WO2023223839A1 - Produit cosmétique de protection solaire - Google Patents

Produit cosmétique de protection solaire Download PDF

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Publication number
WO2023223839A1
WO2023223839A1 PCT/JP2023/017127 JP2023017127W WO2023223839A1 WO 2023223839 A1 WO2023223839 A1 WO 2023223839A1 JP 2023017127 W JP2023017127 W JP 2023017127W WO 2023223839 A1 WO2023223839 A1 WO 2023223839A1
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WO
WIPO (PCT)
Prior art keywords
cosmetic
oil
forming agent
film
mass
Prior art date
Application number
PCT/JP2023/017127
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English (en)
Japanese (ja)
Inventor
ターシャ 小畑
香代子 直井
収希 増田
Original Assignee
株式会社 資生堂
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Filing date
Publication date
Application filed by 株式会社 資生堂 filed Critical 株式会社 資生堂
Publication of WO2023223839A1 publication Critical patent/WO2023223839A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations

Definitions

  • the present invention relates to sunscreen cosmetics. More specifically, it consists of an oil-in-water emulsion (nanoemulsion) that has fine oil droplets containing a UV absorber, and can be used in the form of a top-up cosmetic that is applied on makeup-applied skin.
  • the present invention also relates to a sunscreen cosmetic that exhibits an ultraviolet protection effect exceeding the ultraviolet protection ability originally possessed by the ultraviolet absorber.
  • base cosmetics that are applied to makeup-applied skin and prevent makeup from fading.
  • Conventional base cosmetics generally contain a film-forming agent and protect the base cosmetic with a film formed by the film-forming agent to prevent/suppress makeup fading.
  • the finishing cosmetic described in Patent Document 1 contains a predetermined amount of fine cellulose fibers and a polymer having film-forming ability in an aqueous medium, and is applied in the form of a mist onto makeup cosmetics such as foundation. By spraying on the skin, you can prevent makeup from fading and secondary adhesion.
  • top cosmetics also called “fix mist”
  • fix mist which can be used in the same way as the above-mentioned finishing cosmetics, to have functions such as skin care and UV protection, in addition to functions such as preventing makeup from fading. It has become.
  • cosmetic ingredients with skin care and UV protection functions are often highly polar oils, and it has been difficult to stably incorporate them into an aqueous medium.
  • Patent Document 2 discloses a transparent water-based cosmetic containing predetermined amounts of a UV absorber having a specific triazine skeleton, polyoxyethylene hydrogenated castor oil having an average added mole of polyoxyethylene of 20 to 50 moles, ethanol, and water. Fees are listed.
  • This transparent water-based cosmetic is a stable oil-in-water type fine emulsion (nanoemulsion) in which the particle size of the ultraviolet absorber having a triazine skeleton is 20 to 100 nm.
  • Patent Document 3 discloses an oil-in-water type fine emulsion (average particle size of 150 nm or less) in which a poorly soluble ultraviolet absorber is stably blended by replacing the ethanol in Patent Document 2 with a polyol.
  • a poorly soluble ultraviolet absorber is stably blended by replacing the ethanol in Patent Document 2 with a polyol.
  • stability is maintained even when the amounts of the ultraviolet absorber and the surfactant are approximately the same, but the appearance of the fine emulsion is not transparent.
  • Patent No. 6940980 Patent No. 4226951 JP2013-47206A
  • the present invention was made in view of the current state of the technology, and provides an excellent fine emulsion (nanoemulsion) that can stably incorporate a UV absorber, which is a polar oil, and has a transparent or translucent appearance.
  • the purpose of the present invention is to provide a sunscreen cosmetic that exhibits a UV protection effect.
