WO2024014123A1 - 熱可塑性樹脂組成物、成形体、金属箔積層板、ボンディングシート、フィラメント、及び三次元造形用材料 - Google Patents

熱可塑性樹脂組成物、成形体、金属箔積層板、ボンディングシート、フィラメント、及び三次元造形用材料 Download PDF

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WO2024014123A1
WO2024014123A1 PCT/JP2023/018691 JP2023018691W WO2024014123A1 WO 2024014123 A1 WO2024014123 A1 WO 2024014123A1 JP 2023018691 W JP2023018691 W JP 2023018691W WO 2024014123 A1 WO2024014123 A1 WO 2024014123A1
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Prior art keywords
resin composition
thermoplastic resin
group
component
carbon atoms
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PCT/JP2023/018691
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English (en)
French (fr)
Japanese (ja)
Inventor
敦史 酒井
良輔 藤井
勇希 佐藤
直樹 金子
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Mitsubishi Gas Chemical Co Inc
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Mitsubishi Gas Chemical Co Inc
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Priority to KR1020257000745A priority Critical patent/KR20250036803A/ko
Priority to US18/881,798 priority patent/US20260015501A1/en
Priority to EP23839300.3A priority patent/EP4556528A4/en
Priority to JP2024533536A priority patent/JPWO2024014123A1/ja
Priority to CN202380047700.3A priority patent/CN119384466A/zh
Publication of WO2024014123A1 publication Critical patent/WO2024014123A1/ja
Anticipated expiration legal-status Critical
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/088—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyamides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1003—Preparatory processes
    • C08G73/1007—Preparatory processes from tetracarboxylic acids or derivatives and diamines
    • C08G73/101—Preparatory processes from tetracarboxylic acids or derivatives and diamines containing chain terminating or branching agents
    • C08G73/1017—Preparatory processes from tetracarboxylic acids or derivatives and diamines containing chain terminating or branching agents in the form of (mono)amine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1042—Copolyimides derived from at least two different tetracarboxylic compounds or two different diamino compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1046—Polyimides containing oxygen in the form of ether bonds in the main chain
    • C08G73/105—Polyimides containing oxygen in the form of ether bonds in the main chain with oxygen only in the diamino moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1075—Partially aromatic polyimides
    • C08G73/1082—Partially aromatic polyimides wholly aromatic in the tetracarboxylic moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J171/00—Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J171/00—Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
    • C09J171/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C09J171/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J179/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09J161/00 - C09J177/00
    • C09J179/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C09J179/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/35—Heat-activated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10—Processes of additive manufacturing
    • B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/118—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/12—Applications used for fibers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C08L2203/162—Applications used for films sealable films

Definitions

  • the present invention relates to a thermoplastic resin composition, a molded body, a metal foil laminate, a bonding sheet, a filament, and a three-dimensional modeling material.
  • Polyimide resin is a useful engineering plastic that has high thermal stability, high strength, and high solvent resistance due to the rigidity of its molecular chains, resonance stabilization, and strong chemical bonds, and is used in a wide range of fields.
  • crystalline polyimide resin can further improve its heat resistance, strength, and chemical resistance, and is therefore expected to be used as a metal substitute.
  • polyimide resins have high heat resistance, they do not exhibit thermoplasticity and have low moldability.
  • thermoplastic polyimide resins having thermoplasticity have been reported.
  • thermoplastic polyimide resins also have excellent moldability. Therefore, thermoplastic polyimide resins can be applied to molded products used in harsh environments, where general-purpose thermoplastic resins such as nylon and polyester cannot be applied.
  • Patent Document 1 describes a predetermined compound obtained by reacting a tetracarboxylic acid and/or its derivative containing at least one aromatic ring, a diamine containing at least one alicyclic hydrocarbon structure, and a chain aliphatic diamine. Thermoplastic polyimide resins are disclosed that include repeating structural units of.
  • Patent Document 2 discloses a thermoplastic polyimide resin containing a predetermined repeating unit, and also describes that the polyimide resin and another resin are used in combination as a polymer alloy.
  • Patent Document 3 discloses that a resin molded article containing a polyimide resin in which specific different polyimide constituent units are combined in a specific ratio and has a weight average molecular weight within a specific range, and a polyetherketone resin is produced under a low load environment. It is disclosed that the heat deformation temperature is high and the heat resistance is excellent.
  • the polyimide resins described in Patent Documents 1 to 3 are all crystalline thermoplastic resins.
  • a general molding method using a 3D printer involves laminating a 3D printer molding material containing a sinterable component and a binder component into a desired shape using a 3D printer, and then firing and molding.
  • thermoplastic resin can be used as a binder component, but if a crystalline thermoplastic resin with an excessively high crystallization temperature is used, it will be difficult for the laminated 3D printer molding materials to adhere to each other, resulting in problems during lamination. There is a risk that molding defects may occur due to the occurrence of sink marks due to the temperature difference.
  • An object of the present invention is to provide a thermoplastic resin composition that includes a crystalline thermoplastic resin and can have a lower crystallization temperature than the crystalline thermoplastic resin while maintaining heat resistance and crystallinity. There is a particular thing.
  • thermoplastic resin composition containing two specific types of crystalline thermoplastic resins having a melting point difference within a specific range can solve the above problem. That is, the present invention relates to the following.
  • [1] Contains a repeating structural unit represented by the following formula (1) and a repeating structural unit represented by the following formula (2), the sum of the repeating structural units of the formula (1) and the repeating structural unit of the formula (2)
  • thermoplastic resin composition wherein the absolute value of the difference between the melting point Tm A of the component (A) and the melting point Tm B of the component (B)
  • R 1 is a divalent group having 6 to 22 carbon atoms containing at least one alicyclic hydrocarbon structure.
  • R 2 is a divalent chain aliphatic group having 5 to 16 carbon atoms.
  • X 1 and X 2 are each independently a tetravalent group having 6 to 22 carbon atoms and containing at least one aromatic ring.
  • thermoplastic resin composition according to any one of [1] to [3] above, wherein the total content of the component (A) and the component (B) in the thermoplastic resin composition is 50% by mass or more.
  • Thermoplastic resin composition [5] The thermoplastic resin composition according to any one of [1] to [4] above, wherein the thermoplastic resin composition has a crystallization heat amount of 10 mJ/mg or more.
  • thermoplastic resin composition has a melting point Tm, and the difference (Tm - Tc) between the melting point Tm and the crystallization temperature Tc of the thermoplastic resin composition is 65°C or more.
  • a molded article comprising the thermoplastic resin composition according to any one of [1] to [9] above.
  • a metal foil laminate comprising a layer made of the molded article according to [10] above and a layer made of metal foil.
  • a bonding sheet comprising the thermoplastic resin composition according to any one of [1] to [9] above.
  • a filament comprising the thermoplastic resin composition according to any one of [1] to [9] above.
  • a three-dimensional modeling material comprising the thermoplastic resin composition according to any one of [1] to [9] above.
  • thermoplastic resin composition of the present invention has heat resistance and crystallinity, suppresses the increase in crystallization temperature, has good thermoformability, and does not easily cause adhesive deterioration or sink marks during three-dimensional modeling.
  • it is suitable as a molding material for a 3D printer.
  • thermoplastic resin composition of the present invention exhibits good adhesion to adherends due to the effect of lowering the crystallization temperature, and has high heat resistance, so it can be used for bonding sheets, metal foil laminates such as copper-clad laminates, etc. Also suitable for use.
  • FIG. 2 is a schematic diagram showing a method for preparing a sample (ultra-thin section) used for field emission scanning transmission electron microscopy (FE-STEM) observation.
  • 1 is a micrograph of a cross section of the thermoplastic resin composition (pellet) of Example 3 taken in a direction perpendicular to the machine direction (MD) and observed by FE-STEM.
  • 1 is a micrograph of a cross section of the injection molded article obtained in Example 3, taken in a direction perpendicular to the machine direction (MD) and observed by FE-STEM.
  • It is a schematic diagram for demonstrating the preparation method of the test piece used for adhesive evaluation between films.
  • It is a schematic diagram for demonstrating the evaluation method of the adhesiveness of films.
  • It is a schematic diagram for demonstrating the preparation method of the test piece used for adhesive evaluation of a film and copper foil.
  • It is a schematic diagram for demonstrating the adhesiveness of a film and copper foil, and the evaluation method of tensile adhesive strength.
  • thermoplastic resin composition of the present invention includes a repeating structural unit represented by the following formula (1) and a repeating structural unit represented by the following formula (2), wherein the repeating structural unit of the formula (1) and the repeating structural unit of the formula (2) are combined.
  • ) containing a crystalline thermoplastic polyimide resin (A) in which the content ratio of the repeating structural units of formula (1) to the total of repeating structural units of formula (1) is 15 to 70 mol%, and a polyetherketoneketone resin (B)
  • a thermoplastic resin composition comprising: The absolute value of the difference between the melting point Tm A of the component (A) and the melting point Tm B of the component (B)
  • R 1 is a divalent group having 6 to 22 carbon atoms containing at least one alicyclic hydrocarbon structure.
  • R 2 is a divalent chain aliphatic group having 5 to 16 carbon atoms.
  • X 1 and X 2 are each independently a tetravalent group having 6 to 22 carbon atoms and containing at least one aromatic ring.
