Classifications

• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
  • F25B9/14—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the cycle used, e.g. Stirling cycle
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B1/00—Compression machines, plants or systems with non-reversible cycle
  • F25B1/10—Compression machines, plants or systems with non-reversible cycle with multi-stage compression
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B40/00—Subcoolers, desuperheaters or superheaters
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B41/00—Fluid-circulation arrangements
  • F25B41/20—Disposition of valves, e.g. of on-off valves or flow control valves
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B41/00—Fluid-circulation arrangements
  • F25B41/20—Disposition of valves, e.g. of on-off valves or flow control valves
  • F25B41/24—Arrangement of shut-off valves for disconnecting a part of the refrigerant cycle, e.g. an outdoor part
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B5/00—Compression machines, plants or systems, with several evaporator circuits, e.g. for varying refrigerating capacity
  • F25B5/02—Compression machines, plants or systems, with several evaporator circuits, e.g. for varying refrigerating capacity arranged in parallel
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
  • F25B9/002—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
  • F25B9/08—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point using ejectors
• • H—ELECTRICITY
  • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
  • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
  • H05K7/00—Constructional details common to different types of electric apparatus
  • H05K7/20—Modifications to facilitate cooling, ventilating, or heating
  • H05K7/2029—Modifications to facilitate cooling, ventilating, or heating using a liquid coolant with phase change in electronic enclosures
  • H05K7/20354—Refrigerating circuit comprising a compressor
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B2341/00—Details of ejectors not being used as compression device; Details of flow restrictors or expansion valves
  • F25B2341/001—Ejectors not being used as compression device
  • F25B2341/0011—Ejectors with the cooled primary flow at reduced or low pressure
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B2400/00—Component parts or details not otherwise provided for in this subclass
  • F25B2400/07—Details of compressors or related parts
  • F25B2400/075—Details of compressors or related parts with parallel compressors
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B2400/00—Component parts or details not otherwise provided for in this subclass
  • F25B2400/23—Separators

Definitions

• the invention relates to a pre-cooling circuit and a method for supplying helium to cool at least one consumer to be cooled.
• Cooling temperatures well below 1 K are required in basic research and for cooling quantum computers.
• state-of-the-art mixing cryostats are used, which are pre-cooled to the range of 3 - 4 K with pulsation tube, Sterling or Gifford-McMahon coolers.
• a low pre-cooling temperature is a prerequisite for the efficiency of the mixing cryostat.
• the cooling capacity of these pre-cooling machines is in the range of just a few watts with additional cooling capacity of 50 K as shield cooling. For this reason, mixing cryostats are each equipped with 2 pulsation tube coolers, for example.
• the (closed) pre-cooling circuit for supplying helium cold to at least one consumer to be cooled comprises a supply line and a return line which are connected to one another via a cold emission device, the cold emission device being set up to exchange heat with the at least one consumer to be cooled; a helium chiller configured to dissipate heat to the environment, compress backflow helium, and direct the compressed helium into the supply line; a first and a second cooling bath tank, wherein the supply line runs through a first heat exchanger arranged in a foot space of the first cooling bath tank and subsequently in the direction of the cold delivery device through a second heat exchanger arranged in a foot space of the second cooling bath tank, and wherein a head space of the first cooling bath tank via a return line connected to the helium refrigeration system for supplying the returning helium thereto; and an ejector having a motive flow port, a suction port and a discharge port, wherein the motive flow port is connected to the return line, the suction
• a pre-cooling circuit makes it possible to convey the helium compressed by the compression system to the consumer in a supercritical state, thus avoiding the occurrence of a two-phase mixture (gaseous and liquid helium) which is difficult to control.
• the helium After passing through the consumer, the helium still has sufficient pressure to raise the helium vapor of the second cooling bath container to the pressure of the first cooling bath container by means of the ejector. In total This enables the use of multi-stage bath cooling so that a low temperature can be achieved.
• the at least one consumer to be cooled is preferably a mixing cryostat.
• a secondary return line is preferably provided, which is branched off from the return line after the consumer, runs through a fourth heat exchanger arranged in the footwell of the first cooling bath tank, and opens into the return line in front of the motive flow opening of the ejector, with more preferably in the secondary return line and/or or at least one valve is arranged in the return line parallel to the secondary return line in order to control the flow through the secondary return line.
• the pre-cooling circuit comprises a third cooling bath tank, with the supply line following the second cooling bath tank running through a third heat exchanger arranged in a foot space of the third cooling bath tank, and with a head space of the third cooling bath tank being connected to a vacuum pump which is set up to evacuate helium vapor from the Pump headspace and supply it to the helium cooling system, with a compressor preferably being provided which raises a pressure level of the pumped-out helium to a pressure level of the helium cooling system. This makes it possible to reach a lower temperature.