  • the present inventors selected a specific polyoxyethylene hydrogenated castor oil as a surfactant, and used it to apply polar oil to an aqueous medium containing ethanol.
  • the present inventors have discovered that the above-mentioned problems can be solved by forming a nanoemulsion in which ultraviolet absorbers are finely emulsified and further incorporating powder and/or film forming agents, and have completed the present invention.
  • the present invention (a) UV absorber; (b) lower alcohol; and (c) consisting of an oil-in-water nanoemulsion containing a surfactant containing polyoxyethylene hydrogenated castor oil with an added mole of oxyethylene of 20 to 30;
  • the present invention provides a sunscreen cosmetic characterized by further containing one or both of (d) a powder and (e) a film-forming agent.
  • the sunscreen cosmetic of the present invention is capable of stably retaining (a) the ultraviolet absorber, which is a polar oil. Furthermore, by blending (d) powder and/or (e) film forming agent, the ultraviolet protection ability originally possessed by (a) the ultraviolet absorber is further improved (boosted). Therefore, (a) a high UV protection effect can be achieved even if the amount of oil containing UV absorbers is small, so it feels refreshing when applied to the skin, has a transparent or translucent appearance, and has a mist-like appearance. It can also be applied by spraying. Furthermore, like conventional finishing cosmetics, it is possible to obtain a multifunctional cosmetic that not only prevents makeup from fading but also has an excellent protective effect against ultraviolet rays.
  • the sunscreen cosmetic of the present invention (hereinafter also simply referred to as “cosmetic") comprises (a) an ultraviolet absorber, (b) a lower alcohol, and (c) a polyoxyethylene having an added mole of oxyethylene of 20 to 30. It consists of a nanoemulsion containing a surfactant containing hydrogenated castor oil, and is characterized by further containing (d) powder and/or (e) a film forming agent.
  • polyoxyethylene may be abbreviated as "POE”, polyoxypropylene as “POP”, polyethylene glycol as “PEG”, ethylene oxide as "EO”, and propylene oxide as "PO”.
  • the (a) ultraviolet absorber (hereinafter sometimes simply referred to as "component (a)") in the cosmetic of the present invention is an organic ultraviolet absorber that can be used in cosmetics, etc. Not particularly limited. Among these, it is preferable to contain at least one organic ultraviolet absorber that is liquid at room temperature, such as octyl methoxycinnamate (2-ethylhexyl para-methoxycinnamate), ethylhexyl salicylate, homosalate, octocrylene, and the like.
  • organic UV absorbers oil-soluble UV absorbers
  • polar oils including organic UV absorbers that are liquid at room temperature
  • t-butylmethoxydibenzoylmethane ethylhexyltri Azone
  • diethylaminohydroxybenzoylhexylbenzoate bisethylhexyloxyphenolmethoxyphenyltriazine, oxybenzone-3
  • methylenebisbenzotriazolyltetramethylbutylphenol and the like
  • an oil-soluble ultraviolet absorber it is preferably blended in a state dissolved in polar oil.
  • the polar oil that functions as a solvent for the oil-soluble ultraviolet absorber can be blended into cosmetics, and is not particularly limited as long as it is a highly polar oil that is liquid at room temperature (25°C).
  • the polar oil is preferably selected from oils with an IOB value of 0.1 or more, particularly an IOB value of more than 0.1 and less than 0.6.
  • IOB value is set according to the atom or functional group, and the "inorganic value” and “organic value” of all atoms and functional groups in an organic compound are integrated.
  • the IOB value of the organic compound can be calculated by (for example, see Yoshio Koda, "Organic Conceptual Diagram - Basics and Applications", pp. 11-17, published by Sankyo Publishing, 1984).
  • polar oils other than organic ultraviolet absorbers that are liquid at room temperature
