WO2023181866A1 - 化合物、組成物、表面処理剤、物品の製造方法、及び物品 - Google Patents
化合物、組成物、表面処理剤、物品の製造方法、及び物品 Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/587—Monocarboxylic acid esters having at least two carbon-to-carbon double bonds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/21—Cyclic compounds having at least one ring containing silicon, but no carbon in the ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/18—Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films
Definitions
- Patent Document 1 describes a surface treatment agent made of n-octadecyltrimethoxysilane.
- Means for solving the above problems include the following aspects.
- ⁇ 1> A direct or polyvalent linkage between a straight chain alkyl group having 19 or more carbon atoms or a straight chain alkylene group having 19 or more carbon atoms and the straight chain alkyl group having 19 or more carbon atoms or a straight chain alkylene group having 19 or more carbon atoms. a reactive silyl group linked via a group.
- ⁇ 2> The compound according to ⁇ 1>, wherein the linear alkyl group having 19 or more carbon atoms or the linear alkylene group having 19 or more carbon atoms has 19 to 30 carbon atoms.
- R 31 is a hydrogen atom, a hydroxyl group or an alkyl group.
- the number of carbon atoms in the alkyl group is preferably 1 to 5, more preferably 1 to 3, and even more preferably 1.
- y is an integer from 1 to 10, preferably from 1 to 6.
- Two or more [CH 2 C(R 32 )(-Q d -Si(R) n L 3-n )] may be the same or different.
- X 32 is -O-, -C(O)O-, -SO 2 N(R d )-, -N(R d )SO 2 -, -N(R d ) C(O)-, -C(O)N(R d )-, -OC(O)-, -OC(O)N(R d )-, -S-, -C(O)S- , or -N(R d )- (wherein N in the formula is bonded to Q b1 ).
- the definition of R d is as described above. s1 is 0 or 1.
- Q b1 is a single bond, -OCH 2 CH 2 CH 2 -, -OCH 2 CH 2 OCH 2 CH 2 CH 2 -, and -OCH 2 CH 2 CH 2 Si (CH 3 ) when s1 is 0. 2 OSi(CH 3 ) 2 CH 2 CH 2 - is preferred.
- (X 32 ) s1 is -O-, -CH 2 CH 2 CH 2 - and -CH 2 CH 2 OCH 2 CH 2 CH 2 - are preferable as Q b1 .
- (X 32 ) s1 is -C(O)N(R d )-, it is preferably an alkylene group having 2 to 6 carbon atoms (however, N in the formula is bonded to Q b1 ).
- Q b1 is one of these groups, the compound can be easily produced.
- X 33 is -O-, -NH-, -C(O)O-, -SO 2 N(R d )-, -N(R d )SO 2 -, -N(R d )C(O)- or -C(O)N(R d )-.
- R d is as described above.
- the alkylene group represented by Q a2 preferably has 1 to 20 carbon atoms, more preferably 1 to 10 carbon atoms, even more preferably 1 to 6 carbon atoms, and particularly preferably 1 to 3 carbon atoms.
- Q a2 is -CH 2 -, -CH 2 CH 2 -, -CH 2 CH 2 CH 2 -, -CH 2 OCH 2 CH 2 - , -CH 2 NHCH 2 CH 2 - from the viewpoint of easy production of the compound.
- -CH 2 OC(O)CH 2 CH 2 -, or -C(O)- are preferred.
- s2 is 0 or 1 (however, when Q a2 is a single bond, it is 0). From the viewpoint of easy production of the compound, 0 is preferable.
- Q b2 is an alkylene group or a group having a divalent organopolysiloxane residue, an ether oxygen atom, or -NH- between carbon atoms of an alkylene group having 2 or more carbon atoms.
- the number of carbon atoms in the alkylene group represented by Q b2 is preferably 1 to 30, more preferably 1 to 20, even more preferably 2 to 20, may be 2 to 10, or may be 2 to 6. . Examples include 2, 3, 8, 9, and 11. Further, the number of carbon atoms may be 1 to 10.
- Q b3 is an alkylene group or a group having an ether oxygen atom or a divalent organopolysiloxane residue between carbon atoms of an alkylene group having 2 or more carbon atoms.
- the number of carbon atoms in the alkylene group represented by Q b3 is preferably 1 to 30, more preferably 1 to 20, even more preferably 2 to 20, may be 2 to 10, or may be 2 to 6. . Examples include 2, 3, 8, 9, and 11. Further, the number of carbon atoms may be 1 to 10.
- Q e is -C(O)O-, -SO 2 N(R d )-, -N(R d )SO 2 -, -N(R d )C( O)- or -C(O)N(R d )-.
- R 31 is as described above.
- s4 is 0 or 1.
- Q a4 is a single bond, an alkylene group which may have an etheric oxygen atom (when s4 is 1), or a (poly)oxyalkylene group (when s4 is 0).
