Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
  • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
  • C08F253/00—Macromolecular compounds obtained by polymerising monomers on to natural rubbers or derivatives thereof
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
  • C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L2205/00—Polymer mixtures characterised by other features
  • C08L2205/22—Mixtures comprising a continuous polymer matrix in which are dispersed crosslinked particles of another polymer
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L2207/00—Properties characterising the ingredient of the composition
  • C08L2207/53—Core-shell polymer
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
  • C08L35/02—Homopolymers or copolymers of esters

Definitions

• the present invention relates to curable resin compositions, adhesives, molding materials and cured products.
• curable resins such as epoxy resins, unsaturated polyester resins, vinyl ester resins, and phenolic resins are widely used for civil engineering and construction materials, electrical and electronic materials, fiber-reinforced composite materials, adhesives, etc., due to their excellent heat resistance, mechanical strength, and dimensional accuracy.
• curable resins such as epoxy resins, unsaturated polyester resins, vinyl ester resins, and phenolic resins are widely used for civil engineering and construction materials, electrical and electronic materials, fiber-reinforced composite materials, adhesives, etc., due to their excellent heat resistance, mechanical strength, and dimensional accuracy.
• the cured product of the curable resin exhibits low fracture toughness and brittle properties, there is a problem of poor impact resistance and/or adhesive strength.
• Patent Document 1 discloses a core-shell polymer-containing epoxy resin composition in which the shell portion has a glass transition temperature of less than 25°C and the shell portion contains a monomer having an epoxy group.
• Patent Document 2 contains rubber -containing polymer and epoxy resin, and the rubber -containing polymer contains at least one type of rubber quality and at least one or more vinyl monomers, and the vinyl single body portion is based on multiple function (meta) acrylate, and the epoxy -containing (meta) acrylate (meta).
• an epoxy resin composition has been disclosed, with a unit based on at least one monomer selected from a group consisting of an aromatic vinyl body and a unit based on the alkyl (meta) acrylate.
• the core-shell polymer of Patent Document 1 has a low glass transition temperature in the outermost layer, in the manufacturing process of the core-shell polymer-containing epoxy resin composition, the particles of the core-shell polymer collide with each other to easily agglomerate, and the dispersibility in the epoxy resin tends to decrease.
• the rubber-containing polymer of Patent Document 2 has the problem that the rubber-containing polymer cannot be well dispersed in the epoxy resin unless the rubber-containing polymer and the epoxy resin are premixed using an organic solvent such as methyl ethyl ketone (MEK), or the rubber-containing polymer is not well dispersed in the epoxy resin unless the process is carefully mixed with high-speed shear stirring or a kneader such as a triple roll.
• MEK methyl ethyl ketone
• An object of the present invention is to provide a curable resin composition, an adhesive, a molding material, and a cured product that are excellent in dispersibility of acrylic rubber particles in the curable resin and yield a cured product with excellent appearance quality.
• the curable resin composition according to Item 1 wherein the curable resin (A) is at least one selected from the group consisting of epoxy resins, unsaturated polyester resins, epoxy (meth)acrylates, and urethane (meth)acrylates.
• the curable resin (A) is at least one selected from the group consisting of epoxy resins, unsaturated polyester resins, epoxy (meth)acrylates, and urethane (meth)acrylates.
• the curable resin composition according to item 1 or 2 wherein the outermost layer of the acrylic rubber particles (B) contains at least one selected from the group consisting of carboxyl group-containing monomer units (x) and epoxy group-containing monomer units (y).
• the carboxyl group-containing monomer unit (x) is at least one selected from the group consisting of acrylic acid and methacrylic acid.
• the carboxyl group-containing monomer unit (x) is at least one selected from the group consisting of acrylic acid and methacrylic acid.
• a curable resin composition an adhesive, a molding material, and a cured product that have excellent dispersibility of acrylic rubber particles in the curable resin and provide a cured product with excellent appearance quality.
• the curable resin composition of the present invention contains a curable resin (A) and acrylic rubber particles (B).
• the curable resin (A) is not particularly limited as long as it is a compound having at least two curable functional groups such as epoxy groups or polymerizable unsaturated bonds in the molecule, and known and commonly used resins such as epoxy resins, unsaturated polyester resins, epoxy (meth)acrylates, urethane (meth)acrylates, etc. can be used.
• the epoxy resin is not particularly limited as long as it is a compound having at least two epoxy groups in the molecule, and conventionally known ones can be used.
• epoxy resins examples include bisphenol A type epoxy resins, bisphenol F type epoxy resins, bisphenol AD type epoxy resins, bisphenol E type epoxy resins, naphthalene type epoxy resins, biphenyl type epoxy resins, dicyclopentadiene type epoxy resins, phenol novolac type epoxy resins, alicyclic epoxy resins, and glycidylamine type epoxy resins.
• Modified epoxy resins such as urethane-modified epoxy resins, rubber-modified epoxy resins, and chelate-modified epoxy resins are also included.
• epoxy resins include copolymers of the above epoxy resins and other polymers, and those in which a part of the above epoxy resins is replaced with a reactive diluent having an epoxy group.
• copolymers of epoxy resins and other polymers include polyether-modified epoxy resins and silicone-modified epoxy resins.
• reactive diluents include polyalkylene glycol diglycidyl ethers such as polyethylene glycol diglycidyl ether and polypropylene glycol diglycidyl ether; glycol diglycidyl ethers such as neopentyl glycol diglycidyl ether and 1,4-butanediol diglycidyl ether; diglycidyl esters of aliphatic polybasic acids such as adipic acid diglycidyl ester and maleic acid diglycidyl ester; trimethylolpropane triglycidyl ether and trimethylolethane triglycidyl Glycidyl ethers of dihydric or higher polyhydric aliphatic alcohols such as ethers; monoglycidyl compounds such as resorcinol glycidyl ether, t-butylphenylglycidyl ether and allyl glycidyl ether; and mono
• epoxy resins may be used singly or in combination of two or more.