  • polar oils include, but are not limited to, fatty acids such as oleic acid and isostearic acid; alkyl benzoate (C12-15), isopropyl myristate, octyl palmitate, Isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, isononyl isononanoate, isotridecyl isononanoate, cetyl ethylhexanoate, glycol distearate, glyceryl diisostearate, neopentyl glycol dicaprate, dimalate Isostearyl, glyceryl tri-2-ethylhexanoate (triethylhexanoin), trimethylolpropane trioctanoate, trimethylolpropane triis
  • the cosmetic of the present invention is in the form of a nanoemulsion, it is stable even if it contains a relatively large amount of (a) ultraviolet absorber, which is a polar oil. Therefore, the lower limit of the amount of ultraviolet absorber (a) in the cosmetic of the present invention is, for example, 1% by mass or more, 3% by mass or more, 5% by mass or more, or 7% by mass, based on the total amount of the cosmetic. It can be more than that.
  • the upper limit of the blending amount of the ultraviolet absorber can be, for example, 40% by mass or less, 35% by mass or less, or 30% by mass or less, based on the total amount of the cosmetic.
  • the blending amount range of the ultraviolet absorber can be, for example, 1 to 40% by weight, 3 to 35% by weight, 5 to 30% by weight, or 7 to 30% by weight.
  • it is formulated so that (a) UV absorber accounts for 50% by mass or more, 60% by mass or more, 70% by mass or more, or 80% by mass or more of the total amount of polar oil blended in the cosmetic. It is preferable to do so.
  • the cosmetic of the present invention is a nanoemulsion in which an oil containing the polar oil (including (a) ultraviolet absorber) is finely emulsified in an aqueous medium, and the aqueous medium includes water and (b) Contains lower alcohol.
  • the lower alcohol (b) (hereinafter sometimes simply referred to as "component (b)”) is typically a monohydric alcohol having 1 to 4 carbon atoms. Specific examples include methanol, ethanol, propanol, isopropanol, and butanol, among which ethanol is preferably used.
  • the amount of lower alcohol (b) in the cosmetic of the present invention can be, for example, 1 to 20% by mass, preferably 5 to 15% by mass, and 7 to 12% by mass, based on the total amount of the cosmetic. It is more preferable to express it in mass %. (b) If the amount of lower alcohol is less than 1% by mass, a stable nanoemulsion may not be formed.
  • the cosmetic of the present invention is made by finely emulsifying the (a) oil containing an ultraviolet absorber into the (b) aqueous medium containing a lower alcohol using (c) a surfactant. Contains emulsions.
  • the surfactant (c) used in the present invention (hereinafter sometimes simply referred to as "component (c)") contains polyoxyethylene hydrogenated castor oil having an added mole of oxyethylene of 20 to 30.
  • POE hydrogenated castor oil Polyoxyethylene hydrogenated castor oil (hereinafter referred to as "POE hydrogenated castor oil”) is widely used in cosmetics because it is highly safe for the skin among nonionic surfactants.
  • POE hydrogenated castor oils having an added mole of oxyethylene of 20 to 30 are used.
  • POE hydrogenated castor oil with an added mole of oxyethylene of 20 to 30 refers to POE (20) hydrogenated castor oil with an added mole of oxyethylene of 20 (PEG-20 hydrogenated castor oil).
  • HLB Hydrophilic Balance
  • the amount of "POE hydrogenated castor oil with an added mole of oxyethylene of 20 to 30" is preferably 1 to 15% by mass, and 2 to 12% by mass based on the total amount of the cosmetic. It is more preferable to set it as mass %, and it is still more preferable to set it as 3 mass % or more and less than 10 mass %.
  • the present invention excludes the use of nonionic surfactants or ionic surfactants other than "POE hydrogenated castor oil with an added mole of oxyethylene of 20 to 30" as (c) a surfactant. It's not a thing. However, the blending amount is limited to a range that does not impede the effects of the present invention.
