WO2023171991A1 - 원통형 배터리 셀, 그리고 이를 포함하는 배터리 팩 및 자동차 - Google Patents
원통형 배터리 셀, 그리고 이를 포함하는 배터리 팩 및 자동차 Download PDFInfo
- Publication number
- WO2023171991A1 WO2023171991A1 PCT/KR2023/002982 KR2023002982W WO2023171991A1 WO 2023171991 A1 WO2023171991 A1 WO 2023171991A1 KR 2023002982 W KR2023002982 W KR 2023002982W WO 2023171991 A1 WO2023171991 A1 WO 2023171991A1
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- Prior art keywords
- terminal
- battery
- current collector
- cell
- cylindrical battery
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/564—Terminals characterised by their manufacturing process
- H01M50/567—Terminals characterised by their manufacturing process by fixing means, e.g. screws, rivets or bolts
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/107—Primary casings; Jackets or wrappings characterised by their shape or physical structure having curved cross-section, e.g. round or elliptic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
- H01M50/148—Lids or covers characterised by their shape
- H01M50/152—Lids or covers characterised by their shape for cells having curved cross-section, e.g. round or elliptic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/172—Arrangements of electric connectors penetrating the casing
- H01M50/174—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells
- H01M50/179—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for cells having curved cross-section, e.g. round or elliptic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/533—Electrode connections inside a battery casing characterised by the shape of the leads or tabs
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/538—Connection of several leads or tabs of wound or folded electrode stacks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/547—Terminals characterised by the disposition of the terminals on the cells
- H01M50/548—Terminals characterised by the disposition of the terminals on the cells on opposite sides of the cell
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/552—Terminals characterised by their shape
- H01M50/559—Terminals adapted for cells having curved cross-section, e.g. round, elliptic or button cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/562—Terminals characterised by the material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
- B60L50/00—Electric propulsion with power supplied within the vehicle
- B60L50/50—Electric propulsion with power supplied within the vehicle using propulsion power supplied by batteries or fuel cells
- B60L50/60—Electric propulsion with power supplied within the vehicle using propulsion power supplied by batteries or fuel cells using power supplied by batteries
- B60L50/64—Constructional details of batteries specially adapted for electric vehicles
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/528—Fixed electrical connections, i.e. not intended for disconnection
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present invention relates to cylindrical battery cells, and battery packs and automobiles including the same. More specifically, the present invention relates to a cylindrical battery cell having a structure in which both the positive and negative terminals are arranged adjacent to one side of the cylindrical battery cell without significantly modifying the structure of the conventional cylindrical battery cell, and a cylindrical battery cell including the same. It concerns battery packs and cars.
- Secondary batteries which are easy to apply depending on the product group and have electrical characteristics such as high energy density, are used not only in portable devices but also in electric vehicles (EV, Electric Vehicle) and hybrid vehicles (HEV, Hybrid Electric Vehicle) that are driven by an electrical drive source. It is universally applied.
- EV Electric Vehicle
- HEV Hybrid Electric Vehicle
- These secondary batteries not only have the primary advantage of being able to dramatically reduce the use of fossil fuels, but also have the advantage of not generating any by-products due to energy use, so they are attracting attention as a new energy source for eco-friendliness and improving energy efficiency.
- Types of secondary batteries currently widely used include lithium ion batteries, lithium polymer batteries, nickel cadmium batteries, nickel hydrogen batteries, and nickel zinc batteries.
- the operating voltage of these unit secondary battery cells is approximately 2.5V to 4.5V. Therefore, when a higher output voltage is required, a battery pack is formed by connecting a plurality of battery cells in series. Additionally, a battery pack may be constructed by connecting multiple battery cells in parallel depending on the charge/discharge capacity required for the battery pack. Accordingly, the number of battery cells included in the battery pack and the type of electrical connection can be set in various ways depending on the required output voltage and/or charge/discharge capacity.
- cylindrical, prismatic, and pouch-type battery cells are known as types of secondary battery cells.
- an insulating separator is interposed between the anode and the cathode and wound to form a jelly roll-shaped electrode assembly, which is then inserted into a battery can along with the electrolyte to form a battery.
- a strip-shaped electrode tab may be connected to the uncoated portion of each of the positive and negative electrodes, and the electrode tab electrically connects the electrode assembly and the electrode terminal exposed to the outside.
- the positive electrode terminal is a cap plate of a sealing body that seals the opening of the battery can
- the negative electrode terminal is a battery can.
- the current is concentrated on the strip-shaped electrode tab connected to the positive electrode uncoated area and/or the negative electrode uncoated area, so the resistance is large, a lot of heat is generated, and the current collection efficiency is poor. There was a problem that it wasn't.
- a battery pack mounted on an electric vehicle includes a plurality of cylindrical battery cells. Therefore, inefficiency in electrical wiring causes considerable inconvenience during the assembly process of electric vehicles and during battery pack maintenance.
- cylindrical battery cells are recently applied to electric vehicles, the form factor of cylindrical battery cells is increasing. That is, the diameter and height of cylindrical battery cells are increasing compared to conventional cylindrical battery cells with form factors such as 18650 and 21700. Increasing form factor results in increased energy density, increased safety against thermal runaway, and improved cooling efficiency.
- the energy density of cylindrical battery cells can be further increased when the form factor increases and unnecessary space inside the battery can is minimized. Therefore, the parts used for electrical insulation between the electrode assembly and the battery can and the parts used to collect current from the positive and negative plates must be optimally designed to increase the capacity of the battery cell and lower the overall resistance of the battery cell. There is a need.
- the present invention was created in consideration of the above-described problems, and its purpose is to provide a cylindrical battery cell having a structure in which the positive and negative terminals are applied in the same direction.
- the present invention allows the wide surface of the closed portion of the battery can to be used as an electrode terminal in the case of electrically connecting a plurality of cylindrical battery cells in one direction, thereby providing electrical connection components such as bus bars for battery pack manufacturing.
- One purpose is to secure a sufficient area where the electrode terminals of the cylindrical battery cell can be welded.
- the purpose of the present invention is to improve the process for coupling between a current collector plate (first current collector plate) and a cell terminal and to reduce resistance at the coupling site.
- the present invention is optimally designed so that the area occupied by the upper surface of the cell terminal (first electrode terminal) and the area occupied by the outer surface of the closure (second electrode terminal) are sufficient for coupling to the bus bar. for the purpose of work.
- the present invention provides a contact area between the electrode assembly and the current collector plate (first current collector plate) and/or a contact area between the cell terminal and the current collector plate (first current collector plate) through improvement of the non-coated structure of the electrode assembly.
- the purpose is to minimize the resistance of the cylindrical battery cell by expanding .
- the present invention improves the electrical connection structure between the current collector (second collector plate) and the battery can to multiplex the current path and maximize the contact area to minimize the resistance of the cylindrical battery cell. for the purpose of work.
- the purpose of the present invention is to reduce the current path by improving the electrical connection structure between the current collector (second collector plate) and the battery can, thereby minimizing the resistance of the cylindrical battery cell.
- the present invention minimizes dead space through improving the non-ground structure of the electrode assembly and/or optimal design of the cell terminal height and/or optimal design of the thickness of the battery can, thereby maximizing energy density. for the purpose of work.
- the terminal fastening member may be press-fitted into the first current collector plate and the cell terminal to fasten the cell terminal and the first current collector plate.
- the terminal fastening member includes a base portion; and a fastening portion that extends from the base portion toward the first current collector plate and is pressed into the first current collector plate and the cell terminal from the surface of the first current collector plate. may include.
- the cell terminal and the first current collector plate may include aluminum.
- the terminal fastening member may include boron steel containing 0.001 wt% to 0.008 wt% of boron.
- At least a portion of the first current collector on the outside and inside the fastening part may be pushed into the cell terminal as the fastening part is press-fitted.
- the maximum diameter or maximum width of the terminal fastening member may be smaller than the diameter of the winding center hole of the electrode assembly.
- the cylindrical battery cell may further include a cap plate that seals the opening portion of the battery can.
