WO2023125282A1 - Pièce en alliage d'aluminium modifiée composite à haute plasticité et son procédé de préparation - Google Patents

Pièce en alliage d'aluminium modifiée composite à haute plasticité et son procédé de préparation Download PDF

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WO2023125282A1
WO2023125282A1 PCT/CN2022/141397 CN2022141397W WO2023125282A1 WO 2023125282 A1 WO2023125282 A1 WO 2023125282A1 CN 2022141397 W CN2022141397 W CN 2022141397W WO 2023125282 A1 WO2023125282 A1 WO 2023125282A1
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aluminum
alloy
aluminum alloy
titanium
rare earth
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PCT/CN2022/141397
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English (en)
Chinese (zh)
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彭珞洲
答建成
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上海耀鸿科技股份有限公司
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Priority to EP22914536.2A priority Critical patent/EP4321641A1/fr
Priority to KR1020237039152A priority patent/KR20230170749A/ko
Publication of WO2023125282A1 publication Critical patent/WO2023125282A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C22C1/03—Making non-ferrous alloys by melting using master alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C22C1/026—Alloys based on aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/06—Making non-ferrous alloys with the use of special agents for refining or deoxidising
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/043—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent

Definitions

  • the invention relates to the technical field of alloy materials and preparation, in particular to a high-plastic composite modified aluminum alloy product and a preparation method thereof.
  • Aluminum alloy is the most widely used non-ferrous metal structural material in industry, and has been widely used in aviation, aerospace, automobile, machinery manufacturing, shipbuilding and chemical industry.
  • Cast aluminum alloy has the characteristics of casting fluidity, good air tightness, small shrinkage rate and small thermal cracking tendency, etc., and it has become the first choice material for lightweight automobile wheels.
  • aluminum alloy wheel parts require medium strength and higher ductility to avoid instantaneous fracture of the wheel in the event of frontal impact and side impact (within the design load bearing range).
  • the present invention provides a high-plastic composite modified aluminum alloy product and a preparation method thereof, which can further improve the plasticity and mechanical strength of the aluminum alloy.
  • Step S1 providing an aluminum alloy melt
  • Step S2 providing a modifier
  • the modifier is a combination of rare earth aluminum alloy, aluminum-strontium master alloy, aluminum-titanium or aluminum-titanium-boron master alloy,
  • the modifier is a combination of composite rare earth aluminum alloy, aluminum titanium or aluminum titanium boron intermediate alloy, and the composite rare earth aluminum alloy contains strontium, titanium or titanium boron, and rare earth metals,
  • the rare earth metal in the rare earth aluminum alloy and the composite rare earth aluminum alloy is any one or more of lanthanum, cerium, and yttrium;
  • Step S3 adding the modifying agent to the aluminum alloy melt under an inert gas atmosphere and melting to obtain a modified aluminum alloy melt;
  • Step S4 using the modified aluminum alloy melt to perform casting to obtain the cast aluminum alloy biscuit;
  • Step S5 performing heat treatment on the aluminum alloy green body, wherein the heat treatment includes:
  • Water quenching treatment adding the aluminum alloy biscuit after solid solution treatment into a water bath at a temperature of 60-70°C, and quenching water for 2-4 minutes;
  • step S1 includes:
  • composition of the aluminum alloy master ingot is hypoeutectic aluminum alloy or eutectic aluminum alloy.
  • the modifier is a combination of rare earth aluminum alloy, aluminum-strontium master alloy, aluminum-titanium or aluminum-titanium-boron master alloy, wherein the aluminum-strontium master alloy and the aluminum-titanium or aluminum-titanium The boron master alloy is added at intervals,
  • the rare earth aluminum alloy is added first, or added together with the first added party, or added between the addition of the aluminum-strontium master alloy and the aluminum-titanium or aluminum-titanium-boron master alloy.
  • step S3 includes:
  • Step S301 adding the rare earth aluminum alloy into the aluminum alloy melt and melting to obtain a first homogeneously mixed melt
  • Step S302 adding the aluminum-strontium master alloy into the first homogeneously mixed melt and continuing to smelt to obtain a second homogeneously mixed melt;
  • Step S303 adding the aluminum-titanium or aluminum-titanium-boron master alloy into the second homogeneously mixed melt and continuing melting to obtain the modified aluminum alloy.