  • the cosmetic of the present invention has an embodiment in which (c) the surfactant consists only of "POE hydrogenated castor oil with an added mole of oxyethylene of 20 to 30", for example, polysorbate 80, sorbitan monoisostearate or sorbitan diisostearate. This includes embodiments that do not contain sorbitan fatty acid esters.
  • the powder (d) (hereinafter sometimes referred to as "component (d)") blended into the cosmetic of the present invention is not particularly limited as long as it is a powder component that can be blended into the cosmetic.
  • component (d) The shape of the powder is not particularly limited, and examples include extender pigments, organic or inorganic powders, and clay minerals.
  • extender pigments include talc, kaolin, mica, synthetic mica, sericite, magnesium carbonate, calcium carbonate, barium sulfate, and talc/silica/titanium oxide complex.
  • organic or inorganic powders include organic powders such as nylon, polyacrylonitrile, polyester, polyethylene, polypropylene, polystyrene, polyurethane, cellulose, starch, and silicone resins, magnesium silicate, calcium silicate, titanium oxide, and anhydrous silicon.
  • examples include inorganic powders such as acid (silica).
  • clay minerals include natural or synthetic laponite and smectite, such as montmorillonite, bentonite, saponite, and hectorite.
  • the blending amount of the powder (d) in the cosmetic of the present invention is preferably 0.1 to 5% by mass, more preferably 0.3 to 4% by mass, and 0.5 to 3% by mass based on the total amount of the cosmetic. is even more preferable. If the blending amount is less than 0.1% by mass, the effect of powder blending may not be obtained.
  • film-forming agent (e) (hereinafter also referred to as “component (e)") blended into the cosmetic of the present invention is a substance that forms a film when the solvent evaporates. There is no particular limitation as long as it can be used for food, etc.
  • Film forming agents include water-soluble ones and oil-soluble ones.
  • water-soluble film forming agents include hydroxyethyl cellulose, polyvinyl alcohol, polyvinylpyrrolidone (PVP), hydrolyzed cornstarch, polyethylene glycol (high molecular weight), and the like.
  • oil-soluble film forming agents include vinylpyrrolidone (VP)/dimethylaminoethyl methacrylic acid copolymer, VP/eicosene copolymer, VP/ethyl methacrylate/methacrylic acid copolymer, VP/hexadecene copolymer, VP/vinyl acetate ( Vinylpyrrolidone film forming agents such as VA) copolymers, VP/VA/itaconic acid copolymers, styrene/VP copolymers; ethyl acrylate/acrylic acid amide/acrylic acid copolymers, ethyl acrylate/butyl acrylate copolymers, ethyl acrylate/ Ethyl methacrylate copolymer, ethyl acrylate/methacrylate copolymer, ethyl acrylate/methyl methacrylate copolymer, octy
  • the blending amount of the film forming agent (e) in the cosmetic of the present invention is preferably 0.1 to 5% by mass, more preferably 0.3 to 4% by mass, and 0.5 to 3% by mass, based on the total amount of the cosmetic. Mass % is more preferred. If the blending amount is less than 0.1% by mass, the effect of blending the film forming agent may not be obtained.
  • the cosmetic of the present invention contains (a) an ultraviolet absorber, (b) a lower alcohol (such as ethanol), and (c) a surfactant, and further contains (d) a powder and/or (e) a film forming agent.
  • a nanoemulsion that refers to a fine oil-in-water emulsion whose emulsion particle size is less than 200 nm, preferably less than 100 nm. By forming the nanoemulsion with such a small emulsion particle size, excellent emulsion stability and a transparent or translucent appearance can be achieved.
  • the "emulsion particle diameter" in this specification is a value measured by a dynamic light scattering method, specifically, a value measured at 25° C. using Zeta sizer nano (manufactured by Malvern).
  • the ratio (mass ratio) of the amount of (c) surfactant to the amount of (b) lower alcohol (mass ratio) [(c)/(b)] is preferably less than 1.5, and more preferably Preferably it is 1.2 or less, more preferably 1.0 or less.