- the cap plate is not electrically connected to the electrode assembly, and thus may not have polarity.
- the cylindrical battery cell may further include a second current collector electrically connecting the second electrode tab and the battery can.
- the second current collector plate includes a tab coupling portion coupled to the second electrode tab; and a can coupling portion electrically coupled to the battery can. may include.
- the can coupling portion may be electrically coupled to the inner surface of the sidewall of the battery can.
- the battery can may have a beading portion formed by press-fitting a circumference of an outer peripheral surface of the battery can on the opening side, and the can coupling portion may be electrically coupled to a lower surface of the beading portion.
- a battery pack according to an embodiment of the present invention includes a plurality of the cylindrical battery cells.
- a vehicle according to an embodiment of the present invention includes the battery pack.
- the process can be improved in the coupling between the current collector plate (first current collector plate) and the cell terminal, and the resistance at the coupling site can be reduced.
- the internal resistance of the cylindrical battery cell can be lowered and the energy density can be increased by improving the electrode terminal structure of the cylindrical battery cell to increase space efficiency within the battery can.
- the internal heat generation problem that occurs during rapid charging can be improved by improving the electrode terminal structure of the cylindrical battery cell and expanding the cross-sectional area of the current path.
- electrical wiring work for connecting cylindrical battery cells in series and/or parallel can be performed on one side of the cylindrical battery cell.
- the large surface of the closed portion of the battery can be used as an electrode terminal, and this allows the use of a bus for manufacturing a battery pack. Sufficient area can be secured where electrical connection components such as bars and electrode terminals of cylindrical battery cells can be welded.
- the area occupied by the upper surface of the cell terminal (first electrode terminal) and the area occupied by the outer surface of the closure (second electrode terminal) are optimally designed so that the area is sufficient for coupling to the bus bar. can do.
- the contact area between the electrode assembly and the current collector (first current collector) and/or the contact area between the cell terminal and the current collector (first current collector) are improved by improving the non-coated structure of the electrode assembly. can be expanded, thereby minimizing the resistance of the cylindrical battery cell.
- current path multiplexing is possible through improvement of the electrical connection structure between the current collector (second collector plate) and the battery can, and the contact area between these components is maximized to form a cylindrical battery cell. Resistance can be minimized.
- the current path can be reduced by improving the electrical connection structure between the current collector (second collector plate) and the battery can, thereby minimizing the resistance of the cylindrical battery cell.
- dead space can be minimized by improving the non-free structure of the electrode assembly and/or optimally designing the height of the cell terminal and/or optimally designing the thickness of the battery can, thereby increasing the energy density. can be maximized.
- a battery pack manufactured using a cylindrical battery cell with an improved structure and a vehicle including the same can be provided.
- FIG. 1 is a perspective view showing the appearance of a cylindrical battery cell according to an embodiment of the present invention.
- Figure 2 is a perspective view of an electrode assembly with an uncoated portion bent according to an embodiment of the present invention.
- Figure 3 is a cross-sectional view showing the internal structure of a cylindrical battery cell according to an embodiment of the present invention.
- Figure 4 is a partial cross-sectional view showing the upper structure of a cylindrical battery cell according to an embodiment of the present invention and a partially enlarged view showing an area to which a fastening member is applied.
- Figure 5 is a cross-sectional view of a cylindrical battery cell according to an embodiment of the present invention, and is a diagram for explaining a process of coupling a first current collector and a cell terminal using a fastening member.
- Figure 6 is a conceptual diagram for step-by-step explaining the process of coupling the first current collector and the cell terminal using a fastening member.
- Figure 7 is a diagram showing a first current collector according to an embodiment of the present invention.
- Figure 8 is a partial cross-sectional view showing the lower structure of a cylindrical battery cell according to an embodiment of the present invention.
- Figure 9 is a plan view showing the lower surface of a cylindrical battery cell according to an embodiment of the present invention.
- Figure 10 is a top plan view showing a plurality of cylindrical battery cells connected in series and parallel using a bus bar according to an embodiment of the present invention.
- Figure 11 is a diagram showing the schematic configuration of a battery pack including cylindrical battery cells according to an embodiment of the present invention.
- Figure 12 is a diagram showing the schematic configuration of a vehicle including a battery pack according to an embodiment of the present invention.
- substantially identical may include a deviation that is considered low in the art, for example, a deviation of less than 5%. Additionally, uniformity of a parameter in a predetermined area may mean uniformity from an average perspective.
- the cylindrical battery cell 1 according to an embodiment of the present invention includes an electrode assembly 10, a battery can 20, a cell terminal 40, and a first current collector 50. and a terminal fastening member 60.
- the cylindrical battery cell 1 additionally includes a cap plate 30 and/or an insulator 70 and/or an insulating gasket (G1) and/or a sealing gasket (G2) and/or a second It may further include a current collector 80.
- the electrode assembly 10 includes a first electrode tab 11 having a first polarity and a second electrode tab 12 having a second polarity.
- the first electrode tab 11 and the second electrode tab 12 may have a shape extending in opposite directions along the height direction of the electrode assembly 10 (a direction parallel to the Z-axis).
- the first electrode tab 11 may extend upward and the second electrode tab 12 may extend downward. That is, the first electrode tab 11 may extend toward a closed portion located on the opposite side of the opening formed at the bottom of the battery can 20, and the second electrode tab 12 may extend toward the open portion of the battery can 20. It can extend towards wealth.
- the electrode assembly 10 includes a first electrode having a first polarity, a second electrode having a second polarity, and a separator interposed between the first electrode and the second electrode.
- the first electrode is an anode or a cathode
- the second electrode corresponds to an electrode having a polarity opposite to that of the first electrode.
- the electrode assembly 10 may have, for example, a jelly-roll structure. That is, the electrode assembly 10 is manufactured by winding a laminate formed by stacking a first electrode and a second electrode having a substantially sheet shape at least once with a separator interposed between them, based on the core portion. You can. A winding center hole C may be formed in the core portion of the electrode assembly 10 wound in this way. An additional separator may be provided on the outer peripheral surface of the electrode assembly 10 to insulate it from the battery can 20. Any jelly roll structure known in the art can be applied to the present invention without limitation.
- the first electrode includes a first electrode current collector and a first electrode active material applied on one or both sides of the first electrode current collector.
- a first uncoated portion in which the first electrode active material is not applied exists at one end of the first electrode current collector in the width direction (direction parallel to the Z axis).
- the first uncoated portion functioning as an electrode tab will hereinafter be referred to as the first electrode tab 11.
- the first electrode tab 11 is provided on the top of the electrode assembly 10 accommodated in the battery can 20 in the height direction (direction parallel to the Z axis).
- the first electrode current collector is formed at one end in the width direction (direction parallel to the Z-axis) and has a first uncoated region extending along the longitudinal direction (direction parallel to the X-axis), that is, the active material.
- the layer has an uncoated portion, and this first uncoated portion is exposed to the outside of the separator.
- the first uncoated portion itself is used as an electrode tab.
- the first electrode tab 11 may be, for example, a positive electrode tab.
- the first electrode tab 11 is divided into a plurality of parts divided along the winding direction of the electrode assembly 10. It may include a segmental piece (11a).
- the plurality of segment pieces 11a may be bent along the radial direction of the electrode assembly 10.
- the plurality of banded segment pieces 11a may be overlapped in multiple layers.
- the first tab coupling portion 52 of the first current collector 50 which will be described later, may be coupled to an area where a plurality of segment pieces 11a overlap in multiple layers.
- the electrode assembly 10 is an area where the number of overlapping layers of the segment pieces 11a of the first electrode tab 11 is maintained at approximately the maximum value along the radial direction of the electrode assembly 10. can be provided. In this area, the number of overlapping layers is maintained to a maximum, so it may be advantageous for welding of the first current collector plate 50 and the first electrode tab 11, which will be described later, to be performed within this area. This is to prevent the laser beam from penetrating the first electrode tab 11 and damaging the electrode assembly 10 when, for example, laser welding is applied and the output of the laser is increased to improve welding quality. It is for this purpose. Additionally, this is to effectively prevent foreign substances such as welding spatter from entering the interior of the electrode assembly 10.
