WO2023089072A1 - Brennstoffzellenvorrichtung - Google Patents
Brennstoffzellenvorrichtung Download PDFInfo
- Publication number
- WO2023089072A1 WO2023089072A1 PCT/EP2022/082352 EP2022082352W WO2023089072A1 WO 2023089072 A1 WO2023089072 A1 WO 2023089072A1 EP 2022082352 W EP2022082352 W EP 2022082352W WO 2023089072 A1 WO2023089072 A1 WO 2023089072A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- stack
- fuel cell
- longitudinal axis
- stabilizer
- abutment
- Prior art date
Links
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/2425—High-temperature cells with solid electrolytes
- H01M8/2432—Grouping of unit cells of planar configuration
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/247—Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
- H01M8/248—Means for compression of the fuel cell stacks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/247—Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/247—Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
- H01M8/2475—Enclosures, casings or containers of fuel cell stacks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present invention relates to the field of fuel cell technology, in particular the field of fuel cell technology for means of locomotion and the stabilization of fuel cell stacks.
- Fuel cells offer an opportunity for decarbonization and are being installed more and more frequently, including in means of transport such as motor vehicles. With regard to operational safety, stability, the complexity of the structure and manufacturing costs, there is still a need for improvement.
- the task is to provide a fuel cell and components for fuel cells that enable safe fuel cell operation over the long term and enable a simple structure and inexpensive production.
- a fuel cell device in particular for a means of transportation, the fuel cell device comprising the following: a fuel cell stack and a stack longitudinal axis stabilizer, at least one area of the stack longitudinal axis stabilizer being arranged between a stack surface of the fuel cell stack running parallel to the stack longitudinal axis and an abutment.
- the means of transportation can be a motor vehicle, for example, in particular a motor vehicle that is at least partially driven with the aid of the fuel cell device.
- the motor vehicle can be suitable for driving on paved and/or unpaved roads. It can be a passenger car (car) or truck (truck), for example.
- parallel means that the parallel elements (eg the longitudinal axis of the stack and the stack surface) extend at an angle of at most 20°, eg at most 10°, to one another.
- the abutment is preferably arranged on a further component of the fuel cell device, e.g. on a component of the fuel cell device which is at a distance from the stack surface of the fuel cell stack.
- the abutment described here in connection with the stack longitudinal axis stabilizer can be a further component of the fuel cell device, e.g. a component of the fuel cell device which is at a distance from the stack surface of the fuel cell stack.
- the abutment can, for example, be arranged on a stack housing.
- the abutment described here in connection with the stack longitudinal axis stabilizer can be the stack housing itself or a part of the stack housing. All parts of the fuel cell device that extend into an area at a distance from the stack surface, in particular parts that at least partially enclose the fuel cell stack, are attributed to the stack housing.
- the region spaced from the stack surface is external to the fuel cell stack and extends into a plane that intersects the fuel cell stack and is orthogonal to the longitudinal axis of the fuel cell stack.
- successive reaction zones along the longitudinal axis of the stack are each typically sealed off by seals.
- the seals serve, among other things, to ensure that fuel supplied, e.g. hydrogen (H2), does not escape from the fuel cell stack in an uncontrolled manner.
- the rigidity of the fuel cell stack along the longitudinal axis of the stack is limited by the seals, and bending or bulges can occur along the longitudinal axis of the stack, as will be seen below in particular with reference to FIG of Figs. 1 and 2 explained.
- the longitudinal axis of the stack extends orthogonally to the planes of the bipolar plates through the fuel cell stack.
- the invention stabilizes the longitudinal axis of the stack in a particularly simple manner. Impairments to fuel cell operation, which could occur due to leaks in the fuel cell stack as a result of bulging, can be largely avoided. This enables safe fuel cell operation over the long term, even in the event of impacts and vibrations. At the same time, a simple structure and cost-effective production are ensured.
- the stack longitudinal axis stabilizer is able to transmit at least part of a force acting on the fuel cell stack orthogonally to the stack longitudinal axis to the abutment. This can be sufficient for a desired stabilization along the longitudinal axis of the stack.
- the fuel cell device may include multiple stack longitudinal axis stabilizers.
- the fuel cell device can comprise any number of stack longitudinal axis stabilizers, e.g. at least one, in particular at least two, preferably at least three, particularly preferably at least four stack longitudinal axis stabilizers.
- At least one area of each stack longitudinal axis stabilizer is preferably arranged between one of the stack surfaces of the fuel cell stack running parallel to the stack longitudinal axis and one or more abutments.
- One or more stack longitudinal axis stabilizers are preferably able to transfer at least a portion of several forces acting on the fuel cell stack in different directions orthogonally to the stack longitudinal axis to one or more abutments. At least part of at least one stack longitudinal axis stabilizer is preferably arranged in a contact area of a stack surface in which no fluid conducting structures (eg lines, hoses and/or distributors) run. It can be particularly advantageous if at least part of the stack longitudinal axis stabilizer is elastic. At least a portion of the stack longitudinal axis stabilizer may include an elastomer. This has the advantage that vibrations from the abutment do not affect the stack surface. The edges of certain bipolar plates or also distributors and frame elements on the stack surface can thus be protected from damage and the service life of the fuel cell device can be increased.
- the shape and material of the stack longitudinal axis stabilizer are preferably adapted to the structure of the fuel cell stack and the stack surface such that an acceleration a of 5 g, preferably 8 g, particularly preferably 10 g orthogonal to the stack longitudinal axis, does not damage the fuel cell stack.
- an acceleration a of 5 g, preferably 8 g, particularly preferably 10 g orthogonal to the stack longitudinal axis does not damage the fuel cell stack.
- the stack longitudinal axis stabilizer preferably includes a sliding contact surface.
- the abutment preferably includes an abutment contact surface.
- the sliding contact surface may be arranged on the abutment contact surface.
- the abutment contact surface, together with the sliding contact surface, can define a sliding contact area running parallel to the longitudinal axis of the stack.
- the word element "contact” in the terms “sliding contact surface”, “abutment contact surface” and “sliding contact area” means physical contact, not electrical contact. The effect of this is that a fuel cell stack stabilized by the stack longitudinal axis stabilizer remains movable in the axial direction.
- a force acting along the stack which can occur, for example, when the vehicle vibrates, can thus be damped by a substantially reversible sliding movement in the sliding contact area. Edges of the bipolar plates can slide back and forth in the axial direction without being damaged. This can contribute to an increase in the longevity of the fuel cell stack, especially in the case of a very filigree stack, so that maintenance intervals can be shortened and particularly efficient vehicle operation can be achieved over the long term.
- abutment contact surface and sliding contact surface can be a plastic surface, the other of the two surfaces can be a ceramic surface. This promotes sliding of the sliding contact surface on the abutment contact surface.
- an agent can be applied in the sliding contact area that promotes sliding of the sliding contact surface on the abutment contact surface.
- the stack longitudinal axis stabilizer may comprise an intermediate plate inserted into the fuel cell stack.
- Part of the intermediate plate preferably protrudes from the stack surface.
- This protruding portion may constitute at least part of the portion of the stack longitudinal axis stabilizer located between the stack surface and the abutment.
- the part of the intermediate plate protruding from the stack surface can be connected via a connecting element, for example to a tie rod element (acting as an abutment) of the fuel cell device.
- a connecting element for example to a tie rod element (acting as an abutment) of the fuel cell device.
- tie rod element acting as an abutment
- Specific options for connection are described below in connection with tie rod stabilizers. This can have a synergistic effect on the stability of the fuel cell stack of the fuel cell device. This is because the connection of the intermediate plate to a tie rod element leads not only to stabilization of the longitudinal axis of the stack per se, but also to stabilization of the tie rod element against breakage
- the intermediate plate protrude from one or from several stack surfaces.
- at least part of the intermediate plate can protrude from opposing stacking surfaces.
- the part of the intermediate plate protruding from the stack surface can be connected to a stack housing (acting as an abutment) via a connecting element, for example.
- the connection can be electrically insulating, for example.
- connection can include a sliding bearing.
- a connecting element can be slidably mounted on the abutment (e.g. housing or system frame).
- the abutment may include an adjustable abutment member. This can have the effect that manufacturing tolerances can be compensated for, thermal expansion of the intermediate plate can be accommodated and/or compensated for and/or assembly of the fuel cell stack by a Transfer of the adjustable abutment element can be facilitated from a first position to a second position.
- the abutment contact surface described can be, for example, a surface of the abutment element.
- the sliding contact surface described can be, for example, a surface of a connecting element arranged on the intermediate plate. Adjusting the abutment element can ensure that the sliding contact surface can slide as desired on the abutment contact surface of the adjustable abutment element in the sliding contact area.
- the part of the intermediate plate protruding from the stack surface can be connected to the abutment via an elastic element (spring, elastomer, etc.). This is particularly advantageous with regard to compensating for manufacturing tolerances and thermal expansion of the intermediate plate.
- One possibility consists in supporting the part of the intermediate plate protruding from the stack surface via the connecting element on the housing or on the system frame.
- An anode area defined by an anode-side element can be arranged, e.g. welded, on one side of the intermediate plate.
- a cathode region defined by a cathode-side element can be arranged, for example welded, on one side (the other side) of the intermediate plate.
- the surfaces of the intermediate plate have the shape of corresponding surface areas of the bipolar plates in areas in which the seal is in contact.
- the same sealing geometry is achieved as with the adjacent bipolar plates.
- the same seal can then be installed in the transition from intermediate plate to bipolar plate as in the transition from bipolar plate to bipolar plate. That means, that the fuel cell device can be assembled with particularly little effort.
- a plurality of intermediate plates spaced apart from one another can be inserted into the fuel cell stack.
- stabilization of the longitudinal axis of the stack and/or stabilization of one or more tie rod elements via several intermediate plates, which are inserted into the fuel cell stack at regular intervals can be useful.
- the stack longitudinal axis stabilizer may include a support member that braces the stack surface against the abutment.
- the support member may be a sliding support member.
- the abutment can comprise a carrier on which the sliding support element is slidably guided.
- the abutment contact surface described can be, for example, a surface of the carrier.
- the sliding contact surface comprised by the stack longitudinal axis stabilizer may be a surface of the sliding support element facing the abutment contact surface.
- One or more optional guide elements may extend parallel to the beam.
- the one or more guide members may extend through one or more openings of one or more slide support members.
