WO2024005839A1 - Synthèse à base aqueuse de structures organométalliques - Google Patents

Synthèse à base aqueuse de structures organométalliques Download PDF

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Publication number
WO2024005839A1
WO2024005839A1 PCT/US2022/035925 US2022035925W WO2024005839A1 WO 2024005839 A1 WO2024005839 A1 WO 2024005839A1 US 2022035925 W US2022035925 W US 2022035925W WO 2024005839 A1 WO2024005839 A1 WO 2024005839A1
Authority
WO
WIPO (PCT)
Prior art keywords
metal
linker
organic framework
solvent
disalicylate
Prior art date
Application number
PCT/US2022/035925
Other languages
English (en)
Inventor
Anna C. IVASHKO
Carter W. ABNEY
Nicole M. HERB
Preeti Kamakoti
Aaron W. PETERS
Mathew T. KAPELEWSKI
Marc H. Anthonis
Roxana PEREZ VELEZ
Nadya A. HRYCENKO
Doron Levin
Tara L. REDDINGTON
Scott J. WEIGEL
Original Assignee
ExxonMobil Technology and Engineering Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Technology and Engineering Company filed Critical ExxonMobil Technology and Engineering Company
Priority to PCT/US2022/035925 priority Critical patent/WO2024005839A1/fr
Publication of WO2024005839A1 publication Critical patent/WO2024005839A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28011—Other properties, e.g. density, crush strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078

Abstract

L'invention concerne des procédés de synthèse de compositions à structure organométallique dans un environnement aqueux et/ou dans un solvant mixte alcool/eau. Les procédés peuvent permettre la formation de compositions de structure organométallique MOF-274, telles que EMM-67 (une composition de structure organométallique MOF-274 métallique mixte). Plus généralement, les procédés peuvent permettre la formation de structures MOF qui comprennent des lieurs disalicylate dans un environnement aqueux et/ou dans un solvant alcool/eau mixte.
PCT/US2022/035925 2022-07-01 2022-07-01 Synthèse à base aqueuse de structures organométalliques WO2024005839A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/US2022/035925 WO2024005839A1 (fr) 2022-07-01 2022-07-01 Synthèse à base aqueuse de structures organométalliques

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2022/035925 WO2024005839A1 (fr) 2022-07-01 2022-07-01 Synthèse à base aqueuse de structures organométalliques

Publications (1)

Publication Number Publication Date
WO2024005839A1 true WO2024005839A1 (fr) 2024-01-04

Family

ID=82838951

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2022/035925 WO2024005839A1 (fr) 2022-07-01 2022-07-01 Synthèse à base aqueuse de structures organométalliques

Country Status (1)

Country Link
WO (1) WO2024005839A1 (fr)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070202038A1 (en) 2006-02-28 2007-08-30 The Regents Of The University Of Michigan Preparation of functionalized zeolitic frameworks
US7411081B2 (en) 2004-01-13 2008-08-12 Basf Aktiengesellschaft Process for preparing and organometallic framework material
US20100307336A1 (en) 2009-06-05 2010-12-09 Zheng Ni Porous crystalline materials, their synthesis and use
WO2013059527A1 (fr) 2011-10-18 2013-04-25 The Regents Of The University Of California Structures mixtes organiques-inorganiques à fonction alkylamine pour la séparation des gaz composites
US8653292B2 (en) 2008-04-29 2014-02-18 Universitetet I Oslo Metal organic framework compounds
US20160031920A1 (en) 2014-07-29 2016-02-04 Exxonmobil Research And Engineering Company Metal organic framework materials
US20200101439A1 (en) * 2018-09-28 2020-04-02 The Regents Of The University Of California Metal-organic framework phase and crystallite shape control
WO2020219907A1 (fr) 2019-04-26 2020-10-29 Exxonmobil Research And Engineering Company Systèmes à structure métallique-mixte organique-mixte pour une capture de co2 sélective
US20210053903A1 (en) 2019-08-23 2021-02-25 Exxonmobil Research And Engineering Company Applying hansen solubility parameters to metal-organic framework synthesis conditions

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7411081B2 (en) 2004-01-13 2008-08-12 Basf Aktiengesellschaft Process for preparing and organometallic framework material
US20070202038A1 (en) 2006-02-28 2007-08-30 The Regents Of The University Of Michigan Preparation of functionalized zeolitic frameworks
US8653292B2 (en) 2008-04-29 2014-02-18 Universitetet I Oslo Metal organic framework compounds
US20100307336A1 (en) 2009-06-05 2010-12-09 Zheng Ni Porous crystalline materials, their synthesis and use
WO2013059527A1 (fr) 2011-10-18 2013-04-25 The Regents Of The University Of California Structures mixtes organiques-inorganiques à fonction alkylamine pour la séparation des gaz composites
US9861953B2 (en) 2011-10-18 2018-01-09 The Regents Of The University Of California Alkylamine functionalized metal-organic frameworks for composite gas separations
US20160031920A1 (en) 2014-07-29 2016-02-04 Exxonmobil Research And Engineering Company Metal organic framework materials
US20200101439A1 (en) * 2018-09-28 2020-04-02 The Regents Of The University Of California Metal-organic framework phase and crystallite shape control
WO2020219907A1 (fr) 2019-04-26 2020-10-29 Exxonmobil Research And Engineering Company Systèmes à structure métallique-mixte organique-mixte pour une capture de co2 sélective
US20210053903A1 (en) 2019-08-23 2021-02-25 Exxonmobil Research And Engineering Company Applying hansen solubility parameters to metal-organic framework synthesis conditions

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* Cited by examiner, † Cited by third party
Title
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CHEM SCI, vol. 9, 2018, pages 160
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MCDONALD, TMASON, J.KONG, X. ET AL.: "Cooperative insertion of C0 in diamine-appended metal organic frameworks", NATURE, vol. 519, 2015, pages 303 - 308, XP055233083, DOI: 10.1038/nature14327
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QUADRELLI ET AL.: "The energy-climate challenge: Recent trends in C0 emissions from fuel combustion", ENERGY POLICY, vol. 35, 2007, pages 5938 - 5952, XP022297957, DOI: 10.1016/j.enpol.2007.07.001
SCHOEDEL, LILI, O'KEEFFEYAGHI, CHEM REV., vol. 116, 2016, pages 12466 - 12535

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