WO2023128012A1 - Fibre composite biodégradable et son procédé de fabrication - Google Patents
Fibre composite biodégradable et son procédé de fabrication Download PDFInfo
- Publication number
- WO2023128012A1 WO2023128012A1 PCT/KR2021/020258 KR2021020258W WO2023128012A1 WO 2023128012 A1 WO2023128012 A1 WO 2023128012A1 KR 2021020258 W KR2021020258 W KR 2021020258W WO 2023128012 A1 WO2023128012 A1 WO 2023128012A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- pla
- composite fiber
- polylactic acid
- pha
- Prior art date
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 53
- 239000002131 composite material Substances 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 238000000034 method Methods 0.000 title claims description 4
- 239000004626 polylactic acid Substances 0.000 claims abstract description 45
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 claims description 37
- 238000002844 melting Methods 0.000 claims description 29
- 230000008018 melting Effects 0.000 claims description 21
- 238000000691 measurement method Methods 0.000 claims description 9
- 238000009987 spinning Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 8
- 230000005855 radiation Effects 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 5
- 238000009966 trimming Methods 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 3
- 229920006240 drawn fiber Polymers 0.000 claims 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 13
- 229920000903 polyhydroxyalkanoate Polymers 0.000 description 13
- 239000000155 melt Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 8
- 208000034530 PLAA-associated neurodevelopmental disease Diseases 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 5
- 238000006065 biodegradation reaction Methods 0.000 description 4
- 239000004745 nonwoven fabric Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000000518 rheometry Methods 0.000 description 3
- 229920000954 Polyglycolide Polymers 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229920003232 aliphatic polyester Polymers 0.000 description 2
- 229920006237 degradable polymer Polymers 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920001610 polycaprolactone Polymers 0.000 description 2
- 239000004633 polyglycolic acid Substances 0.000 description 2
- 230000002285 radioactive effect Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 229920006167 biodegradable resin Polymers 0.000 description 1
- 150000001718 carbodiimides Chemical class 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/02—Heat treatment
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
Definitions
- PLA has a problem in that biodegradation occurs slowly in a daily environment because biodegradation proceeds under certain conditions of 60 ° C. or higher and 70% or higher moisture.
- the present invention is formed of a sheath part and a core part, and the biodegradability of PLA can be further improved by including low melting point PLA and PHA in the sheath part and using PLA and PHA together in the core part.
- 1 is a flow chart showing the manufacturing method of the present invention.
- the cis part solvent may be mixed with 50 to 95% by weight of low melting point polylactic acid (PLA), 3 to 45% by weight of polyhydroxyalkanoate (PHA) and 0.1 to 10% by weight of a compatibilizer, preferably More specifically, it may be prepared by mixing 75 to 92% by weight of low-melting polylactic acid (PLA), 5 to 20% by weight of polyhydroxyalkanoate (PHA), and 0.5 to 5% by weight of a compatibilizer.
- PLA low melting point polylactic acid
- PHA polyhydroxyalkanoate
- a compatibilizer preferably More specifically, it may be prepared by mixing 75 to 92% by weight of low-melting polylactic acid (PLA), 5 to 20% by weight of polyhydroxyalkanoate (PHA), and 0.5 to 5% by weight of a compatibilizer.
- the stretching may be performed at a stretching ratio of 1.2 to 6.0, preferably at a stretching ratio of 2 to 4.
- the melt was spun at a temperature of 260° C. at a speed of 1,000 m/min using a spinneret for sheath-core type composite fibers, and the resulting unstretched fibers were drawn at a draw ratio of 3.0. Thereafter, a heat treatment was performed at 50° C., and a fiber having 5 denier was cut to a size of 40 mm to prepare a composite fiber. Conditions according to the manufacture of composite fibers are shown in Table 2 below.