• bisphenol A type epoxy resin bisphenol F type epoxy resin
• alicyclic epoxy resin are preferable because the cured products have excellent heat resistance and are relatively inexpensive.
• epoxy equivalent of the epoxy resin used in the present invention is not particularly limited, those in the range of 80 to 2000 can be mentioned.
• Such an epoxy resin can be obtained by a known method, for example, a method of reacting polyhydric alcohol or polyhydric phenol with an excess amount of epihalohydrin in the presence of a base.
• the compound having at least two polymerizable unsaturated bonds in the molecule used in the present invention is not particularly limited, and examples thereof include curable resins having radically polymerizable carbon-carbon double bonds.
• Specific examples include unsaturated polyester resins, epoxy (meth)acrylates, urethane (meth)acrylates, polyether (meth)acrylates, and acrylated (meth)acrylates. These may be used alone or in combination of two or more.
• unsaturated polyester resins, epoxy (meth)acrylates, and urethane (meth)acrylates are preferable from the viewpoint of economy.
• the unsaturated polyester resin is not particularly limited, and includes, for example, those obtained from a condensation reaction between a polyhydric alcohol and an unsaturated polycarboxylic acid or its anhydride.
• polyhydric alcohols examples include dihydric alcohols such as ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, and 1,4-butanediol. These polyhydric alcohols may be used alone or in combination of two or more.
• unsaturated polycarboxylic acids examples include divalent carboxylic acids such as fumaric acid and maleic acid. These unsaturated polycarboxylic acids may be used alone or in combination of two or more.
• the unsaturated polyester resin can be obtained by condensation reaction of the polyhydric alcohol and the unsaturated polycarboxylic acid or its anhydride in the presence of an esterification catalyst such as an organic titanate such as tetrabutyl titanate or an organic tin compound such as dibutyltin oxide.
• an esterification catalyst such as an organic titanate such as tetrabutyl titanate or an organic tin compound such as dibutyltin oxide.
• Epoxy (meth)acrylate is an addition reaction product obtained by subjecting a polyepoxide such as bisphenol A type epoxy resin, an unsaturated monobasic acid such as (meth)acrylic acid, and optionally a polybasic acid to an addition reaction in the presence of a catalyst.
• a mixture obtained by optionally mixing the addition reaction product with a vinyl monomer is generally called a vinyl ester resin.
• the epoxy (meth)acrylate is not particularly limited.
• it can be obtained by subjecting a polyfunctional epoxy compound having at least two epoxy groups in the molecule, an unsaturated monocarboxylic acid, and optionally a polyvalent carboxylic acid to an esterification reaction in the presence of an esterification catalyst.
• polyfunctional epoxy compounds include those exemplified as the epoxy resins.
• unsaturated monocarboxylic acids examples include acrylic acid and methacrylic acid. It is also possible to replace some of these unsaturated monocarboxylic acids with half esters of cinnamic acid, crotonic acid, sorbic acid and unsaturated dibasic acids.
• polycarboxylic acids examples include maleic acid, maleic anhydride, fumaric acid, itaconic acid, itaconic anhydride, citraconic acid, adipic acid, azelaic acid, phthalic acid, phthalic anhydride, isophthalic acid, terephthalic acid, trimellitic anhydride, hexahydrophthalic anhydride, 1,6-cyclohexanedicarboxylic acid, dodecanedioic acid, and dimer acid.
• esterification catalyst conventionally known compounds can be used. Specifically, for example, tertiary amine compounds such as triethylamine, N,N-dimethylbenzylamine and N,N-dimethylaniline; quaternary ammonium salts such as trimethylbenzylammonium chloride and pyridinium chloride; phosphonium compounds such as triphenylphosphine, tetraphenylphosphonium chloride, tetraphenylphosphonium bromide and tetraphenylphosphonium iodide; Examples include organic metal salts such as zinc tennate.
• tertiary amine compounds such as triethylamine, N,N-dimethylbenzylamine and N,N-dimethylaniline
• quaternary ammonium salts such as trimethylbenzylammonium chloride and pyridinium chloride
• phosphonium compounds such as triphenylphosphine, tetraphen
• reaction method, reaction conditions, etc. when performing the above reaction are not particularly limited. Moreover, in the esterification reaction, it is more preferable to add a polymerization inhibitor and/or molecular oxygen to the reaction system in order to prevent gelation due to polymerization.
• the urethane (meth)acrylate is not particularly limited, and includes, for example, those obtained by a urethanization reaction of a polyisocyanate compound, a polyol compound, and a hydroxyl group-containing (meth)acrylate compound, those obtained by a urethanization reaction between a polyol compound and a (meth)acryloyl group-containing isocyanate compound, and those obtained by a urethanization reaction between a hydroxyl group-containing (meth)acrylate compound and a polyisocyanate compound.
• polyisocyanate compounds include 2,4-tolylene diisocyanate and its hydrides, isomers of 2,4-tolylene diisocyanate and their hydrides, diphenylmethane diisocyanate, hydrogenated diphenylmethane diisocyanate, hexamethylene diisocyanate, trimers of hexamethylene diisocyanate, isophorone diisocyanate, xylene diisocyanate, hydrogenated xylene diisocyanate, dicyclohexylmethane diisocyanate, tolidine diisocyanate, naphthalene diisocyanate, triphenyl Methane triisocyanate; Alternatively, Millionate MR, Coronate L (manufactured by Nippon Polyurethane Industry Co., Ltd.), Barnock D-750, Crisbon NX (manufactured by Dainippon Ink and Chemicals, Inc.), Desmodur L (manufactured
• polyol compounds include polyether polyols, polyester polyols, polybutadiene polyols, adducts of bisphenol A and alkylene oxides such as propylene oxide or ethylene oxide.
• the number average molecular weight of the polyether polyol is preferably in the range of 300-5,000, more preferably in the range of 500-3,000.
• Specific examples include polyoxyethylene glycol, polyoxypropylene glycol, polytetramethylene glycol, and polyoxymethylene glycol.
• the polyester polyol preferably has a number average molecular weight in the range of 1,000 to 3,000.