- the sliding support element can be slidably guided on the carrier with return springs ng. During a sliding movement of the slide support element on the carrier, the restoring resilience can then promote a return of the slide support element to the starting position.
- Many, for example at least six, sliding support elements are preferably guided on the carrier in a displaceable manner, for example with restoring springs.
- a floating bearing element can also be guided on the carrier.
- the fuel cell stack can have at least one contact area on the stack surface, on which at least one sliding support element can rest and support the fuel cell stack.
- the shape of the contact area can be defined by one or more components of the fuel cell stack.
- One or more bipolar plates can define the shape of the at least one contact area.
- One or more seals can define the shape of the at least one contact area.
- One or more bipolar plates and gaskets can collectively define the shape of the at least one contact area.
- In the contact area there are preferably no fluid conducting structures (e.g. lines, hoses and/or distributors).
- the at least one contact area can be adapted to the shape of the at least one sliding support element.
- the sliding support elements With the help of the sliding support elements guided in this way, stabilization of the longitudinal axis of the stack can be achieved in that the surface of the stack is supported via the sliding support elements against a carrier acting as an abutment.
- the restoring spring can dampen movements of the cell edges lying against the sliding support elements in the direction of the longitudinal axis of the stack. This can contribute to further stabilization of the fuel cell stack.
- Stack longitudinal axis stabilizing effect achieves a damping effect acting essentially along the longitudinal axis of the stack.
- the abutment can be formed by a rail element running along a stack surface of the fuel cell stack.
- the support described in connection with the sliding support element can be designed as a rail element.
- the rail element can be a tie rod rail element.
- a tie rod rail element is a rail element that also functions as a tie rod element.
- a buffer element can be arranged between the fuel cell stack and the rail element.
- the cushioning element may contain an elastomer or a polymeric foam. It can be an elastic, polymer foam-based buffer element.
- a stack longitudinal axis stabilizer may run in a concave area of the stack surface of the fuel cell stack.
- the buffer element can support a stack surface against the rail element and thereby stabilize the longitudinal axis of the stack.
- the abutment contact surface described in detail above may be a surface of the rail member.
- the sliding contact surface comprised by the stack longitudinal axis stabilizer can be, for example, a surface of the buffer element which faces the abutment contact surface.
- Stack longitudinal axis stabilizing effect a damping effect acting essentially along the longitudinal axis of the stack can be achieved.
- the fuel cell stack can have at least one contact area on the stack surface, on which at least one buffer element can rest and support the fuel cell stack.
- the shape of the contact area can be defined by one or more components of the fuel cell stack.
- One or more bipolar plates can define the shape of the at least one contact area.
- One or more seals can define the shape of the at least one contact area.
- One or more bipolar plates and gaskets can collectively define the shape of the at least one contact area.
- In the contact area there are preferably no fluid conducting structures (e.g. lines, hoses and/or distributors).
- the at least one contact area can be adapted to the shape of the at least one buffer element.
- At least part of the buffer element can lie in a concave region of the stack surface of the fuel cell stack that runs parallel to the longitudinal axis of the fuel cell stack.
- the rail element is preferably aligned parallel to the longitudinal axis of the fuel cell stack.
- one extension of the rail element which can be referred to as the height of the rail element, for example, can be greater than another extension of the rail element, which can be referred to as the width of the rail element, for example.
- the terms width and height say nothing about the Orientation of the rail element in relation to the direction of gravity.
- a cross section is understood to be an imaginary cut surface of the rail element, which would be obtained if the rail element were cut orthogonally to the longitudinal axis of the rail element.
- the bumper member may be formed to extend partially (e.g., U-shaped) around the rail member in the cross-section between the rail member and the concave stacking surface.
- a surface of the rail element that faces the stack surface can be wider than a surface of the rail element that faces away from the stack surface.
- the cross-section of the rail member may be T-shaped.
- the rail element can, for example, replace a conventional tie rod element with a round cross-section and stabilize the longitudinal axis of the fuel cell stack. It therefore has only a minimal impact on the installation space and can bring about particularly efficient stabilization of the longitudinal axis of the stack with minimal material expenditure.
- the tie rod element can optimally develop its effect, for example vertically below a longitudinal axis of the stack.
- the term "vertically below” here refers to the direction of gravity.
- the stack longitudinal axis stabilizer may include a support pad member.
- the support cushion can be filled with air or foam, for example.
- the support cushion element can be arranged between the stack enclosure and the stack surface(s). This has the advantage of particularly simple assembly.
- One or more support cushion elements can preferably cover at least 5%, particularly at least 10%, particularly preferably at least 25%, for example at least 50% of the total stack surfaces running parallel to the longitudinal axis of the stack.
- the orientation of the fuel cell stack in the stack housing can be controlled via a predefined shape of the support cushion element.
- the increase in surface area is accompanied by a reduction in surface pressure. This results in an advantageous load configuration and thus a lower risk of damage in the area of the stack surface(s).
- the stack longitudinal axis stabilizer may comprise a bulk material.
- the bulk material can be arranged between the stack housing and the stack surface. This allows a particularly simple installation. Since a large part of the space between the stack surfaces and the stack housing can be filled with loose material, there is the possibility of greatly reducing the ignitable volume in the event of a hydrogen escape, so that active ventilation of the space between the stack surface(s) and the stack housing may be unnecessary .
- the stack longitudinal axis stabilizer can comprise a molded part.
- the molding can preferably contain a polymer foam.
- a surface contour of the molded part can be adapted to the contour of the stack surface, for example.
- One or more molded parts can preferably cover at least 5%, particularly at least 10%, particularly preferably at least 25%, for example at least 50% of the entire stack surfaces running parallel to the longitudinal axis of the stack.
- a large-area supporting effect can be achieved in a particularly simple manner by means of one or more molded parts.
- an additional damping effect that acts essentially along the longitudinal axis of the stack with the support cushion element and the molded part is typically not brought about by a sliding contact area, but rather by an intrinsic elasticity of the support cushion element or the molded part.
- a damping effect acting essentially along the longitudinal axis of the stack is also achieved in addition to the effect essentially orthogonal to the longitudinal axis of the stack, which stabilizes the longitudinal axis of the stack.
- this can even be achieved without the sliding contact area.
- a fixing area of the stack longitudinal axis stabilizer extends into a plate space, e.g. bipolar plate space, of the fuel cell stack.
- the fixing area can preferably extend into an edge area of the space between the plates, with the edge area extending from the edge of the plate to a seal.
- a support area of the stack longitudinal axis stabilizer can form the area of the stack longitudinal axis stabilizer arranged between the stack surface and the abutment.
- the abutment contact surface can then be, for example, a surface of an abutment, e.g.
- the sliding contact surface may be a surface of the support portion facing the abutment contact surface.
- the support element described above e.g. sliding support element
- the buffer element described in connection with the rail element e.g., the support cushion element, the bulk material and the molded part are each essentially on the outer contour of the Fuel cell stack and can hit the bipolar plate.
- bipolar plates are often not stacked perfectly, protruding bipolar plates can be exposed to particular forces at the edges and can therefore be damaged by such stack longitudinal axis stabilizers.
- sharp-edged bipolar plates can damage such stack longitudinal axis stabilizers, for example on their plastic surfaces, due to a cutting effect.
- many small particles are generated and released.
- the stabilization of the longitudinal axis of the stack with an intermediate plate can offer advantages.
- one or more intermediate plates require additional components, which must also be sufficiently mechanically stable and electrically conductive. This can be accompanied by a significant additional weight.
- the stack longitudinal axis stabilizer which includes the fixation region and the support region, can be an elastomeric element. Due to the design as an elastomer element, the characteristic of the application of force is relatively "soft", in contrast to an impact on a metallic element. In addition, tolerances in the outer contour of the fuel cell stack can be better compensated for, since stressed stack longitudinal axis stabilizers distribute the force to neighboring elements via the fixing area, among other things.
- the fixation area can be clamped in the space between the plates by the two adjacent plates, eg bipolar plates. This allows local a stable connection between the elastomer element and the adjoining plates can be achieved, which also withstands the introduction of an external force in the direction of the cell level.
- the mean pressure exerted on the fixation area in the space between the plates by the two adjacent plates is higher than the mean pressure exerted on the seal(s) in the space between the plates by the two adjacent bipolar plates.
- One or more fixation areas preferably account for at most 10%, preferably at most 6%, particularly preferably at most 4% of a surface of a bipolar plate. Because of such a local design, the total force applied for bracing the fixing area or areas remains relatively small in relation to the total stack bracing force. This can offer the great advantage that existing concepts for stack bracing can largely be retained.
- Stack longitudinal axis stabilizers with a fixation area and a support area can therefore be added to an established fuel cell design essentially easily without the need for further adjustments.
- the local design permits the elastomer element to be arranged in a region in which the additional force can be easily compensated for by the bracing system (see, for example, FIG. 34), for example in a Area where a spring element of an existing bracing solution comes to lie close to the edge of the pressure distributor plate.
- the spring element can in particular be a disk spring, compression spring, plate spring or spiral spring.
- At least one convex area can be formed on at least one of the surfaces of the fixing area and/or the plate that come into contact with one another.
- Part of the fixing area can preferably be thickened on one or both sides. This means that the part is thicker than an adjacent part of the fixation area.
- Part of the surface of the bipolar plate coming to rest in the fixation area can be thickened.
- the fixing area is pressed in the space between the plates in the clamped fuel cell stack, the fixing area is compressed in particular where the distance to the next plate is particularly small.
- the support area can preferably be made thicker in the direction of the longitudinal axis of the stack than the fixing area.
- the support area may include a shoulder that may extend over an edge surface of a bipolar plate. This can cause the shoulder to press on the edge of a bipolar plate that protrudes slightly from a non-ideally stacked fuel cell stack.
- this can bring about additional stabilization of the fuel cell stack along the longitudinal axis of the stack, since local deviations from the ideal stack geometry are counteracted in a particularly targeted manner can.
- the shoulder rests on the edge of the bipolar plate, it can prevent the fixation area from being pushed deeper into the space between the plates, where the sealing effect of a seal could otherwise be impaired. This means that the risk of H2 escaping can be further reduced and thus the operational reliability of the fuel cell device can be increased even further.
- the support area can be thicker than the attachment area in the direction of the longitudinal axis of the stack, e.g.
- the greatest thickness of both areas in the direction of the longitudinal axis of the stack is included.
