WO2023173502A1 - Gant de protection résistant aux coupures et son procédé de fabrication - Google Patents
Gant de protection résistant aux coupures et son procédé de fabrication Download PDFInfo
- Publication number
- WO2023173502A1 WO2023173502A1 PCT/CN2022/084476 CN2022084476W WO2023173502A1 WO 2023173502 A1 WO2023173502 A1 WO 2023173502A1 CN 2022084476 W CN2022084476 W CN 2022084476W WO 2023173502 A1 WO2023173502 A1 WO 2023173502A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cut
- graphene composite
- glove
- resistant protective
- powder
- Prior art date
Links
- 230000001681 protective effect Effects 0.000 title claims abstract description 65
- 238000004519 manufacturing process Methods 0.000 title abstract 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 97
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 96
- 239000002131 composite material Substances 0.000 claims abstract description 81
- 239000000835 fiber Substances 0.000 claims abstract description 48
- 238000000034 method Methods 0.000 claims abstract description 33
- 239000000463 material Substances 0.000 claims abstract description 26
- 239000003365 glass fiber Substances 0.000 claims abstract description 21
- 239000002657 fibrous material Substances 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims description 66
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 26
- 229920000728 polyester Polymers 0.000 claims description 25
- 239000004677 Nylon Substances 0.000 claims description 24
- 229920001778 nylon Polymers 0.000 claims description 24
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 17
- 239000004917 carbon fiber Substances 0.000 claims description 17
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 17
- 238000002360 preparation method Methods 0.000 claims description 16
- 229920001971 elastomer Polymers 0.000 claims description 14
- 239000000377 silicon dioxide Substances 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 8
- 238000007598 dipping method Methods 0.000 claims description 8
- 238000009940 knitting Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 5
- 239000004816 latex Substances 0.000 claims description 5
- 229920000126 latex Polymers 0.000 claims description 5
- 150000002825 nitriles Chemical class 0.000 claims description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 5
- 150000001336 alkenes Chemical class 0.000 claims 1
- 229910002804 graphite Inorganic materials 0.000 claims 1
- 239000010439 graphite Substances 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 238000001035 drying Methods 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 5
- 239000004800 polyvinyl chloride Substances 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 2
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 208000011092 Hand injury Diseases 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
- A41D19/01505—Protective gloves resistant to mechanical aggressions, e.g. cutting. piercing
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/24—Resistant to mechanical stress, e.g. pierce-proof
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/16—Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/22—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration
- D04B1/24—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel
- D04B1/28—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel gloves
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0034—Polyamide fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0036—Polyester fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2500/00—Materials for garments
- A41D2500/20—Woven
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/10—Clothing
- D06N2211/103—Gloves
Definitions
- the present invention relates to a functional protective glove and a preparation method thereof. Specifically, it relates to a new low-cost cut-resistant protective glove and a preparation method thereof.
- Hands are the parts of the human body that are most exposed to objects during labor and work. Hand injuries account for 2% of all types of accidents, and anti-cut gloves can better protect hands from scratches and cuts. In recent years, the global use of anti-cut gloves has been increasing year by year, and they are used in more and more fields.
- gloves on the market that are cut-resistant and meet the American standard level 2 are made from materials such as high-strength and high-modulus polyethylene fiber, aramid fiber, glass fiber, carbon fiber, etc. These materials are expensive and the gloves made feel stiff. Among them, glass fiber is easy to break and produce powder, which may cause certain harm to the user's respiratory system and may cause allergies to some people. Therefore, there is an urgent need to develop a protective glove that has good cut resistance, soft feel, does not use glass fiber, and is especially low-cost and cost-effective, with cut resistance reaching Level 2 of the American Standard.
- the purpose of the present invention is to provide a functional protective glove and a preparation method thereof, which can solve the existing problems.
- the prepared protective gloves are cost-effective, soft and comfortable, and can be cut-resistant to the American standard level two.
- the present invention provides a method for preparing cut-resistant protective gloves, wherein the method includes: step 1, select cut-resistant low-cost fiber materials to make yarn; step 2, prepare graphene Composite fiber; step 3, use the graphene composite fiber obtained in step 2 to make graphene composite yarn; step 4, mix the yarn obtained in step 1 and the graphene composite yarn obtained in step 3 to knit a glove blank; Step 5: Dip the glove blank obtained in Step 4 into a glove dipping compound and then dry it to obtain a cut-resistant protective glove.
- the fiber material selected is high-strength polyester and/or high-strength nylon.
