WO2023229491A3 - Method for producing hydrogen - Google Patents

Method for producing hydrogen Download PDF

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Publication number
WO2023229491A3
WO2023229491A3 PCT/RU2023/000130 RU2023000130W WO2023229491A3 WO 2023229491 A3 WO2023229491 A3 WO 2023229491A3 RU 2023000130 W RU2023000130 W RU 2023000130W WO 2023229491 A3 WO2023229491 A3 WO 2023229491A3
Authority
WO
WIPO (PCT)
Prior art keywords
stream
hydrogen
fed
sent
synthesis gas
Prior art date
Application number
PCT/RU2023/000130
Other languages
French (fr)
Russian (ru)
Other versions
WO2023229491A2 (en
Inventor
Игорь Анатольевич МНУШКИН
Original Assignee
Игорь Анатольевич МНУШКИН
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from RU2022111779A external-priority patent/RU2791358C1/en
Application filed by Игорь Анатольевич МНУШКИН filed Critical Игорь Анатольевич МНУШКИН
Publication of WO2023229491A2 publication Critical patent/WO2023229491A2/en
Publication of WO2023229491A3 publication Critical patent/WO2023229491A3/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/50Carbon dioxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

A method for producing hydrogen includes: increasing the pressure of an initial feedstock in the form of natural gas using compressor equipment, and/or of liquefied petroleum gas and/or light gasoline and/or hydrocarbon mixtures using pumping equipment; mixing the initial feedstock with a stream of hydrogen to produce a feed stream; heating the feed stream and purifying same of sulphur compounds in a catalytic hydrogenation reactor and a system of desulphurization reactors, which are connected in series. Next, the purified feed stream is mixed with water vapour, the resulting mixture is heated and fed into an adiabatic pre-reforming reactor, and the resulting reaction mixture is mixed with water vapour and heated before being fed into a steam reformer furnace to produce synthesis gas. The synthesis gas is cooled and fed into a carbon monoxide conversion reactor. The converted synthesis gas is then sent for two-stage purification. The hydrogen obtained is divided into two streams: the first stream is sent for mixing with the initial feedstock upstream of the catalytic hydrogenation reactor, and the second stream is sent to consumers. The invention makes it possible to increase the yield of hydrogen and to reduce the energy and material costs of production, while improving the environmental friendliness thereof.
PCT/RU2023/000130 2022-04-29 2023-04-27 Method for producing hydrogen WO2023229491A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2022111779 2022-04-29
RU2022111779A RU2791358C1 (en) 2022-04-29 Hydrogen production method

Publications (2)

Publication Number Publication Date
WO2023229491A2 WO2023229491A2 (en) 2023-11-30
WO2023229491A3 true WO2023229491A3 (en) 2024-02-01

Family

ID=88919647

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2023/000130 WO2023229491A2 (en) 2022-04-29 2023-04-27 Method for producing hydrogen

Country Status (1)

Country Link
WO (1) WO2023229491A2 (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2088518C1 (en) * 1994-08-03 1997-08-27 Акционерное общество Первоуральский новотрубный завод "Уралтрубсталь" Method of producing hydrogen from hydrocarbon gas
RU2378188C2 (en) * 2004-05-28 2010-01-10 Хайрадикс, Инк. Hydrogen synthesis method using steam reforming with partial oxidation
RU2379230C2 (en) * 2008-04-08 2010-01-20 Борис Тихонович Плаченов Method of producing hydrogen through vapour-carbon dioxide conversion of natural gas
RU2394754C1 (en) * 2009-03-26 2010-07-20 Дмитрий Львович Астановский Method of obtaining hydrogen from hydrocarbon material
US20210269307A1 (en) * 2018-10-15 2021-09-02 Haldor Topsøe A/S Carbon recycling in steam reforming process
US11186483B2 (en) * 2011-09-27 2021-11-30 Thermochem Recovery International, Inc. Method of producing sulfur-depleted syngas

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2088518C1 (en) * 1994-08-03 1997-08-27 Акционерное общество Первоуральский новотрубный завод "Уралтрубсталь" Method of producing hydrogen from hydrocarbon gas
RU2378188C2 (en) * 2004-05-28 2010-01-10 Хайрадикс, Инк. Hydrogen synthesis method using steam reforming with partial oxidation
RU2379230C2 (en) * 2008-04-08 2010-01-20 Борис Тихонович Плаченов Method of producing hydrogen through vapour-carbon dioxide conversion of natural gas
RU2394754C1 (en) * 2009-03-26 2010-07-20 Дмитрий Львович Астановский Method of obtaining hydrogen from hydrocarbon material
US11186483B2 (en) * 2011-09-27 2021-11-30 Thermochem Recovery International, Inc. Method of producing sulfur-depleted syngas
US20210269307A1 (en) * 2018-10-15 2021-09-02 Haldor Topsøe A/S Carbon recycling in steam reforming process

Also Published As

Publication number Publication date
WO2023229491A2 (en) 2023-11-30

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