  • the modifying agent is a combination of composite rare earth aluminum alloy, aluminum titanium or aluminum titanium boron master alloy, and the step S3 includes:
  • Step S310 adding the composite rare earth aluminum alloy into the aluminum alloy melt and melting to obtain a fourth uniformly mixed melt
  • Step S320 adding the aluminum-titanium or aluminum-titanium-boron master alloy into the fourth homogeneously mixed melt and continuing melting to obtain the modified aluminum alloy.
  • the preparation of the composite rare earth aluminum alloy includes:
  • Step S211 providing the aluminum melt
  • Step S212 providing an aluminum-strontium master alloy, an aluminum-titanium or aluminum-titanium-boron master alloy, and a rare earth aluminum master alloy, wherein the rare earth metal in the rare earth aluminum master alloy is one or more selected from lanthanum, cerium, and yttrium;
  • Step S213 under an inert gas atmosphere, sequentially add the rare earth aluminum master alloy, aluminum strontium master alloy, aluminum titanium or aluminum titanium boron master alloy into the aluminum melt and melt to obtain the composite rare earth alloy.
  • the modifier accounts for 0.4-0.6wt% of the total amount of the modified aluminum alloy melt, and the mass ratio of the rare earth metal: strontium: titanium or the total amount of titanium boron is 1: (0.1-1.2) : (0.1-1.2).
  • the heating rate in the solution treatment is controlled at 1.5-3° C./min, and the holding time is controlled at 120-180 min.
  • the solid solution treatment, the quenching treatment, and the aging treatment are continuous treatments, and the water bath is a circulating water bath. After the quenching treatment, before the aging treatment, the cast aluminum The temperature of the alloy green body is kept above 55°C.
  • the temperature is raised from 110-140°C to 160-200°C at a heating rate of 2-4°C/min, and then naturally cooled to room temperature.
  • the high-plastic composite modified aluminum alloy product according to the second aspect of the present invention is prepared by the preparation method described in any of the above-mentioned embodiments, and the tensile strength of the high-plastic composite modified aluminum alloy product is: 280MPa or more, the yield strength is 200MPa or more, and the elongation is 12% or more.
  • the aluminum alloy is modified by introducing rare earth metals, and the casting is treated in combination with a specific heat treatment process, so that its plasticity (elongation rate) can be greatly improved ), reduce the occurrence of brittle cracks, and at the same time improve its mechanical strength to meet the needs of aviation, aerospace, and automotive fields.
  • Fig. 1 is the metallographic structure image of aluminum alloy parts in different stages, wherein, (a) is the image of A356 aluminum alloy before heat treatment, (b) is the image of A356 aluminum alloy after heat treatment, (c) is embodiment 1 In (d) is the image after compound modification and heat treatment in Example 1.
  • Step S1 providing an aluminum alloy melt.
  • an aluminum alloy melt is prepared.
  • Purification treatment may include the following steps, for example:
  • Step S11 providing an aluminum alloy ingot
  • Step S12 removing the oxide layer on the surface of the aluminum alloy ingot
  • Step S13 cleaning and drying the aluminum alloy ingot from which the scale layer has been removed
  • Step S14 melting the dried aluminum alloy ingot to obtain an initial melt
  • Step S15 refining the initial melt to obtain the aluminum alloy melt.
  • the oxide scale layer on the surface is first removed, then cleaned to remove surface scum, smelted after drying, and the melt is refined.
  • the specific refining process will be described in detail later.
  • undesired impurities such as Fe, oxides, etc. can be removed. It is beneficial to further improve the modification and refinement of rare earth alloys.
  • Fe and its oxides can be removed by adding manganese or aluminum-manganese alloy to form surface scum, for example.
  • the aluminum alloy melt for example, it may be an aluminum-magnesium alloy, an aluminum-silicon alloy, an aluminum-silicon-magnesium alloy, etc., which is not specifically limited in the present invention.
  • Step S2 providing a modifier.
  • the modifier is a combination of rare earth aluminum alloy, aluminum strontium master alloy, aluminum titanium or aluminum titanium boron master alloy, or the modifier is a combination of compound rare earth aluminum alloy, aluminum titanium or aluminum titanium boron master alloy ,
  • the composite rare earth aluminum alloy contains strontium, titanium or titanium boron, and rare earth metals,
  • the rare earth metal in the rare earth aluminum alloy and the composite rare earth aluminum alloy is any one or more of lanthanum, cerium, and yttrium.
