WO2023141768A1 - Microbolometer and preparation method therefor - Google Patents

Microbolometer and preparation method therefor Download PDF

Info

Publication number
WO2023141768A1
WO2023141768A1 PCT/CN2022/073846 CN2022073846W WO2023141768A1 WO 2023141768 A1 WO2023141768 A1 WO 2023141768A1 CN 2022073846 W CN2022073846 W CN 2022073846W WO 2023141768 A1 WO2023141768 A1 WO 2023141768A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
bridge
getter
microbolometer
metal
Prior art date
Application number
PCT/CN2022/073846
Other languages
French (fr)
Chinese (zh)
Inventor
刘继伟
胡汉林
甘先锋
史杰
王兴祥
Original Assignee
烟台睿创微纳技术股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 烟台睿创微纳技术股份有限公司 filed Critical 烟台睿创微纳技术股份有限公司
Priority to PCT/CN2022/073846 priority Critical patent/WO2023141768A1/en
Publication of WO2023141768A1 publication Critical patent/WO2023141768A1/en

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B7/00Microstructural systems; Auxiliary parts of microstructural devices or systems
    • B81B7/04Networks or arrays of similar microstructural devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J5/00Radiation pyrometry, e.g. infrared or optical thermometry
    • G01J5/02Constructional details
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J5/00Radiation pyrometry, e.g. infrared or optical thermometry
    • G01J5/10Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J5/00Radiation pyrometry, e.g. infrared or optical thermometry
    • G01J5/10Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors
    • G01J5/20Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors using resistors, thermistors or semiconductors sensitive to radiation, e.g. photoconductive devices
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/08Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
    • H01L31/09Devices sensitive to infrared, visible or ultraviolet radiation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof

Definitions

  • the present application relates to the technical field of microelectromechanical system process semiconductor preparation, in particular to a microbolometer and a preparation method thereof.
  • thermal imaging technology represented by uncooled infrared detectors and terahertz detectors has developed rapidly in military, commercial, and industrial fields, especially in the context of the global COVID-19 pandemic. Under the influence of the outbreak, thermal imaging technology has a wide range of needs and applications in the fields of medical treatment and temperature measurement.
  • Both uncooled infrared detectors and terahertz detectors are based on the basic principle of microbolometers, using the photothermal effect to absorb incident electromagnetic radiation, causing temperature changes in internal heat-sensitive materials, and converting electromagnetic radiation into electrical signals for imaging of detectors.
  • the microbolometer is built on the silicon substrate of the readout circuit, and a series of suspended micro-bridge structures with the same structure are prepared through the micro-electro-mechanical system (MEMS, Micro-Electro-Mechanical System) process. It consists of supporting legs, interconnecting wires and substrates. In order to ensure the sensitivity of the detector, the microbolometer needs to be placed in the sealed cavity, and the getter is used to maintain the vacuum degree of the sealed cavity (generally less than 10-3mbar), so as to reduce the radiation heat caused by heat conduction and heat convection Loss.
  • MEMS Micro-Electro-Mechanical System
  • the preparation process of the getter is separated from the preparation process of the microbolometer, which is not conducive to reducing the packaging cost of the microbolometer.
  • an embodiment of the present invention provides a microbolometer with small size and low production cost and a preparation method thereof.
  • the first aspect of the embodiment of the present invention provides a microbolometer, comprising:
  • a support bridge located on a base is a single-layer or multi-layer bridge, each layer of bridges includes piers and bridge decks, the piers of the bottommost bridge are located on the surface of the base, between adjacent two-layer bridges, the upper The piers of the bridge on one level are located above the deck of the bridge on the next level;
  • Heat-sensitive layer on the deck of the topmost bridge is Heat-sensitive layer on the deck of the topmost bridge.
  • the second aspect of the embodiment of the present invention provides a method for preparing a microbolometer, including:
  • the support bridge is a single-layer or multi-layer bridge, each layer of bridge includes piers and bridge decks, the piers of the bottom bridge are located on the base surface, and the bridge deck of the bottom bridge Located above the getter layer, between two adjacent bridges, the pier of the upper bridge is located above the bridge deck of the lower bridge;
  • a thermally sensitive layer is deposited on the bridge surface of the topmost bridge.
  • the getter layer is integrated on the substrate under the bridge deck of the support bridge used to support the heat-sensitive layer, and the microbolometer and the getter can be prepared by MEMS technology layer, which is conducive to optimizing the preparation process of the microbolometer.
  • the getter layer is arranged inside the microbolometer, the microbolometer is not limited by the complexity of the packaging structure and the difficulty of the packaging process, which can effectively improve the production efficiency of the microbolometer and reduce the production cost .
  • Fig. 1 is a schematic diagram of a microbolometer provided according to an embodiment of the present application
  • Fig. 2 is a schematic top view of a getter layer and a base layer in a microbolometer according to an embodiment of the present application;
  • Fig. 3 is a schematic top view of a getter layer and a base layer in a microbolometer according to another embodiment of the present application;
  • Fig. 4 is a schematic flow chart of a preparation method of a microbolometer according to an embodiment of the present application
  • 5a to 5k are schematic diagrams of various structures formed during the preparation process of the microbolometer preparation method provided according to an embodiment of the present application.
  • 6a to 6c are schematic diagrams of partial structures formed during the preparation process of the microbolometer preparation method provided according to another embodiment of the present application.
  • Fig. 7 is a schematic diagram of the packaging structure of the microbolometer provided according to the present application.
  • connection should be understood in a broad sense, for example, it can be a fixed connection or a detachable connection. Connected, or integrally connected; it can be directly connected, or indirectly connected through an intermediary, and it can be the internal communication of two elements. Those of ordinary skill in the art can understand the specific meanings of the above terms in this application according to specific situations.
  • the application provides a microbolometer, which mainly includes a substrate, a getter layer, a support layer and a heat sensitive layer.
  • the supporting bridge is located on the base, the supporting bridge is a single-layer or multi-layer bridge, each layer of bridges includes piers and bridge decks, and the piers of the bottommost bridge are located on the surface of the base, between adjacent two-layer bridges, The piers of the bridge on the upper level are located above the deck of the bridge on the next level, the getter layer is located on the surface of the base, and the getter layer located below the deck of the bridge on the lowest level layer, the thermally sensitive layer on the deck of the topmost bridge.
  • the substrate is a semiconductor substrate with built-in readout circuits.
  • the base is a semiconductor substrate with a built-in readout circuit, the first region on the surface of the semiconductor substrate has a metal electrode layer electrically connected to the readout circuit, and the pier of the bottommost bridge is located on the metal electrode layer.
  • layer, the getter layer is located in the second region of the surface of the semiconductor substrate, and the first region is located in the periphery of the second region.
  • the microbolometer further comprises a metal connecting layer disposed along the piers and the deck of each bridge of the supporting bridge, the metal connecting layer being on the topmost bridge deck It is in contact with the thermal sensitive layer, and extends along the support bridge to the metal electrode layer in contact with the metal electrode layer.
  • the metal connection layer is used to electrically connect the thermal sensitive layer and the metal electrode layer, so as to realize the readout circuit to read out the detection information of the microbolometer.
  • the substrate can also be other supporting substrates, so that the MEMS process can be formed on it. After the MEMS process is completed, the other supporting substrates can be removed, and then the electrodes of the microbolometer can be drawn out and read out. Electrode connection of circuit chip.
  • the getter layer is integrated on the substrate under the bridge deck of the support bridge used to support the heat-sensitive layer, and the microbolometer and the getter layer can be prepared by MEMS technology, It is beneficial to optimize the preparation process of the microbolometer.
  • the getter layer is arranged inside the microbolometer, the pixel structure of the microbolometer can be optimized, so that the microbolometer is not limited by the complexity of the packaging structure and the difficulty of the packaging process, and the microbolometer can be effectively improved. Measure bolometer production efficiency and reduce production costs.
  • the microbolometer provided by the application is suitable for single-layer support bridge structure and multi-layer support bridge structure.
  • the microbolometer with a bridge structure (as shown in FIGS. 6a-6c ) is taken as an example to further specifically illustrate the microbolometer provided in the present application and its preparation method. It should be noted here that this application only uses microbolometers with single-layer and two-layer support bridge structures as examples, but this application also applies to microbolometers with three or more layers of support bridge structures.
  • the present application provides a microbolometer for detecting electromagnetic radiation and a preparation method thereof, and the content of the present application will be described in detail below with reference to FIGS. 1 to 4 and FIGS. 5a to 5k.
  • the microbolometer provided by the present application includes a support bridge 7 on the substrate 1, the support bridge 7 is a single-layer support bridge, which is composed of piers and bridge decks,
  • the bridge pier supports the bridge deck on the base 1; and includes a getter layer 4 located on the surface of the base 1 and below the bridge deck of the supporting bridge 7, the microbolometric
  • the gauge also includes a thermally sensitive layer 8 located on the bridge surface of the supporting bridge 7 .
  • the deck of the support bridge 7 is spaced from the getter layer 4 , and the height of the pier of the support bridge is greater than the thickness of the getter layer.
  • Fig. 1 only illustrates one pixel structure of the microbolometer, but the microbolometer provided in the present application may include a plurality of the pixel structures on the substrate, each of which The pixel structure includes the support bridge 7 , the getter layer 4 and the thermal sensitive layer 8 .
  • the piers of the supporting bridges 7 are located at the periphery of the getter layer 4 .
  • the supporting bridge 7 in the microbolometer provided by the present application is a dielectric thin film layer of silicon nitride or silicon dioxide or a combination thereof with a thickness of 50nm-500nm and which can absorb electromagnetic radiation
  • the film layer is a bent film layer, its horizontal part is the bridge deck of the supporting bridge 7, and the bent part is the pier of the supporting bridge 7, and the supporting bridge 7 plays the role of supporting the heat sensitive layer 8 In addition, it also plays the role of protecting the heat-sensitive layer 8 and absorbing electromagnetic radiation.
  • the heat-sensitive layer 8 has a thickness of 30nm-100nm vanadium oxide heat-sensitive thin film layer, while in other embodiments, the heat-sensitive layer 8 can also be a layer of other heat-sensitive thin film materials.
  • the substrate 1 is a semiconductor substrate with a built-in readout circuit.
  • the first region on the surface of the semiconductor substrate 1 has a metal electrode layer 2 electrically connected to the readout circuit.
  • the first region is arranged at the edge of the surface of the semiconductor substrate 1 in order to maximize the area of the second region where the getter layer 4 is located.
  • the thickness of the metal electrode layer 2 is 50nm-400nm, and the metal electrode layer 2 includes one of aluminum layer or copper layer.
  • the substrate 1 can also be other supporting substrates, so that the MEMS process can be formed thereon. After the MEMS process is completed, the other supporting substrates can be removed, and then the electrodes of the microbolometer can be drawn out to the readout circuit. The electrodes of the chip are connected.
  • the microbolometer in order to prevent the metal electrode layer 2 from being damaged during the subsequent formation of the getter layer 4, the microbolometer further includes a first dielectric layer 3 on the semiconductor substrate 1, the first Part of the dielectric layer 3 is disposed on the part of the surface of the semiconductor substrate 1 between the metal electrode layer 2 and the getter layer 4 to isolate the metal electrode layer 2 from the getter layer 4 .
  • the piers of the supporting bridge 7 connect the bridge surface of the supporting bridge 7 with the metal electrode layer 2 . That is, the positions of the piers of the supporting bridge 7 are set corresponding to the positions of the metal electrode layer 2 .
  • the first dielectric layer 3 is an insulating dielectric layer with a thickness of 10 nm-100 nm, and the insulating dielectric layer is a thin film layer such as silicon nitride or silicon dioxide.
  • the getter layer 4 and the metal electrode layer 2 are located on the same surface of the semiconductor substrate 1 , and the metal electrode layer 2 is located on the periphery of the getter layer 4 . That is, the metal electrode layer 2 is located on the first area of the surface of the semiconductor substrate 1, the getter layer 4 may be located on the second area of the surface of the semiconductor substrate 1, and the first area is located on the periphery of the second area, To maximize the ratio S1/S2 between the area of the getter layer 4 and the area of each pixel structure occupying the surface of the semiconductor substrate 1 .
  • FIG. 2 it is a top view schematic diagram of the getter layer 4 and the semiconductor substrate 1 in Figure 1, wherein, S1 is the area of the getter layer 4, and S2 is the area of each of the above-mentioned pixel structures occupying the semiconductor substrate 1.
  • S1 is the area of the getter layer 4
  • S2 is the area of each of the above-mentioned pixel structures occupying the semiconductor substrate 1.
  • S1/S2 the area of the surface of the substrate 1.
  • the position and shape of the getter layer 4 and the metal electrode layer 2 on the surface of the semiconductor substrate 1 can be maximized through a reasonable layout.
  • the shape of the getter layer 4 can be square, rectangular or polygonal, or other non-geometric shapes. For example, another shape setting of the getter layer 4 is shown in FIG. 3 .
  • the microbolometer also includes a second dielectric layer 9 on the support bridge 7, a metal connection layer 10 on the second dielectric layer 9, and a metal connection layer on the second dielectric layer 9.
  • the passivation layer 11 on the dielectric layer 9 and the metal connection layer 10 exposes the metal electrode layer 2 and the heat-sensitive layer 8, so that the metal connection layer 10 connects the metal electrode layer 2 and the heat-sensitive layer 8 to form an electrical path to complete the reading process.
  • the output circuit reads the thermal signal generated by the thermal sensitive layer.
  • the area of the thermally sensitive layer 8 is slightly smaller than the area of the getter layer 4 below it.
  • the second dielectric layer 9 conforms to the supporting bridge 7 , that is, the second dielectric layer 9 includes a first portion extending along the deck of the supporting bridge 7 and a second portion extending along the pier of the supporting bridge 7 .
  • a part of the metal connection layer 10 extends on the first part of the second dielectric layer 9 to be electrically connected to the exposed heat-sensitive layer of the second dielectric layer 9, and another part extends from the first part of the second dielectric layer 9 to the second part of the second dielectric layer 9 , and continue to extend above the metal electrode layer 2 exposed by the second dielectric layer, so as to be electrically connected to the metal electrode layer 2 .
  • the thickness of the metal electrode layer 2 is 50nm-400nm, and the metal electrode layer 2 includes one of an aluminum layer, a copper layer, a titanium layer and a platinum layer.
  • the constituent material of the metal electrode layer 2 may also be other metal materials with good electrical conductivity.
  • the second dielectric layer 9 is a low-stress film layer with a thickness of 10 nm-100 nm, such as silicon oxide, silicon nitride, and other silicon-based layers.
  • the thickness of the metal connection layer 10 is 5nm-50nm, and the metal connection layer is a metal layer with good electrical conductivity and low thermal conductivity, for example, it includes at least one of titanium and vanadium .
  • the passivation layer 11 is a thin film layer with a thickness of 10 nm-150 nm, such as silicon oxide, silicon nitride, and other silicon-based layers.
  • the package structure of the microbolometer is not limited, for example, the package structure is one of a metal package package structure, a ceramic package package structure, a wafer-level package structure and a pixel-level package structure.
  • the microbolometer shown in FIG. 1 also has a release channel 12 disposed in the stack around the heat-sensitive layer 8, for releasing the sacrificial layer ( removed after microbolometer preparation).
  • the stacked layers around the thermal sensitive layer 8 include the bridge surface of the supporting bridge 7 , the second dielectric layer 9 , the metal connection layer 10 and the passivation layer 11 .
  • the getter layer 4 adopts a getter with low activation temperature and high getter efficiency, such as but not limited to a Zr-Co-RE thin film getter layer.
  • the main material of the getter layer 4 is titanium, zirconium, vanadium, chromium, cobalt, iron, manganese, palladium, barium, aluminum, or a multi-phase alloy composed of these materials and rare metals.
  • the main body of the thin film getter layer is easily saturated, adsorbed or oxidized when exposed to air or oxidizing gases, especially when the sacrificial layer is released during the formation of the microbolometer , the thin-film getter layer is easily oxidized by the plasma with higher activity, which will reduce the getter performance of the getter layer 4 or even lose the getter ability.
  • the semiconductor substrate 1 will also outgas and diffuse into the getter layer 4, which may cause "poisoning" of the getter.
  • the microbolometer further includes a getter seed layer between the surface of the semiconductor substrate 1 (or other substrate surface) and the getter layer 4 (Fig. 1), that is, the getter layer 4 is in contact with the surface of the semiconductor substrate 1 through the getter seed layer.
  • the getter seed layer is used to prevent poisoning of the getter layer 4 and improve the adhesion between the getter layer 4 and the surface of the semiconductor substrate 1 .
  • the microbolometer that the present application provides also further comprise the getter protection layer 5 that is positioned at the getter layer 4 surface, to take protective measure to film getter layer 4 , to protect the getter layer 4 from oxidation.
  • the getter layer 5 is also set
  • the electromagnetic radiation reflective layer is used to reflect the electromagnetic radiation transmitted by the heat-sensitive layer 8 back into the heat-sensitive layer 8 for secondary absorption by the heat-sensitive layer 8 .
  • the getter protective layer 5 and the thermally sensitive layer 8 constitute an optical resonant cavity, therefore, the distance between the getter protective layer 5 and the thermally sensitive layer 8 is
  • the microbolometer described above detects 1/4 the wavelength of electromagnetic radiation.
  • the getter protective layer 5 is a metal layer with a thickness of 5nm-100nm, and the metal layer includes at least one of platinum, gold, silver, nickel, chromium and aluminum. But it should be noted that, in other embodiments, the getter protective layer 5 is not limited to metal layers such as platinum, gold, silver, nickel, chromium, and aluminum, and can also be the detection electromagnetic radiation of the microbolometer.
  • the reflectivity of electromagnetic radiation in the wavelength range is greater than 90% of other metal protective layers.
  • the getter protective layer 5 has two functions, the first function is to improve the oxidation of the getter layer, and the second function is to act as a reflective layer to ensure the microbolometer Detection accuracy.
  • the invention simplifies the design and type selection of the getter layer in the structural packaging design process of the microbolometer, effectively reduces the size of the entire microbolometer, simplifies its process, and improves the reliability of the product sex.
  • the present application also provides a microbolometer with a two-layer bridge structure as a supporting bridge, as shown in Fig. 6c.
  • the support bridge is a multi-layer support bridge.
  • the microbolometer includes: a semiconductor substrate 21 with a readout circuit, the first region of the surface of the semiconductor substrate 21 has a metal electrode layer 22, and the surface of the second region has a getter layer 24, wherein the metal electrode layer 22 and the getter layer 24 are separated by the first dielectric layer 23, and the supporting bridge includes the topmost bridge 271 on the surface of the semiconductor substrate 21 and the bridge surface on the bottommost bridge
  • the upper bridge (topmost bridge) 272, the pier of the lowest bridge 271 is located at the position of the metal electrode layer 22, and the getter layer 24 has a getter protective layer 25.
  • a metal connection layer is arranged along the pier and the bridge deck of each layer of the supporting bridge, wherein the metal connection layer includes the bottom metal connection layer 291 arranged along the pier and the bridge deck of the bottom bridge 271 and the pier along the top bridge 272 and the topmost metal connection layer 292 provided on the bridge deck.
  • There is a passivation layer for protecting the metal connection layer on the metal connection layer and the passivation layer includes the bottom passivation layer 2101 on the bottom metal connection layer 291, the top metal connection layer 292 and the heat sensitive layer 28 on top passivation layer 2102.
  • the heat sensitive layer 28 is located on the topmost bridge 272 and is in contact with the topmost metal connection layer 292 .
  • the stack around the heat sensitive layer 28 has a release channel 212 that penetrates the topmost passivation layer 2102 , the topmost metal connection layer 292 and the bridge surface of the topmost bridge 272 .
  • getter layer 24 and the getter protective layer 25 in this embodiment are the same as those in FIG. 1 , they will not be repeated in this embodiment.
  • FIG. 4 it is a schematic flowchart of the preparation method of the microbolometer provided in some embodiments of the present application.
  • the present application also provides a preparation method of a microbolometer, which includes:
  • the base is a semiconductor substrate with a built-in readout circuit
  • the first region of the surface of the semiconductor substrate has a metal electrode layer electrically connected to the readout circuit
  • the A getter layer is deposited on a second region of the surface of the semiconductor substrate, the first region being located on the periphery of the second region.
  • the substrate can also be other supporting substrates, so that the MEMS process can be formed thereon. After the MEMS process is completed, the other supporting substrates can be removed, and then the electrodes of the microbolometer and the readout circuit chip Electrode connection.
  • S1 specifically includes:
  • S11 Forming a patterned first dielectric layer on the surface of the semiconductor substrate, the first dielectric layer covers the metal electrode layer and exposes a second region of the semiconductor substrate, the metal electrode layer is located on the outside the second area.
  • S12 Deposit a getter layer on a second region of the surface of the semiconductor substrate exposed by the first dielectric layer.
  • the thickness of the getter layer is 200nm-1000nm, and the getter layer adopts a getter with low activation temperature and high gettering efficiency, such as but not limited to a Zr-Co-RE thin film getter layer.
  • the main material of the getter layer is titanium, zirconium, vanadium, chromium, cobalt, iron, manganese, palladium, barium, aluminum, or a multi-phase alloy composed of these materials and rare metals.
  • S1 before performing S11, S1 further includes S101 and S102.
  • S101 Depositing a first metal material layer on the surface of the semiconductor substrate provided with a readout circuit inside.
  • the material of the first metal layer is generally selected from conductive materials such as aluminum and copper, and its thickness is 50nm-400nm.
  • S102 Etching the first metal material layer to form a metal electrode layer located in the first region on the surface of the semiconductor substrate and electrically connected to the readout circuit, the metal electrode layer exposing the surface of the semiconductor substrate The second area of , the first area is located around the second area.
  • S12 specifically includes S121 and S122.
  • S121 Depositing a getter material layer on the surface of the semiconductor substrate by using one of a physical vapor deposition process, a magnetron sputtering process, and an evaporation process;
  • S122 Pattern the getter material layer by using a Lift-Off process or a photolithography process, so as to form a getter layer located in the second region.
  • S2 Form a support bridge on the base, the support bridge is a single-layer or multi-layer bridge, each bridge includes piers and a bridge deck, the piers of the bottom bridge are located on the surface of the base, and the bottom bridge The bridge deck is located above the getter layer, and between two adjacent bridges, the pier of the upper bridge is located above the bridge deck of the lower bridge.
  • the microbolometer after forming the support layer, the microbolometer further includes S4.
  • S4 Form a metal connection layer arranged along the pier and bridge deck of each bridge of the supporting bridge, the metal connecting layer is in contact with the heat-sensitive layer on the topmost bridge surface, and is formed along the supporting bridge extending to the metal electrode layer and contacting the metal electrode layer.
  • the microbolometer is a single layer supported bridge structure, S2 comprising:
  • S21a forming a sacrificial layer covering the getter layer and having a supporting connection channel on the surface of the semiconductor substrate, where the supporting connecting channel exposes the position where the metal electrode layer is located.
  • S22a Deposit an insulating material capable of absorbing electromagnetic radiation on the surface of the sacrifice layer and in the support connection channel to form a single-layer support bridge.
  • a sacrificial material layer covering the getter layer and the metal electrode layer is formed on the surface of the semiconductor substrate by (spin-coating) deposition and curing processes, and the sacrificial material layer is It is an organic material layer with a thickness of 800nm-2500nm, such as an organic material layer such as polyimide. Then the sacrificial material layer is etched to form a sacrificial layer 6 covering the getter layer and having a supporting connection channel, and the supporting connecting channel is opposite to the metal electrode layer.
  • a support bridge that can absorb electromagnetic radiation is deposited on the surface of the sacrificial layer and in the support connection channel by using a plasma-enhanced chemical vapor deposition process, and the support bridge conforms to the surface of the sacrificial layer, that is, the support bridge A bridge deck extends over the surface of the sacrificial layer (opposite the absorbing layer), and the piers of the support bridges are located in the support connection channels and are conformal to the side walls of the support connection channels.
  • One end of the pier of the supporting bridge is connected to the metal electrode layer, and the other end is connected to the deck of the supporting bridge.
  • one end of the support bridge is connected to the metal electrode layer through the first dielectric layer
  • the S4 includes:
  • S42a Form a metal connection layer on the surface of the second dielectric layer, a part of the metal connection layer is located on the bridge surface of the single-layer support bridge and is in contact with the heat-sensitive layer, and the other part of the metal connection layer is along the The pier of the single-layer support bridge extends to the metal electrode layer and contacts the metal electrode layer.
  • S41a includes:
  • S411a depositing a dielectric film material layer composed of silicon nitride and/or silicon dioxide on the pier, the bridge surface and the heat-sensitive layer of the single-layer support bridge.
  • S412a Etching away the bottom of the pier of the single-layer support bridge and the dielectric film material layer composed of silicon nitride and/or silicon oxide on part of the thermal sensitive layer, to form a patterned second dielectric layer.
  • S42a includes:
  • S421a Form a second metal material layer on the second dielectric layer by using a physical or chemical vapor deposition process.
  • S422a Etching the second metal material layer to form a metal connection layer with one end connected to the heat sensitive layer and the other end connected to the metal electrode layer.
  • the manufacturing method of the microbolometer further includes S9, S10, S11 and S12 after completing S8.
  • S41a includes: first depositing a dielectric film material layer of silicon nitride or silicon dioxide or a combination of both on the support bridge and the thermal sensitive layer, and then etching away the bottom of the support connection channel and part of the material layer on the thermal sensitive layer to form a patterned second dielectric layer. During the patterning of the second dielectric layer, the first dielectric layer on the metal electrode layer will be etched away, so the metal electrode layer is exposed by the patterned second dielectric layer.
  • S42a includes forming a second metal material layer on the third thin film layer by using a physical or chemical vapor deposition process, and then etching the second metal material layer to form one end connected to the heat sensitive layer, The other end is connected to the metal connection layer with the metal electrode layer.
  • the second dielectric layer formed in S41a conforms to the supporting bridge, that is, the second dielectric layer includes a first portion extending along the deck of the supporting bridge, and a second portion extending along the pier of the supporting bridge.
  • a part of the metal connection layer formed in S42a extends on the first part of the second dielectric layer to be electrically connected to the heat-sensitive layer exposed by the second dielectric layer, and another part extends from the first part of the second dielectric layer to the second portion of the second dielectric layer, and continue to extend above the metal electrode layer exposed by the second dielectric layer, so as to be electrically connected to the metal electrode layer.
  • the thickness of the metal electrode layer is 50nm-400nm, and the metal electrode layer includes one of an aluminum layer, a copper layer, a titanium layer and a platinum layer.
  • the constituent material of the metal electrode layer may also be other metal materials with good electrical conductivity.
  • the microbolometer also includes:
  • S5a forming a passivation layer on the second dielectric layer and the metal connection layer.
  • a dielectric thin film of silicon nitride or silicon dioxide or a combination thereof is deposited as a passivation layer on the second dielectric layer and the metal connection layer by plasma enhanced chemical vapor deposition.
  • the microbolometer also includes:
  • S6a Etch the stack around the thermal sensitive layer to form a release channel for exposing the sacrificial layer in the stack, the stack includes the support bridge, the second dielectric layer, the The above metal connection layer and passivation layer.
  • the microbolometer also includes:
  • S7a Encapsulating the microbolometer in a housing by using one of a metal package packaging process, a ceramic package package process, a wafer-level packaging process, and a pixel-level packaging process.
  • S3 includes: using an ion beam deposition process or a physical vapor deposition process to deposit a heat-sensitive material layer on the bridge surface of the topmost bridge of the support bridge, using an ion beam etching process or a reactive ion etching process Patterning the thermally sensitive material layer to form a thermally sensitive layer located on the bridge surface of the topmost bridge of the supporting bridges and opposite to the getter layer.
  • the preparation method further includes S012.
  • S012 Form a getter protection layer opposite to the substrate on the getter layer, the getter protection layer is used to protect the getter layer from oxidation.
  • the getter protective layer is also used to reflect the energy of the electromagnetic radiation transmitted from the heat-sensitive layer to the heat-sensitive layer so as to be absorbed by the heat-sensitive layer, That is, the getter protection layer and the heat-sensitive layer form an optical resonant cavity.
  • the distance between the getter protective layer and the thermally sensitive layer is 1/4 of the wavelength of the detected electromagnetic radiation of the microbolometer.
  • the getter protection layer is a metal layer with a thickness of 5nm-100nm, and the metal layer includes at least one of platinum, gold, and silver.
  • the getter The protective layer may also be other metal protective layers whose reflectivity to the electromagnetic radiation in the wavelength range of the detected electromagnetic radiation of the microbolometer is greater than 90%.
  • the micrometer before forming the getter layer, in order to avoid poisoning of the getter layer and increase the adhesion between the getter layer and the surface of the semiconductor substrate, the micrometer provided by the present application
  • the manufacturing method of the bolometer further includes: depositing and forming a getter seed layer on the second region of the surface of the semiconductor substrate (not shown in FIGS. 1 and 6 c ).
  • the getter layer formed subsequently is made to contact the surface of the semiconductor substrate through the getter seed layer, that is, the getter seed layer is located between the getter layer and the surface of the semiconductor substrate.
  • the support bridge of the microbolometer is a multi-layer support bridge, then S2 includes:
  • S21b Form at least two layers of sacrificial layers sequentially on the surface of the semiconductor substrate, each sacrificial layer has a support connection channel, the sacrificial layer at the bottom layer covers the getter layer and the support of the sacrificial layer at the bottom layer The connection channel exposes the position where the metal electrode layer is located.
  • S22b Depositing an insulating material capable of absorbing electromagnetic radiation on the surface of each layer of the sacrificial layer and in the corresponding supporting connection channel to form each layer of the multi-layer supporting bridge, and the pier of each layer of bridge is located in the corresponding supporting connecting channel, The bridge deck is located on the sacrificial layer surface of the corresponding layer.
  • S4 includes: forming the metal connection layer on the pier and bridge deck surface of each layer of the multi-layer support bridge, the metal connection layer is located at the The bridge deck part of the topmost bridge is in contact with the heat-sensitive layer, and the metal connection layer extends from the bridge deck of the topmost bridge to the metal connection layer along each pier and bridge deck of the multi-layer support bridge in turn.
  • the electrode layer is in contact with the metal electrode layer.
  • the preparation method also includes:
  • S6b Etching the stacked layer around the thermal sensitive layer to form a release channel in the stacked layer, the stacked layer including the passivation layer, the metal connection layer and the bridge surface of the topmost bridge.
  • the preparation method of the microbolometer provided by the present application will be specifically described below by taking the preparation methods of the microbolometer of the single-layer support bridge and the microbolometer of the support bridge on both sides as examples.
  • Figures 5a to 5k provide schematic diagrams of the structures formed in each step of the preparation method provided according to an embodiment of the present application, as follows A method of manufacturing a microbolometer according to another embodiment provided by the present application will be described with reference to FIGS. 5a to 5k.
  • the preparation method specifically includes the following steps:
  • Step 1a As shown in FIG. 5a , deposit a metal layer on the semiconductor substrate 1 , the metal layer is generally made of Al, and then etch on the metal layer to form a metal electrode layer 2 .
  • the metal electrode layer 2 is electrically connected with the readout circuit on the semiconductor substrate 1, and the thickness of the metal electrode layer 2 is 50nm-400nm.
  • Step 2a As shown in FIG. 5b , deposit an insulating dielectric layer 3 (first dielectric layer) on the metal electrode layer 2 , and the insulating dielectric layer 3 plays a role of protecting the metal electrode layer 2 .
  • the material of the insulating medium layer 3 can be thin films such as silicon nitride or silicon dioxide, and the thickness of the insulating medium layer 3 is 10nm-100nm.
  • Step 3a As shown in FIG. 5c, a getter material layer is deposited on the semiconductor substrate 1 by using physical vapor deposition (Physical Vapor Deposition, PVD), magnetron sputtering or evaporation, and then using the Lift-Off process or The getter layer 4 is formed after the photolithography process is patterned. Wherein the getter layer 4 is located directly below the microbolometer, and the graphic shape is not limited, and can be square, rectangular or polygonal, etc., as shown in Fig. 2 and Fig. 3 .
  • the ratio of the area S1 of the getter layer 4 to the area S2 of the surface of the semiconductor substrate 1 occupied by the pixel structure is maximized , that is, S1/S2 in Figure 2 is greater than the preset value.
  • the getter 4 can be selected from materials such as but not limited to titanium, zirconium, vanadium, chromium, cobalt, iron, manganese, palladium, barium, aluminum, or a multiphase alloy composed of these materials and rare metals; the getter Layer 4 has a thickness of 200nm-1000nm.
  • step 3 also includes depositing a metal protective layer on the surface of the getter layer 4 and patterning it to form a getter protective layer 5, which is used to ensure that the getter layer 4 is completely covered by the getter protective layer 5, and the getter
  • the material of the aerosol protection layer 5 can be selected but not limited to Pt, Au, Ag and other metals with high reflectivity at the wavelength of the electromagnetic radiation to be detected.
  • the thickness of the getter protection layer 5 is 5nm-100nm.
  • Step 4a As shown in Figure 5d, centrifuge (spin coating) deposition and solidification on the insulating dielectric layer 3 and the getter protective layer 5 to form an organic sacrificial layer 6.
  • the organic sacrificial layer 6 can be selected from but not limited to polyimide class of organic materials.
  • the organic sacrificial layer 6 acts as a separation layer between the microbolometer and the getter layer 4, and its thickness is 800nm-2500nm, and This layer is removed after the microbolometer is formed.
  • Step 5a As shown in FIG. 5e , the organic sacrificial layer 6 is patterned to form a supporting connection channel T corresponding to the second part of the supporting bridge 7 and the metal electrode layer 2 .
  • Step 6a As shown in Figure 5f, use plasma enhanced chemical vapor deposition (Plasma Enhanced Chemical Vapor Deposition, PECVD) to deposit the support bridge 7, the material of the support bridge can be but not limited to films such as silicon oxide and silicon nitride, to protect Heat-sensitive film and the role of absorbing electromagnetic radiation.
  • the thickness of the supporting bridge 7 is 50nm-500nm.
  • step 6 also includes depositing a heat-sensitive material layer on the support bridge 7 by means of ion beam deposition (Ion Beam Deposition, IBD) or physical vapor deposition (PVD), and then using ion beam etching (Ion Beam Etching, IBE) or reactive ion etching (Reactive Ion Etching, RIE) method to pattern the thermally sensitive material layer to form the thermally sensitive layer 8, the thickness of the thermally sensitive layer 8 is 30nm-100nm.
  • IBD ion Beam Deposition
  • PVD physical vapor deposition
  • RIE reactive ion etching
  • Step 7a As shown in FIG. 5g, deposit a dielectric layer 9 on the heat-sensitive layer 8, which can be but not limited to thin films such as low-stress silicon oxide and silicon nitride.
  • the thickness of the dielectric layer 9 is 10nm-100nm.
  • the dielectric layer 9 and the insulating dielectric layer 3 at the pier position are processed by photolithography or etching, and the photolithography or etching ends at the metal electrode layer 2 electrically connected to the readout circuit, so that the metal electrode layer 2 is The dielectric layer 9 is exposed and exposed.
  • Step 8a As shown in FIG. 5h , the dielectric layer 9 is processed by photolithography or etching, so that part of the heat-sensitive layer 8 is exposed.
  • Step 9a As shown in FIG. 5i , deposit a metal connection material layer by physical vapor deposition (PVD) process.
  • the metal connection material layer is a titanium vanadium thin film with good electrical conductivity and low thermal conductivity, and the thickness of the metal connection layer 10 is 5nm-50nm.
  • the metal connection material layer on the heat sensitive layer film 8 is removed by photolithography or etching, so as to form the metal connection layer 10 .
  • One end of the metal connection layer 10 is connected to the heat-sensitive layer 8, and the other end is connected to the metal electrode layer 2 of the readout circuit on the semiconductor substrate 1, so as to form an electrical path, and complete the readout of the temperature-sensitive electrical signal by the readout circuit , the area of the heat-sensitive layer 8 is slightly smaller than the area of the getter layer 4 below; the distance between the heat-sensitive layer 8 and the getter protective layer has a great influence on the secondary absorption effect of electromagnetic radiation, and the design distance is electromagnetic radiation 1/4 of the wavelength can reflect the electromagnetic radiation energy transmitted from above back to the heat-sensitive layer 8 for secondary absorption, increase the absorption of the reflected electromagnetic radiation energy by the heat-sensitive layer 8, and improve the overall absorption efficiency of electromagnetic radiation.
  • Step 10a As shown in Figure 5j, a passivation layer 11 is deposited on the upper surface of the metal connection layer 10 by methods such as plasma enhanced chemical vapor deposition (PECVD).
  • PECVD plasma enhanced chemical vapor deposition
  • the passivation layer 11 can be but not limited to silicon oxide, silicon nitride and other thin films, the thin film mainly plays the role of protecting the heat sensitive layer 8 and the metal connection layer 10, so as to prevent subsequent processes from affecting the heat sensitive layer 8 and the metal connection layer 10.
  • the thickness of the passivation layer 11 is 10 nm-150 nm.
  • Step 11a As shown in FIG. 5k , pattern the stack formed by the support bridge 7 , the dielectric layer 9 , the metal connection layer 10 and the passivation layer 11 to obtain the release channel 12 of the sacrificial layer.
  • Figures 6a to 6c provide schematic diagrams of partial structures formed in the steps of the preparation method according to another embodiment of the present application, as follows A method for manufacturing a microbolometer according to another embodiment provided by the present application will be described with reference to FIGS. 6 a to 6 c.
  • the preparation method specifically includes the following steps:
  • Step 1b As shown in FIG. 6a , a first dielectric layer 23 is formed on the surface of the semiconductor substrate 21 with the metal electrode layer 22 of the readout circuit, and the region of the getter layer 24 is exposed on the first dielectric layer 23 .
  • Step 2b As shown in FIG. 6a , form a getter layer 24 on the exposed surface of the semiconductor substrate 21 of the first dielectric layer 23 , and form a getter layer protective layer 25 on the surface of the getter layer 24 .
  • Step 3b As shown in FIG. 6a, form the bottom sacrificial layer 261 covering the getter layer 24 and the getter protective layer 25 on the surface of the semiconductor substrate 21, and form the exposed metal electrode in the bottom sacrificial layer 261 Support connection channel at the location of layer 2.
  • Step 4b As shown in FIG. 6a , form the bottom bridge 271 on the surface of the bottom sacrificial layer 261 and its corresponding supporting connection channel.
  • Step 5b As shown in FIG. 6a , form a conformal bottommost metal connection layer 291 on the surface of the bottommost bridge 271 .
  • Step 6b As shown in FIG. 6a , the bottommost passivation layer 2101 is formed on the surface of the bottommost metal connection layer 291 , and the bottommost passivation layer 2101 exposes part of the bottommost metal connection layer 291 .
  • Step 7b As shown in FIG. 6b , form the topmost sacrificial layer 262 on the bottommost sacrificial layer 261 and the bottommost passivation layer 291 , and form an exposed layer in the topmost sacrificial layer 262 that is protected by the bottommost passivation layer.
  • the position where the bottommost metal connection layer 291 of the metallization layer 2101 is exposed supports the connection channel.
  • Step 8b As shown in FIG. 6b , form the topmost bridge 272 in the topmost sacrificial layer 262 and the corresponding supporting connection channels.
  • Step 9b As shown in FIG. 6b , a conformal topmost metal connection layer 292 is formed on the surface of the topmost bridge 272 .
  • Step 10b As shown in FIG. 6b , form a heat-sensitive layer 28 on the bridge surface of the topmost bridge 272 .
  • Step 11b As shown in FIG. 6b , form the topmost passivation layer 2102 on the bridge surface of the topmost bridge 272 , the heat-sensitive layer 28 and the topmost metal connection layer 292 .
  • Step 12b As shown in FIG. 6b , form a release channel 212 in the stack around the heat-sensitive layer 28 , and the release channel runs through the topmost passivation layer 2102 , the topmost metal connection layer 292 and the topmost bridge 272 bridge deck.
  • Step 13b As shown in FIG. 6c , etch away the bottommost sacrificial layer 261 and the topmost sacrificial layer 262 to obtain a microbolometer.
  • the getter layer is made inside the microbolometer, when the microbolometer is packaged to obtain a detector, it can be realized by using different packaging processes, such as Chip-level packaging process, pixel-level packaging process, metal packaging process or ceramic packaging process, etc.
  • the microbolometer structure shown in Fig. Cover the surface of the semiconductor substrate 1 to cover the microbolometer structure shown in 5j, and then form a packaging case 14 on the packaging sacrificial material 13, and the packaging case 14 has a packaging release channel 15 thereon.
  • the preparation method according to the present application further includes removing the sacrificial layer and encapsulating the sacrificial material, the release channel is used as the corresponding release channel when removing the sacrificial layer, and the encapsulating release channel is used as the release channel when removing the encapsulation sacrificial material. Corresponding release channel.
  • the present invention provides a microbolometer for detecting electromagnetic radiation, in which the preparation process of the getter layer is integrated into the MEMS process steps of the traditional microbolometer.
  • the getter adopts a getter with low activation temperature and high suction efficiency, which can be but not limited to Zr-Co-RE thin film getter, and the main material of the getter is titanium, zirconium, vanadium, chromium, cobalt, iron , manganese, palladium, barium, aluminum, or multi-phase alloys composed of these materials and rare metals.
  • a metal protection layer with low activity and high reflectivity is sputtered on the getter by PVD method, and the material of the metal protection layer may be but not limited to metals such as Au or Pt. also.
  • a getter seed layer is arranged between the getter layer and the surface of the semiconductor substrate to prevent poisoning of the getter layer and improve the adhesion between the getter layer and the substrate.
  • the main function of the metal protective layer is to improve the oxidation of the passivation layer of the getter, reduce the oxidation of the getter in the subsequent release process, and at the same time act as a reflective layer to ensure the detection accuracy of the microbolometer.
  • the reflectivity of the metal protective layer is greater than 90% within the wavelength range to be detected. Therefore, the present invention reduces the size and production cost of the entire detector by optimizing the getter design of the microbolometer, and significantly improves the production efficiency and reliability of the microbolometer.