  • thermoplastic resin composition of the present invention contains component (A) and component (B) which are crystalline thermoplastic resins, and has a higher heat resistance and crystallinity than the crystalline thermoplastic resin. It is possible to lower the crystallization temperature. That is, the crystallization temperature of the thermoplastic resin composition is lower than the crystallization temperature of component (A) alone or component (B) alone, which is the raw material resin.
  • component ( A ) and component ( B ) has been found to form a lamella-like microphase-separated structure, which will be described later, due to the intermolecular interaction between component (A) and component (B), and due to this characteristic morphology formation. It is inferred that the effect of lowering the crystallization temperature is occurring. It is also believed that practically sufficient heat resistance and crystallinity are maintained.
  • the crystalline thermoplastic polyimide resin (A) used in the present invention (hereinafter also simply referred to as "polyimide resin (A)”) has a repeating structural unit represented by the following formula (1) and a repeating unit represented by the following formula (2). It contains a structural unit, and the content ratio of the repeating structural unit of the formula (1) to the total of the repeating structural unit of the formula (1) and the repeating structural unit of the formula (2) is 15 to 70 mol%.
  • R 1 is a divalent group having 6 to 22 carbon atoms containing at least one alicyclic hydrocarbon structure.
  • R 2 is a divalent chain aliphatic group having 5 to 16 carbon atoms.
  • X 1 and X 2 are each independently a tetravalent group having 6 to 22 carbon atoms and containing at least one aromatic ring.
  • the polyimide resin (A) used in the present invention is a crystalline thermoplastic resin, and its form is preferably powder or pellets.
  • thermoplastic polyimide resin refers to a polyimide resin that does not have a glass transition temperature (Tg), which is formed by molding a polyimide precursor such as polyamic acid and then closing the imide ring, or It is distinguished from polyimide resins, which decompose at temperatures lower than the glass transition temperature.
  • R 1 is a divalent group having 6 to 22 carbon atoms and containing at least one alicyclic hydrocarbon structure.
  • the alicyclic hydrocarbon structure means a ring derived from an alicyclic hydrocarbon compound, and the alicyclic hydrocarbon compound may be saturated or unsaturated, and the alicyclic hydrocarbon structure may be saturated or unsaturated. It may be a ring or a polycyclic ring.
  • alicyclic hydrocarbon structure examples include, but are not limited to, cycloalkane rings such as cyclohexane rings, cycloalkene rings such as cyclohexene, bicycloalkane rings such as norbornane rings, and bicycloalkene rings such as norbornene. Do not mean. Among these, preferred is a cycloalkane ring, more preferred is a cycloalkane ring having 4 to 7 carbon atoms, and even more preferred is a cyclohexane ring.
  • the number of carbon atoms in R 1 is 6 to 22, preferably 8 to 17.
  • R 1 contains at least one alicyclic hydrocarbon structure, preferably 1 to 3 alicyclic hydrocarbon structures.
  • R 1 is preferably a divalent group represented by the following formula (R1-1) or (R1-2).
  • (m 11 and m 12 are each independently an integer of 0 to 2, preferably 0 or 1.
  • m 13 to m 15 are each independently an integer of 0 to 2, preferably 0 or 1)
  • R 1 is particularly preferably a divalent group represented by the following formula (R1-3).
  • R1-3 the positional relationship of the two methylene groups with respect to the cyclohexane ring may be cis or trans, and the ratio of cis to trans is Any value is acceptable.
  • X 1 is a tetravalent group having 6 to 22 carbon atoms and containing at least one aromatic ring.
  • the aromatic ring may be a single ring or a condensed ring, and examples thereof include a benzene ring, a naphthalene ring, an anthracene ring, and a tetracene ring, but are not limited thereto. Among these, benzene rings and naphthalene rings are preferred, and benzene rings are more preferred.
  • the number of carbon atoms in X 1 is 6 to 22, preferably 6 to 18.
  • X 1 contains at least one aromatic ring, preferably 1 to 3 aromatic rings.
  • X 1 is preferably a tetravalent group represented by any of the following formulas (X-1) to (X-4).
  • R 11 to R 18 are each independently an alkyl group having 1 to 4 carbon atoms.
  • p 11 to p 13 are each independently an integer of 0 to 2, preferably 0.
  • p 14 , p 15 , p 16 and p 18 are each independently an integer of 0 to 3, preferably 0.
  • p 17 is an integer of 0 to 4, preferably 0.
  • Each of 13 is independently a single bond, an ether group, a carbonyl group, or an alkylene group having 1 to 4 carbon atoms.
  • X 1 is a tetravalent group having 6 to 22 carbon atoms and containing at least one aromatic ring
  • R 12 , R 13 , p 12 and p 13 in formula (X-2) are represented by formula (X-
  • the number of carbon atoms in the tetravalent group represented by 2) is selected to be within the range of 10 to 22.
  • L 11 , R 14 , R 15 , p 14 and p 15 in formula (X-3) are such that the number of carbon atoms in the tetravalent group represented by formula (X-3) is in the range of 12 to 22.
  • L 12 , L 13 , R 16 , R 17 , R 18 , p 16 , p 17 and p 18 in formula (X-4) are tetravalent groups represented by formula (X-4). is selected such that the number of carbon atoms in the group falls within the range of 18 to 22.
  • X 1 is particularly preferably a tetravalent group represented by the following formula (X-5) or (X-6).
  • R 2 is a divalent chain aliphatic group having 5 to 16 carbon atoms, preferably 6 to 14 carbon atoms, more preferably 7 to 12 carbon atoms, and even more preferably 8 to 10 carbon atoms.
  • the chain aliphatic group means a group derived from a chain aliphatic compound, and the chain aliphatic compound may be saturated or unsaturated, and the chain aliphatic group may be saturated or unsaturated. It may be branched or branched, and may contain a heteroatom such as an oxygen atom.
  • R 2 is preferably an alkylene group having 5 to 16 carbon atoms, more preferably an alkylene group having 6 to 14 carbon atoms, even more preferably 7 to 12 carbon atoms, and especially preferably an alkylene group having 8 to 10 carbon atoms. It is an alkylene group.
  • the alkylene group may be a straight chain alkylene group or a branched alkylene group, but is preferably a straight chain alkylene group.
  • R 2 is preferably at least one selected from the group consisting of an octamethylene group and a decamethylene group, particularly preferably an octamethylene group.
  • R 2 is a divalent chain aliphatic group having 5 to 16 carbon atoms and containing an ether group.
  • the number of carbon atoms is preferably 6 to 14 carbon atoms, more preferably 7 to 12 carbon atoms, and still more preferably 8 to 10 carbon atoms.
  • divalent groups represented by the following formula (R2-1) or (R2-2) are preferred.
  • (m 21 and m 22 are each independently an integer of 1 to 15, preferably 1 to 13, more preferably 1 to 11, even more preferably 1 to 9.
  • m 23 to m 25 are each (Independently, it is an integer from 1 to 14, preferably from 1 to 12, more preferably from 1 to 10, and even more preferably from 1 to 8.)
  • R 2 is a divalent chain aliphatic group having 5 to 16 carbon atoms (preferably 6 to 14 carbon atoms, more preferably 7 to 12 carbon atoms, even more preferably 8 to 10 carbon atoms)
  • m 21 and m 22 in formula (R2-1) are divalent groups represented by formula (R2-1) having 5 to 16 carbon atoms (preferably 6 to 14 carbon atoms, more preferably 7 carbon atoms). to 12 carbon atoms, more preferably 8 to 10 carbon atoms.
  • m 21 +m 22 is 5 to 16 (preferably 6 to 14, more preferably 7 to 12, still more preferably 8 to 10).
  • m 23 to m 25 in formula (R2-2) is a divalent group represented by formula (R2-2) having 5 to 16 carbon atoms (preferably 6 to 14 carbon atoms, more preferably The number of carbon atoms is selected to fall within the range of 7 to 12 carbon atoms, more preferably 8 to 10 carbon atoms. That is, m 23 +m 24 +m 25 is 5 to 16 (preferably 6 to 14 carbon atoms, more preferably 7 to 12 carbon atoms, still more preferably 8 to 10 carbon atoms).
  • X 2 is defined in the same manner as X 1 in formula (1), and preferred embodiments are also the same.
  • the content ratio of the repeating structural unit of formula (1) to the total of the repeating structural unit of formula (1) and the repeating structural unit of formula (2) is 15 to 70 mol%.
  • the content ratio of the repeating structural unit of formula (1) is within the above range, it is possible to crystallize the polyimide resin (A) even in a general injection molding cycle, and it is possible to compound the polyimide resin (A) with the component (B). In this case, the effect of lowering the crystallization temperature can be easily expressed.
  • the content ratio of the repeating structural unit of formula (1) to the sum of the repeating structural units of formula (1) and the repeating structural unit of formula (2) is preferably 20 mol% or more, and more Preferably 25 mol% or more, more preferably 30 mol% or more, even more preferably 32 mol% or more, and from the viewpoint of maintaining high crystallinity, preferably 65 mol% or less, more preferably 60 mol% or less, More preferably, it is 50 mol% or less, even more preferably 40 mol% or less, even more preferably less than 40 mol%, even more preferably 35 mol% or less.