• a hydroxyl group-containing (meth)acrylate compound is a (meth)acrylate compound having at least one hydroxyl group in the molecule.
• the hydroxyl group-containing (meth)acrylate compounds include 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 3-hydroxybutyl (meth)acrylate, polyethylene glycol mono(meth)acrylate, polypropylene glycol mono(meth)acrylate and the like.
• a (meth)acryloyl group-containing isocyanate compound is a type of compound that shares at least one (meth)acryloyl group and an isocyanate group in the molecule.
• the reaction method in the above urethanization reaction is not particularly limited, and reaction conditions such as reaction temperature and reaction time may be appropriately set so as to complete the reaction, and are not particularly limited.
• reaction conditions such as reaction temperature and reaction time may be appropriately set so as to complete the reaction, and are not particularly limited.
• reaction conditions such as reaction temperature and reaction time may be appropriately set so as to complete the reaction, and are not particularly limited.
• reaction conditions such as reaction temperature and reaction time may be appropriately set so as to complete the reaction, and are not particularly limited.
• reaction conditions such as reaction temperature and reaction time may be appropriately set so as to complete the reaction, and are not particularly limited.
• reaction conditions such as reaction temperature and reaction time may be appropriately set so as to complete the reaction, and are not particularly limited.
• a urethanization catalyst in order to promote the urethanization reaction.
• the urethanization catalyst include tertiary amine compounds such as triethylamine and metal salts such as di-n-butyltin dilaurate, but any general urethanization catalyst can be used.
• the acrylic rubber particles (B) are particles containing an acrylic crosslinked rubber polymer obtained by an emulsion polymerization method, and are preferably multi-layered rubber particles having two or more layers containing an outermost layer containing a hard polymer (P) and a crosslinked rubber polymer (Q) in contact with and covering the outermost layer.
• the multi-layered rubber particles have, for example, a two-layer structure (QP) in which the core is a crosslinked rubber polymer (Q) - an outer shell (outermost layer) is a thermoplastic polymer (P), a three-layer structure (RQP) in which a core is a crosslinked rubber polymer (R) - an inner shell is a crosslinked rubber polymer (Q) - an outer shell (outermost layer) is a thermoplastic polymer (P), and a core is a crosslinked rubber polymer (Q) - a first inner shell is a crosslinked polymer (R) - a second inner shell is a crosslinked rubber polymer.
• Particles having a four-layer structure (QRQP) in which the (Q)-shell (outermost layer) is a thermoplastic polymer (P) can be mentioned.
• the mass ratio of a layer other than the outermost layer in the acrylic rubber particles (hereinafter, the layer other than the outermost layer may be referred to as an "inner layer"; for example, the above Q, R+Q, and Q+R+Q respectively correspond to the inner layer) to the outermost layer is preferably 50/50 to 95/5, and more preferably 60/40 to 90/10 for the inner layer/outermost layer.
• the ratio of the layer containing the crosslinked rubber polymer (Q) in the inner layer is preferably 20 to 70% by mass, more preferably 30 to 50% by mass.
• the average particle size of the acrylic rubber particles is preferably 0.05-0.5 ⁇ m, more preferably 0.06-0.4 ⁇ m, even more preferably 0.08-0.35 ⁇ m, and even more preferably 0.1-0.3 ⁇ m.
• acrylic rubber particles having an average particle size within such a range, particularly an average particle size of 0.1 to 0.3 ⁇ m it is possible to develop toughness with a small amount of compounding, so that the rigidity and surface hardness of the molded product are not impaired.
• the average particle size in the present specification is the average value (volume average particle size) in the volume-based particle size distribution measured by a light scattering method, or the average value of particle sizes measured from electron micrographs.
• the hard polymer (P) constituting the outermost layer of the acrylic rubber particles is a polymer having a glass transition temperature of 30°C or higher, preferably 50°C or higher, more preferably 60°C or higher, and even more preferably 70°C or higher.
• the upper limit of the glass transition temperature of the hard polymer (P) is not particularly limited.
• the composition of the hard polymer (P) is not particularly limited, it preferably contains a methacrylic acid alkyl ester having an alkyl group having 1 to 8 carbon atoms (hereinafter sometimes referred to as "methacrylic acid C 1-8 alkyl ester") unit and at least one monomer unit selected from the group consisting of a carboxyl group-containing monomer unit (x) and an epoxy group-containing monomer unit (y).
• methacrylic acid C 1-8 alkyl ester a methacrylic acid alkyl ester having an alkyl group having 1 to 8 carbon atoms
• the methacrylic acid alkyl ester unit indicates a structural unit introduced by polymerization of a methacrylic acid alkyl ester
• the carboxyl group-containing monomer unit indicates a structural unit introduced by polymerization of a carboxyl group-containing ethylenically unsaturated monomer
• the epoxy group-containing monomer unit indicates a structural unit introduced by polymerization of an epoxy group-containing ethylenically unsaturated monomer.
• methacrylic acid alkyl ester having an alkyl group having 1 to 8 carbon atoms for example, methyl methacrylate is preferable.
• Acrylic acid and methacrylic acid are preferable as the carboxyl group-containing monomer unit (x).
• epoxy group-containing monomer unit (y) examples include epoxy group-containing ethylenically unsaturated monomers such as glycidyl (meth)acrylate, allyl glycidyl ether, and 3,4-epoxycyclohexyl (meth)acrylate, with glycidyl (meth)acrylate being preferred.
• the content is preferably 80 to 99.9% by mass, more preferably 90 to 99.5% by mass, based on the mass of the hard polymer (P).
• the content thereof is preferably 0.1 to 20% by mass, more preferably 0.5 to 10% by mass, based on the mass of the hard polymer (P).
• the hard polymer (P) contains the epoxy group-containing monomer unit (y)
• its content is preferably 0.1 to 20% by mass, more preferably 0.5 to 10% by mass, based on the mass of the hard polymer (P).
• the hard polymer (P) may contain other monofunctional monomer units, for example, acrylic acid esters such as methyl acrylate, ethyl acrylate, propyl acrylate, n-butyl acrylate, and 2-ethylhexyl acrylate; and aromatic vinyl monomers such as styrene.