- the second electrode includes a second electrode current collector and a second electrode active material applied on one or both sides of the second electrode current collector. At the other end of the second electrode current collector in the width direction (direction parallel to the Z axis), there is a second uncoated portion where the second electrode active material is not applied.
- the second uncoated portion functioning as an electrode tab will hereinafter be referred to as the second electrode tab 12.
- the second electrode tab 12 is provided below the electrode assembly 10 accommodated in the battery can 20 in the height direction (direction parallel to the Z axis).
- the second electrode current collector is formed at the other end in the width direction (direction parallel to the Z-axis) and has a second uncoated region extending along the longitudinal direction (direction parallel to the X-axis), that is, the active material.
- the layer has an uncoated portion, and this second uncoated portion is exposed to the outside of the separator.
- the second electrode tab 12 may be, for example, a negative electrode tab.
- the second electrode tab 12 may include a plurality of segmented pieces divided along the winding direction of the electrode assembly 10. .
- the plurality of segment pieces may be bent along the radial direction of the electrode assembly 10.
- the plurality of banded segments may be overlapped in multiple layers.
- the second tab coupling portion 82 of the second current collector plate 80 which will be described later, may be coupled to an area where a plurality of segment pieces overlap in multiple layers.
- the electrode assembly 10 may be provided with a uniform stacking number region, which is an area where the number of overlapping layers of the segmented pieces of the second electrode tab 12 is maintained at approximately the maximum value along the radial direction of the electrode assembly 10. there is. In this area, the number of overlapping layers is maintained to a maximum, so it may be advantageous for welding of the second current collector plate 80 and the second electrode tab 12, which will be described later, to be performed within this area. This is to prevent the laser beam from penetrating the second electrode tab 12 and damaging the electrode assembly 10 when, for example, laser welding is applied and the output of the laser is increased to improve welding quality. It is for this purpose. Additionally, this is to effectively prevent foreign substances such as welding spatter from entering the interior of the electrode assembly 10.
- the battery can 20 is a substantially cylindrical container with an opening formed at the bottom and an empty space inside, and is made of a conductive material such as metal, for example. It comes true.
- the material of the battery can 20 may be, for example, steel, stainless steel, or nickel-plated iron. In this way, when an iron-based material with excellent rigidity is used, it can be very advantageous in terms of the rigidity of the battery can 20.
- the battery can ( 20) It is necessary to ensure sufficient rigidity.
- the material of the battery can 20 is not limited by this, and any metal material with conductivity can be used.
- the battery can 20 accommodates the electrode assembly 10 through an opening formed at the bottom, and also accommodates the electrolyte.
- the battery can 20 is electrically connected to the electrode assembly 10.
- the battery can 20 may be electrically coupled to the second electrode tab 12 of the electrode assembly 10.
- the battery can 20 has the same second polarity as the second electrode tab 12.
- the battery can 20 may have a beading portion 21 formed near its lower end.
- the beading portion 21 is formed by press fitting around the outer peripheral surface of the battery can 20 from the opening side of the battery can 20. Accordingly, in the area where the beading portion 21 is formed, the battery can 20 has a shape that is indented inward to a predetermined depth.
- the beading portion 21 prevents the electrode assembly 10, which may have a size approximately corresponding to the inner diameter of the battery can 20, from coming out through the opening formed at the bottom of the battery can 20, and the cap plate ( 30) can function as a support on which it is seated. Referring to FIG.
- the upper surface of the beading portion 21 may function as a support surface on which the electrode assembly 10 can be seated. Additionally, on the inner surface of the battery can 20, the lower surface of the beading portion 21 may function as a support surface on which the cap plate 30 can be seated. Meanwhile, on the inner surface of the battery can 20, the lower surface of the beading portion 21 may function as a support surface on which the can coupling portion 83 of the second current collector 80, which will be described later, can be seated. there is.
- the battery can 20 may be provided with a crimping portion 22 formed at the lower portion of the beading portion 21.
- the crimping part 22 has a shape extending downward from the beading part 21.
- the crimping portion 22 has an extended and bent shape to surround the outer peripheral surface of the cap plate 30 disposed below the beading portion 21 and a portion of the lower surface of the cap plate 30.
- the crimping part 22 can fix the sealing gasket G2 in addition to the cap plate 30.
- the cap plate 30 may be made of, for example, a metal material to ensure rigidity.
- the cap plate 30 seals the opening formed at the bottom of the battery can 20.
- the lower surface of the cap plate 30 forms the lower surface of the cylindrical battery cell (1).
- the cap plate 30 may not have polarity even if it is made of a conductive metal material. Not having polarity means that the cap plate 30 is not electrically connected to the electrode assembly 10. In this case, when the cap plate 30 is not electrically connected to the electrode assembly 10, the cap plate 30 does not function as a positive or negative terminal. That is, in the present invention, the cap plate 30 does not need to be electrically connected to the electrode assembly 10 and the battery can 20, and its material does not necessarily have to be a conductive metal.
- the cap plate 30 When the battery can 20 of the present invention is provided with a beading portion 21, the cap plate 30 may be supported by the lower surface of the beading portion 21 formed on the battery can 20. Additionally, when the battery can 20 of the present invention is provided with a crimping portion 22, the cap plate 30 is fixed by the crimping portion 22. That is, the upper surface of the cap plate 30 may be supported by the beading portion 21, and the outer peripheral surface and lower surface may be supported by the beading portion 21. An airtight gasket G2 may be interposed between the cap plate 30 and the crimping portion 22 of the battery can 20 to ensure airtightness of the battery can 20.
- the battery can 20 of the present invention may not be provided with the beading portion 21 and/or the crimping portion 22, in which case the sealing gasket 90 is attached to the battery can 20. It may be interposed between the cap plate 30 and a fixing structure provided on the open side of the battery can 20 to ensure airtightness.
- the cap plate 30 has a venting portion 31 formed to prevent the internal pressure from increasing beyond a preset value due to gas generated inside the battery can 20. More can be provided.
- the venting portion 31 corresponds to an area of the cap plate 30 that has a thinner thickness compared to the surrounding area.
- the venting portion 31 is structurally weak compared to the surrounding area. Therefore, when an abnormality occurs in the cylindrical battery cell 1 and the internal pressure of the battery can 20 increases above a certain level, the venting portion 31 is ruptured and the gas generated inside the battery can 20 is released. is discharged.
- the venting portion 31 may be formed, for example, by notching on one side or both sides of the cap plate 30 to partially reduce the thickness of the battery can 20. .
- the cylindrical battery cell 1 has a structure in which both a positive terminal and a negative terminal are present at the top, as will be described later, and because of this, the upper structure is more complicated than the lower structure. Therefore, in order to smoothly discharge the gas generated inside the battery can 20, a venting portion 31 is provided on the cap plate 30 that seals the opening of the battery can 20 at the bottom of the cylindrical battery cell 1. can be formed. As shown in FIG. 7, the lower end of the cap plate 30 is preferably positioned higher than the lower end of the battery can 20. In this case, even if the lower end of the battery can 20 touches the ground or the bottom of the housing for module or pack configuration, the cap plate 30 does not touch the ground or the bottom of the housing for module or pack configuration. It becomes out of reach. Therefore, it is possible to prevent the pressure required for fracture of the venting portion 31 from being different from the designed value due to the weight of the cylindrical battery cell 1, and thus the smoothness of fracture of the venting portion 31 can be secured. there is.
- the venting portion 31 may have a shape that extends continuously or discontinuously to surround the central area of the cap plate 30, as shown in FIGS. 8 and 9 .
- the larger the distance from the center of the cap plate 30 to the venting portion 31 is more advantageous. This is because, when the same internal pressure is applied, as the distance from the center point of the cap plate 30 to the venting portion 31 increases, the force acting on the venting portion 31 increases, making fracture easier.
