WO2023226134A1 - 一种聚氨酯用爽滑抗粘母粒及其制备方法 - Google Patents
一种聚氨酯用爽滑抗粘母粒及其制备方法 Download PDFInfo
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- WO2023226134A1 WO2023226134A1 PCT/CN2022/101252 CN2022101252W WO2023226134A1 WO 2023226134 A1 WO2023226134 A1 WO 2023226134A1 CN 2022101252 W CN2022101252 W CN 2022101252W WO 2023226134 A1 WO2023226134 A1 WO 2023226134A1
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- Prior art keywords
- polyurethane
- smooth
- agent
- masterbatch
- parts
- Prior art date
Links
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 47
- 239000004814 polyurethane Substances 0.000 title claims abstract description 47
- 239000004594 Masterbatch (MB) Substances 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title abstract description 3
- 239000000463 material Substances 0.000 claims abstract description 45
- 239000002216 antistatic agent Substances 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 17
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims abstract description 13
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 13
- 239000003242 anti bacterial agent Substances 0.000 claims description 37
- 239000006185 dispersion Substances 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 16
- -1 ethyl ester pyridinium salt Chemical class 0.000 claims description 15
- 230000000181 anti-adherent effect Effects 0.000 claims description 13
- HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 claims description 12
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 150000001408 amides Chemical class 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
- 239000000853 adhesive Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 238000001125 extrusion Methods 0.000 claims description 8
- 238000005453 pelletization Methods 0.000 claims description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 238000007873 sieving Methods 0.000 claims description 6
- 239000012748 slip agent Substances 0.000 claims description 6
- ORAWFNKFUWGRJG-UHFFFAOYSA-N Docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(N)=O ORAWFNKFUWGRJG-UHFFFAOYSA-N 0.000 claims description 5
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 229910052621 halloysite Inorganic materials 0.000 claims description 5
- 239000006249 magnetic particle Substances 0.000 claims description 5
- 239000002071 nanotube Substances 0.000 claims description 5
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 5
- HOJYCNSTMZLRCV-UHFFFAOYSA-N 5,5-dimethyl-3-prop-2-enylimidazolidine-2,4-dione Chemical compound CC1(C)NC(=O)N(CC=C)C1=O HOJYCNSTMZLRCV-UHFFFAOYSA-N 0.000 claims description 4
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical group [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims description 4
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 4
- 235000013539 calcium stearate Nutrition 0.000 claims description 4
- 239000008116 calcium stearate Substances 0.000 claims description 4
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- CKQVRZJOMJRTOY-UHFFFAOYSA-N octadecanoic acid;propane-1,2,3-triol Chemical group OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O CKQVRZJOMJRTOY-UHFFFAOYSA-N 0.000 claims description 4
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical group CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 229910001422 barium ion Inorganic materials 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 3
- 229920002050 silicone resin Polymers 0.000 claims description 3
- BDRVEARQBLPFIP-UHFFFAOYSA-M triethyl(prop-2-enyl)azanium;bromide Chemical compound [Br-].CC[N+](CC)(CC)CC=C BDRVEARQBLPFIP-UHFFFAOYSA-M 0.000 claims description 3
- 239000005909 Kieselgur Substances 0.000 claims description 2
- SWSBIGKFUOXRNJ-CVBJKYQLSA-N ethene;(z)-octadec-9-enamide Chemical compound C=C.CCCCCCCC\C=C/CCCCCCCC(N)=O.CCCCCCCC\C=C/CCCCCCCC(N)=O SWSBIGKFUOXRNJ-CVBJKYQLSA-N 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 claims 2
- 235000021357 Behenic acid Nutrition 0.000 claims 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 1
- 229940116226 behenic acid Drugs 0.000 claims 1
- ZJOLCKGSXLIVAA-UHFFFAOYSA-N ethene;octadecanamide Chemical compound C=C.CCCCCCCCCCCCCCCCCC(N)=O.CCCCCCCCCCCCCCCCCC(N)=O ZJOLCKGSXLIVAA-UHFFFAOYSA-N 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 239000004599 antimicrobial Substances 0.000 abstract 2
- 238000009499 grossing Methods 0.000 abstract 1
- 238000009413 insulation Methods 0.000 description 5