  • the ratio (mass ratio) of the amount of (c) surfactant to (a) the amount of polar oil containing an ultraviolet absorber [(c)/polarity oil] is preferably 4 or less, more preferably 3 or less, still more preferably 2 or less.
  • the range of this ratio [(c)/polar oil] is preferably from 0.3 to 3, particularly preferably from 0.4 to 2.
  • the cosmetic composition of the present invention may contain other optional components that can be normally incorporated into cosmetic compositions within a range that does not impair the effects of the present invention.
  • examples include oils (other than polar oils), humectants, thickeners, various medicinal ingredients, preservatives, antioxidants, and the like.
  • polyhydric alcohols such as glycerin, ethylene glycol, propylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, 1,2-pentanediol (pentylene glycol), 1,5-pentane Diol, neopentyl glycol, 1,2-hexanediol, 1,6-hexanediol, 1,2-cyclohexanediol, heptanediol, 1,8-octanediol, 1,9-nonanediol, 1,10-decanediol , diglycerin, pentaerythritol, diethylene glycol, dipropylene glycol, triethylene glycol, tetraethylene glycol, polyethylene glycol (low molecular weight), polypropylene glycol, thiodiglycol, and the like.
  • the cosmetic of the present invention can be easily used as a top cosmetic that is applied on makeup-applied skin. Since it is in the form of an oil-in-water nanoemulsion with fine oil droplets, it feels refreshing and less sticky when applied to the skin. For example, it can be provided in a container equipped with a nozzle with a diameter of 0.1 to 1.0 ⁇ , and used by spraying it in a mist.
  • the cosmetic of the present invention is preferably prepared to have a viscosity that does not run off on the skin, for example, a viscosity of about 1000 mPa ⁇ s.
  • the cosmetic of the present invention can contain a relatively large amount of ultraviolet absorber as an oil-in-water nanoemulsion cosmetic, and has a transparent or translucent appearance. It is particularly suitable as a sunscreen cosmetic that prevents or suppresses makeup fading and at the same time exhibits high UV protection ability.
  • the blending amount is expressed in mass % based on the system in which the component is blended.
  • Nanoemulsion compositions were prepared according to the formulations listed in Tables 1 to 3 below.
  • the composition of each example was evaluated for makeup durability, UV protection ability, rate of increase in UV protection ability (booster effect), transparency of appearance, and usability using the following methods.
  • composition (cosmetic) of each example was dropped in an amount of 2 mg/cm 2 onto a measurement plate (S plate) (5 x 5 cm V-groove PMMA (polymethyl methacrylate) plate, SPFMASTER-PA01), and the mixture was poured with a finger for 60 seconds. After coating and drying for 15 minutes, the absorbance of the formed coating film was measured using a U-3500 self-recording spectrophotometer manufactured by Hitachi, Ltd.
  • UV protection ability increase rate (%)] ⁇ ([Accumulated absorbance value of each example]/[Accumulated absorbance value of control]) ⁇ 100 ⁇ -100
  • compositions (cosmetics) of each example were placed in a container equipped with a nozzle with a diameter of 0.25 to 0.4 ⁇ , and mist was sprayed onto the skin of a professional panel on which makeup was applied, and the stickiness after application was sensory evaluated.
  • an oil containing an ultraviolet absorber is added to (b) an aqueous medium containing a lower alcohol, and (c) a hydrogenated polyoxyethylene with an added mole number of oxyethylene of 20 to 30.
  • the cosmetic of the present invention is made of an oil-in-water nanoemulsion finely emulsified using a surfactant containing castor oil, and contains (d) a powder or (e) a film-forming agent. It can be sprayed with a mist from a small nozzle, has excellent usability and long-lasting makeup, and shows particularly high (boosted) UV protection effects.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
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Abstract