  • the modifier is a combination of rare earth aluminum alloy, aluminum strontium master alloy, aluminum titanium or aluminum titanium boron master alloy.
  • the aluminum-strontium master alloy is the modifier
  • the aluminum-titanium master alloy or the aluminum-titanium-boron master alloy is the refiner. That is, conventional modifiers and refiners can be used.
  • the modifier and/or the refiner commercially available materials can be used, or the corresponding metal strontium, titanium, titanium & boron can be weighed and melted in aluminum melt to form A homogeneous alloy is prepared.
  • rare earth aluminum alloys are further introduced to overcome the limitation of mechanical properties due to the "poisoning" reaction between modifiers and refiners.
  • the rare earth metal in the rare earth aluminum alloy considering the strontium in the modifier and the titanium and boron in the refiner, the group IIIB elements whose electronic structure is in between can be selected. In comprehensive consideration of its stability, resources, etc., preferably, one or more of yttrium, lanthanum in lanthanide metals, and cerium are used.
  • the rare earth aluminum alloy for example, one or more of commercially available Al-10Ce, Al-20Ce, Al-20La, Al-10La, Al-20Y, and Al-10Y can be used.
  • the rare earth aluminum alloy can also be prepared by itself, for example, it can be prepared by the following method:
  • the rare earth aluminum alloy is obtained by standing for a predetermined time and pouring.
  • the aluminum melt can be treated by using commercially available high-purity aluminum ingots with reference to the above-mentioned purification treatment of aluminum alloy ingots, which will not be repeated here.
  • aluminum-strontium master alloys aluminum-titanium master alloys or aluminum-titanium-boron master alloys, and rare-earth aluminum alloys
  • descaling, ultrasonic cleaning, and refining can be performed sequentially, respectively.
  • unwanted impurities and oxides can be further removed, which is beneficial to improving the refinement and modification of the composite rare earth alloy as a product.
  • the modifier is a combination of composite rare earth aluminum alloy, aluminum titanium or aluminum titanium boron master alloy.
  • the composite rare earth aluminum alloy can be prepared by melting and refining the above rare earth aluminum alloy, aluminum strontium master alloy, aluminum titanium or aluminum titanium boron master alloy, and aluminum melt.
  • the preparation of the complex rare earth aluminum alloy may include:
  • Step S211 providing aluminum melt
  • Step S212 providing an aluminum-strontium master alloy, an aluminum-titanium or aluminum-titanium-boron master alloy, and a rare earth aluminum alloy, wherein the rare earth metal in the rare earth aluminum alloy is one or more selected from lanthanum, cerium, and yttrium;
  • Step S213 adding the rare earth aluminum alloy, aluminum strontium master alloy, aluminum titanium or aluminum titanium boron master alloy into the aluminum melt under an inert gas atmosphere and melting to obtain the composite rare earth alloy.
  • the aluminum-strontium master alloy is added separately from the aluminum-titanium or aluminum-titanium-boron master alloy, and the rare earth aluminum alloy is added before the aluminum-strontium master alloy and the aluminum-titanium or aluminum-titanium-boron master alloy, or It is added together with the first addition, or added between the addition of the aluminum-strontium master alloy and the aluminum-titanium or aluminum-titanium-boron master alloy.
  • the rare earth aluminum alloy, the aluminum-strontium master alloy, the aluminum-titanium or aluminum-titanium-boron master alloy are sequentially added to the aluminum melt at intervals.
  • step S3 under an inert gas atmosphere, the modifier is added to the aluminum alloy melt and smelted to obtain the modified aluminum alloy melt.
  • the modifier is added to the aluminum melt for further melting under an inert gas atmosphere to obtain a modified aluminum alloy melt.
  • the mutual poisoning effect between the modifying agent and the refining agent can be greatly overcome, the addition amount of modifying agent and refining agent can be increased, and at the same time it can Improves the effect of metamorphism and refinement.
  • modifier being a rare earth aluminum alloy, an aluminum strontium master alloy, an aluminum titanium or an aluminum titanium boron master alloy:
  • the rare earth aluminum alloy is added first, or together with the first added party, or at the The aluminum-strontium master alloy and the aluminum-titanium or aluminum-titanium-boron master alloy are interstitially added.
  • the step S3 may specifically include:
  • Step S301 adding the rare earth aluminum alloy into the aluminum melt and melting to obtain a first homogeneously mixed melt
  • Step S302 adding the aluminum-strontium master alloy into the first homogeneously mixed melt and continuing to smelt to obtain a second homogeneously mixed melt;
  • Step S303 adding the aluminum-titanium or aluminum-titanium-boron master alloy into the second homogeneously mixed melt and continuing melting to obtain the modified aluminum alloy.