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- OXDXXMDEEFOVHR-CLFAGFIQSA-N (z)-n-[2-[[(z)-octadec-9-enoyl]amino]ethyl]octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCNC(=O)CCCCCCC\C=C/CCCCCCCC OXDXXMDEEFOVHR-CLFAGFIQSA-N 0.000 description 3
- 229920003225 polyurethane elastomer Polymers 0.000 description 3
- OIDIRWZVUWCCCO-UHFFFAOYSA-N 1-ethylpyridin-1-ium Chemical class CC[N+]1=CC=CC=C1 OIDIRWZVUWCCCO-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- JADNEWQXDKBXRI-UHFFFAOYSA-M ethyl-dimethyl-(2-prop-2-enoyloxyethyl)azanium;bromide Chemical compound [Br-].CC[N+](C)(C)CCOC(=O)C=C JADNEWQXDKBXRI-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Natural products CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 description 1
- NHAMZGUBPHHQHF-UHFFFAOYSA-N ON1C(NC(C1(C)C)=O)=O Chemical compound ON1C(NC(C1(C)C)=O)=O NHAMZGUBPHHQHF-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 102000011759 adducin Human genes 0.000 description 1
- 108010076723 adducin Proteins 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000001147 anti-toxic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006306 polyurethane fiber Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2475/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2275—Ferroso-ferric oxide (Fe3O4)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/01—Magnetic additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
Definitions
- the invention relates to the field of masterbatch materials for polyurethane, and in particular to a smooth and anti-stick masterbatch for polyurethane and a preparation method thereof.
- Polyurethane whose full name is polyurethane, is a polymer compound. This object was made by Otto Bayer and others in 1937. Polyurethane is divided into two categories: polyester type and polyether type. They can be made into polyurethane plastics (mainly foam plastics), polyurethane fibers (called spandex in China), polyurethane rubber and elastomers.
- Soft polyurethane is mainly a thermoplastic linear structure. It has better stability, chemical resistance, resilience and mechanical properties than PVC foam materials, and has smaller compression deformation. It has good heat insulation, sound insulation, earthquake resistance and anti-toxic properties. Therefore it is used as packaging, sound insulation and filtering materials.
- Rigid polyurethane plastic is lightweight, has superior sound and thermal insulation properties, is resistant to chemicals, has good electrical properties, is easy to process, and has low water absorption. It is mainly used in structural materials for construction, automobiles, aviation industry, and thermal insulation.
- the performance of polyurethane elastomer is between that of plastic and rubber, with oil resistance, wear resistance, low temperature resistance, aging resistance, high hardness and elasticity. Mainly used in shoemaking industry and medical industry. Polyurethane can also be used to make adhesives, coatings, synthetic leather, etc.
- Polyurethane appeared in the 1930s. After nearly eighty years of technological development, this material has been widely used in the home furnishing field, construction field, daily necessities field, transportation field, home appliance field, etc. However, polyurethane has poor slippery properties, which causes Inconvenience to use.
- the present invention provides a smooth and anti-stick masterbatch for polyurethane that has good smooth effect and is easy to use.
- the invention also provides a method for preparing smooth and anti-stick masterbatch for polyurethane, which has a simple process and convenient operation.
- a smooth and anti-adhesive masterbatch for polyurethane including the following components in parts by mass:
- thermoplastic polyurethane is 65-88 parts.
- the anti-adhesive agent is SiO 2 -coated Fe 3 O 4 magnetic particles, halloysite nanotubes, a compound of amide wax and nanoscale silica, kaolin, silicon One of algae, calcium carbonate or talc.
- the slip agent is one of oleic acid amide, erucic acid amide, zinc stearate, calcium stearate, palmitamide, behenic acid amide or silicone resin, preferably Ethylene bis-oleamide (EBO), ethylene bis-stearamide (EBS), palmitamide, behenic acid amide, pentaerythritol stearate (PETS).
- EBO Ethylene bis-oleamide
- EBS ethylene bis-stearamide
- PETS pentaerythritol stearate
- the organic antibacterial agent is 6-bromocaproic acid-2-(2-methacryloyloxy)ethyl ester pyridinium salt, acryloyloxyethyl dimethylethyl bromide One of ammonium, 3-allyl-5,5-dimethylhydantoin, N-allylpyridine, or allyltriethylammonium bromide.