La présente invention concerne un produit cosmétique de protection solaire qui présente une excellente protection contre les UV, est une émulsion fine (nanoémulsion) d'aspect transparent ou translucide, et peut être mélangé de manière stable avec un absorbeur d'UV, qui est une huile polaire. La présente invention concerne un produit cosmétique de protection solaire comprenant une nanoémulsion de type huile dans l'eau contenant (a) un absorbeur d'UV, (b) un alcool inférieur, et (c) un tensioactif contenant de l'huile de ricin hydrogénée de polyoxyéthylène ayant de 20 à 30 moles ajoutées d'oxyéthylène et caractérisé en ce qu'il contient également (d) une poudre et/ou (e) un agent filmogène.
PCT/JP2023/017127 2022-05-18 2023-05-02 Produit cosmétique de protection solaire WO2023223839A1 (fr)

Applications Claiming Priority (2)

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JP2022-081547 2022-05-18
JP2022081547 2022-05-18

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WO2023223839A1 true WO2023223839A1 (fr) 2023-11-23

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002068935A (ja) * 2000-07-13 2002-03-08 L'oreal Sa 非イオン性ポリマーを含有するナノエマルジョン、及びその使用、特に化粧、皮膚科学、薬学、及び／又は眼科学の分野における使用
JP2004352678A (ja) * 2003-05-30 2004-12-16 Shiseido Co Ltd 透明水系組成物
JP2008537952A (ja) * 2005-04-14 2008-10-02 モーメンティブ・パフォーマンス・マテリアルズ・インク 良好な特性を有する、シリコーン樹脂含有パーソナルケア組成物、その製造方法並びにその使用
JP2012140404A (ja) * 2010-12-13 2012-07-26 Shiseido Co Ltd 水中油型乳化日焼け止め化粧料
JP2015503587A (ja) * 2012-01-04 2015-02-02 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド イオン性シリコーンおよび膜形成剤を含有するパーソナルケア組成物
JP2019151567A (ja) * 2018-03-01 2019-09-12 花王株式会社 ミスト化粧料
WO2020175398A1 (fr) * 2019-02-27 2020-09-03 株式会社コーセー Produit cosmétique de protection de maquillage de type multicouche
JP2021059534A (ja) * 2019-10-04 2021-04-15 ジョンソン・アンド・ジョンソン・コンシューマー・インコーポレイテッドＪｏｈｎｓｏｎ ＆ Ｊｏｈｎｓｏｎ Ｃｏｎｓｕｍｅｒ Ｉｎｃ． 噴霧可能な日焼け止め組成物

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002068935A (ja) * 2000-07-13 2002-03-08 L'oreal Sa 非イオン性ポリマーを含有するナノエマルジョン、及びその使用、特に化粧、皮膚科学、薬学、及び／又は眼科学の分野における使用
JP2004352678A (ja) * 2003-05-30 2004-12-16 Shiseido Co Ltd 透明水系組成物
JP2008537952A (ja) * 2005-04-14 2008-10-02 モーメンティブ・パフォーマンス・マテリアルズ・インク 良好な特性を有する、シリコーン樹脂含有パーソナルケア組成物、その製造方法並びにその使用
JP2012140404A (ja) * 2010-12-13 2012-07-26 Shiseido Co Ltd 水中油型乳化日焼け止め化粧料
JP2015503587A (ja) * 2012-01-04 2015-02-02 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド イオン性シリコーンおよび膜形成剤を含有するパーソナルケア組成物
JP2019151567A (ja) * 2018-03-01 2019-09-12 花王株式会社 ミスト化粧料
WO2020175398A1 (fr) * 2019-02-27 2020-09-03 株式会社コーセー Produit cosmétique de protection de maquillage de type multicouche
JP2021059534A (ja) * 2019-10-04 2021-04-15 ジョンソン・アンド・ジョンソン・コンシューマー・インコーポレイテッドＪｏｈｎｓｏｎ ＆ Ｊｏｈｎｓｏｎ Ｃｏｎｓｕｍｅｒ Ｉｎｃ． 噴霧可能な日焼け止め組成物

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