• the first cooling bath container is set up to receive liquid helium in the footwell, which is in equilibrium with helium vapor in the headspace, with a pressure in the range of 1.0 bar to 1.5 bar
• the second cooling bath container is set up to hold liquid helium in the footwell accommodating helium in equilibrium with helium vapor in the headspace, a second equilibrium pressure preferably being in the range 0.4 bar to 0.65 bar, and optionally the third
• Cooling bath tanks adapted to hold liquid helium in the footwell which is in equilibrium with helium vapor in the headspace, with a third equilibrium pressure preferably being in the range of 0.1 bar to 0.3 bar.
• a third equilibrium pressure preferably being in the range of 0.1 bar to 0.3 bar.
• temperatures of less than or equal to 3.6 K can be achieved.
• temperatures below 3 K can be achieved
• the helium cooling system preferably comprises at least one compressor and is set up to compress helium to a pressure in the range from 7 bar to 18 bar, preferably in the range from 10 bar to 15 bar. The high pressure avoids the formation of a two-phase helium mixture.
• the helium cooling system preferably comprises a heat exchanger system, with the return-flowing helium being passed through the heat exchanger system in countercurrent to the compressed helium.
• the refrigeration delivery device comprises a shield circuit; and the helium refrigerator is configured to provide a helium shield flow, the helium shield flow being routed from the helium refrigerator to the shield circuit and from there back to the helium refrigerator.
• the helium refrigerator is configured to provide a helium shield flow, the helium shield flow being routed from the helium refrigerator to the shield circuit and from there back to the helium refrigerator.
• the cold output device is preferably set up to exchange heat with a number of consumers to be cooled, with the consumers being able to be connected and disconnected to the supply line and the return line independently of one another. It is therefore possible to vary the number of consumers.
• a low-temperature system comprises a (closed) pre-cooling circuit according to the invention and at least one mixing cryostat, which is connected to the cold delivery device as the at least one consumer to be cooled; wherein the cold delivery device is preferably set up in such a way that the supply line and the return line are connected to at least one helium bath of the at least one mixing cryostat.
• the method according to the invention for helium refrigeration supply of at least one consumer to be cooled comprises compressing backflowing helium; passing the compressed helium through a first cooling bath and a subsequent second cooling bath to keep helium in a supercritical state; conducting the supercritical helium to a refrigeration delivery device which is in heat exchange with the at least one consumer to be cooled; directing a return flow of the helium from the refrigeration dispenser to a motive flow port of an ejector; drawing a second helium vapor in equilibrium with the second cooling bath by the ejector and supplying it to a first helium vapor in equilibrium with the first cooling bath; and venting the first helium vapor to obtain the reverse flow helium.
• the process further comprises diverting at least a portion of the recycle stream to form a secondary recycle stream; passing the secondary reflux through the first cooling bath and then into the reflux.
• the method includes passing the compressed helium through a third cooling bath after the second cooling bath.
• this application speaks of a 'cooling supply' or a 'cooling release' by the pre-cooling circuit, or it is said that 'a consumer is supplied with coldness' or that 'coldness is released to a consumer'.
• This is to be understood in the sense that the pre-cooling circuit absorbs and dissipates heat from the consumer (by means of a respective heat exchange device).
• 'conduit' or 'conduit' refers to conduits for fluids, particularly helium, which is preferably gaseous. It means pipes or pipelines.
• 'connected' refers to the fact that there is a fluid connection via a (pipe) line.
• valves can be provided which influence or control the fluid flow through the line.
• FIG. 1 shows a pre-cooling circuit with two-stage bath cooling according to a preferred embodiment of the invention
• FIG. 2 shows a pre-cooling circuit with a variably designed two-stage bath cooling system according to another preferred embodiment of the invention
• FIG. 3 shows a pre-cooling circuit with three-stage bath cooling according to a further preferred embodiment of the invention
• FIG. 4 shows a pre-cooling circuit with a variably designed three-stage bath cooling according to a further preferred embodiment of the invention
• FIG. 5 shows a cold delivery device which is connected to consumers to be cooled, in particular mixing cryostats
• FIG. 6 shows the method according to the invention according to a preferred embodiment.
• FIG. 1 shows a pre-cooling circuit 100 with two-stage bath cooling according to a preferred embodiment of the invention.
• the pre-cooling circuit comprises a helium refrigerator 2 including a compressor system 4 and a heat exchanger system 6 and a bath cooling system 8 including a first cooling bath tank 34 and a second cooling bath tank 36 .