- the ion antibacterial agent is one of silver ion antibacterial agent, zinc ion antibacterial agent, iron ion antibacterial agent, aluminum ion antibacterial agent, barium ion antibacterial agent or magnesium ion antibacterial agent.
- the antistatic agent is one of a stearic acid glycerin antistatic agent, an amide antistatic agent, and an ethylamine antistatic agent.
- a method for preparing smooth and anti-stick masterbatch for polyurethane including the following steps:
- thermoplastic polyurethane material A, material B, and antistatic agent to the high-speed disperser in proportion and mix for 15-25 minutes to obtain a mixture
- step S4 Add the mixed material obtained in step S3 to a twin-screw extruder to melt, and after extrusion and pelletization, a smooth and anti-stick masterbatch for polyurethane is obtained.
- step S1 the dispersion temperature is 40-45°C and the dispersion time is 65-80 minutes.
- step S2 the dispersion temperature is 45-50°C and the dispersion time is 20-30 minutes.
- the smooth and anti-adhesive masterbatch for polyurethane of the present invention has good anti-adhesion and slippery effects, and has good mechanical strength and toughness. It is easy to use, simple to operate, and can better improve the performance of the product and the processing environment, etc., and has a relatively good Good application prospects.
- a smooth and anti-adhesive masterbatch for polyurethane including the following components by mass: 60-95 parts of thermoplastic polyurethane; 20-25 parts of anti-adhesive agent; 15-24 parts of smooth agent; 5-10 parts of organic antibacterial agent ; 4-8 parts of ionic antibacterial agent; 1-3 parts of antistatic agent.
- thermoplastic polyurethane is 65-88 parts.
- the anti-adhesive agent is SiO 2 -coated Fe 3 O 4 magnetic particles, halloysite nanotubes, a compound of amide wax and nanoscale silica, kaolin, diatomaceous earth, calcium carbonate or A type of talcum powder.
- the slip agent is one of oleic acid amide, erucic acid amide, zinc stearate, calcium stearate, palmitamide, behenic acid amide or silicone resin, preferably ethylene bisoleic acid amide.
- EBO ethylene bisstearamide
- EBS ethylene bisstearamide
- PES pentaerythritol stearate
- the organic antibacterial agent is 6-bromocaproic acid-2-(2-methacryloyloxy)ethyl ester pyridinium salt, acryloyloxyethyldimethylethylammonium bromide, 3-allyl One of hydroxy-5,5-dimethylhydantoin, N-allylpyridine or allyltriethylammonium bromide.
- the ion antibacterial agent is one of silver ion antibacterial agent, zinc ion antibacterial agent, iron ion antibacterial agent, aluminum ion antibacterial agent, barium ion antibacterial agent or magnesium ion antibacterial agent.
- the antistatic agent is one of a stearic acid glycerin antistatic agent, an amide antistatic agent, and an ethylamine antistatic agent.
- a method for preparing smooth and anti-stick masterbatch for polyurethane including the following steps:
- thermoplastic polyurethane material A, material B, and antistatic agent to the high-speed disperser in proportion and mix for 15-25 minutes to obtain a mixture
- step S4 Add the mixed material obtained in step S3 to a twin-screw extruder to melt, and after extrusion and pelletization, a smooth and anti-stick masterbatch for polyurethane is obtained.
- a method for preparing smooth and anti-stick masterbatch for polyurethane including the following steps:
- thermoplastic polyurethane material A, material B, and 1 part of amide antistatic agent into a high-speed disperser in proportion and mix for 15 minutes to obtain a mixture;
- step S4 Add the mixed material obtained in step S3 to a twin-screw extruder to melt, and after extrusion and pelletization, a smooth and anti-stick masterbatch for polyurethane is obtained.
- a method for preparing smooth and anti-stick masterbatch for polyurethane including the following steps:
- thermoplastic polyurethane material A, material B, and 1 part of stearic acid glycerin antistatic agent into a high-speed disperser in proportion and mix for 15 minutes to obtain a mixture;
- step S4 Add the mixed material obtained in step S3 to a twin-screw extruder to melt, and after extrusion and pelletization, a smooth and anti-stick masterbatch for polyurethane is obtained.