- the venting portion 31 is an edge of the central region that protrudes downward (direction pointing downward with respect to FIG. 8) among the entire area of the cap plate 30 and has a substantially flat shape. It may be advantageous to be formed along the perimeter.
- venting portion 31 is formed continuously in a substantially circular shape on the cap plate 30, but the present invention is not limited thereto.
- the venting portion 31 may have an approximately elliptical shape formed to include the center point of the cap plate 30 on the inside, or may have another geometric shape. Additionally, the venting portion 31 may be formed discontinuously rather than continuously.
- the cell terminal 40 is electrically connected to the first electrode tab 11. Electrical connection between the first electrode tab 11 and the cell terminal 40 is made through the first current collector 50.
- the cell terminal 40 may be exposed to the outside of the battery can 20 through the closing part of the battery can 20.
- the cell terminal 40 is made of a conductive metal material.
- the cell terminal 40 may include aluminum (Al).
- the material of the cell terminal 40 may be aluminum.
- riveting and/or terminal fastening members 60 are used to fix the cell terminal 40 on the inner surface of the closed portion of the battery can 20, as will be described later. Press-fit can be facilitated.
- 10 series aluminum can be applied to maximize ease of processing and minimize electrical resistance.
- the cell terminal 40 has the same first polarity as the first electrode tab 11 of the electrode assembly 10. Accordingly, the cell terminal 40 can function as a first electrode terminal in the cylindrical battery cell 1 of the present invention.
- the cell terminal 40 is electrically insulated from the battery can 20 having a second polarity. Electrical insulation between the cell terminal 40 and the battery can 20 can be realized in various ways. For example, insulation can be achieved by interposing an insulating gasket G1 between the cell terminal 40 and the battery can 20. Alternatively, insulation can be achieved by forming an insulating coating layer on a portion of the cell terminal 40.
- a method may be applied in which the cell terminal 40 is structurally firmly fixed so that contact between the cell terminal 40 and the battery can 20 is impossible. Alternatively, a plurality of methods among the methods described above may be applied together.
- the cell terminal 40 includes a terminal exposure portion 41 and a terminal insertion portion 42.
- the terminal insertion portion 42 may include an electrical connection portion 42a and a flange portion 42b.
- the terminal exposed portion 41 is exposed to the outside of the battery can 20.
- the terminal exposed portion 41 may be located approximately at the center of the closed portion of the battery can 20.
- the maximum width of the terminal exposed portion 41 may be larger than the maximum width of the hole formed in the battery can 20 for insertion of the cell terminal 40.
- the terminal insertion portion 42 passes through approximately the center of the closed portion of the battery can 20, and the electrical connection portion 42a of the terminal insertion portion 42 may be electrically connected to the first electrode tab 11. there is.
- the bottom surface of the cell terminal 40 may have a substantially flat shape with at least a portion of the area approximately parallel to the closed portion of the battery can 20.
- the first current collector 50 applied for electrical connection between the cell terminal 40 and the first electrode tab 11 and The contact area between the cell terminals 40 can be maximized, thereby minimizing contact resistance.
- the flange portion 42b of the terminal insertion portion 42 is formed around the electrical connection portion 42a and may be riveted on the inner surface of the closed portion of the battery can 20. That is, the flange portion 42b of the terminal insertion portion 42 may have a shape bent toward the inner surface of the closed portion of the battery can 20. Therefore, the maximum width of the terminal insertion portion 42 after the riveting process for fixing the cell terminal 40 is performed is the maximum width of the hole formed in the battery can 20 through which the terminal insertion portion 42 passes. It can be formed larger.
- the electrical connection portion 42a of the terminal insertion portion 42 may be coupled to the first current collector 50, which will be described later.
- the electrical connection portion 42a of the terminal insertion portion 42 may have a substantially cylindrical shape, for example.
- the shape of the electrical connection portion 42a of the terminal insertion portion 42 is not limited to this.
- the electrical connection portion 42a of the terminal insertion portion 42 may have various shapes, such as a cylindrical shape with an elliptical cross-section, a square pillar shape, a hexagonal pillar shape, or an octagonal pillar shape.
- the bottom surface of the electrical connection portion 42a of the terminal insertion portion 42 may be formed to be at least partially substantially flat.
- the insulating gasket G1 is interposed between the battery can 20 and the cell terminal 40 to prevent the battery can 20 and the cell terminal 40, which have opposite polarities, from contacting each other.
- the outer surface 20a of the closed portion of the battery can 20, which has a substantially flat shape, can function as the second electrode terminal of the cylindrical battery cell 1.
- the insulating gasket (G1) includes a gasket exposed portion (G1A) and a gasket insertion portion (G1B).
- the gasket exposed portion G1A is interposed between the terminal exposed portion 41 of the cell terminal 40 and the battery can 20.
- the gasket exposed portion G1A may extend longer than the terminal exposed portion 41 along a direction approximately parallel to the closed portion of the battery can 20 in order to maximize insulation. As a result, when the cylindrical battery cell 1 is viewed from above, a portion of the gasket exposed portion G1A may be exposed to the outside of the terminal exposed portion 41.
- the gasket insertion portion G1A is interposed between the terminal insertion portion 42 of the cell terminal 40 and the battery can 20.
- the gasket insertion portion G1A may be deformed together during riveting using the flange portion 42b of the terminal insertion portion 42 and may come into close contact with the inner surface of the closing portion of the battery can 20.
- the insulating gasket G1 may be made of, for example, a resin material having insulating properties and elasticity.
- the insulating gasket (G1) When the insulating gasket (G1) is made of a resin material, the insulating gasket (G1) can be coupled to the battery can 20 and the cell terminal 40 by heat fusion. In this case, airtightness can be strengthened at the bonding interface between the insulating gasket (G1) and the cell terminal 40 and the bonding interface between the insulating gasket (G1) and the battery can 20.
- the gasket exposed portion G1A of the insulating gasket G1 has an extended shape to cover the outer peripheral surface of the terminal exposed portion 41, or the outer peripheral surface of the terminal exposed portion 41. In addition, it can have an extended form to cover even part of the upper surface.
- the cell terminal (40) may be used, for example, by insert injection molding. It may be formed integrally with the insulating gasket (G1).
- the entire upper surface area of the battery can 20 viewed from the top of the cylindrical battery cell 1, the entire area excluding the area occupied by the cell terminal 40 and the insulating gasket G1, that is, the battery can 20
- the area occupied by the outer surface 20a of the closed portion corresponds to a second electrode terminal having an opposite polarity to the cell terminal (first electrode terminal) 40.
- the first current collector plate 50 is coupled to the upper part of the electrode assembly 10. Additionally, the first current collector 50 is coupled to the cell terminal 40. More specifically, the first current collector plate 50 has a first side and a second side opposite to the second side, the first side is coupled to the first electrode tab 11, and the second side is connected to the first electrode tab 11. The surface is coupled to the cell terminal 40. Accordingly, the first current collector plate 50 electrically connects the first electrode tab 11 of the electrode assembly 10 and the cell terminal 40.
- the first current collector plate 50 is made of a conductive metal material and is coupled to the first electrode tab 11. When the first electrode tab 11 is a positive electrode tab, the first current collector plate 50 may include aluminum, for example. Preferably, the first current collector plate 50 may be made of aluminum.
- the bottom surface of the cell terminal 40 that is, the bottom surface of the electrical connection portion 42a of the terminal insertion portion 42, may be formed at least in part with a flat portion that is approximately parallel to the inner surface of the closed portion of the battery can 20. , the first current collector 50 is coupled to this flat portion.
- the first current collector 50 is coupled to the end of the first electrode tab 11.
- the first electrode tab 11 and the first current collector 50 may be joined by, for example, laser welding.
- the laser welding may be performed by partially melting the base material of the first current collector plate 50, with solder for welding interposed between the first current collector plate 50 and the first electrode tab 11. It may come true.
- the solder preferably has a lower melting point compared to the first current collector 50 and the first electrode tab 11.
- the first current collector plate 50 may be coupled to a coupling surface formed by bending an end of the first electrode tab 11 in a direction parallel to the first current collector plate 50.
