at a rate of 50°C/h and keeping warm for 4 hours. The purpose is to completely eliminate moisture in the furnace lining.
- Semi-sintering stage heat up to 900°C at 50°C/h, hold for 3 hours, heat up to 1200°C at 100°C/h, hold for 3 hours. The heating rate must be controlled to prevent cracks.
- Complete sintering stage During high-temperature sintering, the sintered structure of the crucible is the basis for improving its service life. If the sintering temperature is different, the thickness of the sintering layer is insufficient, and the service life is significantly reduced.
- the initial setting time of wear-resistant ceramic coating is not less than 30 minutes, bonding strength, Q420FRWZ35 substrate ⁇ 5.0MPa, LMJ10 concrete substrate ⁇ 2.0MPa; heat resistance, 300°C, 24h, the paint film does not blister or Cracking, non-sticking; resistant to Cold and hot alternation, room temperature of 300°C-23°C, natural cooling for 10 cycles, no bubbling, no cracking, no powdering; emissivity ⁇ ⁇ 0.923, adhesion level 2, no clear liquid or delamination.
- the first step is to prepare sticky glass powder: the composition of the glass powder is: 29.8% CaO, 28.3% Al 2 O 3 , 40.4% SiO 2 , 1% ZnO, and the chemical purity of the raw materials used is >99.0%.
- Various raw materials weighed according to composition are mixed evenly and put into a corundum crucible, and then melted in a silicon-aluminum rod electric furnace at 1400°C for 1 hour. After the glass is melted evenly, it is poured into water and quenched into fine particles, dried, crushed and ball milled.
- the second step is to prepare cordierite powder: mix MgO, Al 2 O 3 and SiO 2 with a purity of >99.0% according to the stoichiometric ratio of cordierite, MgO 13.8%, Al 2 O 3 34.8%, SiO 2 51.4%. And add 1.5% mass proportion of blackening agent ferrochrome black, and then place the batch in a ball mill, add absolute ethanol, and ball mill for 24 hours.
- the ball milling medium is agate ball.
- Step 3 Preparation of coating: Mix glass powder and ceramic powder in a mass ratio of 50:50, ball-mill for 16 hours with absolute ethanol as the medium, agate balls as the ball-milling medium, and then add 42% acrylic acid copolymer aqueous solution by mass. Tangshan Yonghe Water Treatment Agent Co., Ltd.'s BF-211 acrylic acid/itaconic acid copolymer is stirred and dispersed evenly to obtain a high temperature and wear-resistant ceramic coating with a solid content of 70%.
- the fourth step, coating with high temperature and wear-resistant ceramic coating is the fourth step, coating with high temperature and wear-resistant ceramic coating:
- Coating spraying After the treated metal substrate is preheated to 30°C, the high-temperature resistant ceramic anti-corrosion and heat-insulating coating is sprayed on the substrate;
- Baking stage Heating at a speed of 50°C/h to 600°C and keep warm for 4 hours. The purpose is to completely eliminate the moisture in the furnace lining.
- Semi-sintering stage heat up to 900°C at 50°C/h, hold for 3 hours, heat up to 1200°C at 100°C/h, hold for 3 hours. The heating rate must be controlled to prevent cracks.
- Complete sintering stage During high-temperature sintering, the sintered structure of the crucible is the basis for improving its service life. If the sintering temperature is different, the thickness of the sintering layer is insufficient, and the service life is significantly reduced.
- the initial setting time of wear-resistant ceramic coating is not less than 30 minutes, bonding strength, Q420FRWZ35 substrate ⁇ 5.0MPa, LMJ10 concrete substrate ⁇ 2.0MPa; heat resistance, 300°C, 24h, the paint film does not blister or Cracking, non-sticky; resistant to alternating hot and cold temperatures, 300°C-23°C room temperature, 10 cycles of natural cooling, no foaming, no cracking, no powdering; emissivity ⁇ ⁇ 0.937, adhesion level 2, no clear liquid Or layered.
- the test method is carried out with reference to the following standards and methods.
- the sample preparation is carried out according to YB/T5202.2; the porosity detection of the sample is carried out according to YB/T5200; the bulk density detection is carried out according to YB/T5200; the flexural strength and compressive strength
- the inspection is carried out according to YB/T5201; the inspection of wear value is carried out according to GB/T18301; the inspection of heating permanent line change is carried out according to YB/T5203; YB/T5200-1993 Test method for apparent porosity and bulk density of dense refractory castables; YB/T5201 -1993 Test method for room temperature flexural strength and compressive strength of dense refractory castables.
- GB/T17617-1998 Sampling of refractory raw materials and unshaped refractory materials; YB/T5202.2-2003 Sample preparation method for unshaped refractory castables; YB/T5203-1993 Line change test method for dense refractory castables; GB/T18301 -2012 Test method for normal temperature wear resistance of refractory materials; YB/T 134-2015 High temperature infrared radiation environmentally friendly coating.