  • the step S3 includes:
  • Step S310 adding the composite rare earth aluminum alloy into the aluminum melt and melting to obtain a fourth homogeneously mixed melt
  • Step S320 adding the aluminum-titanium or aluminum-titanium-boron master alloy into the fourth homogeneously mixed melt and continuing melting to obtain the modified aluminum alloy.
  • the rare earth aluminum alloy, modifier, refining agent, and aluminum are smelted in advance to obtain a composite rare earth aluminum alloy, it can be prepared by adding it to the above aluminum melt at one time.
  • a refiner to the composite rare earth aluminum alloy when it is completely melted and mixed with the aluminum alloy. That is, aluminum-titanium master alloy or aluminum-titanium-boron master alloy controls grain growth.
  • the modifier preferably accounts for 0.4-0.6 wt% of the total amount of the modified aluminum alloy.
  • the refining in any of the above steps that is, the refining in the process of purifying the aluminum melt, the refining in the process of preparing the rare earth aluminum alloy, and the refining of each melt in the composite rare earth aluminum alloy can be carried out in the following manner:
  • the addition of the refining agent accounts for 0.1 to 0.3% of the mass of the added melt
  • the addition of the slag remover accounts for 0.1 to 0.3% of the mass of the added melt
  • the components of the refining agent contain by mass:
  • the components of the slag remover contain by mass:
  • the hydrogen content is estimated by testing the density of the melt, that is to say, the closer the melt density is to its theoretical density (slightly different according to the different components contained in the alloy, roughly around 2.7g/cm 3 ), then Indicates that the hydrogen contained in it is lower. For example, it can be set that when the density of the melt is less than 2.65g/cm 3 , the refining process is performed; when the density of the melt is greater than or equal to 2.65g/cm 3 , the refining process is not performed or the refining process is terminated. deal with.
  • Step S4 casting the modified aluminum alloy melt to obtain a modified aluminum alloy biscuit.
  • the obtained modified aluminum alloy melt is cast into a mold to obtain the modified aluminum alloy green body.
  • Step S5 performing heat treatment on the modified aluminum alloy biscuit.
  • the inventor has developed a corresponding heat treatment process on the basis of repeated research.
  • the heat treatment includes:
  • Water quenching treatment adding the aluminum alloy biscuit after solid solution treatment into a water bath at a temperature of 60-70°C, and quenching water for 2-4 minutes;
  • the aluminum alloy biscuit is successively subjected to solution treatment, water quenching treatment, and aging treatment.
  • the casting is rapidly cooled, so that the strengthening components are dissolved in the alloy to the maximum extent and then fixed and stored at room temperature.
  • the rise of temperature and the extension of time will result in the recombination of atoms in the supersaturated solid solution lattice, forming a solute atom-enriched region (called the G-PI region) and disappearing of the G-PI region.
  • the atoms of the second phase segregate according to a certain rule and form a G-PII region, forming a metastable second phase (transition phase), a large number of G-PII regions and a small amount of metastable phase combine and the metastable phase transforms into a stable phase ,
  • the second phase particle aggregation The second phase particle aggregation.
  • low-temperature aging is first adopted, so that more phase transitions are in the GP region and the ⁇ 1 region, thereby ensuring sufficient elongation.
  • the heating rate in the solution treatment is controlled at 1.5-3°C/min, and the holding time is controlled at 120-180min.
  • the rose-like ⁇ -Al phase and the rounder spherical ⁇ -Al phase can be further increased, the primary ⁇ -Al phase can be refined, and the number of dendrites can be reduced.
  • the solid solution treatment, the quenching treatment, and the aging treatment are continuous treatments, and the water bath is a circulating water bath.
  • the water bath is a circulating water bath.
  • the temperature is raised from 110-140°C to 160-200°C at a heating rate of 2-4°C/min, and then naturally cooled to room temperature.
  • the cooling rate in the aging treatment stage By controlling the cooling rate in the aging treatment stage, the introduction of defects can be greatly reduced, which helps to improve its plasticity and maintain a high level of mechanical strength.