- the first electrode tab 11 may be bent along the radial direction of the electrode assembly 10 .
- the bending direction of the first electrode tab 11 may be, for example, toward the winding center of the electrode assembly 10, that is, toward the core.
- the space occupied by the first electrode tab 11 is reduced, thereby improving energy density.
- an increase in the bonding area between the first electrode tab 11 and the first current collector 50 can result in the effect of improving bonding force and reducing resistance. there is.
- the current collector 50 and the first electrode tab 11 are joined within an area where the number of stacks is uniform.
- the first current collector plate 50 applied to the present invention includes a first tab coupling portion 52 and a cell terminal 40 coupled to the first electrode tab 11. ) and a terminal coupling portion 53 coupled to the terminal.
- the first current collector 50 may further include an edge portion 51.
- the edge portion 51 is disposed at the top of the electrode assembly 10.
- the edge portion 51 may have an approximate rim shape with an empty space S formed therein.
- the edge portion 51 unlike what is shown, may have a substantially square rim shape, a hexagonal rim shape, an octagonal rim shape, or any other rim shape.
- the terminal coupling portion 53 may be substantially similar to the diameter of the flat portion formed on the bottom surface of the cell terminal 40 in order to secure an area for coupling with the flat portion formed on the bottom surface of the cell terminal 40. may have the same or larger diameter. However, this does not limit the area of the terminal coupling portion 53.
- the first tab coupling portion 52 extends inward from the edge portion 51 and is coupled to the first electrode tab 11.
- the terminal coupling portion 53 is spaced apart from the first tab coupling portion 52 and is located inside the edge portion 51. As will be described later, the terminal coupling portion 53 may be coupled to the cell terminal 40 by a mechanical fastening method.
- the terminal coupling portion 53 may be located, for example, at approximately the center of the inner space surrounded by the edge portion 51.
- the terminal coupling portion 53 may be provided at a position corresponding to the winding center hole C formed in the core portion of the electrode assembly 10.
- the terminal coupling portion 53 is configured to cover the winding center hole C of the electrode assembly 10 so that the winding center hole C of the electrode assembly 10 is not exposed to the outside of the terminal coupling portion 53.
- the terminal coupling portion 53 may have a larger diameter or width than the winding center hole C of the electrode assembly 10.
- the first tab coupling portion 52 and the terminal coupling portion 53 are not directly connected but are arranged to be spaced apart from each other and may be indirectly connected by the edge portion 51.
- the first current collector plate 50 has a structure in which the first tab coupling portion 52 and the terminal coupling portion 53 are not directly connected to each other, but are only indirectly connected through the edge portion 51. Shock can be dispersed. That is, when shock and/or vibration occurs in the cylindrical battery cell 1 of the present invention, the coupling portion between the first tab coupling portion 52 and the first electrode tab 11 and the terminal coupling portion 53 and the cell terminal (40) It can disperse the impact applied to the liver binding site.
- first tab coupling portions 52 In the drawing of the present invention, only the case where there are four first tab coupling portions 52 is shown, but the present invention is not limited thereto.
- the number of the first tab coupling portions 52 can be determined in various ways by considering the difficulty of manufacturing according to the complexity of the shape, electrical resistance, and the space inside the edge portion 51 considering electrolyte impregnation.
- the first current collector 50 may further include a bridge portion 54 that extends inward from the edge portion 51 and is connected to the terminal coupling portion 53.
- the bridge portion 54 may include a current blocking portion N formed to partially reduce the cross-sectional area of the bridge portion 54. Adjustment of the cross-sectional area of the current blocking portion N may be realized, for example, by partially reducing the width and/or thickness of the bridge portion 54.
- the current blocking portion N may have the form of a notch, groove, hole, etc. formed on at least one surface of the bridge portion 54.
- the current blocking portion N is a stack of the electrode assembly 10 described above in order to prevent foreign substances generated during rupture from flowing into the interior of the electrode assembly 10 and causing problems such as internal short circuit. It is preferable that it is provided in an area corresponding to the water uniformity area. This is because, in this area, the number of overlapping layers of the segment pieces 11a (see FIG. 2) of the first electrode tab 11 is maintained at the maximum, and thus the overlapped segments can function as a mask.
- the current blocking portion N may be provided in an area corresponding to approximately the center of the electrode assembly 10 in the radial direction.
- the first tab coupling portion 52 may be provided in plural numbers.
- the plurality of first tab coupling portions 52 may be arranged at substantially equal intervals from each other along the extending direction of the edge portion 51 .
- the extension lengths of each of the plurality of first tab coupling portions 52 may be substantially equal to each other.
- the first tab coupling portion 52 may be coupled to the first electrode tab 11 by, for example, welding.
- the terminal coupling portion 53 may be arranged to be surrounded by a plurality of first tab coupling portions 52 .
- the terminal coupling portion 53 may be coupled to the cell terminal 40 by a terminal fastening member 60.
- the bridge portion 54 may be located between a pair of adjacent first tab coupling portions 52. In this case, the distance from the bridge portion 54 to one of the pair of first tab coupling portions 52 along the extending direction of the edge portion 51 is the distance from the bridge portion 54 to the edge portion 51. It may be substantially equal to the distance to the remaining one of the pair of first tab coupling portions 52 along the extension direction.
- the cross-sectional area of each of the plurality of first tab coupling portions 52 may be formed to be substantially the same.
- the width and thickness of each of the plurality of first tab coupling portions 52 may be formed to be substantially the same.
- each of the plurality of bridge parts 54 may be disposed between a pair of adjacent first tab coupling parts 52.
- the plurality of bridge portions 54 may be arranged at substantially equal intervals from each other along the extending direction of the edge portion 51 .
- the distance from each of the plurality of bridge portions 54 to one of a pair of first tab coupling portions 52 adjacent to each other along the extending direction of the edge portion 51 is the distance from the remaining first tab coupling portion 52. ) may be substantially the same as the distance reached.
- the terminal fastening member 60 couples the cell terminal 40 and the first current collector plate 50. That is, in the present invention, the connection between the cell terminal 40 and the first current collector 50 can be achieved not by welding but by a mechanical fastening method using a separate member for fastening. When welding is applied to join the cell terminal 40 and the first current collector 50, welding spatter (in the case of laser welding) or splash occurs, damaging the electrode assembly 10. Metal foreign substances may enter the interior. Metal foreign substances may move along the electrolyte when the electrolyte is injected and cause an internal short circuit. Therefore, in the present invention, a mechanical fastening method can be applied to couple the cell terminal 40 and the first current collector 50, thereby solving this problem.
- the cell terminal 40 is located on the closed side of the battery can 20, and thus the coupling between the cell terminal 40 and the first current collector 50
- the process for must be performed along the direction of the arrow in FIG. 5 through the winding center hole (C) of the electrode assembly (10).
- metal foreign matter caused by welding spatter or splash inside the winding center hole (C)
- the terminal fastening member 60 may couple the cell terminal 40 and the first current collector 50 using, for example, a SPR (self-piercing rivet) method.
- the terminal fastening member 60 may be press-fitted into the first current collector plate 50 and the cell terminal 40 to fasten the cell terminal 40 and the first current collector plate 50.
- the terminal fastening member 60 may include a base portion 61 and a fastening portion 62.
- the base portion 61 may be arranged approximately parallel to the first current collector 50.
- the fastening portion 62 extends from the base portion 61 toward the first current collector 50 and extends from the surface of the first current collector 50 to the inside of the first current collector 50 and the cell terminal 40. can be press-fitted.
- the fastening portion 62 is located on the lower surface of the terminal coupling portion 53 provided on the first current collector 50 (the inner side of the winding center hole C among both sides of the terminal coupling portion 53). surface facing) and the bottom surface of the cell terminal 40.
- the terminal coupling portion 53 of the first current collector plate 50 may be dug inward through the bottom surface of the cell terminal 40 during the press-fitting process, and thus the first current collector plate 50 may be connected to the cell terminal 40. It can be in close contact with the cell terminal 40 while maximizing the contact area with it.