Abstract

The present application provides a microbolometer and a preparation method therefor. In the microbolometer, a getter layer is integrated on a substrate below a bridge surface of a support bridge for supporting a thermally sensitive layer, and the microbolometer and the getter layer can be prepared by using an MEMS process, thereby facilitating optimizing the preparation process of the microbolometer. In addition, the getter layer is arranged inside the microbolometer, so that the microbolometer is not limited by the complexity of a packaging structure and the difficulty of a packaging process, the efficiency of production of the microbolometer can be effectively improved, and the production cost is reduced.

Description

微测辐射热计及其制备方法Microbolometer and its preparation method 技术领域technical field
本申请涉及微机电系统工艺半导体制备技术领域,尤其涉及一种微测辐射热计及其制备方法。The present application relates to the technical field of microelectromechanical system process semiconductor preparation, in particular to a microbolometer and a preparation method thereof.
背景技术Background technique
近年来,得益于夜视、安检的需求,以非制冷红外探测器和太赫兹探测器为代表的热成像技术在军品、商业、工业等方面发展迅速,特别是在全球范围内新冠疫情大爆发的影响下,热成像技术在医疗、测温等领域有广泛的需求和应用。非制冷红外探测器和太赫兹探测器,都是基于微测辐射热计的基本原理,利用光热效应,吸收入射电磁辐射,引起内部热敏材料的温度变化,将电磁辐射转换为电信号进行成像的探测器。In recent years, thanks to the needs of night vision and security checks, thermal imaging technology represented by uncooled infrared detectors and terahertz detectors has developed rapidly in military, commercial, and industrial fields, especially in the context of the global COVID-19 pandemic. Under the influence of the outbreak, thermal imaging technology has a wide range of needs and applications in the fields of medical treatment and temperature measurement. Both uncooled infrared detectors and terahertz detectors are based on the basic principle of microbolometers, using the photothermal effect to absorb incident electromagnetic radiation, causing temperature changes in internal heat-sensitive materials, and converting electromagnetic radiation into electrical signals for imaging of detectors.
微测辐射热计是建立在读出电路的硅基板上,通过微机电系统(MEMS,Micro-Electro-Mechanical System)工艺制备出一系列结构相同的悬空的微桥结构,一般由热敏感层、支撑腿、互联导线和基底等部分组成。为保证探测器的灵敏度,微测辐射热计都需要放置于密封腔内,并利用吸气剂来维持密封腔的真空度(一般小于10-3mbar),以减少热传导和热对流造成的辐射热量的损失。The microbolometer is built on the silicon substrate of the readout circuit, and a series of suspended micro-bridge structures with the same structure are prepared through the micro-electro-mechanical system (MEMS, Micro-Electro-Mechanical System) process. It consists of supporting legs, interconnecting wires and substrates. In order to ensure the sensitivity of the detector, the microbolometer needs to be placed in the sealed cavity, and the getter is used to maintain the vacuum degree of the sealed cavity (generally less than 10-3mbar), so as to reduce the radiation heat caused by heat conduction and heat convection Loss.
目前吸气剂的制备工艺都是与微测辐射热计的制备工艺分开的,不利于降低微测辐射热计的封装成本。At present, the preparation process of the getter is separated from the preparation process of the microbolometer, which is not conducive to reducing the packaging cost of the microbolometer.
技术问题technical problem
为了解决现有存在的技术问题,本发明实施例提供了一种尺寸小、生产成本低的微测辐射热计及其制备方法。In order to solve the existing technical problems, an embodiment of the present invention provides a microbolometer with small size and low production cost and a preparation method thereof.
技术解决方案technical solution
本发明实施例第一方面提供了一种微测辐射热计,包括:The first aspect of the embodiment of the present invention provides a microbolometer, comprising:
位于基底上的支撑桥,所述支撑桥为单层或多层桥,每层桥包括桥墩和桥面,最底层桥的桥墩位于所述基底表面上,相邻的两层桥之间,上一层桥的所述桥墩位于下一层桥的所述桥面上方;A support bridge located on a base, the support bridge is a single-layer or multi-layer bridge, each layer of bridges includes piers and bridge decks, the piers of the bottommost bridge are located on the surface of the base, between adjacent two-layer bridges, the upper The piers of the bridge on one level are located above the deck of the bridge on the next level;
位于所述基底表面上,且位于所述最底层桥的所述桥面下方的吸气剂层;a getter layer on the surface of the substrate and below the deck of the bottommost bridge;
位于最顶层桥的桥面上的热敏感层。Heat-sensitive layer on the deck of the topmost bridge.
本发明实施例第二方面提供了一种微测辐射热计的制备方法,包括:The second aspect of the embodiment of the present invention provides a method for preparing a microbolometer, including:
在基底上沉积吸气剂层;depositing a getter layer on the substrate;
在所述基底上形成支撑桥,所述支撑桥为单层或多层桥,每层桥包括桥墩和桥面,最底层桥的桥墩位于所述基底表面上,所述最底层桥的桥面位于所述吸气剂层上方,相邻的两层桥之间,上一层桥的所述桥墩位于下一层桥的所述桥面上方;Form a support bridge on the base, the support bridge is a single-layer or multi-layer bridge, each layer of bridge includes piers and bridge decks, the piers of the bottom bridge are located on the base surface, and the bridge deck of the bottom bridge Located above the getter layer, between two adjacent bridges, the pier of the upper bridge is located above the bridge deck of the lower bridge;
在最顶层桥的桥面上沉积热敏感层。A thermally sensitive layer is deposited on the bridge surface of the topmost bridge.
有益效果Beneficial effect
上述实施例所提供的微测辐射热计中将吸气剂层集成在用于支撑热敏感层的支撑桥的桥面下方的基底上,可以采用MEMS工艺制备微测辐射热计以及吸气剂层,有利于优化微测辐射热计的制备工艺。此外,由于吸气剂层设置在微测辐射剂内部,使微测辐射热计不受封装结构复杂度和封装工艺难度的限制,可有效的提高微测辐射热计生产效率,并降低生产成本。In the microbolometer provided in the above embodiments, the getter layer is integrated on the substrate under the bridge deck of the support bridge used to support the heat-sensitive layer, and the microbolometer and the getter can be prepared by MEMS technology layer, which is conducive to optimizing the preparation process of the microbolometer. In addition, since the getter layer is arranged inside the microbolometer, the microbolometer is not limited by the complexity of the packaging structure and the difficulty of the packaging process, which can effectively improve the production efficiency of the microbolometer and reduce the production cost .
附图说明Description of drawings
图1为依据本申请一实施例提供的微测辐射热计的示意图;Fig. 1 is a schematic diagram of a microbolometer provided according to an embodiment of the present application;
图2为依据本申请一实施例提供的微测辐射热计中的吸气剂层与基底层俯视示意图;Fig. 2 is a schematic top view of a getter layer and a base layer in a microbolometer according to an embodiment of the present application;
图3为依据本申请另一实施例提供的微测辐射热计中的吸气剂层与基底层俯视示意图;Fig. 3 is a schematic top view of a getter layer and a base layer in a microbolometer according to another embodiment of the present application;
图4为依据本申请一实施例提供的微测辐射热计的制备方法流程示意图;Fig. 4 is a schematic flow chart of a preparation method of a microbolometer according to an embodiment of the present application;
图5a至图5k为依据本申请一实施例提供的微测辐射热计的制备方法的制备过程中形成的各个结构的示意图;5a to 5k are schematic diagrams of various structures formed during the preparation process of the microbolometer preparation method provided according to an embodiment of the present application;
图6a至图6c为依据本申请另一实施例提供的微测辐射热计的制备方法的 制备过程中形成的部分结构的示意图;6a to 6c are schematic diagrams of partial structures formed during the preparation process of the microbolometer preparation method provided according to another embodiment of the present application;
图7为依据本申请提供的微测辐射热计封装结构示意图。Fig. 7 is a schematic diagram of the packaging structure of the microbolometer provided according to the present application.
本发明的实施方式Embodiments of the present invention
以下结合说明书附图及具体实施例对本申请技术方案做进一步的详细阐述。The technical solution of the present application will be further elaborated below in combination with the accompanying drawings and specific embodiments.
除非另有定义,本文所使用的所有的技术和科学术语与属于本申请的技术领域的技术人员通常理解的含义相同。本文中在本申请的说明书中所使用的术语只是为了描述具体的实施例的目的,不是旨在于限制本申请的实现方式。本文所使用的术语“及/或”包括一个或多个相关的所列项目的任意的和所有的组合。Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the technical field to which this application belongs. The terms used herein in the description of the application are only for the purpose of describing specific embodiments, and are not intended to limit the implementation of the application. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
在本申请的描述中,需要理解的是,术语“中心”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。在本申请的描述中,除非另有说明,“多个”的含义是两个或两个以上。In the description of this application, it is to be understood that the terms "center", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", The orientations or positional relationships indicated by "top", "bottom", "inner", "outer", etc. are based on the orientations or positional relationships shown in the drawings, and are only for the convenience of describing the application and simplifying the description, rather than indicating or implying References to devices or elements must have a particular orientation, be constructed, and operate in a particular orientation and therefore should not be construed as limiting the application. In the description of the present application, unless otherwise specified, "plurality" means two or more.
在本申请的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本申请中的具体含义。In the description of this application, it should be noted that unless otherwise specified and limited, the terms "installation", "connection", and "connection" should be understood in a broad sense, for example, it can be a fixed connection or a detachable connection. Connected, or integrally connected; it can be directly connected, or indirectly connected through an intermediary, and it can be the internal communication of two elements. Those of ordinary skill in the art can understand the specific meanings of the above terms in this application according to specific situations.
本申请提供了一种微测辐射热计,主要包括基底、吸气剂层、支撑层和热敏感层。其中,The application provides a microbolometer, which mainly includes a substrate, a getter layer, a support layer and a heat sensitive layer. in,
所述支撑桥位于基底上,所述支撑桥为单层或多层桥,每层桥包括桥墩和桥面,最底层桥的桥墩位于所述基底表面上,相邻的两层桥之间,上一层桥的所述桥墩位于下一层桥的所述桥面上方,所述吸气剂层位于所述基底表面上,且位于所述最底层桥的所述桥面下方的吸气剂层,位于最顶层桥的桥面上的热敏感层。The supporting bridge is located on the base, the supporting bridge is a single-layer or multi-layer bridge, each layer of bridges includes piers and bridge decks, and the piers of the bottommost bridge are located on the surface of the base, between adjacent two-layer bridges, The piers of the bridge on the upper level are located above the deck of the bridge on the next level, the getter layer is located on the surface of the base, and the getter layer located below the deck of the bridge on the lowest level layer, the thermally sensitive layer on the deck of the topmost bridge.
在一些实施例中,所述基底为内设读出电路的半导体衬底。所述基底为内设读出电路的半导体衬底,所述半导体衬底表面的第一区域具有与所述读出电路电连接的金属电极层,所述最底层桥的桥墩位于所述金属电极层上,所述吸 气剂层位于所述半导体衬底表面的第二区域,且所述第一区域位于所述第二区域外围。因此,在一些实施例中,所述微测辐射热计还包括沿所述支撑桥的每层桥的桥墩和桥面设置的金属连接层,所述金属连接层在所述最顶层桥面上与所述热敏感层接触,并沿所述支撑桥延伸至所述金属电极层处与所述金属电极层接触。所述金属连接层用于将热敏感层和所述金属电极层电连接,从而实现读出电路读出所述微测辐射热计的探测信息。在其它实施例中,所述基底也可以为其它支撑基底,以便在其上形成MEMS工艺,在完成MEMS工艺后,可以将其它支撑基底去除,再将微测辐射热计的电极引出与读出电路芯片的电极连接。In some embodiments, the substrate is a semiconductor substrate with built-in readout circuits. The base is a semiconductor substrate with a built-in readout circuit, the first region on the surface of the semiconductor substrate has a metal electrode layer electrically connected to the readout circuit, and the pier of the bottommost bridge is located on the metal electrode layer. layer, the getter layer is located in the second region of the surface of the semiconductor substrate, and the first region is located in the periphery of the second region. Therefore, in some embodiments, the microbolometer further comprises a metal connecting layer disposed along the piers and the deck of each bridge of the supporting bridge, the metal connecting layer being on the topmost bridge deck It is in contact with the thermal sensitive layer, and extends along the support bridge to the metal electrode layer in contact with the metal electrode layer. The metal connection layer is used to electrically connect the thermal sensitive layer and the metal electrode layer, so as to realize the readout circuit to read out the detection information of the microbolometer. In other embodiments, the substrate can also be other supporting substrates, so that the MEMS process can be formed on it. After the MEMS process is completed, the other supporting substrates can be removed, and then the electrodes of the microbolometer can be drawn out and read out. Electrode connection of circuit chip.
本申请提供的微测辐射热计中将吸气剂层集成在用于支撑热敏感层的支撑桥的桥面下方的基底上,可以采用MEMS工艺制备微测辐射热计以及吸气剂层,有利于优化微测辐射热计的制备工艺。此外,由于吸气剂层设置在微测辐射剂内部,可优化微测辐射热计的像素结构,使微测辐射热计不受封装结构复杂度和封装工艺难度的限制,可有效的提高微测辐射热计生产效率,并降低生产成本。In the microbolometer provided by the present application, the getter layer is integrated on the substrate under the bridge deck of the support bridge used to support the heat-sensitive layer, and the microbolometer and the getter layer can be prepared by MEMS technology, It is beneficial to optimize the preparation process of the microbolometer. In addition, because the getter layer is arranged inside the microbolometer, the pixel structure of the microbolometer can be optimized, so that the microbolometer is not limited by the complexity of the packaging structure and the difficulty of the packaging process, and the microbolometer can be effectively improved. Measure bolometer production efficiency and reduce production costs.
本申请提供的微测辐射热计适应于单层支撑桥结构和多层支撑桥结构,下面分别以单层支撑桥结构的微测辐射热计(如图5a至5l所示)和多层支撑桥结构的微测辐射热计(如图6a-6c所示)为例进一步具体阐述本申请提供的微测辐射热计及其制备方法。这里需要说明的是,本申请仅以单层和两层支撑桥结构的微测辐射热计为例进行说明,但本申请同样三层或三层以上的支撑桥结构的微测辐射热计。The microbolometer provided by the application is suitable for single-layer support bridge structure and multi-layer support bridge structure. The microbolometer with a bridge structure (as shown in FIGS. 6a-6c ) is taken as an example to further specifically illustrate the microbolometer provided in the present application and its preparation method. It should be noted here that this application only uses microbolometers with single-layer and two-layer support bridge structures as examples, but this application also applies to microbolometers with three or more layers of support bridge structures.
本申请提供了一种用于检测电磁辐射的微测辐射热计及其制备方法,下面将结合图1至图4以及图5a至图5k具体阐述本申请内容。The present application provides a microbolometer for detecting electromagnetic radiation and a preparation method thereof, and the content of the present application will be described in detail below with reference to FIGS. 1 to 4 and FIGS. 5a to 5k.
如图1所示,在一些实施例中,本申请提供的微测辐射热计包括位于基底1上的支撑桥7,所述支撑桥7为单层支撑桥,其由桥墩和桥面构成,所述桥墩将所述桥面支撑在所述基底1上;以及包括位于所述基底1表面上,且位于所述支撑桥7的桥面下方的吸气剂层4,所述微测辐射热计还包括位于所述支撑桥7的桥面上的热敏感层8。进一步的,所述支撑桥7的桥面与所述吸气剂层4相互间隔,所述支撑桥的桥墩的高度大于所述吸气剂层的厚度。As shown in FIG. 1 , in some embodiments, the microbolometer provided by the present application includes a support bridge 7 on the substrate 1, the support bridge 7 is a single-layer support bridge, which is composed of piers and bridge decks, The bridge pier supports the bridge deck on the base 1; and includes a getter layer 4 located on the surface of the base 1 and below the bridge deck of the supporting bridge 7, the microbolometric The gauge also includes a thermally sensitive layer 8 located on the bridge surface of the supporting bridge 7 . Further, the deck of the support bridge 7 is spaced from the getter layer 4 , and the height of the pier of the support bridge is greater than the thickness of the getter layer.
需要说明的是,图1仅示意了微辐射热计的一个像元结构,但本申请提供的微测辐射热计可包括位于所述基底上的多个所述像元结构,每一个所述像元结 构包括所述支撑桥7、所述吸气剂层4以及所述热敏感层8。在一些实施例中,在每一个所述像元结构中,所述支撑桥7的桥墩位于所述吸气剂层4的外围。It should be noted that Fig. 1 only illustrates one pixel structure of the microbolometer, but the microbolometer provided in the present application may include a plurality of the pixel structures on the substrate, each of which The pixel structure includes the support bridge 7 , the getter layer 4 and the thermal sensitive layer 8 . In some embodiments, in each of the pixel structures, the piers of the supporting bridges 7 are located at the periphery of the getter layer 4 .
在一些实施例中,本申请提供的微测辐射热计中的支撑桥7为厚度为50nm-500nm且可吸收电磁辐射的氮化硅或二氧化硅或其二者组合的介质薄膜薄膜层,该薄膜层为弯折的薄膜层,其水平部分为所述支撑桥7的桥面,弯折部分为所述支撑桥7的桥墩,所述支撑桥7除了起支撑所述热敏感层8作用外,还起到保护热敏感层8和吸收电磁辐射的作用。In some embodiments, the supporting bridge 7 in the microbolometer provided by the present application is a dielectric thin film layer of silicon nitride or silicon dioxide or a combination thereof with a thickness of 50nm-500nm and which can absorb electromagnetic radiation, The film layer is a bent film layer, its horizontal part is the bridge deck of the supporting bridge 7, and the bent part is the pier of the supporting bridge 7, and the supporting bridge 7 plays the role of supporting the heat sensitive layer 8 In addition, it also plays the role of protecting the heat-sensitive layer 8 and absorbing electromagnetic radiation.
在一些实施例中,所述热敏感层8的厚度为30nm-100nm氧化钒热敏薄膜层,而在其它实施例中,所述热敏感层8也可以为对热敏感的其它薄膜材料层。In some embodiments, the heat-sensitive layer 8 has a thickness of 30nm-100nm vanadium oxide heat-sensitive thin film layer, while in other embodiments, the heat-sensitive layer 8 can also be a layer of other heat-sensitive thin film materials.
进一步的,继续参考图1所示,在本实施例中,基底1为内设读出电路的半导体衬底。半导体衬底1表面的第一区域具有与所述读出电路电连接的金属电极层2。所述第一区域设置在半导体衬底1表面的边缘,以便于最大化吸气剂层4所在的第二区域的面积。所述金属电极层2的厚度为50nm-400nm,所述金属电极层2包括铝层或铜层之一。在其它实施例中,基底1也可以为其它支撑基底,以便在其上形成MEMS工艺,在完成MEMS工艺后,可以将其它支撑基底去除,再将微测辐射热计的电极引出与读出电路芯片的电极连接。Further, continuing to refer to FIG. 1 , in this embodiment, the substrate 1 is a semiconductor substrate with a built-in readout circuit. The first region on the surface of the semiconductor substrate 1 has a metal electrode layer 2 electrically connected to the readout circuit. The first region is arranged at the edge of the surface of the semiconductor substrate 1 in order to maximize the area of the second region where the getter layer 4 is located. The thickness of the metal electrode layer 2 is 50nm-400nm, and the metal electrode layer 2 includes one of aluminum layer or copper layer. In other embodiments, the substrate 1 can also be other supporting substrates, so that the MEMS process can be formed thereon. After the MEMS process is completed, the other supporting substrates can be removed, and then the electrodes of the microbolometer can be drawn out to the readout circuit. The electrodes of the chip are connected.