  • Aluminum alloy aluminum-silicon-magnesium alloy (A356) (purchased from: Shandong Weiqiao Aluminum Industry)
  • High-purity aluminum ingot (purchased from Chinalco, composition: Al (99.99%), Fe ⁇ 0.1%, impurity ⁇ 0.05%)
  • Melting first add the preheated aluminum-silicon-magnesium alloy A356 into the pre-heating melting furnace, and heat and melt it into aluminum water within the range of 760 degrees.
  • Degassing and slag removal After melting into aluminum water, nitrogen (or argon) is introduced and refining agent (0.3wt% refining agent) is blown into the aluminum water, and the ventilation time is controlled at 15 minutes.
  • Al-Sr master alloy purchased from Nantong Angshen Metal Materials Co., Ltd., composition: Al-10Sr, Fe ⁇ 0.05.
  • Pretreatment Use a grinder to clean the scale and surface of the Al-Sr master alloy.
  • Ultrasonic cleaning put the pretreated aluminum-strontium master alloy into an ultrasonic cleaning tank for ultrasonic treatment.
  • Drying put the cleaned aluminum-strontium master alloy into an oven and bake at 60-100°C for 30-60 minutes.
  • Refining treatment After the aluminum-strontium master alloy is melted, it is refined. The molten high-purity aluminum is refined by feeding the Ar+graphite automatic degassing stirring rod. Refining with Ar blowing at 730-750°C for 5-10 minutes, the amount of refining being blown in is 0.1-0.3% of the melt, and kept at 3-5 minutes. During the refining process, there should be no boiling bubbles on the upper surface of the aluminum liquid.
  • Refining agent refining treatment of Al-Ti-B master alloy
  • Aluminum-titanium-boron master alloy purchased from Nantong Angshen Metal Materials Co., Ltd. (composition and content: Ti: 5%, B: 1%, the rest: Al)
  • Pretreatment Use a grinder to clean the oxide skin and surface layer on the surface of the high-purity aluminum ingot.
  • Ultrasonic cleaning Put the pretreated high-purity aluminum ingot into the cleaning agent for ultrasonic treatment.
  • Drying Put the high-purity aluminum ingot after ultrasonic cleaning into an oven and bake at 60-100°C for 30-60 minutes.
  • Refining treatment is performed after the high-purity aluminum is melted. Specifically: Refining the molten high-purity aluminum through the Ar+graphite automatic degassing stirring rod. Refining by blowing Ar at 740-760°C for 5-10 minutes, the amount of refining being blown in is 0.1-0.3% of the melt, and kept for 3-5 minutes. After that, let it stand for 10-20 minutes, put 0.1-0.3% scum remover in it to make it evenly disperse, and remove the scum on the surface.
  • Refining treatment The whole process is under the protection of argon atmosphere, and the refining treatment is performed after the rare earth aluminum-lanthanum alloy is melted. Feed the Ar+graphite automatic degassing stirring rod to refine the melted one. Refining with Ar blowing at 760-780°C for 5-10 minutes, the amount of refining being blown in is 0.1-0.3% of the melt, and kept at 3-5 minutes. During the refining process, there should be no boiling bubbles on the upper surface of the aluminum liquid. Remove scum on the surface of the melt: put in 0.1-0.3% slag remover in 15-20 minutes and spread evenly to remove the scum on the surface.
  • the aluminum melt, the rare earth aluminum alloy, the aluminum-strontium master alloy, and the aluminum-titanium-boron master alloy are respectively prepared through the above, and then mixed and smelted to obtain a composite rare earth alloy.
  • the rare earth aluminum alloy is firstly added to the aluminum melt, then the aluminum strontium alloy is added, and finally the aluminum titanium boron alloy is added. details as follows:
  • Step 1 Ingredients: Preheat the high-purity aluminum, aluminum-titanium-boron master alloy, aluminum-strontium master alloy, and rare earth aluminum alloy obtained above according to the required mass percentage.
  • high-purity aluminum 4.8 parts
  • aluminum-titanium-boron master alloy 0.2 parts
  • aluminum-strontium master alloy 60 parts
  • rare earth aluminum alloy 35 parts.
  • Step 2 Adding and melting the rare earth aluminum alloy: For the above aluminum melt, first heat the above purified rare earth aluminum alloy to 780-820°C to soften before melting, and then control the overall temperature of the aluminum melt at 760-820°C 780°C, add rare earth aluminum alloy into the aluminum melt for heat preservation.
  • the whole process adopts the protection of argon atmosphere and melts the rare earth aluminum alloy.