- a plurality of convex portions may be formed at the fixing portion.
- a convex portion closer to the support member and a convex portion farther from the support member may be formed.
- one or more further convex areas can be formed between these two convex areas.
- the fixing area is designed in such a way that the force required to press the fixing area between the plates decreases towards the edges of the fixing area.
- the fixing area can taper towards the edge of the fixing area.
- the thickness of the fixing area can be smaller at a convex area closer to the support element and at a convex area further away from the support element than the thickness of a convex area formed between these two convex areas.
- Significantly increased compression forces can occur locally in the fixing area. If the fixing areas of adjacent stack longitudinal axis stabilizers are offset, this can lead to the introduction of bending moments into the existing bipolar plates. If this changes the sealing gap in the area of the adjacent seal, this could impair the sealing function.
- At least one seal and the stack longitudinal axis stabilizer are designed as a one-piece seal-stabilizer unit, e.g. as a seal-stabilizer unit which has a seal, a fixing area and a support area connected to the seal via the fixing area.
- This has the advantage that the seal and the stack longitudinal axis stabilizer do not have to be manufactured separately. In addition, fewer individual parts have to be installed in the production of the fuel cell device.
- the object is also achieved by a seal-stabilizer unit for sealing successive reaction zones along the longitudinal axis of a fuel cell stack, the seal-stabilizer unit having a seal, a fixing area and a support area connected to the seal via the fixing area.
- the features of the stack longitudinal axis stabilizer described herein, of its fixing area and of its support area can also represent features of the seal-stabilizer unit.
- the object is also achieved by a bipolar plate for a fuel cell stack, with an edge surface of the bipolar plate defining an edge support surface whose width D, measured orthogonally to the plane of the plate, exceeds the thickness of the bipolar plate material. If the bipolar plate material thickness is not uniform, the average bipolar plate material thickness is considered for the comparison with the width D. If the width D is not uniform, the average width of the edge support surface is considered as the width D.
- D is preferably at least 125% of the bipolar plate material thickness, particularly preferably at least 150%, in particular at least 175%, e.g. at least 200% of the bipolar plate material thickness.
- the edge support surface may be bent or beaded.
- This adaptation of the edge surface can serve to avoid damage to the stack longitudinal axis stabilizer or the seal-stabilizer unit under vibration loading.
- the support includes a shoulder that extends beyond the peripheral surface of a bipolar plate, the increased width D can counteract cutting of the peripheral surface into the shoulder of the support.
- the invention is not limited to the edge support surface, the width D of which, measured orthogonally to the plane of the plate, exceeds the thickness of the bipolar plate material, is in contact with a support area described herein.
- the edge support surface can also enable direct or almost direct support on the abutment, e.g. on the stack housing, and thereby stabilize the longitudinal axis of the fuel cell stack.
- a fuel cell device comprising a fuel cell stack with at least one bipolar plate, with an edge surface of the bipolar plate having a Defined edge support surface whose width D measured orthogonally to the plane of the plate exceeds the thickness of the bipolar plate material and wherein the stack longitudinal axis of the fuel cell stack is stabilized in that the edge support surface is arranged on an abutment, eg on the stack housing.
- the features specified above for the bipolar plate in particular with regard to the width D and the shape of the edge support surface, can of course also be features of the bipolar plate comprised by the fuel cell device.
- edge support surface is arranged on the abutment, e.g. on the stack housing, can mean that the edge support surface is supported on the abutment or that there is a small distance between the edge support surface, which is e.g. at most 5% of the length of the fuel cell stack along the longitudinal axis of the stack .
- the edge support surface is electrically isolated from the abutment.
- a layer of an electrically insulating material can be arranged between the edge support surface and the abutment.
- an electrically insulating coating can be applied to the abutment and/or to the edge support surface.
- the edge support surface can then directly form the sliding contact surface described herein, which in other embodiments of the invention is comprised by the stack longitudinal axis stabilizer.
- the abutment can comprise the abutment contact surface.
- the sliding contact surface may be arranged on the abutment contact surface.
- the abutment contact surface, together with the sliding contact surface, can define a sliding contact area running parallel to the longitudinal axis of the stack.
- the edge surface of the bipolar plate can be oriented orthogonally to the plane of the plate, for example.
- Orthogonal means here that the orthogonal elements (e.g. the plate plane and the edge surface) run at an angle to one another that does not deviate from 90° or deviates by at most 20°, preferably at most 10°.
- a convex area of a bipolar plate e.g.
- two convex regions of a bipolar plate e.g.
- the convex portion of the bipolar plate may also be a corner portion of a bipolar plate, e.g., a corner portion of a substantially rectangular bipolar plate.
- This configuration of the stack longitudinal axis stabilizer reverses the possibility described above of arranging a fixing region of the stack longitudinal axis stabilizer in a plate intermediate space. Conversely, it makes it possible to arrange a convex area of the bipolar plate or a plate projection area in the recess of the stack longitudinal axis stabilizer.
- the recess can be a slot.
- the recess can be delimited by recess edge areas.
- the edge areas of the recess can, for example, limit the depth and length of the slot.
- the recess edge areas can be adapted to the edge contour of the convex area of the bipolar plate, for example. Sections of the recess edge areas can be adapted to the edge contour of the convex area of the bipolar plate or together form a recess edge area continuously adapted to the edge contour of the convex area.
- the recess edge area continuously adapted to the edge contour of the convex area can be adapted to the edge contour essentially over the entire length of the edge contour.
- the support element of the stack longitudinal axis stabilizer can be formed by a region of the stack longitudinal axis stabilizer which projects beyond the plate projection region in the plane of the bipolar plate. At least one recess edge area can be in the transition from the recess to the support element.
- the stack longitudinal axis stabilizer may include a sliding contact surface.
- the sliding contact surface comprised by the stack longitudinal axis stabilizer can be a surface of the support element, preferably a surface of the support element lying on the support element opposite a recess edge area.
- the sliding contact surface may abut an abutment contact surface.
- the abutment contact surface may be an interior surface of a stack enclosure. The abutment contact surface, together with the sliding contact surface, then defines a sliding contact area running parallel to the longitudinal axis of the stack.
- the convex area of the bipolar plate can be arranged in the recess with a force fit and/or with a form fit.
- the stack longitudinal axis stabilizer surrounding the recess can be a plastic part.
- the plastic part can preferably be formed from a plastic that can be formed by injection molding.
- the stack longitudinal axis stabilizer can be formed, for example, by overmolding the convex area of the bipolar plate with a plastic.
- the stack longitudinal axis stabilizer can be connected to the convex region of the bipolar plate via an undercut.
- the bipolar plate In the convex area, the bipolar plate can have a depression, for example.
- the stack longitudinal axis stabilizer can engage in the depression.
- the bipolar plate In the convex area, the bipolar plate can have an elevation, for example.
- the stack longitudinal axis stabilizer may extend around the ridge.
- a bipolar plate for a fuel cell stack comprising a convex area and a stack longitudinal axis stabilizer, e.g.
- the stack longitudinal axis stabilizer comprised by this bipolar plate according to the invention and the convex region of the bipolar plate can have the features that are described herein.
- the above features of the recess, recess edge regions, the support region, the sliding contact surface and the type of arrangement of the convex region in the recess, the material of the longitudinal stack stabilizer comprising the recess, the manufacture of the longitudinal stack stabilizer comprising the recess, the connection via the undercut also Be features of the associated bipolar plate according to the invention.
- a fuel cell device in particular for a means of locomotion, the fuel cell device comprising the following: a fuel cell stack and a cell suspension element which directly or indirectly connects a cell of the fuel cell stack to an abutment.
- the cell suspension element can be arranged or formed on a component of the cell. Then the cell suspension element connects the cell directly to the abutment.
- a component is a cell frame element that belongs to a cell frame of a single cell.
- Another example of such a component is a gasket for sealing a cell.
- the cell suspension element can also be arranged or formed on another component of the fuel cell stack, e.g. on a component of the fuel cell stack that extends over several cells or between two cells. Then the cell suspension element connects the cell indirectly to the abutment.
- a component of the fuel cell stack that extends over several cells or between two cells.
- the cell suspension element connects the cell indirectly to the abutment.
- An example of such a device is a bipolar plate, as it extends between two cells.
- Another example of such a component is a cell frame element that belongs to a frame enclosing several cells.
- a cell or “the cell” in connection with a cell suspension element, if the cell suspension element cannot be attributed to a particular cell, it is the cell nearest to the cell suspension element or any two cells nearest to the cell suspension element meant.
- the cell suspension element is preferably formed on a cell frame element.
- the cell frame element can belong to a cell frame of a cell or also to a frame enclosing several cells.
- the cell suspension element connects the cell to the abutment.
- connects in this context typically refers to a mechanical connection.
- the cell suspension element connects the cell to the abutment such that the cell is directly or indirectly attached to the abutment is mounted, the cell is directly or indirectly mechanically coupled to the abutment and/or the freedom of movement of the cell relative to the abutment is at least restricted.
- the cell suspension element can connect the cell to the abutment, e.g. in a force-fitting, form-fitting and/or cohesive manner, preferably in a force-fitting and/or form-fitting manner.
- the connection may include an undercut.
- the cell suspension element is advantageously anchored in the abutment.
- the abutment can be anchored in the cell suspension element.
- the cell suspension element may have a head portion and a neck portion.
- the head portion may be attached to the cell via the neck portion.
- a collar area can be formed on the abutment for anchoring.
- the collar area can, for example, be adapted to the dimensions and shape of the head area and neck area of the cell suspension element in such a way that the neck area can come to rest in the collar area, but the head area rests on a side of the collar area facing away from the cell, so that the head does not slip out of the collar area can.
- the head area is preferably accommodated in the abutment by the collar area extending towards the neck area.
- the described embodiment with head area, neck area and collar area is only an example for the implementation of the invention. It goes without saying that the cell suspension element can also be anchored in a different way in the abutment.
- the abutment may have an abutment surface remote from the cell.
- the abutment surface remote from the cell may be parallel to the stack surface or inclined to the stack surface. Reference is made to the stack surface (running parallel to the longitudinal axis of the stack) that faces the abutment.
- the cell suspension element may have a suspension surface facing the cell.
- the suspension surface facing the cell may be parallel to the stack surface or inclined to the stack surface.