  • the total content ratio of the repeating constituent units of formula (1) and repeating constituent units of formula (2) to all repeating constituent units constituting the polyimide resin (A) is preferably 50 to 100 mol%, more preferably 75% by mole. ⁇ 100 mol%, more preferably 80 ⁇ 100 mol%, even more preferably 85 ⁇ 100 mol%.
  • the total of all repeating structural units constituting the polyimide resin (A) refers to the total of the structural units in the polyimide resin (A) when a structural unit containing one polyimide structure is considered as one structural unit. means.
  • the polyimide resin (A) may further contain a repeating structural unit of the following formula (3).
  • the content ratio of the repeating structural unit of formula (3) to the total of the repeating structural unit of formula (1) and the repeating structural unit of formula (2) is preferably 25 mol% or less to maintain crystallinity. From the viewpoint of this, it is preferably 20 mol% or less, more preferably 15 mol% or less. Further, from the viewpoint of improving heat resistance, the content ratio is preferably 5 mol% or more, more preferably 10 mol% or more.
  • R 3 is a divalent group having 6 to 22 carbon atoms containing at least one aromatic ring.
  • X 3 is a tetravalent group having 6 to 22 carbon atoms containing at least one aromatic ring.
  • R 3 is a divalent group having 6 to 22 carbon atoms and containing at least one aromatic ring.
  • the aromatic ring may be a single ring or a condensed ring, and examples thereof include a benzene ring, a naphthalene ring, an anthracene ring, and a tetracene ring, but are not limited thereto. Among these, benzene rings and naphthalene rings are preferred, and benzene rings are more preferred.
  • the number of carbon atoms in R 3 is 6 to 22, preferably 6 to 18.
  • R 3 contains at least one aromatic ring, preferably 1 to 3 aromatic rings. Further, a monovalent or divalent electron-withdrawing group may be bonded to the aromatic ring.
  • Examples of monovalent electron-withdrawing groups include nitro group, cyano group, p-toluenesulfonyl group, halogen, halogenated alkyl group, phenyl group, and acyl group.
  • Examples of divalent electron-withdrawing groups include fluorinated alkylene groups (for example, -C(CF 3 ) 2 -, -(CF 2 ) p - (where p is an integer from 1 to 10)).
  • examples include -CO-, -SO 2 -, -SO-, -CONH-, -COO-, and the like.
  • R 3 is preferably a divalent group represented by the following formula (R3-1) or (R3-2).
  • (m 31 and m 32 are each independently an integer of 0 to 2, preferably 0 or 1.
  • m 33 and m 34 are each independently an integer of 0 to 2, preferably 0 or 1.
  • R 21 , R 22 and R 23 are each independently an alkyl group having 1 to 4 carbon atoms, an alkenyl group having 2 to 4 carbon atoms, or an alkynyl group having 2 to 4 carbon atoms.
  • p 21 , p 22 and p 23 are integers of 0 to 4, preferably 0.
  • L 21 is a single bond, an ether group, a carbonyl group, or an alkylene group having 1 to 4 carbon atoms.
  • R 3 is a divalent group having 6 to 22 carbon atoms and containing at least one aromatic ring
  • m 31 , m 32 , R 21 and p 21 in formula (R3-1) are represented by formula (R3-1).
  • the number of carbon atoms in the divalent group represented by 1) is selected to be within the range of 6 to 22.
  • L 21 , m 33 , m 34 , R 22 , R 23 , p 22 and p 23 in formula (R3-2) have the number of carbon atoms in the divalent group represented by formula (R3-2). It is selected to fall within the range of 12 to 22.
  • X 3 is defined in the same manner as X 1 in formula (1), and preferred embodiments are also the same.
  • the polyimide resin (A) may further contain a repeating structural unit represented by the following formula (4).
  • R 4 is a divalent group containing -SO 2 - or -Si(R x ) (R y ) O-, and R x and R y are each independently a chain aliphatic group having 1 to 3 carbon atoms. group or phenyl group.
  • X 4 is a tetravalent group having 6 to 22 carbon atoms and containing at least one aromatic ring.
  • X 4 is defined in the same manner as X 1 in formula (1), and preferred embodiments are also the same.
  • the terminal structure of the polyimide resin (A) is not particularly limited, and may have an aromatic ring-containing group, an aliphatic group, etc. in addition to a terminal amino group and a terminal carboxy group. Among these, it is preferable that the polyimide resin (A) has a chain aliphatic group having 5 to 14 carbon atoms at the end. The chain aliphatic group may be saturated or unsaturated, and may be linear or branched. When the polyimide resin (A) has the above-mentioned specific group at the end, a resin composition having excellent heat aging resistance can be obtained.
  • Examples of the saturated chain aliphatic group having 5 to 14 carbon atoms include n-pentyl group, n-hexyl group, n-heptyl group, n-octyl group, n-nonyl group, n-decyl group, n-undecyl group, Lauryl group, n-tridecyl group, n-tetradecyl group, isopentyl group, neopentyl group, 2-methylpentyl group, 2-methylhexyl group, 2-ethylpentyl group, 3-ethylpentyl group, isooctyl group, 2-ethylhexyl group , 3-ethylhexyl group, isononyl group, 2-ethyloctyl group, isodecyl group, isododecyl group, isotridecyl group, isotetradecyl group, and the like.
  • Examples of unsaturated chain aliphatic groups having 5 to 14 carbon atoms include 1-pentenyl group, 2-pentenyl group, 1-hexenyl group, 2-hexenyl group, 1-heptenyl group, 2-heptenyl group, 1-octenyl group. , 2-octenyl group, nonenyl group, decenyl group, dodecenyl group, tridecenyl group, tetradecenyl group and the like.
  • the chain aliphatic group is preferably a saturated chain aliphatic group, more preferably a saturated straight chain aliphatic group.
  • the chain aliphatic group preferably has 6 or more carbon atoms, more preferably 7 or more carbon atoms, even more preferably 8 or more carbon atoms, and preferably 12 or less carbon atoms, more preferably has 10 or less carbon atoms, more preferably 9 or less carbon atoms.
  • the number of the above-mentioned chain aliphatic groups may be one, or two or more.
  • the chain aliphatic group is particularly preferably at least one selected from the group consisting of n-octyl group, isooctyl group, 2-ethylhexyl group, n-nonyl group, isononyl group, n-decyl group, and isodecyl group. More preferably at least one selected from the group consisting of n-octyl group, isooctyl group, 2-ethylhexyl group, n-nonyl group, and isononyl group, most preferably n-octyl group, isooctyl group, and At least one type selected from the group consisting of 2-ethylhexyl group.
  • the polyimide resin (A) preferably has only a chain aliphatic group having 5 to 14 carbon atoms at the end in addition to the terminal amino group and the terminal carboxy group.
  • the terminal group has a group other than the above, its content is preferably 10 mol % or less, more preferably 5 mol % or less, based on the chain aliphatic group having 5 to 14 carbon atoms.
  • the content of the above-mentioned chain aliphatic group having 5 to 14 carbon atoms in the polyimide resin (A) is set to 100% in total of all repeating structural units constituting the polyimide resin (A), from the viewpoint of exhibiting excellent heat aging resistance. Based on the mol%, it is preferably 0.01 mol% or more, more preferably 0.1 mol% or more, and still more preferably 0.2 mol% or more.
  • the content of the above-mentioned chain aliphatic groups having 5 to 14 carbon atoms in the polyimide resin (A) must be adjusted to It is preferably 10 mol% or less, more preferably 6 mol% or less, still more preferably 3.5 mol% or less, based on the total 100 mol% of all repeating structural units.
  • the content of the chain aliphatic group having 5 to 14 carbon atoms in the polyimide resin (A) can be determined by depolymerizing the polyimide resin (A).
  • the polyimide resin (A) has a melting point of 360°C or lower and a glass transition temperature of 150°C or higher.
  • the melting point Tm A of the polyimide resin (A) is preferably 270°C or higher, more preferably 280°C or higher, and even more preferably 290°C or higher, and from the viewpoint of exhibiting high moldability,
  • the temperature is preferably 345°C or lower, more preferably 340°C or lower, even more preferably 335°C or lower.
  • the glass transition temperature Tg of the polyimide resin (A) is preferably 160°C or higher, more preferably 170°C or higher from the viewpoint of heat resistance, and preferably 250°C or higher from the viewpoint of exhibiting high moldability. °C or less, more preferably 230°C or less, still more preferably 200°C or less.
  • the crystallization temperature Tc of the polyimide resin (A) is preferably 200°C or higher, more preferably 220°C or higher, even more preferably 250°C or higher, from the viewpoint of heat resistance, and from the viewpoint of moldability, preferably The temperature is 350°C or lower, more preferably 320°C or lower, even more preferably 300°C or lower.
  • the polyimide resin (A) has a heat of fusion Hm of preferably 5.0 mJ/mg or more, more preferably 10.0 mJ/mg or more, and Preferably it is 17.0 mJ/mg or more.
  • the upper limit of the heat of fusion Hm is not particularly limited, but is usually 45.0 mJ/mg or less.
  • the heat of fusion Hm of the polyimide resin (A) is determined by differential scanning calorimeter measurement by heating the polyimide resin (A) at a heating rate of 10°C/min to melt it at a temperature equal to or higher than its melting point, and then melting it at a temperature lowering rate of 20°C. This refers to the amount of heat at the peak of heat of fusion near the melting point observed when the material is cooled at a rate of 10° C./min and then heated again at a temperature increase rate of 10° C./min to melt it.