  • Step 3 After the rare earth aluminum alloy is completely melted, the temperature is controlled at 750-770° C. and stirred for 5-10 minutes.
  • the whole process is protected by an argon atmosphere, and the stirring rod is made of graphite material and preheated to 400-500°C before stirring.
  • Step 4 heat-preserve the melted melt at 740-760° C. and control the heat-retaining time within 5-20 minutes. In this stage, an alloying reaction occurs.
  • Step 5 After the heat preservation is completed, refining, degassing and slag removal are carried out. 0.3% refining agent is blown into the melt by argon, and the aeration time is controlled at 3 to 8 minutes; after that, further add 0.2% slag remover, stir for 5 minutes and let stand to remove the slag and impurities on the surface of the melt . The whole process is protected by argon atmosphere.
  • the aluminum melt is sampled before and during refining and its density is determined to estimate the hydrogen content.
  • the measurement method adopts the density method (compared with the theoretical value of aluminum of 2.70g/cm3), the closer the measured sample is to 2.7g/cm3, the lower the internal hydrogen content of aluminum. Generally, it cannot reach 2.7g/cm3 normally; the density test of the sample is about 2.65g/cm3 to estimate the hydrogen content.
  • the hydrogen content must be vacuumized. The slag agent is refined again.
  • Step 6 Stand still: put the melt that has been added with the rare earth aluminum alloy and refined for 3-5 minutes, and the temperature is controlled at 740-760 degrees.
  • Step 7 Adding and melting the aluminum-strontium master alloy: adding the above-mentioned refined aluminum-strontium master alloy into the melt in step 6, and controlling the temperature at 780-820° C. to completely melt the aluminum-strontium master alloy. The whole process is protected by argon atmosphere, and the aluminum-strontium master alloy is melted.
  • Step 8 After the aluminum-strontium master alloy is melted, control the temperature at 740-760° C. and stir for 3-8 minutes to achieve homogenization. The whole process is protected by argon atmosphere, the stirring rod is made of graphite material, and it is preheated to 400-500°C before stirring.
  • Step 9 heat preservation treatment is carried out at 725-750°C.
  • the heat preservation time is controlled at 15-30 minutes.
  • Step 10 Refining, degassing and slag removal: After the heat preservation of the melt is completed, blow in 0.3% of the refining agent into the aluminum-rare-earth composite melt after argon gas is introduced, and the ventilation time is controlled at 5 to 10 minutes; put in 0.2% of Put the slag removal agent into the aluminum melt, stir for 5 minutes and remove the slag and impurities on the surface of the aluminum-rare-earth composite melt. The whole process is protected by argon atmosphere.
  • the aluminum melt is sampled before and during refining to determine the hydrogen content. (Hydrogen content requirement: greater than or equal to 2.65g/cm 3 ;) During the hydrogen measurement process, it must be vacuumized. If the hydrogen content is unqualified, then further refining, that is, adding refining agents and slag removers to refine again.
  • Step 11 Add Al-Ti-B master alloy: Add Al-Ti-B master alloy to the melt treated in Step 10 above, heat to melt completely, and stir evenly for 3-5 minutes to homogenize.
  • Step 12 heat preservation: after stirring, heat the melt for 8-12 minutes, and control the temperature at 715-725°C.
  • Step 13 Refining, degassing and slag removal: After the heat preservation of the melt is completed, blow in 0.3% of the refining agent into the aluminum-rare-earth composite melt after argon gas is introduced, and the ventilation time is controlled at 5 to 10 minutes; put in 0.2% of Put the slag removal agent into the aluminum melt, stir for 5 minutes and remove the slag and impurities on the surface of the aluminum-rare-earth composite melt. The whole process is protected by argon atmosphere.
  • the aluminum melt is sampled before and during refining to determine the hydrogen content. (Hydrogen content requirement: greater than or equal to 2.65g/cm 3 ;) Vacuum treatment must be performed during the hydrogen measurement process. If the hydrogen content is unqualified, further refining is carried out, that is, refining agents and slag removers are added repeatedly until it is qualified.
  • Step 14 casting: the mold is preheated at 300-400°C.
  • the temperature of the composite rare earth alloy melt obtained in step 13 above is controlled at 715-725° C. for casting.
  • the oxides on the surface of the aluminum-rare-earth composite melt are filtered through a glass fiber filter; before each casting, the surface of the aluminum-rare-earth composite melt is filtered before casting.