- the fastening portion 62 of the terminal fastening member 60 may penetrate the terminal coupling portion 53 at a position press-fitted to a predetermined depth from the bottom surface of the cell terminal 40. Of course, unlike this, the fastening portion 62 of the terminal fastening member 60 may not penetrate the first current collector plate 50 until it reaches the maximum press-fit depth.
- the fastening part 62 may be configured to form a space inside, and may have a side wall shape that continuously or discontinuously surrounds the empty space. At least a portion of the first current collector plate 50 on the outside and inside of the fastening part 62 will be inserted from the bottom surface of the cell terminal 40 into the inside of the cell terminal 40 as the fastening part 62 is pressed in. You can. In a state in which press-fitting by the terminal fastening member 60 is completed, the first current collector plate 50 can contact both the base portion 61 and the fastening portion 62 on the outside of the fastening portion 62, and the fastening portion ( Even within the space formed inside the 62), both the base portion 61 and the fastening portion 62 can be contacted.
- the terminal fastening member 60 is inserted through the winding center hole C of the electrode assembly 10 to couple the first electrode current collector plate 50 and the cell terminal 40.
- the maximum diameter or maximum width of the terminal fastening member 60 must be smaller than the diameter of the winding center hole C of the electrode assembly 10.
- the terminal fastening member 60 may be made of boron steel (boron steel) to which a trace amount of boron in the range of approximately 0.001 to 0.008 wt% is added. These boron steels have the advantage of having very high hardness and excellent wear resistance.
- the present inventors discussed the case where the cell terminal 40 and the first current collector 50 made of aluminum were fastened using a terminal fastening member 60 made of boron steel using a self-piercing rivet method (example) and the case of laser welding.
- the resistance approximately 0.12 to 0.22 milliohm
- a 3 mm thick aluminum plate (element 1 corresponding to the cell terminal 40) and a 0.2 mm thick aluminum plate (element 2 corresponding to the first current collector 50) were made of boron steel.
- a rivet (element 3 corresponding to the terminal fastening member 60) was prepared. After placing element 2 on the top and element 1 on the bottom, element 3 was introduced into the SPR equipment, and samples were manufactured by applying a fastening pressure of 15 to 25 N and 3 different shapes of jigs (Examples 1 to 2). 6).
- the SPR process for manufacturing the sample was performed using a first aluminum plate instead of the cell terminal 40 and a second aluminum plate instead of the first current collector plate 50.
- the lower part of the first aluminum plate is supported by a jig (D)
- a boron steel material replacing the terminal fastening member 60 is press-fitted from the upper part of the second aluminum plate.
- Press-fitting was performed using a member. Press-fitting using the press-fitting member was performed by inserting the press-fitting member into the blank holder (B) and pressing the press-fitting member downward using a punch (P) from the top of the press-fitting member.
- Comparative Examples 1 to 3 the same conditions as Examples 1 to 3 were applied, except that NiCu coated boron steel was applied as element 3.
- the resistance between the surface of the aluminum plate (element 1) corresponding to the cell terminal 40 and the surface of the aluminum plate (element 2) corresponding to the first current collector 50 was measured. Resistance measurement was performed using Hioki's microresistance meter. As a result of measuring resistance, in Example 1, 0.125 ⁇ 0.008 m ⁇ was measured, in Example 2, 0.134 ⁇ 0.025 m ⁇ , and in Example 3, 0.221 ⁇ 0.047 m ⁇ .
- Comparative Example 1 0.159 ⁇ 0.018 m ⁇ was measured, in Comparative Example 2, 0.134 ⁇ 0.008 m ⁇ was measured, and in Comparative Example 3, 0.203 ⁇ 0.038 m ⁇ was measured. Additionally, in Comparative Example 4, as mentioned above, a resistance of approximately 0.2 m ⁇ was measured.
- the case where the mechanical fastening method of the present invention is applied shows a smaller resistance value or Alternatively, it can be seen that it shows a similar level of resistance value. Therefore, considering the problems caused by metal foreign substances that may occur during welding, it can be seen that it may be more advantageous to adopt the mechanical fastening method of the present invention (comparison of Examples 1 to 3 and Comparative Example 4).
- Examples 1 to 3 in which the terminal fastening member 60 made of boron steel was applied compared to Examples 1 to 3 in which the terminal fastening member 60 made of boron steel was applied.
- a comparative example in which a terminal fastening member 60 with a NiCu coating layer formed on the surface of the terminal fastening member 60 made of boron steel was applied. In the case of 1 to 3, you can see that the resistance value appears relatively large. Therefore, in terms of the material of the terminal fastening member 60, it can be seen that it is desirable to use boron steel.
- the insulator 70 is provided between the first current collector 50 coupled to the upper part of the electrode assembly 10 and the inner surface of the closed portion of the battery can 20.
- the insulator 70 prevents contact between the first current collector plate 50 and the battery can 20.
- the insulator 70 may also be interposed between the top of the outer peripheral surface of the electrode assembly 10 and the side wall of the battery can 20. That is, the insulator 70 may also be interposed between the first electrode tab 11 and the inner surface of the side wall of the battery can 20.
- the terminal insertion portion 42 of the cell terminal 40 is connected to the first current collector plate through the hole formed in the insulator 70. It is coupled to the terminal coupling portion 53 of (50).
- the hole formed in the insulator 70 may be formed at a position corresponding to the winding center hole C of the electrode assembly 10. Additionally, the hole formed in the insulator 70 may be formed at a position corresponding to the terminal coupling portion 53 of the first current collector 50.
- the insulator 70 fills the space between the inner surface of the closed portion of the battery can 20 and the first current collector 50 along the height direction, preventing space for the electrode assembly 10 to flow up and down. In order to prevent this, it may have a thickness corresponding to the distance between the inner surface of the closed portion of the battery can 20 and the first current collector plate 50. In another aspect, the upper surface of the insulator 70 may contact the inner surface of the closed portion of the battery can 20, and the lower surface of the insulator 70 may contact the upper surface of the first current collector 50. .
- the second current collector plate 80 is disposed below the electrode assembly 10 . Additionally, the second current collector plate 80 may be configured to electrically connect the second electrode tab 12 of the electrode assembly 10 and the battery can 20.
- the second current collector plate 80 is made of a conductive metal material and is connected to the second electrode tab 12. Additionally, the second current collector 80 is electrically connected to the battery can 20.
- the second current collector 80 may be interposed and fixed between the inner surface of the battery can 20 and the sealing gasket G2.
- the second current collector 80 may be, for example, interposed between the lower surface of the beading portion 21 provided in the battery can 20 and the sealing gasket G2.
- the second current collector 80 is coupled to the end of the second electrode tab 12.
- the second electrode tab 12 and the second current collector 80 may be joined by, for example, laser welding.
- the laser welding may be performed by partially melting the base material of the second current collector plate 80, with solder for welding interposed between the second current collector plate 80 and the second electrode tab 12. It may come true.
- the solder preferably has a lower melting point compared to the second current collector plate 80 and the second electrode tab 12.
- the second current collector plate 80 may be coupled to a coupling surface formed by bending an end of the second electrode tab 12 in a direction parallel to the second current collector plate 80.
- the second electrode tab 12 may be bent along the radial direction of the electrode assembly 10 .
- the bending direction of the second electrode tab 12 may be, for example, toward the core of the electrode assembly 10.
- the space occupied by the second electrode tab 12 is reduced, thereby improving energy density.
- an increase in the bonding area between the second electrode tab 12 and the second current collector 80 can result in the effect of improving bonding force and reducing resistance. there is.
- the current collector plate 80 and the second electrode tab 12 are combined within an area where the number of stacks is uniform.
- the second current collector plate 80 may include a current collector hole 80a formed at a position corresponding to the winding center hole C formed in the core portion of the electrode assembly 10.