  • the polyimide resin (A) has a crystallization heat amount Hc of preferably 5.0 mJ/mg or more, more preferably 10.0 mJ/mg or more. , more preferably 17.0 mJ/mg or more.
  • the upper limit of the crystallization heat amount Hc is not particularly limited, but is usually 45.0 mJ/mg or less.
  • the crystallization heat amount Hc of the polyimide resin (A) is the heat amount of the crystallization exothermic peak observed when the polyimide resin (A) is melted and then cooled at a cooling rate of 20°C/min, as measured by a differential scanning calorimeter. means.
  • the melting point TmA , glass transition temperature Tg, crystallization temperature Tc, heat of fusion Hm, and crystallization heat Hc of the polyimide resin (A) can be specifically measured by the methods described in Examples.
  • the logarithmic viscosity of the 0.5% by mass concentrated sulfuric acid solution of the polyimide resin (A) at 30°C is preferably in the range of 0.2 to 2.0 dL/g, more preferably in the range of 0.3 to 1.8 dL/g. . If the logarithmic viscosity is 0.2 dL/g or more, sufficient mechanical strength can be obtained when the obtained thermoplastic resin composition is made into a molded product, and if it is 2.0 dL/g or less, molding processability and Improves handling properties.
  • the weight average molecular weight Mw of the polyimide resin (A) is preferably 10,000 to 150,000, more preferably 15,000 to 100,000, still more preferably 20,000 to 80,000, even more preferably 30, 000 to 70,000, more preferably 35,000 to 65,000. If the weight average molecular weight Mw of the polyimide resin (A) is 10,000 or more, the mechanical strength of the molded product obtained will be good; if it is 40,000 or more, the stability of the mechanical strength will be good; ,000 or less, moldability becomes good.
  • the weight average molecular weight Mw of the polyimide resin (A) can be measured by gel filtration chromatography (GPC) using polymethyl methacrylate (PMMA) as a standard sample.
  • Polyimide resin (A) can be manufactured by reacting a tetracarboxylic acid component and a diamine component.
  • the tetracarboxylic acid component contains a tetracarboxylic acid containing at least one aromatic ring and/or a derivative thereof
  • the diamine component contains a diamine containing at least one alicyclic hydrocarbon structure and a chain aliphatic diamine. .
  • the tetracarboxylic acid containing at least one aromatic ring is preferably a compound in which four carboxy groups are directly bonded to the aromatic ring, and may contain an alkyl group in its structure. Further, the tetracarboxylic acid preferably has 6 to 26 carbon atoms.
  • the tetracarboxylic acid include pyromellitic acid, 2,3,5,6-toluenetetracarboxylic acid, 3,3',4,4'-benzophenonetetracarboxylic acid, 3,3',4,4'-biphenyl Tetracarboxylic acid, 1,4,5,8-naphthalenetetracarboxylic acid and the like are preferred. Among these, pyromellitic acid is more preferred.
  • Examples of the derivative of tetracarboxylic acid containing at least one aromatic ring include anhydrides or alkyl esters of tetracarboxylic acid containing at least one aromatic ring.
  • the tetracarboxylic acid derivative preferably has 6 to 38 carbon atoms.
  • tetracarboxylic acid anhydrides include pyromellitic monoanhydride, pyromellitic dianhydride, 2,3,5,6-toluenetetracarboxylic dianhydride, 3,3',4,4'-diphenyl Sulfonetetracarboxylic dianhydride, 3,3',4,4'-benzophenonetetracarboxylic dianhydride, 3,3',4,4'-biphenyltetracarboxylic dianhydride, 1,4,5, Examples include 8-naphthalenetetracarboxylic dianhydride.
  • alkyl esters of tetracarboxylic acids include dimethyl pyromellitate, diethyl pyromellitate, dipropyl pyromellitate, diisopropyl pyromellitate, dimethyl 2,3,5,6-toluenetetracarboxylate, 3,3',4 , dimethyl 4'-diphenylsulfonetetracarboxylate, dimethyl 3,3',4,4'-benzophenonetetracarboxylate, dimethyl 3,3',4,4'-biphenyltetracarboxylate, 1,4,5,8 -Dimethyl naphthalenetetracarboxylate and the like.
  • the alkyl group preferably has 1 to 3 carbon atoms.
  • At least one compound selected from the above may be used alone, or two or more compounds may be used in combination.
  • the diamine containing at least one alicyclic hydrocarbon structure preferably has 6 to 22 carbon atoms, such as 1,2-bis(aminomethyl)cyclohexane, 1,3-bis(aminomethyl)cyclohexane, 1,4- Bis(aminomethyl)cyclohexane, 1,2-cyclohexanediamine, 1,3-cyclohexanediamine, 1,4-cyclohexanediamine, 4,4'-diaminodicyclohexylmethane, 4,4'-methylenebis(2-methylcyclohexylamine) , carbondiamine, limonenediamine, isophoronediamine, norbornanediamine, bis(aminomethyl)tricyclo[5.2.1.0 2,6 ]decane, 3,3'-dimethyl-4,4'-diaminodicyclohexylmethane, 4 , 4'-diaminodicyclohexylpropane and the like are preferred.
  • diamines containing an alicyclic hydrocarbon structure generally have structural isomers, but the ratio of cis/trans isomers is not limited.
  • the chain aliphatic diamine may be linear or branched, and preferably has 5 to 16 carbon atoms, more preferably 6 to 14 carbon atoms, and even more preferably 7 to 12 carbon atoms. Further, as long as the chain portion has 5 to 16 carbon atoms, an ether bond may be included therebetween.
  • chain aliphatic diamines examples include 1,5-pentamethylene diamine, 2-methylpentane-1,5-diamine, 3-methylpentane-1,5-diamine, 1,6-hexamethylene diamine, 1,7-hepta Methylenediamine, 1,8-octamethylenediamine, 1,9-nonamethylenediamine, 1,10-decamethylenediamine, 1,11-undecamethylenediamine, 1,12-dodecamethylenediamine, 1,13-trideca Preferred are methylene diamine, 1,14-tetradecamethylene diamine, 1,16-hexadecamethylene diamine, 2,2'-(ethylenedioxy)bis(ethyleneamine), and the like.
  • Chain aliphatic diamines may be used alone or in combination. Among these, chain aliphatic diamines having 8 to 10 carbon atoms can be preferably used, and at least one selected from the group consisting of 1,8-octamethylene diamine and 1,10-decamethylene diamine is particularly preferred. Can be used.
  • the ratio is preferably 15 to 70 mol%.
  • the molar amount is preferably 20 mol% or more, more preferably 25 mol% or more, still more preferably 30 mol% or more, even more preferably 32 mol% or more, and from the viewpoint of developing high crystallinity, preferably 60 mol% or more. It is less than mol %, more preferably less than 50 mol %, even more preferably less than 40 mol %, even more preferably less than 35 mol %.
  • the diamine component may contain a diamine containing at least one aromatic ring.
  • the diamine containing at least one aromatic ring preferably has 6 to 22 carbon atoms, such as orthoxylylene diamine, metaxylylene diamine, paraxylylene diamine, 1,2-diethynylbenzenediamine, 1,3-diethynyl Benzenediamine, 1,4-diethynylbenzenediamine, 1,2-diaminobenzene, 1,3-diaminobenzene, 1,4-diaminobenzene, 4,4'-diaminodiphenyl ether, 3,4'-diaminodiphenyl ether, 4 , 4'-diaminodiphenylmethane, ⁇ , ⁇ '-bis(4-aminophenyl)1,4-diisopropylbenzene, ⁇ , ⁇ '-bis(3-aminophenyl)-1,4-diisoprop
  • the molar ratio of the amount of diamine containing at least one aromatic ring to the total amount of diamine containing at least one alicyclic hydrocarbon structure and chain aliphatic diamine is 5 mol% or less.
  • the content is more preferably 20 mol% or less, still more preferably 15 mol% or less.
  • the content is preferably 5 mol% or more, more preferably 10 mol% or more.
  • the molar ratio is preferably 12 mol% or less, more preferably 10 mol% or less, still more preferably 5 mol% or less, and even more preferably 0 mol%. %.
  • the charging ratio of the tetracarboxylic acid component to the diamine component is preferably such that the diamine component is 0.9 to 1.1 mol per mol of the tetracarboxylic acid component. .
  • a terminal capping agent may be mixed in addition to the tetracarboxylic acid component and the diamine component.
  • the terminal capping agent is preferably at least one selected from the group consisting of monoamines and dicarboxylic acids.
  • the amount of the terminal capping agent to be used may be any amount that can introduce a desired amount of terminal groups into the polyimide resin (A), and is 0.0001 to 0.000% per mole of the tetracarboxylic acid and/or its derivative. It is preferably 1 mol, more preferably 0.001 to 0.06 mol, and even more preferably 0.002 to 0.035 mol.
  • monoamine end-capping agents are preferred as the terminal-capping agent, from the viewpoint of improving heat aging resistance by introducing the above-mentioned chain aliphatic group having 5 to 14 carbon atoms to the terminal of the polyimide resin (A).
  • monoamines having a linear aliphatic group having 5 to 14 carbon atoms are more preferred, and monoamines having a saturated linear aliphatic group having 5 to 14 carbon atoms are even more preferred.