- the number of carbon atoms in the alkylene group or (poly)oxyalkylene group which may have an etheric oxygen atom is preferably 1 to 20, more preferably 1 to 10, even more preferably 1 to 6, particularly 1 to 3. preferable. Further, the number of carbon atoms may be 2 to 6.
- t4 is 0 or 1 (however, when Q a4 is a single bond, it is 0).
- u4 is 0 or 1.
- -(O) u4 -Q b4 - includes -CH 2 CH 2 -, -CH 2 CH 2 CH 2 -, -CH 2 OCH 2 CH 2 CH 2 -, -CH 2 from the viewpoint of easy production of the compound.
- OCH 2 CH 2 CH 2 CH 2 CH 2 -, -OCH 2 CH 2 CH 2 -, -OSi(CH 3 ) 2 CH 2 CH 2 CH 2 -, -OSi(CH 3 ) 2 OSi(CH 3 ) 2 CH 2 CH 2 CH 2 -- and --CH 2 CH 2 CH 2 Si(CH 3 ) 2 PhSi(CH 3 ) 2 CH 2 CH 2 -- are preferred (however, the right side is bonded to Si).
- group (3-1A-4) include the following groups.
- * represents the bonding position with CH 3 (CH 2 ) m1 - or -(CH 2 ) m2 -.
- Q a5 is a single bond or a (poly)oxyalkylene group.
- the number of carbon atoms in the (poly)oxyalkylene group is preferably 1 to 20, more preferably 1 to 10, even more preferably 1 to 6, particularly preferably 1 to 3. Further, the number of carbon atoms may be 2 to 6.
- Q a5 from the viewpoint of easy production of the compound, a single bond, -OCH 2 CH 2 CH 2 -, and -OCH 2 CH 2 OCH 2 CH 2 CH 2 - are preferable (provided that the right side is bonded to Si. ).
- Q b5 is an alkylene group or a group having an ether oxygen atom or a divalent organopolysiloxane residue between carbon atoms of an alkylene group having 2 or more carbon atoms.
- the number of carbon atoms in the alkylene group represented by Q b5 is preferably 1 to 30, more preferably 1 to 20, even more preferably 2 to 20, may be 2 to 10, or may be 2 to 6. . Examples include 2, 3, 8, 9, and 11. Further, the number of carbon atoms may be 1 to 10.
- the number of carbon atoms in the group having an ether oxygen atom or a divalent organopolysiloxane residue between carbon atoms of the alkylene group having 2 or more carbon atoms represented by Q b5 is preferably 2 to 20, and 2 to 20. 10 is more preferable, and 2 to 6 is even more preferable. From the viewpoint of easy production of the compound, Q b5 is preferably -CH 2 CH 2 CH 2 - and -CH 2 CH 2 OCH 2 CH 2 CH 2 - (provided that the right side is Si(R) n L 3- bond to n ).
- the three [-Q b5 -Si(R) n L 3-n ] may be the same or different.
- group (3-1A-5) include the following groups.
- * represents the bonding position with CH 3 (CH 2 ) m1 - or -(CH 2 ) m2 -.
- Q a6 is a single bond, an alkylene group which may have an etheric oxygen atom (when v is 1), or a (poly)oxyalkylene group.
- the number of carbon atoms in the alkylene group or (poly)oxyalkylene group which may have an etheric oxygen atom is preferably 1 to 20, more preferably 1 to 10, even more preferably 1 to 6, particularly 1 to 3. preferable. Further, the number of carbon atoms may be 2 to 6.
- Q a6 is -CH 2 OCH 2 CH 2 CH 2 -, -CH 2 OCH 2 CH 2 OCH 2 CH 2 CH 2 -, -CH 2 CH 2 from the viewpoint of easy production of the compound .
- Q b6 is an alkylene group or a group having an ether oxygen atom or a divalent organopolysiloxane residue between carbon atoms of an alkylene group having 2 or more carbon atoms.
- the number of carbon atoms in the alkylene group represented by Q b6 is preferably 1 to 30, more preferably 1 to 20, even more preferably 2 to 20, may be 2 to 10, or may be 2 to 6. . Examples include 2, 3, 8, 9, and 11. Further, the number of carbon atoms may be 1 to 10.
- group (3-1A-6) include the following groups.
- * represents the bonding position with CH 3 (CH 2 ) m1 - or -(CH 2 ) m2 -.
- Z c may consist of a hydrocarbon chain, may have an ether oxygen atom between carbon atoms of the hydrocarbon chain, and is preferably composed of a hydrocarbon chain.
- the valence of Z c is preferably 5 to 20, more preferably 5 to 10, even more preferably 5 to 8, particularly preferably penta or hexavalent.
- the number of carbon atoms in Z c is preferably 3 to 50, more preferably 4 to 40, even more preferably 5 to 30.