- a method for preparing smooth and anti-stick masterbatch for polyurethane including the following steps:
- thermoplastic polyurethane material A, material B, and 2 parts of amide antistatic agent into a high-speed disperser in proportion and mix for 25 minutes to obtain a mixture;
- step S4 Add the mixed material obtained in step S3 to a twin-screw extruder to melt, and after extrusion and pelletization, a smooth and anti-stick masterbatch for polyurethane is obtained.
- a method for preparing smooth and anti-stick masterbatch for polyurethane including the following steps:
- thermoplastic polyurethane material A, material B, and 1 part of ethylamine antistatic agent into a high-speed disperser in proportion and mix for 25 minutes to obtain a mixture;
- step S4 Add the mixed material obtained in step S3 to a twin-screw extruder to melt, and after extrusion and pelletization, a smooth and anti-stick masterbatch for polyurethane is obtained.
- a method for preparing smooth and anti-stick masterbatch for polyurethane including the following steps:
- thermoplastic polyurethane material A, material B, and 1 part of ethylamine antistatic agent into a high-speed disperser in proportion and mix for 15 minutes to obtain a mixture;
- step S4 Add the mixed material obtained in step S3 to a twin-screw extruder to melt, and after extrusion and pelletization, a smooth and anti-stick masterbatch for polyurethane is obtained.
- Example 1-5 The products prepared in Examples 1-5 were cut into 25 ⁇ 25mm samples to be tested, and mechanical properties were tested according to the method of GB/T528-1998 (ISO37:2005). The results are shown in Table 1.
- the anti-adhesion corona surface Corona surface (set in a constant temperature and humidity experimental box at 50°C and 70% humidity, covering 2KG/100cm2 pressure, for 24 hours).