  • the terminal capping agent is particularly preferably at least one selected from the group consisting of n-octylamine, isooctylamine, 2-ethylhexylamine, n-nonylamine, isononylamine, n-decylamine, and isodecylamine. , more preferably at least one selected from the group consisting of n-octylamine, isooctylamine, 2-ethylhexylamine, n-nonylamine, and isononylamine, and most preferably n-octylamine, isooctylamine, and 2-ethylhexylamine.
  • polymerization method for producing the polyimide resin (A) As a polymerization method for producing the polyimide resin (A), a known polymerization method can be applied, and the method described in International Publication No. 2016/147996 can be used.
  • thermoplastic resin composition of the present invention contains a specific crystalline thermoplastic polyimide resin (A) and a polyetherketoneketone resin (B).
  • Preferable examples of the polyetherketoneketone resin (B) include resins represented by the following structural formula (I). (In the formula, p and q each independently represent the number of constituent units.)
  • the resin represented by the structural formula (I) is manufactured using diphenyl ether, terephthalic acid chloride, and isophthalic acid chloride.
  • the molar ratio of the structural units derived from terephthalic acid chloride to the structural units derived from isophthalic acid chloride (hereinafter also referred to as "T/I ratio") ensures crystallinity. From the viewpoint of obtaining a sufficient crystallization temperature reduction effect when compounded with component (A), preferably 50/50 to 99/1, more preferably 50/50 to 90/10, even more preferably The ratio is 60/40 to 80/20, even more preferably 60/40 to 75/25, even more preferably 65/35 to 75/25.
  • the melting point Tm B of the polyetherketoneketone resin (B) is preferably 270°C or higher, more preferably 280°C or higher, and even more preferably 290°C or higher, from the viewpoint of heat resistance, from the viewpoint of exhibiting high moldability.
  • the temperature is preferably 360°C or lower, more preferably 345°C or lower, even more preferably 340°C or lower, even more preferably 335°C or lower.
  • the glass transition temperature of the polyetherketoneketone resin (B) is preferably 140°C or higher, more preferably 150°C or higher, from the viewpoint of heat resistance, and preferably 200°C or lower, from the viewpoint of exhibiting high moldability. More preferably it is 180°C or lower.
  • the melting point Tm B and glass transition temperature of the polyetherketoneketone resin (B) can both be measured using a differential scanning calorimeter in the same manner as for component (A).
  • polyetherketoneketone resin (B) commercially available products such as polyetherketoneketone resin (PEKK) 6000 series, 7000 series, and 8000 series manufactured by ARKEMA can also be used.
  • PEKK polyetherketoneketone resin
  • is the effect of reducing the crystallization temperature.
  • the temperature is 0 to 40°C, preferably 0 to 30°C, more preferably 0 to 20°C, and still more preferably 0 to 15°C. If
  • the melting point Tm A of component ( A ) and the melting point Tm B of component ( B ) used in the thermoplastic resin composition are both determined from the viewpoint of improving crystallinity and heat resistance, and from the viewpoint of ensuring appropriate crystallinity.
  • the temperature range is preferably from 270 to 360°C, more preferably from 280 to 350°C, even more preferably from 290 to 345°C.
  • the mass ratio of component (A) and component (B) in the thermoplastic resin composition is preferably 1/99 to 1/99 from the viewpoint of improving the crystallization temperature reduction effect and ensuring appropriate crystallinity.
  • the ratio is 80/20, more preferably 5/95 to 70/30, even more preferably 10/90 to 70/30, even more preferably 15/85 to 70/30.
  • the thermoplastic resin composition of the present invention may further contain a filler depending on desired performance.
  • the shape of the filler is not particularly limited, and any of granular, plate-like, and fibrous fillers can be used.
  • the particle size of the granular or plate-like filler can be appropriately selected depending on the use of the thermoplastic resin composition, etc., but it is important to maintain the molding processability of the thermoplastic resin composition and the machine processing of the resulting molded product. From the viewpoint of improving physical strength etc., the average particle size is preferably 0.1 to 200 ⁇ m, more preferably 0.5 to 100 ⁇ m.
  • the filler is preferably an inorganic filler from the viewpoint of heat resistance.
  • Granular or plate-like inorganic fillers include silica, alumina, kaolinite, wollastonite, mica, talc, clay, sericite, magnesium carbonate, barium carbonate, magnesium sulfate, barium sulfate, calcium oxide, silicon carbide, Examples include antimony sulfide, tin sulfide, copper sulfide, iron sulfide, bismuth sulfide, zinc sulfide, and glass. Note that the glass may be glass powder, glass flakes, or glass beads.
  • fibrous inorganic fillers examples include glass fiber, carbon fiber, metal fiber, graphite fiber, silica fiber, silica/alumina fiber, alumina fiber, zirconia fiber, boron nitride fiber, silicon nitride fiber, boron fiber, and potassium titanate whiskers. , aluminum borate whiskers, magnesium whiskers, silicon whiskers, and the like. Note that these inorganic fillers may be surface-treated.
  • the content of the filler in the thermoplastic resin composition varies depending on the desired performance, but is preferably 0.05 to 70% by mass, more preferably 0.05% by mass.
  • the amount is 1 to 50% by weight, more preferably 1 to 30% by weight.
  • thermoplastic resin composition of the present invention includes a matting agent, a plasticizer, an antistatic agent, an anticoloring agent, an antigelation agent, a coloring agent, a sliding property improver, an antioxidant, and an ultraviolet ray protector.
  • Additives such as a conductive agent, a conductive agent, and a resin modifier can be added as necessary.
  • heat In the plastic resin composition it is usually 50% by mass or less, preferably 0.0001 to 30% by mass, more preferably 0.001 to 15% by mass, and even more preferably 0.01 to 10% by mass.
  • the other resin is preferably a highly heat-resistant thermoplastic resin, such as polyamide resin, polyester resin, polyimide resin other than polyimide resin (A), polycarbonate resin, polyetherimide resin, polyamideimide resin, polyphenylene etherimide. resin, polyphenylene sulfide resin, polysulfone resin, polyether sulfone resin, polyarylate resin, liquid crystal polymer, polyether ether ketone resin, polyether ketone resin, polyether ether ketone ketone resin, polybenzimidazole resin, and the like.
  • a highly heat-resistant thermoplastic resin such as polyamide resin, polyester resin, polyimide resin other than polyimide resin (A), polycarbonate resin, polyetherimide resin, polyamideimide resin, polyphenylene etherimide. resin, polyphenylene sulfide resin, polysulfone resin, polyether sulfone resin, polyarylate resin, liquid crystal polymer, polyether ether ketone resin, polyether ket
  • the total content of component (A) and component (B) in the thermoplastic resin composition of the present invention is preferably 30% by mass or more, more preferably The content is 40% by mass or more, more preferably 50% by mass or more, even more preferably 70% by mass or more, even more preferably 80% by mass or more, even more preferably 90% by mass or more, and 100% by mass or less.
  • thermoplastic resin composition of the present invention can take any form, it is preferably in the form of pellets.
  • the thermoplastic resin composition of the present invention is in the form of pellets, for example, after dry blending the polyimide resin (A), polyetherketoneketone resin (B), and various optional components as necessary, Alternatively, after feeding the polyetherketoneketone resin (B) and any optional components separately from the feeding of the polyimide resin (A) to the extruder, the strands are extruded by melt-kneading in the extruder. It can be made into pellets by cutting.
  • the thermoplastic resin composition of the present invention preferably does not contain a solvent from the viewpoint of forming it into pellets.
  • the content of the solvent in the thermoplastic resin composition is preferably 5% by mass or less, more preferably 1% by mass or less, and still more preferably 0.1% by mass or less.
  • the thermoplastic resin composition preferably has a heat of crystallization Hc of 10 mJ/mg or more, more preferably 15 mJ/mg or more, and still more preferably 17 mJ/mg or more.
  • the upper limit of the heat of crystallization Hc of the thermoplastic resin composition is not particularly limited, but is usually 45 mJ/mg or less.
  • the thermoplastic resin composition has a melting point Tm, and the melting point Tm and the crystallization temperature Tc of the thermoplastic resin composition It is preferable that the difference (Tm - Tc) is 65°C or more.
  • (Tm-Tc) is more preferably 70°C or higher, still more preferably 80°C or higher, even more preferably 95°C or higher.
  • the upper limit of (Tm-Tc) is not particularly limited, but is usually 150°C or less.
  • the melting point Tm of the thermoplastic resin composition is preferably 270°C or higher, more preferably 280°C or higher, even more preferably 290°C or higher, even more preferably 320°C or higher, and has high thermoformability.
  • the temperature is preferably 360°C or lower, more preferably 345°C or lower, even more preferably 340°C or lower, even more preferably 335°C or lower.
  • the heat of crystallization Hc, melting point, and crystallization temperature of the thermoplastic resin composition can be measured in the same manner as described above.
  • the Tc MIN of the thermoplastic resin composition is preferably 190°C or higher, more preferably 200°C or higher, and even more preferably 220°C or higher, from the viewpoint of ensuring sufficient crystallinity, and from the viewpoint of developing sufficient adhesiveness.
  • the temperature is preferably 300°C or lower, more preferably 270°C or lower, and even more preferably 255°C or lower.
  • the present invention provides a molded article containing the thermoplastic resin composition. Since the thermoplastic resin composition of the present invention has thermoplasticity, the molded article of the present invention can be easily produced by thermoforming.