- the graphene composite fiber is graphene composite polyester and/or graphene composite nylon.
- the hard material includes silica powder or alumina powder, as well as glass fiber powder and carbon fiber powder.
- the above-mentioned preparation method of anti-cut protective gloves wherein the raw materials used for the graphene composite fiber include, in mass percentage: graphene powder 0.1-0.5%, silica powder or alumina powder 0.1-1%, glass Fiber powder and carbon fiber powder total 0.1-0.5%, and the remainder is polyester chips and/or nylon chips.
- step 4 two kinds of yarns are mixed, and the glove blank is woven using tight weave and U2 weave on a glove knitting machine; graphene composite yarn and another The mass ratio of the yarn is (1 ⁇ 4):1.
- the impregnating rubber material adopts any one or more of natural latex, nitrile latex, PU resin, and PVC resin.
- the present invention also provides cut-resistant protective gloves prepared by the above method, wherein the cut-resistance of the gloves reaches Level 2 of the American Standard.
- the cut resistance of the dipped gloves prepared by this method can reach the American standard level two, and the preparation method is simple, low cost, soft to the touch, comfortable and durable, and has a wide range of applications. It can provide laborers and other operators with a new type of hand with high cost performance. protective gloves and cost 30%-40% less than similar secondary cut-resistant gloves made from other cut-resistant fibers.
- the method for preparing cut-resistant protective gloves provided by the present invention can prepare protective gloves that are cost-effective, soft and comfortable, and have cut-resistant gloves that can reach Level 2 of the American Standard.
- the method includes: step 1, select cutting-resistant low-cost fiber materials to make yarn; step 2, prepare graphene composite fiber; step 3, use the graphene composite fiber obtained in step 2 to make graphene composite yarn ; Step 4, mix the yarn obtained in step 1 and the graphene composite yarn obtained in step 3, knit the glove blank, and prepare the knitted glove blank for dipping; step 5, combine the glove blank obtained in step 4, The gloves are dipped in rubber and then dried to obtain anti-cut protective gloves.
- the fiber material selected has certain cutting resistance and low cost, preferably high-strength polyester and/or high-strength nylon, to produce low-priced yarn with certain cutting resistance.
- the graphene composite fiber is graphene composite polyester and/or graphene composite nylon.
- step 2 graphene and other hard materials are first mixed and extruded to form a masterbatch, and then evenly mixed with polyester chips and/or nylon chips, and then melt-spun to obtain graphene composite fibers.
- Hard materials include silica powder or aluminum oxide powder, as well as glass fiber powder and carbon fiber powder.
- Graphene composite fiber uses raw materials including, by mass percentage: graphene powder 0.1-0.5%, silica powder or alumina powder 0.1-1%, glass fiber powder and carbon fiber powder mixed in any mass ratio, a total of 0.1-0.5%. 0.5%, the remainder is polyester chips and/or nylon chips.
- step 4 two kinds of yarns are mixed, and the glove blank is woven using the tight weave method and the U2 weave method on a glove knitting machine; the mass ratio of the graphene composite yarn and the other yarn is (1 ⁇ 4):1.
- step 5 the glove blank is placed on the hand film, impregnated with natural or chemical slurry, and then dried, sorted, and packaged to make anti-cut protective gloves.
- the impregnating rubber material uses any one or more of natural latex, nitrile latex, PU (polyurethane) resin, and PVC (polyvinyl chloride) resin.
- the present invention also provides cut-resistant protective gloves prepared by this method.
- the cut-resistance of the gloves reaches the second level of the American standard.
- the gloves are soft to the touch and low in cost.
- the cost is 30% lower than similar second-level cut-resistant gloves made of other cut-resistant fibers. %-40%.
- a method for preparing anti-cut protective gloves which includes:
- Step 1 Select cut-resistant, low-cost fiber materials to make yarn.
- the fiber material selected is high-strength polyester.
- Step 2 Prepare graphene composite fibers.
- the graphene composite fiber is preferably graphene composite polyester.
- graphene and other hard materials are mixed and extruded to form a masterbatch, then evenly mixed with polyester chips, and then melted and spun to obtain graphene composite fibers.
- Hard materials include silica powder, as well as glass fiber powder and carbon fiber powder.
- Graphene composite fiber uses raw materials including, in mass percentage: graphene powder 0.1%, silica powder 0.1%, glass fiber powder and carbon fiber powder totaling 0.1%, and the remainder is polyester slices.