- the smooth and anti-adhesive masterbatch for polyurethane of the present invention has good anti-adhesion and slippery effects, and has good mechanical strength and toughness. It is easy to use, simple to operate, and can better improve the performance of the product and the processing environment, etc., and has a relatively good Good application prospects.
Abstract
本发明涉及聚氨酯用母粒材料领域，特别是涉及一种聚氨酯用爽滑抗粘母粒，包括如下质量份数的组分：热塑性聚氨酯60-95份；抗粘连剂20-25份；爽滑剂15-24份；有机抗菌剂5-10份；离子抗菌剂4-8份；抗静电剂1-3份。本发明提供一种爽滑效果好和使用方便的聚氨酯用爽滑抗粘母粒。本发明还提供一种聚氨酯用爽滑抗粘母粒的制备方法，工艺简单，操作便捷。
Description
本发明涉及聚氨酯用母粒材料领域，特别是涉及一种聚氨酯用爽滑抗粘母粒及其制备方法。
聚氨酯，全名为聚氨基甲酸酯，是一种高分子化合物。1937年由奥托·拜耳等制出此物。聚氨酯有聚酯型和聚醚型二大类。他们可制成聚氨酯塑料(以泡沫塑料为主)、聚氨酯纤维(中国称为氨纶)、聚氨酯橡胶及弹性体。
软质聚氨酯主要是具有热塑性的线性结构，它比PVC发泡材料有更好的稳定性、耐化学性、回弹性和力学性能，具有更小的压缩变型性。隔热、隔音、抗震、防毒性能良好。因此用作包装、隔音、过滤材料。硬质聚氨酯塑料质轻、隔音、绝热性能优越、耐化学药品，电性能好，易加工，吸水率低。它主要用于建筑、汽车、航空工业、保温隔热的结构材料。聚氨酯弹性体性能介于塑料和橡胶之间，耐油，耐磨，耐低温，耐老化，硬度高，有弹性。主要用于制鞋工业和医疗业。聚氨酯还可以制作粘合剂、涂料、合成革等。
聚氨酯出现于20世纪30年代，经过近八十年的技术发展，该种材料已经广泛应用于家居领域、建筑领域、日用品领域、交通领域、家电领域等，但聚氨酯的爽滑性比较差，给使用带来不便。
发明内容
为解决上述技术问题，本发明提供一种爽滑效果好和使用方便的聚氨酯用爽滑抗粘母粒。
本发明还提供一种聚氨酯用爽滑抗粘母粒的制备方法，工艺简单，操作便捷。
本发明采用如下技术方案：
一种聚氨酯用爽滑抗粘母粒，包括如下质量份数的组分：
对上述技术方案的进一步改进为，所述热塑性聚氨酯的质量份数为65-88份。
对上述技术方案的进一步改进为，所述抗粘连剂为SiO
2包覆Fe
3O
4的磁性粒子、埃洛石纳米管、酰胺类蜡与纳米级二氧化硅的复配物、高岭土、硅藻土、碳酸钙或滑石粉中的一种。
对上述技术方案的进一步改进为，所述爽滑剂为油酸酰胺、芥酸酰胺、硬脂酸锌、硬脂酸钙、棕榈酰胺、山嵛酸酰胺或硅树脂中的一种，优选为乙撑双油酸酰胺(EBO)、乙撑双硬脂酰胺(EBS)、棕榈酰胺、山嵛酸酰胺、季戊四醇硬脂酸酯(PETS)。
对上述技术方案的进一步改进为，所述有机抗菌剂为6-溴己酸-2-(2-甲基丙烯酰氧)乙基酯吡啶盐、丙烯酰氧乙基二甲基乙基溴化铵、3-烯丙基-5,5-二甲基乙内酰脲、N-烯丙基吡啶或溴化烯丙基三乙基铵中的一种。
对上述技术方案的进一步改进为，所述离子抗菌剂为银离子抗菌剂、锌离子抗菌剂、铁离子抗菌剂、铝离子抗菌剂、钡离子抗菌剂或镁离子抗菌剂中的一种。
对上述技术方案的进一步改进为，所述抗静电剂为硬脂酸甘油类抗静电剂、酰胺类抗静电剂、乙基胺类抗静电剂中的一种。
一种聚氨酯用爽滑抗粘母粒的制备方法，包括如下步骤：
S1、按照质量份数把抗粘连剂、爽滑剂投入到高速分散机中分散均匀，获得A料；
S2、按照质量份数把有机抗菌剂、离子抗菌剂投入到高速分散机中分散均匀，经过过滤、烘干、过筛获得B料；
S3、把热塑性聚氨酯、A料、B料、抗静电剂按照比例加入到高速分散机中进行混合，时间15-25min，得到混合物；
S4、将步骤S3中所得的混合物料加入双螺杆挤出机熔融，经过挤出切粒后，获得一种聚氨酯用爽滑抗粘母粒。
对上述技术方案的进一步改进为，在所述步骤S1中，所述分散的温度40-45℃，分散的时间65-80min。