- the abutment surface remote from the cell may extend into an area between the cell and the cell-facing suspension surface.
- the abutment may have an abutment surface facing the cell.
- the abutment surface facing the cell may be parallel to the stack surface or inclined to the stack surface. In this case, reference is made to that stack surface which runs parallel to the longitudinal axis of the stack and faces the abutment.
- the cell e.g., the cell frame member, advantageously has a suspension surface remote from the cell.
- suspension surfaces described herein interact with the abutment surfaces to limit movement of the cell suspension member into and out of the abutment. This will be particular will be apparent from the specific embodiments shown in Figures 16 to 19 and described in more detail hereinbelow.
- the cell suspension element can connect the cell to the abutment via a damping element, for example. This can cause vibration decoupling. Moreover, a support or suspension of the fuel cell stack can be implemented efficiently essentially without additional installation space.
- the cushioning element may be constructed and arranged such that a portion of the cushioning element extends into an area between one of the abutment surfaces and one of the suspension surfaces.
- a portion may extend into an area between the abutment surface remote from the cell and the suspension surface facing the cell.
- This section may be referred to as the first section and the area as the first area.
- a portion may extend into an area between the abutment surface facing the cell and the suspension surface facing away from the cell.
- This section may be referred to as the second section and the area as the second area.
- a particularly advantageous damping element can have a first and a second section.
- the first portion may extend into the first area.
- the second portion may extend into the second area.
- the fuel cell stack is then particularly efficiently decoupled from impact movements of the abutment, both when the impact leads to a movement of the abutment away from the cell and towards the cell.
- the abutment can include a counter bearing.
- a cavity remaining in the area of the abutment and cell suspension element can be completely or partially filled with a filling material.
- the filling material can contain, for example, a resin and/or an elastomer. This can be advantageous in order to compensate for tolerances and to connect the cell or the cell frame mechanically to the abutment, for example the stack housing.
- At least 10% of the cells or at least every tenth cell of the fuel cell stack can each have an attached cell suspension element.
- At least 20% of the cells or at least every fifth cell of the fuel cell stack can each have an attached cell suspension element.
- At least 33% of the cells or at least every third cell of the fuel cell stack can each have an attached cell suspension element.
- At least 50% of the cells or at least every second cell of the fuel cell stack can each have an attached cell suspension element.
- each cell of the fuel cell stack may have an attached cell suspension element.
- the ratio of the number of cell suspension elements to the number of cells comprised by the fuel cell stack is 0.1 to 10, in particular 0.2 to 5.
- a higher proportion of cells with cell suspension elements can make it possible to design individual cell suspension elements to be weaker.
- more and stronger designed cell suspension elements can be advantageous.
- a few weaker cell suspension elements can be advantageous for fuel cell stacks that are constructed from relatively light cells and that are exposed to no or relatively little vibration during operation.
- the relatively high proportions of cells with cell suspension element specified above make mechanical suspension on the abutment possible at the level of a few cells or even at the level of a single cell. The same applies if the above ratio is 1 or more.
- a cell suspension element or elements may then be sufficient to form the cell suspension element or elements from an easily shaped material of a cell frame element or a gasket. It is thus possible to realize a cell suspension element as a cell suspension element formed in one piece with a cell frame element or a seal, e.g. by casting, in particular by plastic injection molding.
- a cell suspension frame element for a fuel cell stack in particular for a cell or several cells of a fuel cell stack, e.g. for a cell of a fuel cell stack, wherein the cell suspension frame element comprises a cell suspension element formed on a cell frame element.
- the cell suspension frame member may be a plastic part, such as a plastic injection molded part.
- the cell or the cell suspension frame element has a plurality of cell suspension elements, in particular at least two, more preferably at least three, e.g. at least four cell suspension elements.
- the cell or the cell suspension frame element has at most 32, in particular at most 24, further preferably at most 20, for example at most 16, cell suspension elements.
- the cell suspension generally withstands the usual mechanical loads, e.g. associated with impacts and vibrations in ferry operations, without any problems.
- a plurality of cells can each have a plurality of cell suspension elements.
- the cell suspension elements are preferably oriented in different directions.
- a direction predetermined by a stack surface of the fuel cell stack is regarded as one direction.
- cell suspension elements can therefore be oriented in up to four directions.
- At least two cell suspension elements are oriented in opposite directions.
- At least three cell suspension elements are very particularly preferably oriented in three different directions. This can create the possibility of suspension on an abutment arranged above a fuel cell stack and at the same time on abutments arranged laterally on both sides of the fuel cell stack.
- four cell suspension elements may be oriented in four different directions.
- This can offer the additional option of mechanically connecting the fuel cell stack to an abutment arranged below the fuel cell stack, so that briefly upward forces that can occur, for example, when driving over speed bumps, can also be absorbed.
- a speed bump is considered in particular to be a structural elevation on the roadway arranged transversely to the direction of travel, which leads to a reduction in speed and is therefore intended to contribute to traffic calming.
- the abutment can be formed in any shape.
- it may be a slot in a stack enclosure.
- the abutment may preferably comprise a counter suspension element.
- the counter suspension element can, for example, be adapted to the cell suspension element in such a way that the cell suspension element can connect the cell to the abutment via the counter suspension element in a non-positive, positive and/or material connection.
- the mating suspension element can be arranged on a stack enclosure.
- the counter-suspension element can be a profile rail element.
- the counter-suspension element or the profile rail element can have, for example, the abutment surface facing away from the cell.
- the mating suspension member or profile rail member may include a leg extending orthogonally to the nearest stacking surface.
- the mating suspension member or profile rail member may comprise a leg having the abutment surface remote from the cell.
- the leg may extend parallel to the nearest stacking surface.
- the collar area formed on the abutment can be formed by two legs extending parallel to the nearest stack surface.
- Certain profile rail elements can have an L-shaped profile cross section.
- the area between the fuel cell stack and the stack housing can be divided into several channel sections.
- the cell suspension elements described here can be located between adjacent channel sections.
- a cell anchor stabilizer or a stack longitudinal axis stabilizer can be located between adjacent channel sections instead or in addition, e.g. a stack longitudinal axis stabilizer with a support area and a fixing area.
- Ventilation systems are often used to implement explosion protection in fuel cell devices.
- the stack housing or the fuel cell housing is selectively flown through with air and thereby possible occurring H2 leaks mixed into a non-critical mixture composition.
- air baffle plates or flow guides may be necessary in conventional fuel cell devices. Depending on the situation, this requires additional elements that have to be manufactured and installed at high cost. Because air baffles are expensive and have to be installed.
- the positions of the ventilation inlets and outlets cannot be chosen freely; inlets and outlets must be positioned where it makes sense in terms of flow/ventilation. Poor mixing/flow control can be counteracted with higher aeration volume flows, but at the expense of system efficiency.
- the cell suspension elements described herein and/or a cell anchor stabilizer described herein or a stack longitudinal axis stabilizer described herein can lie between the adjacent channel sections. These channel sections can form part of a ventilation system that serves to protect the fuel cell device from explosion.
- the ventilation system can, for example, connect at least one opening of the fuel cell device for supplying ventilation air to an outlet of the fuel cell device for discharging ventilation air.
- a particular advantage results from the fact that a cell suspension element and/or cell anchor stabilizer and/or stack longitudinal axis stabilizer located between the channel sections can at least partially replace an air baffle otherwise required for ventilation.
- a high proportion of the cells e.g. at least 10%, preferably at least 20%, more preferably at least 25%, particularly preferably at least 33%, very particularly preferably at least 50% of the cells each have at least one attached cell suspension element and/or a stack longitudinal axis stabilizer, can Air baffles can be dispensed with and still a very good ventilation of the fuel cell device can be achieved.
- the channel sections can be defined in whole or in part by the cell suspension elements.
- the channel sections can be defined entirely or partially by the cell suspension elements and/or at least one cell anchor stabilizer.
- the channel sections can be defined in whole or in part by the cell suspension elements and/or at least one stack longitudinal axis stabilizer (e.g. in one of the embodiments with support area and fixation area).
- a channel section can be delimited, for example, along the longitudinal axis of the stack by cell suspension elements and transversely to the longitudinal axis of the stack by at least one cell anchor stabilizer or one stabilizer for the longitudinal axis of the stack.
- channel sections entirely or partially by cell suspension elements can enable efficiency-efficient ventilation of a fuel cell housing without additional components and also enable a geometrically more flexible design and positioning of the inlet and outlet of the ventilation.
- Channel sections running parallel to one another and to the longitudinal axis of the stack can run on one or more stack surfaces.
- the ends of two adjacent channel sections can each merge into one another at one end of a stacking surface.
- a ventilation channel that is routed in a meandering manner around the fuel cell stack can be formed as a result. This results in the possibility of constructing the inlet and the outlet of the ventilation channel close to one another on the fuel cell device.
- a further advantage of the defined channel sections is the spatial limitation of the flame front in the event of a fault and thus a reduction in the harmful effects of any mixture ignition that occurs.
- a fuel cell device which comprises one or more sensor elements for detecting a force and/or a change in the fuel cell device which can be attributed to the action of the force.
- all of the fuel cell devices described herein can include one or more sensor elements for detecting a force and/or a change in the fuel cell device that is attributable to the action of the force.
- the one or more sensor elements can be designed for strain measurement, for stress measurement or for displacement measurement.
- Such sensor elements are known to those skilled in the art.
- it can be a piezoelectric or an electromagnetic sensor element.
- the sensor element(s) result in advantages, e.g. detection of critical states of the clamping system. For example, falling below the minimum clamping force or exceeding the maximum clamping force, detection of tilting, detection of bending along the longitudinal axis of the stack, etc. There is also a possibility of deriving necessary measures, e.g. operating states, service requirements, etc.
- At least one sensor element can transmit data to a data evaluation system.
- the data evaluation system can be configured to compare a target value with an actual measured value. It can also be configured to output a message if the actual value deviates from the target value or if the actual value deviates too far from the target value.
- a fuel cell device in particular for a means of locomotion, the fuel cell device comprising the following: a tie rod element; Tension bracing elements connected via the tie rod element, e.g
- Tie rod plates Tie rod plates, and a tie rod stabilizer which is in contact with the tie rod element between the tension bracing elements.
- the fuel cell device can comprise one or more tie rod elements, e.g. at least two, preferably at least four, particularly preferably at least six tie rod elements.