• a monofunctional monomer unit indicates a structural unit introduced by polymerization of a monofunctional monomer.
• the outermost layer may be a single layer made of one type of hard polymer (P), or may be a multiple layer made of two or more types of hard polymers (P).
• the crosslinked rubber polymer (Q) that constitutes the inner layer of the acrylic rubber particles contains acrylate ester monomer units.
• An acrylate monomer unit indicates a structural unit introduced by polymerization of an acrylate ester.
• the acrylate monomer units include acrylate units having an alkyl group having 1 to 8 carbon atoms, such as methyl acrylate, ethyl acrylate, propyl acrylate, n-butyl acrylate, and 2-ethylhexyl acrylate. From the viewpoint of the toughness of the cured product, n-butyl acrylate and 2-ethylhexyl acrylate are preferred, and n-butyl acrylate is more preferred.
• the crosslinked rubber polymer (Q) may contain monofunctional monomer units other than acrylic acid esters and polyfunctional monomer units.
• monofunctional monomer unit refers to a structural unit introduced by polymerization of a monofunctional monomer
• polyfunctional monomer unit refers to a structural unit introduced by polymerization of a polyfunctional monomer.
• the content of the acrylic ester monomer unit in the crosslinked rubber polymer (Q) is preferably 10 to 100% by mass, more preferably 15 to 95% by mass, based on the mass of the crosslinked rubber polymer (Q).
• the content of the monofunctional monomer unit other than the acrylic acid ester in the crosslinked rubber polymer (Q) is preferably 0 to 90% by mass, more preferably 5 to 85% by mass, based on the mass of the crosslinked rubber polymer (Q).
• the polyfunctional monomer unit in the crosslinked rubber polymer (Q) is preferably 0.01 to 3% by mass, more preferably 0.1 to 2% by mass, relative to the mass of the crosslinked rubber polymer (Q).
• composition of the crosslinked polymer (R) is not particularly limited as long as it does not impair the effects of the present invention, but it preferably comprises methyl methacrylate units, monofunctional monomer units other than methyl methacrylate, and polyfunctional monomer units.
• the methyl methacrylate unit indicates a structural unit introduced by polymerization of methyl methacrylate.
• the amount of methyl methacrylate units constituting the crosslinked polymer (R) is preferably 40 to 98.5% by mass, more preferably 80 to 95% by mass, based on the mass of the crosslinked polymer (R).
• the amount of monofunctional monomer units other than methyl methacrylate constituting the crosslinked polymer (R) is 1 to 59.5% by mass, preferably 5 to 20% by mass, based on the mass of the crosslinked polymer (R).
• monofunctional monomers other than methyl methacrylate are preferably acrylic acid esters such as methyl acrylate, ethyl acrylate, propyl acrylate, n-butyl acrylate and 2-ethylhexyl acrylate, and aromatic vinyl compounds such as styrene.
• the amount of the polyfunctional monomer units constituting the crosslinked polymer (R) is preferably 0.05 to 0.4% by mass, more preferably 0.1 to 0.3% by mass, based on the mass of the crosslinked polymer (R).
• the amount of the crosslinked polymer (R) is preferably 5-40% by mass, more preferably 7-35% by mass, and still more preferably 10-30% by mass, relative to the amount of the multi-layered rubber particles.
• acrylic acid esters used in the hard polymer (P), the crosslinked rubber polymer (Q), and the crosslinked polymer (R) include alkyl acrylates having an alkyl group having 1 to 8 carbon atoms, such as methyl acrylate, ethyl acrylate, n-propyl acrylate, n-butyl acrylate, s-butyl acrylate, t-butyl acrylate, n-butylmethyl acrylate, n-heptyl acrylate, 2-ethylhexyl acrylate, and n-octyl acrylate.
• These acrylic acid esters can be used singly or in combination of two or more. Among these, methyl acrylate and/or n-butyl acrylate are preferred.
• polyfunctional monomer units used in the crosslinked rubber polymer (Q) and the crosslinked polymer (R) include ethylene glycol dimethacrylate, propylene glycol dimethacrylate, triethylene glycol dimethacrylate, hexanediol dimethacrylate, ethylene glycol diacrylate, propylene glycol diacrylate, triethylene glycol diacrylate, allyl methacrylate, and triallyl isocyanurate.
• the monofunctional monomer units other than methyl methacrylate in the crosslinked polymer (R) and the monofunctional monomer units other than acrylic acid ester in the crosslinked rubber polymer (Q) may be any vinyl monomers that can be copolymerized with methacrylic acid esters or acrylic acid esters.
• aromatic vinyl monomers such as styrene, p-methylstyrene, o-methylstyrene, and vinylnaphthalene
• monomers vinyl halide monomers such as vinyl chloride, vinylidene chloride and vinylidene fluoride
• unsaturated carboxylic acid monomers such as acrylic acid, methacrylic acid and maleic anhydride
• maleimide monomers such as vinyl acetate, N-propylmaleimide, N-cyclohexylmaleimide and No-chlorophenylmaleimide.
• the thickness of the outermost layer of the acrylic rubber particles (B) is 3.5 nm or more, preferably 5 nm to 40 nm, more preferably 6 nm to 35 nm, still more preferably 7.5 to 30 nm. By setting the thickness of the outermost layer of the acrylic rubber particles (B) within the above range, the acrylic rubber particles (B) can be dispersed well in the curable resin composition.
• the glass transition temperature of the crosslinked rubber polymer (Q) constituting the inner layer of the acrylic rubber particles (B) is preferably 10°C or lower, more preferably 0°C or lower, and even more preferably -10°C or lower.
• the glass transition temperature of the outermost layer of the acrylic rubber particles (B) is preferably 50°C or higher, more preferably 60°C or higher, and even more preferably 70°C or higher.