- Step 3 Use the graphene composite fiber obtained in Step 2 to make graphene composite yarn.
- Step 4 Mix the yarn obtained in Step 1 and the graphene composite yarn obtained in Step 3 to knit a glove blank.
- Step 5 Dip the glove blank obtained in Step 4 into a glove dipping compound and then dry it to obtain a cut-resistant protective glove.
- the glove blank is placed on the hand film, dipped in impregnated rubber, and then dried, sorted, and packaged to make anti-cut protective gloves.
- the impregnating rubber material is natural latex.
- This embodiment also provides cut-resistant protective gloves prepared by this method.
- a method for preparing anti-cut protective gloves which includes:
- Step 1 Select cut-resistant, low-cost fiber materials to make yarn.
- the fiber material selected is high-strength nylon.
- Step 2 Prepare graphene composite fibers.
- the graphene composite fiber is preferably graphene composite nylon.
- graphene and other hard materials are mixed and extruded to form a masterbatch, then evenly mixed with nylon slices, and then melted and spun to obtain graphene composite fibers.
- Hard materials include aluminum oxide powder, as well as glass fiber powder and carbon fiber powder.
- Graphene composite fiber uses raw materials including, in mass percentage: graphene powder 0.2%, silica powder or alumina powder 0.4%, glass fiber powder and carbon fiber powder 0.2% in total, and the remainder is nylon slices.
- Step 3 Use the graphene composite fiber obtained in Step 2 to make graphene composite yarn.
- Step 4 Mix the yarn obtained in Step 1 and the graphene composite yarn obtained in Step 3 to knit a glove blank.
- Step 5 Dip the glove blank obtained in Step 4 into a glove dipping compound and then dry it to obtain a cut-resistant protective glove.
- the glove blank is placed on the hand film, dipped in impregnated rubber, and then dried, sorted, and packaged to make anti-cut protective gloves.
- the impregnating rubber material is nitrile latex.
- This embodiment also provides cut-resistant protective gloves prepared by this method.
- a method for preparing anti-cut protective gloves which includes:
- Step 1 Select cut-resistant, low-cost fiber materials to make yarn.
- the fiber material selected is high-strength polyester.
- Step 2 Prepare graphene composite fibers.
- the graphene composite fiber is preferably graphene composite polyester.
- graphene and other hard materials are mixed and extruded to form a masterbatch, then evenly mixed with polyester chips, and then melted and spun to obtain graphene composite fibers.
- Hard materials include aluminum oxide powder, as well as glass fiber powder and carbon fiber powder.
- Graphene composite fiber uses raw materials including, in mass percentage: graphene powder 0.3%, alumina powder 0.5%, glass fiber powder and carbon fiber powder 0.3% in total, and the remainder is polyester slices.
- Step 3 Use the graphene composite fiber obtained in Step 2 to make graphene composite yarn.
- Step 4 Mix the yarn obtained in Step 1 and the graphene composite yarn obtained in Step 3 to knit a glove blank.
- Step 5 Dip the glove blank obtained in Step 4 into a glove dipping compound and then dry it to obtain a cut-resistant protective glove.
- the glove blank is placed on the hand film, dipped in impregnated rubber, and then dried, sorted, and packaged to make anti-cut protective gloves.
- the impregnating compound uses PU resin.
- This embodiment also provides cut-resistant protective gloves prepared by this method.
- a method for preparing anti-cut protective gloves which includes:
- Step 1 Select cut-resistant, low-cost fiber materials to make yarn.
- the fiber material selected is high-strength nylon.
- Step 2 Prepare graphene composite fibers.
- the graphene composite fiber is preferably graphene composite nylon.
- graphene and other hard materials are mixed and extruded to form a masterbatch, then evenly mixed with nylon slices, and then melted and spun to obtain graphene composite fibers.
- Hard materials include silica powder, as well as glass fiber powder and carbon fiber powder.
- Graphene composite fiber uses raw materials including, in mass percentage: graphene powder 0.4%, silica powder 0.8%, glass fiber powder and carbon fiber powder 0.4% in total, and the remainder is nylon slices.
- Step 3 Use the graphene composite fiber obtained in Step 2 to make graphene composite yarn.
- Step 4 Mix the yarn obtained in Step 1 and the graphene composite yarn obtained in Step 3 to knit a glove blank.
- Step 5 Dip the glove blank obtained in Step 4 into a glove dipping compound and then dry it to obtain a cut-resistant protective glove.