- the fuel cell device can include one or more tie rod stabilizers.
- the tie rod elements of a fuel cell stack can experience large flexural vibration amplitudes and possibly break.
- the contact of the tie rod stabilizer at least partially suppresses or dampens bending vibrations of the tie rod element. Consequently, the risk of breakage of the tie rod element is reduced.
- the invention can be integrated in a particularly simple manner in conventional fuel cell devices braced with tie rod elements.
- tie rod elements An increase in the diameter of the tie rod elements or the use of tightening straps instead of tie rod elements would entail a considerable amount of adjustment work on other components of the fuel cell device as well. This can be avoided by the invention.
- the tie rod element can, for example, also be a tie rod rail element described elsewhere herein.
- the tie rod stabilizer is in contact with the tie rod element between the tension bracing elements, e.g. Contact can be made in any way.
- tension bracing element means in particular a tension anchor plate.
- tension bracing element is not limited to this, since the tension bracing function of a tie anchor plate can also be fulfilled, for example, by the wall of a stack housing.
- tie rod plate is to be understood functionally.
- Each component of a fuel cell device that is connected to a tie rod element and via which a tensile stress of the tie rod element can be transmitted directly or indirectly to a fuel cell stack is a tie rod plate.
- a sufficiently torsion-resistant, essentially grid-shaped plate would also be conceivable, for example.
- the tensile stress can be transmitted indirectly, e.g. with the help of a spring element, as shown in Fig. 15 by way of example.
- Pressure distributor plates or force introduction plates for example, can also be arranged between the tie rod plate and the fuel cell stack.
- the contact between the tie rod stabilizer and the tie rod element can be form-fitting, force-fitting and/or material-fitting. It is preferably form-fitting and/or force-fitting.
- the tie rod stabilizer preferably has a tie rod connection element.
- a particularly preferred tie rod connection element is adapted to the shape of the tie rod.
- the tie rod connection element can be a snap connection element, for example.
- the tie rod element can then be accommodated in the snap connection element.
- the snap connection element can have two gripping elements.
- the gripping elements can form a receiving area that is adapted to the shape of the tie rod element.
- the receiving area is preferably round.
- the inner diameter of the round receiving area can then be adapted to the outer diameter of the rod-shaped tie rod element.
- the gripping elements can define a tapered receptacle for the tie rod element. At least one gripping element can be elastically deformed when the tie rod stabilizer is attached to the tie rod element and can be releasably or non-releasably, preferably releasably, hooked onto the tie rod element. Such an elastic deformation of a joining part is common in snap connections.
- the tie rod stabilizer can have a connection securing element.
- This can be an element of any design, with which a tie rod stabilizer connected in the tie rod connection element can be secured in the tie rod connection element.
- the connection securing element can, for example, be a recess or an opening over which / which the tie rod stabilizer (e.g. with a strap or a cable tie) can be attached to the tie rod element.
- the tie rod stabilizer is also in contact with at least one other component of the fuel cell device.
- the contact to the further component can be made in any way.
- a bending vibration amplitude of the tie rod element in the contact area with the tie rod stabilizer can then be more strongly damped.
- the bending vibration amplitude can also be damped by the other component that is also in contact with the tie rod stabilizer.
- the at least one further component can be selected, for example, from a further tie rod element (or a plurality of further tie rod elements), an intermediate plate inserted into the fuel cell stack of the fuel cell device (or a plurality of intermediate plates inserted into the fuel cell stack of the fuel cell device) and a stack housing.
- a part of the intermediate plate which is in contact with the tie rod element preferably protrudes from the stack surface.
- the tie rod stabilizer can in particular have a further connection element.
- the further connection element can be, for example, a further tie rod connection element or an intermediate plate connection element.
- the fuel cell device can include, for example: a plurality of tie rod elements, tension bracing elements connected via the tie rod elements, eg tie rod plates, with the tie rod stabilizer being in contact with a plurality of tie rod elements between the tension bracing elements.
- the tie rod stabilizer can advantageously be in contact with the tie rod elements via tie rod connection elements, in particular via snap connection elements. This has the advantage that the tie rod stabilizer can then be easily clipped onto the tie rod elements.
- Advantageous tie rod stabilizers have several tie rod connection elements and a stabilizer strut area, with the stabilizer strut area extending from tie rod connection element to tie rod connection element.
- Two tie rod connection elements can be aligned in such a way that the tie rod stabilizer connects regions of two tie rods that are offset relative to one another in the longitudinal direction of the stack. Due to the offset, the two interconnected areas do not oscillate in phase and with the same amplitude. This results in the particular advantage that effective damping of bending vibrations is also achieved when both tie rods are excited or vibrate in phase.
- a connection of such mutually offset areas of two tie rods is achieved, for example, when several tie rod connection elements coincide with the corners of a triangle or a square.
- the tie rod stabilizer can, for example, have at least three tie rod connection elements, with at least three of the tie rod connection elements coinciding with the corners of a triangle, preferably a right-angled triangle. It is then advantageous if the tie rod stabilizer has a plurality of stabilizer strut areas which extend along at least two, preferably three, sides of the triangle from tie rod connection element to tie rod connection element.
- the tie rod stabilizer can have, for example, at least four tie rod connection elements, with at least four of the tie rod connection elements coinciding with the corners of a square, preferably a rectangle. It is then advantageous if the tie rod stabilizer has a plurality of stabilizer strut areas which extend along at least three, preferably four, sides of the quadrilateral from tie rod connection element to tie rod connection element.
- the tie rod stabilizer can advantageously have a stabilizer strut area that runs inclined to the longitudinal axis of the stack. Particularly advantageously, it has several stabilizer strut areas inclined in opposite directions to the longitudinal axis of the stack.
- the trellis portion may include stabilizer bar portions that extend and intersect in at least two different directions.
- the lattice area can, for example, have several stabilizer strut areas running parallel to one another and inclined to the longitudinal axis of the stack.
- it particularly advantageously has a plurality of stabilizer strut regions which run parallel to one another and are inclined in the opposite direction to the longitudinal axis of the stack.
- the tie rod stabilizer can also be in contact with a tension bracing element, e.g. a tie rod plate. It can also be in contact with another tension bracing element, e.g. another tie rod plate. This creates a simple way of preventing the tie rod stabilizer from slipping along the tie rod elements.
- the tie rod stabilizer can have an intermediate plate connection element.
- the tie rod stabilizer can have, for example, a tie rod connection element and an intermediate plate connection element.
- a tie rod element can be accommodated in the tie rod connection element.
- a part of an intermediate plate that is in contact with the tie rod stabilizer can be accommodated in the intermediate plate connection element.
- the intermediate plate can be included in the fuel cell stack.
- the intermediate plate connection element can have any shape suitable for connection to an intermediate plate.
- the intermediate plate connection element is preferably a snap connection element.
- the object is also achieved according to the invention by using a connecting element having two tie rod connection elements or one tie rod connection element and one intermediate plate connection element as a tie rod stabilizer of a fuel cell device.
- a tie rod stabilizer for a fuel cell having: two tie rod connection elements or one tie rod connection element and one intermediate plate connection element.
- connecting element and the tie rod stabilizer can have more tie rod connection elements and/or intermediate plate connection elements than here in connection with FIG Use according to the invention and the tie rod stabilizer according to the invention are explicitly mentioned.
- the intermediate plate connection element can be aligned orthogonally to the axis of the tie rod connection element.
- the axis of the tie rod connection element coincides with the axis of the tie rod element that can be connected via the tie rod connection element.
- the orthogonal orientation is preferred when the intermediate plate is planar.
- tie rod stabilizer Specific configuration options for the tie rod stabilizer have been described in connection with the fuel cell device according to the invention. Of course, they also apply to the tie rod stabilizer according to the invention discussed here and the use of the connecting element according to the invention discussed here, the structure of which can correspond to the tie rod stabilizer.
- an intermediate plate for a fuel cell stack one edge of the intermediate plate having a concave edge area, flanked by two convex edge areas, for receiving a tie rod element and a latching element, e.g. a locking head, for connecting an intermediate plate connection element of a tie rod stabilizer is.
- the intermediate plate may be connected to a tie rod stabilizer for a fuel cell, which has a tie rod connection element and an intermediate plate connection element.
- the intermediate plate connection element can be aligned orthogonally to the axis of the tie rod connection element.
- the intermediate plate can be connected to the tie rod stabilizer via a snap connection, with the intermediate plate connecting element being arranged on the remaining element, for example on a convex edge region of the intermediate plate adjoining the latching head.
- the invention also relates to a fuel cell device which includes a stack longitudinal axis stabilizer and a cell suspension element.
- the invention also relates to a fuel cell device which includes a stack longitudinal axis stabilizer and a tie rod stabilizer.
- the invention also relates to a fuel cell device which includes a cell suspension element and a tie rod stabilizer.
- the invention also relates to a fuel cell device which comprises a stack longitudinal axis stabilizer, a cell suspension element and a tie rod stabilizer.
- Figures 1 and 2 show schematically the problem of bending of a fuel cell stack
- 3 shows an intermediate plate for stabilizing the longitudinal axis of the stack; 4 connecting elements;
- Fig. 5 is a schematic representation of a
- FIG. 6 shows a detailed view of the structure of a fuel cell stack with an intermediate plate
- Fig. 8 shows a carrier with sliding support elements
- Fig. 9 is another view of the carrier of Fig. 8.
- FIG. 11 shows a fuel cell device with support cushion elements
- 16 shows a fuel cell stack in which the cell is connected to abutments via two cell suspension elements
- 17 shows a fuel cell stack in which the cell is connected to abutments via eight cell suspension elements
- FIG. 18 shows an embodiment of a cell suspension element with an abutment and damping element
- FIG. 19 shows a further embodiment of a cell suspension element with an abutment, a damping element and an abutment
- FIG. 21 is another view of the fuel cell stack of FIG. 20;
- FIG. 23 is another view of the fuel cell stack of FIG. 22;
- FIG. 25 shows another view of the tie rod stabilizer from FIG. 24
- 26 shows another tie rod stabilizer
- FIG. 28 shows another view of the fuel cell stack from FIG.
- FIGS. 27 and 29 shows another view of the fuel cell stack of FIGS. 27 and
- FIG. 31 shows an enlarged section XXXI of FIG. 30; 32-35 fuel cell stack with stack longitudinal axis stabilization via support elements and counter elements;
- 41 is a cross section of a bipolar plate in which a sliding contact surface is formed by an edge support surface
- FIG. 42 shows a schematic representation of a plate projection area accommodated in a recess of a stack longitudinal stabilizer.