  • thermoforming methods include injection molding, extrusion molding, inflation molding, blow molding, hot press molding, vacuum forming, pressure forming, laser molding, welding, welding, and 3D printer molding. Molding is possible using any method.
  • Thermoforming is preferable because molding can be performed without setting the molding temperature to a high temperature exceeding, for example, 400°C.
  • injection molding is preferred because molding can be performed without setting the molding temperature and the mold temperature during molding to high temperatures.
  • the molding temperature is preferably 400°C or lower, more preferably 360°C or lower, and the mold temperature is preferably 260°C or lower, more preferably 220°C or lower.
  • the pellets are introduced into various molding machines and thermoformed, preferably at 290 to 360°C, to form the molded body into a desired shape. body can be manufactured.
  • the shape of the molded article of the present invention is not particularly limited, and examples thereof include sheets, films, strands, filaments, and the like. These may be intermediate members of industrial products or may be final products.
  • a filament-shaped molded object can be easily produced. That is, according to the present invention, a filament containing the thermoplastic resin composition can be provided.
  • the shape of the filament is not particularly limited, but from the viewpoint of production using a 3D printer molding method, the filament diameter is preferably 10 mm or less, more preferably 5 mm or less, still more preferably 3.5 mm or less, and preferably 0. .1 mm or more.
  • the molded article of the present invention may be a fiber-reinforced composite material obtained by impregnating continuous fibers such as carbon fibers and glass fibers with the thermoplastic resin composition.
  • the thermoplastic resin composition and molded article of the present invention preferably have a lamella-like microphase-separated structure.
  • the term "lamellar-like microphase-separated structure” refers to a substantially layered or fibrous microphase-separated structure, for example, when observing the surface or cross section of a thermoplastic resin composition or molded article using a scanning transmission electron microscope (STEM). It can be determined by The aspect ratio of the substantially layered or fibrous phase-separated structure in the lamella-like microphase-separated structure is preferably 4 or more, more preferably 5 or more, and usually 200 or less. Observation of the microphase separation structure of a thermoplastic resin composition or a molded article can be performed by the method described in Examples.
  • thermoplastic resin composition of the present invention has heat resistance and crystallinity, suppresses an increase in crystallization temperature, has good thermoformability, and is less likely to cause a decrease in adhesion or sink marks during three-dimensional modeling. Therefore, it is suitable as a molding material for 3D printers, for example.
  • the thermoplastic resin composition of the present invention exhibits good adhesion to adherends due to the effect of lowering the crystallization temperature, and has high heat resistance, so it can be used for bonding sheets, metal foil laminates such as copper-clad laminates, etc. Also suitable for use. Therefore, the present invention can provide a three-dimensional modeling material and a bonding sheet containing the thermoplastic resin composition. Further, the present invention can provide a metal foil laminate having a layer made of a molded body containing the thermoplastic resin composition and a layer made of metal foil.
  • metal foil laminates include mainly copper-clad laminates, and the copper-clad laminates include a layer consisting of a film-shaped molded body containing the thermoplastic resin composition (hereinafter also simply referred to as a "resin film layer"). ) and at least one copper foil layer.
  • the copper-clad laminates include a layer consisting of a film-shaped molded body containing the thermoplastic resin composition (hereinafter also simply referred to as a "resin film layer").
  • the resin film used for manufacturing the copper-clad laminate can be manufactured by the same method as the method for manufacturing the molded body.
  • the thickness of the resin film and the resin film layer in the copper-clad laminate is preferably 5 to 500 ⁇ m from the viewpoint of ensuring the strength of the copper-clad laminate and improving the adhesiveness between the resin film layer and the copper foil layer. , more preferably 10 to 300 ⁇ m, still more preferably 12.5 to 200 ⁇ m.
  • the copper foil used for manufacturing the copper-clad laminate is not particularly limited, and commercially available rolled copper foil, electrolytic copper foil, etc. can be used, but rolled copper foil is preferred from the viewpoint of flexibility.
  • the thickness of the copper foil layer and the copper foil used for its formation is preferably 2 to 50 ⁇ m, more preferably 3 to 30 ⁇ m, from the viewpoint of ensuring sufficient conductivity and improving adhesiveness with the resin film layer. More preferably, it is 5 to 20 ⁇ m.
  • the thickness is the thickness per copper foil layer or per copper foil.
  • the surface roughness of the copper foil used to manufacture copper-clad laminates is not particularly limited, but the surface roughness of the copper foil is directly connected to the electrical properties of the laminate itself obtained after laminating the resin film, and is generally Generally speaking, the lower the roughness, the better the dielectric properties of the laminate. Therefore, the value of the maximum height roughness Rz of the surface of the copper foil is preferably in the range of 0.1 to 1 ⁇ m, more preferably in the range of 0.2 to 0.8 ⁇ m. The maximum height roughness Rz of the surface of the copper foil can be measured using, for example, a surface roughness meter.
  • the thickness of the copper-clad laminate is preferably 15 to 600 ⁇ m, more preferably 25 to 500 ⁇ m, and still more preferably 50 to 300 ⁇ m, from the viewpoint of improving the strength and conductivity of the copper-clad laminate.
  • the copper-clad laminate may have any layer other than the resin film layer and copper foil layer as long as the effects of the present invention are not impaired.
  • the method for manufacturing the copper-clad laminate is not particularly limited, and any known method can be used. For example, there is a method of laminating the resin film and copper foil by overlapping them and then bonding them together under heat and pressure conditions. Since the resin film contains a thermoplastic polyimide resin (A), it can be bonded to a copper foil by pressing the surface in a thermally molten state.
  • the equipment used to manufacture the copper-clad laminate may be any equipment that can bond the resin film and copper foil together under heating and pressure conditions, such as a roll laminator, flat plate laminator, vacuum press equipment, Examples include double belt press equipment.
  • a vacuum press device or a double belt press device is equipped with a pair of upper and lower endless belts, and between the belts, film-shaped materials (resin film and copper foil) forming each layer are continuously fed and heated through the endless belts.
  • This device is capable of manufacturing a laminate by heating and press-molding the material using a pressure mechanism.
  • Examples of the double belt press device include the device described in Japanese Unexamined Patent Publication No. 2010-221694, the double belt press device manufactured by Dimco Co., Ltd., and the like.
  • the heating temperature when manufacturing a copper-clad laminate by the above method is not particularly limited as long as it is a temperature that can soften or melt the resin film, but from the viewpoint of reducing the burden on the equipment and manufacturing, it is preferably The temperature range is from 250 to 400°C, more preferably from 280 to 350°C.
  • the pressure conditions when manufacturing a copper-clad laminate are preferably 0.1 to 0.1 to 0.0, from the viewpoint of improving the adhesion between the resin film and the copper foil, and from the viewpoint of reducing the burden on equipment and manufacturing. 20 MPa, more preferably 0.15 to 15 MPa, even more preferably 0.2 to 12 MPa.
  • the pressurizing time is preferably in the range of 1 to 600 seconds, more preferably 5 to 400 seconds, and still more preferably 10 to 300 seconds.
  • the resin film is characterized in that it can be thermally welded, it is also possible to bond the resin film and copper foil together using an adhesive in the production of a copper-clad laminate.
  • the adhesive may be arbitrarily selected from varnish-like adhesives, sheet-like adhesives, powder-like adhesives, and the like.
  • the adhesive has low dielectric properties. Examples of adhesives with low dielectric properties include the polyimide adhesive "PIAD" series manufactured by Arakawa Chemical Industries, Ltd.
  • thermoplastic resin composition or molded article of the present invention include transportation equipment (automobiles, aircraft, etc.), industrial equipment, electrical and electronic components, semiconductor/liquid crystal manufacturing equipment parts (wafer carriers, IC trays, transport rollers, etc.) , food and beverage manufacturing equipment parts, medical equipment parts (housings for various instruments, sterilization instruments, disinfection instruments, biological materials, HPLC columns, filters, infusion pump gears, equipment handles, etc.), aircraft parts (clips, bracket fasteners, structural parts, (compartment retainers, vent grills, etc.), satellite parts, insulation films, copier belt films, switches, connectors, motor parts, bearings, seal rings, gears, compressor rings, valves, tubes, ABS braking systems, transmission parts.
  • transportation equipment automobiles, aircraft, etc.
  • industrial equipment electrical and electronic components
  • semiconductor/liquid crystal manufacturing equipment parts wafer carriers, IC trays, transport rollers, etc.
  • food and beverage manufacturing equipment parts food and beverage manufacturing equipment parts
  • medical equipment parts housings for various instruments, sterilization
  • IR measurement of the polyimide resin was performed using "JIR-WINSPEC50" manufactured by JEOL Ltd.
  • ⁇ Logarithmic viscosity ⁇ > After drying the polyimide resin at 190 to 200°C for 2 hours, a polyimide resin solution prepared by dissolving 0.100 g of the polyimide resin in 20 mL of concentrated sulfuric acid (96%, manufactured by Kanto Kagaku Co., Ltd.) was used as a measurement sample, and the Cannon-Fenske viscosity was measured. Measurements were made at 30°C using a meter.
  • the thermal history conditions were as follows: first temperature increase (temperature increase rate: 10°C/min), then cooling (temperature decrease rate: 20°C/min), and then second temperature increase (temperature increase rate: 10°C/min).