在一些实施例中,为了避免金属电极层2在后续形成吸气剂层4的过程中被破坏,微测辐射热计还包括位于所述半导体衬底1上的第一介质层3,第一介质层3的部分设置在金属电极层2与吸气剂层4之间的这一部分半导体衬底1表面上,以将金属电极层2和吸气剂层4隔离。所述支撑桥7的桥墩将其支撑桥7的桥面与所述金属电极层2连接。即支撑桥7的桥墩的位置与金属电极层2的位置对应设置。在一些实施例中,第一介质层3的厚度为10nm-100nm的绝缘介质层,该绝缘介质层为氮化硅或二氧化硅等薄膜层。In some embodiments, in order to prevent the metal electrode layer 2 from being damaged during the subsequent formation of the getter layer 4, the microbolometer further includes a first dielectric layer 3 on the semiconductor substrate 1, the first Part of the dielectric layer 3 is disposed on the part of the surface of the semiconductor substrate 1 between the metal electrode layer 2 and the getter layer 4 to isolate the metal electrode layer 2 from the getter layer 4 . The piers of the supporting bridge 7 connect the bridge surface of the supporting bridge 7 with the metal electrode layer 2 . That is, the positions of the piers of the supporting bridge 7 are set corresponding to the positions of the metal electrode layer 2 . In some embodiments, the first dielectric layer 3 is an insulating dielectric layer with a thickness of 10 nm-100 nm, and the insulating dielectric layer is a thin film layer such as silicon nitride or silicon dioxide.
所述吸气剂层4与所述金属电极层2位于所述半导体衬底1相同的表面,且所述金属电极层2位于所述吸气剂层4的外围。即金属电极层2位于所述半导体衬底1表面的第一区域上,吸气剂层4可以位于半导体衬底1表面的第二区域上,所述第一区域位于所述第二区域外围,以最大化吸气剂层4面积与每个上述像元结构占所述半导体衬底1表面的面积之间的比值S1/S2。如图2所示,其为图1中的吸气剂层4与半导体衬底1的俯视示意图,其中,S1为吸气剂层4的面积,S2为每个上述像元结构占所述半导体衬底1表面的面积。为了尽可能的提高吸气剂层4的 吸气量,需要使S1/S2大于预设值。可通过合理的布局将吸气剂层4与金属电极层2在半导体衬底1表面的位置及形状来最大化S1/S2。吸气剂层4的形状可为正方形、长方形或多边形,也可以为其它非几何形状,如吸气剂层4的另一形状设置如图3所示。The getter layer 4 and the metal electrode layer 2 are located on the same surface of the semiconductor substrate 1 , and the metal electrode layer 2 is located on the periphery of the getter layer 4 . That is, the metal electrode layer 2 is located on the first area of the surface of the semiconductor substrate 1, the getter layer 4 may be located on the second area of the surface of the semiconductor substrate 1, and the first area is located on the periphery of the second area, To maximize the ratio S1/S2 between the area of the getter layer 4 and the area of each pixel structure occupying the surface of the semiconductor substrate 1 . As shown in Figure 2, it is a top view schematic diagram of the getter layer 4 and the semiconductor substrate 1 in Figure 1, wherein, S1 is the area of the getter layer 4, and S2 is the area of each of the above-mentioned pixel structures occupying the semiconductor substrate 1. The area of the surface of the substrate 1. In order to improve the gettering capacity of the getter layer 4 as much as possible, it is necessary to make S1/S2 greater than the preset value. The position and shape of the getter layer 4 and the metal electrode layer 2 on the surface of the semiconductor substrate 1 can be maximized through a reasonable layout. The shape of the getter layer 4 can be square, rectangular or polygonal, or other non-geometric shapes. For example, another shape setting of the getter layer 4 is shown in FIG. 3 .
继续参考图1所示,所述微测辐射热计还包括位于所述支撑桥7上的第二介质层9、位于所述第二介质层9上的金属连接层10以及位于所述第二介质层9和所述金属连接层10上的钝化层11。其中,所述第二介质层10裸露所述金属电极层2和所述热敏感层8,以便金属连接层10将金属电极层2与热敏感层8进行连接,以形成电学的通路,完成读出电路对热敏感层产生的热敏信号的读取。在一些实施例中,热敏感层8的面积略小于位于其下方的吸气剂层4的面积。其中,第二介质层9与支撑桥7共形,即第二介质层9包括沿所述支撑桥7的桥面延伸的第一部分,以及沿支撑桥7的桥墩延伸的第二部分。金属连接层10的一部分在第二介质层9的第一部分上延伸,以与被所述第二介质层9裸露的热敏感层电连接,另一部分由所述第二介质层9的第一部分延伸至所述第二介质层9的第二部分,并继续延伸至被所述第二介质层裸露的所述金属电极层2上方,以与所述金属电极层2电连接。在一些实施例中,所述金属电极层2的厚度为50nm-400nm,所述金属电极层2包括铝层、铜层、钛层和铂层之一。在其它实施例中,所述金属电极层2的构成材料也可以为其它导电性良好的金属材料。Continuing to refer to FIG. 1, the microbolometer also includes a second dielectric layer 9 on the support bridge 7, a metal connection layer 10 on the second dielectric layer 9, and a metal connection layer on the second dielectric layer 9. The passivation layer 11 on the dielectric layer 9 and the metal connection layer 10 . Wherein, the second dielectric layer 10 exposes the metal electrode layer 2 and the heat-sensitive layer 8, so that the metal connection layer 10 connects the metal electrode layer 2 and the heat-sensitive layer 8 to form an electrical path to complete the reading process. The output circuit reads the thermal signal generated by the thermal sensitive layer. In some embodiments, the area of the thermally sensitive layer 8 is slightly smaller than the area of the getter layer 4 below it. Wherein, the second dielectric layer 9 conforms to the supporting bridge 7 , that is, the second dielectric layer 9 includes a first portion extending along the deck of the supporting bridge 7 and a second portion extending along the pier of the supporting bridge 7 . A part of the metal connection layer 10 extends on the first part of the second dielectric layer 9 to be electrically connected to the exposed heat-sensitive layer of the second dielectric layer 9, and another part extends from the first part of the second dielectric layer 9 to the second part of the second dielectric layer 9 , and continue to extend above the metal electrode layer 2 exposed by the second dielectric layer, so as to be electrically connected to the metal electrode layer 2 . In some embodiments, the thickness of the metal electrode layer 2 is 50nm-400nm, and the metal electrode layer 2 includes one of an aluminum layer, a copper layer, a titanium layer and a platinum layer. In other embodiments, the constituent material of the metal electrode layer 2 may also be other metal materials with good electrical conductivity.
在一些实施例中,所述第二介质层9为厚度为10nm-100nm的低应力的薄膜层,如氧化硅、氮化硅等硅基等。In some embodiments, the second dielectric layer 9 is a low-stress film layer with a thickness of 10 nm-100 nm, such as silicon oxide, silicon nitride, and other silicon-based layers.
在一些实施例中,所述金属连接层10的厚度为5nm-50nm,且所述金属连接层为导电性较好且导热性较小的金属层,例如其包括钛、钒中的至少一种。In some embodiments, the thickness of the metal connection layer 10 is 5nm-50nm, and the metal connection layer is a metal layer with good electrical conductivity and low thermal conductivity, for example, it includes at least one of titanium and vanadium .
在一些实施例中,所述钝化层11为厚度为10nm-150nm的薄膜层,如氧化硅、氮化硅等硅基等。In some embodiments, the passivation layer 11 is a thin film layer with a thickness of 10 nm-150 nm, such as silicon oxide, silicon nitride, and other silicon-based layers.
在一些实施例中,由于吸气剂层集成在所述微测辐射热计内部。因此,本申请提供的微测辐射热计的封装结构不做限定,如封装结构为金属管壳封装结构、陶瓷管壳封装结构、晶圆级封装结构和像素级封装结构中之一。In some embodiments, since the getter layer is integrated inside the microbolometer. Therefore, the package structure of the microbolometer provided in the present application is not limited, for example, the package structure is one of a metal package package structure, a ceramic package package structure, a wafer-level package structure and a pixel-level package structure.
进一步的,图1所示的微测辐射热计还具有设置在位于所述热敏感层8周围的叠层中的释放通道12,以用于释放微测辐射热计形成过程中的牺牲层(在微 测辐射热计制备完成后已被去除)。其中,位于所述热敏感层8周围的叠层包括所述支撑桥7的桥面、所述第二介质层9、所述金属连接层10以及所述钝化层11。Further, the microbolometer shown in FIG. 1 also has a release channel 12 disposed in the stack around the heat-sensitive layer 8, for releasing the sacrificial layer ( removed after microbolometer preparation). Wherein, the stacked layers around the thermal sensitive layer 8 include the bridge surface of the supporting bridge 7 , the second dielectric layer 9 , the metal connection layer 10 and the passivation layer 11 .
在本申请提供的微测辐射热计中,吸气剂层4采用激活温度低、吸气效率高的吸气剂,例如可以是但不限于Zr-Co-RE系薄膜吸气剂层。在一些实施例中,吸气剂层4的主体材料选用钛、锆、钒、铬、钴、铁、锰、钯、钡、铝,或者这些材料和稀有金属组成的多相合金。由于薄膜吸气剂层具有较大的活性比表面积,接触到空气或氧化性气体,薄膜吸气剂层的主体容易饱和吸附或氧化,尤其在微测辐射热计形成过程中的牺牲层释放时,薄膜吸气剂层容易被活性较高的等离子体氧化,这会降低吸气剂层4的吸气性能甚至失去吸气能力。此外,在微测辐射热计的激活过程中,半导体衬底1也会放气并向吸气剂层4内部扩散,可能会导致吸气剂的“中毒”。In the microbolometer provided in this application, the getter layer 4 adopts a getter with low activation temperature and high getter efficiency, such as but not limited to a Zr-Co-RE thin film getter layer. In some embodiments, the main material of the getter layer 4 is titanium, zirconium, vanadium, chromium, cobalt, iron, manganese, palladium, barium, aluminum, or a multi-phase alloy composed of these materials and rare metals. Due to the large active specific surface area of the thin film getter layer, the main body of the thin film getter layer is easily saturated, adsorbed or oxidized when exposed to air or oxidizing gases, especially when the sacrificial layer is released during the formation of the microbolometer , the thin-film getter layer is easily oxidized by the plasma with higher activity, which will reduce the getter performance of the getter layer 4 or even lose the getter ability. In addition, during the activation process of the microbolometer, the semiconductor substrate 1 will also outgas and diffuse into the getter layer 4, which may cause "poisoning" of the getter.
因此,在一些实施例中,所述微测辐射热计还进一步包括位于所述半导体衬底1表面(或其它基底表面)与所述吸气剂层4之间的吸气剂种子层(图1中未示意),即所述吸气剂层4通过所述吸气剂种子层与所述半导体衬底1表面接触。所述吸气剂种子层用于防止吸气剂层4中毒,并提高吸气剂层4与半导体衬底1表面的附着力。Therefore, in some embodiments, the microbolometer further includes a getter seed layer between the surface of the semiconductor substrate 1 (or other substrate surface) and the getter layer 4 (Fig. 1), that is, the getter layer 4 is in contact with the surface of the semiconductor substrate 1 through the getter seed layer. The getter seed layer is used to prevent poisoning of the getter layer 4 and improve the adhesion between the getter layer 4 and the surface of the semiconductor substrate 1 .
以及,继续参考图1所示,在本申请提供的微测辐射热计中,还进一步包括位于吸气剂层4表面的吸气剂保护层5,以对薄膜吸气剂层4采取保护措施,保护吸气剂层4不被氧化。And, continue to refer to shown in Fig. 1, in the microbolometer that the present application provides, also further comprise the getter protection layer 5 that is positioned at the getter layer 4 surface, to take protective measure to film getter layer 4 , to protect the getter layer 4 from oxidation.
此外为了进一步提高微测辐射热计的探测性能,需要对热敏感层8透射出的电磁辐射进行反射,因此在本申请提供的微测辐射热计中,还将所述吸气剂层5设置为电磁辐射反射层,以将热敏感层8透射出的电磁辐射进行反射回热敏感层8中,以供热敏感层8二次吸收。In addition, in order to further improve the detection performance of the microbolometer, it is necessary to reflect the electromagnetic radiation transmitted by the heat-sensitive layer 8, so in the microbolometer provided by the application, the getter layer 5 is also set The electromagnetic radiation reflective layer is used to reflect the electromagnetic radiation transmitted by the heat-sensitive layer 8 back into the heat-sensitive layer 8 for secondary absorption by the heat-sensitive layer 8 .
具体的,在本实施例中,所述吸气剂保护层5与所述热敏感层8构成光学谐振腔,因此,吸气剂保护层5与所述热敏感层8之间的距离为所述微测辐射热计的探测电磁辐射波长的1/4。所述吸气剂保护层5为厚度为5nm-100nm的金属层,该金属层包括铂、金、银、镍、铬以及铝中的至少一种。但需要说明的是,在其它实施例中,吸气剂保护层5不限于铂、金、银、镍、铬以及铝等金属层,也可以为对所述微测辐射热计的探测电磁辐射波长范围的电磁辐射的反射率大于90%其它金属保护层。Specifically, in this embodiment, the getter protective layer 5 and the thermally sensitive layer 8 constitute an optical resonant cavity, therefore, the distance between the getter protective layer 5 and the thermally sensitive layer 8 is The microbolometer described above detects 1/4 the wavelength of electromagnetic radiation. The getter protective layer 5 is a metal layer with a thickness of 5nm-100nm, and the metal layer includes at least one of platinum, gold, silver, nickel, chromium and aluminum. But it should be noted that, in other embodiments, the getter protective layer 5 is not limited to metal layers such as platinum, gold, silver, nickel, chromium, and aluminum, and can also be the detection electromagnetic radiation of the microbolometer. The reflectivity of electromagnetic radiation in the wavelength range is greater than 90% of other metal protective layers.
因此,在本申请中,吸气剂保护层5有两个作用,第一个作用是改善吸气剂层被氧化的状况,第二个作用是充当反射层,确保了微测辐射热计的检测精度。本发明简化了微测辐射热计的结构封装设计过程中吸气剂层的设计和选型,有效的减小整个微测辐射热计的的尺寸,以及简化其工艺过程,提高了产品的可靠性。Therefore, in the present application, the getter protective layer 5 has two functions, the first function is to improve the oxidation of the getter layer, and the second function is to act as a reflective layer to ensure the microbolometer Detection accuracy. The invention simplifies the design and type selection of the getter layer in the structural packaging design process of the microbolometer, effectively reduces the size of the entire microbolometer, simplifies its process, and improves the reliability of the product sex.
本申请还提供了一种支撑桥为两层桥结构的微测辐射热计,具体如图6c所示。与图1所示的微测辐射热计不同的是,在本实施例中,所述支撑桥为多层支撑桥。The present application also provides a microbolometer with a two-layer bridge structure as a supporting bridge, as shown in Fig. 6c. Different from the microbolometer shown in FIG. 1 , in this embodiment, the support bridge is a multi-layer support bridge.
请参考图6c,所述微测辐射热计包括:具有读出电路的半导体衬底21,所述半导体衬底21的表面第一区域具有金属电极层22,第二区域表面具有吸气剂层24,其中,金属电极层22与吸气剂层24之间由第一介质层23隔离,所述支撑桥包括位于半导体衬底21表面的最顶底层桥271和位于最底层桥的桥面上的上一层桥(最顶层桥)272,最底层桥271的桥墩位于所述金属电极层22所在位置处,吸气剂层24上具有吸气剂保护层25。沿支撑桥各层的桥墩和桥面设置有金属连接层,其中,所述金属连接层包括沿最底层桥271的桥墩和桥面设置的最底层金属连接层291和沿最顶层桥272的桥墩和桥面设置的最顶层金属连接层292。所述金属连接层上具有用于保护金属连接层的钝化层,所述钝化层包括位于最底层金属连接层291上的最底层钝化层2101以及最顶层金属连接层292和热敏感层28上的最顶层钝化层2102。所述热敏感层28位于最顶层桥272上,且与最顶层金属连接层292接触。热敏感层28周围的叠层具有释放通道212,所述释放通道贯穿最顶层钝化层2102、最顶层金属连接层292以及最顶层桥272的桥面。Please refer to FIG. 6c, the microbolometer includes: a semiconductor substrate 21 with a readout circuit, the first region of the surface of the semiconductor substrate 21 has a metal electrode layer 22, and the surface of the second region has a getter layer 24, wherein the metal electrode layer 22 and the getter layer 24 are separated by the first dielectric layer 23, and the supporting bridge includes the topmost bridge 271 on the surface of the semiconductor substrate 21 and the bridge surface on the bottommost bridge The upper bridge (topmost bridge) 272, the pier of the lowest bridge 271 is located at the position of the metal electrode layer 22, and the getter layer 24 has a getter protective layer 25. A metal connection layer is arranged along the pier and the bridge deck of each layer of the supporting bridge, wherein the metal connection layer includes the bottom metal connection layer 291 arranged along the pier and the bridge deck of the bottom bridge 271 and the pier along the top bridge 272 and the topmost metal connection layer 292 provided on the bridge deck. There is a passivation layer for protecting the metal connection layer on the metal connection layer, and the passivation layer includes the bottom passivation layer 2101 on the bottom metal connection layer 291, the top metal connection layer 292 and the heat sensitive layer 28 on top passivation layer 2102. The heat sensitive layer 28 is located on the topmost bridge 272 and is in contact with the topmost metal connection layer 292 . The stack around the heat sensitive layer 28 has a release channel 212 that penetrates the topmost passivation layer 2102 , the topmost metal connection layer 292 and the bridge surface of the topmost bridge 272 .
由于本实施例中的吸气剂层24与吸气剂保护层25与图1中的相同,本实施例中不再累述。Since the getter layer 24 and the getter protective layer 25 in this embodiment are the same as those in FIG. 1 , they will not be repeated in this embodiment.
此外,如图4所示,其为本申请一些实施例提供的微测辐射热计的制备方法流程示意图。本申请还提供了微测辐射热计的制备方法,其包括:In addition, as shown in FIG. 4 , it is a schematic flowchart of the preparation method of the microbolometer provided in some embodiments of the present application. The present application also provides a preparation method of a microbolometer, which includes:
S1:在基底上沉积吸气剂层。S1: Depositing a getter layer on a substrate.
具体的,在一本实施例中,所述基底为内设读出电路的半导体衬底,所述半导体衬底表面的第一区域具有与所述读出电路电连接的金属电极层,所述吸气剂层沉积在半导体衬底表面的第二区域,所述第一区域位于所述第二区域外围。在其它实施例中,基底也可以为其它支撑基底,以便在其上形成MEMS工 艺,在完成MEMS工艺后,可以将其它支撑基底去除,再将微测辐射热计的电极与读出电路芯片的电极连接。在本实施例中,S1具体包括:Specifically, in one embodiment, the base is a semiconductor substrate with a built-in readout circuit, the first region of the surface of the semiconductor substrate has a metal electrode layer electrically connected to the readout circuit, the A getter layer is deposited on a second region of the surface of the semiconductor substrate, the first region being located on the periphery of the second region. In other embodiments, the substrate can also be other supporting substrates, so that the MEMS process can be formed thereon. After the MEMS process is completed, the other supporting substrates can be removed, and then the electrodes of the microbolometer and the readout circuit chip Electrode connection. In this embodiment, S1 specifically includes:
S11:在所述半导体衬底表面形成图案化的第一介质层,所述第一介质层覆盖所述金属电极层且裸露所述半导体衬底的第二区域,所述金属电极层位于所述第二区域外围。S11: Forming a patterned first dielectric layer on the surface of the semiconductor substrate, the first dielectric layer covers the metal electrode layer and exposes a second region of the semiconductor substrate, the metal electrode layer is located on the outside the second area.
S12:在被所述第一介质层裸露的所述半导体衬底表面的第二区域沉积吸气剂层。S12: Deposit a getter layer on a second region of the surface of the semiconductor substrate exposed by the first dielectric layer.
所述吸气剂层的厚度为200nm-1000nm,且吸气剂层采用激活温度低、吸气效率高的吸气剂,例如可以是但不限于Zr-Co-RE系薄膜吸气剂层。在一些实施例中,吸气剂层的主体材料选用钛、锆、钒、铬、钴、铁、锰、钯、钡、铝,或者这些材料和稀有金属组成的多相合金。The thickness of the getter layer is 200nm-1000nm, and the getter layer adopts a getter with low activation temperature and high gettering efficiency, such as but not limited to a Zr-Co-RE thin film getter layer. In some embodiments, the main material of the getter layer is titanium, zirconium, vanadium, chromium, cobalt, iron, manganese, palladium, barium, aluminum, or a multi-phase alloy composed of these materials and rare metals.
在一些实施例中,在进行S11之前,S1还包括S101、S102。In some embodiments, before performing S11, S1 further includes S101 and S102.
S101:在内设有读出电路的半导体衬底表面沉积第一金属材料层。S101: Depositing a first metal material layer on the surface of the semiconductor substrate provided with a readout circuit inside.