• the weight average molecular weight of the hard polymer (P) constituting the outermost layer of the acrylic rubber particles (B) is preferably 25,000 to 100,000, more preferably 30,000 to 95,000, even more preferably 35,000 to 90,000. When the weight average molecular weight is within this range, the toughness of the cured product of the curable resin composition is improved.
• a part of the outermost layer of the acrylic rubber particles (B) is preferably covalently bonded to the inscribed crosslinked rubber polymer.
• Such a structure can be formed by including a polyfunctional monomer unit in the monomer units constituting the crosslinked rubber polymer inscribed in the outermost layer.
• the content of the polyfunctional monomer unit in the crosslinked rubber polymer inscribed in the outermost layer is preferably 0.01 to 3% by mass, more preferably 0.1 to 2% by mass.
• the method for producing the acrylic rubber particles (B) is not particularly limited, but specific examples include a method comprising the steps of emulsifying a monomer mixture containing a (meth)acrylic acid ester monomer to obtain a latex containing a multi-layered acrylic polymer; coagulating the latex containing a multi-layered acrylic polymer to obtain a slurry containing the acrylic rubber particles (B); washing and dehydrating the slurry; and drying the dehydrated slurry.
• a latex of acrylic rubber particles containing an outermost layer composed of a thermoplastic polymer (P), an inner shell composed of a crosslinked rubber polymer (Q) in contact with and covered with the outermost layer, and optionally a core composed of a crosslinked polymer (R) can be produced according to a conventional method by polymerizing in multiple stages using a monomer mixture, a polymerization initiator, an emulsifier, and the like.
• the polymerization initiator used in each polymerization is not particularly limited.
• the polymerization initiator include water-soluble inorganic initiators such as potassium persulfate and ammonium persulfate; redox initiators obtained by using inorganic initiators in combination with sulfites or thiosulfates; redox initiators obtained by using organic peroxides in combination with ferrous salts, sodium sulfoxylates, and the like.
• the polymerization initiator may be added to the reaction system all at once at the start of the polymerization, or may be added to the reaction system at the start of the polymerization and during the polymerization in consideration of the reaction rate and the like.
• the amount of the polymerization initiator to be used can be appropriately set, for example, so that the average particle size of the particles contained in the acrylic rubber particles is within the range described above.
• the emulsifier used in each polymerization is not particularly limited.
• the emulsifier include anionic emulsifiers such as long-chain alkylsulfonates, alkyl sulfosuccinates, and alkylbenzenesulfonates; nonionic emulsifiers such as polyoxyethylene alkyl ether and polyoxyethylene nonylphenyl ether; nonionic/anionic emulsifiers such as polyoxyethylene nonylphenyl ether sulfates such as sodium polyoxyethylene nonylphenyl ether sulfate, polyoxyethylene alkyl ether sulfates such as sodium polyoxyethylene alkyl ether sulfate, and alkyl ether carboxylates such as sodium polyoxyethylene tridecyl ether acetate.
• the amount of the emulsifier to be used can be appropriately set, for example, so that the average particle size of the particles contained in the acrylic rubber particles is within the range
• a chain transfer agent can be used in each polymerization to control the molecular weight.
• the chain transfer agent used for each polymerization is not particularly limited.
• Examples of the chain transfer agent include alkyl mercaptan compounds such as n-octyl mercaptan, n-dodecyl mercaptan, t-dodecyl mercaptan and n-hexadecyl mercaptan; xanthogen disulfide compounds such as dimethyl xanthogen disulfide and diethyl xanthogen disulfide; thiuram disulfide compounds such as tetrathiuram disulfide; and halogenated hydrocarbons such as carbon tetrachloride and ethylene bromide.
• the amount of the chain transfer agent to be used can be appropriately set within a range in which the polymer can be adjusted to have a predetermined molecular weight in each polymerization.
• the amount of the chain transfer agent used in the polymerization of the outermost layer varies depending on the amount of the polymerization initiator used in the polymerization of the outermost layer and the like, but it is preferably 0.05 to 2 parts by weight, more preferably 0.08 to 1 part by weight, with respect to 100 parts by weight of the total amount of monomers used in the polymerization of the outermost layer.
• the recovery of the acrylic rubber particles (B) from the emulsified latex is performed by coagulating the emulsified latex.
• Coagulation of latex can be performed by a known method.
• the solidification method a freezing solidification method, a salting out solidification method, an acid precipitation solidification method, and the like can be mentioned.
• the salting-out coagulation method is preferred because it can continuously produce high-quality coagulates.
• the coagulant that can be used in the present invention may be an aqueous solution of an inorganic acid or its salt, or an organic acid or its salt that has the property of coagulating and coagulating the emulsion polymerized latex.
• the emulsified latex used in the coagulation step may be a latex containing an acrylic multilayer structure polymer alone, a mixture of two or more latexes containing an acrylic multilayer structure polymer, or a mixture of a latex containing an acrylic multilayer structure polymer and at least one single-layer acrylic polymer latex.
• the slurry can be washed and dewatered using, for example, a filter press, a belt press, a Gina type centrifuge, a screw decanter type centrifuge, or the like. From the viewpoint of productivity and washing efficiency, it is preferable to use a screw decanter centrifuge. It is preferable to wash and dewater the slurry at least twice. As the number of times of washing and dehydration increases, the remaining amount of water-soluble components decreases. However, from the viewpoint of productivity, the number of times of washing and dehydration is preferably 3 or less.
• the moisture content of the coagulum after dehydration is preferably 5-50% by mass, more preferably 5-45% by mass, and even more preferably 5-40% by mass. It is preferable that the water content after dehydration of the coagulum is within the above range because the subsequent drying can be sufficiently performed and a coagulum having a suitable moisture content can be obtained after the drying.
• the turbidity of the wastewater discharged during dehydration is preferably 1000 or less, more preferably 700 or less, and even more preferably 400 or less. It is preferable to set the turbidity of the wastewater discharged during dehydration within the above range, because high solid-liquid separability can be obtained, thereby improving the product yield and preventing troubles such as clogging of the strainer of the discharge pump.
• the coagulum is dried so that the water content is preferably less than 0.2% by mass, more preferably less than 0.1% by mass.