  • the melting point Tm was determined by reading the peak top value of the endothermic peak observed at the second temperature rise.
  • the glass transition temperature Tg was determined by reading the value observed at the second temperature rise.
  • the crystallization temperature Tc was determined by reading the peak top value of the exothermic peak observed during cooling. Regarding Tm, Tg, and Tc, if multiple peaks were observed, the peak top value of each peak was read.
  • the heat of fusion Hm (mJ/mg) is determined by heating the measurement sample at a heating rate of 10°C/min to a temperature above the melting point to melt it, cooling it at a cooling rate of 20°C/min, and raising the temperature again. It was calculated from the area of the heat of fusion peak (endothermic peak) near the melting point observed when melting at a rate of 10° C./min.
  • the heat of crystallization Hc (mJ/mg) was observed when the measurement sample was heated to a temperature above the melting point at a heating rate of 10°C/min to melt it, and then cooled at a cooling rate of 20°C/min. It was calculated from the area of the crystallization exothermic peak.
  • ⁇ Half crystallization time> The half-crystallization time of the polyimide resin was measured using a differential scanning calorimeter device (“DSC-6220” manufactured by SII Nano Technology Co., Ltd.). After completely melting the polyimide resin by holding it at 420°C for 10 minutes in a nitrogen atmosphere, a rapid cooling operation was performed at a cooling rate of 70°C/min. I calculated the time it took to reach it. In Table 1, when the half crystallization time was 20 seconds or less, it was written as " ⁇ 20".
  • thermoplastic resin alone used in each example or the thermoplastic resin composition obtained in each example
  • a molded article of 80 mm x 10 mm x 4 mm thickness was manufactured by the method described below and used for measurement. .
  • the measurement was conducted in accordance with JIS K7191-1, 2:2015, and a flatwise test was performed.
  • an HDT test device "Auto-HDT3D-2" manufactured by Toyo Seiki Seisakusho Co., Ltd.
  • heat was applied under the conditions of a distance between fulcrums of 64 mm, a load of 1.80 MPa, and a heating rate of 120°C/hour.
  • the deformation temperature was measured.
  • Production example 1 (manufacture of polyimide resin 1) 500 g of 2-(2-methoxyethoxy) ethanol (manufactured by Nippon Nyukazai Co., Ltd.) and pyromellitic dianhydride ( 218.12 g (1.00 mol) of Mitsubishi Gas Chemical Co., Ltd. was introduced, and after nitrogen flow, the mixture was stirred at 150 rpm to form a uniform suspension solution.
  • 1,8- A mixed diamine solution was prepared by dissolving 93.77 g (0.65 mol) of octamethylene diamine (manufactured by Kanto Kagaku Co., Ltd.) in 250 g of 2-(2-methoxyethoxy)ethanol.
  • the mixed diamine solution was added slowly using a plunger pump. Although heat generation occurred during dropping, the internal temperature was adjusted to within 40 to 80°C.
  • polyimide resin 1 In the process of increasing the temperature, precipitation of polyimide resin powder and dehydration due to imidization were observed when the liquid temperature ranged from 120 to 140°C. After holding at 190°C for 30 minutes, the mixture was allowed to cool to room temperature and filtered. The obtained polyimide resin powder was washed with 300 g of 2-(2-methoxyethoxy)ethanol and 300 g of methanol, filtered, and then dried in a dryer at 180°C for 10 hours to obtain 317 g of crystalline thermoplastic polyimide resin 1. (hereinafter also simply referred to as "polyimide resin 1”) powder was obtained.
  • Production example 2 production of polyimide resin 2 769 g of 2-(2-methoxyethoxy) ethanol (manufactured by Nippon Nyukazai Co., Ltd.) and pyromellitic dianhydride ( 174.50 g (0.80 mol) of Mitsubishi Gas Chemical Co., Ltd. was introduced, and after nitrogen flow, the mixture was stirred at 150 rpm to form a uniform suspension solution.
  • 1,8- A mixed diamine solution was prepared by dissolving 80.79 g (0.56 mol) of octamethylene diamine (manufactured by Kanto Kagaku Co., Ltd.) in 250 g of 2-(2-methoxyethoxy)ethanol. The mixed diamine solution was added slowly using a plunger pump. Although heat generation occurred during dropping, the internal temperature was adjusted to within 40 to 80°C.
  • polyimide resin 2 In the process of increasing the temperature, precipitation of polyimide resin powder and dehydration due to imidization were observed when the liquid temperature ranged from 120 to 140°C. After being held at 185° C. for 30 minutes, the mixture was allowed to cool to room temperature and filtered. The obtained polyimide resin powder was washed with 600 g of methanol, filtered, and then dried in a dryer at 185°C for 10 hours to obtain 256 g of crystalline thermoplastic polyimide resin 2 (hereinafter also simply referred to as "polyimide resin 2"). ) powder was obtained.
  • Polyimide resin 2 had a Tm of 330°C, a Tg of 179°C, a Tc of 278°C, a heat of fusion of 34 mJ/mg, a heat of crystallization of 32 mJ/mg, and a Mw of 37,000.
  • Production example 3 production of polyimide resin 3) 769 g of 2-(2-methoxyethoxy) ethanol (manufactured by Nippon Nyukazai Co., Ltd.) and pyromellitic dianhydride ( 174.50 g (0.80 mol) of Mitsubishi Gas Chemical Co., Ltd. was introduced, and after nitrogen flow, the mixture was stirred at 150 rpm to form a uniform suspension solution.
  • 1,8- A mixed diamine solution was prepared by dissolving 92.33 g (0.64 mol) of octamethylene diamine (manufactured by Kanto Kagaku Co., Ltd.) in 250 g of 2-(2-methoxyethoxy)ethanol.
  • the mixed diamine solution was added slowly using a plunger pump. Although heat generation occurred during dropping, the internal temperature was adjusted to within 40 to 80°C.
  • polyimide resin 3 crystalline thermoplastic polyimide resin 3 (hereinafter also simply referred to as "polyimide resin 3"). ) powder was obtained.
  • Tm was 344°C
  • Tg was 166°C
  • Tc was 299°C
  • heat of fusion was 40 mJ/mg
  • heat of crystallization was 35 mJ/mg
  • Mw was 36,000.
  • Production example 4 production of polyimide resin 4) 650 g of 2-(2-methoxyethoxy) ethanol (manufactured by Nippon Nyukazai Co., Ltd.) and pyromellitic dianhydride ( After introducing 257.75 g (1.180 mol) of Mitsubishi Gas Chemical Co., Ltd. and creating a nitrogen flow, the mixture was stirred at 150 rpm to form a uniform suspension solution.
  • a mixed diamine solution was prepared by dissolving in 250 g of -(2-methoxyethoxy)ethanol.
  • the mixed diamine solution was added slowly using a plunger pump. Although heat generation occurred during dropping, the internal temperature was adjusted to within 40 to 80°C.
  • a nitrogen flow state was maintained throughout, and the rotation speed of the stirring blade was 250 rpm.
  • 100 g of 2-(2-methoxyethoxy)ethanol and 2.270 g (0.0176 mol) of n-octylamine (manufactured by Kanto Kagaku Co., Ltd.) as an end capping agent were added and further stirred. .
  • Table 1 shows the composition and evaluation results of the polyimide resins (A) obtained in Production Examples 1 to 4.
  • the mol% of the tetracarboxylic acid component and the diamine component in Table 1 is a value calculated from the amount of each component charged at the time of producing the polyimide resin.
  • Table 1 The abbreviations in Table 1 are as follows. ⁇ PMDA; Pyromellitic dianhydride ⁇ 1,3-BAC; 1,3-bis(aminomethyl)cyclohexane ⁇ OMDA; 1,8-octamethylenediamine ⁇ HMDA; 1,6-hexamethylenediamine ⁇ ODA; 4 , 4'-diaminodiphenyl ether/n-OcA; n-octylamine/BzA; benzylamine
  • the strand extruded from the extruder was air-cooled and then pelletized using a pelletizer ("Fan Cutter FC-Mini-4/N” manufactured by Hoshi Plastics Co., Ltd.).
  • the obtained pellets were dried at 150° C. for 12 hours and then used for injection molding.
  • Injection molding was performed using an injection molding machine (“Roboshot ⁇ -S130iA” manufactured by Fanuc Corporation) at a barrel temperature of 360°C, a mold temperature of 200°C, and a molding cycle of 207 seconds, and the above evaluation (HDT measurement) was performed.
  • An injection molded article of a predetermined shape was produced.
  • various evaluations were performed using the methods described above. The results are shown in Table 2.
  • Example 2 Same as Example 1 except that the powder of polyimide resin 1 obtained in Production Example 1 and the pellets of polyetherketoneketone resin were used in the ratio shown in Table 2, and injection molding was performed at a molding cycle of 244 seconds. Pellets and injection molded products were produced and various evaluations were performed. The results are shown in Table 2.
  • Example 3 Same as Example 1 except that the powder of polyimide resin 1 obtained in Production Example 1 and the pellets of polyetherketoneketone resin were used in the ratio shown in Table 2, and injection molding was performed at a molding cycle of 224 seconds. Pellets and injection molded products were produced and various evaluations were performed. The results are shown in Table 2.