对上述技术方案的进一步改进为，在所述步骤S2中，所述分散的温度45-50℃，分散的时间20-30min。
本发明的有益效果为：
本发明聚氨酯用爽滑抗粘母粒的抗粘连爽滑效果好，并具有良好的机械强度和韧性，其使用方便，操作简单，并能较好地改善制品的性能及加工环境等，具有较好的应用前景。
下面结合具体实施方式，对本发明做进一步描述，需要说明的是，在不相冲突的前提下，以下描述的各实施例之间或各技术特征之间可以任意组合形成新的实施例。以下是本发明具体的实施例，在下述实施例中所采用的原材料、设备等除特殊限定外均可以通过购买方式获得。
一种聚氨酯用爽滑抗粘母粒，包括如下质量份数的组分：热塑性聚氨酯60-95份；抗粘连剂20-25份；爽滑剂15-24份；有机抗菌剂5-10份；离子抗菌剂4-8份；抗静电剂1-3份。
进一步地，所述热塑性聚氨酯的质量份数为65-88份。
进一步地，所述抗粘连剂为SiO
2包覆Fe
3O
4的磁性粒子、埃洛石纳米管、酰胺类蜡与纳米级二氧化硅的复配物、高岭土、硅藻土、碳酸钙或滑石粉中的一种。
进一步地，所述爽滑剂为油酸酰胺、芥酸酰胺、硬脂酸锌、硬脂酸钙、棕榈酰胺、山嵛酸酰胺或硅树脂中的一种，优选为乙撑双油酸酰胺(EBO)、乙撑双硬脂酰胺(EBS)、棕榈酰胺、山嵛酸酰胺、季戊四醇硬脂酸酯(PETS)。
进一步地，所述有机抗菌剂为6-溴己酸-2-(2-甲基丙烯酰氧)乙基酯吡啶盐、丙烯酰氧乙基二甲基乙基溴化铵、3-烯丙基-5,5-二甲基乙内酰脲、N-烯丙基吡啶或溴化烯丙基三乙基铵中的一种。
进一步地，所述离子抗菌剂为银离子抗菌剂、锌离子抗菌剂、铁离子抗菌剂、铝离子抗菌剂、钡离子抗菌剂或镁离子抗菌剂中的一种。
进一步地，所述抗静电剂为硬脂酸甘油类抗静电剂、酰胺类抗静电剂、乙基胺类抗静电剂中的一种。
一种聚氨酯用爽滑抗粘母粒的制备方法，包括如下步骤：
S1、按照质量份数把抗粘连剂、爽滑剂投入到高速分散机中分散均匀，获得A料；所述分散的温度40-45℃，分散的时间65-80min；
S2、按照质量份数把有机抗菌剂、离子抗菌剂投入到高速分散机中分散均匀，经过过滤、烘干、过筛获得B料；所述分散的温度45-50℃，分散的时间20-30min；
S3、把热塑性聚氨酯、A料、B料、抗静电剂按照比例加入到高速分散机中进行混合，时间15-25min，得到混合物；
S4、将步骤S3中所得的混合物料加入双螺杆挤出机熔融，经过挤出切粒后，获得一种聚氨酯用爽滑抗粘母粒。
实施例1
一种聚氨酯用爽滑抗粘母粒的制备方法，包括如下步骤：
S1、把20份SiO
2包覆Fe
3O
4的磁性粒子、15份硬脂酸锌投入到高速分散机中分散均匀，获得A料；所述分散的温度40℃，分散的时间65min；
S2、把5份3-烯丙基-5,5-二甲基乙内酰脲、4份银离子抗菌剂投入到高速分散机中分散均匀，经过过滤、烘干、过筛获得B料；所述分散的温度45℃，分散的时间20min；
S3、把60份热塑性聚氨酯、A料、B料、1份酰胺类抗静电剂按照比例加入到高速分散机中进行混合，时间15min，得到混合物；
S4、将步骤S3中所得的混合物料加入双螺杆挤出机熔融，经过挤出切粒后，获得一种聚氨酯用爽滑抗粘母粒。
实施例2
一种聚氨酯用爽滑抗粘母粒的制备方法，包括如下步骤：
S1、把20份埃洛石纳米管、15份硬脂酸钙投入到高速分散机中分散均匀，获得A料；所述分散的温度40℃，分散的时间65min；
S2、把6份丙烯酰氧乙基二甲基乙基溴化铵、4份铝离子抗菌剂投入到高速分散机中分散均匀，经过过滤、烘干、过筛获得B料；所述分散的温度45℃，分散的时间20min；
S3、把65份热塑性聚氨酯、A料、B料、1份硬脂酸甘油类抗静电剂按照比例加入到高速分散机中进行混合，时间15min，得到混合物；
S4、将步骤S3中所得的混合物料加入双螺杆挤出机熔融，经过挤出切粒后，获得一种聚氨酯用爽滑抗粘母粒。
实施例3
一种聚氨酯用爽滑抗粘母粒的制备方法，包括如下步骤：
S1、把20份酰胺类蜡与纳米级二氧化硅的复配物、20份油酸酰胺投入到高速分散机中分散均匀，获得A料；所述分散的温度40℃，分散的时间65min；
S2、把8份6-溴己酸-2-(2-甲基丙烯酰氧)乙基酯吡啶盐、5份锌离子抗菌剂投入到高速分散机中分散均匀，经过过滤、烘干、过筛获得B料；所述分散的温度50℃，分散的时间25min；