- w3 is preferably 4 to 20, more preferably 4 to 16, even more preferably 4 to 8, and particularly preferably 4 or 5.
- w4 is preferably 0 to 10, more preferably 0 to 8, even more preferably 0 to 6, particularly preferably 0 to 3, and most preferably 0 or 1.
- Q 13 is a single bond, an alkylene group, a group having -C(O)NR 6 -, -C(O)-, -NR 6 - or O- between carbon atoms of an alkylene group having 2 or more carbon atoms; , or a group having -C(O)- at the N-side end of the alkylene group.
- Q 14 is Q 12 when the atom in Z 1 to which Q 14 is bonded is a carbon atom, and is Q 13 when the atom in Z 1 to which Q 14 is bonded is a nitrogen atom; and Q 14 is Y 10 , Y 11 or When Y 12 has two or more Q 14 , two or more Q 14 may be the same or different.
- e1 is an integer of 1 to 3 in Y 10 , preferably 1 or 2, and is 1 in Y 11 and Y 12 .
- e2 is an integer from 1 to 3 in Y 10 , preferably 2 or 3, and is 2 or 3 in Y 11 and Y 12 .
- h1 is an integer of 1 or more in Y10 , preferably 1 or 2, and is 1 in Y11 and Y12 .
- h2 is an integer of 1 or more, preferably 2 or 3.
- i1+i2 is 3 or 4.
- i1 is an integer of 1 to 3 in Y 10 , preferably 1 or 2, and is 1 in Y 11 and Y 12 .
- i2 is an integer of 1 to 3 in Y 10 , preferably 2 or 3, and is 2 or 3 in Y 11 and Y 12 .
- i3 is 2 or 3.
- the number of carbon atoms in the alkyl group of R e1 , R e2 or R e3 is preferably 1 to 6, more preferably 1 to 3, and even more preferably 1 to 2 from the viewpoint of ease of manufacturing the compound.
- the number of carbon atoms in the alkyl group portion of the acyloxy group in R e2 is preferably 1 to 6, more preferably 1 to 3, and even more preferably 1 to 2 from the viewpoint of ease of manufacturing the compound.
- h1 is preferably 1 to 6, more preferably 1 to 4, even more preferably 1 or 2, and particularly preferably 1, from the viewpoint of easy production of the compound and the viewpoint of further excellent wear resistance of the surface treatment layer.
- h2 is preferably 2 to 6, more preferably 2 to 4, and even more preferably 2 or 3, from the viewpoint of ease of manufacturing the compound and the viewpoint of further excellent wear resistance of the surface treatment layer.
- Examples of the compound (3-1) in which Y 10 is a group (g2-2) include compounds of the following formula.
- Examples of the compound (3-1) in which Y 10 is a group (g2-3) include compounds of the following formula.
- Examples of the compound (3-1) in which Y 10 is a group (g2-9) include compounds of the following formula.
- Examples of the compound (3-1) in which Y 10 is a group (g2-14) include compounds of the following formula.
- Examples of the compound (3-2) in which Y 11 and Y 12 are groups (g2-2) include compounds of the following formula:
- Examples of the compound (3-2) in which Y 11 and Y 12 are groups (g2-3) include compounds of the following formula.
- halogenated organic solvents include dichloromethane, chloroform, carbon tetrachloride, dichloroethane, chlorobenzene, o-chlorotoluene, m-chlorotoluene, p-chlorotoluene, m-dichlorobenzene, 1,2,3-trichloropropane. can be mentioned.
- composition of the present disclosure contains a liquid medium, it is useful for coating purposes and can be used as a coating liquid.
- Group 2 elements of the periodic table mean beryllium, magnesium, calcium, strontium, and barium.
- Group 2 elements magnesium, calcium, and barium are used because they enable the surface treatment layer to be formed more uniformly on the underlayer without defects, and from the viewpoint of suppressing variations in the composition of the underlayer between samples.
- magnesium and calcium are more preferable.
- the underlayer may contain two or more types of Group 2 elements.
- Group 13 elements of the periodic table mean boron, aluminum, gallium, and indium.
- Group 13 elements boron, aluminum, and gallium are selected from the viewpoint of forming a surface treatment layer on the underlayer more uniformly without defects, or from the viewpoint of suppressing variations in the composition of the underlayer between samples.
- boron and aluminum are more preferable.
- the base layer may contain two or more types of Group 13 elements.
- the oxide contained in the base layer may be a mixture of oxides of the above elements (silicon and specific elements) alone (for example, a mixture of silicon oxide and an oxide of a specific element), or a mixture of the above elements (silicon and specific elements). It may be a composite oxide containing two or more types, or a mixture of an oxide of the above element alone and a composite oxide.
- a plurality of boats may be used, or all the evaporation materials may be placed in a single boat.