  • the cooling control of the casting mold adopts a water cooling method to cool the aluminum-rare-earth composite melt cast into the mold.
  • the solidification speed of the aluminum melt is controlled at 50-100°C/s, and the solidification method is sequential solidification.
  • composition ratio of the composite rare earth aluminum alloy is not limited by the above embodiments, for example, it can be designed such that the mass ratio of the rare earth metal: strontium: titanium or titanium boron weight is 1: (0.1-1.2): (0.1-1.2).
  • the aluminum-silicon-magnesium alloy, the composite rare-earth aluminum alloy, and the aluminum-titanium-boron master alloy are prepared with a mass ratio of aluminum alloy:composite rare earth aluminum alloy:aluminium-titanium-boron master alloy of 99.4:0.4:0.2.
  • Heat preservation After stirring, control the temperature at 735 degrees for heat preservation, and the heat preservation time is controlled at 20 minutes;
  • Add refiner add 0.2% Al-Ti-B intermediate alloy to the refined aluminum water, wait for it to melt and stir and continue refining;
  • Heat preservation and standing After refining, the aluminum water flows into the heat preservation pool, and when the temperature is controlled at 710 ⁇ 3 degrees, the slag and impurities on the surface of the aluminum water are removed after standing for 10 ⁇ 2 minutes;
  • the refined modified aluminum alloy with the above temperature controlled at 700 ⁇ 5 is cast into the mold, and the modified aluminum alloy biscuit is obtained after cooling.
  • the thickness of the modified aluminum alloy biscuit is 30mm.
  • Solution treatment put the modified aluminum alloy biscuit in a heating furnace, heat it to 540°C at a heating rate of 2°C/min, and keep it there for 120min.
  • the modified aluminum alloy biscuit after the above solid solution treatment is added into a circulating water bath at a temperature of 65° C., and water is quenched for 3 minutes.
  • Fig. 1 shows the metallographic structure images of aluminum alloy parts in different stages, wherein, (a) is the image of A356 aluminum alloy before heat treatment, (b) is the image of A356 aluminum alloy after heat treatment, (c) is the The image after compound modification and before heat treatment in Example 1, (d) is the image after compound modification and heat treatment in Example 1.
  • the metallographic structure of the modified and heat-treated aluminum alloy in this embodiment is further increased compared with the rounded spherical ⁇ -Al phase, and the primary ⁇ -Al phase and dendrites are basically invisible. That is to say, the grains are further homogenized and the microstructure is more uniform.
  • the spherical ⁇ -Al phase is uniformly distributed at the grain boundaries.
  • the metallographic structure of the aluminum alloy after heat treatment ie (c)
  • the primary ⁇ -Al phase and dendrites are basically invisible. That is to say, the grains are further homogenized and the microstructure is more uniform.
  • Example 1 Through the heat treatment in Example 1, even without heat treatment, the plasticity can be greatly improved.
  • its yield strength and tensile strength are greatly improved (compared to the unmodified and unheated aluminum alloy master ingot, the yield strength and tensile strength are increased by nearly 3 times respectively , more than 2 times), while maintaining a high level of elongation (compared to the untreated aluminum alloy master ingot, it has increased by more than 5 times), which greatly improves the comprehensive mechanical properties.
  • rare earth aluminum alloy (the purification treatment of rare earth aluminum alloy is the same as in Example 1): aluminum strontium alloy: aluminum titanium boron intermediate alloy mass ratio is the ratio of 99.4:0.2:0.2:0.2 to prepare the above-mentioned aluminum silicon magnesium alloy, rare earth Aluminum alloys, aluminum-strontium master alloys, and aluminum-titanium-boron master alloys.
  • Heat preservation After stirring, control the temperature at 735 degrees for heat preservation, and the heat preservation time is controlled at 20 minutes;
  • Add aluminum-strontium master alloy add 0.2% aluminum-strontium master alloy to the refined aluminum water, wait for it to melt and stir and continue refining;
  • Heat preservation Next, heat preservation treatment is carried out at 725-750°C, and the heat preservation time is controlled at 15-30 minutes;
  • Add refiner add 0.2% Al-Ti-B intermediate alloy to the refined aluminum water, wait for it to melt and stir and continue refining;
  • Heat preservation and standing After refining, the aluminum water flows into the heat preservation pool, and when the temperature is controlled at 710 ⁇ 3 degrees, the slag and impurities on the surface of the aluminum water are removed after standing for 10 ⁇ 2 minutes;
  • the modified alloy 2 represents the green body after modification without heat treatment.