• a closed pre-cooling circuit (for the consumer to be further cooled) is formed together with a cold delivery device 10, which is set up for heat exchange with at least one consumer to be cooled, with helium being used as the cooling medium.
• the compressor system 4 comprises at least one compressor 16 which compresses helium flowing back through a return line 18 .
• a pressure of the backflow helium is typically around 1.05 bar.
• a pressure of the compressed helium is typically in the range of 7 to 18 bar, preferably in the range of 10 to 15 bar.
• Drawn-in heat dissipation device can be provided, via which heat can be dissipated to the environment.
• the compressed helium is fed to a feed line 30 via a feed line 20 .
• the return line 18 and the supply line 20 run through the
• Heat exchange system 6 so that a heat exchange is made possible between the returning helium and the compressed helium in countercurrent.
• one or more turbines 22 can be provided in the refrigeration system 2, on the compressed helium that the supply line at a point in the
• Heat exchanger system 6 is removed, is expanded to the pressure level of the supply line, and the returning helium in the return line is fed back to a (possibly different) point in the heat exchanger system, so that in principle a Brayton cycle is formed.
• the supply line 30 running through the bath cooling system 8 first runs through a first heat exchanger 40 arranged in a footwell of the first cooling bath tank 34 and then through a second heat exchanger 42 arranged in a footwell of the second cooling bath tank 36.
• the cooling bath tanks are each set up in such a way that in the footwell a helium bath, i.e. helium in the liquid state, and there is helium vapor in the headspace which is in equilibrium with the liquid helium in the footwell.
• a pressure, i.e. an equilibrium pressure, in the cooling bath tank can therefore be assigned a corresponding temperature (corresponding to the vapor pressure curve).
• the pressure is preferably about 1.25 bar, i.e.
• the pressure is preferably about 0.5 bar, i.e. in the range of 0.4 bar to 0.65 bar.
• the base of the first cooling bath container 34 is connected via a line to the second cooling bath container 36 or its head space in order to be able to supply helium to the latter, with a valve 54 being provided in the line in order to be able to control this helium supply.
• a temperature of the helium that is supplied to the cold dispenser 10 can be lowered to 3.6 K or less.
• the helium is passed from the cold delivery device into the return line 32 .
• the return line 32 is connected to an ejector 50 so that helium returned through the return line from the cold dispenser can be used as a motive flow in the ejector to draw helium vapor from the second cooling bath vessel 36 and pressurize it to the pressure of the first cooling bath vessel 34 and expel it.
• a motive flow port of the ejector is connected to the return line
• a suction port of the ejector is connected to the head space of the second cooling bath tank (via a line)
• a discharge port of the ejector is connected to the head space of the first cooling bath tank (via a line).
• a valve 52 is preferably provided in the connecting line between the head space of the second cooling bath container 36 and the ejector 50 or its suction opening, in order to be able to control the steam flow from the head space of the second cooling bath container to the ejector.
• the head space of the first cooling bath container 34 is connected to the return line 20 of the refrigeration system 2 so that the helium circuit is closed.
• a shield current supply line 80 and a shield current return line 82 are provided, with compressed helium taken from the heat exchanger system 6 or the supply line 18 being routed to the consumer via the shield current supply line 80 and the helium being fed back into the heat exchanger system 6 via the shield current return line 82, e.g the turbines 22.
• FIG. 2 shows a pre-cooling circuit 200 with a variably designed two-stage bath cooling system according to another preferred embodiment of the invention. This embodiment largely corresponds to the embodiment shown in FIG. In the following, therefore, essentially only different or additional elements will be discussed and elements that have already been explained in connection with FIG. 1 will not be explained again.
• a secondary return line 58 is additionally provided here.
• the secondary return line is connected to a branch from the return line 32 so that helium coming from the cold dispenser 10 can be partially diverted from the return line.
• Valves 60, 62 are provided in the sub-return line and the return line to control the flow of helium into the sub-return line and the return line, respectively.
• the secondary return line 58 leads through a fourth heat exchanger 46 arranged in the footwell of the first cooling bath tank 34 and is then brought back together with the return line 32 before the ejector 50 .
• the pre-cooling circuit can thus be used with different loads, since the helium flow is essentially determined by the operating point of the ejector. For example, a different number of consumers to be cooled can be supplied with cold via the cold delivery device 10 .
• FIG. 3 shows a pre-cooling circuit 300 with three-stage bath cooling according to a further preferred embodiment of the invention.
• This embodiment largely corresponds to the embodiment shown in FIG. In the following, therefore, essentially only different or additional elements will be discussed and elements that have already been explained in connection with FIG. 1 will not be explained again.