- the vapor deposition method may be codeposition, alternate vapor deposition, or the like. Specifically, examples include mixing silica and a specific element source in the same boat, co-evaporating silica and a specific element source in separate boats, and alternately depositing silica and a specific element source in separate boats. can be mentioned.
- the conditions, order, etc. of vapor deposition are appropriately selected depending on the structure of the underlying layer.
- the article of the present disclosure is preferably an optical member.
- optical components include medical devices such as car navigation systems, mobile phones, smartphones, digital cameras, digital video cameras, PDAs, portable audio players, car audio, game devices, eyeglass lenses, camera lenses, lens filters, sunglasses, and gastrocameras.
- medical devices such as car navigation systems, mobile phones, smartphones, digital cameras, digital video cameras, PDAs, portable audio players, car audio, game devices, eyeglass lenses, camera lenses, lens filters, sunglasses, and gastrocameras.
- Examples include personal appliances, copying machines, PCs, displays (eg, liquid crystal displays, organic EL displays, plasma displays, touch panel displays), touch panels, protective films, and antireflection films.
- the article is preferably a display or a touch panel.
- an operation may be performed to accelerate the reaction between the compound of the present disclosure and the base material, if necessary.
- Such operations include heating, humidification, light irradiation, and the like.
- a hydrolysis reaction of hydrolyzable groups, a reaction between hydroxyl groups, etc. on the surface of the base material and silanol groups, and a condensation reaction of silanol groups. can promote reactions such as the formation of siloxane bonds.
- compounds in the surface treatment layer that are not chemically bonded to other compounds or the base material may be removed as necessary. Examples of the removal method include a method of pouring a solvent onto the surface treatment layer, a method of wiping with a cloth impregnated with a solvent, and the like.
- the compounds of the present disclosure are useful as surface treatment agents.
- the surface treatment agent can be used, for example, for substrates in display devices such as touch panel displays, optical elements, semiconductor elements, building materials, automobile parts, nanoimprint technology, and the like.
- the surface treatment agent can be used for bodies, window glasses (windshields, side glasses, rear glasses), mirrors, bumpers, etc. of transportation equipment such as trains, automobiles, ships, and airplanes.
- the surface treatment agent can be used for outdoor articles such as building exterior walls, tents, solar power generation modules, sound insulation boards, and concrete; fishing nets, insect nets, and aquariums.
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Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202380029333.4A CN118974064A (zh) | 2022-03-24 | 2023-03-03 | 化合物、组合物、表面处理剂、物品的制造方法、及物品 |
| JP2024509926A JPWO2023181866A1 (https=) | 2022-03-24 | 2023-03-03 | |
| US18/892,759 US20250034428A1 (en) | 2022-03-24 | 2024-09-23 | Compound, composition, surface treatment agent, method of producing article, and article |
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| JP2022-049074 | 2022-03-24 | ||
| JP2022049074 | 2022-03-24 |
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| US18/892,759 Continuation US20250034428A1 (en) | 2022-03-24 | 2024-09-23 | Compound, composition, surface treatment agent, method of producing article, and article |
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| WO2023181866A1 true WO2023181866A1 (ja) | 2023-09-28 |
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| US (1) | US20250034428A1 (https=) |
| JP (1) | JPWO2023181866A1 (https=) |
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| WO (1) | WO2023181866A1 (https=) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2025100478A1 (ja) * | 2023-11-08 | 2025-05-15 | Agc株式会社 | 組成物、表面処理剤、物品、及び物品の製造方法 |
| WO2025100477A1 (ja) * | 2023-11-08 | 2025-05-15 | Agc株式会社 | 組成物、表面処理剤、物品、及び物品の製造方法 |
| WO2025239180A1 (ja) * | 2024-05-17 | 2025-11-20 | 信越化学工業株式会社 | 表面処理剤及び物品 |
| WO2025253868A1 (ja) * | 2024-06-03 | 2025-12-11 | 信越化学工業株式会社 | 炭化水素末端基含有化合物、表面処理剤、硬化被膜及び物品 |
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Cited By (4)
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| WO2025100478A1 (ja) * | 2023-11-08 | 2025-05-15 | Agc株式会社 | 組成物、表面処理剤、物品、及び物品の製造方法 |
| WO2025100477A1 (ja) * | 2023-11-08 | 2025-05-15 | Agc株式会社 | 組成物、表面処理剤、物品、及び物品の製造方法 |
| WO2025239180A1 (ja) * | 2024-05-17 | 2025-11-20 | 信越化学工業株式会社 | 表面処理剤及び物品 |
| WO2025253868A1 (ja) * | 2024-06-03 | 2025-12-11 | 信越化学工業株式会社 | 炭化水素末端基含有化合物、表面処理剤、硬化被膜及び物品 |
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| US20250034428A1 (en) | 2025-01-30 |
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