第一金属层材料一般选用铝、铜等导电性材料,其厚度为50nm-400nm。The material of the first metal layer is generally selected from conductive materials such as aluminum and copper, and its thickness is 50nm-400nm.
S102:蚀刻所述第一金属材料层,以形成位于所述半导体衬底表面的第一区域且与所述读出电路电连接的金属电极层,所述金属电极层裸露所述半导体衬底表面的第二区域,所述第一区域位于所述第二区域周围。S102: Etching the first metal material layer to form a metal electrode layer located in the first region on the surface of the semiconductor substrate and electrically connected to the readout circuit, the metal electrode layer exposing the surface of the semiconductor substrate The second area of , the first area is located around the second area.
则在S1中,所述第一介质层覆盖所述金属电极层,并至少裸露部分所述第二区域。因此,S12具体包括S121、S122。Then in S1, the first dielectric layer covers the metal electrode layer and exposes at least part of the second region. Therefore, S12 specifically includes S121 and S122.
S121:采用物理气相沉积工艺、磁控溅射工艺和蒸镀工艺中之一在所述半导体衬底表面沉积吸气剂材料层;S121: Depositing a getter material layer on the surface of the semiconductor substrate by using one of a physical vapor deposition process, a magnetron sputtering process, and an evaporation process;
S122:利用Lift-Off工艺或光刻工艺图案化所述吸气剂材料层,以形成位于所述第二区域的吸气剂层。S122: Pattern the getter material layer by using a Lift-Off process or a photolithography process, so as to form a getter layer located in the second region.
S2:在所述基底上形成支撑桥,所述支撑桥为单层或多层桥,每层桥包括桥墩和桥面,最底层桥的桥墩位于所述基底表面上,所述最底层桥的桥面位于所述吸气剂层上方,相邻的两层桥之间,上一层桥的所述桥墩位于下一层桥的所述桥面上方。S2: Form a support bridge on the base, the support bridge is a single-layer or multi-layer bridge, each bridge includes piers and a bridge deck, the piers of the bottom bridge are located on the surface of the base, and the bottom bridge The bridge deck is located above the getter layer, and between two adjacent bridges, the pier of the upper bridge is located above the bridge deck of the lower bridge.
S3:在最顶层桥的桥面上沉积热敏感层。S3: Depositing a thermally sensitive layer on the bridge surface of the topmost bridge.
在一些实施例中,在形成所述支撑层后,所述微测辐射热计还包括S4。In some embodiments, after forming the support layer, the microbolometer further includes S4.
S4:形成沿所述支撑桥的每层桥的桥墩和桥面设置的金属连接层,所述金属连接层在所述最顶层桥面上与所述热敏感层接触,并沿所述支撑桥延伸至所述金属电极层处与所述金属电极层接触。S4: Form a metal connection layer arranged along the pier and bridge deck of each bridge of the supporting bridge, the metal connecting layer is in contact with the heat-sensitive layer on the topmost bridge surface, and is formed along the supporting bridge extending to the metal electrode layer and contacting the metal electrode layer.
在一些实施例中,微测辐射热计为单层支撑桥结构,S2包括:In some embodiments, the microbolometer is a single layer supported bridge structure, S2 comprising:
S21a:在所述半导体衬底表面上形成覆盖所述吸气剂层且具有支撑连接通道的牺牲层,所述支撑连接通道裸露所述金属电极层所在的位置。S21a: forming a sacrificial layer covering the getter layer and having a supporting connection channel on the surface of the semiconductor substrate, where the supporting connecting channel exposes the position where the metal electrode layer is located.
S22a:在所述牲层表面以及所述支撑连接通道中沉积可吸收电磁辐射的绝缘材料,以形成单层支撑桥。S22a: Deposit an insulating material capable of absorbing electromagnetic radiation on the surface of the sacrifice layer and in the support connection channel to form a single-layer support bridge.
具体的,在一些实施例中,先利用(旋涂)沉积、固化工艺在所述半导体衬底表面形成覆盖所述吸气剂层和所述金属电极层的牺牲材料层,所述牺牲材料层为厚度为800nm-2500nm的有机材料层,如聚酰亚胺之类的有机材料层。然后在蚀刻所述牺牲材料层,以形成覆盖所述吸剂层且具有支撑连接通道的牺牲层6,所述支撑连接通道与所述金属电极层相对。Specifically, in some embodiments, a sacrificial material layer covering the getter layer and the metal electrode layer is formed on the surface of the semiconductor substrate by (spin-coating) deposition and curing processes, and the sacrificial material layer is It is an organic material layer with a thickness of 800nm-2500nm, such as an organic material layer such as polyimide. Then the sacrificial material layer is etched to form a sacrificial layer 6 covering the getter layer and having a supporting connection channel, and the supporting connecting channel is opposite to the metal electrode layer.
利用等离子体增强化学气相沉积工艺在所述牺牲层表面以及所述支撑连接通道中沉积可吸收电磁辐射的支撑桥,所述支撑桥与所述牺牲层的表面共形,即所述支撑桥的桥面在所述牺牲层的表面(与吸收层相对)延伸,所述支撑桥的桥墩位于所述支撑连接通道中,且与所述支撑连接通道的侧壁共形。所述支撑桥的桥墩一端与所述金属电极层连接,另一端与所述支撑桥的桥面连接。具体的,所述支撑桥的一端通过所述第一介质层与所述金属电极层连接A support bridge that can absorb electromagnetic radiation is deposited on the surface of the sacrificial layer and in the support connection channel by using a plasma-enhanced chemical vapor deposition process, and the support bridge conforms to the surface of the sacrificial layer, that is, the support bridge A bridge deck extends over the surface of the sacrificial layer (opposite the absorbing layer), and the piers of the support bridges are located in the support connection channels and are conformal to the side walls of the support connection channels. One end of the pier of the supporting bridge is connected to the metal electrode layer, and the other end is connected to the deck of the supporting bridge. Specifically, one end of the support bridge is connected to the metal electrode layer through the first dielectric layer
在单层支撑桥的微测辐射热计中,S4包括:Among microbolometers for single-layer support bridges, the S4 includes:
S41a:在所述单层支撑桥的桥面形成所述热敏感层之后,在所述单层支撑桥的桥墩、桥面和所述热敏感层上形成第二介质层,所述第二介质层裸露部分所述热敏感层和所述金属电极层所在的位置。S41a: After the heat-sensitive layer is formed on the bridge deck of the single-layer support bridge, a second medium layer is formed on the pier, the bridge deck, and the heat-sensitive layer of the single-layer support bridge, and the second medium layer The exposed part of the layer is where the heat-sensitive layer and the metal electrode layer are located.
S42a:在所述第二介质层表面形成金属连接层,所述金属连接层的一部分位于所述单层支撑桥的桥面并与所述热敏感层接触,所述金属连接层的另一部分沿所述单层支撑桥的桥墩延伸至所述金属电极层处与所述金属电极层接触。S42a: Form a metal connection layer on the surface of the second dielectric layer, a part of the metal connection layer is located on the bridge surface of the single-layer support bridge and is in contact with the heat-sensitive layer, and the other part of the metal connection layer is along the The pier of the single-layer support bridge extends to the metal electrode layer and contacts the metal electrode layer.
进一步的,S41a包括:Further, S41a includes:
S411a:在所述单层支撑桥的桥墩、桥面和所述热敏感层上沉积氮化硅和/或二氧化硅构成的介质薄膜材料层。S411a: depositing a dielectric film material layer composed of silicon nitride and/or silicon dioxide on the pier, the bridge surface and the heat-sensitive layer of the single-layer support bridge.
S412a:蚀刻掉所述单层支撑桥的桥墩的底部和部分所述热敏感层上的氮化硅和/或氧化硅构成的介质薄膜材料层,形成图案化的第二介质层。S412a: Etching away the bottom of the pier of the single-layer support bridge and the dielectric film material layer composed of silicon nitride and/or silicon oxide on part of the thermal sensitive layer, to form a patterned second dielectric layer.
进一步的,S42a包括:Further, S42a includes:
S421a:利用物理或化学气相沉积工艺在所述第二介质层上形成第二金属材料层。S421a: Form a second metal material layer on the second dielectric layer by using a physical or chemical vapor deposition process.
S422a:蚀刻所述第二金属材料层,形成一端与所述热敏感层连接,另一端与所述金属电极层连接的金属连接层。S422a: Etching the second metal material layer to form a metal connection layer with one end connected to the heat sensitive layer and the other end connected to the metal electrode layer.
在一些实施例中,如图5所示,微测辐射热计的制备方法在完成S8后还进一步包括S9、S10、S11以及S12。In some embodiments, as shown in FIG. 5 , the manufacturing method of the microbolometer further includes S9, S10, S11 and S12 after completing S8.
S9:在所述支撑桥和所述热敏感层上形成图案化的第二介质层,所述第二介质层裸露所述金属电极层和所述热敏感层。S9: forming a patterned second dielectric layer on the supporting bridge and the thermal sensitive layer, the second dielectric layer exposing the metal electrode layer and the thermal sensitive layer.
在一些实施例中,S41a包括:先在所述支撑桥和所述热敏感层上沉积氮化硅或二氧化硅或其二者组合的介质薄膜材料层,然后蚀刻掉所述支撑连接通道底部和部分所述热敏感层上的材料层,形成图案化的第二介质层。在图案化所述第二介质层期间,还会将所述金属电极层上的第一介质层刻蚀掉,因此所述金属电极层被图案化的所述第二介质层裸露。In some embodiments, S41a includes: first depositing a dielectric film material layer of silicon nitride or silicon dioxide or a combination of both on the support bridge and the thermal sensitive layer, and then etching away the bottom of the support connection channel and part of the material layer on the thermal sensitive layer to form a patterned second dielectric layer. During the patterning of the second dielectric layer, the first dielectric layer on the metal electrode layer will be etched away, so the metal electrode layer is exposed by the patterned second dielectric layer.
在一些实施例中,S42a包括利用物理或化学气相沉积工艺在所述第三薄膜层上形成第二金属材料层,然后蚀刻所述第二金属材料层,形成一端与所述热敏感层连接,另一端与所述金属电极层连接的金属连接层。In some embodiments, S42a includes forming a second metal material layer on the third thin film layer by using a physical or chemical vapor deposition process, and then etching the second metal material layer to form one end connected to the heat sensitive layer, The other end is connected to the metal connection layer with the metal electrode layer.
在S41a中形成的所述第二介质层与支撑桥共形,即第二介质层包括沿所述支撑桥的桥面延伸的第一部分,以及包括沿支撑桥的桥墩延伸的第二部分。S42a中形成的金属连接层的一部分在第二介质层的第一部分上延伸,以与被所述第二介质层裸露的热敏感层电连接,另一部分由所述第二介质层的第一部分延伸至所述第二介质层的第二部分,并继续延伸至被所述第二介质层裸露的所述金属电极层上方,以与所述金属电极层电连接。在一些实施例中,所述金属电极层的厚度为50nm-400nm,所述金属电极层包括铝层、铜层、钛层和铂层之一。在其它实施例中,所述金属电极层的构成材料也可以为其它导电性良好的金属材料。The second dielectric layer formed in S41a conforms to the supporting bridge, that is, the second dielectric layer includes a first portion extending along the deck of the supporting bridge, and a second portion extending along the pier of the supporting bridge. A part of the metal connection layer formed in S42a extends on the first part of the second dielectric layer to be electrically connected to the heat-sensitive layer exposed by the second dielectric layer, and another part extends from the first part of the second dielectric layer to the second portion of the second dielectric layer, and continue to extend above the metal electrode layer exposed by the second dielectric layer, so as to be electrically connected to the metal electrode layer. In some embodiments, the thickness of the metal electrode layer is 50nm-400nm, and the metal electrode layer includes one of an aluminum layer, a copper layer, a titanium layer and a platinum layer. In other embodiments, the constituent material of the metal electrode layer may also be other metal materials with good electrical conductivity.
进一步的,在完成S42a后,所述微测辐射热计还包括:Further, after completing S42a, the microbolometer also includes:
S5a:在所述第二介质层和所述金属连接层上形成钝化层。S5a: forming a passivation layer on the second dielectric layer and the metal connection layer.
具体的,在所述第二介质层和所述金属连接层上利用等离子增强化学气相沉积法沉积氮化硅或二氧化硅或其二者组合的介质薄膜作为钝化层。Specifically, a dielectric thin film of silicon nitride or silicon dioxide or a combination thereof is deposited as a passivation layer on the second dielectric layer and the metal connection layer by plasma enhanced chemical vapor deposition.
进一步的,在完成S5a后,所述微测辐射热计还包括:Further, after completing S5a, the microbolometer also includes:
S6a:蚀刻所述热敏感层周围的叠层,以在所述叠层中形成用于裸露所述牺牲层的释放通道,所述叠层包括所述支撑桥、所述第二介质层、所述金属连接层和钝化层。S6a: Etch the stack around the thermal sensitive layer to form a release channel for exposing the sacrificial layer in the stack, the stack includes the support bridge, the second dielectric layer, the The above metal connection layer and passivation layer.
进一步的,在完成S6a后,所述微测辐射热计还包括:Further, after completing S6a, the microbolometer also includes:
S7a:采用金属管壳封装工艺、陶瓷管壳封装工艺、晶圆级封装工艺和像素级封装工艺中之一将所述微测辐射热计封装于外壳中。S7a: Encapsulating the microbolometer in a housing by using one of a metal package packaging process, a ceramic package package process, a wafer-level packaging process, and a pixel-level packaging process.
在一些实施例中,S3包括:利用离子束沉积工艺或物理气相沉积工艺在所述支撑桥的最顶层桥的桥面上沉积热敏感材料层,利用离子束刻蚀工艺或反应离子刻蚀工艺图案化所述热敏感材料层,以形成位于所述支撑桥的最顶层桥的桥面上,且与所述吸气剂层相对的热敏感层。In some embodiments, S3 includes: using an ion beam deposition process or a physical vapor deposition process to deposit a heat-sensitive material layer on the bridge surface of the topmost bridge of the support bridge, using an ion beam etching process or a reactive ion etching process Patterning the thermally sensitive material layer to form a thermally sensitive layer located on the bridge surface of the topmost bridge of the supporting bridges and opposite to the getter layer.
在一些实施例中,在完成所述S1之后以及进行S2之前,所述制备方法还包括S012。In some embodiments, after completing S1 and before performing S2, the preparation method further includes S012.
S012:在所述吸气剂层上形成与所述基底相对的吸气剂保护层,所述吸气剂保护层用于保护所述吸气剂层不被氧化。S012: Form a getter protection layer opposite to the substrate on the getter layer, the getter protection layer is used to protect the getter layer from oxidation.
具体的,在一些实施例中,所述吸气剂保护层还用于将从所述热敏感层透射出的电磁辐射的能量反射到所述热敏感层,以被所述热敏感层吸收,即所述吸气剂保护层与所述热敏感层构成光学谐振腔。因此,在一些实施例中,所述吸气剂保护层与所述热敏感层之间的距离为所述微测辐射热计的探测电磁辐射波长的1/4。Specifically, in some embodiments, the getter protective layer is also used to reflect the energy of the electromagnetic radiation transmitted from the heat-sensitive layer to the heat-sensitive layer so as to be absorbed by the heat-sensitive layer, That is, the getter protection layer and the heat-sensitive layer form an optical resonant cavity. Thus, in some embodiments, the distance between the getter protective layer and the thermally sensitive layer is 1/4 of the wavelength of the detected electromagnetic radiation of the microbolometer.
在一些实施例中,所述吸气剂保护层为厚度为5nm-100nm的金属层,所述金属层包括铂、金、银中的至少一种,在其它实施例中,所述吸气剂保护层也可以为对所述微测辐射热计的探测电磁辐射波长范围的电磁辐射的反射率大于90%其它金属保护层。In some embodiments, the getter protection layer is a metal layer with a thickness of 5nm-100nm, and the metal layer includes at least one of platinum, gold, and silver. In other embodiments, the getter The protective layer may also be other metal protective layers whose reflectivity to the electromagnetic radiation in the wavelength range of the detected electromagnetic radiation of the microbolometer is greater than 90%.
此外,在一些实施例中,在形成所述吸气剂层之前,为了避免吸气剂层中毒以及增加所述吸气剂层与半导体衬底表面之间的附着力,本申请提供的微测 辐射热计的制备方法还包括:在所述半导体衬底表面的第二区域上沉积形成吸气剂种子层(图1和6c中未示意出)。使得后续形成的所述吸气剂层通过所述吸气剂种子层与所述半导体衬底表面接触,即所述吸气剂种子层位于所述吸气剂层与半导体衬底表面之间。In addition, in some embodiments, before forming the getter layer, in order to avoid poisoning of the getter layer and increase the adhesion between the getter layer and the surface of the semiconductor substrate, the micrometer provided by the present application The manufacturing method of the bolometer further includes: depositing and forming a getter seed layer on the second region of the surface of the semiconductor substrate (not shown in FIGS. 1 and 6 c ). The getter layer formed subsequently is made to contact the surface of the semiconductor substrate through the getter seed layer, that is, the getter seed layer is located between the getter layer and the surface of the semiconductor substrate.
在一些实施例中,所述微测辐射热计的支撑桥为多层支撑桥,则S2包括:In some embodiments, the support bridge of the microbolometer is a multi-layer support bridge, then S2 includes:
S21b:在所述半导体衬底表面依次形成至少两层牺牲层,每一次层牺牲层均具有支撑连接通道,最底层所述牺牲层覆盖所述吸气剂层且所述最底层牺牲层的支撑连接通道裸露所述金属电极层所在的位置。S21b: Form at least two layers of sacrificial layers sequentially on the surface of the semiconductor substrate, each sacrificial layer has a support connection channel, the sacrificial layer at the bottom layer covers the getter layer and the support of the sacrificial layer at the bottom layer The connection channel exposes the position where the metal electrode layer is located.
S22b:在每层所述牺牲层表面和对应的支撑连接通道中沉积可吸收电磁辐射的绝缘材料,形成多层支撑桥的每一层桥,每层桥的桥墩位于对应的支撑连接通道中,桥面位于对应层的所述牺牲层表面。S22b: Depositing an insulating material capable of absorbing electromagnetic radiation on the surface of each layer of the sacrificial layer and in the corresponding supporting connection channel to form each layer of the multi-layer supporting bridge, and the pier of each layer of bridge is located in the corresponding supporting connecting channel, The bridge deck is located on the sacrificial layer surface of the corresponding layer.
进一步的,在多层支撑桥的微测辐射热计中,S4包括:在所述多层支撑桥的每层桥的桥墩和桥面表面形成所述金属连接层,所述金属连接层位于所述最顶层桥的桥面部分与所述热敏感层接触,所述金属连接层由所述最顶层桥的桥面依次沿所述多层支撑桥的每层桥墩和桥面延伸至所述金属电极层处与所述金属电极层接触。Further, in the microbolometer of the multi-layer support bridge, S4 includes: forming the metal connection layer on the pier and bridge deck surface of each layer of the multi-layer support bridge, the metal connection layer is located at the The bridge deck part of the topmost bridge is in contact with the heat-sensitive layer, and the metal connection layer extends from the bridge deck of the topmost bridge to the metal connection layer along each pier and bridge deck of the multi-layer support bridge in turn. The electrode layer is in contact with the metal electrode layer.
进一步的,在完成S4之后,所述制备方法还包括:Further, after completing S4, the preparation method also includes:
S5b:在所述金属连接层上形成钝化层。S5b: forming a passivation layer on the metal connection layer.
S6b:蚀刻所述热敏感层周围的叠层,以在所述叠层中形成释放通道,所述叠层包括所述钝化层、所述金属连接层以及所述最顶层桥的桥面。S6b: Etching the stacked layer around the thermal sensitive layer to form a release channel in the stacked layer, the stacked layer including the passivation layer, the metal connection layer and the bridge surface of the topmost bridge.
下面分别以单层支撑桥的微测辐射热计和两侧支撑桥的微测辐射热计的制备方法为例具体阐述本申请提供的微测辐射热计的制备方法。The preparation method of the microbolometer provided by the present application will be specifically described below by taking the preparation methods of the microbolometer of the single-layer support bridge and the microbolometer of the support bridge on both sides as examples.
为了进一步清楚描述本申请提供的具有单层支撑桥的微测辐射热计的制备方法,图5a至5k提供了依据本申请一实施例提供的制备方法各个步骤中形成的各结构的示意图,下面将结合图5a至图5k描述依据本申请提供的另一实施例的微测辐射热计的制备方法。在本实施例中,所述制备方法具体包括以下步骤:In order to further clearly describe the preparation method of the microbolometer with a single-layer support bridge provided by the present application, Figures 5a to 5k provide schematic diagrams of the structures formed in each step of the preparation method provided according to an embodiment of the present application, as follows A method of manufacturing a microbolometer according to another embodiment provided by the present application will be described with reference to FIGS. 5a to 5k. In this embodiment, the preparation method specifically includes the following steps:
步骤1a:如图5a所示,在半导体衬底1上沉积金属层,该金属层材料一般选用Al,然后在该金属层上进行刻蚀形成金属电极层2。其中,金属电极层2与半导体衬底1上的读出电路电连接,金属电极层2厚度为50nm-400nm。Step 1a: As shown in FIG. 5a , deposit a metal layer on the semiconductor substrate 1 , the metal layer is generally made of Al, and then etch on the metal layer to form a metal electrode layer 2 . Wherein, the metal electrode layer 2 is electrically connected with the readout circuit on the semiconductor substrate 1, and the thickness of the metal electrode layer 2 is 50nm-400nm.
步骤2a:如图5b所示,在金属电极层2上沉积绝缘介质层3(第一介质层),该绝缘介质层3起到保护金属电极层2的作用。绝缘介质层3的材料可以选用氮化硅或二氧化硅等薄膜,绝缘介质层3的厚度为10nm-100nm。Step 2a: As shown in FIG. 5b , deposit an insulating dielectric layer 3 (first dielectric layer) on the metal electrode layer 2 , and the insulating dielectric layer 3 plays a role of protecting the metal electrode layer 2 . The material of the insulating medium layer 3 can be thin films such as silicon nitride or silicon dioxide, and the thickness of the insulating medium layer 3 is 10nm-100nm.
步骤3a:如图5c所示,在半导体衬底1上采用物理气相沉积(Physical Vapor Deposition,PVD)、磁控溅射或蒸镀的工艺沉积吸气剂材料层,然后利用Lift-Off工艺或光刻工艺进行图形化后形成吸气剂层4。其中吸气剂层4位于微测辐射热计的正下方,图形形状不受限制,可以是正方形、长方形或多边形等,如图2和图3所示。通过金属电极层2和吸气剂层4的位置和形状的合理设置,使得吸气剂层4的面积S1与所述像元结构占所述半导体衬底1的表面的面积S2之比最大化,即图中2中的S1/S2大于预设值。具体的,吸气剂4可选用但不限于钛、锆、钒、铬、钴、铁、锰、钯、钡、铝等材料,或选用这些材料和稀有金属组成的多相合金;吸气剂层4的厚度为200nm-1000nm。此外,步骤3还包括在吸气剂层4的表面沉积金属保护层,并图形化以形成吸气剂保护层5,用于保证吸气剂层4被吸气剂保护层5完全覆盖,吸气剂保护层5的材料可以选用但不限于Pt、Au、Ag等在待检测电磁辐射波长反射率较高的金属。吸气剂保护层5的厚度为5nm-100nm。Step 3a: As shown in FIG. 5c, a getter material layer is deposited on the semiconductor substrate 1 by using physical vapor deposition (Physical Vapor Deposition, PVD), magnetron sputtering or evaporation, and then using the Lift-Off process or The getter layer 4 is formed after the photolithography process is patterned. Wherein the getter layer 4 is located directly below the microbolometer, and the graphic shape is not limited, and can be square, rectangular or polygonal, etc., as shown in Fig. 2 and Fig. 3 . Through rational setting of the position and shape of the metal electrode layer 2 and the getter layer 4, the ratio of the area S1 of the getter layer 4 to the area S2 of the surface of the semiconductor substrate 1 occupied by the pixel structure is maximized , that is, S1/S2 in Figure 2 is greater than the preset value. Specifically, the getter 4 can be selected from materials such as but not limited to titanium, zirconium, vanadium, chromium, cobalt, iron, manganese, palladium, barium, aluminum, or a multiphase alloy composed of these materials and rare metals; the getter Layer 4 has a thickness of 200nm-1000nm. In addition, step 3 also includes depositing a metal protective layer on the surface of the getter layer 4 and patterning it to form a getter protective layer 5, which is used to ensure that the getter layer 4 is completely covered by the getter protective layer 5, and the getter The material of the aerosol protection layer 5 can be selected but not limited to Pt, Au, Ag and other metals with high reflectivity at the wavelength of the electromagnetic radiation to be detected. The thickness of the getter protection layer 5 is 5nm-100nm.
步骤4a:如图5d所示,在绝缘介质层3和吸气剂保护层5上离心(旋涂)沉积、固化形成有机牺牲层6,有机牺牲层6可以选用但不限于聚酰亚胺之类的有机材料。以保证对金属电极层2和吸气剂保护层5的良好覆盖,有机牺牲层6起将微测辐射热计与吸气剂层4之间进行分离层作用,其厚度为800nm-2500nm,且该层在微测辐射热计形成后被去除。Step 4a: As shown in Figure 5d, centrifuge (spin coating) deposition and solidification on the insulating dielectric layer 3 and the getter protective layer 5 to form an organic sacrificial layer 6. The organic sacrificial layer 6 can be selected from but not limited to polyimide class of organic materials. In order to ensure good coverage of the metal electrode layer 2 and the getter protective layer 5, the organic sacrificial layer 6 acts as a separation layer between the microbolometer and the getter layer 4, and its thickness is 800nm-2500nm, and This layer is removed after the microbolometer is formed.
步骤5a:如图5e所示,对有机牺牲层6进行图形化处理,形成与支撑桥7的第二部分、金属电极层2对应的支撑连接通道T。Step 5a: As shown in FIG. 5e , the organic sacrificial layer 6 is patterned to form a supporting connection channel T corresponding to the second part of the supporting bridge 7 and the metal electrode layer 2 .
步骤6a:如图5f所示,用等离子体增强化学气相沉积(Plasma Enhanced Chemical Vapor Deposition,PECVD)沉积支撑桥7,支撑桥材料可以是但不限于氧化硅、氮化硅等薄膜,起到保护热敏薄膜和吸收电磁辐射的作用。支撑桥7厚度为50nm-500nm。Step 6a: As shown in Figure 5f, use plasma enhanced chemical vapor deposition (Plasma Enhanced Chemical Vapor Deposition, PECVD) to deposit the support bridge 7, the material of the support bridge can be but not limited to films such as silicon oxide and silicon nitride, to protect Heat-sensitive film and the role of absorbing electromagnetic radiation. The thickness of the supporting bridge 7 is 50nm-500nm.
此外,在步骤6还包括在支撑桥7上用离子束沉积(Ion Beam Deposition,IBD)或物理气相沉积(PVD)的方法沉积热敏感材料层,然后再用离子束刻蚀(Ion  Beam Etching,IBE)或反应离子刻蚀(Reactive Ion Etching,RIE)的方法图形化热敏感材料层,形成热敏感层8,热敏感层8的厚度为30nm-100nm。In addition, step 6 also includes depositing a heat-sensitive material layer on the support bridge 7 by means of ion beam deposition (Ion Beam Deposition, IBD) or physical vapor deposition (PVD), and then using ion beam etching (Ion Beam Etching, IBE) or reactive ion etching (Reactive Ion Etching, RIE) method to pattern the thermally sensitive material layer to form the thermally sensitive layer 8, the thickness of the thermally sensitive layer 8 is 30nm-100nm.
步骤7a:如图5g所示,在热敏感层8上沉积介质层9,其可以但不限于低应力氧化硅、氮化硅等薄膜,介质层9的厚度为10nm-100nm,对支撑桥7的桥墩位置处的介质层9和绝缘介质层3通过光刻或刻蚀的方法处理,光刻或刻蚀终止于与读出电路电连接的金属电极层2,目的是使金属电极层2被介质层9裸露裸漏出来。Step 7a: As shown in FIG. 5g, deposit a dielectric layer 9 on the heat-sensitive layer 8, which can be but not limited to thin films such as low-stress silicon oxide and silicon nitride. The thickness of the dielectric layer 9 is 10nm-100nm. The dielectric layer 9 and the insulating dielectric layer 3 at the pier position are processed by photolithography or etching, and the photolithography or etching ends at the metal electrode layer 2 electrically connected to the readout circuit, so that the metal electrode layer 2 is The dielectric layer 9 is exposed and exposed.
步骤8a:如图5h所示,对介质层9通过光刻或刻蚀的方法处理,使部分热敏感层8裸漏出来。Step 8a: As shown in FIG. 5h , the dielectric layer 9 is processed by photolithography or etching, so that part of the heat-sensitive layer 8 is exposed.
步骤9a:如图5i所示,用物理气相沉积(PVD)工艺沉积金属连接材料层。金属连接材料层为导电性较好、热导较小的钛钒薄膜,金属连接层10的厚度为5nm-50nm。并对热敏层薄膜8上的金属连接材料层进行光刻或刻蚀的方法处理去除,以形成金属连接层10。金属连接层10的一端与热敏感层8连接,另一端与半导体衬底1上的读出电路的金属电极层2相连,以形成电学的通路,完成读出电路对热敏电信号的读取,热敏感层8的面积略小于下方吸气剂层4的面积;热敏感层8与吸气剂保护层之间的距离对电磁辐射的二次吸收效果有较大影响,设计距离为电磁辐射波长的1/4,可将从上方透射来的电磁辐射能量反射回热敏感层8进行二次吸收,增加热敏感层8对反射回来的电磁辐射能量的吸收,提高电磁辐射的整体吸收效率。Step 9a: As shown in FIG. 5i , deposit a metal connection material layer by physical vapor deposition (PVD) process. The metal connection material layer is a titanium vanadium thin film with good electrical conductivity and low thermal conductivity, and the thickness of the metal connection layer 10 is 5nm-50nm. And the metal connection material layer on the heat sensitive layer film 8 is removed by photolithography or etching, so as to form the metal connection layer 10 . One end of the metal connection layer 10 is connected to the heat-sensitive layer 8, and the other end is connected to the metal electrode layer 2 of the readout circuit on the semiconductor substrate 1, so as to form an electrical path, and complete the readout of the temperature-sensitive electrical signal by the readout circuit , the area of the heat-sensitive layer 8 is slightly smaller than the area of the getter layer 4 below; the distance between the heat-sensitive layer 8 and the getter protective layer has a great influence on the secondary absorption effect of electromagnetic radiation, and the design distance is electromagnetic radiation 1/4 of the wavelength can reflect the electromagnetic radiation energy transmitted from above back to the heat-sensitive layer 8 for secondary absorption, increase the absorption of the reflected electromagnetic radiation energy by the heat-sensitive layer 8, and improve the overall absorption efficiency of electromagnetic radiation.
步骤10a:如图5j所示,在金属连接层10上表面用等离子体增强化学气相沉积法(PECVD)等方法沉积钝化层11,钝化层11可以是但不限于氧化硅、氮化硅等薄膜,薄膜主要起到保护热敏感层8和金属连接层10的作用,避免后续工艺对热敏感层8和金属连接层10造成影响。其中,钝化层11的厚度为10nm-150nm。Step 10a: As shown in Figure 5j, a passivation layer 11 is deposited on the upper surface of the metal connection layer 10 by methods such as plasma enhanced chemical vapor deposition (PECVD). The passivation layer 11 can be but not limited to silicon oxide, silicon nitride and other thin films, the thin film mainly plays the role of protecting the heat sensitive layer 8 and the metal connection layer 10, so as to prevent subsequent processes from affecting the heat sensitive layer 8 and the metal connection layer 10. Wherein, the thickness of the passivation layer 11 is 10 nm-150 nm.
步骤11a:如图5k所示,对支撑桥7、介质层9、金属连接层10和钝化层11构成的叠层进行图形化得到牺牲层的释放通道12。Step 11a: As shown in FIG. 5k , pattern the stack formed by the support bridge 7 , the dielectric layer 9 , the metal connection layer 10 and the passivation layer 11 to obtain the release channel 12 of the sacrificial layer.
为了进一步清楚描述本申请提供的具有多层支撑桥的微测辐射热计的制备方法,图6a至6c提供了依据本申请另一实施例提供的制备方法步骤中形成的部分结构的示意图,下面将结合图6a至图6c描述依据本申请提供的另一实施例的微测辐射热计的制备方法。在本实施例中,所述制备方法具体包括以下步骤:In order to further clearly describe the preparation method of the microbolometer with multi-layer support bridges provided by the present application, Figures 6a to 6c provide schematic diagrams of partial structures formed in the steps of the preparation method according to another embodiment of the present application, as follows A method for manufacturing a microbolometer according to another embodiment provided by the present application will be described with reference to FIGS. 6 a to 6 c. In this embodiment, the preparation method specifically includes the following steps:
步骤1b:如图6a所示,在具有读出电路的金属电极层22的半导体衬底21表面形成第一介质层23,第一介质层23裸露吸气剂层24的区域。Step 1b: As shown in FIG. 6a , a first dielectric layer 23 is formed on the surface of the semiconductor substrate 21 with the metal electrode layer 22 of the readout circuit, and the region of the getter layer 24 is exposed on the first dielectric layer 23 .
步骤2b:如图6a所示,在第一介质层23裸露的半导体衬底21表面形成吸气剂层24,以及在吸气剂层24表面形成吸气剂层保护层25。Step 2b: As shown in FIG. 6a , form a getter layer 24 on the exposed surface of the semiconductor substrate 21 of the first dielectric layer 23 , and form a getter layer protective layer 25 on the surface of the getter layer 24 .
步骤3b:如图6a所示,在半导体衬底21表面形成覆盖吸气剂层24和吸气剂保护层25的最底层牺牲层261,并在最底层牺牲层261中形成裸露所述金属电极层2所在位置处的支撑连接通道。Step 3b: As shown in FIG. 6a, form the bottom sacrificial layer 261 covering the getter layer 24 and the getter protective layer 25 on the surface of the semiconductor substrate 21, and form the exposed metal electrode in the bottom sacrificial layer 261 Support connection channel at the location of layer 2.
步骤4b:如图6a所示,在所述最底层牺牲层261的表面以及其对应的支撑连接通道中形成最底层桥271。Step 4b: As shown in FIG. 6a , form the bottom bridge 271 on the surface of the bottom sacrificial layer 261 and its corresponding supporting connection channel.
步骤5b:如图6a所示,在最所述最底层桥271表面形成共形的最底层金属连接层291。Step 5b: As shown in FIG. 6a , form a conformal bottommost metal connection layer 291 on the surface of the bottommost bridge 271 .
步骤6b:如图6a所示,最所述最底层金属连接层291的表面形成最底层钝化层2101,所述最底层钝化层2101裸露部分最底层金属连接层291。Step 6b: As shown in FIG. 6a , the bottommost passivation layer 2101 is formed on the surface of the bottommost metal connection layer 291 , and the bottommost passivation layer 2101 exposes part of the bottommost metal connection layer 291 .
步骤7b:如图6b所示,在所述最底层牺牲层261以及最底层钝化层291上形成最顶层牺牲层262,以及在所述最顶层牺牲层262中形成裸露被所述最底层钝化层2101裸露的最底层金属连接层291所在的位置处支撑连接通道。Step 7b: As shown in FIG. 6b , form the topmost sacrificial layer 262 on the bottommost sacrificial layer 261 and the bottommost passivation layer 291 , and form an exposed layer in the topmost sacrificial layer 262 that is protected by the bottommost passivation layer. The position where the bottommost metal connection layer 291 of the metallization layer 2101 is exposed supports the connection channel.
步骤8b:如图6b所示,在所述最顶层牺牲层262和对应的支撑连接通道中形成最顶层桥272。Step 8b: As shown in FIG. 6b , form the topmost bridge 272 in the topmost sacrificial layer 262 and the corresponding supporting connection channels.
步骤9b:如图6b所示,在最所述最顶层桥272表面形成共形的最顶层金属连接层292。Step 9b: As shown in FIG. 6b , a conformal topmost metal connection layer 292 is formed on the surface of the topmost bridge 272 .
步骤10b:如图6b所示,在最所述最顶层桥272的桥面表面形成热敏感层28。Step 10b: As shown in FIG. 6b , form a heat-sensitive layer 28 on the bridge surface of the topmost bridge 272 .
步骤11b:如图6b所示,在最所述最顶层桥272的桥面、所述成热敏感层28以及所述最顶层金属连接层292上形成最顶层钝化层2102。Step 11b: As shown in FIG. 6b , form the topmost passivation layer 2102 on the bridge surface of the topmost bridge 272 , the heat-sensitive layer 28 and the topmost metal connection layer 292 .
步骤12b:如图6b所示,在所述热敏感层28周围的叠层中形成释放通道212,所述释放通道贯穿最顶层钝化层2102、最顶层金属连接层292以及最顶层桥272的桥面。Step 12b: As shown in FIG. 6b , form a release channel 212 in the stack around the heat-sensitive layer 28 , and the release channel runs through the topmost passivation layer 2102 , the topmost metal connection layer 292 and the topmost bridge 272 bridge deck.
步骤13b:如图6c所示,蚀刻掉最底层牺牲层261和最顶层牺牲层262获得微测辐射热计。Step 13b: As shown in FIG. 6c , etch away the bottommost sacrificial layer 261 and the topmost sacrificial layer 262 to obtain a microbolometer.
此外,由于在本申请中,将吸气剂层做在了所述微测辐射热计内部,则将所述微测辐射热计进行封装获得探测器时,可以采用不同的封装工艺实现,如芯片级封装工艺、像素级封装工艺、金属封装工艺或陶瓷封装工艺等。如图7所示,以单层支撑桥结构的微测辐射热计为例,可以采用像素级封装工艺对图5j中所示的微测辐射热计结构进行封装,其包括采用封装牺牲材料13覆盖在所述半导体衬底1表面,以覆盖5j中所示的微测辐射热计结构,然后在封装牺牲材料13上形成封装壳体14,封装壳体14上具有封装释放通道15。In addition, since in this application, the getter layer is made inside the microbolometer, when the microbolometer is packaged to obtain a detector, it can be realized by using different packaging processes, such as Chip-level packaging process, pixel-level packaging process, metal packaging process or ceramic packaging process, etc. As shown in Fig. 7, taking a microbolometer with a single-layer support bridge structure as an example, the microbolometer structure shown in Fig. Cover the surface of the semiconductor substrate 1 to cover the microbolometer structure shown in 5j, and then form a packaging case 14 on the packaging sacrificial material 13, and the packaging case 14 has a packaging release channel 15 thereon.
需要说明的是,为了形成真空腔体,依据本申请提供的制备方法还进一步包括去除牺牲层以及封装牺牲材料,释放通道作为去除牺牲层时对应的释放通道,封装释放通道作为去除封装牺牲材料时对应的释放通道。It should be noted that, in order to form a vacuum cavity, the preparation method according to the present application further includes removing the sacrificial layer and encapsulating the sacrificial material, the release channel is used as the corresponding release channel when removing the sacrificial layer, and the encapsulating release channel is used as the release channel when removing the encapsulation sacrificial material. Corresponding release channel.
由上可见,本发明提供了用于检测电磁辐射的微测辐射热计中,将吸气剂层的制备过程集成到传统微测辐射热计的MEMS工艺步骤中。吸气剂采用激活温度低、吸气效率高的吸气剂,可以是但不限于Zr-Co-RE系薄膜吸气剂,吸气剂主体材料选用钛、锆、钒、铬、钴、铁、锰、钯、钡、铝,或者这些材料和稀有金属组成的多相合金。然后在吸气剂的上面通过PVD的方法溅射一层活性低、反射率高的金属保护层,金属保护层的材料可以是但不限于Au或者Pt等金属。此外。吸气剂层与半导体衬底表面之间设置吸气剂种子层,起到防止吸气剂层中毒,并提高吸气剂层与衬底的附着力。金属保护层的主要作用是改善吸气剂钝化层被氧化的状况,降低后续释放过程对吸气剂的氧化,同时又充当反射层的作用,保证微测辐射热计的检测精度。金属保护层反射率满足在待检测波长范围内反射率大于90%。因此,本发明通过优化微测辐射热计的吸气剂设计,减小了整个探测器的尺寸和生产成本,明显提高了微测辐射热计的生产效率和可靠性。As can be seen from the above, the present invention provides a microbolometer for detecting electromagnetic radiation, in which the preparation process of the getter layer is integrated into the MEMS process steps of the traditional microbolometer. The getter adopts a getter with low activation temperature and high suction efficiency, which can be but not limited to Zr-Co-RE thin film getter, and the main material of the getter is titanium, zirconium, vanadium, chromium, cobalt, iron , manganese, palladium, barium, aluminum, or multi-phase alloys composed of these materials and rare metals. Then, a metal protection layer with low activity and high reflectivity is sputtered on the getter by PVD method, and the material of the metal protection layer may be but not limited to metals such as Au or Pt. also. A getter seed layer is arranged between the getter layer and the surface of the semiconductor substrate to prevent poisoning of the getter layer and improve the adhesion between the getter layer and the substrate. The main function of the metal protective layer is to improve the oxidation of the passivation layer of the getter, reduce the oxidation of the getter in the subsequent release process, and at the same time act as a reflective layer to ensure the detection accuracy of the microbolometer. The reflectivity of the metal protective layer is greater than 90% within the wavelength range to be detected. Therefore, the present invention reduces the size and production cost of the entire detector by optimizing the getter design of the microbolometer, and significantly improves the production efficiency and reliability of the microbolometer.
以上所述,仅为本申请的具体实施方式,但本申请的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本申请揭露的技术范围之内,可轻易想到变化或替换,都应涵盖在本申请的保护范围之内。因此,本申请的保护范围应以所述权利要求的保护范围为准。The above is only a specific implementation of the application, but the scope of protection of the application is not limited thereto. Any person familiar with the technical field can easily think of changes or substitutions within the technical scope disclosed in the application. All should be covered within the scope of protection of this application. Therefore, the protection scope of the present application should be determined by the protection scope of the claims.