• the acrylic rubber particles (B) have good dispersibility in the curable resin composition.
• the content of the acrylic rubber particles (B) in the curable resin composition is preferably 3-50% by mass, more preferably 4-40% by mass, and even more preferably 5-30% by mass, relative to the total amount of the curable resin composition.
• the content of the acrylic rubber particles (B) is 3% by mass or more, the toughness of the cured product is improved.
• the curable resin composition of the present invention may optionally contain a curing accelerator.
• a hardening accelerator A well-known thing can be used as a hardening accelerator.
• urea compounds such as 3-(3,4-dichlorophenyl)-1,1-dimethylurea (DCMU), etc.
• imidazole compounds such as 2-methylimidazole and 2-ethyl-4-methylimidazole
• organic phosphorus compounds such as triphenylphosphine
• borate compounds such as tetraphenylphosphinetetraphenylborate
• DBU cycloundecene
• the content of the curing accelerator is preferably 1 part by mass or more and 20 parts by mass or less, more preferably 2 parts by mass or more and 10 parts by mass or less, relative to 100 parts by mass of the curable resin. If the content of the curing accelerator is at least the lower limit of the above range, the curing speed will be more excellent. If the content of the curing accelerator is equal to or less than the upper limit of the above range, the toughness will be more excellent.
• curable resin composition of the present invention include, for example, antioxidants; release agents such as silicone oil, natural wax, and synthetic wax; powders such as glass beads, crystalline silica, fused silica, calcium silicate, and alumina; fibers such as glass fibers and carbon fibers; flame retardants such as antimony trioxide; dyes.
• antioxidants such as silicone oil, natural wax, and synthetic wax
• powders such as glass beads, crystalline silica, fused silica, calcium silicate, and alumina
• fibers such as glass fibers and carbon fibers
• flame retardants such as antimony trioxide
• the curable resin composition preferably contains an antioxidant from the viewpoint of suppressing oxidative deterioration of the resin and obtaining more excellent heat-resistant coloring resistance.
• antioxidant known antioxidants can be used, but from the viewpoint of antioxidant performance, at least one selected from the group consisting of phenol-based antioxidants, thioether-based antioxidants and phosphite-based antioxidants is preferable, and at least one selected from the group consisting of phenol-based antioxidants and thioether-based antioxidants is more preferable.
• Phenolic antioxidants include, for example, dibutylhydroxytoluene, 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane, 4,4'-butylidenebis(6-tert-butyl-m-cresol), stearyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, pentaerythritol-tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl ) propionate], bis[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionic acid][ethylenebis(oxyethylene)].
• stearyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate and pentaerythritol-tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate] are preferred.
• Thioether antioxidants include, for example, dilauryl-3,3'-thiodipropionate, ditridecyl-3,3'-thiodipropionate, dimyristyl-3,3'-thiodipropionate, distearyl-3,3'-thiodipropionate, laurylstearyl-3,3'-thiodipropionate, pentaerythritol tetrakis(3-laurylthiopropionate), Bis[2-methyl-4-(3-laurylthiopropionyloxy)-5-tert-butylphenyl]sulfide, octadecyldisulfide, mercaptobenzimidazole, 2-mercapto-6-methylbenzimidazole, 1,1'-thiobis(2-naphthol) (bis[3-(dodecylthio)propionic acid] 2,2-bis[[3-(dodecyl
• Phosphite-based antioxidants include, for example, triphenylphosphite, trisnonylphenylphosphite, tris(2,4-di-tert-butylphenyl)phosphite, tridecylphosphite, trioctylphosphite, trioctadecylphosphite, didecylmonophenylphosphite, dioctylmonophenylphosphite, diisopropylmonophenylphosphite, monobutyldiphenylphosphite, monodecyldiphenylphosphite, monooctyldiphenyl Phosphites, bis(2,6-di-tert-butyl-4-methylphenyl)pentaerythritol diphosphite, 2,2-methylenebis(4,6-di-tert-butylphenyl)oc
• the content of the antioxidant is preferably 0.0001 parts by mass or more and 10 parts by mass or less with respect to 100 parts by mass of the curable resin composition.
• the lower limit amount is more preferably 0.001 parts by mass or more, and more preferably 0.01 parts by mass or more.
• the upper limit amount is more preferably 6 parts by mass or less, and even more preferably 3 parts by mass or less. If the content of the antioxidant is at least the above lower limit, there is a tendency for the heat-resistant coloring to be more excellent. On the other hand, when the content of the antioxidant is equal to or less than the above upper limit value, a cured product with good surface appearance can be obtained.
• the method for producing the curable resin composition of the present invention is not particularly limited, and known methods can be used.
• a curable resin, acrylic rubber particles, and optionally a curing accelerator and other components may be mixed at the same time, or some components (for example, a curable resin and acrylic rubber particles) may be mixed in advance, and the mixture and the remaining components may be mixed.
• the mixing method is not particularly limited, and known mixers such as mechanical stirrers, planetary mixers, rotation/revolution mixers, mixing rolls such as three rolls, and kneaders can be used.
• the epoxy resin composition may be obtained by mixing the latex of the rubber-containing polymer and the epoxy resin, and then removing the aqueous phase.
• An epoxy resin composition may be obtained by mixing a rubber-containing polymer latex, an epoxy resin, and an organic solvent, and removing the aqueous phase and the organic phase.
• a cured product of the curable resin composition of the present invention can be obtained by adding a curing agent to the curable resin composition and curing the composition.
• the curing agent cures the curable resin composition and is used to adjust curability and cured product properties.
• curing agent those known as curing agents for curable resins can be used.
• Curing agents for epoxy resins include, for example, acid anhydrides, amine compounds, phenol compounds, latent curing agents, and cationic polymerization initiators.