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- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
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Abstract
La présente invention se rapporte au domaine technique des revêtements. L'invention divulgue un procédé pour préparer un revêtement céramique résistant à l'usure et aux hautes températures. Le revêtement céramique résistant à l'usure selon l'invention peut être appliqué sur un parement ou une surface d'un substrat d'une manière manuelle ou mécanique. Le revêtement céramique résistant à l'usure présente une résistance mécanique et une rigidité extrêmement élevées, une densité élevée, et aucun défaut macroscopique important, et peut résister efficacement à un impact et à une contrainte de cisaillement des matériaux. L'utilisation de gel de polycarboxylate permet une liaison chimique après frittage, de sorte qu'une résistance élevée est obtenue. Après densification par frittage, des cristaux de céramique de dureté élevée sont présents dans le revêtement, de sorte que le revêtement a une force de liaison et une dureté élevées à température ambiante. Un agent de noircissement d'oxyde de métal de transition ajouté est susceptible de se dissoudre dans des cristaux pour former une solution solide, de sorte que l'émissivité est améliorée, une excellente ténacité et une excellente résistance aux vibrations sont obtenues, et les dommages et les décollements dus aux impacts peuvent être efficacement empêchés. Comme une liaison ionique et une liaison covalente sont des liaisons fortes, l'énergie de liaison est élevée, les fissures ou les dommages dues aux vibrations thermiques sont moins susceptibles de se produire, et la résistance à l'usure est bonne.
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CN202210947689.3A CN115108820B (zh) | 2022-08-09 | 2022-08-09 | 一种耐高温耐磨陶瓷涂料的制备方法 |
CN202210947689.3 | 2022-08-09 |
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CN115108820B (zh) * | 2022-08-09 | 2023-03-28 | 安徽新大陆特种涂料有限责任公司 | 一种耐高温耐磨陶瓷涂料的制备方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4196004A (en) * | 1978-03-22 | 1980-04-01 | Manfred Berretz | Corrosion resistant glasses that contain chemical additives for application over metal substrates |
CN1583904A (zh) * | 2004-06-07 | 2005-02-23 | 华东船舶工业学院 | 自润滑防粘涂料及其制备方法 |
CN106587965A (zh) * | 2016-12-06 | 2017-04-26 | 武汉钢铁股份有限公司 | 适用于金属基材的低温烧结高导热陶瓷涂料及其制备方法和应用 |
CN106752132A (zh) * | 2016-12-06 | 2017-05-31 | 武汉钢铁股份有限公司 | 用于金属换热器的高导热防腐蚀陶瓷涂料及其制备方法和应用 |
CN111793434A (zh) * | 2020-07-01 | 2020-10-20 | 安徽新大陆特种涂料有限责任公司 | 一种耐高温陶瓷防腐隔热涂料的制备方法 |
WO2022056967A1 (fr) * | 2020-09-21 | 2022-03-24 | 江苏大学 | Revêtement photothermique à haute température et résistance aux chocs thermiques, large spectre et haute absorption, et procédé de préparation associé |
CN115108820A (zh) * | 2022-08-09 | 2022-09-27 | 安徽新大陆特种涂料有限责任公司 | 一种耐高温耐磨陶瓷涂料的制备方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1027691C (zh) * | 1990-03-24 | 1995-02-22 | 广州师范学院 | 高温节能耐腐蚀陶瓷涂料组合物 |
JP2008214152A (ja) * | 2007-03-06 | 2008-09-18 | Hitachi Powdered Metals Co Ltd | ガラスペースト組成物 |
CN102701746B (zh) * | 2012-05-14 | 2014-02-19 | 武汉理工大学 | 尖晶石-硅酸盐多相复合体系红外辐射陶瓷粉料的制备方法 |
CN103804030A (zh) * | 2013-12-27 | 2014-05-21 | 西北工业大学 | 一种用于碳陶刹车盘的防氧化复合涂层的制备方法 |
CN107011704B (zh) * | 2017-03-27 | 2019-10-15 | 汕头大学 | 一种微波发热涂料 |
CN108949012A (zh) * | 2018-06-08 | 2018-12-07 | 苏州加减士空间设计装饰工程有限公司 | 一种墙体保温防火涂料 |
CN111073503B (zh) * | 2019-12-24 | 2021-06-08 | 洛阳嘉德节能科技有限公司 | 一种耐高温高辐射率防腐涂料 |
CN111517651B (zh) * | 2020-04-27 | 2021-12-14 | 佛山市东鹏陶瓷有限公司 | 一种耐磨釉料、其制备方法及使用其的釉面砖 |
-
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- 2022-08-09 CN CN202210947689.3A patent/CN115108820B/zh active Active
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- 2023-06-25 WO PCT/CN2023/102078 patent/WO2024032163A1/fr unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4196004A (en) * | 1978-03-22 | 1980-04-01 | Manfred Berretz | Corrosion resistant glasses that contain chemical additives for application over metal substrates |
CN1583904A (zh) * | 2004-06-07 | 2005-02-23 | 华东船舶工业学院 | 自润滑防粘涂料及其制备方法 |
CN106587965A (zh) * | 2016-12-06 | 2017-04-26 | 武汉钢铁股份有限公司 | 适用于金属基材的低温烧结高导热陶瓷涂料及其制备方法和应用 |
CN106752132A (zh) * | 2016-12-06 | 2017-05-31 | 武汉钢铁股份有限公司 | 用于金属换热器的高导热防腐蚀陶瓷涂料及其制备方法和应用 |
CN111793434A (zh) * | 2020-07-01 | 2020-10-20 | 安徽新大陆特种涂料有限责任公司 | 一种耐高温陶瓷防腐隔热涂料的制备方法 |
WO2022056967A1 (fr) * | 2020-09-21 | 2022-03-24 | 江苏大学 | Revêtement photothermique à haute température et résistance aux chocs thermiques, large spectre et haute absorption, et procédé de préparation associé |
CN115108820A (zh) * | 2022-08-09 | 2022-09-27 | 安徽新大陆特种涂料有限责任公司 | 一种耐高温耐磨陶瓷涂料的制备方法 |
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