- the winding center hole C of the electrode assembly 10 and the current collector hole 80a which communicate with each other, are terminals for coupling between the cell terminal 40 and the terminal coupling portion 53 of the first current collector plate 50. It may function as a passage for inserting a tool for inserting the fastening member 60 and press-fitting the terminal fastening member 60 into the first current collector plate 50 and the cell terminal 40.
- the current collector hole 80a may have a diameter substantially the same as or larger than the hole formed in the winding center of the electrode assembly 10.
- the current collector hole 80a may be used as a passage for injection of electrolyte.
- the can coupling portion 83 may be electrically coupled to the battery can 20 at a plurality of points. In this case, the combined area of the second current collector 80 and the battery can 20 can be maximized, and the current path can be multiplexed, thereby allowing the second current collector 80 and the battery can 20 ) can minimize the electrical resistance at the binding site.
- the can coupling portion 83 may be coupled to the lower surface of the beading portion 21, for example.
- the can coupling portion 83 may be electrically coupled to the flat portion formed on the lower surface of the beading portion 21 of the battery can 20, and the lower surface of the beading portion 21 and the sealing gasket. (G2) may be interposed between.
- the can coupling portion 83 may have a shape extending to a predetermined length along the circumferential direction of the battery can 20 on the beading portion 21.
- the maximum distance from the center of the second current collector plate 80 to the end of the second tab coupling portion 82 along the radial direction of the electrode assembly 10 multiplied by 2 is the length of the beading portion 21.
- the inner diameter of the battery can 20 in the formed area is substantially equal to or smaller than the minimum inner diameter of the battery can 20. This prevents interference between the second current collector plates 80 due to the beading portion 21 during the sizing process of compressing the battery can 20 along the height direction (direction parallel to the Z-axis). This is to prevent the electrode assembly 10 from being pressed by the second current collector plate 80.
- the cylindrical battery cell 1 has a structure in which the cap plate 30 does not necessarily have polarity.
- the second current collector 80 is connected to the side wall of the battery can 20, so that the outer surface 20a of the closed portion of the battery can 20 is connected to the cell terminal 40.
- the outer surface 20a of the closed portion of the battery can 20 and the cell terminal 40 are used to connect the cylindrical battery cells 1. Wiring work such as bus bar connection can be performed at the top.
- the cell terminal 40 exposed to the outside of the battery can 20 may function as a first electrode terminal, and may function as a first electrode terminal outside the closed portion of the battery can 20.
- the area of the surface 20a occupied by the exposed surface substantially parallel to the upper surface of the first electrode terminal may function as the second electrode terminal.
- a first bus bar may be coupled to the upper surface of the cell terminal 40 exposed to the outside of the battery can 20, and the battery can 20
- a second bus bar may be coupled to an area of the outer surface 20a of the closed portion occupied by the exposed surface substantially parallel to the upper surface of the first electrode terminal.
- a plurality of cylindrical battery cells 1 may be connected in series and parallel at the top of the cylindrical battery cell 1 using a bus bar 150.
- the number of cylindrical battery cells 1 can be increased or decreased considering the capacity of the battery pack.
- the cell terminal 40 may have a positive polarity and the outer surface 20a of the closed portion of the battery can 20 may have a negative polarity.
- the opposite is also possible.
- a plurality of cylindrical battery cells 1 may be arranged in a plurality of columns and rows. Columns are in a vertical direction with respect to FIG. 10 , and rows are in a left-right direction with respect to FIG. 10 . Additionally, in order to maximize space efficiency, the cylindrical battery cells 1 may be arranged in a closest packing structure. The close packing structure is formed when the centers of the exposed terminal portions 41 of the cell terminal 40 exposed to the outside of the battery can 20 are connected to each other to form an equilateral triangle.
- the bus bar 150 may be disposed on top of the plurality of cylindrical battery cells 1, more preferably between adjacent rows. Alternatively, bus bars 150 may be placed between adjacent rows.
- the bus bar 150 may connect cells 1 arranged in the same row in parallel and connect cylindrical battery cells 1 arranged in two adjacent rows in series.
- the bus bar 150 may include a body portion 151, a plurality of first bus bar terminals 152, and a plurality of second bus bar terminals 153 for serial and parallel connection.
- the body portion 151 may extend between cell terminals 40 of adjacent cylindrical battery cells 1, preferably between rows of cylindrical battery cells 1. Alternatively, the body portion 151 may extend along the row of cylindrical battery cells 1 and be bent regularly, such as in a zigzag shape.
- the plurality of first bus bar terminals 152 protrude and extend from one side of the body portion 151 toward the cell terminal 40 of each cylindrical battery cell 1, and may be electrically coupled to the cell terminal 40. there is. Electrical coupling between the first bus bar terminal 152 and the cell terminal 40 may be achieved by laser welding, ultrasonic welding, etc. Additionally, the plurality of second bus bar terminals 153 may be electrically coupled to the outer surface 20a of each cylindrical battery cell 1 from the other side of the body portion 151. Electrical coupling between the second bus bar terminal 153 and the outer surface 20a may be achieved by laser welding, ultrasonic welding, etc.
- the body portion 151, the plurality of first bus bar terminals 152, and the plurality of second bus bar terminals 153 may be made of one conductive metal plate.
- the metal plate may be, for example, an aluminum plate or a copper plate, but the present invention is not limited thereto.
- the body portion 151, the plurality of first bus bar terminals 152, and the second bus bar terminals 153 may be manufactured as separate pieces and then connected to each other through welding or the like.
- the cell terminal 40 with positive polarity and the outer surface 20a of the closed portion of the battery can 20 with negative polarity are located in the same direction, so the bus bar ( Electrical connection of the cylindrical battery cells 1 can be easily implemented using 150).
- the cell terminal 40 of the cylindrical battery cell 1 and the outer surface 20a of the closed portion of the battery can 20 have a large area, a sufficient coupling area of the bus bar 150 is secured to secure the cylindrical battery cell 1. ) can sufficiently lower the resistance of the battery pack containing.
- the cylindrical battery cell is, for example, a cylindrical battery cell with a form factor ratio (defined as the diameter of the cylindrical battery cell divided by the height, i.e. the ratio of the diameter ( ⁇ ) to the height (H)) greater than approximately 0.4. You can.
- the form factor refers to values representing the diameter and height of a cylindrical battery cell.
- Cylindrical battery cells may be, for example, 46110 cells, 48750 cells, 48110 cells, 48800 cells, or 46800 cells.
- the first two numbers indicate the diameter of the cell
- the next two numbers indicate the height of the cell
- the last number 0 indicates that the cross section of the cell is circular.
- the battery cell according to an embodiment of the present invention may be a cylindrical battery cell with a diameter of approximately 46 mm, a height of approximately 110 mm, and a form factor ratio of approximately 0.418.
- a battery cell according to another embodiment may be a cylindrical battery cell with a diameter of approximately 48 mm, a height of approximately 75 mm, and a form factor ratio of approximately 0.640.
- a battery cell according to another embodiment may be a cylindrical battery cell with a diameter of approximately 48 mm, a height of approximately 110 mm, and a form factor ratio of approximately 0.418.
- a battery cell according to another embodiment may be a cylindrical battery cell with a diameter of approximately 48 mm, a height of approximately 80 mm, and a form factor ratio of approximately 0.600.
- a battery cell according to another embodiment may be a cylindrical battery cell with a diameter of approximately 46 mm, a height of approximately 80 mm, and a form factor ratio of approximately 0.575.
- battery cells with a form factor ratio of approximately 0.4 or less have been used. That is, conventionally, for example, 18650 cells, 21700 cells, etc. were used. For an 18650 cell, its diameter is approximately 18 mm, its height is approximately 65 mm, and the form factor ratio is approximately 0.277. For a 21700 cell, its diameter is approximately 21 mm, its height is approximately 70 mm, and the form factor ratio is approximately 0.300.
- the cylindrical battery cell 1 of the present invention has a structure in which resistance is minimized through expansion of the contact area between components, multiplexing of current paths, and minimization of current path length.
- the AC resistance of the cylindrical battery cell (1) measured through a resistance meter between the positive and negative electrodes, that is, between the upper surface of the cell terminal (40) and the outer surface (20a) of the closed portion of the battery can (20) is It may be approximately 4 milliohms (mohm) or less.