- FIG. 1 and 2 show a highly simplified fuel cell device 300 that includes a fuel cell stack 100 .
- the dashed line shows a stack longitudinal axis of the fuel cell stack.
- the fuel cell device 300 when installed in a means of transportation, e.g. in a motor vehicle, it can be exposed to shocks and vibrations.
- the shock and vibration can cause the
- Fuel cell stack tends to increase along the longitudinal stack axis to bend. Bending of the longitudinal axis of the stack is shown schematically in FIG.
- the bending of the fuel cell stack 100 along the longitudinal axis of the stack can result in particular as a result of horizontal accelerations, for example when braking, accelerating and/or cornering. or as a result of vertical acceleration, for example when driving over potholes.
- the undesired bending of the fuel cell stack 100 along the stack longitudinal axis can also be favored by the fact that in the fuel cell stack 100 successive reaction zones are each sealed off by seals 108 (cf. FIG. 6).
- the sealing materials also have a residual compressibility in the clamped state, so that the flexural rigidity of the fuel cell stack 100 along the longitudinal axis of the stack is relatively low. This can be understood, for example, from Figure 6, which shows that gaskets 108 generally lie marginally between bipolar plates 104.
- FIG. 3-6 illustrate embodiments for stabilizing the longitudinal axis of the stack by means of an intermediate plate 110.
- the fuel cell device 300 includes a stack longitudinal axis stabilizer.
- the stack longitudinal axis stabilizer comprises an intermediate plate 110 inserted into the fuel cell stack 100.
- the intermediate plate 110 divides the fuel cell stack 100 into two fuel cell stack sections 102.
- 5 clearly shows that part of the intermediate plate 110 protrudes from the stack surface and is thus arranged between a stack surface of the fuel cell stack 100 running parallel to the longitudinal axis of the stack and an abutment. 5 also shows a Connection or support of the part of the intermediate plate protruding from the stack surface via a connecting element 111 on the housing or on the system frame.
- connection includes a sliding bearing.
- Connecting element 111 is slidably mounted on the abutment via the adjustable abutment element 119 .
- Assembly of the fuel cell stack is made easier by moving the adjustable abutment element 119 from a first position into a second position.
- a surface of the abutment element 119 forms an abutment contact surface 123 .
- a surface of a connecting element arranged on the intermediate plate forms a sliding contact surface 121. Adjusting the abutment element can ensure that the sliding contact surface 121 slides as desired on the abutment contact surface 123 of the adjustable abutment element 119 in the sliding contact area.
- Connector 111 may be a ceramic connector or a plastic connector, for example.
- the connecting element 111 can, for example, be attached to the intermediate plate via an elastic intermediate element, not shown here.
- connection of the fuel cell stack to the abutment shown in Fig. 5 offers further advantages, e.g. high electrical insulation, compensation for manufacturing tolerances and thermal expansion of the intermediate plate (among other things due to the elastic intermediate element).
- a tie rod element 138 can also function as an abutment (cf. FIG. 3). Each part of the intermediate plate 110 protruding from the stack surface can be connected to a respective tie rod element 138 or otherwise to an abutment via connecting elements 111 shown schematically in FIGS. 3-5.
- FIGS. 3 and 6 Possibilities for constructing the intermediate plate 110 are particularly clear from FIGS. 3 and 6, with parts of the intermediate plate protruding from the stack surface not being shown in FIG. As shown on the left in FIG. 3, two edges of the intermediate plate each have a concave edge area flanked by two convex edge areas for receiving a tie rod element.
- the design of the convex edge areas is conceivable, e.g. with locking head 284, as described in more detail below in connection with FIGS.
- connecting elements 111 can also have a stabilizing effect on the tie rod element.
- FIG. 6 shows that the intermediate plate 110 can be thicker than the bipolar plates 104 in the two fuel cell stack sections 102.
- FIG. 6 is also the location of membrane electrode assemblies 106 between the intermediate plate 110 and adjacent bipolar plates 104 and between each two bipolar plates 104 and 104 in the two fuel cell sections 102 on either side of the intermediate plate 110 are shown.
- the membrane-electrode units 106 between the intermediate plate 110 and adjacent bipolar plates 104 can be, for example, membrane-electrode units 106 with a 5-layer structure.
- the membrane-electrode units 106 between the bipolar plates 104, 104 can be, for example, membrane-electrode units 106 with a 7-layer structure.
- Seals 108 are located at the edge between the plates 104 and 110 that follow one another in the stack structure.
- an anode area 112 and a cathode area 114 are welded onto the intermediate plate, so that the surfaces of the intermediate plate 110 are in areas where the seal 108 rests , having the shape of corresponding surface areas of the bipolar plates 104 .
- 7-9 show a further possible embodiment of a stack longitudinal axis stabilization for a fuel cell device.
- a stack longitudinal axis stabilizer comprises a sliding support element 120 which supports the stack surface against a support 122 which acts as an abutment 118 .
- the sliding support elements 120 can, for example, rest directly on the outer contour of the cell.
- at least a portion of at least one slide support member 120 is located in an area of a stack surface where no fluid-conveying structures (e.g., conduits, hoses, and/or manifolds) pass.
- FIG. 7 shows only a very small section of the outer cell contour lying against the sliding support element 120 .
- the fuel cell stack can have one or more contact areas on which or on which the sliding support elements rest and support the fuel cell stack.
- the contact areas can be formed by one or more components of the fuel cell stack.
- One or more bipolar plates can also define the shape of one or more contact areas.
- the spring indicated in FIG. 7 and the dashed line symbolize the elasticity of the material from which the sliding support element 120 is made.
- the overlying cell can be protected. In the event of vibrations and impacts, the force transmission to the stack surface or the edge of one or more adjacent cells is distributed and damped over the surface of the sliding support element.
- FIG. 8 shows that sliding support elements 120 and a floating bearing element 126 are guided in a displaceable manner on the carrier 122 .
- Guide elements 124 e.g Guide rods extend parallel to the carrier 122 through the sliding support elements 120 and through the floating bearing element 126 .
- Springs 128, e.g., coil springs, may be disposed about the guide rods between the slide support members. These are shown in FIG. The ends of the springs 128 remote from the slide support members 120 may be positioned on the guide rods by spring positioning members shown in FIG.
- the abutment contact surface 123 is thus a surface of the carrier 122 here.
- the sliding contact surface 121 comprised by the stack longitudinal axis stabilizer is a surface of the sliding support element 120 facing the abutment contact surface 123 .
- the longitudinal axis of the stack is stabilized in that the surface of the stack is supported via the sliding support element 120 against a carrier 122 acting as an abutment.
- the springs 128 damp movements of the cell edges resting against the sliding support elements 120 in the direction of the longitudinal axis of the stack. This can contribute to further stabilization of the fuel cell stack.
- FIG. 10 shows an embodiment in which stabilization along the longitudinal axis of the stack takes place in a concave region of the stack surface of the fuel cell stack by a rail element 132 functioning as an abutment.
- An elastic buffer element 130 is arranged between the fuel cell stack and the rail element; it is an elastomer buffer element.
- a further element 134 can be arranged between buffer element 130 and rail element 132 .
- the further element 134 can be a sliding element, for example, which promotes a sliding of the buffer element 130 along the longitudinal axis of the rail element 132 .
- the abutment contact surface 123 is thus a surface of the rail element 132 here.
- the sliding contact surface comprised by the stack longitudinal axis stabilizer is a surface of the buffer element 130 facing the abutment contact surface 123 . In Fig. 10, not all abutment contact surfaces and sliding contact surfaces are provided with the corresponding reference numerals.
- the buffer element 130 is arranged between a concave region of the stack surface of the fuel cell stack 100 running parallel to the longitudinal axis of the fuel cell stack 100 and the rail element 132 functioning as an abutment. It is used for cell support.
- the rail element can replace a tie rod or a tie rod element 138 of a conventional fuel cell device.
- FIG. 11 shows an embodiment in which stabilization along the longitudinal axis of the stack is provided by support cushion elements 140 .
- the support pad elements 140 function as stack longitudinal axis stabilizers.
- FIG. 12 shows a further embodiment in which stabilization along the longitudinal axis of the stack is provided by support cushion elements 140 .
- the support pad elements 140 function as stack longitudinal axis stabilizers. Deviating from the embodiment shown in FIG. 11, the support cushions shown here are only in contact with the fuel cell stack 100 in a central region thereof.
- FIG. 13 shows an embodiment in which bulk material 150 stabilizes along the longitudinal axis of the stack.
- the loose material 150 acts as a stack longitudinal axis stabilizer.
- FIG. 14 shows an embodiment in which a stabilization along the longitudinal axis of the stack is effected by molded parts 160 . Moldings 160 function as stack longitudinal axis stabilizers.
- FIGS. 11 to 14 the two ends of the fuel cell stack 100 are each in contact with a force introduction plate 146.
- FIG. The structure of the fuel cell stack 100 and the two force introduction plates 146 is each arranged between a tie rod plate 142 and a pressure distributor plate 144 .
- FIG. 15 shows locations of a fuel cell device 300.
- One or more sensor element(s) for detecting a force and/or a change in the fuel cell device 300 attributable to the action of the force can be arranged at these locations.
- the arrows shown with reference number 260 point to these points, the sensor elements themselves not being shown. As shown, the points can be e.g /or a fixed storage disk.
- FIG. 16 schematically shows the interior of a fuel cell device 300, which includes: a fuel cell stack 100 and a cell suspension element 202 attached to a cell 200 of the fuel cell stack 100.
- the cell suspension element 202 connects the cell 200 to an abutment 118.
- the cell 200 includes the one also shown Membrane electrode unit 106.
- the cell 200 comprises a cell suspension frame element 222.
- the cell suspension frame element 222 comprises the cell frame element 220 and the cell suspension element 202 formed thereon.
- the cell suspension element 202 is anchored in the abutment 118 .
- FIG. 16 shows a cell 200 having two cell suspension elements 202.
- FIG. The cell suspension elements 202 protrude beyond mutually opposite stack surfaces of the fuel cell stack 100 not shown in detail here.
- Fig. 17 schematically shows the interior of another fuel cell device 300.