Claims (19)

  1. 一种微测辐射热计,其特征在于,包括:A kind of microbolometer is characterized in that, comprises:
    位于基底上的支撑桥,所述支撑桥为单层或多层桥,每层桥包括桥墩和桥面,最底层桥的桥墩位于所述基底表面上,相邻的两层桥之间,上一层桥的所述桥墩位于下一层桥的所述桥面上方;A support bridge located on a base, the support bridge is a single-layer or multi-layer bridge, each layer of bridges includes piers and bridge decks, the piers of the bottommost bridge are located on the surface of the base, between adjacent two-layer bridges, the upper The piers of the bridge on one level are located above the deck of the bridge on the next level;
    位于所述基底表面上,且位于所述最底层桥的所述桥面下方的吸气剂层;a getter layer on the surface of the substrate and below the deck of the bottommost bridge;
    位于最顶层桥的桥面上的热敏感层。Heat-sensitive layer on the deck of the topmost bridge.
  2. 根据权利要求1所述的微测辐射热计,其特征在于,所述基底为内设读出电路的半导体衬底,所述半导体衬底表面的第一区域具有与所述读出电路电连接的金属电极层,所述最底层桥的桥墩位于所述金属电极层上;The microbolometer according to claim 1, wherein the substrate is a semiconductor substrate with a built-in readout circuit, and the first region on the surface of the semiconductor substrate has a power connection with the readout circuit. The metal electrode layer, the pier of the bottom bridge is located on the metal electrode layer;
    所述微测辐射热计还包括沿所述支撑桥的每层桥的桥墩和桥面设置的金属连接层,所述金属连接层在所述最顶层桥面上与所述热敏感层接触,并沿所述支撑桥延伸至所述金属电极层处与所述金属电极层接触;The microbolometer also includes a metal connection layer arranged along the pier and the bridge deck of each bridge of the supporting bridge, the metal connection layer is in contact with the heat-sensitive layer on the topmost bridge deck, And extending along the support bridge to the metal electrode layer to contact the metal electrode layer;
    所述吸气剂层位于所述半导体衬底表面的第二区域,且所述第一区域位于所述第二区域外围。The getter layer is located on a second area of the surface of the semiconductor substrate, and the first area is located on the periphery of the second area.
  3. 根据权利要求2所述的微测辐射热计,其特征在于,所述微测辐射热计还包括:The microbolometer according to claim 2, wherein the microbolometer further comprises:
    位于所述半导体衬底表面的第一介质层,所述第一介质层的部分设置在所述金属电极层与所述吸气剂层之间的位置,以将所述金属电极层和所述吸气剂层隔离;A first dielectric layer located on the surface of the semiconductor substrate, a part of the first dielectric layer is disposed between the metal electrode layer and the getter layer, so that the metal electrode layer and the getter layer getter layer isolation;
    位于所述金属连接层和所述热敏感层表面的钝化层;a passivation layer located on the surface of the metal connection layer and the heat-sensitive layer;
    位于所述热敏感层周围的释放通道,所述释放通道贯穿所述钝化层、所述金属连接层以及所述最顶层桥的桥面。A release channel located around the heat sensitive layer, the release channel penetrates the passivation layer, the metal connection layer and the bridge surface of the topmost bridge.
  4. 根据权利要求2所述的微测辐射热计,其特征在于,还包括位于所述最顶层桥和所述热敏感层上的第二介质层;The microbolometer according to claim 2, further comprising a second dielectric layer positioned on the topmost bridge and the heat-sensitive layer;
    沿所述最顶层桥的桥墩和桥面设置的部分所述金属连接层位于所述第二介质层上,并穿过所述第二介质层与所述热敏感层接触。The part of the metal connection layer disposed along the pier and the bridge deck of the topmost bridge is located on the second dielectric layer, and contacts the heat-sensitive layer through the second dielectric layer.
  5. 根据权利要求1所述的微测辐射热计,其特征在于,所述吸气剂层的制作材料包括钛、锆、钒、铬、钴、铁、锰、钯、钡、铝中的至少一种;或,The microbolometer according to claim 1, wherein the material for making the getter layer comprises at least one of titanium, zirconium, vanadium, chromium, cobalt, iron, manganese, palladium, barium, and aluminum. species; or,
    所述吸气剂层的制作材料包括钛、锆、钒、铬、钴、铁、锰、钯、钡、铝中的至少一种和稀有金属组成的多相合金。The material for making the getter layer includes a multi-phase alloy composed of at least one of titanium, zirconium, vanadium, chromium, cobalt, iron, manganese, palladium, barium, aluminum and rare metals.
  6. 根据权利要求2所述的微测辐射热计,其特征在于,所述微测辐射热计还包括:The microbolometer according to claim 2, wherein the microbolometer further comprises:
    位于所述基底表面与所述吸气剂层之间的吸气剂种子层。A getter seed layer positioned between the substrate surface and the getter layer.
  7. 根据权利要求1至6中任意一项所述的微测辐射热计,其特征在于,所述微测辐射热计还包括位于所述吸气剂层上的吸气剂保护层,所述吸气剂保护层用于保护所述吸气剂层不被氧化;The microbolometer according to any one of claims 1 to 6, characterized in that, the microbolometer further comprises a getter protective layer on the getter layer, and the getter The aerosol protection layer is used to protect the getter layer from oxidation;
    所述支撑桥的桥墩高度大于所述吸气剂层与所述吸气剂层保护层的高度之和。The pier height of the supporting bridge is greater than the sum of the heights of the getter layer and the getter layer protective layer.
  8. 根据权利要求7所述的微测辐射热计,其特征在于,所述吸气剂保护层与所述热敏感层构成光学谐振腔,使得所述吸气剂保护层将从所述热敏感层透射出的电磁辐射的能量反射到所述热敏感层,以被所述热敏感层吸收。The microbolometer according to claim 7, wherein the getter protective layer and the heat-sensitive layer form an optical resonant cavity, so that the getter protective layer will The energy of the transmitted electromagnetic radiation is reflected to the thermally sensitive layer to be absorbed by the thermally sensitive layer.
  9. 根据权利要求8所述的微测辐射热计,其特征在于,所述吸气剂保护层的制作材料包括铂、金、银、镍、铬以及铝中的至少一种。The microbolometer according to claim 8, wherein the material of the getter protection layer includes at least one of platinum, gold, silver, nickel, chromium and aluminum.
  10. 一种微测辐射热计的制备方法,其特征在于,包括:A preparation method of a microbolometer, characterized in that it comprises:
    在基底上沉积吸气剂层;depositing a getter layer on the substrate;
    在所述基底上形成支撑桥,所述支撑桥为单层或多层桥,每层桥包括桥墩和桥面,最底层桥的桥墩位于所述基底表面上,所述最底层桥的桥面位于所述吸气剂层上方,相邻的两层桥之间,上一层桥的所述桥墩位于下一层桥的所述桥面上方;Form a support bridge on the base, the support bridge is a single-layer or multi-layer bridge, each layer of bridge includes piers and bridge decks, the piers of the bottom bridge are located on the base surface, and the bridge deck of the bottom bridge Located above the getter layer, between two adjacent bridges, the pier of the upper bridge is located above the bridge deck of the lower bridge;
    在最顶层桥的桥面上沉积热敏感层。A thermally sensitive layer is deposited on the bridge surface of the topmost bridge.
  11. 根据权利要求10所述的制备方法,其特征在于,所述基底为内设读出电路的半导体衬底,所述半导体衬底表面的第一区域具有与所述读出电路电连接的金属电极层,所述在基底上沉积吸气剂层,包括:The preparation method according to claim 10, wherein the substrate is a semiconductor substrate with a built-in readout circuit, and the first region on the surface of the semiconductor substrate has a metal electrode electrically connected to the readout circuit layer, said depositing a getter layer on a substrate, comprising:
    在所述半导体衬底表面形成图案化的第一介质层,所述第一介质层覆盖所述金属电极层且裸露所述半导体衬底表面的第二区域,所述第一区域位于所述第二区域外围;A patterned first dielectric layer is formed on the surface of the semiconductor substrate, the first dielectric layer covers the metal electrode layer and exposes a second region of the semiconductor substrate surface, the first region is located on the first The periphery of the second area;
    在所述第二区域沉积吸气剂层;depositing a getter layer on said second region;
    其中,所述吸气剂层的制作材料包括钛、锆、钒、铬、钴、铁、锰、钯、钡、铝中的至少一种,或者所述吸气剂层的制作材料包括钛、锆、钒、铬、钴、铁、锰、钯、钡、铝中的至少一种和稀有金属组成的多相合金;Wherein, the material for making the getter layer includes at least one of titanium, zirconium, vanadium, chromium, cobalt, iron, manganese, palladium, barium, and aluminum, or the material for making the getter layer includes titanium, A multi-phase alloy composed of at least one of zirconium, vanadium, chromium, cobalt, iron, manganese, palladium, barium, aluminum and a rare metal;
    所述制备方法括还包括:The preparation method also includes:
    形成沿所述支撑桥的每层桥的桥墩和桥面设置的金属连接层,所述金属连接层在所述最顶层桥面上与所述热敏感层接触,并沿所述支撑桥延伸至所述金属电极层处与所述金属电极层接触。Forming a metal connection layer arranged along the pier and the bridge deck of each layer of the supporting bridge, the metal connecting layer is in contact with the heat-sensitive layer on the topmost bridge surface, and extends along the supporting bridge to The metal electrode layer is in contact with the metal electrode layer.
  12. 根据权利要求11所述的制备方法,其特征在于,所述在所述第二区域沉积吸气剂层,包括:The preparation method according to claim 11, wherein the depositing a getter layer in the second region comprises:
    采用物理气相沉积工艺、磁控溅射工艺和蒸镀工艺中之一在所述第二区域上沉积吸气剂材料层;depositing a layer of getter material on said second region using one of a physical vapor deposition process, a magnetron sputtering process, and an evaporation process;
    利用Lift-Off工艺或光刻工艺图案化所述吸气剂材料层,以形成所述吸气剂层。The getter material layer is patterned using a Lift-Off process or a photolithography process to form the getter layer.
  13. 根据权利要求11所述的制备方法,其特征在于,所述在所述半导体衬底表面形成图案化的第一介质层之前,所述在基底上沉积吸气剂层,还包括:The preparation method according to claim 11, wherein, before forming the patterned first dielectric layer on the surface of the semiconductor substrate, depositing a getter layer on the substrate further comprises:
    在内设有读出电路的半导体衬底表面沉积第一金属材料层;Depositing a first metal material layer on the surface of the semiconductor substrate provided with a readout circuit;
    蚀刻所述第一金属材料层,以形成位于所述第一区域且与所述读出电路电连接的金属电极层,所述金属电极层裸露所述第二区域。Etching the first metal material layer to form a metal electrode layer located in the first region and electrically connected to the readout circuit, the metal electrode layer exposing the second region.
  14. 根据权利要求11所述的制备方法,其特征在于,所述在所述基底上形成支撑桥,包括:The preparation method according to claim 11, wherein said forming a support bridge on said substrate comprises:
    在所述半导体衬底表面上形成覆盖所述吸气剂层且具有支撑连接通道的牺牲层,所述支撑连接通道裸露所述金属电极层所在的位置;forming a sacrificial layer covering the getter layer and having a supporting connection channel on the surface of the semiconductor substrate, the supporting connecting channel exposing the position where the metal electrode layer is located;
    在所述牺牲层表面以及所述支撑连接通道中沉积可吸收电磁辐射的绝缘材料,以形成单层支撑桥;depositing an insulating material capable of absorbing electromagnetic radiation on the surface of the sacrificial layer and in the supporting connection channel to form a single-layer supporting bridge;
    形成沿所述支撑桥的每层桥的桥墩和桥面设置的金属连接层,包括:Forming the metal connection layer arranged along the pier and the bridge deck of each layer of the supporting bridge, including:
    在所述单层支撑桥的桥面形成所述热敏感层之后,在所述单层支撑桥的桥墩、桥面和所述热敏感层上形成第二介质层,所述第二介质层裸露部分所述热敏感层和所述金属电极层所在的位置;After the heat-sensitive layer is formed on the bridge deck of the single-layer support bridge, a second dielectric layer is formed on the pier, bridge deck and the heat-sensitive layer of the single-layer support bridge, and the second dielectric layer is exposed The position where part of the heat-sensitive layer and the metal electrode layer are located;
    在所述第二介质层表面形成金属连接层,所述金属连接层的一部分位于所述单层支撑桥的桥面并与所述热敏感层接触,所述金属连接层的另一部分沿所述单层支撑桥的桥墩延伸至所述金属电极层处与所述金属电极层接触。A metal connection layer is formed on the surface of the second dielectric layer, a part of the metal connection layer is located on the bridge surface of the single-layer support bridge and is in contact with the heat-sensitive layer, and the other part of the metal connection layer is along the The pier of the single-layer support bridge extends to the metal electrode layer and contacts the metal electrode layer.
  15. 根据权利要求14所述的制备方法,其特征在于,所述在所述单层支撑桥的桥墩、桥面和所述热敏感层上形成第二介质层,包括:The preparation method according to claim 14, wherein the formation of the second dielectric layer on the pier, the bridge deck and the heat-sensitive layer of the single-layer support bridge comprises:
    在所述单层支撑桥的桥墩、桥面和所述热敏感层上沉积氮化硅和/或二氧化硅构成的介质薄膜材料层;Depositing a dielectric film material layer composed of silicon nitride and/or silicon dioxide on the pier, bridge deck and the heat-sensitive layer of the single-layer support bridge;
    蚀刻掉所述单层支撑桥的桥墩的底部和部分所述热敏感层上的氮化硅和/或氧化硅构成的介质薄膜材料层,形成图案化的第二介质层;Etching away the bottom of the pier of the single-layer support bridge and the dielectric film material layer composed of silicon nitride and/or silicon oxide on part of the heat-sensitive layer to form a patterned second dielectric layer;
    在所述第二介质层上形成图案化的金属连接层,包括:Forming a patterned metal connection layer on the second dielectric layer, comprising:
    利用物理或化学气相沉积工艺在所述第二介质层上形成第二金属材料层;forming a second metal material layer on the second dielectric layer by using a physical or chemical vapor deposition process;
    蚀刻所述第二金属材料层,形成一端与所述热敏感层连接,另一端与所述金属电极层连接的金属连接层。Etching the second metal material layer to form a metal connection layer with one end connected to the heat sensitive layer and the other end connected to the metal electrode layer.
  16. 根据权利要求11所述的制备方法,其特征在于,所述在所述基底上形成支撑桥,包括:The preparation method according to claim 11, wherein said forming a support bridge on said substrate comprises:
    在所述半导体衬底表面依次形成至少两层牺牲层,每层所述牺牲层均具有支撑连接通道,最底层所述牺牲层覆盖所述吸气剂层且最底层所述牺牲层的支撑连接通道裸露所述金属电极层所在的位置;At least two layers of sacrificial layers are sequentially formed on the surface of the semiconductor substrate, each layer of the sacrificial layer has a support connection channel, the sacrificial layer at the bottom layer covers the getter layer and the support connection of the sacrificial layer at the bottom layer The channel exposes the position where the metal electrode layer is located;
    在每层所述牺牲层表面和对应的支撑连接通道中沉积可吸收电磁辐射的绝缘材料,形成多层支撑桥的每一层桥,每层桥的桥墩位于对应的支撑连接通道中,桥面位于对应层的所述牺牲层表面;An insulating material capable of absorbing electromagnetic radiation is deposited on the surface of each layer of the sacrificial layer and the corresponding supporting connection channel to form each layer of the multi-layer supporting bridge, and the pier of each layer of bridge is located in the corresponding supporting connecting channel, and the bridge deck The surface of the sacrificial layer located on the corresponding layer;
    形成沿所述支撑桥的每层桥的桥墩和桥面设置的金属连接层,包括:Forming the metal connection layer arranged along the pier and the bridge deck of each layer of the supporting bridge, including:
    在所述多层支撑桥的每层桥的桥墩和桥面表面形成所述金属连接层,所述金属连接层位于所述最顶层桥的桥面部分与所述热敏感层接触,所述金属连接层由所述最顶层桥的桥面依次沿所述多层支撑桥的每层桥墩和桥面延伸至所述金属电极层处与所述金属电极层接触。The metal connection layer is formed on the pier and bridge deck surface of each layer of the multi-layer support bridge, and the metal connection layer is located at the bridge deck part of the topmost bridge in contact with the heat-sensitive layer. The connection layer extends from the bridge surface of the topmost bridge along each pier and bridge surface of the multi-layer support bridge to the metal electrode layer in contact with the metal electrode layer.
  17. 根据权利要求11所述的制备方法,其特征在于,形成沿所述支撑桥的每层桥的桥墩和桥面设置的金属连接层后,所述制备方法还包括:The preparation method according to claim 11, wherein, after forming the metal connection layer arranged along the pier and the bridge deck of each bridge of the supporting bridge, the preparation method also includes:
    在所述金属连接层上形成钝化层;forming a passivation layer on the metal connection layer;
    蚀刻所述热敏感层周围的叠层,以在所述叠层中形成释放通道,所述叠层包括所述钝化层、所述金属连接层以及所述最顶层桥的桥面。Etching the stack around the thermally sensitive layer to form a release channel in the stack, the stack including the passivation layer, the metal connection layer, and the bridge deck of the topmost bridge.
  18. 根据权利要求10所述的制备方法,其特征在于,所述在所述基底上沉积吸气剂层之前,所述制备方法还包括:The preparation method according to claim 10, wherein, before depositing the getter layer on the substrate, the preparation method further comprises:
    在所述基底表面上形成吸气剂种子层;forming a getter seed layer on the surface of the substrate;
    所述在所述基底上沉积吸气剂层,包括:The depositing a getter layer on the substrate comprises:
    在所述吸气剂种子层上沉积吸气剂层。A getter layer is deposited on the getter seed layer.
  19. 根据权利要求10至18中任意一项所述的制备方法,其特征在于,在所述基底表面沉积吸气剂层之后,且在所述基底表面上形成覆盖所述吸气剂层且具有支撑连接通道的牺牲层之前,所述制备方法还包括:According to the preparation method according to any one of claims 10 to 18, it is characterized in that, after the getter layer is deposited on the surface of the substrate, a getter layer covering the getter layer and having a support is formed on the surface of the substrate. Before connecting the sacrificial layer of the channel, the preparation method also includes:
    在所述吸气剂层上形成与所述基底相对的吸气剂保护层,所述吸气剂保护层用于保护所述吸气剂层不被氧化;forming a getter protective layer opposite to the substrate on the getter layer, the getter protective layer is used to protect the getter layer from oxidation;
    其中,所述支撑连接通道的高度大于所述吸气剂层与所述吸气剂保护层的厚度之和;所述吸气剂保护层与所述热敏感层构成光学谐振腔,使得所述吸气剂保护层将从所述热敏感层透射出的电磁辐射的能量反射到所述热敏感层,以被所述热敏感层吸收。Wherein, the height of the supporting connection channel is greater than the sum of the thicknesses of the getter layer and the getter protective layer; the getter protective layer and the heat-sensitive layer form an optical resonant cavity, so that the The getter protective layer reflects energy of electromagnetic radiation transmitted from the heat sensitive layer to the heat sensitive layer to be absorbed by the heat sensitive layer.
PCT/CN2022/073846 2022-01-25 2022-01-25 Microbolometer and preparation method therefor WO2023141768A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/CN2022/073846 WO2023141768A1 (en) 2022-01-25 2022-01-25 Microbolometer and preparation method therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2022/073846 WO2023141768A1 (en) 2022-01-25 2022-01-25 Microbolometer and preparation method therefor