- the glove blank is placed on the hand film, dipped in impregnated rubber, and then dried, sorted, and packaged to make anti-cut protective gloves.
- the impregnating compound uses PVC resin.
- This embodiment also provides cut-resistant protective gloves prepared by this method.
- a method for preparing anti-cut protective gloves which includes:
- Step 1 Select cut-resistant, low-cost fiber materials to make yarn.
- the fiber materials selected are high-strength polyester and high-strength nylon.
- Step 2 Prepare graphene composite fibers.
- the graphene composite fiber is preferably graphene composite polyester and graphene composite nylon.
- graphene and other hard materials are mixed and extruded to form a masterbatch, then evenly mixed with polyester chips and nylon chips, and then melted and spun to obtain graphene composite fibers.
- Hard materials include silica powder or aluminum oxide powder, as well as glass fiber powder and carbon fiber powder.
- Graphene composite fiber uses raw materials including, by mass percentage: 0.5% graphene powder, 1% silica powder or alumina powder, 0.5% glass fiber powder and carbon fiber powder in total, and the remainder is polyester slices and nylon slices.
- Step 3 Use the graphene composite fiber obtained in Step 2 to make graphene composite yarn.
- Step 4 Mix the yarn obtained in Step 1 and the graphene composite yarn obtained in Step 3 to knit a glove blank.
- Step 5 Dip the glove blank obtained in Step 4 into a glove dipping compound and then dry it to obtain a cut-resistant protective glove.
- the glove blank is placed on the hand film, dipped in impregnated rubber, and then dried, sorted, and packaged to make anti-cut protective gloves.
- the impregnating rubber material can be any of natural latex, nitrile latex, PU resin, and PVC resin.
- This embodiment also provides cut-resistant protective gloves prepared by this method.
- the cut-resistant protective gloves prepared in various embodiments of the present invention were tested, and the results showed that the cut-resistance of the gloves reached Level 2 of the American Standard.
- the invention provides anti-cut protective gloves and its preparation method by selecting other fibers with low cost and good anti-cut function, and then preparing graphene composite polyester fibers with certain anti-cut and anti-bacterial functions, and then combining the two fibers.
- the yarns are made separately.
- the glove blanks are produced using compact and U2 weaving methods, and are finally impregnated with slurry.
- the result is a protective glove with good cut resistance, soft and comfortable feel, no glass fiber, low cost, high cost performance, and cut resistance reaching Level 2 of the American Standard.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Dispersion Chemistry (AREA)
- Gloves (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
Abstract
La présente invention concerne un gant de protection résistant aux coupures et son procédé de fabrication. Le procédé de fabrication comprend : étape 1, la sélection d'un matériau fibreux résistant aux coupures et à faible coût pour préparer des fils ; étape 2, la préparation d'une fibre composite de graphène ; étape 3, l'utilisation de la fibre composite de graphène obtenue à l'étape 2 pour préparer des fils composites de graphène ; étape 4, le mélange des fils obtenus à l'étape 1 avec les fils composites de graphène obtenus à l'étape 3 pour tisser une ébauche de gant ; et étape 5, l'imprégnation de l'ébauche de gant obtenue à l'étape 4 dans un matériau d'imprégnation de gant, puis le séchage pour obtenir le gant de protection résistant aux coupures. La présente invention concerne en outre un gant de protection résistant aux coupures fabriqué par le procédé. Selon le gant de protection résistant aux coupures et son procédé de fabrication fourni par la présente invention, le gant fabriqué présente une bonne résistance aux coupures, peut atteindre la qualité standard américaine 2, a une sensation de main douce, n'utilise pas de fibre de verre, et présente en particulier les avantages d'un faible coût et d'une performance de coût élevé.