• This embodiment also includes a third cooling bath tank 38, the supply line 32 after the second cooling bath tank 36 through a footwell in the third cooling bath container 38 arranged third heat exchanger 44 is performed.
• the third cooling bath tank 38 there is again an equilibrium between liquid helium in the foot space and helium vapor in the head space.
• the pressure is preferably about 0.2 bar, ie in the range from 0.1 bar to 0.3 bar. In this way, a further reduction in the temperature of the helium supplied through the supply line to the cold-dispensing device can be achieved. For example, a temperature below 3 K can be reached.
• a vacuum pump 64 is connected via a line to a headspace of the third cooling bath vessel 38 and is configured to pump helium vapor from the headspace.
• the pumped-out helium is fed into the return line 18 of the refrigeration system 2 via a line 68 in which a compressor 66 is arranged.
• the compressor serves to raise the pressure of the helium to the level in the return line.
• the footwell of the first cooling bath tank 34 is connected via a line to the third
• a third cooling stage i.e. a third cooling bath tank, a vacuum pump, a compressor and the corresponding lines/valves, according to Figure 3.
• a corresponding pre-cooling circuit 400 is shown in FIG. All elements of this pre-cooling circuit have already been explained in connection with FIGS.
• FIG. 5 shows a cold delivery device 10 which is connected to consumers 72 to be cooled, in particular mixing cryostats.
• This cold delivery device 10 can be used in particular for any of the designs according to FIGS. 1, 2, 3.
• the assignment of the connections is marked in the figures by arrows which are provided with the letters 'A', 'B', 'C' and 'D'.
• the cold dispensing device 10 comprises a plurality of (here, for example three) valve groups 74, in each of which lines connected to the supply line 32 or the return line 34 lead to individual consumers or consumer groups 72 are provided. These lines are provided with valves in the valve groups so that the helium can be routed from the supply line to individual consumers and from there to the return line.
• the consumers 72 can thus be connected and disconnected independently of one another with the supply line (TV) and the return line ('B'). This is particularly advantageous in conjunction with the pre-cooling circuits 200, 400 of FIGS. 2 and 4, which allow part-load operation.
• Valve assemblies 74 also provide conduit and valves for shield refrigerant flow to be routed from the shield power supply line ('C') to the loads and back to the shield power return line ('D'). So a shield circuit is formed.
• a cold box or several cold boxes are preferably provided again, within which the valve groups and preferably also consumers, in particular the mixing cryostats, are arranged.
• FIG. 6 shows the method according to the invention according to a preferred embodiment.
• the individual steps are part of a cycle that the helium goes through.
• the returning helium is compressed (such as by the compressor system).
• the pressure achieved is in the range from 7 to 18 bar, preferably from 10 to 15 bar.
• the compressed helium is passed through a first cooling bath and a subsequent second cooling bath in step 604 to maintain helium in a supercritical state.
• the helium is passed through a third cooling bath.
• the cooling baths are in equilibrium with a respective first, second and third helium vapor.
• the equilibrium pressure corresponds to the pressure mentioned above in connection with the first, second and third cooling bath containers.
• step 610 the supercritical helium is routed to a cold delivery device which is in heat exchange with the at least one consumer to be cooled.
• a reverse flow of helium from the cold dispenser is directed to a motive flow port of an ejector.
• diverting at least a portion of the reflux to form a secondary reflux passing the secondary reflux through the first cooling bath, and then passing it into the reflux.
• the ejector draws in the second helium vapor that is in equilibrium with the second cooling bath and feeds the first helium vapor that is in equilibrium with the first cooling bath.
• the first helium vapor is vented at step 618 to yield the reverse flow helium, which is compressed at step 602 to complete the cycle.

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• Engineering & Computer Science (AREA)
• Physics & Mathematics (AREA)
• Thermal Sciences (AREA)
• Mechanical Engineering (AREA)
• General Engineering & Computer Science (AREA)
• Microelectronics & Electronic Packaging (AREA)
• Containers, Films, And Cooling For Superconductive Devices (AREA)

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• 2021
  • 2021-07-05 EP EP21020348.5A patent/EP4116639A1/de not_active Withdrawn
• 2022
  • 2022-07-04 US US18/575,596 patent/US20240302081A1/en active Pending
  • 2022-07-04 KR KR1020237045404A patent/KR20240054924A/ko active Pending
  • 2022-07-04 WO PCT/EP2022/025306 patent/WO2023280439A1/de not_active Ceased
  • 2022-07-04 EP EP22737751.2A patent/EP4367449A1/de active Pending
  • 2022-07-04 JP JP2023579098A patent/JP2024523917A/ja active Pending
  • 2022-07-04 CN CN202280044589.8A patent/CN117545968A/zh active Pending

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