  • Example 4 Same as Example 1 except that the powder of polyimide resin 1 obtained in Production Example 1 and the pellets of polyetherketoneketone resin were used in the ratio shown in Table 2, and injection molding was performed at a molding cycle of 374 seconds. Pellets and injection molded products were produced and various evaluations were performed. The results are shown in Table 2.
  • Comparative example 1 The powder of polyimide resin 1 obtained in Production Example 1 was melt-kneaded and extruded using a Laboplast Mill (manufactured by Toyo Seiki Seisakusho Co., Ltd.) at a barrel temperature of 360° C. and a screw rotation speed of 150 rpm. The strand extruded from the extruder was air-cooled and then pelletized using a pelletizer ("Fan Cutter FC-Mini-4/N" manufactured by Hoshi Plastics Co., Ltd.). The obtained pellets were dried at 150° C. for 12 hours and then used for injection molding.
  • a Laboplast Mill manufactured by Toyo Seiki Seisakusho Co., Ltd.
  • Injection molding was performed using an injection molding machine ("ROBOSHOT ⁇ -S30iA" manufactured by Fanuc Corporation) at a barrel temperature of 350 °C, a mold temperature of 200 °C, and a molding cycle of 50 seconds, and used for the above evaluation (HDT measurement). An injection molded article having a predetermined shape was produced. Using the obtained pellets or injection molded products, various evaluations were performed using the methods described above. The results are shown in Table 2.
  • Comparative example 2 The pellets of the polyetherketoneketone resin ("7002" manufactured by ARKEMA) were dried at 160° C. for 6 hours and then used for injection molding. Injection molding was performed using an injection molding machine (“ROBOSHOT ⁇ -S130iA” manufactured by Fanuc Corporation) at a barrel temperature of 360°C, a mold temperature of 200°C, and a molding cycle of 404 seconds, and used for the above evaluation (HDT measurement). An injection molded article having a predetermined shape was produced. Using the obtained pellets or injection molded products, various evaluations were performed using the methods described above. The results are shown in Table 2.
  • ROBOSHOT ⁇ -S130iA manufactured by Fanuc Corporation
  • Comparative example 4 The polyether ether ketone resin ("PEEK 90G” manufactured by VICTREX) was melt-kneaded and extruded using a Laboplast Mill (manufactured by Toyo Seiki Seisakusho Co., Ltd.) at a barrel temperature of 350° C. and a screw rotation speed of 150 rpm. The strand extruded from the extruder was air-cooled and then pelletized using a pelletizer ("Fan Cutter FC-Mini-4/N" manufactured by Hoshi Plastics Co., Ltd.). The obtained pellets were dried at 160° C. for 6 hours and then used for injection molding.
  • Injection molding was performed using an injection molding machine (“ROBOSHOT ⁇ -S30iA” manufactured by Fanuc Corporation) at a barrel temperature of 350°C, a mold temperature of 195°C, and a molding cycle of 60 seconds, and used for the above evaluation (HDT measurement). An injection molded article having a predetermined shape was produced. Using the obtained pellets or injection molded products, various evaluations were performed using the methods described above. The results are shown in Table 2.
  • Comparative examples 5 to 7 pellets were produced in the same manner as in Comparative Example 1, except that the polyimide resin powder listed in Table 2 was used instead of the polyimide resin 1 powder, and various evaluations were performed. The results are shown in Table 2.
  • Example 4 pellets were produced in the same manner as in Example 4, except that the polyimide resin powder listed in Table 2 was used instead of the polyimide resin 1 powder, and various evaluations were performed. The results are shown in Table 2.
  • the minimum crystallization temperature Tc MIN of the thermoplastic resin composition of this example is the crystallization temperature of component (A) or component (B) alone, which is the raw material resin. It can be seen that it is lower than Tc. Further, all of the thermoplastic resin compositions of this example have a heat of crystallization Hc of 10 mJ/mg or more, and maintain sufficient crystallinity. In addition, the value of (Tm-Tc MIN ) of the thermoplastic resin composition of this example is higher than the value of component (A) or component (B) alone, which is the raw resin, and is more suitable for thermoforming. It is thought that the material has similar physical properties.
  • Example 3 Furthermore, the morphology of the pellets and injection molded products obtained in Example 3 was confirmed by the following method.
  • the pellet obtained in Example 3 was examined using an ultramicrotome (Leica Microsystems "EM UC7") in a direction perpendicular to the flow direction (MD) of the pellet (that is, the TD cross section was In Figure 1, 1 is a pellet and 2 is an ultra-thin section. After staining this section for 30 minutes in the gas phase of ruthenium tetroxide, it was stained using a field emission scanning transmission electron microscope (FE-STEM, "GeminiSEM500” manufactured by ZEISS) at an acceleration voltage of 30 kV and an observation magnification of 30,000 times. Transmission observation was performed using a STEM detector ( Figure 2).
  • FE-STEM field emission scanning transmission electron microscope
  • Example 3 the injection molded product obtained in Example 3 was cut in the direction perpendicular to the machine direction (MD) of the test section of the multipurpose test piece of the injection molded product using a diamond wheel saw (“MODEL650” manufactured by SOUTHBAY TECHNOLOGY). That is, the specimen was cut so that the TD cross section was exposed, and the central portion of the test portion was cut out. An ultrathin section was prepared from near the center of the cut cross section using an ultramicrotome in the same manner as the pellet.
  • MD machine direction
  • Example 8 (Production and evaluation of film, and evaluation of adhesion between the film and copper foil) ⁇ Production of film> After drying the pellets of the thermoplastic resin composition obtained in Example 3 at 150°C for 10 hours, they were put into a ⁇ 20mm single-screw extrusion molding machine equipped with a 150mm wide T die, and the resin temperature was adjusted to 350 to 360°C. The mixture was melted and kneaded. The melt-kneaded thermoplastic resin composition was continuously extruded from a T-die of a single-screw extruder, and then cooled with a metal roll, which is a cooling roll at 140°C, to obtain a film with a thickness of 50 ⁇ m.
  • the temperature of the ⁇ 20 mm single screw extruder was set at 335 to 340°C
  • the temperature of the T die was set at 335°C.
  • Total light transmittance The total light transmittance (%) of the film was measured in accordance with JIS K7361-1:1997 using a simultaneous color and turbidity meter ("COH400" manufactured by Nippon Denshoku Kogyo Co., Ltd.).
  • YI> The YI value of the film was measured in accordance with JIS K7373:2006 using a simultaneous color and turbidity meter ("COH400" manufactured by Nippon Denshoku Kogyo Co., Ltd.).
  • the dielectric constant and dielectric loss tangent of the film were determined in accordance with IEC 62810 using "PNA-L Network Analyzer N5230A” manufactured by Agilent Technologies Co., Ltd. and a cavity resonator "CP531” manufactured by Kanto Denshi Application Development Co., Ltd.
  • the heat sealing conditions were a temperature of 250° C. and a pressure of 0.4 MPa (gauge pressure) for 60 seconds. After heat-sealing, the release paper was removed and the film was cut in the MD direction shown in FIG. 6(a) to produce a strip-shaped test piece with a width of 1 cm (FIG. 6(b)). The bonding area between the film 3a' and the copper foil 4' in FIG. 6(b) is 1 cm 2 . Next, when holding the short side of the film 3a' of the obtained test piece and hanging it so that the long side is parallel to the direction of gravity as shown in Fig. 7, the lower copper foil 4' If it did not fall, it was determined that it had adhesive properties.
  • Test piece was prepared in the same manner as in the evaluation of "adhesiveness to copper foil” and used for evaluation. Place the test piece in the grip of a universal testing machine (“Strograph VG” manufactured by Toyo Seiki Seisakusho Co., Ltd.) so that the upper side is the film and the lower side is the copper foil, with the long side parallel to the direction of gravity. installed ( Figure 7).
  • a tensile shear test was conducted in accordance with JIS K 6849-1994 at a temperature of 23° C., a test range of 200 N, and a test speed of 5 mm/min to determine the tensile adhesive strength (N/cm 2 ).
  • Example 9 Comparative Examples 8 to 10 A film was produced and evaluated in the same manner as in Example 8, except that the thermoplastic resin composition used for producing the film was changed to the thermoplastic resin or thermoplastic resin composition listed in Table 3. . The results are shown in Table 3.
  • the film made of the thermoplastic resin composition of the present invention shows a significant decrease in total light transmittance or an extreme increase in Haze, YI, etc., even when compared to a film made of one type of thermoplastic resin. It is transparent and has no problems. Furthermore, it exhibits a low dielectric constant and a low dielectric loss tangent, and can ensure adhesion between films and between films and copper foil. Note that, as shown in Comparative Example 10, the PEEK film has low adhesion to copper foil.
  • thermoplastic resin composition of the present invention has heat resistance and crystallinity, suppresses the increase in crystallization temperature, has good thermoformability, and does not easily cause adhesive deterioration or sink marks during three-dimensional modeling.
  • it is suitable as a molding material for a 3D printer.
  • thermoplastic resin composition of the present invention exhibits good adhesion to adherends due to the effect of lowering the crystallization temperature, and has high heat resistance, so it can be used for bonding sheets, metal foil laminates such as copper-clad laminates, etc. Also suitable for use.

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CN119384466A (zh) 2025-01-28
TW202411350A (zh) 2024-03-16
KR20250036803A (ko) 2025-03-14

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