S3、把75份热塑性聚氨酯、A料、B料、2份酰胺类抗静电剂按照比例加入到高速分散机中进行混合，时间25min，得到混合物；
S4、将步骤S3中所得的混合物料加入双螺杆挤出机熔融，经过挤出切粒后，获得一种聚氨酯用爽滑抗粘母粒。
实施例4
一种聚氨酯用爽滑抗粘母粒的制备方法，包括如下步骤：
S1、把25份埃洛石纳米管、24份芥酸酰胺投入到高速分散机中分散均匀，获得A料；所述分散的温度45℃，分散的时间80min；
S2、把10份3-烯丙基-5,5-二甲基乙内酰脲、8份铁离子抗菌剂投入到高速分散机中分散均匀，经过过滤、烘干、过筛获得B料；所述分散的温度50℃，分散的时间30min；
S3、把90份热塑性聚氨酯、A料、B料、1份乙基胺类抗静电剂按照比例加入到高速分散机中进行混合，时间25min，得到混合物；
S4、将步骤S3中所得的混合物料加入双螺杆挤出机熔融，经过挤出切粒后，获得一种聚氨酯用爽滑抗粘母粒。
实施例5
一种聚氨酯用爽滑抗粘母粒的制备方法，包括如下步骤：
S1、把20份SiO
2包覆Fe
3O
4的磁性粒子、15份硬脂酸锌投入到高速分散机中分散均匀，获得A料；所述分散的温度40℃，分散的时间65min；
S2、把5份6-溴己酸-2-(2-甲基丙烯酰氧)乙基酯吡啶盐、4份铝离子抗菌剂投入到高速分散机中分散均匀，经过过滤、烘干、过筛获得B料；所述分散的温度45℃，分散的时间20min；
S3、把95份热塑性聚氨酯、A料、B料、1份乙基胺类抗静电剂按照比例加入到高速分散机中进行混合，时间15min，得到混合物；
S4、将步骤S3中所得的混合物料加入双螺杆挤出机熔融，经过挤出切粒后，获得一种聚氨酯用爽滑抗粘母粒。
对实施例1-5所制备的产品裁剪成25×25mm的待测试样品，按照GB/T528-1998(ISO37:2005)的方法进行机械性能测试，结果见表1，其中抗粘连电晕面对电晕面(在恒温恒湿实验箱中设定50℃湿度70％，覆盖2KG/100cm2压强下，24小时)。
本发明聚氨酯用爽滑抗粘母粒的抗粘连爽滑效果好，并具有良好的机械强度和韧性，其使用方便，操作简单，并能较好地改善制品的性能及加工环境等，具有较好的应用前景。
上述实施方式仅为本发明的优选实施方式，不能以此来限定本发明保护的范围，本领域的技术人员在本发明的基础上所做的任何非实质性的变化及替换均属于本发明所要求保护的范围。
Claims (10)
- 一种聚氨酯用爽滑抗粘母粒，其特征在于，包括如下质量份数的组分：
- 根据权利要求1所述的聚氨酯用爽滑抗粘母粒，其特征在于，所述热塑性聚氨酯的质量份数为65-88份。
- 根据权利要求1所述的聚氨酯用爽滑抗粘母粒，其特征在于，所述抗粘连剂为SiO 2包覆Fe 3O 4的磁性粒子、埃洛石纳米管、酰胺类蜡与纳米级二氧化硅的复配物、高岭土、硅藻土、碳酸钙或滑石粉中的一种。
- 根据权利要求1所述的聚氨酯用爽滑抗粘母粒，其特征在于，所述爽滑剂为油酸酰胺、芥酸酰胺、硬脂酸锌、硬脂酸钙、棕榈酰胺、山嵛酸酰胺或硅树脂中的一种，优选为乙撑双油酸酰胺、乙撑双硬脂酰胺、棕榈酰胺、山嵛酸酰胺、季戊四醇硬脂酸酯。
- 根据权利要求1所述的聚氨酯用爽滑抗粘母粒，其特征在于，所述有机抗菌剂为6-溴己酸-2-(2-甲基丙烯酰氧)乙基酯吡啶盐、丙烯酰氧乙基二甲基乙基溴化铵、3-烯丙基-5,5-二甲基乙内酰脲、N-烯丙基吡啶或溴化烯丙基三乙基铵中的一种。
- 根据权利要求1所述的聚氨酯用爽滑抗粘母粒，其特征在于，所述离子抗菌剂为银离子抗菌剂、锌离子抗菌剂、铁离子抗菌剂、铝离子抗菌剂、钡离子抗菌剂或镁离子抗菌剂中的一种。
- 根据权利要求1所述的聚氨酯用爽滑抗粘母粒，其特征在于，所述抗静电剂为硬脂酸甘油类抗静电剂、酰胺类抗静电剂、乙基胺类抗静电剂中的一种。
- 一种聚氨酯用爽滑抗粘母粒的制备方法，其特征在于，包括如下步骤：S1、按照质量份数把抗粘连剂、爽滑剂投入到高速分散机中分散均匀，获 得A料；S2、按照质量份数把有机抗菌剂、离子抗菌剂投入到高速分散机中分散均匀，经过过滤、烘干、过筛获得B料；S3、把热塑性聚氨酯、A料、B料、抗静电剂按照比例加入到高速分散机中进行混合，时间15-25min，得到混合物；S4、将步骤S3中所得的混合物料加入双螺杆挤出机熔融，经过挤出切粒后，获得一种聚氨酯用爽滑抗粘母粒。