  • the rare earth aluminum alloy and the aluminum strontium master alloy are first smelted to prepare a composite rare earth aluminum alloy, and the composite modified aluminum alloy obtained by modifying the composite rare earth aluminum alloy is Part (i.e. embodiment 1) has higher comprehensive mechanical properties.
  • Example 1 For specific preparation, refer to Example 1, and its detailed description is omitted here.
  • Example 3 It can be seen from Table 3 that the heat treatment in Example 3 can also obtain similar results to those in Examples 1 and 2 above. That is to say, the preparation process of the present invention is also applicable to the eutectic aluminum alloy, which can obtain better strength and higher toughness.

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  • Crystallography & Structural Chemistry (AREA)
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Abstract

L'invention concerne une pièce en alliage d'aluminium modifiée composite à haute plasticité et son procédé de préparation. Le procédé de préparation comprend les étapes suivantes : étape S1, fourniture d'une masse fondue d'alliage d'aluminium ; étape S2, fourniture d'un modificateur ; étape S3, ajout du modificateur dans la masse fondue d'alliage d'aluminium sous une atmosphère de gaz inerte et sa fusion pour obtenir une masse fondue d'alliage d'aluminium modifiée ; étape S4, réalisation d'une coulée à l'aide de la masse fondue d'alliage d'aluminium modifiée pour obtenir l'ébauche en alliage d'aluminium coulé ; et S5, réalisation d'un traitement thermique sur l'ébauche en alliage d'aluminium modifiée, le traitement thermique comprenant : un traitement de solution, impliquant le chauffage de l'ébauche en alliage d'aluminium à 530 °C-550 °C et le maintien de la température pendant 120 à 300 min ; un traitement de trempe à l'eau, impliquant l'ajout de l'ébauche en alliage d'aluminium après le traitement de solution dans un bain d'eau ayant la température de 60 °C à 70 °C, et la trempe à l'eau de celle-ci pendant 2 à 4 min ; un traitement de vieillissement, impliquant le maintien de l'ébauche en alliage d'aluminium après le traitement de trempe à l'eau à 110 °C à 140 °C pendant 120 à 240 min, puis l'élévation supplémentaire de la température à 160 °C à 200 °C et le maintien de la température pendant 20 à 60 min, puis le refroidissement à température ambiante pour obtenir la pièce en alliage d'aluminium modifiée composite à haute plasticité.
PCT/CN2022/141397 2021-12-30 2022-12-23 Pièce en alliage d'aluminium modifiée composite à haute plasticité et son procédé de préparation WO2023125282A1 (fr)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011023060A1 (fr) * 2009-08-27 2011-03-03 贵州华科铝材料工程技术研究有限公司 Alliage d'aluminium à l'épreuve de la chaleur et à résistance mécanique élevée, et procédé de production correspondant
CN104561690A (zh) * 2015-01-26 2015-04-29 上海交通大学 高塑性铸造铝合金及其挤压铸造制备方法
CN112143945A (zh) * 2020-09-23 2020-12-29 上海耀鸿科技股份有限公司 一种多种复合稀土元素的高强韧性铸造铝硅合金及其制备方法
CN114293044A (zh) * 2021-12-30 2022-04-08 上海耀鸿科技股份有限公司 高塑性复合改性铝合金制件及其制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
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CN108823446A (zh) * 2018-07-16 2018-11-16 山东华宇合金材料有限公司 一种提高a356.2铝合金力学性能的工艺方法
CN109439976B (zh) * 2019-01-09 2019-12-24 广东省材料与加工研究所 一种铸造铝硅合金的复合变质方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011023060A1 (fr) * 2009-08-27 2011-03-03 贵州华科铝材料工程技术研究有限公司 Alliage d'aluminium à l'épreuve de la chaleur et à résistance mécanique élevée, et procédé de production correspondant
CN104561690A (zh) * 2015-01-26 2015-04-29 上海交通大学 高塑性铸造铝合金及其挤压铸造制备方法
CN112143945A (zh) * 2020-09-23 2020-12-29 上海耀鸿科技股份有限公司 一种多种复合稀土元素的高强韧性铸造铝硅合金及其制备方法
CN114293044A (zh) * 2021-12-30 2022-04-08 上海耀鸿科技股份有限公司 高塑性复合改性铝合金制件及其制备方法

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