- Cells 200 of this fuel cell device differ from cells 200 of the fuel cell device shown in Fig. 16 essentially by a higher number of cell suspension elements 202 and corresponding abutments 118.
- Fig. 17 shows a cell 200 , which has eight cell suspension elements 202.
- the cell 200 has a substantially rectangular cross section. Three cell suspension elements are attached to each of the two long sides of the cell 200 . A cell suspension element is attached to each of the two short sides of the cell.
- the cell suspension elements 202 protrude beyond mutually opposite stack surfaces of the fuel cell stack 100 not shown in detail here.
- FIG. 18 shows a section of a further fuel cell device 300 in an enlarged view, with a cell suspension element 202 connecting the cell 200 to an abutment 118 via a damping element 230 .
- the cell suspension element 202 has a head area 204 and a neck area 206 .
- the head portion 204 is over the neck portion 206 on the cell 200 attached.
- 18 also shows that a collar area 208 is formed on the abutment 118 and that the head area 204 is accommodated in the abutment 118 by the collar area 208 extending towards the neck area 206 .
- the abutment 118 has an abutment surface 210 facing away from the cell 200 and the cell suspension member 202 has a suspension surface 212 facing the cell 200.
- FIG. The abutment surface 210 extends into an area between the cell 200 and the suspension surface 212.
- the abutment 118 also has an abutment surface 214 facing the cell 200 . Furthermore, the cell frame member 220 has a suspension surface 216 facing away from the cell. The suspension surface 216 extends into an area between the cell 200 and the abutment surface 214. This limits the cell suspension element 202 from sliding into the abutment 118.
- abutment surface 210 remote from the cell 200 is in contact with the suspension surface 212 in all of the abutments 118. There, abutment surfaces 210, 214 and suspension surfaces 212, 216 are not referenced, respectively.
- a first section of the damping element 230 extends into an area between the abutment surface 210 and the suspension surface 212.
- a second section of the damping element 230 extends into an area between the abutment surface 214 and the suspension surface 216.
- the Cell suspension element 202 from the abutment 118 so braked by a compression of the first portion of the damping element 230 and ultimately stopped. Sliding of the cell suspension element 202 into the abutment 118 is slowed down and ultimately stopped by a compression of the second section of the damping element 230 .
- the damping element 230 can contain an elastomer. It can be an elastomer bearing or an elastomer damper. This can be made, for example, from a material that can be used for seals 108 described herein.
- FIG 19 shows an embodiment with an abutment 240 arranged on a side of the cell suspension element 202 facing away from the cell.
- This abutment 240 can also counteract the cell suspension element 202 sliding into the abutment 118 .
- the anvil may be formed of a resin and/or elastomer and/or mechanically attach the cell suspension frame member 222 to the stack enclosure 174 via the cell suspension member 202 .
- cells 200 of the fuel cell stack 100 (preferably at least 10% of the cells 200 or at least every tenth cell 200 of the fuel cell stack 100, particularly preferably at least 50% of the cells 200 or at least every second cell 200 of the fuel cell stack 100, e.g. every cell 200 of the fuel cell stack 100) have cell suspension elements 202 which are attached as shown in the respective figure for the cell 200 shown there .
- the abutment or abutments 118 comprise counter-suspension elements 218. These are arranged on the stack housing 174.
- the cell suspension elements 202 lie between adjacent channel sections 250 and can delimit the channel sections 250 from one another.
- the channel sections 250 can offer the particular advantage of better ventilation of the area between the fuel cell stack 100 and the stack housing 174 .
- a gas flow for example an air flow, can be guided through the channel sections 250 . It can be guided in a meandering manner around the stack surface, as indicated in FIG. 17 with symbols which indicate an inflow towards the viewer and an outflow from the viewer. A formation of ignitable gas mixtures can thereby be avoided in the entire area and thus the operational safety of the fuel cell device can be further increased.
- FIGS. 20 and 21 show a fuel cell stack 100 for a fuel cell device from different sides. This comprises: several tie rod elements 138, tie rod plates 142 connected via the tie rod elements 138 and tie rod stabilizers 270.
- the tie rod stabilizers 270 stand between the tie rod plates 142 with three each Tie rod elements 138 in contact.
- Cells 200 are only indicated in the fuel cell stacks 100 as parallel lines.
- three mutually spaced tie rod stabilizers 270 are in contact with three tie rod elements 138 on two mutually opposite stack surfaces between the tie rod plates 142 .
- tie rod stabilizer 270 has three tie rod connection elements 272.
- a stabilizer bar area 276 extends from tie rod connection element 272 to tie rod connection element 272.
- the tie rod connection elements 272 are adapted to the tie rod shape. They each have two gripping elements that form a round receiving area for the round, rod-shaped tie rod element 138 , the inner diameter of the round receiving area being adapted to the outer diameter of the round, rod-shaped tie rod element 138 .
- the tie rod connection elements 272 are snap connection elements.
- the tie rod stabilizer shown in FIGS. 24 and 25 preferably has connection securing elements 274 in the form of openings.
- the tie rod stabilizer can be secured in the tie rod connection element 272 with a cable tie, for example, via these openings.
- the cable tie is passed through the opening and around the tie rod attached in the tie rod connection element 272 (not shown here).
- FIG. 26 shows another embodiment of a tie rod stabilizer 270 in which a stabilizer strut area 276 also extends from tie rod connection element 272 to tie rod connection element 272 .
- tie rod connection elements 272 are also snap connection elements.
- FIGS. 27 and 28 also show a fuel cell stack 100 for a fuel cell device from different sides.
- This also includes: several tie rod elements 138, tie rod plates 142 connected via the tie rod elements 138, and tie rod stabilizers 270.
- the tie rod stabilizers 270 are in contact with the tie rod element 138 between the tie rod plates 142.
- Figure 29 shows the same fuel cell stack 100 in a schematic view with a view of a bipolar plate 104 inside the fuel cell stack 100.
- the two tie rod stabilizers 270 shown in FIGS. 27 to 29 each have twelve tie rod connection elements 272, which are not all provided with reference numbers in the figures and are partially covered by other tie rod stabilizer areas.
- Four tie rod connection elements 272 of each tie rod stabilizer 270 are in contact with a tie rod element 138 .
- the tie rod connection elements 272 are each designed as shown in FIGS.
- tie rod connection elements 272 coincide with the corners of a right-angled triangle.
- tie rod attachment elements 272 one can identify many groups of three tie rod attachment elements 272 each, which coincide with the corners of a right triangle.
- stabilizer bar portions 276, 278, 280, 282 extend along at least two of the sides of the triangle from tie rod attachment 272 to tie rod attachment 272.
- stabilizer strut portions 276, 280 and 282 extend along three sides of a triangle. It can also be clearly seen from FIGS. 27 and 28 that at least four of the tie rod connection elements 272 coincide with the corners of a rectangle.
- tie rod connection elements 272 many groups of four tie rod connection elements 272 can be identified, which coincide with the corners of a rectangle. For example, there are four tie rod connection elements 272 at the four corners of tie rod stabilizer 270. In the corresponding rectangle, four stabilizer strut areas extend along the four sides of tie rod stabilizer 270 from tie rod connection element 272 to tie rod connection element 272.
- the tie rod stabilizer 270 shown in FIGS. 27 and 28 has stabilizer strut regions 276 running at right angles to the longitudinal axis of the stack as well as stabilizer strut regions 278 and 280 running inclined to the longitudinal axis of the stack.
- Fig. 30 shows tie rod stabilizers 270 connected to an intermediate plate 110.
- Fig. 31 shows a detailed view of a tie rod stabilizer 270 from Fig. 30.
- the tie rod stabilizer 270 shown in these figures has a tie rod connection element 272 and two intermediate plate connection elements 286, with only the element facing the viewer Intermediate plate connection element is provided with reference number 286.
- a tie rod element 138 can be received in the tie rod connection element 272 .
- a part of an intermediate plate 110 in contact with the tie rod stabilizer 270 is accommodated in the intermediate plate connection element 286 .
- the two intermediate plate connection elements 286 are snap connection elements.
- the tie rod stabilizer 270 clearly visible in FIG. 31 has a tie rod connection element 272 and an intermediate plate connection element 286 aligned orthogonally to the axis of the tie rod connection element 272 .
- the axis of the tie rod connection element 272 coincides with the axis of the tie rod element 138, which via the tie rod connection element 272 can be connected.
- the alignment of the intermediate plate connection element 286 orthogonal to the axis of the tie rod connection element 272 means that this axis is aligned orthogonal to the plate plane of an intermediate plate 110 that can be connected via the intermediate plate connection element 286 .
- FIGS. 30 and 31 show the tie rod stabilizer 270 on an intermediate plate 110.
- This is an intermediate plate 110 for a fuel cell stack 100.
- One edge of the intermediate plate 110 has a concave edge area flanked by two convex edge areas for receiving a tie rod element 138.
- a latching head 284 is formed on each of the two convex edge regions. The locking heads 284 are each used to connect an intermediate plate connection element 286 of the tie rod stabilizer 270.
- the sliding contact surface 121 comprised by the stack longitudinal axis stabilizer can be an inner surface of the tie rod connection element 272 .
- the abutment contact surface, not shown here, is then a surface of the tie rod element.
- FIGS. 32-40 are characterized in that a fixing area 170 (cf. Fig. 36-40) of a stack longitudinal axis stabilizer 116 made of an elastomer and/or a plastic (cf. Fig. 37), which is also part a seal-stabilizer unit 180 (see Fig. 36, 38, 39 and 40), extends into a plate gap 176 and is clamped in the plate gap 176 by the two adjacent bipolar plates 104, 104 (see Fig. 36 -40).
- a fixing area 170 cf. Fig. 36-40
- a stack longitudinal axis stabilizer 116 made of an elastomer and/or a plastic
- a seal-stabilizer unit 180 see Fig. 36, 38, 39 and 40
- FIG. 32 shows a fuel cell stack 100 with a view along the longitudinal axis of the stack onto a surface of a bipolar plate 104, the Plate gaps extending fixation areas 170 covered by the bipolar plate 104.
- support areas 178 of stack longitudinal axis stabilizers form areas which are arranged between the four stack surfaces and abutments which are not fully shown here.
- the abutment can, for example, comprise a part of the stacking enclosure, not shown here.