- 根据权利要求8所述的聚氨酯用爽滑抗粘母粒的制备方法，其特征在于，在所述步骤S1中，所述分散的温度40-45℃，分散的时间65-80min。
- 根据权利要求8所述的聚氨酯用爽滑抗粘母粒的制备方法，其特征在于，在所述步骤S2中，所述分散的温度45-50℃，分散的时间20-30min。
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| WO (1) | WO2023226134A1 (zh) |
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| CN116253984A (zh) * | 2022-09-09 | 2023-06-13 | 深圳市金露兴科技有限公司 | 一种密封条及其生产工艺 |
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| KR20180030959A (ko) * | 2016-09-17 | 2018-03-27 | 이종영 | 전기장 차단, 세균 방지, 곰팡이 방지, 난연 기능, 원적외선 방사기능을 가진 인체 친화적 고분자물질과 그 응용제품 |
| CN110283373A (zh) * | 2019-07-19 | 2019-09-27 | 航天特种材料及工艺技术研究所 | 一种热塑磁性复合材料及制备方法 |
| CN113480842A (zh) * | 2021-06-08 | 2021-10-08 | 浙江凯阳新材料股份有限公司 | 一种热塑性聚氨酯薄膜用抗粘连母粒及其制备方法 |
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- 2022-05-27 CN CN202210587650.5A patent/CN114773832A/zh active Pending
- 2022-06-24 WO PCT/CN2022/101252 patent/WO2023226134A1/zh unknown
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| JPH02199166A (ja) * | 1989-01-27 | 1990-08-07 | Kuraray Co Ltd | 熱可塑性ポリウレタン成形体及びその製造法 |
| US20080131704A1 (en) * | 2004-11-29 | 2008-06-05 | Naoki Mizuno | Laminated Thermoplastic Resin Film and Laminated Thermoplastic Resin Film Roll |
| CN104193949A (zh) * | 2014-07-30 | 2014-12-10 | 苏州市雄林新材料科技有限公司 | 一种纳米抗菌tpu材料及其制备方法 |
| CN104193950A (zh) * | 2014-07-30 | 2014-12-10 | 东莞市吉鑫高分子科技有限公司 | 一种纳米抗菌聚氨酯组合物及其制备方法 |
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| KR20180030959A (ko) * | 2016-09-17 | 2018-03-27 | 이종영 | 전기장 차단, 세균 방지, 곰팡이 방지, 난연 기능, 원적외선 방사기능을 가진 인체 친화적 고분자물질과 그 응용제품 |
| CN110283373A (zh) * | 2019-07-19 | 2019-09-27 | 航天特种材料及工艺技术研究所 | 一种热塑磁性复合材料及制备方法 |
| CN113480842A (zh) * | 2021-06-08 | 2021-10-08 | 浙江凯阳新材料股份有限公司 | 一种热塑性聚氨酯薄膜用抗粘连母粒及其制备方法 |
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| CN114773832A (zh) | 2022-07-22 |
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