- Biodegradability Measure the biodegradability for 60 days according to the ASTM D5338 standard
- Radiation rating Evaluate the number of troubles such as trimming and drop that occur during one hour per radiation position by classifying them into S to D (S: 0 times, A: 1 time, B: 2-3 times, C: 4-6 times) times, D: 7 times or more)
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Multicomponent Fibers (AREA)
Abstract
La présente invention a pour objectif de réaliser une fibre composite biodégradable ayant une excellente biodégradabilité et une excellente aptitude au filage. La présente invention concerne une fibre composite biodégradable comprenant : de 30 à 70 % en poids d'une portion centrale contenant de l'acide polylactique (PLA) ; et de 30 à 70 % en poids d'une portion de gaine contenant de l'acide polylactique (PLA).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2021-0189379 | 2021-12-28 | ||
| KR1020210189379A KR102517291B1 (ko) | 2021-12-28 | 2021-12-28 | 생분해성 복합섬유 및 이를 제조하는 방법 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2023128012A1 true WO2023128012A1 (fr) | 2023-07-06 |
Family
ID=85936557
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/KR2021/020258 WO2023128012A1 (fr) | 2021-12-28 | 2021-12-30 | Fibre composite biodégradable et son procédé de fabrication |
Country Status (2)
| Country | Link |
|---|---|
| KR (1) | KR102517291B1 (fr) |
| WO (1) | WO2023128012A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118166550A (zh) * | 2024-03-13 | 2024-06-11 | 杭州易川塑业有限公司 | 一种环保网布用丙纶包覆丝及其制备方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20050068593A (ko) * | 2003-12-30 | 2005-07-05 | 주식회사 휴비스 | 숭고성 및 내구성이 향상된 폴리락트산계 복합섬유의제조방법 |
| KR20100097486A (ko) * | 2009-02-26 | 2010-09-03 | 코오롱글로텍주식회사 | 생분해성 섬유 및 이의 제조방법, 이로부터 제조된 부직포 |
| KR20110020786A (ko) * | 2008-05-30 | 2011-03-03 | 킴벌리-클라크 월드와이드, 인크. | 폴리락트산 섬유 |
| JP2018525170A (ja) * | 2015-08-28 | 2018-09-06 | フィテサ ノンウォーヴン、インコーポレイテッドＦｉｔｅｓａ Ｎｏｎｗｏｖｅｎ， Ｉｎｃ． | 高含有量のバイオ系材料を有する吸収性物品 |
| KR20210045153A (ko) * | 2019-10-16 | 2021-04-26 | 주식회사 휴비스 | 저융점 폴리에스테르 섬유를 포함하는 캐빈에어필터용 부직포 |
| KR20210146168A (ko) * | 2020-05-26 | 2021-12-03 | 도레이첨단소재 주식회사 | 생분해성 복합섬유 및 이를 포함하는 부직포 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5910545A (en) * | 1997-10-31 | 1999-06-08 | Kimberly-Clark Worldwide, Inc. | Biodegradable thermoplastic composition |
-
2021
- 2021-12-28 KR KR1020210189379A patent/KR102517291B1/ko active IP Right Grant
- 2021-12-30 WO PCT/KR2021/020258 patent/WO2023128012A1/fr unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20050068593A (ko) * | 2003-12-30 | 2005-07-05 | 주식회사 휴비스 | 숭고성 및 내구성이 향상된 폴리락트산계 복합섬유의제조방법 |
| KR20110020786A (ko) * | 2008-05-30 | 2011-03-03 | 킴벌리-클라크 월드와이드, 인크. | 폴리락트산 섬유 |
| KR20100097486A (ko) * | 2009-02-26 | 2010-09-03 | 코오롱글로텍주식회사 | 생분해성 섬유 및 이의 제조방법, 이로부터 제조된 부직포 |
| JP2018525170A (ja) * | 2015-08-28 | 2018-09-06 | フィテサ ノンウォーヴン、インコーポレイテッドＦｉｔｅｓａ Ｎｏｎｗｏｖｅｎ， Ｉｎｃ． | 高含有量のバイオ系材料を有する吸収性物品 |
| KR20210045153A (ko) * | 2019-10-16 | 2021-04-26 | 주식회사 휴비스 | 저융점 폴리에스테르 섬유를 포함하는 캐빈에어필터용 부직포 |
| KR20210146168A (ko) * | 2020-05-26 | 2021-12-03 | 도레이첨단소재 주식회사 | 생분해성 복합섬유 및 이를 포함하는 부직포 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118166550A (zh) * | 2024-03-13 | 2024-06-11 | 杭州易川塑业有限公司 | 一种环保网布用丙纶包覆丝及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR102517291B1 (ko) | 2023-04-03 |
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