- the abutment comprises counter-elements 172 which can press on the support areas 178 with a defined pretensioning force, so that a deflection of the fuel cell stack 100 in relation to the longitudinal axis of the stack is made more difficult and stabilization of the longitudinal axis of the stack is thereby achieved.
- FIG. 32 also shows that counter-elements 172 can have very different shapes.
- a flat surface of a counter element 172 can press flat on a flat surface of a support area 178 .
- Counter elements 172 can also be curved and press on a surface of a support region 178 via one or more curves.
- the bipolar plate 104 shown in FIG. 33 is widened at two opposite edges. Its contour resembles that of a bone. This creates additional inward corners that can be used to stabilize the longitudinal axis of the stack.
- the inwardly arranged corners offer a good mechanical connection possibility for stack longitudinal axis stabilizers with fixing area 170 and support area 178. This is because the bipolar plates and seals have no interruption there through distributors. In principle, the corners arranged on the outside are also suitable for mechanical connection. Depending on the load characteristics, fewer than four stack longitudinal axis stabilizers can be sufficient for a space between the plates.
- the bipolar plate 104 shown in FIG. 34 has expansion areas on two opposite edges which protrude beyond the otherwise rectangular basic shape of the bipolar plate 104 . Force peaks that could lead to bending along the longitudinal axis of the stack (cf. FIGS. 1 and 2) can be absorbed particularly well in these expansion areas. In this way, these expansion areas can be braced (with) between force introduction plates or end plates of the stack, without excessive localized compression of a seal of the fuel cell stack occurring as a result.
- those of the fuel cell stack 100 shown in FIG. 35 have a rectangular shape.
- Such a seal-stabilizer unit 180 is shown in section, for example, in Figures 36, 38, 39 and 40.
- the seal-stabilizer units 180 shown there have a support area 178 connected to the seal 108 via the fixing area 170 .
- the abutments 118 can each comprise a part of the stack housing 174 and counter-elements 172 arranged thereon, which press on the support areas 178 with a defined prestressing force.
- Counter-elements 172 can be slidably arranged on the stack housing 174 in order to be able to set the defined prestressing force on the support areas of the stack longitudinal axis stabilizers 116 or seal-stabilizer units 180 .
- the abutment contact surfaces 123 are surfaces of the mating elements 172 that face the support region 178.
- Sliding contact surfaces 121 are surfaces of the support regions 178 that face the abutment contact surfaces 123.
- the sections of Fig. 36-40 show edge areas of bipolar plates 104 with membrane electrode unit 106 and seal 108 arranged between the bipolar plates 104, with a fixing area 170 which extends into an intermediate plate space 176 and with a support area 178.
- the bipolar plates 104 define a seal receiving area 190 and a stabilizer receiving area 192 at their edge.
- the stabilizer receiving area 192 lies between the edge of the bipolar plates 106 and the seal receiving area 190.
- the fixation portion 170 and the support portion 178 belong to a stack longitudinal axis stabilizer 116 that is offset from the seal 108.
- both the two areas 170 and 178 characteristic of the stack longitudinal axis stabilizer 116 and the seal 108 belong to a one-piece seal-stabilizer unit 180.
- the longest dimension of the seal 108 is greater than the longest dimension of the support portion 178.
- the support area is made thicker in the direction of the longitudinal axis of the stack than the fixing area.
- the support area has two shoulders each. The shoulders extend over the edge surfaces of the two bipolar plates between which the fixation area is fixed.
- 38 and 39 show embodiments with metal bipolar plates 104, with an optional adaptation of the edge of the bipolar plates 104.
- the adaptation of the edge is aimed at avoiding damage to the stack longitudinal axis stabilizer or the seal-stabilizer unit 180 under vibration loading.
- By bending (FIG. 38) or beading (FIG. 39) the cutting effect of the metal edge on the support area 178 or its shoulder can be reduced to a permissible level.
- an edge support surface 194 is defined on an edge surface of the bipolar plate oriented orthogonally to the plane of the plate, the width D of which, measured orthogonally to the plane of the plate, exceeds the thickness of the bipolar plate material.
- Parts of the fixing area 170 are thickened in each case in FIGS. 36-40.
- In the fixing area of FIG. 37 four thickened portions are formed on one side.
- the sliding contact surface 121 is a surface of the support element 178.
- the fixation area 170 is designed such that the force required to press the fixation area 170 between the bipolar plates 104 decreases towards the edges of the fixation area 170 .
- the thickness of the fixing portion 170 is at a thickening closest to the support member 178 and at a thickening from the support member at furthest away thickening is less than the thickness of a thickening formed between these two thickenings.
- the section in FIG. 41 also shows an edge area of bipolar plates
- an edge surface of the bipolar plate defines an edge support surface 194 whose width D measured orthogonally to the plate plane exceeds the bipolar plate material thickness.
- the longitudinal axis of the fuel cell stack can then be stabilized by arranging this edge support surface 194 on an abutment, e.g. on the stack housing.
- FIG. 1 A further possibility for stabilizing a fuel cell stack along the longitudinal axis of the stack is shown in FIG.
- An edge region of a bipolar plate 104 according to the invention is shown there.
- the recess 117 is a slot.
- the recess 117 is delimited by a recess edge area. This is continuously adapted to the edge contour of the flap shown in dotted lines. The edge area of the recess thus limits the depth and length of the recess 117.
- the support element 178 of the stack longitudinal axis stabilizer 116 is formed by a region of the stack longitudinal axis stabilizer 116 which projects beyond the tab in the plane of the bipolar plate. The edge area of the recess is therefore in the transition from the recess 117 to the support element 178.
- the sliding contact surface 121 covered by the stack longitudinal axis stabilizer is a surface of the support element 178, namely the surface of the support element 178 lying on the support element 178 opposite the edge area of the recess.
- the sliding contact surface 121 can rest, for example, on an inner surface of a stack housing, not shown in FIG.
- the tab is arranged in the recess 117 in a non-positive and positive manner.
- the stack longitudinal axis stabilizer 116 is a plastic part here, which is formed by overmolding the lug of the bipolar plate 104 with a plastic.
- the stack longitudinal axis stabilizer 116 is connected to the tab via an undercut.
- the tab has two tab indentations 125 .
- the tab indentations 125 may be openings that pass through the bipolar plate 104 in the area of the tab.
- the plastic of the stack longitudinal axis stabilizer 116 formed by overmoulding the tab extends into the tab depressions 125 .
- the stack longitudinal axis stabilizer 116 thus engages in the tab depressions 125 .
- Fuel cell stack 100 Fuel cell stack 100
- Rail element 132 further element 134
- Seal Stabilizer Unit 180 Seal Receiving Area 190 Stabilizer Receiving Area 192 Edge Support Surface 194
- Tie rod connection element 272 Connection securing element 274 Stabilizer strut area 276 Stabilizer strut area 278
- Stabilizer bar area 280 Stabilizer bar area 282
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Abstract
Description
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CN202280076465.8A CN118266112A (zh) | 2021-11-18 | 2022-11-17 | 燃料电池装置 |
DE112022005514.6T DE112022005514A5 (de) | 2021-11-18 | 2022-11-17 | Brennstoffzellenvorrichtung |
US18/661,263 US20240297329A1 (en) | 2021-11-18 | 2024-05-10 | Fuel cell device |
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DE102021213008.9 | 2021-11-18 | ||
DE102021213008.9A DE102021213008A1 (de) | 2021-11-18 | 2021-11-18 | Brennstoffzellenvorrichtung |
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US18/661,263 Continuation US20240297329A1 (en) | 2021-11-18 | 2024-05-10 | Fuel cell device |
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WO2023089072A1 true WO2023089072A1 (de) | 2023-05-25 |
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CN (1) | CN118266112A (de) |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005067086A2 (en) * | 2003-12-24 | 2005-07-21 | Toyota Jidosha Kabushiki Kaisha | Fuel cell stack structure |
EP2584640A1 (de) * | 2011-10-21 | 2013-04-24 | Siemens Aktiengesellschaft | Aufnahmegestell mit Brennstoffzellendruckbehälter |
US20170229719A1 (en) * | 2016-02-09 | 2017-08-10 | GM Global Technology Operations LLC | Robust fuel cell stack sealing materials and methods using thin elastomeric seals |
CN109585893B (zh) * | 2018-12-04 | 2021-04-06 | 大连交通大学 | 一种长寿命的燃料电池及制作方法 |
DE102020119021B3 (de) * | 2020-07-17 | 2021-07-29 | kraftwerk TUBES GmbH | Brennstoffzellenstapel, Brennstoffzellenvorrichtung sowie Brennstoffzellen-Fahrzeug |
Family Cites Families (1)
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JP5278158B2 (ja) | 2009-05-20 | 2013-09-04 | トヨタ自動車株式会社 | 車両用燃料電池 |
-
2021
- 2021-11-18 DE DE102021213008.9A patent/DE102021213008A1/de not_active Withdrawn
-
2022
- 2022-11-17 DE DE112022005514.6T patent/DE112022005514A5/de active Pending
- 2022-11-17 CN CN202280076465.8A patent/CN118266112A/zh active Pending
- 2022-11-17 WO PCT/EP2022/082352 patent/WO2023089072A1/de active Application Filing
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2024
- 2024-05-10 US US18/661,263 patent/US20240297329A1/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005067086A2 (en) * | 2003-12-24 | 2005-07-21 | Toyota Jidosha Kabushiki Kaisha | Fuel cell stack structure |
EP2584640A1 (de) * | 2011-10-21 | 2013-04-24 | Siemens Aktiengesellschaft | Aufnahmegestell mit Brennstoffzellendruckbehälter |
US20170229719A1 (en) * | 2016-02-09 | 2017-08-10 | GM Global Technology Operations LLC | Robust fuel cell stack sealing materials and methods using thin elastomeric seals |
CN109585893B (zh) * | 2018-12-04 | 2021-04-06 | 大连交通大学 | 一种长寿命的燃料电池及制作方法 |
DE102020119021B3 (de) * | 2020-07-17 | 2021-07-29 | kraftwerk TUBES GmbH | Brennstoffzellenstapel, Brennstoffzellenvorrichtung sowie Brennstoffzellen-Fahrzeug |
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DE102021213008A1 (de) | 2023-05-25 |
DE112022005514A5 (de) | 2024-08-29 |
US20240297329A1 (en) | 2024-09-05 |
CN118266112A (zh) | 2024-06-28 |
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