Publications (1)

Publication Number Publication Date
WO2023141768A1 true WO2023141768A1 (en) 2023-08-03

Family

ID=87470078

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2022/073846 WO2023141768A1 (en) 2022-01-25 2022-01-25 Microbolometer and preparation method therefor

Country Status (1)

Country Link
WO (1) WO2023141768A1 (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040092041A1 (en) * 2000-11-07 2004-05-13 Jean-Louis Ouvrier-Buffet Device for detecting three-dimensional electromagnetic radiation and method for making same
CN102012269A (en) * 2009-06-12 2011-04-13 原子能和代替能源委员会 Device for detecting and/or emitting electromagnetic radiation and method for manufacturing such a device
CN103776546A (en) * 2014-01-21 2014-05-07 武汉高芯科技有限公司 Non-refrigeration infrared focal plane array detector of double-layer structure
CN105449008A (en) * 2014-07-10 2016-03-30 上海巨哥电子科技有限公司 Infrared sensor and packaging structure thereof and preparation method thereof
CN106052883A (en) * 2016-05-09 2016-10-26 电子科技大学 Three-layer micro-bridge structure, three-layer uncooled micro-bolometer and preparation method thereof
CN106340561A (en) * 2016-09-29 2017-01-18 烟台睿创微纳技术股份有限公司 Novel uncooled infrared focal plane detector pixel and fabrication method thereof
CN209027681U (en) * 2018-11-09 2019-06-25 无锡元创华芯微机电有限公司 A kind of non-refrigerate infrared focal plane array seeker

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040092041A1 (en) * 2000-11-07 2004-05-13 Jean-Louis Ouvrier-Buffet Device for detecting three-dimensional electromagnetic radiation and method for making same
CN102012269A (en) * 2009-06-12 2011-04-13 原子能和代替能源委员会 Device for detecting and/or emitting electromagnetic radiation and method for manufacturing such a device
CN103776546A (en) * 2014-01-21 2014-05-07 武汉高芯科技有限公司 Non-refrigeration infrared focal plane array detector of double-layer structure
CN105449008A (en) * 2014-07-10 2016-03-30 上海巨哥电子科技有限公司 Infrared sensor and packaging structure thereof and preparation method thereof
CN106052883A (en) * 2016-05-09 2016-10-26 电子科技大学 Three-layer micro-bridge structure, three-layer uncooled micro-bolometer and preparation method thereof
CN106340561A (en) * 2016-09-29 2017-01-18 烟台睿创微纳技术股份有限公司 Novel uncooled infrared focal plane detector pixel and fabrication method thereof
CN209027681U (en) * 2018-11-09 2019-06-25 无锡元创华芯微机电有限公司 A kind of non-refrigerate infrared focal plane array seeker

Similar Documents

Publication Publication Date Title
CN106352989B (en) A kind of production method and structure of non-refrigerated infrared focal plane probe microbridge
JP7045430B2 (en) Thermal infrared sensor array in wafer level package
JP4315832B2 (en) Thermal infrared sensor element and thermal infrared sensor array
CN106441595B (en) Infrared detector array class encapsulation structure and its manufacturing method
JP3514681B2 (en) Infrared detector
US6690014B1 (en) Microbolometer and method for forming
KR100925214B1 (en) Bolometer and manufacturing method thereof
US9258894B2 (en) Bolometer and preparation method thereof
CN106629578B (en) Infrared detector and its manufacturing method with micro-bridge structure
AU2001278843A1 (en) Microbolometer and method for forming
JP2013529295A (en) Uncooled infrared detector and method for manufacturing the same
JP2006214758A (en) Infrared detector
CN110118604B (en) Wide-spectrum microbolometer based on mixed resonance mode and preparation method thereof
US5831266A (en) Microbridge structure for emitting or detecting radiations and method for forming such microbridge structure
US11359973B2 (en) MEMS device having curved reflective layer and method for manufacturing MEMS device
KR100538996B1 (en) Infrared ray sensor using silicon oxide film as a infrared ray absorption layer and method for fabricating the same
WO2023141768A1 (en) Microbolometer and preparation method therefor
CN101881666A (en) Film-type pyroelectric infrared sensor and preparation method thereof
US20150206908A1 (en) Focal plane array and method for manufacturing the same
JP4865957B2 (en) Method for manufacturing thermal infrared solid-state imaging device
CN113447148A (en) Infrared focal plane detector
CN106672891A (en) Double-layer uncooled infrared detector structure and preparation method thereof
KR102587111B1 (en) A Bolometer MEMS Device And The Manufacturing Method of the Bolometer MEMS Device
CN113735053B (en) Micro-electromechanical infrared sensor and preparation method thereof
CN115060371A (en) Micro-bolometer, manufacturing method and infrared detector

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 22922619

Country of ref document: EP

Kind code of ref document: A1