• acid anhydrides include phthalic anhydride, methyltetrahydrophthalic anhydride, methylhexahydrophthalic anhydride, hexahydrophthalic anhydride, tetrahydrophthalic anhydride, trialkyltetrahydrophthalic anhydride, methylhimic anhydride, methylcyclohexene dicarboxylic anhydride, trimellitic anhydride, pyromellitic anhydride, benzophenone tetracarboxylic anhydride, ethylene glycol bis trimellitate, glycerol tristrimellitate, dodecenyl succinic anhydride, polyaze Line acid anhydride, poly(ethyloctadecanedioic acid) anhydride.
• methylhexahydrophthalic anhydride and hexahydrophthalic anhydride are preferred for applications requiring weather resistance, light resistance, heat resistance, and the like. These may be used individually by 1 type, and may use 2 or more types together.
• Amine compounds include, for example, 2,5(2,6)-bis(aminomethyl)bicyclo[2,2,1]heptane, isophoronediamine, ethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, diethylaminopropylamine, bis(4-amino-3-methyldicyclohexyl)methane, diaminodicyclohexylmethane, bis(aminomethyl)cyclohexane, bis(aminomethyl)norbornane, bis(4-aminocyclohexyl)methane, Diaminodiphenylsulfones such as metaphenylenediamine, diaminodiphenylmethane, diaminodiphenylsulfone, diaminodiethyldiphenylmethane, diethyltoluenediamine, 3,3'-diaminodiphenylsulfone (3,
• phenol compounds include phenol novolak resin, cresol novolak resin, bisphenol A, bisphenol F, bisphenol AD, and derivatives of diallylated products of these bisphenol compounds. These may be used individually by 1 type, and may use 2 or more types together.
• a latent curing agent is a compound that is solid at room temperature and liquefies when the epoxy resin composition is heat-cured to act as a curing agent.
• latent curing agents include dicyandiamide, carbohydrazide, oxalic acid dihydrazide, malonic acid dihydrazide, succinic acid dihydrazide, iminodiacetic acid dihydrazide, adipic acid dihydrazide, pimelic acid dihydrazide, suberic acid dihydrazide, azelaic acid dihydrazide, sebacic acid dihydrazide, dodecane dihydrazide, hexadecane dihydrazide Drazide, maleic dihydrazide, fumaric dihydrazide, diglycolic acid dihydrazide, tartaric acid dihydrazide, malic acid dihydrazide, isophthalic acid dihydrazide, terephthalic acid dihydrazide, 2,6-naphthoic acid dihydrazide, 4,4'-bisbenzene dihydrazide, 1,4-naphthoic
• cationic polymerization initiators examples include diallyliodonium salts, triallyl sulfonium salts and aliphatic sulfonium salts having BF 4 , PF 6 , AsF 6 and SbF 6 as counter anions.
• Commercially available products such as those manufactured by Kogyo Co., Ltd. can be used. These may be used individually by 1 type, and may use 2 or more types together.
• a radical initiator can be used as the curing agent when a compound having at least two polymerizable unsaturated bonds in the molecule such as an unsaturated polyester resin, epoxy (meth)acrylate, or urethane (meth)acrylate is used as the curing resin (A).
• radical initiators include organic peroxides such as benzoyl peroxide, cumene hydroperoxide, dicumyl peroxide, lauroyl peroxide, di-t-butyl peroxide, t-butyl hydroperoxide, methyl ethyl ketone peroxide, t-butyl peroxybenzoate, t-butyl peroxy-2-ethylhexanoate, and t-butyl peroxyoctanoate; and azo compounds such as azobisisobutyronitrile.
• organic peroxides such as benzoyl peroxide, cumene hydroperoxide, dicumyl peroxide, lauroyl peroxide, di-t-butyl peroxide, t-butyl hydroperoxide, methyl ethyl ketone peroxide, t-butyl peroxybenzoate, t-butyl peroxy-2-ethylhexanoate, and
• one or more selected from the group consisting of benzoyl peroxide, cumene hydroperoxide, dicumyl peroxide, and methyl ethyl ketone peroxide are preferred, and cumene hydroperoxide and methyl ethyl ketone peroxide are more preferred. These may be used alone or in combination of two or more.
• a radical initiator is optionally used with a curing coagent and/or cocatalyst.
• the curing aid is an additive that acts as a catalyst for the decomposition reaction (radical generation reaction) of the radical initiator, and includes metal salts of naphthenic acid or octenic acid (cobalt salts, tin salts, lead salts, etc.). Cobalt naphthenate is preferable from the viewpoint of improving toughness and appearance.
• a curing accelerator it is preferable to add 0.1 to 1 part by mass with respect to 100 parts by mass of the curable resin (A) immediately before the curing reaction in order to prevent the curing reaction from occurring rapidly.
• the co-catalyst is an additive that causes radical generation at low temperatures by decomposing the radical initiator even at low temperatures, and includes amine-based compounds such as N,N-dimethylaniline, triethylamine, and triethanolamine, but N,N-dimethylaniline is preferred because efficient reactions are possible.
• a promoter When a promoter is added, it is preferably added in an amount of 0.01 to 0.5 parts by weight per 100 parts by weight of component (A), or in an amount of 1 to 15 parts by weight per 100 parts by weight of the radical initiator.
• the content of the curing agent can be appropriately selected according to the type of curing agent.
• the curing agent is dicyandiamide, it is preferably 3 parts by mass or more and 20 parts by mass or less, more preferably 3 parts by mass or more and 12 parts by mass or less with respect to 100 parts by mass of the epoxy resin.
• the content of the curing agent is at least the lower limit of the above range, the adhesive strength after curing is more excellent. If the content of the curing agent is equal to or less than the upper limit of the above range, the pot life of the curable resin composition is more excellent.
• the method of adding the curing agent, curing aid, and co-catalyst to the curable resin composition is not particularly limited, and known methods can be used.
• the curable resin (A), the acrylic rubber particles (B), the curing agent, and optionally the curing accelerator and other components, which constitute the curable resin composition may be mixed at the same time, or after the curable resin composition is produced in advance, the curing agent, optionally the curing aid, the co-catalyst, etc. may be mixed.
• the mixing method is not particularly limited, and known mixers such as those described above can be used.
• the method for curing the curable resin composition of the present invention is not particularly limited, and conventionally employed curing methods for curable resin compositions can be used, typically a thermosetting method is used.