- the battery pack 3 includes a secondary battery assembly in which a plurality of cylindrical battery cells 1 according to an embodiment of the present invention are electrically connected as described above, and the same. It includes a pack housing (2) that accommodates it.
- a pack housing (2) that accommodates it.
- parts such as bus bars, cooling units, and power terminals for electrical connection are omitted for convenience of illustration.
- the electrical connection structure of the plurality of battery cells 1 for manufacturing the battery pack 3 has been exemplarily described above with reference to FIG. 10 .
- the vehicle 5 may be, for example, an electric vehicle, a hybrid vehicle, or a plug-in hybrid vehicle, and includes a battery pack 3 according to an embodiment of the present invention. Includes.
- the vehicle 5 operates by receiving power from the battery pack 3 according to an embodiment of the present invention.
- Second electrode tab (second uncoated portion)
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Connection Of Batteries Or Terminals (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Battery Mounting, Suspending (AREA)
Abstract
Description
Claims (15)
- 제1 극성을 갖는 제1 전극 탭 및 제2 극성을 갖는 제2 전극 탭을 구비하는 전극 조립체;하단에 형성된 개방부 및 상단에 형성된 폐쇄부를 구비하며, 상기 개방부를 통해 상기 전극 조립체를 수용하며 상기 제2 전극 탭과 전기적으로 연결되는 전지 캔;상기 제1 전극 탭과 전기적으로 연결되며, 상기 전지 캔의 폐쇄부를 통해 상기 전지 캔의 외부로 노출되고, 상기 전지 캔과 전기적으로 절연되는 셀 단자;제1 면 및 상기 제1 면의 반대측 면인 제2 면을 구비하며, 상기 제1 면은 상기 제1 전극 탭과 결합되고 상기 제2 면은 상기 셀 단자와 결합되는 제1 집전판; 및상기 셀 단자와 상기 제1 집전판을 기계적으로 체결시키는 단자 체결 부재;를 포함하는 원통형 배터리 셀.
- 제1항에 있어서,상기 단자 체결 부재는,상기 제1 집전판 및 셀 단자의 내측으로 압입되어 상기 셀 단자와 상기 제1 집전판을 체결시키는 것을 특징으로 하는 원통형 배터리 셀.
- 제1항에 있어서,상기 단자 체결 부재는,베이스부; 및상기 베이스부로부터 상기 제1 집전판을 향해 연장되어 상기 제1 집전판의 표면으로부터 상기 제1 집전판 및 셀 단자의 내측으로 압입되는 체결부;를 포함하는 것을 특징으로 하는 원통형 배터리 셀.
- 제1항에 있어서,상기 셀 단자 및 상기 제1 집전판은 알루미늄을 포함하는 것을 특징으로 하는 원통형 배터리 셀.
- 제4항에 있어서,상기 단자 체결 부재는,붕소를 0.001wt% 내지 0.008wt% 함유하는 보론강을 포함하는 것을 특징으로 하는 원통형 배터리 셀.
- 제3항에 있어서,상기 체결부의 외측 및 상기 체결부의 내측에서 상기 제1 집전판의 적어도 일부가 상기 체결부의 압입에 따라 상기 셀 단자의 내측으로 내입되는 것을 특징으로 하는 원통형 배터리 셀.
- 제1항에 있어서,상기 단자 체결 부재의 최대 직경 또는 최대 폭은,상기 전극 조립체의 권취 중심 홀의 직경보다 작은 것을 특징으로 하는 원통형 배터리 셀.
- 제1항에 있어서,상기 원통형 배터리 셀은,상기 전지 캔의 상기 개방부를 밀폐하는 캡 플레이트를 더 포함하는 것을 특징으로 하는 원통형 배터리 셀.
- 제8항에 있어서,상기 캡 플레이트는,상기 전극 조립체와 전기적으로 연결되지 않으며, 이로써 극성을 갖지 않는 것을 특징으로 하는 원통형 배터리 셀.
- 제1항에 있어서,상기 원통형 배터리 셀은, 상기 제2 전극 탭과 상기 전지 캔 사이를 전기적으로 연결하는 제2 집전판을 더 포함하는 것을 특징으로 하는 원통형 배터리 셀.
- 제10항에 있어서,상기 제2 집전판은,상기 제2 전극 탭과 결합되는 탭 결합부; 및상기 전지 캔과 전기적으로 결합되는 캔 결합부;를 포함하는 것을 특징으로 하는 원통형 배터리 셀.
- 제11항에 있어서,상기 캔 결합부는,상기 전지 캔의 측벽의 내측면 상에 전기적으로 결합되는 것을 특징으로 하는 원통형 배터리 셀.
- 제12항에 있어서,상기 전지 캔은,상기 개방부 측에서 상기 전지 캔의 외주면 둘레를 압입하여 형성되는 비딩부를 구비하고,상기 캔 결합부는,상기 비딩부의 하면 상에 전기적으로 결합되는 것을 특징으로 하는 원통형 배터리 셀.
- 제1항 내지 제13항 중 어느 한 항에 따른 원통형 배터리 셀을 복수개 포함하는 배터리 팩.
- 제14항에 따른 배터리 팩을 포함하는 자동차.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202380012593.0A CN117597826A (zh) | 2022-03-08 | 2023-03-03 | 圆柱形二次电池电芯、以及包括其的电池组和车辆 |
| JP2024505157A JP7743604B2 (ja) | 2022-03-08 | 2023-03-03 | 円筒型バッテリーセル、並びにこれを含むバッテリーパック及び自動車 |
| EP23767092.2A EP4354631A4 (en) | 2022-03-08 | 2023-03-03 | CYLINDRICAL SECONDARY BATTERY CELL, AND BATTERY PACK AND VEHICLE COMPRISING SAME |
| US18/689,144 US20250219267A1 (en) | 2022-03-08 | 2023-03-03 | Cylindrical battery cell, and battery pack and vehicle including the same |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2022-0029614 | 2022-03-08 | ||
| KR1020220029614A KR20230132286A (ko) | 2022-03-08 | 2022-03-08 | 원통형 배터리 셀, 그리고 이를 포함하는 배터리 팩 및 자동차 |
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| Publication Number | Publication Date |
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| WO2023171991A1 true WO2023171991A1 (ko) | 2023-09-14 |
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| Application Number | Title | Priority Date | Filing Date |
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| PCT/KR2023/002982 Ceased WO2023171991A1 (ko) | 2022-03-08 | 2023-03-03 | 원통형 배터리 셀, 그리고 이를 포함하는 배터리 팩 및 자동차 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20250219267A1 (ko) |
| EP (1) | EP4354631A4 (ko) |
| JP (1) | JP7743604B2 (ko) |
| KR (1) | KR20230132286A (ko) |
| CN (1) | CN117597826A (ko) |
| WO (1) | WO2023171991A1 (ko) |
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-
2023
- 2023-03-03 WO PCT/KR2023/002982 patent/WO2023171991A1/ko not_active Ceased
- 2023-03-03 JP JP2024505157A patent/JP7743604B2/ja active Active
- 2023-03-03 CN CN202380012593.0A patent/CN117597826A/zh active Pending
- 2023-03-03 US US18/689,144 patent/US20250219267A1/en active Pending
- 2023-03-03 EP EP23767092.2A patent/EP4354631A4/en active Pending
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| KR102260835B1 (ko) * | 2016-09-20 | 2021-06-03 | 삼성에스디아이 주식회사 | 이차전지, 전극 조립체 및 전극 조립체 제조 방법 |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN117597826A (zh) | 2024-02-23 |
| KR20230132286A (ko) | 2023-09-15 |
| JP2024527080A (ja) | 2024-07-19 |
| EP4354631A4 (en) | 2025-07-02 |
| JP7743604B2 (ja) | 2025-09-24 |
| US20250219267A1 (en) | 2025-07-03 |
| EP4354631A1 (en) | 2024-04-17 |
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