Applications Claiming Priority (2)
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CN202210264905.4 | 2022-03-17 | ||
CN202210264905.4A CN116784547A (zh) | 2022-03-17 | 2022-03-17 | 一种抗切割防护手套及其制备方法 |
Publications (1)
Publication Number | Publication Date |
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WO2023173502A1 true WO2023173502A1 (fr) | 2023-09-21 |
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PCT/CN2022/084476 WO2023173502A1 (fr) | 2022-03-17 | 2022-03-31 | Gant de protection résistant aux coupures et son procédé de fabrication |
PCT/CN2022/133737 WO2023173800A1 (fr) | 2022-03-17 | 2022-11-23 | Gants de protection résistant aux coupures et leur procédé de préparation |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/CN2022/133737 WO2023173800A1 (fr) | 2022-03-17 | 2022-11-23 | Gants de protection résistant aux coupures et leur procédé de préparation |
Country Status (2)
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CN (1) | CN116784547A (fr) |
WO (2) | WO2023173502A1 (fr) |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1647197A2 (fr) * | 2004-09-23 | 2006-04-19 | Api Seplast | Procédé de réalisation d'un gant de protection |
CN107354566A (zh) * | 2017-06-21 | 2017-11-17 | 江苏工程职业技术学院 | 一种环境友好型石墨烯抗静电抗菌防割手套的制备方法 |
CN109778408A (zh) * | 2017-11-10 | 2019-05-21 | 江苏云蝠服饰股份有限公司 | 一种阻燃混纺针织面料 |
CN111850786A (zh) * | 2020-07-01 | 2020-10-30 | 安徽省吉祥纺织工程先进技术研究院 | 一种防割手套材料、防割手套及其制造方法 |
CN112779623A (zh) * | 2020-09-17 | 2021-05-11 | 安丹达工业技术(上海)有限公司 | 用于耐切割纤维的组合物和耐切割纤维及应用和制法 |
CN113737511A (zh) * | 2021-08-24 | 2021-12-03 | 南通强生石墨烯科技有限公司 | 一种石墨烯高抗切割特种纤维及其制备方法 |
CN113969499A (zh) * | 2021-10-25 | 2022-01-25 | 南通强生新材料科技股份有限公司 | 一种抗切割手套及其制备方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106690592A (zh) * | 2016-11-17 | 2017-05-24 | 无锡市长安曙光手套厂 | 一种耐磨防切割手套 |
CN107956030B (zh) * | 2017-12-14 | 2020-05-22 | 江苏工程职业技术学院 | 一种石墨烯夜光防割阻燃消防手套的制备方法 |
CN108374217A (zh) * | 2018-01-15 | 2018-08-07 | 南通强生安全防护科技股份有限公司 | 石墨烯-超高分子量聚乙烯纤维包覆纱线的制备方法及用途 |
CN108149358A (zh) * | 2018-01-15 | 2018-06-12 | 南通强生安全防护科技股份有限公司 | 石墨烯-超高分子量聚乙烯纤维包覆纱线的制备方法及用途 |
CN109629028A (zh) * | 2018-11-15 | 2019-04-16 | 南通强生安全防护科技股份有限公司 | 一种石墨烯超高分子量聚乙烯复合纤维及其制备方法 |
CN110512326A (zh) * | 2019-08-20 | 2019-11-29 | 南通嘉得利安全用品有限公司 | 一种包芯纱线及其制造方法及防割制品 |
CN113498899A (zh) * | 2021-05-25 | 2021-10-15 | 鸿瀚防护科技南通有限公司 | 一种导电手套及其制备工艺 |
-
2022
- 2022-03-17 CN CN202210264905.4A patent/CN116784547A/zh active Pending
- 2022-03-31 WO PCT/CN2022/084476 patent/WO2023173502A1/fr unknown
- 2022-11-23 WO PCT/CN2022/133737 patent/WO2023173800A1/fr unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1647197A2 (fr) * | 2004-09-23 | 2006-04-19 | Api Seplast | Procédé de réalisation d'un gant de protection |
CN107354566A (zh) * | 2017-06-21 | 2017-11-17 | 江苏工程职业技术学院 | 一种环境友好型石墨烯抗静电抗菌防割手套的制备方法 |
CN109778408A (zh) * | 2017-11-10 | 2019-05-21 | 江苏云蝠服饰股份有限公司 | 一种阻燃混纺针织面料 |
CN111850786A (zh) * | 2020-07-01 | 2020-10-30 | 安徽省吉祥纺织工程先进技术研究院 | 一种防割手套材料、防割手套及其制造方法 |
CN112779623A (zh) * | 2020-09-17 | 2021-05-11 | 安丹达工业技术(上海)有限公司 | 用于耐切割纤维的组合物和耐切割纤维及应用和制法 |
CN113737511A (zh) * | 2021-08-24 | 2021-12-03 | 南通强生石墨烯科技有限公司 | 一种石墨烯高抗切割特种纤维及其制备方法 |
CN113969499A (zh) * | 2021-10-25 | 2022-01-25 | 南通强生新材料科技股份有限公司 | 一种抗切割手套及其制备方法 |
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CN116784547A (zh) | 2023-09-22 |
WO2023173800A1 (fr) | 2023-09-21 |
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