• the curable resin composition of the present invention is useful as an adhesive, a molding material, etc., because the acrylic rubber particles are well dispersed in the curable resin and a cured product with excellent surface smoothness can be obtained.
• adhesives examples include adhesives for the structure of vehicles such as automobiles, for civil engineering and construction, for electronic materials, for general office use, for medical use, and for industrial use.
• adhesives for electronic materials include interlayer adhesives for multilayer substrates such as build-up substrates, die bonding agents, adhesives for semiconductors such as underfills, underfills for BGA reinforcement, anisotropic conductive films (ACF), mounting adhesives such as anisotropic conductive pastes (ACP), and the like.
• molding materials include sheets, films, and fiber reinforced composite materials (FRP).
• Applications of the molding material include aircraft, automobiles, sporting goods, and windmills.
• the use of the curable resin composition of the present invention is not limited to the above, and it can be used for other uses.
• it can be used for various applications in which a thermosetting resin such as an epoxy resin is used.
• examples of such uses include paints, coating agents, insulating materials (including printed circuit boards, wire coatings, etc.), sealants, and the like.
• Examples of the encapsulant include potting, dipping, transfer mold encapsulation of capacitors, transistors, diodes, light emitting diodes, ICs, LSIs, etc., potting encapsulation of COBs, COFs, TABs of ICs and LSIs, underfills such as flip chips, encapsulation (including underfills for reinforcement) when mounting IC packages such as QFP, BGA, CSP, and the like.
• volume average particle size Using an emulsion containing acrylic rubber particles (B), the volume average particle size (median size) was determined by a light scattering method using a LA-950V2 laser diffraction/scattering particle size distribution analyzer manufactured by Horiba, Ltd.
• the thickness of the outermost layer was calculated from the following equation using the ratio of the value obtained by subtracting the total value of the monomer units constituting the outermost layer (d) from the particle diameter of the acrylic rubber particles (B) obtained by the above-described method and the total value of the monomer units constituting the acrylic rubber particles (B) to the total value of the monomer units constituting the acrylic rubber particles (B) as the inner layer ratio.
• Curing resin (A-1) Celoxide 2021P manufactured by Daicel Corporation
• Curable resin (A-2) jER828 manufactured by Mitsubishi Chemical Corporation
• Curing resin (A-3) Neopol 8250L manufactured by Japan U-Pica Co., Ltd.
• abbreviations indicate the following substances, respectively.
• MMA methyl methacrylate MA: methyl acrylate
• ALMA allyl methacrylate
• BA butyl acrylate
• St styrene
• MAA methacrylic acid
• GMA glycidyl methacrylate
• nOM n-octyl mercaptan
• Latex and coagulated powder of acrylic rubber particles (B-2) were obtained in the same manner as in Production Example 1, except that the amount of sodium alkyldiphenyl ether disulfonate added was changed to 1.88 parts by mass.
• the volume average particle size of the acrylic rubber particles (B-2) in the latex was 0.10 ⁇ m.
• a latex of acrylic rubber particles (B-3) was obtained in the same manner as in Production Example 1, except that the composition of the monomer mixture was changed as shown in Table 1.
• a coagulated powder of acrylic rubber particles (B-3) was obtained in the same manner as in Production Example 1, except that the amount of magnesium sulfate heptahydrate added was 6 parts by mass, the liquid temperature during aggregation was 40°C, and the liquid temperature during granulation was 90°C.
• the volume average particle size of the acrylic rubber particles (B-3) in the latex was 0.29 ⁇ m.
• Latex and coagulated powder of acrylic rubber particles (B-4) were obtained in the same manner as in Production Example 1, except that the composition of the monomer mixture was changed as shown in Table 1.
• the volume average particle size of the acrylic rubber particles (B-4) in the latex was 0.25 ⁇ m.
• Latex and coagulated powder of acrylic rubber particles (B-5) were obtained in the same manner as in Production Example 1 except that the amount of sodium alkyldiphenyl ether disulfonate added was 1.88 parts by mass and the composition of the monomer mixture was changed as shown in Table 1.
• the volume average particle diameter of the acrylic rubber particles (B-5) in the latex was 0.10 ⁇ m.
• a latex and a coagulum of acrylic rubber particles (B-6) were obtained in the same manner as in Production Example 1, except that the composition of the monomer mixture was changed as shown in Table 1.
• the volume average particle size of the acrylic rubber particles (B-6) in the latex was 0.26 ⁇ m.
• Example 1 95 parts by mass of the curable resin (A-1) and 5 parts by mass of the coagulated powder of the acrylic rubber particles (B-1) were added to a separable glass flask equipped with a mechanical stirrer equipped with a half-moon stirring blade, and the mixture was heated to 60° C. and stirred at a stirring speed of 600 rpm for 3 hours to obtain a curable resin composition (C-1).
• the dispersion state of the acrylic rubber particles (B-1) in the curable resin composition (C-1) was evaluated as A.
• Examples 2, 5 to 7, Comparative Examples 1 to 2> A curable resin composition (C-2, 5 to 9) and a cured product thereof were obtained in the same manner as in Example 1 except that the composition of the curable resin composition was changed as shown in Tables 2 and 3. Tables 2 and 3 show the evaluation results.
• a curable resin composition (C-3) was obtained in the same manner as in Example 1, except that the composition of the curable resin composition was changed as shown in Table 2.
• Table 2 shows the evaluation results.
• Example 4 A curable resin composition (C-4) and a cured product thereof were obtained in the same manner as in Example 3, except that the composition of the curable resin composition was changed as shown in Table 2. Table 2 shows the evaluation results.
• the curable resin compositions obtained in Examples 1 to 7 are excellent in the dispersibility of the acrylic rubber particles and can give cured products with excellent surface smoothness.
• the curable resin compositions obtained in Comparative Examples 1 and 2 had low dispersibility of the acrylic rubber particles, and the surface smoothness of the cured products was low due to the remaining coagulum of the acrylic rubber particles.

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